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WO2004110642A1 - Electrostatic atomizer with anion ion generating function and air cleaner using same - Google Patents

Electrostatic atomizer with anion ion generating function and air cleaner using same Download PDF

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Publication number
WO2004110642A1
WO2004110642A1 PCT/JP2004/007597 JP2004007597W WO2004110642A1 WO 2004110642 A1 WO2004110642 A1 WO 2004110642A1 JP 2004007597 W JP2004007597 W JP 2004007597W WO 2004110642 A1 WO2004110642 A1 WO 2004110642A1
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WO
WIPO (PCT)
Prior art keywords
liquid
edge
electrostatic atomizer
carrier
ionization needle
Prior art date
Application number
PCT/JP2004/007597
Other languages
French (fr)
Japanese (ja)
Inventor
Kazuhiro Suzuki
Kenji Obata
Takayuki Nakada
Hiroshi Suda
Mikio Ito
Atsushi Isaka
Original Assignee
Matsushita Electric Works, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Works, Ltd. filed Critical Matsushita Electric Works, Ltd.
Publication of WO2004110642A1 publication Critical patent/WO2004110642A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/14Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • A61L9/145Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes air-liquid contact processes, e.g. scrubbing
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/22Ionisation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F6/00Air-humidification, e.g. cooling by humidification
    • F24F6/12Air-humidification, e.g. cooling by humidification by forming water dispersions in the air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/30Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by ionisation
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/22Treatment by sorption, e.g. absorption, adsorption, chemisorption, scrubbing, wet cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/017Combinations of electrostatic separation with other processes, not otherwise provided for

Definitions

  • the present invention relates to an electrostatic atomizer having a negative ion generating function and an air purifier using the same.
  • the present invention relates to an electrostatic atomizer having a minus ion generating function added to an electrostatic atomizer function for discharging liquid as fine charged particles, and an air purifier using the same.
  • Japanese Patent Publication No. 3260 150 discloses a conventional electrostatic atomizer.
  • This electrostatic atomizer uses a capillary structure as a liquid carrier, supplies the liquid to the discharge end at the tip of the carrier using the capillary action, and transports the liquid so that the liquid is positively charged.
  • a high voltage is applied between the transmitter and the surrounding eight housings to discharge liquid from the discharge end as charged fine particles.
  • it is proposed to improve the indoor environment by causing corona discharge in air to negatively charge molecules such as oxygen, oxygen compounds, and nitrogen compounds present in the air to generate negative ions. Have been. Disclosure of the invention
  • An object of the present invention is to provide an electrostatic atomizer capable of generating the air and an air purifier incorporating the electrostatic atomizer.
  • the electrostatic atomizer according to the present invention includes a carrier, the carrier having a liquid collecting end and a discharging end opposite to the liquid collecting end, wherein the liquid collecting end collects the liquid and discharges the liquid. Convey to the edge.
  • This device includes a negative electrode for electrically charging the liquid to be negative, an opposite electrode facing the discharge end to create a predetermined potential difference with the negative electrode, and a voltage source.
  • the voltage source applies a voltage between the negative electrode and the counter electrode, charges the liquid at the discharge end, and discharges it as fine negatively charged particles.
  • the apparatus is further provided with an ionization needle, electrically connected to the negative electrode, and disposed close to the counter electrode, so that corona discharge occurs between the tip of the ionization needle and the effective electrode. They are generated to produce negative ions.
  • the counter electrode is negatively charged in cooperation with the discharge end of the carrier.
  • a first edge for generating fine particles of the liquid, a second edge for generating the negative ions in cooperation with the ionization needle, and a shortest distance between the second edge and the ionization needle is equal to the first edge. It is longer than the shortest distance from the discharge end.
  • a plurality of carriers are arranged circumferentially around the ionization needle, so that a large amount of liquid can be electrostatically atomized.
  • the counter electrode has an opening edge ⁇ a single opening, around which a plurality of arcuate edges are aligned.
  • Each arc-shaped portion surrounds the opposite discharge end at a fixed distance to define the first edge, and a connection point between two adjacent arc-shaped edges forms the second edge.
  • the apparatus is provided with a tank for storing the liquid, and the carrier collects the liquid by immersing the liquid collecting end in the liquid in the tank and transports the collected liquid to the discharging end.
  • the ionization needle protrudes into this tank and maintains electrical contact with the liquid, so that the ionization needle is reliably kneaded on the negative side of the high voltage applied to the liquid.
  • the electrostatic liquid atomizing device having such a configuration into a device such as an air purifier.
  • the air purifier is equipped with a filter that traps contaminants and a fan that circulates air through this filter, so the atomizer is installed inside the fan and the downstream of the filter. I do.
  • the fine charged fine particles of liquid and negative ions generated from the ionization needles can be widely released into the room by placing them on a clean airflow from which contaminants have been removed by the filter, and the deodorizing effect exhibited by these substances
  • Other environmental improvement effects can be provided over a wide area and within the room.
  • Fig. 2 is a longitudinal sectional view of the same device.
  • m 3 is a schematic diagram showing the operation of the above device.
  • Fig. 4 is a top view of the electrode plate used in the above device.
  • FIG. 5 is a sectional view showing an example of an air purifier incorporating the above device.
  • FIG. 6 is a longitudinal sectional view showing an electrostatic atomizer according to another embodiment of the present invention.
  • the electrostatic atomizer M is manufactured to make water fine and charge it to produce nanometer-sized charged fine particle water as an example; As shown in FIGS. 1 to 3, the electrostatic atomizer M includes a base 1 O for holding a plurality of capillary carriers 20, a cylindrical body 30 surrounding the upper surface of the base 10, and a cylindrical body 30. It comprises an electrode plate 40 housed in the upper end opening, and a water tank 50 detachably attached to the lower surface of the base 1O.
  • Each capillary transport body 20 is formed of porous ceramic as a porous rod having a diameter of about 5 mm and a length of about 7 Omm, penetrates the base 10, and protrudes to the upper surface side of the base 10.
  • the tip of the portion is sharpened, and this is defined as a discharge end 21, and the portion protruding to the lower surface side of the base 10 is defined as a liquid collection end 22.
  • the liquid collecting end 22 is immersed in water in the water tank 50, absorbs water from the liquid collecting end 22, and transports the water to the discharge end 21 by capillary action.
  • the base 10 is formed of a conductive synthetic resin, and functions as a negative electrode that applies a negative potential to each of the capillary carriers 20.
  • a terminal 12 connected to the negative potential of the high voltage power supply 70 is provided on a part of the peripheral surface of the base 10.
  • An electrode tube 14 protrudes from the lower surface of the base 10 into the water tank 50 so that the water in the water tank 50 also applies the same negative potential as that of the capillary carrier 20.
  • the high-voltage power supply 70 applies a high voltage having an electric field strength of 500 VZmm between the base 10 and the electrode plate 40, and as a result, as shown in FIG.
  • the atomization phenomenon occurs between the discharge m 21 and the electrode plate 40 that constitutes the counter electrode facing the discharge, and fine water is charged as charged particles from the discharge end 21 to the electrode plate 4 O. To release it. That is, due to the action of the high voltage, the water sent out from the discharge end 21 undergoes rail splitting to generate negatively charged water of the charged fine particles, thereby discharging the mist of the charged fine particles.
  • the electrode plate 40 is made of a conductive synthetic resin and has a circular outer periphery, and is formed into an opening at the center. Then, an opening edge 41 is formed on the periphery of the central opening. The opening edge 41 faces the discharge end 21 of each of the capillary transport bodies 20 and discharge occurs between the opening edge 41 and the discharge end 21.
  • a terminal 48 connected to the positive side of the high-voltage power supply 70 is formed on a part of the electrode plate 20 in the circumferential direction. A continuous or pulsed high voltage is applied between the electrode plate 40 and the base 10 from the high voltage source.
  • an ionization needle 60 is held at the center of the base 10, and the tip is projected above the base 10 so as to be substantially at the same height as the discharge end at the tip of the capillary carrier 20. It is charged to the same potential as.
  • the capillary transport bodies 20 are arranged at equal angular intervals on a concentric circle with the ionization needle 60 as a center.
  • the encircling portion 41 of the electrode plate 40 serving as a common counter electrode for the capillary carrier 20 and the ionization needle 60 has a shape in which a plurality of arcuate edges 42 are continuous, and each arcuate edge 42 is It has a semicircular shape centered on the discharge end 21 of the opposed capillary carrier 20, and the distance from the discharge end 21 is constant. Between adjacent arc-shaped edges 42, a second edge 44 protruding inward in the radial direction is defined. The second edge 44 faces the ionization needle 6 O at the shortest distance, and a corona discharge is generated between the two edges. This causes negatively charged molecules such as oxygen, oxygen compounds, and nitrogen compounds in the air to generate negative ions while suppressing the generation of ozone.
  • the distance R 2 between the second edge 44 and the cutter needle ionization needle 60 is greater than the distance R 1 between the first squash-shaped first edge 42 and the discharge end 21 and has the same height.
  • the optimal conditions for atomizing the liquid at the discharge end 2 and generating negative ions at the ionization needle 6 O are respectively optimized. It can be done in.
  • the capillary carrier 20 is a porous ceramic having a particle diameter of 2 to 500 m and a porosity of 10 to 70%, and discharges water by a capillary action through a fine channel formed inside. Convey to edge 21.
  • a ceramic a mixture of one or any combination of alumina, titania, zirconia, silica, and magnesium is used.
  • the ceramic material a material whose equipotential point of this material is lower than the water port H used is used.
  • the reason for selecting a ceramic material based on such criteria is that if the water used contains mineral components such as Mg and C a, these components will travel to the discharge end 21 of the capillary transporter 20 and become air CO 2 and Han'asa prevented from precipitating as M gO Yu C a C0 3 in, is intended to prevent the electrostatic atomizing is impaired by precipitation of such components. That is, by utilizing the electroosmotic flow in the capillary carrier 20, Mg ions dispersed in water, C a This is to prevent ions from entering the discharge end 21.
  • a plurality of opening windows 32 are formed on the outer peripheral wall of the cylindrical body 30.
  • an air flow discharged from the central opening of the electrode plate 40 can be generated, and the discharge end 2 is formed.
  • the negatively charged fine particle water generated between the electrode plate 1 and the electrode plate 40 can be sent to a large space in a misted state by being carried on this air flow.
  • the charged fine particles can be utilized by using the forced air flow created by the air purifier 100. Water can be scattered over a wide area.
  • the air purifier 100 is provided with an air suction unit 102 and an air blowing unit 104, and is provided with a fan 110 and a filter 120 for collecting dust in the housing 101. External air is sucked through the filter 120 by 10 and clean air is blown out from the CM O 4.
  • the electrostatic atomizer M is disposed downstream of the filter 120 and the fan 110 and in the vicinity of the air blower D 104 of the air cleaner.
  • the mist of charged particle water generated by electrostatic atomization is 3 to 1 O Onm when the tip diameter of the capillary transporter 20 is 0.5 mm or less and the electric field strength is 500 VZmm or more and about 0.02 m ⁇ / min. It becomes ultra-fine particles of nanometer size and can contain active species such as hydroxyl radical, superoxide, nitric oxide radical, and oxygen radical in combination with oxygen in the air.
  • active species such as hydroxyl radical, superoxide, nitric oxide radical, and oxygen radical in combination with oxygen in the air.
  • Reference numeral 6 denotes another embodiment of the present invention, which is basically the same as the above embodiment, except that the ionization needle 60 penetrates the base 10 and protrudes into the water tank 50. It is designed to come into contact with the water stored here. Members in common with the above-described embodiment include No. is added. As described above, the electrode tube 14 protrudes from the base 10 into the water tank 50, contacts the water over a wide range, and negatively charges the water, and the ionization needle 60 also passes through the water. Even if a sufficient electrical connection cannot be obtained at the joint between the base 10 and the ionization needle 60, the ionization needle 60 is reliably charged to the negative and stable. To generate negative ions. The lower end of the ionization needle 60 is held by a perforated cap 54 attached to the lower end of the electrode tube 51.
  • a foldable handle 80 is provided at the upper end of the cylindrical body 30.
  • the bundle 80 is usually folded so as to overlap the outer periphery of the upper end of the simple body 30, and is used by being pulled upward when carrying the entire device.
  • Applicable liquids include water containing active ingredients such as vitamin C and amino acids, water containing aroma oils and air fresheners and deodorants, as well as, for example, a color solution such as a cosmetic mouth lotion. is there.

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • Epidemiology (AREA)
  • Dispersion Chemistry (AREA)
  • Electrostatic Spraying Apparatus (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Electrostatic Separation (AREA)

Abstract

Negatively charged liquid particles are released by applying a high voltage between an eclectic discharge end of a carrier for carrying a liquid and an electrode opposed to the electric discharge end. Corona discharge is caused between an ionization needle provided separately from the carrier and a counter electrode opposed to the ionization needle to negatively charge molecules in the air to generate anions. The liquid carried by the carrier and the ionization needle are connected to a common negative electrode to apply the same high voltage between the electrical discharge end of the carrier and the electrode and between the ionization meddle and the counter electrode.

Description

明細書  Specification
マイナスイオン発生機能付き静電霧化装置及びこれを用いた空気清浄機 技術分野  TECHNICAL FIELD The present invention relates to an electrostatic atomizer having a negative ion generating function and an air purifier using the same.
本発明は、 液体を微細な帯電粒子として放出する めの静電霧化機能にマイナスィォ ン発生機能が付加された静電霧化装置及びこれを用いた空気清淨機に関するちのである。 日本特許公報特許 3260 1 50号は、 従来の静電霧化装置を開示している。 この静 電霧化装置は、 毛細構造体を液体の搬送体として使用し、 毛細管作用を利用して搬送体 先端の放電端へ毛細管作用によって液体を供給し、 液体をプラスに帯電させるように搬 送体と、 これを包囲する八ウジングとの間に高電圧を印加して放電端から液体を帯電微 粒子として放出している。 一方、 空気中でコロナ放電を起こして、 空気中に存在する酸 素、 酸素化合物、 窒素化合物等の分子をマイナスに帯電させてマイナスイオンを発生さ せることで、 室内環境を向上させることが提案されている。 発明の開示  The present invention relates to an electrostatic atomizer having a minus ion generating function added to an electrostatic atomizer function for discharging liquid as fine charged particles, and an air purifier using the same. Japanese Patent Publication No. 3260 150 discloses a conventional electrostatic atomizer. This electrostatic atomizer uses a capillary structure as a liquid carrier, supplies the liquid to the discharge end at the tip of the carrier using the capillary action, and transports the liquid so that the liquid is positively charged. A high voltage is applied between the transmitter and the surrounding eight housings to discharge liquid from the discharge end as charged fine particles. On the other hand, it is proposed to improve the indoor environment by causing corona discharge in air to negatively charge molecules such as oxygen, oxygen compounds, and nitrogen compounds present in the air to generate negative ions. Have been. Disclosure of the invention
本発明は、 同一の高電圧源を使用して、 液体を微細な帯電微粒子として静電霧化によ り放出させることに加えて、 空気中に存在する分子をマイナスに帯電させてマイナスィ オンを発生させることができる静電霧化装置及びこの静電霧化装置を内蔵する空気清浄 機を提供するちのである。  According to the present invention, in addition to discharging liquid as fine charged fine particles by electrostatic atomization using the same high-voltage source, molecules existing in the air are negatively charged and negative ions are generated. An object of the present invention is to provide an electrostatic atomizer capable of generating the air and an air purifier incorporating the electrostatic atomizer.
本発明に係る静電霧化装置は搬送体を備え、 この搬送体は液体収集端及びこれと反対 側の放電端とを有し、 上記液体収集端が液体を収集してこの液体を上記放電端に搬送す る。 この装置には、 液体を電気的にマイナスに帯電させるマイナス電極、 上記放電端に 対向してマイナス電極との間に所定の電位差を作り出す対向電極、 及び電圧源とを備え る。 電圧源はマイナス電極と対向電極との間に電圧を印加して、 放電端で液体を帯電さ せてこれを微細なマイナス帯電粒子として放出する。 本装置には、 更にイオン化針が備 えられ、 上記マイナス電極に電気的に接続されて、 上記対向電極に近接配置されること で、 イオン化針の先端と效向電極との間でコロナ放電を発生させて、 マイナスイオンを 生成するちのである。  The electrostatic atomizer according to the present invention includes a carrier, the carrier having a liquid collecting end and a discharging end opposite to the liquid collecting end, wherein the liquid collecting end collects the liquid and discharges the liquid. Convey to the edge. This device includes a negative electrode for electrically charging the liquid to be negative, an opposite electrode facing the discharge end to create a predetermined potential difference with the negative electrode, and a voltage source. The voltage source applies a voltage between the negative electrode and the counter electrode, charges the liquid at the discharge end, and discharges it as fine negatively charged particles. The apparatus is further provided with an ionization needle, electrically connected to the negative electrode, and disposed close to the counter electrode, so that corona discharge occurs between the tip of the ionization needle and the effective electrode. They are generated to produce negative ions.
好ましい実施形態では、 上記対向電極は、 搬送体の放電端と共同してマイナスに帯電 しだ液体の微粒子を発生させる第 1縁部、 イオン化針と共同して上記マイナスイオンを 発生させる第 2縁部を有し、 第 2縁部とイオン化針との最短距離が第 1縁部と放電端と の最短距離よりも長くされている。 このような構成を採用することで、 搬送体及びィォ ン化針に対する 2つの対向電極を単一の部材で形成でき、 同じ高電圧を搬送体及びィォ ン化針に作用させながらち、 ィオン化針と第縁部との間で不要なオゾンが多 <発生する のを回避することができる。 In a preferred embodiment, the counter electrode is negatively charged in cooperation with the discharge end of the carrier. A first edge for generating fine particles of the liquid, a second edge for generating the negative ions in cooperation with the ionization needle, and a shortest distance between the second edge and the ionization needle is equal to the first edge. It is longer than the shortest distance from the discharge end. By adopting such a configuration, two opposing electrodes for the carrier and the ionization needle can be formed by a single member, and the same high voltage is applied to the carrier and the ionization needle. The generation of unnecessary ozone between the ionization needle and the first edge can be avoided.
好ましくは、 複数の搬送体がイオン化針の回りで周方向に沿って配置され、 多量の液 体の静電霧化が達成できる。  Preferably, a plurality of carriers are arranged circumferentially around the ionization needle, so that a large amount of liquid can be electrostatically atomized.
これに関連して、 対向電極が開口周縁を備え ^単一の開口を備え、 この周縁に複数の 弧状縁部が並^。 各弧状緣部は対麻する放電端を一定の距離で包囲して上記の第 1縁部 を規定し、 隣接する 2つの弧状縁部間の接続点で上記の第 2縁部を形成する。 これによ り、 複数の搬送体の放電端とこれに対 /Sする弧状の第 1縁部との距離を一定として、 複 数の搬送体の放電端からの多量で安定し £液体の静電霧化を達成できる共に、 ィオン化 針と第 2縁部との距離を比較的長くすることができて、 オゾンの発生を抑制して有効に マイナスイオンを空気中に生成することができる。  In this connection, the counter electrode has an opening edge ^ a single opening, around which a plurality of arcuate edges are aligned. Each arc-shaped portion surrounds the opposite discharge end at a fixed distance to define the first edge, and a connection point between two adjacent arc-shaped edges forms the second edge. As a result, the distance between the discharge ends of the plurality of carriers and the arc-shaped first edge facing the / S is constant, and a large amount of the liquid is stable from the discharge ends of the plurality of carriers. The atomization can be achieved, and the distance between the ionization needle and the second edge can be made relatively long, so that the generation of ozone can be suppressed and negative ions can be effectively generated in the air.
また、 本装置には、 液体を蓄えるタンクが備えられ、 搬送体はその液体収集端をタン ク内の液体に浸して液体を収集してこれを放電端へ搬送する。 イオン化針はこのタンク 内に突出して液体との電気接触が維持されることで、 液体に印加される高電圧のマイナ ス側に確実に電気接練される。  In addition, the apparatus is provided with a tank for storing the liquid, and the carrier collects the liquid by immersing the liquid collecting end in the liquid in the tank and transports the collected liquid to the discharging end. The ionization needle protrudes into this tank and maintains electrical contact with the liquid, so that the ionization needle is reliably kneaded on the negative side of the high voltage applied to the liquid.
このよラな構成の静電液体霧化装置を空気清浄機等の機器に組み込 ことが望ましい。 空気清浄機は汚染物質を捕捉するフィルタと、 このフィルタを通して空気を循環させる ファンとを/ \ウジングに備えるちので、 霧化装置をフアンとフィルタの下流側の/ \ゥジ ング内に配匱する。 これにより、 フィルタで汚染物質を除去したきれいな空気流に乗せ て液体の微細帯電微粒子及びイオン化針から生成されるマイナスイオンを室内空間へ広 く放出することができ、 これらの物質が発揮する脱臭効果ゆその他の環境改善効果を室 内の広レ、範囲に亘つて与えることができる。  It is desirable to incorporate the electrostatic liquid atomizing device having such a configuration into a device such as an air purifier. The air purifier is equipped with a filter that traps contaminants and a fan that circulates air through this filter, so the atomizer is installed inside the fan and the downstream of the filter. I do. As a result, the fine charged fine particles of liquid and negative ions generated from the ionization needles can be widely released into the room by placing them on a clean airflow from which contaminants have been removed by the filter, and the deodorizing effect exhibited by these substances Other environmental improvement effects can be provided over a wide area and within the room.
上述の課題ゆこれ以外の利点は、 図面を参照して説明する実施形態の説明で明確にさ れる。 図面の簡単な説明 ' m 1は本発明の一実施形態に係る液体静電霧化装置の分解斜視図。 The above-described problems and other advantages will be clarified in the description of the embodiment with reference to the drawings. Brief description of the drawings '' m1 is an exploded perspective view of the liquid electrostatic atomizer according to one embodiment of the present invention.
図 2は同上の装置の縦断面図。 Fig. 2 is a longitudinal sectional view of the same device.
m 3は同上の装置の作用を示す概略図。 m 3 is a schematic diagram showing the operation of the above device.
図 4は同上の装置に使用する電極プレー卜の上面図。 Fig. 4 is a top view of the electrode plate used in the above device.
図 5は同上の装置を組み込んだ空気清浄機の一例を示す断面図。 FIG. 5 is a sectional view showing an example of an air purifier incorporating the above device.
6は本発明の他の実施形態に係る静電霧化装置を示す縦断面図。 発明を実施する めの最良の形態 FIG. 6 is a longitudinal sectional view showing an electrostatic atomizer according to another embodiment of the present invention. BEST MODE FOR CARRYING OUT THE INVENTION
本発明の一実施例に係る静電霧化装置 Mは、 一例として水を微細化して帯電させ ナ ノメータサイズの帯電微粒子水を生成するために制作され; £ちのである。 図 1〜3に示 すように、 静電霧化装置 Mは、 複数の毛細管搬送体 20を保持する基台 1 Oと、 基台 1 0の上面を包囲する筒体 30、 筒体 30の上端開口に収める電極プレー卜 40と、 基台 1 Oの下面側に着脱自在に取り付けられる水タンク 50とで構成される。 各毛細管搬送 体 20は、 直径が約 5mm、 長さが約 7 Ommの多孔質の棒体として多孔質セラミック で形成されて基台 1 0を貫通し、 基台 1 0の上面側に突出する部分の先端を尖らせて、 ここを放電端 21とし、基台 1 0の下面側に突出する部分を液体収集端 22としている。 この液体収集端 22は、 水タンク 50内の水に浸され、 ここから水を吸収して毛細管作 用により放電端 21へ水を搬送する。 基台 1 0は、 導電性合成樹脂により成形され、 各 毛細管搬送体 20にマイナスの電位を与えるマイナス電極として作用する。 基台 1 0の 周面の一部に高圧電源 70の負電位に接続される端子 1 2が設けられている。 基台 1 0 の下面からは水タンク 50内に電極筒 1 4が突出して、 水タンク 50内の水もまた毛細 管搬送体 20と同じマイナス電位を印加させるようになっている。  The electrostatic atomizer M according to an embodiment of the present invention is manufactured to make water fine and charge it to produce nanometer-sized charged fine particle water as an example; As shown in FIGS. 1 to 3, the electrostatic atomizer M includes a base 1 O for holding a plurality of capillary carriers 20, a cylindrical body 30 surrounding the upper surface of the base 10, and a cylindrical body 30. It comprises an electrode plate 40 housed in the upper end opening, and a water tank 50 detachably attached to the lower surface of the base 1O. Each capillary transport body 20 is formed of porous ceramic as a porous rod having a diameter of about 5 mm and a length of about 7 Omm, penetrates the base 10, and protrudes to the upper surface side of the base 10. The tip of the portion is sharpened, and this is defined as a discharge end 21, and the portion protruding to the lower surface side of the base 10 is defined as a liquid collection end 22. The liquid collecting end 22 is immersed in water in the water tank 50, absorbs water from the liquid collecting end 22, and transports the water to the discharge end 21 by capillary action. The base 10 is formed of a conductive synthetic resin, and functions as a negative electrode that applies a negative potential to each of the capillary carriers 20. A terminal 12 connected to the negative potential of the high voltage power supply 70 is provided on a part of the peripheral surface of the base 10. An electrode tube 14 protrudes from the lower surface of the base 10 into the water tank 50 so that the water in the water tank 50 also applies the same negative potential as that of the capillary carrier 20.
高圧電源 70は、 例えぱ、 500 VZmmの電界強度の高電圧を基台 1 0と電極プレ 一卜 40との間に印加して、 この結果、 図 3に示すように、 毛細管搬送体 20先端の放 m 2 1とこれに対向する対向電極を構成する電極プレー卜 40との間で静電霧化現象 が発生し、 微細な水を帯電粒子として放電端 2 1から電極プレート 4 Oに向けて放出さ せるおのである。 すなわち、 高電圧の作用により、 放電端 2 1から送り出される水にレ イリ一分裂を起こさせて、 マイナスに帯電した帯電微粒子水を発生させて、 帯電微粒子 のミス卜を放出する。  For example, the high-voltage power supply 70 applies a high voltage having an electric field strength of 500 VZmm between the base 10 and the electrode plate 40, and as a result, as shown in FIG. The atomization phenomenon occurs between the discharge m 21 and the electrode plate 40 that constitutes the counter electrode facing the discharge, and fine water is charged as charged particles from the discharge end 21 to the electrode plate 4 O. To release it. That is, due to the action of the high voltage, the water sent out from the discharge end 21 undergoes rail splitting to generate negatively charged water of the charged fine particles, thereby discharging the mist of the charged fine particles.
電極プレー卜 40は導電性合成樹脂で円形の外周を有し、 中央が開口した形に成型さ れ、 中央開口の周縁に開口縁部 41を形成する。 この開口縁部 4 1は各毛細管搬送体 2 0の放電端 21に近接対向し、 開口縁部 41と放電端 2 1との間で放電が行われる。 電 極プレー卜 20の周方向の一部には、 高圧電源 70のプラス側に接続される端子 48が 形成されている。 高電圧源からは連続した或いはパルス状の高電圧が電極プレー卜 40 と基台 1 0との間に印加される。 The electrode plate 40 is made of a conductive synthetic resin and has a circular outer periphery, and is formed into an opening at the center. Then, an opening edge 41 is formed on the periphery of the central opening. The opening edge 41 faces the discharge end 21 of each of the capillary transport bodies 20 and discharge occurs between the opening edge 41 and the discharge end 21. A terminal 48 connected to the positive side of the high-voltage power supply 70 is formed on a part of the electrode plate 20 in the circumferential direction. A continuous or pulsed high voltage is applied between the electrode plate 40 and the base 10 from the high voltage source.
また、 基台 1 0の中央にはイオン化針 60が保持されて尖端を基台 1 0の上方に突出 させて、 毛細管搬送体 20先端の放電端とほぼ同じ高さに揃え、 毛細管搬送体 20と同 電位に帯電させている。 上記の毛細管搬送体 20は、 図 4に示すように、 このイオン化 針 60を中心とし 同心円上に等角度間隔で配置される。 毛細管搬送体 20及びイオン 化針 60に対して共通の対向電極となる電極プレー卜 40の閧ロ緣部 4 1は、 複数の弧 状縁部 42が連続した形となり、 各弧状縁部 42は対向する毛細管搬送体 20の放電端 2 1を中心とした半円周形となり、 放電端 2 1との距離を一定としている。 隣り合う弧 状縁部 42間は、 半径方向内方に突出する第 2縁部 44を規定し、 この第 2縁部 44が イオン化針 6 Oに対して最短距離で対向してこの間でコロナ放電を起こして、 オゾンの 発生を抑えながら、 空気中の酸素、 酸素化合物、 窒素化合物等の分子をマイナスに帯電 させてマイナスイオンを発生させる。 すなわち、 第 2縁部 44とェ Sッタ針イオン化針 60との距離 R 2は、 3瓜状の第 1縁部 42と放電端 2 1との距離 R 1よりち大きくなり、 同一の高電圧のマイナス電位をイオン化針 60と搬送体 20の放電端 2 1に与えながら ち、 放電端 2 での液体の霧化作用とイオン化針 6 Oでのマイナスイオン発生とをそれ ぞれ最適な条件で行えるようにしている。  In addition, an ionization needle 60 is held at the center of the base 10, and the tip is projected above the base 10 so as to be substantially at the same height as the discharge end at the tip of the capillary carrier 20. It is charged to the same potential as. As shown in FIG. 4, the capillary transport bodies 20 are arranged at equal angular intervals on a concentric circle with the ionization needle 60 as a center. The encircling portion 41 of the electrode plate 40 serving as a common counter electrode for the capillary carrier 20 and the ionization needle 60 has a shape in which a plurality of arcuate edges 42 are continuous, and each arcuate edge 42 is It has a semicircular shape centered on the discharge end 21 of the opposed capillary carrier 20, and the distance from the discharge end 21 is constant. Between adjacent arc-shaped edges 42, a second edge 44 protruding inward in the radial direction is defined. The second edge 44 faces the ionization needle 6 O at the shortest distance, and a corona discharge is generated between the two edges. This causes negatively charged molecules such as oxygen, oxygen compounds, and nitrogen compounds in the air to generate negative ions while suppressing the generation of ozone. In other words, the distance R 2 between the second edge 44 and the cutter needle ionization needle 60 is greater than the distance R 1 between the first squash-shaped first edge 42 and the discharge end 21 and has the same height. While applying a negative potential of voltage to the ionization needle 60 and the discharge end 21 of the carrier 20, the optimal conditions for atomizing the liquid at the discharge end 2 and generating negative ions at the ionization needle 6 O are respectively optimized. It can be done in.
毛細管搬送体 20は、 粒径が 2〜500 mで気孔率 1 0~70%となった多孔質セ ラミツクであり、 内部に形成される微細な流路を通し 毛細管作用によつて水を放電端 2 1へ搬送する。 セラミックとしては、 アルミナ、 チタニア、 ジルコニァ、 シリカ、 マ グネシァの一つまたは任意の組み合わせの混合物が使用される。 セラミック材料として は、 この材料の等電位点の p Hが使用される水の口 Hよりち低くいものが利用される。 このような基準に基づいてセラミック材料を選択する理由は、 使用する水に M gゆ C a 等のミネラル成分が含まれる場合に、 これらの成分が毛細管搬送体 20の放電端 21へ 進み、 空気中の CO 2と反麻し M gOゆ C a C03として析出するのを防止し、 このよう な成分の析出によって静電霧化作用が損なわれることを防ぐものである。 すなわち、 毛 細管搬送体 20内での電気浸透流を利用して、 水内に分散している M gイオンゆ、 C a イオンが放電端 21に進 のを防止することである。 The capillary carrier 20 is a porous ceramic having a particle diameter of 2 to 500 m and a porosity of 10 to 70%, and discharges water by a capillary action through a fine channel formed inside. Convey to edge 21. As the ceramic, a mixture of one or any combination of alumina, titania, zirconia, silica, and magnesium is used. As the ceramic material, a material whose equipotential point of this material is lower than the water port H used is used. The reason for selecting a ceramic material based on such criteria is that if the water used contains mineral components such as Mg and C a, these components will travel to the discharge end 21 of the capillary transporter 20 and become air CO 2 and Han'asa prevented from precipitating as M gO Yu C a C0 3 in, is intended to prevent the electrostatic atomizing is impaired by precipitation of such components. That is, by utilizing the electroosmotic flow in the capillary carrier 20, Mg ions dispersed in water, C a This is to prevent ions from entering the discharge end 21.
筒体 30の外周壁には、 複数の開口窓 32が形成され、 ここから空気流を取り込むこ とで、 電極プレー卜 40の中央開口から吐出される空気流を作り出すことができ、 放電 端 2 1と電極プレー卜 40との間で発生するマイナスに帯電し 微粒子水をこの空気流 に乗せてミス卜状態で広い空間へ送る出すことができる。 例えば、 図 5に示すように、 上記の静電霧化装置 Mを空気清浄機 1 00に組み込こ ことで、 空気清浄機 1 00で作 り出される強制空気流を利用して、 帯電微粒子水を広い範囲に亘つて飛散させることが できる。 空気清浄機 1 00は空気吸い込みロ1 02と空気吹き出しロ1 04を備え 7£八 ウジング 1 0 1内に、ファン 1 1 0及び塵埃を捕集するフィルタ 1 20を備えだもので、 ファン 1 1 0によりフィルタ 1 20を通して外部の空気を吸引し、 清浄な空気を空気吹 き出し CM O 4から放出する。 静電霧化装置 Mは、 フィルタ 1 20及びファン 1 1 0よ り下流側で、 空気清净機の空気吹き出し D 1 04の近傍に配置される。  A plurality of opening windows 32 are formed on the outer peripheral wall of the cylindrical body 30. By taking in the air flow from the opening window 32, an air flow discharged from the central opening of the electrode plate 40 can be generated, and the discharge end 2 is formed. The negatively charged fine particle water generated between the electrode plate 1 and the electrode plate 40 can be sent to a large space in a misted state by being carried on this air flow. For example, as shown in FIG. 5, by incorporating the electrostatic atomizer M into the air purifier 100, the charged fine particles can be utilized by using the forced air flow created by the air purifier 100. Water can be scattered over a wide area. The air purifier 100 is provided with an air suction unit 102 and an air blowing unit 104, and is provided with a fan 110 and a filter 120 for collecting dust in the housing 101. External air is sucked through the filter 120 by 10 and clean air is blown out from the CM O 4. The electrostatic atomizer M is disposed downstream of the filter 120 and the fan 110 and in the vicinity of the air blower D 104 of the air cleaner.
静電霧化で生じる帯電粒子水のミス卜は、 毛細管搬送体 20の尖端径を 0. 5mm以 下として、 電界強度 500VZmm以上において毎分 0. 02m〗程度にした時、 3〜 1 O Onmの粒径となっ ナノメータサイズの超微細な粒子となる共に、 空気中の酸素 と反 I®してヒドロキシルラジカル、 スーパーオキサイド、 一酸化窒素ラジカル、 酸素ラ ジカルなどの活性種を含 ことができる。 匸のような帯電粒子水のミストは室内空間に 放出された時、 室内の空気ゆ室内壁面等に付着している付着物の脱臭を行うことができ る。 以下の式は、 これらの活性種による脱臭効果を示す活性種と臭気との脱臭反廂式で ある。  The mist of charged particle water generated by electrostatic atomization is 3 to 1 O Onm when the tip diameter of the capillary transporter 20 is 0.5 mm or less and the electric field strength is 500 VZmm or more and about 0.02 m〗 / min. It becomes ultra-fine particles of nanometer size and can contain active species such as hydroxyl radical, superoxide, nitric oxide radical, and oxygen radical in combination with oxygen in the air. When the mist of charged particle water such as shin is released into the indoor space, it can deodorize adhering substances adhering to the indoor air and the indoor wall surface. The following equation is a deodorizing reaction equation between the active species and the odor that show the deodorizing effect of these active species.
アンモニア 2ΝΗ3+6 · OH-*N2+6H20 Ammonia 2ΝΗ 3 + 6OH- * N 2 + 6H 20
ァセ卜アルデヒド CH3CHO+6 · OH+02→2C02+5H20 § Se Bok aldehyde CH 3 CHO + 6 · OH + 0 2 → 2C0 2 + 5H 2 0
酢酸 CH3COOH+4 · 0H+02→2 · C02+4H20 Acetic acid CH 3 COOH + 4 0H + 0 2 → 2C0 2 + 4H 20
メタンガス CH4+4■ 0H+02→C02+4H20 Methane gas CH 4 + 4 ■ 0H + 0 2 → C0 2 + 4H 2 0
一酸化炭素 CO+2 · OH→C02+H20 Carbon monoxide CO + 2 · OH → C0 2 + H 2 0
一酸化窒素 2NO+4 · OH—N2+2 · 02+2H20 Nitric oxide 2NO + 4 · OH-N 2 +2 · 0 2 + 2H 2 0
ホルムアルデヒド HCHO+4 · OH— C02+3H20 Formaldehyde HCHO + 4 · OH- C0 2 + 3H 2 0
囡 6は、 本発明の他の実施形態を示すもので、 基本的には前述の実施形態と同一であ るが、 イオン化針 60が基台 1 0を貫通して、 水タンク 50内に突出してここに蓄えら れる水に接触するように設計されている。 前述の実施形態と共通する部材には、 囘じ番 号を付記する。 前述したように、 基台 1 0からは水タンク 50内に電極筒 1 4が突出し て、 広い範囲に亘つて水に接触して水をマイナスに帯電させており、 イオン化針 60も 水を介して確実にマイナスに帯電させており、 基台 1 0とイオン化針 60との結合部位 において十分な電気接続が得られない場合でも、 イオン化針 6 0を確実にマイナスに帯 電させて、 安定してマイナスイオンを発生させることができる。 イオン化針 60の下端 は、 電極筒 5 1の下端に装着される穴あきキャップ 54に保持される。 Reference numeral 6 denotes another embodiment of the present invention, which is basically the same as the above embodiment, except that the ionization needle 60 penetrates the base 10 and protrudes into the water tank 50. It is designed to come into contact with the water stored here. Members in common with the above-described embodiment include No. is added. As described above, the electrode tube 14 protrudes from the base 10 into the water tank 50, contacts the water over a wide range, and negatively charges the water, and the ionization needle 60 also passes through the water. Even if a sufficient electrical connection cannot be obtained at the joint between the base 10 and the ionization needle 60, the ionization needle 60 is reliably charged to the negative and stable. To generate negative ions. The lower end of the ionization needle 60 is held by a perforated cap 54 attached to the lower end of the electrode tube 51.
このほか、 本実施 ¾態では、 筒体 30の上端に折り畳み自在の八ンドル 80が設けら れる。 この八ンドル 80は通常、 簡体 30の上端外周に重ねるように折り畳まれ、 装置 全体を持ち運 場合は、 上方に引き出して使甩される。  In addition, in the present embodiment, a foldable handle 80 is provided at the upper end of the cylindrical body 30. The bundle 80 is usually folded so as to overlap the outer periphery of the upper end of the simple body 30, and is used by being pulled upward when carrying the entire device.
尚、 上述の実施形態では、 水を使用して帯電微粒子水のミス卜を発生させる事例を説 明したが、 本発明はこの実施形態に限定されるものではな <、 水以外の種 の液体の静 電霧化に適用できる。 適用できる液体としては、 ビタミン Cやアミノ酸等の有効成分が 入った水、 ァロマオイルゆ芳香剤や消臭材等が入つ 水の他に、 例えば、 化粧口一ショ ンのようなコロィド溶液等がある。  In the above-described embodiment, an example in which water is used to generate a mist of charged fine particle water has been described. However, the present invention is not limited to this embodiment. It can be applied to electrostatic atomization. Applicable liquids include water containing active ingredients such as vitamin C and amino acids, water containing aroma oils and air fresheners and deodorants, as well as, for example, a color solution such as a cosmetic mouth lotion. is there.

Claims

am求の範囲 am seeking range
1 . マイナスイオン発生機能付き静電霧化装置、 1. Electrostatic atomizer with negative ion generation function,
搬送体、 この搬送体は液体収集端及びこれと反対側の放電端とを有し、 上記液体収集 端が液体を収集してこの液体を上記放電端に搬送する; A carrier, the carrier having a liquid collecting end and an opposite discharging end, wherein the liquid collecting end collects the liquid and conveys the liquid to the discharging end;
上記液体を電気的にマイナスに帯電させるマイナス電極、 A negative electrode that electrically charges the liquid negatively,
上記放電端に刘向する対! ¾電極、 The electrode facing the discharge end!
電圧源、 この電圧源はマイナス電極と対向電極との間に電圧を印加して、 上記放電端 で液体を帯電させてこれを微細な帯電粒子として放出する、  A voltage source, which applies a voltage between the negative electrode and the counter electrode, charges the liquid at the discharge end, and discharges it as fine charged particles;
イオン化針、 このイオン化針は上記マイナス電極に電気的に接続されてマイナスに帯 璽し、 上記対向電極に近接配置されてこの間にコロナ放電を発生させて、 マイナスィ 才ンを放出する。  An ionization needle, which is electrically connected to the negative electrode and forms a negative polarity, is disposed in proximity to the counter electrode, generates a corona discharge during this interval, and discharges a negative ion.
2. 請求項 1に記載の静電霧化装置において、 2. The electrostatic atomizer according to claim 1,
上記対向電極は、 上記搬送体の放電端と共同してマイナスに帯電し 液体の微粒子を 発生させる第 1縁部を有し、  The counter electrode has a first edge portion that is negatively charged in cooperation with the discharge end of the carrier to generate liquid fine particles,
上記対向電極は、 上記のイオン化針と共同して上記マイナスイオンを発生させる第 2 緣部を有し、 .  The counter electrode has a second part that generates the negative ion in cooperation with the ionization needle.
上記第 2縁部と上記イオン化針との最短距離が上記第 1縁部と放電端との最短距離よ りち長ぐなつた。  The shortest distance between the second edge and the ionization needle was longer than the shortest distance between the first edge and the discharge end.
3. 請求項 2に記載の静電霧化装置において、 3. The electrostatic atomizer according to claim 2,
上記装置には、 先が尖つだ棒状となった上記搬送体を複数備え、 これらの搬送体が上 記ィォン化針の周りで周方向に沿つて配置されだ。  The above-mentioned device is provided with a plurality of the above-mentioned carriers in the form of a pointed rod, and these carriers are arranged along the circumferential direction around the above-mentioned ionization needle.
4. 請求項 3に記載の静電霧化装置において、 4. The electrostatic atomizer according to claim 3,
上記対向電極は開口周縁を備えた単一の開口を備え、  The counter electrode comprises a single opening with an opening periphery;
この周縁は複数の弧状縁部から形成され、 各弧状縁部は上記放電端のそれぞれを一定 の距離で包囲して、 上記第 1縁部を規定し、 上記弧状縁部が上記周縁に沿って配置さ れて隣接する 2つの弧状縁部間の接続点で上記の第 2縁部を形成する。 The peripheral edge is formed from a plurality of arc-shaped edges, each arc-shaped edge surrounding each of the discharge ends at a fixed distance to define the first edge, and the arc-shaped edge extends along the peripheral edge. The second edge is formed at the connection point between the two arcuate edges that are arranged and adjacent to each other.
5. 請求項 1に記載の静電霧化装置において、 5. The electrostatic atomizer according to claim 1,
上記装置は液体を蓄えるタンクを備え、 The device has a tank for storing liquid,
上記搬送体は、 上記液体収集端をタンク内の液体に浸して液体を収集してこれを上記 放電端へ搬送する、 Wherein the carrier collects the liquid by immersing the liquid collecting end in the liquid in the tank and conveys the liquid to the discharging end;
上記イオン化針はタンク内に突出してタンク内の液体との電気接触が維持される。 The ionization needle projects into the tank to maintain electrical contact with the liquid in the tank.
6. 請求項 1に記載の静電霧化装置を含 空気清浄機であって、 6. An air purifier including the electrostatic atomizer according to claim 1,
この空気清浄機は、 污染物質を捕捉するフィルタと、 このフィルタを通して空気を循 環させるファンとを備えだノ \ウジングを有し、 This air purifier has a nozzle equipped with a filter for trapping contaminants and a fan for circulating air through the filter.
上記噴霧装置は上記/ \ウジング内で上記ファンと上記フィルタの下流側に配置され 。 The spraying device is disposed downstream of the fan and the filter in the housing.
PCT/JP2004/007597 2003-06-04 2004-05-26 Electrostatic atomizer with anion ion generating function and air cleaner using same WO2004110642A1 (en)

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CN102084189A (en) * 2008-03-07 2011-06-01 Lg电子株式会社 Humidifier
CN114543190A (en) * 2022-02-17 2022-05-27 青岛海信日立空调系统有限公司 Air conditioner indoor unit
CN116271174A (en) * 2022-12-29 2023-06-23 广东骏丰频谱股份有限公司 Low-temperature plasma air sterilizing device for small space

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JP4877290B2 (en) * 2008-07-25 2012-02-15 パナソニック電工株式会社 Electrostatic atomizer with negative ion generation function and air cleaner equipped with the same
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CN114543190B (en) * 2022-02-17 2023-09-26 青岛海信日立空调系统有限公司 Indoor unit of air conditioner
CN116271174A (en) * 2022-12-29 2023-06-23 广东骏丰频谱股份有限公司 Low-temperature plasma air sterilizing device for small space

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JP4186718B2 (en) 2008-11-26
TW200427518A (en) 2004-12-16
JP2004358358A (en) 2004-12-24

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