Nothing Special   »   [go: up one dir, main page]

WO2006095505A1 - Heat-resistant filling and process for producing the same - Google Patents

Heat-resistant filling and process for producing the same Download PDF

Info

Publication number
WO2006095505A1
WO2006095505A1 PCT/JP2006/301400 JP2006301400W WO2006095505A1 WO 2006095505 A1 WO2006095505 A1 WO 2006095505A1 JP 2006301400 W JP2006301400 W JP 2006301400W WO 2006095505 A1 WO2006095505 A1 WO 2006095505A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil
fat
heat
fatty acid
melting point
Prior art date
Application number
PCT/JP2006/301400
Other languages
French (fr)
Japanese (ja)
Inventor
Koji Asama
Yoshio Yamawaki
Hideki Komai
Original Assignee
Fuji Oil Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Oil Company, Limited filed Critical Fuji Oil Company, Limited
Priority to JP2007507001A priority Critical patent/JPWO2006095505A1/en
Publication of WO2006095505A1 publication Critical patent/WO2006095505A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/02Other edible oils or fats, e.g. shortenings, cooking oils characterised by the production or working-up
    • A23D9/04Working-up
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/56Cocoa products, e.g. chocolate; Substitutes therefor making liquid products, e.g. for making chocolate milk drinks and the products for their preparation, pastes for spreading, milk crumb
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/346Finished or semi-finished products in the form of powders, paste or liquids

Definitions

  • the present invention relates to a filling having an oil composition composition in a foaming state having excellent heat resistance.
  • the present invention relates to heat-resistant fillings that are well melted even at high temperatures, such as in summer, and that are prevented from being deformed or changed in oil separation, and a method for producing the same.
  • oil-based products such as butter, margarine, or shortening are used as a continuous phase
  • solid fat filling, topping, etc. While maintaining the shape of solid fat filling, topping, etc. in these fat-based products such as butter and margarine and retaining aqueous components and bubbles, the solid fat melts and becomes liquid as the temperature rises.
  • Patent Document 1 proposes a method in which an oil and fat component having a melting point of 35 ° C. or less and an excellent fat and oil component including a heat-resistant extremely hardened oil are separately manufactured and then mixed. Not foamed.
  • Patent Document 2 proposes a method of rapid cooling and kneading while forcibly injecting an inert gas into a mixture in which a solid is dispersed in completely melted fats and oils.
  • Patent Document 1 the manufacturing process is complicated, and in Patent Document 2, a dedicated device is required, both of which are economically burdensome.
  • Patent Document 3 proposes adding edible wax to oils and fats to provide heat-resistant shape retention of the center cream, but the bubble-containing ability is not specified and is generally known. However, there are many expensive waxes and there is a price constraint to obtain a sufficient effect.
  • Patent Document 4 the amount of crystals at 10 ° C is small! / Emulsifier is added to fats and oils to create a soft texture
  • An aerobic oil / fat composition has been proposed, but it is clearly indicated for its heat-resistant shape retention!
  • Patent Document 1 Japanese Patent Application Laid-Open No. 62-22547
  • Patent Document 2 JP-A-3-292858
  • Patent Document 3 Japanese Patent Laid-Open No. 6-7087
  • Patent Document 4 Japanese Patent Laid-Open No. 10-276672
  • An object of the present invention is to provide fillings that have better heat resistance and better melting in the mouth than conventional products, and a method for producing the same.
  • the first of the present invention is a force that is an oily thread and composition (A) obtained by mixing a trisaturated fatty acid glyceride with an oil and fat having a melting point not higher than body temperature to make a foamed state, or the oily thread and composition.
  • These are heat resistant fillings which are oil and fat compositions (B) containing an oil and fat component.
  • the second is a force having a specific gravity of the oil and fat composition (A) of 0.2 to 0.5, or a specific gravity of the fat and oil composition (B) is 0.2 to 0.9, Filling.
  • the third is the heat-resistant filling according to the first or second aspect, wherein the fat having a melting point not higher than the body temperature is a liquid fat and / or node butter at 20 ° C.
  • the fourth is the heat-resistant filling according to any one of the first to third, wherein the tri-saturated fatty acid glyceride is a tri-saturated fatty acid glyceride containing behenic acid.
  • the fifth is the heat-resistant filling according to the fourth aspect, in which behenic acid in the saturated fatty acid is 30% by weight or more of fat and oil as trisaturated fatty acid glyceride containing behenic acid.
  • the content of behenic acid is 2.0 to 10.0% by weight in the case of the oil and fat composition (A) with respect to the total amount of fillings, and is 0. 0% in the case of the oil and fat composition (B).
  • the seventh is the heat resistant filling according to the first, further comprising an aqueous component.
  • a mixed oil of fat and trisaturated fatty acid glyceride having a melting point below the body temperature is heated to melt the crystals, and then cooled to foam in the state where crystals of the trisaturated fatty acid glycerides are precipitated. This is a method for producing heat-resistant fillings.
  • the oil and fat composition according to the present invention causes a mixed oil containing trisaturated fatty acid glycerides and edible oils and fats in a certain ratio range to crystallize under specific conditions, thereby foaming them with a simple apparatus.
  • the fillings obtained in this way are well melted in the mouth and can maintain the shape even in the high temperature range.
  • the heat-resistant fillings of the present invention are the oil and fat composition (A) obtained by mixing a tri-saturated fatty acid glyceride with an oil and fat having a melting point not higher than body temperature to make a foamed state.
  • the oil / fat composition (B) containing an oil / fat component is required.
  • the fats and oils having a melting point below body temperature are, for example, rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil , Shea fat, monkey fat, cacao butter, coconut oil, palm kernel oil and other vegetable oils or fish oils, beef tallow, pork fat and other animal fats and oils processed, separated, and ester exchanged Can be illustrated. Vegetable oils are superior in flavor compared to animal oils such as fish oil! / Therefore, vegetable oils are preferred.
  • it is a fat or oil that is liquid at 20 ° C. or Z and No, butter, and is preferred in terms of dispersing crystals of trisaturated fatty acid glycerides.
  • Tri-saturated fatty acid glycerides containing behenic acid are preferred when whipping a mixture of liquid oils and trisaturated fatty acid glycerides at 20 ° C. Even if these fats are crystalline, they are fluid in a wide temperature range. Therefore, it is preferable because workability is improved and a smooth texture can be obtained.
  • hard butter for example, tempering type fats and oils such as cacao butter and cacao substitute fat, trans type hard butter having elaidic acid as a constituent fatty acid, and lauric type fats and oils such as coconut oil, palm kernel oil and hardened oils thereof, etc. Good to use.
  • fillings obtained by whipping a mixed oil of trisaturated fatty acid glycerides containing hard butter and behenic acid are preferred because they provide good mouth melt.
  • a stearin fraction obtained by fractionating an extremely hardened oil or fat of oils and fats can be used.
  • the saturated fatty acid myristic acid, palmitic acid, stearic acid, arachidic acid, behenic acid, and lignoceric acid are preferable. Examples include extremely hardened oil of high erucic acid rapeseed oil, extremely hardened oil of palm oil, and extremely hardened oil of rice bran oil.
  • oils and fats containing erucic acid can usually be obtained by hydrogenation using an iodine value of 1 or less and a melting point of 60 ° C or more.
  • saturated behenic acid can be obtained by curing unsaturated erucic acid.
  • Oils containing 30% or more of erucic acid include rapeseed oil with high erucic acid, potato oil, clam bean oil, and burberry. The power of seed oils, etc. Highly erucic acid rapeseed oil, which is readily available, is preferred.
  • tri-saturated fatty acid glyceride is mixed with oil having a melting point not higher than body temperature to form a foamed state.
  • These mixing ratios are preferably 85:15 to 95: 5.
  • the trisaturated fatty acid glyceride is more than this ratio, not only the fluidity of the mixed oil is deteriorated and it is difficult to handle, but also the foaming property, that is, the whipping property tends to be deteriorated. Further, if the trisaturated fatty acid glyceride is less than this ratio, the whipping property and, consequently, the heat-resistant shape retention property are deteriorated.
  • the fat and oil composition is preliminarily melted with an oil having a melting point not higher than body temperature, and a trisaturated fatty acid glyceride remains as a crystal, preferably 25 to It is possible to use a method in which the temperature is adjusted in a temperature range of 45 ° C. and whipped with a simple vertical mixer or the like in addition to a continuous whipper.
  • the foamed state in the present invention refers to a state in which bubbles are stably taken into the oil and fat composition and have an appropriate plasticity when performing operations such as squeezing.
  • the heat-resistant fillings of the present invention are prepared by mixing a trisaturated fatty acid glyceride with an oil and fat having a melting point not higher than body temperature to prepare a foam composition (A), or the oil or fat. It can be obtained by preparing an oil / fat composition (B) using a non-fat component in the composition.
  • a non-fat component is added to the fat having a melting point not higher than the body temperature, and the tri-saturated fatty acid glyceride is not mixed. Includes oil and fat components and foaming It is.
  • Non-fat components include solid sugars such as sugar, milk powder, fruit juice powder, cocoa powder, coffee powder, cheese powder, eggshell powder, spices, powder seasonings, dried fruits, seeds, and freeze-dried foods.
  • solid sugars such as sugar, milk powder, fruit juice powder, cocoa powder, coffee powder, cheese powder, eggshell powder, spices, powder seasonings, dried fruits, seeds, and freeze-dried foods.
  • flavor components and flavor components such as chocolates and fragrances selected by mixing two or more of these solid component forces can be used.
  • the amount of these non-oil components used is 1 to 80% by weight, preferably 2 to 70% by weight, based on the whole filling. If it is less than 1% by weight, it contains the non-oil component, but it is the oil composition (A).
  • the heat-resistant fillings of the present invention can be used in the same way as existing flour pastes, custard creams, whipped creams or conventional fat-based fillings as confectionery bread filling materials that are not particularly limited in their applications. .
  • the heat-resistant fillings of the present invention for baked confectionery, etc. that are marketed even in the summer, when the distribution period is several months and one year is high, the effect can be further demonstrated. I can do it. That is, since the fillings of the present invention are excellent in heat resistance, the fats and oils composition is foamed, filled in a confectionery bakery, etc., sanded, and exposed to 40 ° C, which is close to the summer temperature. As a result, the shape is kept without flowing out or bubbles are removed, and the amount of oil and grease oozing out is extremely small! /, So that the commercial value can be kept in a good state.
  • the content of behenic acid is 2.0 to 10.0% by weight in the case of the oil and fat composition (A) with respect to the total amount of the fillings.
  • 0.15 to: LO. 0% by weight is preferable. If the content of behenic acid is high, the melting point of the fat becomes too high and whips, but the viscosity of the fillings increases sharply during whipping. Depending on the temperature at the time of whipping, solidification occurs during the whipping. Even if a whip is made, the heat resistance as a filling can be imparted. On the other hand, if the amount is small, the specific gravity of the fillings does not decrease, and workability such as filling and sanding and heat retention resistance cannot be obtained.
  • the specific gravity of the fat and oil composition (A) is 0.2 to 0.5, or the specific gravity of the fat and oil composition (B) to which a non-fat and fat component is added is 0.2 to 0.9. Is preferred. When the specific gravity is higher than that, the oily feeling is strongly felt and the flavor is not preferred, and the heat-resistant shape retention cannot be sufficiently obtained. Ma In order to make the specific gravity lower than that, mechanical or apparatus processes such as forced agitation and decompression are required.
  • the heat-resistant fillings of the present invention are improved in workability as a filling by making the foamed state, and overcome the contradictory problems of heat resistance and melting in the mouth.
  • the heat-resistant fillings of the present invention can have a variety of fresh flavors by further using an aqueous component.
  • aqueous component include fresh cream, compound cream, plant cream, milk, fruit juice, jam, sauce, juice, liquid sugar, maple syrup, honey, sake, extract and the like.
  • the amount of the aqueous component used is a water content within a range in which the oZw type emulsification system is maintained, and is 30% by weight or less, preferably 20% by weight or less of the whole filling.
  • the product temperature of the mixed oil is cooled to 30 to 45 ° C to precipitate crystals. It is good to use the fats and oils which adjusted after cooling. As a result, an oil / fat composition in which crystals of trisaturated fatty acid glycerides containing behenic acid are dispersed in a low-melting oil / fat having a lower melting point can be obtained, which can be suitably used as a fat / oil composition for filling. it can.
  • a device that can add a kneader, such as an onrator, to a product temperature of 30 to 45 ° C after completely mixing the fat and oil of melting point below body temperature and trisaturated fatty acid glyceride containing behenic acid. After cooling and precipitating crystals, it can be cooled and adjusted. In other methods, for example, when the solution is simply left at room temperature and slowly cooled, the size of the crystal becomes too large, and it is unsuitable for including bubbles in the oil and fat composition. On the other hand, if it is rapidly cooled using a combinator or the like, the crystal system is different, so even in the case of force, it is not suitable for including bubbles in the oil and fat composition.
  • a kneader such as an onrator
  • the present invention it is preferable to whip a mixed oil of fat and oil having a melting point below body temperature and trisaturated fatty acid glyceride containing behenic acid at a temperature at which the crystals of trisaturated fatty acid glyceride containing behenic acid do not melt.
  • the melting point was measured in accordance with the method prescribed in Japan Oil Chemistry Association Standard Oil Analysis Method (1996 version) 2.2.2.
  • the fatty acid composition was measured according to the method specified in the test method 2.4.2.1.2 Methyl esterification method (boron trifluoride methanol method).
  • the fillings of the present invention are based on the following method and criteria, specific gravity, drawability, heat-resistant shape retention (degree of maintaining the height at 40 ° C, degree of maintaining the edge at 40 ° C , Oil and fat oozing) and melting in the mouth were evaluated.
  • the specific gravity was calculated by filling the containers with fillings, measuring the weight of the contents, and dividing by the weight of water instead.
  • the product is stirred and cooled to a temperature of 30 to 45 ° C in a 15 ° C water bath.
  • the resulting fat and oil composition was obtained by dispersing trisaturated fatty acid glyceride crystals in a fat and oil having a melting point below body temperature, and the fat and oil composition was stored at 20 ° C.
  • An oil and fat composition was obtained from 11 parts of the mixed oil by the method described in paragraph [0020] and stored at 20 ° C.
  • the oil and fat composition adjusted to 40 ° C. was stirred at a high speed for 5 minutes with a Kenwood mixer (using Whisper) to obtain a foaming filling of the present invention.
  • the specific gravity was measured to be 0.28, and the drawability as a filling, heat-resistant shape retention (degree of maintaining the height at 40 ° C, degree of maintaining the edge at 40 ° C, oil and fat resistance Miso), melting in the mouth was evaluated, and these results are summarized in Table 1.
  • palm fraction oil (iodine value 45, melting point 26 ° C, Fuji Oil Co., Ltd., trade name “Pamel 26”) and 89 parts of trisaturated fatty acid glycerides containing behenic acid are high.
  • Elcic acid rapeseed oil extremely hardened oil (iodine value 1 or less, melting point 62 ° C, behenic acid 45%)
  • an oil and fat composition was obtained in the same manner as in Example 1, and at 20 ° C saved .
  • the oil and fat composition adjusted to 40 ° C. was stirred at a high speed for 5 minutes with a Kenwood mixer (using Whisper) to obtain a foaming filling of the present invention.
  • Hard butter as an oil with a melting point below body temperature (iodine value 34, melting point 34 ° C, manufactured by Fuji Oil Co., Ltd., trade name “Melano New SS7”) and 89 parts of besulic acid-containing trisaturated fatty acid glycerides
  • An extremely hard oil of acid rapeseed oil (iodine value 1 or less, melting point 62 ° C, containing 45% behenic acid) From 11 parts of mixed oil, an oil and fat composition was obtained in the same manner as in Example 1 and stored at 20 ° C .
  • the oil and fat composition adjusted to 45 ° C. was stirred at high speed for 5 minutes with a Kenwood mixer (using Whisper) to obtain a foaming filling of the present invention.
  • the specific gravity was measured to be 0.30, and it was suitable for drawing as a filling, heat-resistant shape retention (degree of maintaining the height at 40 ° C, degree of maintaining the edge at 40 ° C, Shidashi), melting in the mouth was evaluated, and these results are summarized in Table 1.
  • the conventional shortening (iodine value 51, melting point 38 ° C, Fuji Oil Co., Ltd., trade name “BSL40”) is adjusted to 30 ° C, and this is high-speed for 5 minutes with a Kenwood mixer (using Whisper). Stir and whip. Its specific gravity was measured to be 0.31, and it was suitable for drawing as a filling, heat-resistant shape retention (degree of maintaining the height at 40 ° C, degree of maintaining the edge at 40 ° C, Miso), melting in the mouth was evaluated, and these results are summarized in Table 1.
  • Partially hardened oil (iodine value 36, melting point 45 ° C) of palm middle melting point oil and fat 2 parts diglycerin monopalmitate (trade name “Poem DP95RF” manufactured by Riken Vitamin Co., Ltd.) and 1 part lecithin 80 ° After melting at C, this was whipped for 5 minutes in the same manner as in Example 1 and the specific gravity was measured to be 0.30, which was squeezable as a filling, and heat-resistant shape retention (height at 40 ° C).
  • the degree of maintenance, the degree of edge maintenance at 40 ° C, the oozing of fats and oils) and the melting in the mouth were evaluated, and the results are summarized in Table 1.
  • palm fractionated oil (iodine number 45, melting point 26 ° C, Fuji Oil Co., Ltd., trade name “Pamel 26”) 94.5 parts and trisaturated fatty acid glyceride containing behenic acid
  • Highly hardened oil of high erucic acid rapeseed oil (iodine value 1 or less, melting point 62 ° C, containing 45% behenic acid) 5.
  • the oil and fat composition adjusted to a temperature of 40 ° C. was stirred at high speed for 5 minutes with a Kenwood mixer (using Whisper) to obtain a foaming filling of the present invention.
  • palm fraction oil (iodine value 45, melting point 26 ° C, Fuji Oil Co., Ltd., trade name “Pamel 26”) 96.7 parts and trisaturated fatty acid glyceride containing behenic acid
  • Highly hardened oil of erucic acid rapeseed oil (iodine value 1 or less, melting point 62 ° C, containing 45% behenic acid) 3.
  • the fat composition adjusted to 40 ° C was stirred at high speed for 10 minutes with a Kenwood mixer (using Whisper) to obtain a foaming filling.
  • Palm fraction oil (iodine value 45, melting point 26 ° C, manufactured by Fuji Oil Co., Ltd., trade name "Pamel 26") as a fat with a melting point below body temperature 97.8 parts and trisaturated fatty acid glycerides containing behenic acid
  • Highly hardened oil of high erucic acid rapeseed oil (iodine value 1 or less, melting point 62 ° C, containing 45% behenic acid) 2.
  • the fat composition adjusted to 40 ° C was stirred at high speed for 10 minutes with a Kenwood mixer (using Whisper) and whipped.
  • the specific gravity was measured to be 0.78, and it was not possible to squeeze as a filling.
  • Example 2 50 parts of the oil / fat composition prepared in Example 2 was adjusted to a temperature of 40 ° C., 50 parts of powdered sugar was added thereto, and the mixture was stirred at high speed for 5 minutes with a Kend mixer (using Whisper) to obtain a foaming filling of the present invention. .
  • the specific gravity was measured to be 0.64, and it had physical properties suitable for squeezing as a filling. Separately, when this filling was sandwiched and eaten in cookies, a sand cream with good melting characteristics and good compatibility was obtained. In addition, even if it was placed at 40 ° C for 1 day, it was also powerful that the sand cream that exuded the fat and oil leaked out.
  • Example 2 50 parts of the oil / fat composition prepared in Example 2 was temperature-controlled at 40 ° C., and 50 parts of cheese powder was whipped at a high speed for 5 minutes with a calokenwood mixer (using Whisper). When the specific gravity was measured, it was 0.61, and it had physical properties suitable for squeezing as a filling. Aside from this, when this filling was filled into a pie and eaten, a cheese-like filling with good compatibility was obtained. Even if it is placed at 40 ° C for 1 day, it will remove oil and grease. Injury filling was also powerful. These results are summarized in Table 3.
  • Example 5 The results of Example 5, Example 6, and Example 7 are summarized in Table 3.
  • Example 2 70 parts of the oil and fat composition prepared in Example 2 was adjusted to a temperature of 40 ° C, and liquid sugar (Towa Kasei Kogyo ( Co., Ltd., concentration 70%, reduced starch saccharified product, trade name “AMAMIR” (30 parts) was added, and the mixture was whipped by stirring at high speed for 5 minutes with Kenwood mixer (using Whisper). Its specific gravity was measured to be 0.38, and the emulsified state was good, drawing suitability as a filling, heat-resistant shape retention (degree of maintaining the height at 40 ° C, maintaining the edge at 40 ° C) The degree of oozing, fat and oil oozing), and melting in the mouth were evaluated, and these results are summarized in Table 4. After eating this, it had a good melt in the mouth. In addition, when this was left to stand at 40 ° C for 1 day, the shape was maintained sufficiently, and it was powerful with no air bubbles or oil oozing out.
  • liquid sugar Towa Kasei Kogyo (
  • Comparative Example 1 The shortening used in Comparative Example 1 (iodine number 51, melting point 38 ° C, Fuji Oil Co., Ltd., trade name “BSL40”) was adjusted to 30 ° C. and used in Example 8. 30 parts of liquid sugar (manufactured by Towa Kasei Kogyo Co., Ltd., concentration 70%, reduced starch saccharified product, trade name “AMAMIR”) was added, and the mixture was whipped with a Kenwood mixer (using Whisper) for 5 minutes at high speed. The specific gravity was measured to be 0.44, the emulsified state was good, and the material had properties that could be squeezed as a filling.
  • liquid sugar manufactured by Towa Kasei Kogyo Co., Ltd., concentration 70%, reduced starch saccharified product, trade name “AMAMIR”
  • Example 8 30 parts of the liquid sugar used in Example 8 was added to 70 parts of the oil and fat composition used in Comparative Example 2, and this was whipped for 5 minutes in the same manner as in Example 1. However, the oil phase and the aqueous phase were not able to be emulsified. separated. These results are summarized in Table 4.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Edible Oils And Fats (AREA)
  • Fats And Perfumes (AREA)
  • Confectionery (AREA)

Abstract

A filling which is superior in heat resistance to conventional products and has satisfactory meltability in the mouth. The heat-resistant filling is a fat composition (A) which is obtained by mixing a fat having a melting point not higher than the body temperature with a saturated fatty acid triglyceride and whipping the mixture or is a fat composition (B) which comprises that fat composition further containing a non-fat ingredient, wherein the fat composition (A) has a specific gravity of 0.2-0.5 or the fat composition (B) has a specific gravity of 0.2-0.9.

Description

明 細 書  Specification
耐熱性フィリング類及びその製造法  Heat resistant fillings and process for producing the same
技術分野  Technical field
[0001] 本発明は、耐熱性に優れた起泡状態にある油脂組成物力もなるフィリング類に関し TECHNICAL FIELD [0001] The present invention relates to a filling having an oil composition composition in a foaming state having excellent heat resistance.
、詳しくは夏場のような気温が高い場合にも口溶けが良好であり、かつ形崩れ、油分 離などの変化が防止された耐熱性フィリング類及びその製造法に関する。 More particularly, the present invention relates to heat-resistant fillings that are well melted even at high temperatures, such as in summer, and that are prevented from being deformed or changed in oil separation, and a method for producing the same.
背景技術  Background art
[0002] 一般にバター、マーガリンまたはショートニング等の油脂主体製品を連続相とし、こ れに粉糖、粉末果汁、種子類等の固形物、液糖、果汁等の液体、さらに空気、窒素 等の気体を気泡の状態で不連続相として分散させたものが、菓子等のフィリング、トツ ビング等に利用されている。これらバター、マーガリン等の油脂主体製品中の固形脂 力 ィリング、トッピング等の形状を維持しかつ水性成分や気泡を保持するが、温度 の上昇にともない固形脂が融解し、液状状態となる。このため口溶け良好な固形脂 は夏季のような高温下では油脂組成物の形状を保つことが困難となり、フィリング、ト ッビング等としての商品価値が失われてしまう。そこで従来は夏季用の油脂組成物で はマーガリン、ショートニング等の融点を高くし、高温下での固形脂含量を増力!]させる ことで耐熱性を付与してきた。し力しながらこの方法では口溶けが悪くなり、形状は保 てても商品の完成度は高 ヽものとはならな ヽ。このような問題に対して耐熱性ある ヽ は食感、口溶けを改善する目的でこれまでに種々の提案がされて 、る。  [0002] In general, oil-based products such as butter, margarine, or shortening are used as a continuous phase, and powdered sugar, powdered fruit juice, solids such as seeds, liquids such as liquid sugar and fruit juice, and gases such as air and nitrogen Is dispersed as a discontinuous phase in the form of bubbles, and is used for filling and topping of confectionery. While maintaining the shape of solid fat filling, topping, etc. in these fat-based products such as butter and margarine and retaining aqueous components and bubbles, the solid fat melts and becomes liquid as the temperature rises. For this reason, solid fats that melt well in the mouth are difficult to maintain the shape of the oil and fat composition at high temperatures such as in the summer, and the commercial value as filling, topping, etc. is lost. Thus, in the past, oil and fat compositions for summer have been given heat resistance by increasing the melting point of margarine, shortening, etc., and increasing the solid fat content at high temperatures!]. However, with this method, the melting of the mouth worsens, and even if the shape is maintained, the perfection of the product will not be high. Various proposals have been made for heat-resistant rice cakes for such problems in order to improve the texture and the melting of the mouth.
特許文献 1では融点 35°C以下の口溶け良好な油脂成分と、耐熱性を有する極度 硬化油を含む油脂成分を個別に製造した後、これらを混合する方法が提案されてい る力 このものは起泡されていない。また、特許文献 2では完全融解した油脂中に固 形物を分散させた混合物に不活性ガスを強制的に注入しながら急冷混練する方法 が提案されている。しかし特許文献 1では、製造工程が煩雑であり、特許文献 2では 専用の装置が必要となり、いずれも経済的に負担となった。  Patent Document 1 proposes a method in which an oil and fat component having a melting point of 35 ° C. or less and an excellent fat and oil component including a heat-resistant extremely hardened oil are separately manufactured and then mixed. Not foamed. Patent Document 2 proposes a method of rapid cooling and kneading while forcibly injecting an inert gas into a mixture in which a solid is dispersed in completely melted fats and oils. However, in Patent Document 1, the manufacturing process is complicated, and in Patent Document 2, a dedicated device is required, both of which are economically burdensome.
特許文献 3では食用ワックスを油脂に加えてセンタークリームの耐熱保形性を付与 することが提案されているが、含気泡能力については明示されておらず、また一般的 にワックスには高価なものが多ぐ十分な効果を得るためには価格的な制約が生じる 特許文献 4では 10°Cでの結晶量の少な!/、油脂に乳化剤を加え、ソフトな食感の含 気油脂組成物が提案されて!ヽるが、耐熱保形性につ!ヽては明示されて!ヽな!ヽ。 Patent Document 3 proposes adding edible wax to oils and fats to provide heat-resistant shape retention of the center cream, but the bubble-containing ability is not specified and is generally known. However, there are many expensive waxes and there is a price constraint to obtain a sufficient effect. In Patent Document 4, the amount of crystals at 10 ° C is small! / Emulsifier is added to fats and oils to create a soft texture An aerobic oil / fat composition has been proposed, but it is clearly indicated for its heat-resistant shape retention!
[0003] 特許文献 1 :特開昭 62— 22547号公報 Patent Document 1: Japanese Patent Application Laid-Open No. 62-22547
特許文献 2:特開平 3 - 292858号公報  Patent Document 2: JP-A-3-292858
特許文献 3:特開平 6— 7087号公報  Patent Document 3: Japanese Patent Laid-Open No. 6-7087
特許文献 4:特開平 10— 276672号公報  Patent Document 4: Japanese Patent Laid-Open No. 10-276672
発明の開示  Disclosure of the invention
発明が解決しょうとする課題  Problems to be solved by the invention
[0004] 本発明の目的は、従来品に比べ耐熱性に優れ且つ口溶けが良好なフィリング類及 びその製造法を提供する事にある。 [0004] An object of the present invention is to provide fillings that have better heat resistance and better melting in the mouth than conventional products, and a method for producing the same.
課題を解決するための手段  Means for solving the problem
[0005] 本発明者らは鋭意研究を行った結果、特殊な装置や乳化剤を用いずとも耐熱性と 口溶けに優れたフィリング類が得られることを見出し、本発明を完成させた。 [0005] As a result of intensive studies, the present inventors have found that fillings excellent in heat resistance and melting in the mouth can be obtained without using a special apparatus or emulsifier, and completed the present invention.
即ち本発明の第 1は、体温以下の融点の油脂にトリ飽和脂肪酸グリセリドを混合し 起泡状態にしてなる油脂糸且成物 (A)である力、又は当該油脂糸且成物に更に非油脂 成分を含む油脂組成物 (B)である耐熱性フィリング類である。第 2は、油脂組成物 (A )の比重が 0. 2〜0. 5である力、又は油脂組成物(B)の比重が 0. 2〜0. 9である、 第 1記載の耐熱性フィリング類である。第 3は、体温以下の融点の油脂が 20°Cで液 状の油脂又は/及びノヽードバターである、第 1又は第 2記載の耐熱性フィリング類で ある。第 4は、トリ飽和脂肪酸グリセリドがべヘン酸を含有するトリ飽和脂肪酸グリセリド である、第 1乃至第 3何れか 1に記載の耐熱性フィリング類である。第 5は、ベヘン酸 を含有するトリ飽和脂肪酸グリセリドとして、飽和脂肪酸中のベヘン酸が 30重量%以 上の油脂である、第 4記載の耐熱性フィリング類である。第 6は、ベヘン酸の含有量が 、フィリング類全量に対して、油脂組成物 (A)の場合は 2. 0〜10. 0重量%であり、 油脂組成物(B)の場合は 0. 15〜: LO. 0重量%である、第 4記載の耐熱性フィリング 類である。第 7は、更に水性成分を含有してなる、第 1記載の耐熱性フィリング類であ る。第 8は、体温以下の融点の油脂とトリ飽和脂肪酸グリセリドの混合油を、加温して 結晶を融解させた後、冷却してトリ飽和脂肪酸グリセリドの結晶を析出させた状態で、 起泡させることを特徴とする、耐熱性フィリング類の製造法である。 That is, the first of the present invention is a force that is an oily thread and composition (A) obtained by mixing a trisaturated fatty acid glyceride with an oil and fat having a melting point not higher than body temperature to make a foamed state, or the oily thread and composition. These are heat resistant fillings which are oil and fat compositions (B) containing an oil and fat component. The second is a force having a specific gravity of the oil and fat composition (A) of 0.2 to 0.5, or a specific gravity of the fat and oil composition (B) is 0.2 to 0.9, Filling. The third is the heat-resistant filling according to the first or second aspect, wherein the fat having a melting point not higher than the body temperature is a liquid fat and / or node butter at 20 ° C. The fourth is the heat-resistant filling according to any one of the first to third, wherein the tri-saturated fatty acid glyceride is a tri-saturated fatty acid glyceride containing behenic acid. The fifth is the heat-resistant filling according to the fourth aspect, in which behenic acid in the saturated fatty acid is 30% by weight or more of fat and oil as trisaturated fatty acid glyceride containing behenic acid. Sixth, the content of behenic acid is 2.0 to 10.0% by weight in the case of the oil and fat composition (A) with respect to the total amount of fillings, and is 0. 0% in the case of the oil and fat composition (B). 15-: LO. 0% by weight, The heat-resistant filling according to the fourth item. The seventh is the heat resistant filling according to the first, further comprising an aqueous component. The Eighth, a mixed oil of fat and trisaturated fatty acid glyceride having a melting point below the body temperature is heated to melt the crystals, and then cooled to foam in the state where crystals of the trisaturated fatty acid glycerides are precipitated. This is a method for producing heat-resistant fillings.
発明の効果  The invention's effect
[0006] 本発明にかかわる油脂組成物は、トリ飽和脂肪酸グリセリドと食用油脂をそれぞれ 一定比率の範囲で含有する混合油を特定の条件で結晶析出させることにより、これ を簡易な装置で起泡させて得られたフィリング類は口溶けが良好でかつ、高温域に ぉ ヽても形状を維持することができる。  [0006] The oil and fat composition according to the present invention causes a mixed oil containing trisaturated fatty acid glycerides and edible oils and fats in a certain ratio range to crystallize under specific conditions, thereby foaming them with a simple apparatus. The fillings obtained in this way are well melted in the mouth and can maintain the shape even in the high temperature range.
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0007] 本発明の耐熱性フィリング類は、体温以下の融点の油脂にトリ飽和脂肪酸グリセリド を混合し起泡状態にしてなる油脂組成物 (A)であるか、又は当該油脂組成物に更に 非油脂成分を含む油脂組成物 (B)であることが必要である。 [0007] The heat-resistant fillings of the present invention are the oil and fat composition (A) obtained by mixing a tri-saturated fatty acid glyceride with an oil and fat having a melting point not higher than body temperature to make a foamed state. The oil / fat composition (B) containing an oil / fat component is required.
本発明における体温以下の融点の油脂とは、例えば菜種油、大豆油、ヒマヮリ種子 油、綿実油、落花生油、米糠油、コーン油、サフラワー油、ォリーブ油、カポック油、 胡麻油、月見草油、パーム油、シァ脂、サル脂、カカオ脂、ヤシ油、パーム核油等の 植物性油脂又は、魚油、牛脂、豚脂等の動物性油脂並びにそれらの硬化、分別、ェ ステル交換等を施した加工油脂が例示できる。植物性油脂は魚油等の動物性油脂 に比べて風味上優れて!/、るので植物性油脂が好ま 、。  In the present invention, the fats and oils having a melting point below body temperature are, for example, rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil , Shea fat, monkey fat, cacao butter, coconut oil, palm kernel oil and other vegetable oils or fish oils, beef tallow, pork fat and other animal fats and oils processed, separated, and ester exchanged Can be illustrated. Vegetable oils are superior in flavor compared to animal oils such as fish oil! / Therefore, vegetable oils are preferred.
更に好ましくは、 20°Cで液状の油脂又は Z及びノ、ードバターであり、トリ飽和脂肪 酸グリセリドの結晶を分散させる点にぉ 、て好まし 、。  More preferably, it is a fat or oil that is liquid at 20 ° C. or Z and No, butter, and is preferred in terms of dispersing crystals of trisaturated fatty acid glycerides.
[0008] 20°Cで液状の油脂とトリ飽和脂肪酸グリセリドの混合油をホイップする際、ベヘン酸 を含有するトリ飽和脂肪酸グリセリドが好ましぐこれらの油脂が結晶状態でも広い温 度帯において流動性を有しているので作業性が向上するとともに滑らかな食感が得 られるので好ましい。または、好ましくは、ハードバター例えば、カカオ脂、カカオ代用 脂等のテンパリング型油脂、エライジン酸を構成脂肪酸とするトランス型ハードバター 並びにヤシ油、パーム核油及びこれらの硬化油等のラウリン型油脂を使用するのが 良い。ハードバターとベヘン酸を含有するトリ飽和脂肪酸グリセリドの混合油をホイツ プして得られるフィリング類は良好な口溶けが得られるので好ま 、。 [0009] 本発明におけるトリ飽和脂肪酸グリセリドは、油脂の極度硬化油又は油脂を分別し て得るステアリン画分を使用できる。飽和脂肪酸としては、ミリスチン酸、パルミチン酸 、ステアリン酸、ァラキン酸、ベヘン酸、リグノセリン酸が好ましい。例えば、高エルシ ン酸菜種油の極度硬化油、パーム油の極度硬化油、米糠油の極度硬化油等のもの があげられる。 [0008] Tri-saturated fatty acid glycerides containing behenic acid are preferred when whipping a mixture of liquid oils and trisaturated fatty acid glycerides at 20 ° C. Even if these fats are crystalline, they are fluid in a wide temperature range. Therefore, it is preferable because workability is improved and a smooth texture can be obtained. Or, preferably, hard butter, for example, tempering type fats and oils such as cacao butter and cacao substitute fat, trans type hard butter having elaidic acid as a constituent fatty acid, and lauric type fats and oils such as coconut oil, palm kernel oil and hardened oils thereof, etc. Good to use. Fillings obtained by whipping a mixed oil of trisaturated fatty acid glycerides containing hard butter and behenic acid are preferred because they provide good mouth melt. [0009] As the tri-saturated fatty acid glyceride in the present invention, a stearin fraction obtained by fractionating an extremely hardened oil or fat of oils and fats can be used. As the saturated fatty acid, myristic acid, palmitic acid, stearic acid, arachidic acid, behenic acid, and lignoceric acid are preferable. Examples include extremely hardened oil of high erucic acid rapeseed oil, extremely hardened oil of palm oil, and extremely hardened oil of rice bran oil.
好ましくは、ベヘン酸を含有するトリ飽和脂肪酸グリセリドが好ましい。具体的には、 エルシン酸を含む油脂を水素添カ卩により通常沃素価 1以下、融点 60°C以上にするこ とにより得ることができる。(不飽和のエルシン酸を硬化すれば、飽和のベヘン酸を得 ることができる。)エルシン酸を 30%以上含む油脂としては高エルシン酸の菜種油、 力 し油、クランべ油、うぜんばれん種子油等が挙げられる力 容易に入手可能な高 エルシン酸の菜種油が好ま 、。  A trisaturated fatty acid glyceride containing behenic acid is preferred. Specifically, oils and fats containing erucic acid can usually be obtained by hydrogenation using an iodine value of 1 or less and a melting point of 60 ° C or more. (Saturated behenic acid can be obtained by curing unsaturated erucic acid.) Oils containing 30% or more of erucic acid include rapeseed oil with high erucic acid, potato oil, clam bean oil, and burberry. The power of seed oils, etc. Highly erucic acid rapeseed oil, which is readily available, is preferred.
[0010] 本発明では体温以下の融点の油脂にトリ飽和脂肪酸グリセリドを混合し起泡状態に するのである力 これらの混合割合は、 85 : 15〜95 : 5の割合で混合するのが良い。 当該トリ飽和脂肪酸グリセリドがこの割合より多いと、混合油の流動性を悪くして扱い にくいばかりか、起泡性即ちホイップ性が悪くなる傾向がある。また当該トリ飽和脂肪 酸グリセリドがこの割合より少な 、とホイップ性、ひ ヽては耐熱保形性が悪くなる。  [0010] In the present invention, tri-saturated fatty acid glyceride is mixed with oil having a melting point not higher than body temperature to form a foamed state. These mixing ratios are preferably 85:15 to 95: 5. When the trisaturated fatty acid glyceride is more than this ratio, not only the fluidity of the mixed oil is deteriorated and it is difficult to handle, but also the foaming property, that is, the whipping property tends to be deteriorated. Further, if the trisaturated fatty acid glyceride is less than this ratio, the whipping property and, consequently, the heat-resistant shape retention property are deteriorated.
[0011] 起泡する即ちホイップする方法としては、当該油脂糸且成物を予め体温以下の融点 の油脂が融解し、且つトリ飽和脂肪酸グリセリドが結晶として残存するような温度域、 好ましくは 25〜45°Cの温度域にて温調しておき、これを連続ホイッパーの他、簡便 な縦型ミキサー等でホイップする方法を用いることが可能である。  [0011] As a method of foaming, that is, whipping, the fat and oil composition is preliminarily melted with an oil having a melting point not higher than body temperature, and a trisaturated fatty acid glyceride remains as a crystal, preferably 25 to It is possible to use a method in which the temperature is adjusted in a temperature range of 45 ° C. and whipped with a simple vertical mixer or the like in addition to a continuous whipper.
本発明での起泡状態とは油脂組成物中に気泡が安定的に取り込まれ、且つ絞り出 し等の作業を行なう上で適度な可塑性を有するものを指す。  The foamed state in the present invention refers to a state in which bubbles are stably taken into the oil and fat composition and have an appropriate plasticity when performing operations such as squeezing.
[0012] 上記方法において本発明の耐熱性フィリング類は、体温以下の融点の油脂にトリ飽 和脂肪酸グリセリドを混合し起泡状態にして油脂組成物 (A)を調製するか、又は当 該油脂組成物に更に非油脂成分を使用して油脂組成物 (B)を調製することにより得 ることができる。この場合、体温以下の融点の油脂にトリ飽和脂肪酸グリセリドを混合 し予め起泡状態にした後、非油脂成分を加える態様も、体温以下の融点の油脂にト リ飽和脂肪酸グリセリドを混合し、非油脂成分も加え起泡状態にする態様も含むもの である。 [0012] In the above method, the heat-resistant fillings of the present invention are prepared by mixing a trisaturated fatty acid glyceride with an oil and fat having a melting point not higher than body temperature to prepare a foam composition (A), or the oil or fat. It can be obtained by preparing an oil / fat composition (B) using a non-fat component in the composition. In this case, after adding a tri-saturated fatty acid glyceride to a fat having a melting point not higher than the body temperature to obtain a foamed state in advance, a non-fat component is added to the fat having a melting point not higher than the body temperature, and the tri-saturated fatty acid glyceride is not mixed. Includes oil and fat components and foaming It is.
非油脂成分としては、砂糖をはじめとする糖類、粉乳、果汁粉末、ココア粉末、コー ヒー粉末、チーズ粉末、卵殻粉末、香辛料、粉末調味料、ドライフルーツ、種子類、フ リーズドライ食品等の固形分やこれらの固形分力 2種以上選択してなるチョコレート 類や香料等の各種呈味成分や風味成分を用いることができる。  Non-fat components include solid sugars such as sugar, milk powder, fruit juice powder, cocoa powder, coffee powder, cheese powder, eggshell powder, spices, powder seasonings, dried fruits, seeds, and freeze-dried foods. Various flavor components and flavor components such as chocolates and fragrances selected by mixing two or more of these solid component forces can be used.
これら非油脂成分の使用量としては、フィリング類全体に対して 1〜80重量%であり 、好ましくは 2〜70重量%である。 1重量%未満のものについては非油脂成分を含ん で 、ても、油脂組成物 (A)とする。  The amount of these non-oil components used is 1 to 80% by weight, preferably 2 to 70% by weight, based on the whole filling. If it is less than 1% by weight, it contains the non-oil component, but it is the oil composition (A).
本発明の耐熱性フィリング類はその用途に特に限定はなぐ製菓製パン用フィリン グ材として既存のフラワーペースト、カスタードクリーム、ホイップクリームあるいは従来 のショートニングを用いた油脂主体のフィリング類と同様に使用できる。特に流通期 間が数ケ月力 1力年程度と長ぐ気温が高くなる夏場でも市販される常温流通焼き 菓子等に本発明の耐熱性フィリング類を用いることで、その効果をより発揮することが 出来る。すなわち、本発明のフィリング類は耐熱性に優れているため、当該油脂組成 物を起泡させ製菓製パン等に充填、サンドし、これを夏場の気温に近い 40°Cにさらし てもフィリング類が流れ出したり気泡が抜けることなく形状は保たれ、且つ油脂のしみ だしが極端に少な!/、ため、商品価値を良好な状態に保つことが可能となる。  The heat-resistant fillings of the present invention can be used in the same way as existing flour pastes, custard creams, whipped creams or conventional fat-based fillings as confectionery bread filling materials that are not particularly limited in their applications. . In particular, by using the heat-resistant fillings of the present invention for baked confectionery, etc. that are marketed even in the summer, when the distribution period is several months and one year is high, the effect can be further demonstrated. I can do it. That is, since the fillings of the present invention are excellent in heat resistance, the fats and oils composition is foamed, filled in a confectionery bakery, etc., sanded, and exposed to 40 ° C, which is close to the summer temperature. As a result, the shape is kept without flowing out or bubbles are removed, and the amount of oil and grease oozing out is extremely small! /, So that the commercial value can be kept in a good state.
[0013] 本発明の耐熱性フィリング類は、ベヘン酸の含有量が、フィリング類全量に対して、 油脂組成物 (A)の場合は 2. 0〜10. 0重量%であり、油脂組成物(B)の場合は 0. 1 5〜: LO. 0重量%であることが好ましい。ベヘン酸の含有量が多いと油脂の融点が高 くなりすぎホイップはするもののホイップ途中でフィリング類の粘度増加が激しぐホイ ップ時の温度によってはホイップ途中で固化してしまう。さらにホイップができたとして もフィリング類としての耐熱性は付与される力 非常に口溶けの悪いものになってしま う。逆に少ない場合、フィリング類の比重が低下せず充填やサンド等の作業適性、耐 熱保形性が得られない。  [0013] In the heat resistant fillings of the present invention, the content of behenic acid is 2.0 to 10.0% by weight in the case of the oil and fat composition (A) with respect to the total amount of the fillings. In the case of (B), 0.15 to: LO. 0% by weight is preferable. If the content of behenic acid is high, the melting point of the fat becomes too high and whips, but the viscosity of the fillings increases sharply during whipping. Depending on the temperature at the time of whipping, solidification occurs during the whipping. Even if a whip is made, the heat resistance as a filling can be imparted. On the other hand, if the amount is small, the specific gravity of the fillings does not decrease, and workability such as filling and sanding and heat retention resistance cannot be obtained.
[0014] 油脂組成物 (A)の比重が 0. 2〜0. 5であるか、又は非油脂成分を加えた油脂組 成物(B)の比重が 0. 2〜0. 9であるのが好ましい。比重がそれよりも高い場合は油 性感を強く感じ風味的に好ましくないばかりか、耐熱保形性が十分に得られない。ま た、比重をそれよりも低くするには強制攪拌、減圧等の機械、あるいは装置的な工程 が必要となる。 [0014] The specific gravity of the fat and oil composition (A) is 0.2 to 0.5, or the specific gravity of the fat and oil composition (B) to which a non-fat and fat component is added is 0.2 to 0.9. Is preferred. When the specific gravity is higher than that, the oily feeling is strongly felt and the flavor is not preferred, and the heat-resistant shape retention cannot be sufficiently obtained. Ma In order to make the specific gravity lower than that, mechanical or apparatus processes such as forced agitation and decompression are required.
このように本発明の耐熱性フィリング類は、起泡状態とすることによって、フィリング 類としての作業性が向上すると共に、耐熱性と口溶けという矛盾する課題を克服した ものである。  As described above, the heat-resistant fillings of the present invention are improved in workability as a filling by making the foamed state, and overcome the contradictory problems of heat resistance and melting in the mouth.
[0015] 本発明の耐熱性フィリング類は、更に水性成分を使用することにより、みずみずしい 風味の多様ィ匕が可能となる。水性成分としては、生クリーム、コンパゥンドクリーム、植 物性クリーム、れん乳、果汁、ジャム、ソース、ジュース、液糖、メイプルシロップ、蜂蜜 、酒、エキス等が挙げられる。  [0015] The heat-resistant fillings of the present invention can have a variety of fresh flavors by further using an aqueous component. Examples of the aqueous component include fresh cream, compound cream, plant cream, milk, fruit juice, jam, sauce, juice, liquid sugar, maple syrup, honey, sake, extract and the like.
水性成分の使用量としては oZw型の乳化系が保たれる範囲の水分量であって、 フィリング類全体の 30重量%以下、好ましくは 20重量%以下である。  The amount of the aqueous component used is a water content within a range in which the oZw type emulsification system is maintained, and is 30% by weight or less, preferably 20% by weight or less of the whole filling.
[0016] 本発明では体温以下の融点の油脂とベヘン酸を含有するトリ飽和脂肪酸グリセリド の混合油を完全に融解した後、混合油の品温を 30〜45°Cまで冷却し結晶を析出さ せた後、冷却して調整した油脂を使用するのが良い。このことによりべヘン酸を含有 するトリ飽和脂肪酸グリセリドの結晶をそれより融点の低い低融点油脂中に分散させ てなる油脂組成物が得られ、これはフィリング用油脂組成物として好適に用いること ができる。体温以下の融点の油脂とベヘン酸を含有するトリ飽和脂肪酸グリセリドの 混合油脂を完全に融解した後、オンレーター等の練りを加えることのできる装置を用 いて、品温を 30〜45°Cまで冷却し結晶を析出させた後、冷却させて調整することが できる。これ以外の方法、例えば単純に室温に放置して徐冷却した場合では結晶の サイズが大きくなり過ぎ油脂組成物に気泡を含ませるには不向きとなる。逆にコンビ ネーターなどを用いて急冷却させると結晶系が異なるため力 の場合も油脂組成物 に気泡を含ませるには不向きとなる。 [0016] In the present invention, after the mixed oil of fat and oil having a melting point below body temperature and trisaturated fatty acid glyceride containing behenic acid is completely melted, the product temperature of the mixed oil is cooled to 30 to 45 ° C to precipitate crystals. It is good to use the fats and oils which adjusted after cooling. As a result, an oil / fat composition in which crystals of trisaturated fatty acid glycerides containing behenic acid are dispersed in a low-melting oil / fat having a lower melting point can be obtained, which can be suitably used as a fat / oil composition for filling. it can. Use a device that can add a kneader, such as an onrator, to a product temperature of 30 to 45 ° C after completely mixing the fat and oil of melting point below body temperature and trisaturated fatty acid glyceride containing behenic acid. After cooling and precipitating crystals, it can be cooled and adjusted. In other methods, for example, when the solution is simply left at room temperature and slowly cooled, the size of the crystal becomes too large, and it is unsuitable for including bubbles in the oil and fat composition. On the other hand, if it is rapidly cooled using a combinator or the like, the crystal system is different, so even in the case of force, it is not suitable for including bubbles in the oil and fat composition.
[0017] 本発明では体温以下の融点の油脂とベヘン酸を含有するトリ飽和脂肪酸グリセリド の混合油を、ベヘン酸を含有するトリ飽和脂肪酸グリセリドの結晶が融解しない温度 でホイップすることが好ま 、。特にべヘン酸を含有するトリ飽和脂肪酸グリセリドが 結晶状態で存在することが必要であり、これによりべヘン酸を含有するトリ飽和脂肪 酸グリセリドは他の油脂、例えばノヽードバター等と相互作用しないためフィリングの口 溶けを悪くしない。しかし、完全に融解した状態で使用した場合ホイップするために 必要な結晶量が不足しフィリングの比重が低下しないばかりか、ベヘン酸を含有する トリ飽和脂肪酸グリセリドが例えばノ、ードバターと相互作用し、油脂の融点を上昇させ 最終フィリングの耐熱性は上がる力 口溶けが非常に悪いものとなる。このため体温 以下の融点の油脂とベヘン酸を含有するトリ飽和脂肪酸グリセリドの混合油の品温は[0017] In the present invention, it is preferable to whip a mixed oil of fat and oil having a melting point below body temperature and trisaturated fatty acid glyceride containing behenic acid at a temperature at which the crystals of trisaturated fatty acid glyceride containing behenic acid do not melt. In particular, it is necessary for trisaturated fatty acid glycerides containing behenic acid to exist in a crystalline state, so that trisaturated fatty acid glycerides containing behenic acid do not interact with other fats and oils such as node butter. Filling mouth Does not worsen melting. However, when used in a completely melted state, not only does the amount of crystals necessary for whipping become insufficient and the specific gravity of the filling does not decrease, but also trisaturated fatty acid glycerides containing behenic acid interact with eg butter and Increases the melting point of fats and oils and increases the heat resistance of the final filling. For this reason, the product temperature of the mixed oil of fats and oils with melting points below body temperature and trisaturated fatty acid glycerides containing behenic acid is
25〜45°Cの範囲に温度調整し、これらを混合してホイップする必要がある。但し、テ ンパリング型のハードバターを使用する場合、テンパリングを行ったフィリングのテン ノ リングが壊れない温度例えば 31°Cでホイップすることが必要となる。 It is necessary to adjust the temperature in the range of 25 to 45 ° C, mix these, and whip. However, when using a tempering type hard butter, it is necessary to whip at a temperature at which the tenoring of the tempering filling does not break, for example, 31 ° C.
実施例  Example
[0018] 以下に本発明の実施例を示し本発明をより詳細に説明する力 本発明の精神は以 下の実施例に限定されるものではない。なお、例中、%及び部は、いずれも重量基 準を意味する。  [0018] The power of the present invention will be described in more detail below with reference to examples of the present invention. The spirit of the present invention is not limited to the following examples. In the examples, “%” and “part” mean weight standards.
融点は日本油化学協会基準油脂分析試験法 (1996年版) 2. 2. 4. 2融点 (上昇 融点)に規定の方法に準じて測定した。また、脂肪酸組成は同試験法 2. 4. 1. 2メチ ルエステル化法 (三フッ化ホウ素メタノール法)に規定の方法に準じて測定した。  The melting point was measured in accordance with the method prescribed in Japan Oil Chemistry Association Standard Oil Analysis Method (1996 version) 2.2.2. The fatty acid composition was measured according to the method specified in the test method 2.4.2.1.2 Methyl esterification method (boron trifluoride methanol method).
[0019] 本発明のフィリング類は以下の方法と基準に基づいて、比重、絞り適性、耐熱保形 性 (40°Cでの高さの維持の度合い、 40°Cでのエッジの維持の度合い、油脂のしみだ し)、 口溶けを評価した。 [0019] The fillings of the present invention are based on the following method and criteria, specific gravity, drawability, heat-resistant shape retention (degree of maintaining the height at 40 ° C, degree of maintaining the edge at 40 ° C , Oil and fat oozing) and melting in the mouth were evaluated.
,比重  ,specific gravity
比重の測定は容器にフィリング類を充填して内容物の重量を測定し、かわりに水の 重量で除して算出した。  The specific gravity was calculated by filling the containers with fillings, measuring the weight of the contents, and dividing by the weight of water instead.
,絞り適性  , Squeezing aptitude
星型口金と絞り袋を用いてフィリング類を絞り出した際に保形性があり、かつ、エツ ジ (かど)の出来具合が明瞭であるものを良好であると評価した。  When the fillings were squeezed out using a star-shaped base and a squeeze bag, it was evaluated that it had good shape retention and had a clear edge.
'耐熱保形性  'Heat-resistant shape retention
フィリング類を、高さ 4cm、重さ約 9gになるよう、透明榭脂容器に絞り出し、これを 2 0°C、 1日静置して力も 40°C、 1日保持した後の状態力も評価した。すなわち 40°Cで の高さの維持の度合いは、 40°C1日後の高さを 0時間の高さで除して算出した。 40 °Cでのエッジの維持の度合い、油脂のしみだしについては目視により評価した。 •口溶け Squeeze the fillings into a transparent grease container so that the height is 4cm and the weight is about 9g, and leave it at 20 ° C for 1 day, and the force is 40 ° C. did. In other words, the degree of maintaining the height at 40 ° C was calculated by dividing the height after 1 day at 40 ° C by the height of 0 hours. 40 The degree of edge maintenance at ° C and the oozing of oil and fat were evaluated visually. • Melting mouth
官能評価を行なった。  Sensory evaluation was performed.
[0020] (体温以下の融点の油脂にトリ飽和脂肪酸グリセリドの結晶を分散させてなる油脂組 成物の調整方法)  [0020] (Preparation method of oil and fat composition in which crystals of trisaturated fatty acid glyceride are dispersed in fat and oil having a melting point below body temperature)
体温以下の融点の油脂とトリ飽和脂肪酸グリセリドの混合油を一旦完全に 80°Cで 融解した後、水温 15°Cの水浴中で油脂の品温が 30〜45°Cまで攪拌冷却して油脂 の結晶を析出させ、体温以下の融点の油脂にトリ飽和脂肪酸グリセリドの結晶を分散 させてなる油脂組成物を得、この油脂組成物を 20°Cで保存した。  Once the oil and fat with a melting point below body temperature and the trisaturated fatty acid glyceride are completely melted at 80 ° C, the product is stirred and cooled to a temperature of 30 to 45 ° C in a 15 ° C water bath. The resulting fat and oil composition was obtained by dispersing trisaturated fatty acid glyceride crystals in a fat and oil having a melting point below body temperature, and the fat and oil composition was stored at 20 ° C.
[0021] 実施例 1 [0021] Example 1
体温以下の融点の油脂として低エルシン酸の菜種油の微水添油(沃素価 95、融点 10°C) 89部とベヘン酸を含有するトリ飽和脂肪酸グリセリドとして高エルシン酸菜種 油の極度硬化油(沃素価 1以下、融点 62°C、ベヘン酸 45%含有) 11部の混合油か ら段落番号〔0020〕記載の方法にて油脂組成物を得、 20°Cで保存した。 40°Cに温 調した当該油脂組成物をケンウッドミキサー (ホイツパー使用)で 5分間高速攪拌し起 泡状態の本発明のフィリングを得た。その比重を測定したところ 0. 28であり、フィリン グとしての絞り適性、耐熱保形性 (40°Cでの高さの維持の度合い、 40°Cでのエッジ の維持の度合い、油脂のしみだし)、口溶けを評価し、これらの結果を表 1に纏めた。  Ultra-hardened oil of low erucic acid rapeseed oil as tri-saturated fatty acid glyceride containing 89 parts of low erucic acid rapeseed oil (iodine number 95, melting point 10 ° C) and behenic acid as fat with melting point below body temperature (Iodine number 1 or less, melting point 62 ° C, containing 45% behenic acid) An oil and fat composition was obtained from 11 parts of the mixed oil by the method described in paragraph [0020] and stored at 20 ° C. The oil and fat composition adjusted to 40 ° C. was stirred at a high speed for 5 minutes with a Kenwood mixer (using Whisper) to obtain a foaming filling of the present invention. The specific gravity was measured to be 0.28, and the drawability as a filling, heat-resistant shape retention (degree of maintaining the height at 40 ° C, degree of maintaining the edge at 40 ° C, oil and fat resistance Miso), melting in the mouth was evaluated, and these results are summarized in Table 1.
[0022] 実施例 2 [0022] Example 2
体温以下の融点の油脂としてパーム分別油 (沃素価 45、融点 26°C、不二製油 (株 )製、商品名「パーメル 26」)89部とベヘン酸を含有するトリ飽和脂肪酸グリセリドとし て高エルシン酸菜種油の極度硬化油(沃素価 1以下、融点 62°C、ベヘン酸 45%含 有) 11部の混合油から実施例 1と同様の方法にて油脂組成物を得、 20°Cで保存した 。 40°Cに温調した当該油脂組成物をケンウッドミキサー(ホイツパー使用)で 5分間高 速攪拌し起泡状態の本発明のフィリングを得た。その比重を測定したところ 0. 29で あり、フィリングとしての絞り適性、耐熱保形性 (40°Cでの高さの維持の度合い、 40°C でのエッジの維持の度合い、油脂のしみだし)、 口溶けを評価し、これらの結果を表 1 に纏めた。 [0023] 実施例 3 As oil with a melting point below body temperature, palm fraction oil (iodine value 45, melting point 26 ° C, Fuji Oil Co., Ltd., trade name “Pamel 26”) and 89 parts of trisaturated fatty acid glycerides containing behenic acid are high. Elcic acid rapeseed oil extremely hardened oil (iodine value 1 or less, melting point 62 ° C, behenic acid 45%) From 11 parts of mixed oil, an oil and fat composition was obtained in the same manner as in Example 1, and at 20 ° C saved . The oil and fat composition adjusted to 40 ° C. was stirred at a high speed for 5 minutes with a Kenwood mixer (using Whisper) to obtain a foaming filling of the present invention. Its specific gravity was measured to be 0.29, and it was squeezable as a filling, heat-resistant shape retention (degree of maintaining the height at 40 ° C, degree of maintaining the edge at 40 ° C, and exudation of oil and fat. ), Melting in the mouth was evaluated, and these results are summarized in Table 1. [0023] Example 3
体温以下の融点の油脂としてハードバター (沃素価 34、融点 34°C、不二製油 (株) 製、商品名「メラノ New SS7」) 89部とベヘン酸を含有するトリ飽和脂肪酸グリセリド として高エルシン酸菜種油の極度硬化油(沃素価 1以下、融点 62°C、ベヘン酸 45% 含有) 11部の混合油から実施例 1と同様の方法にて油脂組成物を得、 20°Cで保存 した。 45°Cに温調した当該油脂組成物をケンウッドミキサー(ホイツパー使用)で 5分 間高速攪拌し起泡状態の本発明のフィリングを得た。その比重を測定したところ 0. 3 0であり、フィリングとしての絞り適性、耐熱保形性 (40°Cでの高さの維持の度合い、 4 0°Cでのエッジの維持の度合い、油脂のしみだし)、 口溶けを評価し、これらの結果を 表 1に纏めた。  Hard butter as an oil with a melting point below body temperature (iodine value 34, melting point 34 ° C, manufactured by Fuji Oil Co., Ltd., trade name “Melano New SS7”) and 89 parts of besulic acid-containing trisaturated fatty acid glycerides An extremely hard oil of acid rapeseed oil (iodine value 1 or less, melting point 62 ° C, containing 45% behenic acid) From 11 parts of mixed oil, an oil and fat composition was obtained in the same manner as in Example 1 and stored at 20 ° C . The oil and fat composition adjusted to 45 ° C. was stirred at high speed for 5 minutes with a Kenwood mixer (using Whisper) to obtain a foaming filling of the present invention. The specific gravity was measured to be 0.30, and it was suitable for drawing as a filling, heat-resistant shape retention (degree of maintaining the height at 40 ° C, degree of maintaining the edge at 40 ° C, Shidashi), melting in the mouth was evaluated, and these results are summarized in Table 1.
[0024] 比較例 1 [0024] Comparative Example 1
従来製品であるショートニング (沃素価 51、融点 38°C、不二製油 (株)製、商品名「 BSL40」)を 30°Cに温調し、これをケンウッドミキサー(ホイツパー使用)で 5分間高速 攪拌しホイップさせた。その比重を測定したところ 0. 31であり、フィリングとしての絞り 適性、耐熱保形性 (40°Cでの高さの維持の度合い、 40°Cでのエッジの維持の度合 い、油脂のしみだし)、口溶けを評価し、これらの結果を表 1に纏めた。  The conventional shortening (iodine value 51, melting point 38 ° C, Fuji Oil Co., Ltd., trade name “BSL40”) is adjusted to 30 ° C, and this is high-speed for 5 minutes with a Kenwood mixer (using Whisper). Stir and whip. Its specific gravity was measured to be 0.31, and it was suitable for drawing as a filling, heat-resistant shape retention (degree of maintaining the height at 40 ° C, degree of maintaining the edge at 40 ° C, Miso), melting in the mouth was evaluated, and these results are summarized in Table 1.
[0025] 比較例 2 [0025] Comparative Example 2
パーム中融点油脂の部分硬化油(沃素価 36、融点 45°C) 97部にジグリセリンモノ パルミテート (理研ビタミン社製、商品名「ポエム DP95RF」)を 2部、レシチンを 1部を 加え 80°Cで融解した後、これを実施例 1と同様に 5分間ホイップし、その比重を測定 したところ 0. 30であり、フィリングとしての絞り適性、耐熱保形性 (40°Cでの高さの維 持の度合い、 40°Cでのエッジの維持の度合い、油脂のしみだし)、口溶けを評価し、 これらの結果を表 1に纏めた。  Partially hardened oil (iodine value 36, melting point 45 ° C) of palm middle melting point oil and fat 2 parts diglycerin monopalmitate (trade name “Poem DP95RF” manufactured by Riken Vitamin Co., Ltd.) and 1 part lecithin 80 ° After melting at C, this was whipped for 5 minutes in the same manner as in Example 1 and the specific gravity was measured to be 0.30, which was squeezable as a filling, and heat-resistant shape retention (height at 40 ° C). The degree of maintenance, the degree of edge maintenance at 40 ° C, the oozing of fats and oils) and the melting in the mouth were evaluated, and the results are summarized in Table 1.
[0026] 比較例 3 [0026] Comparative Example 3
低エルシン酸の菜種油の微水添油(沃素価 95) 89部とベヘン酸を含有するトリ飽 和脂肪酸グリセリドとして高エルシン酸菜種油の極度硬化油(沃素価 1以下、融点 62 °C) 11部の混合油をー且 80°Cで融解した後、コンビネーターを用いて品温 10°Cま で急冷 '混和した。この混合油を実施例 1と同様に 5分ホイップしても起泡せず、さら に 10分まで延長してホイップしても本発明のような起泡状態とはならな力つた。その 比重を測定したところ 0. 86であり、フィリング類として絞れるような状態にはならなか つた。これらの結果を表 1に纏めた。 Low hydrogenated erucic acid rapeseed oil (iodine value 95) 89 parts and high erucic acid rapeseed oil as tri-saturated fatty acid glyceride containing behenic acid (iodine value 1 or less, melting point 62 ° C) 11 parts The mixed oil was melted at 80 ° C. and then rapidly cooled to a product temperature of 10 ° C. using a combinator. Even if this mixed oil was whipped for 5 minutes in the same manner as in Example 1, foaming did not occur. Even when the whip was extended for 10 minutes, the foaming state as in the present invention was not strong. The specific gravity was measured and found to be 0.86, and it was not possible to squeeze as fillings. These results are summarized in Table 1.
実施例 1〜実施 3及び比較例 1〜比較例 3の結果を表 1に纏めた。  The results of Examples 1 to 3 and Comparative Examples 1 to 3 are summarized in Table 1.
[表 1] [table 1]
Figure imgf000011_0001
実施例 4
Figure imgf000011_0001
Example 4
体温以下の融点の油脂としてパーム分別油 (沃素価 45、融点 26°C、不二製油 (株 )製、商品名「パーメル 26」)94. 5部とベヘン酸を含有するトリ飽和脂肪酸グリセリドと して高エルシン酸菜種油の極度硬化油(沃素価 1以下、融点 62°C、ベヘン酸 45% 含有) 5. 5部の混合油から上記方法にて油脂組成物を得、 20°Cで保存した。 40°C に温調した当該油脂組成物をケンウッドミキサー (ホイツパー使用)で 5分間高速攪拌 し起泡状態の本発明のフィリングを得た。その比重を測定したところ 0. 29であり、フィ リングとしての絞り適性、耐熱保形性 (40°Cでの高さの維持の度合い、 40°Cでのエツ ジの維持の度合い、油脂のしみだし)、口溶けを評価し、これらの結果を表 2に纏め た。 As a fat with a melting point below body temperature, palm fractionated oil (iodine number 45, melting point 26 ° C, Fuji Oil Co., Ltd., trade name “Pamel 26”) 94.5 parts and trisaturated fatty acid glyceride containing behenic acid Highly hardened oil of high erucic acid rapeseed oil (iodine value 1 or less, melting point 62 ° C, containing 45% behenic acid) 5. Obtain fat composition from 5 parts of mixed oil by the above method and store at 20 ° C did. The oil and fat composition adjusted to a temperature of 40 ° C. was stirred at high speed for 5 minutes with a Kenwood mixer (using Whisper) to obtain a foaming filling of the present invention. The specific gravity was measured to be 0.29. Evaluate squeezability as a ring, heat-resistant shape retention (degree of maintenance of height at 40 ° C, degree of maintenance of edge at 40 ° C, exudation of oil and fat), and melting in the mouth. It is summarized in Table 2.
[0029] 比較例 4  [0029] Comparative Example 4
体温以下の融点の油脂としてパーム分別油 (沃素価 45、融点 26°C、不二製油 (株 )製、商品名「パーメル 26」)96. 7部とベヘン酸を含有するトリ飽和脂肪酸グリセリドと して高エルシン酸菜種油の極度硬化油(沃素価 1以下、融点 62°C、ベヘン酸 45% 含有) 3. 3部の混合油から上記方法にて油脂組成物を得、 20°Cで保存した。 40°C に温調した当該油脂組成物をケンウッドミキサー (ホイツパー使用)で 10分間高速攪 拌し起泡状態のフィリングを得た。その比重を測定したところ 0. 31であり、フィリング としての絞り適性、耐熱保形性 (40°Cでの高さの維持の度合い、 40°Cでのエッジの 維持の度合い、油脂のしみだし)、 口溶けを評価し、これらの結果を表 2に纏めた。  As a fat with a melting point below body temperature, palm fraction oil (iodine value 45, melting point 26 ° C, Fuji Oil Co., Ltd., trade name “Pamel 26”) 96.7 parts and trisaturated fatty acid glyceride containing behenic acid Highly hardened oil of erucic acid rapeseed oil (iodine value 1 or less, melting point 62 ° C, containing 45% behenic acid) 3. Obtain oil composition from 3 parts of mixed oil by the above method and store at 20 ° C did. The fat composition adjusted to 40 ° C was stirred at high speed for 10 minutes with a Kenwood mixer (using Whisper) to obtain a foaming filling. Its specific gravity was measured to be 0.31, and it was squeezable as a filling, heat-resistant shape retention (degree of maintaining the height at 40 ° C, degree of maintaining the edge at 40 ° C, and exudation of oil and fat. ), Melting in the mouth was evaluated, and these results are summarized in Table 2.
[0030] 比較例 5 [0030] Comparative Example 5
体温以下の融点の油脂としてパーム分別油 (沃素価 45、融点 26°C、不二製油 (株 )製、商品名「パーメル 26」) 97. 8部とベヘン酸を含有するトリ飽和脂肪酸グリセリドと して高エルシン酸菜種油の極度硬化油(沃素価 1以下、融点 62°C、ベヘン酸 45% 含有) 2. 2部の混合油から上記方法にて油脂組成物を得、 20°Cで保存した。 40°C に温調した当該油脂組成物をケンウッドミキサー (ホイツパー使用)で 10分間高速攪 拌しホイップさせた。その比重を測定したところ 0. 78であり、フィリングとして絞れるよ うな状態にはならなかった。これらの結果を表 2に纏めた。  Palm fraction oil (iodine value 45, melting point 26 ° C, manufactured by Fuji Oil Co., Ltd., trade name "Pamel 26") as a fat with a melting point below body temperature 97.8 parts and trisaturated fatty acid glycerides containing behenic acid Highly hardened oil of high erucic acid rapeseed oil (iodine value 1 or less, melting point 62 ° C, containing 45% behenic acid) 2. Obtain oil composition from 2 parts of mixed oil by the above method and store at 20 ° C did. The fat composition adjusted to 40 ° C was stirred at high speed for 10 minutes with a Kenwood mixer (using Whisper) and whipped. The specific gravity was measured to be 0.78, and it was not possible to squeeze as a filling. These results are summarized in Table 2.
[0031] 実施例 4、比較例 4、比較例 5の結果を表 2に纏めた。 [0031] The results of Example 4, Comparative Example 4, and Comparative Example 5 are summarized in Table 2.
[表 2]
Figure imgf000013_0001
[Table 2]
Figure imgf000013_0001
[0032] 実施例 5 [0032] Example 5
実施例 2で作製した油脂組成物 50部を 40°C温調し、これに粉糖 50部を加えケンゥ ッドミキサー (ホイツパー使用)で 5分間高速攪拌し起泡状態の本発明のフィリングを 得た。その比重を測定したところ 0. 64であり、フィリングとして絞るために適した物性 を有していた。これとは別に、このフィリングをクッキーにサンドして食したところ、相性 が良ぐ口溶けのよいサンドクリームが得られた。また、これを 40°Cに 1日置いても油 脂のしみだしゃ泡抜けがなぐサンドクリームが流れ出すこともな力つた。これらの結 果を表 3に纏めた。  50 parts of the oil / fat composition prepared in Example 2 was adjusted to a temperature of 40 ° C., 50 parts of powdered sugar was added thereto, and the mixture was stirred at high speed for 5 minutes with a Kend mixer (using Whisper) to obtain a foaming filling of the present invention. . The specific gravity was measured to be 0.64, and it had physical properties suitable for squeezing as a filling. Separately, when this filling was sandwiched and eaten in cookies, a sand cream with good melting characteristics and good compatibility was obtained. In addition, even if it was placed at 40 ° C for 1 day, it was also powerful that the sand cream that exuded the fat and oil leaked out. These results are summarized in Table 3.
[0033] 実施例 6 [0033] Example 6
実施例 2で作製した油脂組成物 50部を 40°C温調し、これにチーズ粉末 50部をカロ ぇケンウッドミキサー(ホイツパー使用)で 5分間高速攪拌しホイップさせた。その比重 を測定したところ 0. 61であり、フィリングとして絞るために適した物性を有していた。こ れとは別に、このフィリングをパイにフィリングして食したところ、相性が良ぐチーズ風 味の良好なフィリングが得られた。これを 40°Cに 1日置いても油脂のしみだしゃ泡抜 けがなぐフィリングが流れ出すこともな力つた。これらの結果を表 3に纏めた。 50 parts of the oil / fat composition prepared in Example 2 was temperature-controlled at 40 ° C., and 50 parts of cheese powder was whipped at a high speed for 5 minutes with a calokenwood mixer (using Whisper). When the specific gravity was measured, it was 0.61, and it had physical properties suitable for squeezing as a filling. Aside from this, when this filling was filled into a pie and eaten, a cheese-like filling with good compatibility was obtained. Even if it is placed at 40 ° C for 1 day, it will remove oil and grease. Injury filling was also powerful. These results are summarized in Table 3.
[0034] 実施例 7 [0034] Example 7
実施例 2で作製した油脂組成物 100部を 40°C温調し、これにスクラロース(三栄源 エフ'エフ'アイ (株)製 商品名「サンスイート su— 100」、蔗糖を 1とした場合の甘味 度は約 600) 0. 5部を加えケンウッドミキサー(ホイツパー使用)で 5分間高速攪拌し 起泡状態の本発明のフィリングを得た。その比重を測定したところ 0. 31であり、フイリ ングとして絞るために適した物性を有していた。これとは別に、このフィリングをクッキ 一にサンドして食したところ、相性が良ぐ口溶けのよいサンドクリームが得られた。ま た、これを 40°Cに 1日置いても油脂のしみだしゃ泡抜けがなぐサンドクリームが流れ 出すこともなかった。これらの結果を表 3に纏めた。  When 100 parts of the fat and oil composition prepared in Example 2 was temperature-controlled at 40 ° C., and sucralose (trade name “Sunsweet su-100” manufactured by San-Eigen F. F. Eye Co., Ltd.) and sucrose as 1. The sweetness of this product was about 600). 0.5 part was added, and the mixture was stirred at high speed for 5 minutes with a Kenwood mixer (using Whisper) to obtain a foaming filling of the present invention. When the specific gravity was measured, it was 0.31, and it had physical properties suitable for narrowing as a filling. Separately, when this filling was eaten with a crisp sand, a well-melted sand cream with good compatibility was obtained. In addition, even if this was placed at 40 ° C for 1 day, the sand cream that did not allow the oil to leak out did not flow out. These results are summarized in Table 3.
[0035] 実施例 5、実施例 6、実施例 7の結果を表 3に纏めた。 The results of Example 5, Example 6, and Example 7 are summarized in Table 3.
[表 3]  [Table 3]
Figure imgf000014_0001
Figure imgf000014_0001
[0036] 実施例 8 [0036] Example 8
実施例 2で作製した油脂組成物 70部を 40°C温調し、これに液糖 (東和化成工業 ( 株)製、濃度 70%、還元澱粉糖化物、商品名「アマミール」) 30部を加えケンウッドミ キサー (ホイツパー使用)で 5分間高速攪拌しホイップさせた。その比重を測定したと ころ 0. 38であり乳化状態は良好で、フィリングとしての絞り適性、耐熱保形性 (40°C での高さの維持の度合い、 40°Cでのエッジの維持の度合い、油脂のしみだし)、口 溶けを評価し、これらの結果を表 4に纏めた。これを食したところ良好な口溶けを有し ていた。また、 40°Cにて 1日これを静置したところ、形状は十分保たれており、気泡の 抜けや油脂のしみだしも見られな力つた。 70 parts of the oil and fat composition prepared in Example 2 was adjusted to a temperature of 40 ° C, and liquid sugar (Towa Kasei Kogyo ( Co., Ltd., concentration 70%, reduced starch saccharified product, trade name “AMAMIR” (30 parts) was added, and the mixture was whipped by stirring at high speed for 5 minutes with Kenwood mixer (using Whisper). Its specific gravity was measured to be 0.38, and the emulsified state was good, drawing suitability as a filling, heat-resistant shape retention (degree of maintaining the height at 40 ° C, maintaining the edge at 40 ° C) The degree of oozing, fat and oil oozing), and melting in the mouth were evaluated, and these results are summarized in Table 4. After eating this, it had a good melt in the mouth. In addition, when this was left to stand at 40 ° C for 1 day, the shape was maintained sufficiently, and it was powerful with no air bubbles or oil oozing out.
[0037] 比較例 6 [0037] Comparative Example 6
比較例 1で用いたショートニング (沃素価 51、融点 38°C、不二製油 (株)製、商品名 「BSL40」) 70部を 30°Cに温調し、これに実施例 8で用いた液糖 (東和化成工業 (株 )製、濃度 70%、還元澱粉糖化物、商品名「アマミール」) 30部を加えケンウッドミキ サー (ホイツパー使用)で 5分間高速攪拌しホイップさせた。その比重を測定したとこ ろ 0. 44であり、乳化状態は良好でフィリングとして絞れる物性を有していた。これを 食したところヌルヌルとした食感で、口溶けが悪く口中で高融点成分が残った。また、 40°Cにて 1日これを静置したところ、形状はかなり変形しており油脂の滲み出しもか なり認められた。これらの結果を表 4に纏めた。  The shortening used in Comparative Example 1 (iodine number 51, melting point 38 ° C, Fuji Oil Co., Ltd., trade name “BSL40”) was adjusted to 30 ° C. and used in Example 8. 30 parts of liquid sugar (manufactured by Towa Kasei Kogyo Co., Ltd., concentration 70%, reduced starch saccharified product, trade name “AMAMIR”) was added, and the mixture was whipped with a Kenwood mixer (using Whisper) for 5 minutes at high speed. The specific gravity was measured to be 0.44, the emulsified state was good, and the material had properties that could be squeezed as a filling. As a result of eating this, it had a slimy texture, with poor melting in the mouth and high melting point components remaining in the mouth. In addition, when this was left to stand at 40 ° C for 1 day, the shape was considerably deformed and oil and oil oozing was observed. These results are summarized in Table 4.
[0038] 比較例 7 [0038] Comparative Example 7
比較例 2で用いた油脂組成物 70部に、実施例 8で用いた液糖を 30部加え、これを 実施例 1と同様に 5分間ホイップしたが、乳化できずに油相と水相が分離した。これら の結果を表 4に纏めた。  30 parts of the liquid sugar used in Example 8 was added to 70 parts of the oil and fat composition used in Comparative Example 2, and this was whipped for 5 minutes in the same manner as in Example 1. However, the oil phase and the aqueous phase were not able to be emulsified. separated. These results are summarized in Table 4.
[0039] 実施例 8、比較例 6、比較例 7の結果を表 4に纏めた。 [0039] The results of Example 8, Comparative Example 6, and Comparative Example 7 are summarized in Table 4.
[表 4]
Figure imgf000016_0001
[Table 4]
Figure imgf000016_0001
産業上の利用可能性 Industrial applicability
本発明により、特殊な装置や乳化剤を用いずとも耐熱性と口溶けに優れたフィリン グ類及びその製造法を提供することが可能になったのである。  According to the present invention, it is possible to provide fillings excellent in heat resistance and mouth melting without using a special apparatus or emulsifier and a method for producing the same.

Claims

請求の範囲 The scope of the claims
[1] 体温以下の融点の油脂にトリ飽和脂肪酸グリセリドを混合し起泡状態にしてなる油脂 組成物 (A)である力、又は当該油脂組成物に更に非油脂成分を含む油脂組成物( [1] Oil or fat composition (A) obtained by mixing a trisaturated fatty acid glyceride with a fat having a melting point not higher than body temperature to form a foam, or an oil or fat composition further containing a non-fat component in the oil or fat composition (
B)である耐熱性フィリング類。 B) Heat resistant fillings.
[2] 油脂組成物 (A)の比重が 0. 2〜0. 5である力、又は油脂組成物(B)の比重が 0. 2[2] The oil or fat composition (A) has a specific gravity of 0.2 to 0.5, or the oil or fat composition (B) has a specific gravity of 0.2.
〜0. 9である、請求項 1記載の耐熱性フィリング類。 The heat-resistant filling according to claim 1, which is ˜0.9.
[3] 体温以下の融点の油脂が 20°Cで液状の油脂又は Z及びノ、ードバターである、請求 項 1又は請求項 2記載の耐熱性フィリング類。 [3] The heat-resistant filling according to claim 1 or claim 2, wherein the fat or oil having a melting point not higher than body temperature is oil or fat that is liquid at 20 ° C, or Z, No, and butter.
[4] トリ飽和脂肪酸グリセリドがべヘン酸を含有するトリ飽和脂肪酸グリセリドである、請求 項 1乃至請求項 3何れか 1項に記載の耐熱性フィリング類。 [4] The heat-resistant filling according to any one of claims 1 to 3, wherein the tri-saturated fatty acid glyceride is a tri-saturated fatty acid glyceride containing behenic acid.
[5] ベヘン酸を含有するトリ飽和脂肪酸グリセリドとして、飽和脂肪酸中のベヘン酸が 30 重量%以上の油脂である、請求項 4記載の耐熱性フィリング類。 5. The heat-resistant filling according to claim 4, wherein the trisaturated fatty acid glyceride containing behenic acid is behenic acid in a saturated fatty acid of 30% by weight or more.
[6] ベヘン酸の含有量が、フィリング類全量に対して、油脂組成物 (A)の場合は 2. 0〜1[6] The content of behenic acid is 2.0 to 1 in the case of the oil and fat composition (A) with respect to the total amount of fillings.
0. 0重量%であり、油脂組成物(B)の場合は 0. 15〜: L0. 0重量%である、請求項 4 記載の耐熱性フィリング類。 The heat-resistant filling according to claim 4, which is 0.0% by weight, and in the case of the oil and fat composition (B), 0.15 to: L0.0% by weight.
[7] 更に水性成分を含有してなる、請求項 1記載の耐熱性フィリング類。 7. The heat-resistant filling according to claim 1, further comprising an aqueous component.
[8] 体温以下の融点の油脂とトリ飽和脂肪酸グリセリドの混合油を、加温して結晶を融解 させた後、冷却してトリ飽和脂肪酸グリセリドの結晶を析出させた状態で、起泡させる ことを特徴とする、耐熱性フィリング類の製造法。 [8] A mixed oil of fat and trisaturated fatty acid glyceride having a melting point not higher than body temperature is heated to melt crystals, and then cooled to foam in a state where crystals of trisaturated fatty acid glyceride are precipitated. A process for producing heat-resistant fillings characterized by
PCT/JP2006/301400 2005-03-08 2006-01-30 Heat-resistant filling and process for producing the same WO2006095505A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007507001A JPWO2006095505A1 (en) 2005-03-08 2006-01-30 Heat resistant fillings and process for producing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005-063887 2005-03-08
JP2005063887 2005-03-08

Publications (1)

Publication Number Publication Date
WO2006095505A1 true WO2006095505A1 (en) 2006-09-14

Family

ID=36953109

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2006/301400 WO2006095505A1 (en) 2005-03-08 2006-01-30 Heat-resistant filling and process for producing the same

Country Status (4)

Country Link
JP (1) JPWO2006095505A1 (en)
KR (1) KR20070117538A (en)
CN (1) CN101115397A (en)
WO (1) WO2006095505A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009060829A (en) * 2007-09-05 2009-03-26 Fuji Oil Co Ltd Bubble-containing chocolate and method for preparing the same
WO2019021615A1 (en) * 2017-07-25 2019-01-31 不二製油グループ本社株式会社 Foamable oil-in-water-type emulsion and method for manufacturing foamed oil-in-water-type emulsion

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101075559B1 (en) * 2009-09-28 2011-10-20 씨제이제일제당 (주) A process for preparing hard butter

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000057715A1 (en) * 1999-03-30 2000-10-05 Fuji Oil Company, Limited Foamed chocolate and process for producing the same
JP2003250448A (en) * 2002-03-05 2003-09-09 Lotte Co Ltd Chocolate confectionery and method for producing the same
JP2003265109A (en) * 2002-03-15 2003-09-24 Fuji Oil Co Ltd Air bubble-containing chocolate-coated confectionery and method for producing the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000057715A1 (en) * 1999-03-30 2000-10-05 Fuji Oil Company, Limited Foamed chocolate and process for producing the same
JP2003250448A (en) * 2002-03-05 2003-09-09 Lotte Co Ltd Chocolate confectionery and method for producing the same
JP2003265109A (en) * 2002-03-15 2003-09-24 Fuji Oil Co Ltd Air bubble-containing chocolate-coated confectionery and method for producing the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009060829A (en) * 2007-09-05 2009-03-26 Fuji Oil Co Ltd Bubble-containing chocolate and method for preparing the same
WO2019021615A1 (en) * 2017-07-25 2019-01-31 不二製油グループ本社株式会社 Foamable oil-in-water-type emulsion and method for manufacturing foamed oil-in-water-type emulsion
JPWO2019021615A1 (en) * 2017-07-25 2019-08-08 不二製油株式会社 Foamable oil-in-water emulsion and process for producing the foamed oil-in-water emulsion

Also Published As

Publication number Publication date
CN101115397A (en) 2008-01-30
KR20070117538A (en) 2007-12-12
JPWO2006095505A1 (en) 2008-08-14

Similar Documents

Publication Publication Date Title
RU2422032C2 (en) Food products with low content of saturated and trans-isomeric unsaturated fats
JP5634264B2 (en) Oil and fat composition and plastic oil and fat composition
JP5980682B2 (en) Oil and fat composition and method for producing the same
JP5519933B2 (en) Organized granular composition
TWI548347B (en) An oil-in-oil composition for a foamed oil-in-water emulsion, and a foamed oil-in-water type emulsion containing the fat and oil composition
EP1992231A1 (en) Food products with low content of saturated and trans unsaturated fats
JP6788238B1 (en) Frozen dessert oil and fat composition and chocolates for frozen dessert
da Silva Lannes et al. Structuring fat foods
JP6571933B2 (en) Oil composition for butter cream and butter cream using the same
JPS62259545A (en) Soft cream composition filled with soybean oil
JP2010004806A (en) Oil-and-fat composition for baked confectionery
JP4930294B2 (en) Aerated chocolate and method for producing the same
WO2006095505A1 (en) Heat-resistant filling and process for producing the same
JP2000129286A (en) Oil-and-fat composition and its preparation
JP3818182B2 (en) Foam-containing chocolate-coated confectionery and method for producing the same
JP5317999B2 (en) Butter cream
WO2002080692A1 (en) Process for producing water-containing chocolates
EP2030508A1 (en) Reduced fat content products, with low saturated and trans unsaturated fat content
CN111328883B (en) Non-hydrogenated oil and fat composition and application thereof in food
JP7099001B2 (en) Oil composition for butter cream
JP6063717B2 (en) Method for producing chocolate compound food
JP7330608B2 (en) fat composition
JPH0669341B2 (en) Heat-resistant edible oil and fat composition and method for producing the same
JP2021101647A (en) Fillings
JP2016189703A (en) Production method of chocolate material for confectionery

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2007507001

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 1020077015376

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 200680004207.X

Country of ref document: CN

NENP Non-entry into the national phase

Ref country code: DE

NENP Non-entry into the national phase

Ref country code: RU

WWW Wipo information: withdrawn in national office

Ref document number: RU

122 Ep: pct application non-entry in european phase

Ref document number: 06712543

Country of ref document: EP

Kind code of ref document: A1

WWW Wipo information: withdrawn in national office

Ref document number: 6712543

Country of ref document: EP