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WO2007037723A3 - Method for storing hydrogen by carrying out aromatic substrate hydrogenating-dehydrogenating reactions under a shf(hf) radiation effect - Google Patents

Method for storing hydrogen by carrying out aromatic substrate hydrogenating-dehydrogenating reactions under a shf(hf) radiation effect Download PDF

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Publication number
WO2007037723A3
WO2007037723A3 PCT/RU2006/000504 RU2006000504W WO2007037723A3 WO 2007037723 A3 WO2007037723 A3 WO 2007037723A3 RU 2006000504 W RU2006000504 W RU 2006000504W WO 2007037723 A3 WO2007037723 A3 WO 2007037723A3
Authority
WO
WIPO (PCT)
Prior art keywords
shf
hydrogenating
radiation effect
dehydrogenating
hydrogen
Prior art date
Application number
PCT/RU2006/000504
Other languages
French (fr)
Russian (ru)
Other versions
WO2007037723A2 (en
Inventor
Andrey Leonidovich Tarasov
Leonid Modestovich Kustov
Viktor Ignatyevich Bogdan
Arkadiy Leonidovich Kustov
Original Assignee
Obshchestvo S Ogranichennoi Ot
Andrey Leonidovich Tarasov
Leonid Modestovich Kustov
Viktor Ignatyevich Bogdan
Arkadiy Leonidovich Kustov
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Obshchestvo S Ogranichennoi Ot, Andrey Leonidovich Tarasov, Leonid Modestovich Kustov, Viktor Ignatyevich Bogdan, Arkadiy Leonidovich Kustov filed Critical Obshchestvo S Ogranichennoi Ot
Publication of WO2007037723A2 publication Critical patent/WO2007037723A2/en
Publication of WO2007037723A3 publication Critical patent/WO2007037723A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0015—Organic compounds; Solutions thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The invention relates to catalysis and organic chemistry, in particular to a method for intensifying catalytic reactions under a SHF(HF) radiation effect. The inventive hydrogen storing method is based on reversible hydrogenating-dehydrogenating catalytic reactions of an organic substrate by heating it in such a way that said substrate is absorbed and a hydrogen is released by using a heterogeneous catalyst containing a hydrocarbon or oxide carrier and an active metal applied thereto. The organic substrate is heated by the SHF or HF radiation effect. The heterogeneous catalyst is embodied in the form of an energy absorbing material comprising the hydrocarbon or oxide carrier which exhibits a high specific surface area and a high dielectric loss tangent value, and the active metal applied thereto. The SHF or HF radiation effect is produced at the atmospheric pressure and temperatures ranging from 20 to 100 °C for the hydrogenating stage and from 100 to 200 °C for the dehydrogenating stage, respectively. Said invention makes it possible to reduce the energy consumption for catalytic processes and to increase the system capacity in hydrogen with relatively low temperatures of the hydrogenating-dehydrogenating processes.
PCT/RU2006/000504 2005-09-30 2006-09-29 Method for storing hydrogen by carrying out aromatic substrate hydrogenating-dehydrogenating reactions under a shf(hf) radiation effect WO2007037723A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2005130340 2005-09-30
RU2005130340/15A RU2333885C2 (en) 2005-09-30 2005-09-30 Method of hydrogen storage by carrying out catalytic reactions of hydration/dehydration of aromatic substrates under action of shf (hf) radiation

Publications (2)

Publication Number Publication Date
WO2007037723A2 WO2007037723A2 (en) 2007-04-05
WO2007037723A3 true WO2007037723A3 (en) 2007-05-18

Family

ID=37900186

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2006/000504 WO2007037723A2 (en) 2005-09-30 2006-09-29 Method for storing hydrogen by carrying out aromatic substrate hydrogenating-dehydrogenating reactions under a shf(hf) radiation effect

Country Status (2)

Country Link
RU (1) RU2333885C2 (en)
WO (1) WO2007037723A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2699629C1 (en) * 2018-03-15 2019-09-06 федеральное государственное бюджетное образовательное учреждение высшего образования "Самарский государственный технический университет" Liquid organic hydrogen carrier, method for production thereof and hydrogen cycle based thereon
RU2725230C2 (en) * 2018-10-15 2020-06-30 федеральное государственное бюджетное образовательное учреждение высшего образования "Самарский государственный технический университет" Liquid organic hydrogen carrier, method of its production and hydrogen cycle based on it
RU2714810C1 (en) * 2018-10-15 2020-02-19 федеральное государственное бюджетное образовательное учреждение высшего образования "Самарский государственный технический университет" Method for selective hydrogenation of styrene oligomers and still residues of reaction resins (srrr), use thereof as liquid organic hydrogen carrier and hydrogen cycle based thereon
RU2741301C1 (en) * 2019-11-13 2021-01-25 федеральное государственное бюджетное образовательное учреждение высшего образования "Самарский государственный технический университет" Diphenylferrocene as liquid organic hydrogen carrier, as well as hydrogen cycle based thereon
RU2768354C1 (en) * 2021-09-28 2022-03-23 Игорь Анатольевич Мнушкин Complex for production, storage and transportation of hydrogen

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3761531A (en) * 1970-06-26 1973-09-25 Universal Oil Prod Co Dehydrogenation with a multicomponent catalyst
US5336828A (en) * 1993-03-03 1994-08-09 Sri International Hydrocarbon processing using fullerene catalysts
RU2064889C1 (en) * 1993-02-11 1996-08-10 Институт катализа им.Г.К.Борескова СО РАН Method of hydrogen and carbon material producing
RU2095136C1 (en) * 1995-05-06 1997-11-10 Акционерное общество открытого типа "Научно-исследовательский и проектный институт мономеров с опытным заводом" Nickel hydrogenation catalyst on carrier and method of preparing modified nickel hydrogenation catalyst on carrier

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3761531A (en) * 1970-06-26 1973-09-25 Universal Oil Prod Co Dehydrogenation with a multicomponent catalyst
RU2064889C1 (en) * 1993-02-11 1996-08-10 Институт катализа им.Г.К.Борескова СО РАН Method of hydrogen and carbon material producing
US5336828A (en) * 1993-03-03 1994-08-09 Sri International Hydrocarbon processing using fullerene catalysts
RU2095136C1 (en) * 1995-05-06 1997-11-10 Акционерное общество открытого типа "Научно-исследовательский и проектный институт мономеров с опытным заводом" Nickel hydrogenation catalyst on carrier and method of preparing modified nickel hydrogenation catalyst on carrier

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JUNWANG TANG ET AL.: "Microwave-Assisted Purification of Automotive Emissions", JOURNAL OF CATALYSIS, vol. 211, 2002, pages 560 - 564, XP003011848 *
SHINYA HODOSHIMA ET AL.: "Liquid-film-type catalytic decalin dehydrogeno-aromatization for long-term storage and long-distance transportation of hydrogen", INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, vol. 28, 2003, pages 197 - 204, XP003011847 *

Also Published As

Publication number Publication date
RU2333885C2 (en) 2008-09-20
RU2005130340A (en) 2007-04-10
WO2007037723A2 (en) 2007-04-05

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