WO2004035716A1 - Apparatus for producing water-in-oil emulsified fuel and supplying the same - Google Patents
Apparatus for producing water-in-oil emulsified fuel and supplying the same Download PDFInfo
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- WO2004035716A1 WO2004035716A1 PCT/KR2002/001935 KR0201935W WO2004035716A1 WO 2004035716 A1 WO2004035716 A1 WO 2004035716A1 KR 0201935 W KR0201935 W KR 0201935W WO 2004035716 A1 WO2004035716 A1 WO 2004035716A1
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- Prior art keywords
- oil
- water
- mixer
- emulsified fuel
- flow meter
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
- C10L1/328—Oil emulsions containing water or any other hydrophilic phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/41—Emulsifying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/43—Mixing liquids with liquids; Emulsifying using driven stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/45—Mixing liquids with liquids; Emulsifying using flow mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/49—Mixing systems, i.e. flow charts or diagrams
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/30—Injector mixers
- B01F25/31—Injector mixers in conduits or tubes through which the main component flows
- B01F25/312—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/30—Injector mixers
- B01F25/31—Injector mixers in conduits or tubes through which the main component flows
- B01F25/312—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof
- B01F25/3124—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof characterised by the place of introduction of the main flow
- B01F25/31243—Eductor or eductor-type venturi, i.e. the main flow being injected through the venturi with high speed in the form of a jet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/431—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
- B01F25/4314—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor with helical baffles
- B01F25/43141—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor with helical baffles composed of consecutive sections of helical formed elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/433—Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/433—Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
- B01F25/4338—Mixers with a succession of converging-diverging cross-sections, i.e. undulating cross-section
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/50—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
- B01F25/51—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle in which the mixture is circulated through a set of tubes, e.g. with gradual introduction of a component into the circulating flow
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/80—Mixing plants; Combinations of mixers
- B01F33/82—Combinations of dissimilar mixers
- B01F33/821—Combinations of dissimilar mixers with consecutive receptacles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/80—Mixing plants; Combinations of mixers
- B01F33/82—Combinations of dissimilar mixers
- B01F33/821—Combinations of dissimilar mixers with consecutive receptacles
- B01F33/8212—Combinations of dissimilar mixers with consecutive receptacles with moving and non-moving stirring devices
Definitions
- the present invention relates to an apparatus for producing emulsified fuel and supplying the same to a boiler, and more particularly, to an apparatus for producing and supplying water-in-oil emulsified fuel that supplies to a boiler water-in-oil emulsified fuel, which is emulsified by mixing an emulsifier and water in crude oil such as bunker C oil or bunker A oil.
- emulsion refers to the state of uniform dispersion to a minute particle state of a liquid that is within a liquid and unmixed with the same.
- water-in-oil (W/O) emulsified fuel is realized by mixing water or waste water, and a surface active agent (an emulsifier) in a high carbide, high viscosity oil such as crude oil (bunker C oil), which is a low cost, highly efficient heat source that is severely limited in use because it contributes to air pollution.
- Water-in-oil emulsified fuel refers also to purified oil that is completely combusted in a combustion boiler as a result of micro explosions taking place by water bubbles, and that contains an additive that minimizes the concentration of dust, smoke, SOx, NOx, CO, etc., which are the main causes of air pollution in exhaust gas, such that the resulting fuel is highly efficient and environmentally friendly.
- the present invention has been made in an effort to solve these problems. It is an object of the present invention to provide an apparatus for producing and supplying water-in-oil emulsified fuel in which an emulsifier and water are mixed in crude oil such as bunker C oil (hereinafter 'B-C oil') or bunker A oil (hereinafter 'B-A oil') at an optimal ratio, and the resulting water-in-oil emulsified fuel is supplied to a boiler where full combustion takes place, thereby preventing contribution to air pollution and reducing energy requirements.
- crude oil such as bunker C oil (hereinafter 'B-C oil') or bunker A oil (hereinafter 'B-A oil')
- 'B-A oil' bunker A oil
- An apparatus for producing and supplying water-in-oil emulsified fuel includes an additive storage tank for storing an emulsifier that prevents the separation of water and oil when maintaining water-in-oil emulsified fuel at a high temperature; an emulsion tank for storing water-in-oil emulsified fuel and supplying the same to a boiler from a center side area through a boiler supply line; a circulation electric heater mounted to one side within the emulsion tank to uniformly maintain a temperature of the supplied water-in-oil emulsified fuel; a level switch mounted to the emulsion tank to adjust a storage amount of the water-in-oil emulsified fuel, which is established to mach a usage load of the boiler; an additive supply pump connected to the additive storage tank supplying at a predetermined amount the emulsifier stored therein to allow for mixing of the emulsifier with water and B-C oil; an additive flow meter connected to the additive supply pump and
- the additive supply pump, the B-C oil supply pump, the water cutoff valve, the additive flow meter, the B-C oil flow meter, and the water flow meter operate when a LOW signal of the level switch of the emulsion tank is transmitted, and the additive flow pump, the B-C oil supply, and the water cutoff valve, to which are connected respectively the additive flow meter, the B-C oil flow meter, and the water flow meter discontinue operation according to a discontinue signal transmitted when predetermined values of these flow meters are reached.
- emulsified fuel mixed in a circulation system of the emulsion tank, the mixer pump, the second mixer, and the circulation electric heater is continuously circulated even if raw material supply is stopped such that emulsified fuel that is always in a uniform state is supplied while maintaining a predetermined ratio, a predetermined moisture particle state, and a predetermined temperature.
- the apparatus further includes a steam coil mounted to an inner surface of the additive storage tank for maintaining the emulsifier stored therein at a predetermined temperature.
- the steam coil maintains the emulsifier stored in the additive storage tank at a temperature of 60 ⁇ 1 10 ° C .
- the apparatus further includes an electric heater mounted to a lower output side of the additive storage tank for uniformly maintaining the emulsifier exiting the additive storage tank at a predetermined temperature such that stable additive supply is ensured during initial operation.
- the electric heater maintains the emulsifier stored in the additive storage tank at a temperature of 60 ⁇ 1 10 ° C .
- the capacity of the emulsion tank is at least two batches of a raw material supply amount.
- the apparatus further includes a temperature retaining electric heater mounted to an exterior of the emulsion tank to maintain a temperature of the water-in-oil emulsified fuel stored in the emulsion tank at a predetermined level.
- the temperature retaining electric heater maintains the water-in-oil emulsified fuel stored in the emulsion tank at a temperature of 60 — 80 ° C .
- the circulation electric heater preferably maintains the water-in-oil emulsified fuel supplied to the emulsion tank at a temperature of 60 — 80 ° C .
- the additive supply pump supplies an emulsifier at a fixed ratio of 0.5 — 1 % of the first batch raw material supply amount
- the B-C supply pump supplies B-C oil at a fixed ratio of 69.5 — 89.5% of the first batch raw material supply amount
- the water cutoff valve supplies water at a fixed ratio of 10 — 30% of the first batch raw material supply amount.
- the first mixer may be a single-type line mixer, and the second mixer may be a double-type line mixer.
- the mixer pump may include a pre-mixer pump and a main mixer pump, which are connected in parallel between the emulsion tank and the second mixer.
- a shell and tube heat exchanger may be used for the circulation electric heater.
- An apparatus for producing and supplying water-in-oil emulsified fuel includes an additive storage tank for storing an emulsifier that prevents the separation of water and oil when maintaining water-in-oil emulsified fuel at a high temperature; an emulsion tank having a capacity of at least a first batch raw material supply amount, and storing and mixing water-in-oil emulsified fuel; a circulation electric heater mounted to one side within the emulsion tank to uniformly maintain a temperature of the supplied water-in-oil emulsified fuel; a level switch mounted to the emulsion tank to adjust a storage amount of the water-in-oil emulsified fuel, which is established to match a usage load of the boiler; a service tank receiving mixed water-in-oil emulsified fuel from the emulsion tank through an emulsified fuel transporting pump, which is connected to a lower end of the emulsion tank, temporarily storing the received water-in-
- ⁇ supplying water by a predetermined amount for mixing with the B-C oil and the emulsifier; a water flow meter connected to the water cutoff valve and controlling an operation of the same such that water is supplied by a predetermined supply amount; a mixing ejector connected both to a water supply line, which is connected to the water flow meter, and to the first mixer, the mixing ejector primarily uniformly mixing a raw material oil of the B-C oil and the emulsifier, and discharging a resulting mixture; a mixer pump connected to the mixing ejector and a lower end of the emulsion tank for remixing the raw material oil supplied from the mixing ejector and the emulsified fuel supplied from the emulsion tank; and a second mixer connected to the mixer pump for remixing the primarily mixed raw material oil and the emulsified fuel to uniformly emulsify a resulting mixture to uniform minute particles, then supplying a result to the emulsion tank through the circulation electric heater.
- the additive supply pump, the B-C oil supply pump, the water cutoff valve, the additive flow meter, the B-C oil flow meter, and the water flow meter operate when a LOW signal of the level switch of the emulsion tank is transmitted.
- emulsified fuel mixed in a circulation system of the emulsion tank, the mixer pump, the second mixer, and the circulation electric heater is continuously circulated even if raw material supply is stopped such that emulsified fuel that is always in a uniform state is supplied while maintaining a predetermined ratio, a predetermined moisture particle state, and a predetermined temperature.
- the apparatus further includes a level switch mounted in the service tank to allow for adjustment of the amount of the water-in-oil emulsified fuel, which is established to correspond to a usage load of the boiler, and the emulsified fuel transporting pump operates when a LOW signal of the level switch of the service tank is sensed, and discontinues operation when a LOW signal of a level switch of the emulsion tank is sensed.
- a level switch mounted in the service tank to allow for adjustment of the amount of the water-in-oil emulsified fuel, which is established to correspond to a usage load of the boiler, and the emulsified fuel transporting pump operates when a LOW signal of the level switch of the service tank is sensed, and discontinues operation when a LOW signal of a level switch of the emulsion tank is sensed.
- the apparatus further includes a temperature retaining electric heater mounted to an outer circumference of the service tank such that the temperature of the water-in-oil emulsified fuel stored therein may be maintained at a predetermined temperature.
- the first mixer is a single-type line mixer
- the second mixer is a double-type line mixer.
- An apparatus for producing and supplying water-in-oil emulsified fuel according to a third embodiment includes an additive storage tank for storing an emulsifier that prevents the separation of water and oil when maintaining water-in-oil emulsified fuel at a high temperature; an emulsion tank for storing water-in-oil emulsified fuel and supplying the same to a boiler from a center side area through a boiler supply line; a level switch mounted to the emulsion tank to adjust a storage amount of the water-in-oil emulsified fuel, which is established to mach a usage load of the boiler; an additive supply pump connected to the additive storage tank supplying at a predetermined amount the emulsifier stored therein to allow for mixing of the emulsifier with water and B-C oil; an additive flow meter connected to the additive supply pump and controlling an operation of the same such that the
- the additive supply pump, the B-C oil supply pump, the water cutoff valve, the additive flow meter, the B-C oil flow meter, and the water flow meter operate when a LOW signal of the level switch of the emulsion tank is transmitted.
- emulsified fuel mixed in a circulation system of the emulsion tank, the mixer pump, the circulation electric heater, and the third mixer is continuously circulated even if raw material supply is stopped such that emulsified fuel that is always in a uniform state is supplied while maintaining a predetermined ratio, a predetermined moisture particle state, and a predetermined temperature.
- the first mixer and the second mixer are single-type mixers, and the third mixer is a double-type mixer.
- An apparatus for producing and supplying water-in-oil emulsified fuel includes an additive storage tank for storing an emulsifier that prevents the separation of water and oil when maintaining water-in-oil emulsified fuel at a high temperature; an emulsion tank having a capacity of at least a second batch raw material supply amount, and storing and mixing water-in-oil emulsified fuel; a level switch mounted to the emulsion tank to adjust a storage amount of the water-in-oil emulsified fuel, which is established to mach a usage load of a boiler; an additive supply pump connected to the additive storage tank supplying at a predetermined amount the emulsifier stored therein to allow for mixing of the emulsifier with water and B-C oil; an additive flow meter connected to the additive supply pump and controlling an operation of the same such that the emulsifier is supplied by a predetermined supply amount; a B-A oil supply pump supplying B-A oil by a
- the additive supply pump, the B-A oil supply pump, the water cutoff valve, the additive flow meter, the B-A oil flow meter, and the water flow meter operate when a LOW signal of the level switch of the emulsion tank is transmitted.
- emulsified fuel mixed in a circulation system of the emulsion tank, the mixer pump, and the third mixer is continuously circulated even if raw material supply is stopped such that emulsified fuel that is always in a uniform state is supplied while maintaining a predetermined ratio, a predetermined moisture particle state, and a predetermined temperature.
- an emulsifier and water are primarily mixed in crude oil such as B-C oil or B-A oil, then an emulsified fuel, which has undergone a second mixing process that forms very minute water-in-oil particles, is maintained at a predetermined temperature in the emulsion tank.
- the emulsified fuel circulates through the circulation system of the emulsion tank to be supplied to the boiler while being maintained in an optimum emulsion state. As a result, a combustion is not discontinued, and fuel consumption is reduced.
- the fuel particles combusted in the combustion chamber are made into minute particles, that is, to particle sizes roughly 10,000 smaller than with conventional fuel such that the possibility of contact with oxygen during combustion is increased, thereby ensuring significantly greater full combustion and reducing excessive oxygen concentration in the exhaust gas. Therefore, energy is saved and boiler efficiency is increased.
- an air pollution reduction device such as dust collecting equipment is unneeded, and overall equipment operation costs such as power costs and maintenance are reduced.
- FIG. 1 is a structural view of an apparatus for producing and supplying water-in-oil emulsified fuel according to a first embodiment of the n present invention.
- FIG. 2 is a sectional view of a single-type line mixture applied to an apparatus for producing and supplying water-in-oil emulsified fuel according to a first embodiment of the present invention.
- FIG. 3 is a sectional view of a mixing ejector applied to an apparatus for producing and supplying water-in-oil emulsified fuel according to a first embodiment of the present invention.
- FIG. 4 is a sectional view of a double-type line mixer applied to an apparatus for producing and supplying water-in-oil emulsified fuel according to a first embodiment of the present invention.
- FIG. 5 is a structural view of an apparatus for producing and supplying water-in-oil emulsified fuel according to a second embodiment of the present invention.
- FIG. 6 is a structural view of an apparatus for producing and supplying water-in-oil emulsified fuel according to a third embodiment of the present invention.
- FIG. 7 is an apparatus for producing and supplying water-in-oil emulsified fuel according to a fourth embodiment of the present invention.
- FIG. 1 is a structural view of an apparatus for producing and supplying water-in-oil emulsified fuel according to a first embodiment of the present invention.
- an apparatus 10 for producing and supplying water-in-oil emulsified fuel includes an additive storage tank 20 for storing an emulsifier; an emulsion tank 30 for storing water-in-oil emulsified fuel; a raw material supplier for supplying at a predetermined ratio and according to predetermined values B-C oil, an emulsifier, and water, which become the raw materials for water-in-oil emulsified fuel; a first mixing section for consecutively and uniformly mixing the supplied raw materials; and a second mixing section for mixing the primarily mixed raw material oil with re-emulsified fuel to perform emulsion.
- the emulsifier stored in the additive storage tank 20 is an additive that acts to prevent the separation of water and oil when a high temperature state of the water-in-oil emulsified fuel is
- Glass wool is provided to an exterior of the additive storage tank 20 to insulate the same and maintain a constant temperature. Further, a level gauge 19 is attached to the tank 20 to sense a storage amount of the emulsifier.
- a steam coil 22 is mounted to an inner surface of the additive storage tank 20 to maintain the stored emulsifier at a temperature of 60 — 110 ° C .
- an electric heater 24 is mounted to a lower output side of the additive storage tank 20 to uniformly maintain the emulsifier exiting the tank 20 at a temperature of 60 — 1 10 ° C .
- the emulsifier exits an additive supply pump 21 at a fixed rate.
- the additive supply pump 21 will be described below.
- the emulsion tank 30 stores water-in-oil emulsified fuel, and, at the same time, performs the function of a service tank that supplies the fuel to a boiler (not shown). Such supply of the water-in-oil emulsified fuel is realized through a boiler supply line Lb, which is formed from a lower, side portion of the emulsion tank 30.
- a level switch 34 for adjusting a storage amount of the water-in-oil emulsified fuel, which is established to match a usage load of the boiler, is mounted to the emulsion tank 30.
- the level switch 34 senses a HIGH or a
- the level switch 34 operates a high level switch 34a to transmit a stop signal to the fuel supply section.
- the first batch raw material supply amount refers to a total amount of raw material (B-C oil, emulsifier, water) that is continuously supplied during a first supply time.
- the emulsion tank 30 is manufactured having a capacity of at least a two batch raw material supply amount.
- a circulation electric heater 32 is mounted adjacent to an inner surface of the emulsion tank 30.
- the circulation electric heater 32 provides sufficient heat to water-in-oil emulsified fuel, which is at a low temperature, newly mixed, and supplied to the emulsion tank 30, such that the fuel is maintained at a temperature of 60 — 80 ° C to thereby minimize a temperature difference within the emulsion tank 30.
- a structure of the circulation electric heater 32 is realized through a shell and tube heat exchanger such that a heat exchange speed is increased.
- a reducer nozzle is used at an exit according to the flow amount, and an angle of the nozzle is set at 45 ° to be directed toward an entrance of mixer pumps 28a and 28b, which will be explained below, to thereby create a vortex so that heat circulation of the water-in-oil emulsified fuel is made smooth, and uniformly mixed particles are first raised to an upper level such that outflow occurs starting with stable particles.
- a temperature retaining electric heater 31 is mounted to an exterior of the emulsion tank 30.
- the temperature retaining electric heater 31 senses the temperature of the stored water-in-oil emulsified fuel and maintains the temperature at a predetermined temperature within the range of 60 ⁇ 80 ° C .
- the heat temperature retaining electric heater 31 undergoes operation linked with the circulation electric heater 32 during an emulsion mixing operation, in the case where the temperature retaining electric heater 31 is stopped for a long duration of time following completion of one operation and before the next operation, the linking is severed and the temperature retaining electric heater 31 operates independently to maintain the emulsion tank at a constant temperature.
- the raw material supplier includes pumps and flow meters to supply each of an emulsifier, B-C oil, and water uniformly and according to predetermined values.
- the additive supply pump 21 is connected to an output of the additive storage tank 20, and operates after receiving a LOW signal of the level switch 34 of the emulsion tank 30 to supply an emulsifier at a fixed ratio of 0.5 — 1 % of the first batch raw material supply amount.
- the additive supply pump 21 discontinues operation when receiving a stop signal from the additive flow meter 23. When receiving the stop signal, the additive supply pump 21 blocks the pipe to thereby act as an additive supply line stop valve.
- the additive flow meter 23 is connected to the additive supply pump 21 and controls the same such that an emulsifier is supplied according to an emulsifier adding predetermined value. That is, the additive flow meter 23 operates when detecting a LOW signal of the level switch 34 of the emulsion tank 30. Following the supply of an emulsifier to a predetermined supply amount, the additive flow meter 23 transmits a stop signal to the additive supply pump 21 so that the same discontinues operation.
- B-C oil supply pump In order to supply B-C oil, there are provided a B-C oil supply pump
- the B-C oil supply pump 12 operates when detecting a LOW signal of the level switch 34 of the emulsion tank 30 to supply B-C oil at a fixed ratio of 69.5 — 89.5% of the first batch raw material supply amount.
- the B-C oil supply pump 12 discontinues operation when receiving a stop signal from the B-C oil flow meter 14. This signal transmission is realized through a control panel (not shown).
- the B-C oil flow meter 14 is connected to the B-C oil supply pump 12 and controls the same such that B-C oil is supplied according to a predetermined B-C oil supply amount. That is, the B-C oil flow meter 14 operates when detecting a LOW signal of the level switch 34 of the emulsion tank 30. Following the supply of B-C oil to the predetermined supply amount, the B-C flow meter 14 transmits a stop signal to the B-C oil supply pump 12 so that the same discontinues operation.
- a water cutoff valve 16 In order to supply water, there are provided a water cutoff valve 16 and a water flow meter 18.
- the water cutoff valve 16 operates when detecting a LOW signal of the level switch 34 of the emulsion tank 30 to supply water at a fixed ratio of 10 — 30% of the first batch raw material supply amount.
- the water cutoff valve 16 discontinues operation when receiving a stop signal from the water flow meter 18. This signal transmission is realized through a control panel (not shown).
- the water flow meter 18 is connected to the water cutoff valve 16 and controls the same such that water is supplied according to a predetermined water supply amount. That is, the water flow meter 18 operates when detecting a LOW signal of the level switch 34 of the emulsion tank 30. Following the supply of water to the predetermined supply amount, the water flow meter 18 transmits a stop signal to the water cutoff valve 16 to thereby discontinue the supply of water.
- the first mixing section which performs an initial pre-mix function and maximizes the efficiency of the second mixing section, includes a first mixer 25 and a mixing ejector 27.
- An additive supply line La connected to the additive flow meter 23 and a B-C oil supply line Lo connected to the B-C oil flow meter 14 are both connected to the first mixer 25 such that B-C oil and an emulsifier are mixed.
- a single-type (S-type) line mixer is used for the first mixer 25.
- a water supply line Lw and the first mixer 25 are connected to the mixing ejector 27 such that water is mixed with the raw materials that contain an emulsifier.
- the mixing ejector 27, with reference to FIG. 3, utilizes a method of performing mixing by inserting a secondary supply pipe in a venturi pipe, which is a pipe having enlarged and reduced inner diameter.
- the second mixing section performs the function mixing to minute particles the first raw material oil, which is uniformly mixed in the first mixing section, and includes a mixer pump 28 and a second mixer 29.
- the mixer pump 28 is connected to both the mixing ejector 27 and a lower end of the emulsion tank 3, and re-mixes raw material oil supplied from the mixing ejector 27 and emulsified fuel supplied from the emulsion tank 30.
- the mixer pump 28 undergoes continuous operation while the apparatus of the embodiment of the present invention is driven, and it is preferable that the mixer pump 28 has a capacity to enable mixing of the entire emulsified fuel capacity stored in the emulsion tank 30 during the time it takes for a combustion apparatus to consume one batch.
- the mixer pump 28 includes a pre-mixer pump 28b and a main mixer pump 28a, which are connected in parallel between the emulsion tank 30 and the second mixer 29, to thereby allow provisions against states of emergency and for repair of the apparatus.
- the second mixer 29 is connected to the mixer pump 28 such that water-in-oil emulsified fuel, in which raw material oil that undergoes primary mixing is emulsified to uniform minute particles, is supplied to the emulsion tank 30 through the circulation electric heater 32.
- a double-type (D-type) line mixer is preferably used.
- a capacity of the second mixer 29 is at least two times the first batch raw material supply amount, and the raw material oil that undergoes primary mixing and the emulsified fuel ideally mixed in the emulsion tank 30 are each supplied at approximately 20 - 50% to undergo secondary mixing, thereby maximizing a water ratio and particle stability.
- the apparatus 10 for producing and supplying water-in-oil emulsified fuel operates as a system that replenishes and supplies an emulsified fuel to the emulsion tank 30 according to a load amount of a boiler (not shown) while retaining a predetermined amount of fuel in the emulsion tank 30.
- operation begins at or above a low level of the emulsion tank 30.
- the level switch 34 senses a low level and transmits a LOW signal while fuel is being consumed by the operation of the boiler.
- a signal is sent to the raw material supplier from the control panel (not shown), which receives the transmitted LOW signal, such that the additive supply pump 21 and the B-C oil supply pump 12 are operated, and the water cutoff valve 16 is opened, thereby performing first batch driving.
- first batch driving an emulsifier, B-C oil, and water are supplied for a predetermined duration of time and at a predetermined ratio.
- the emulsifier and the B-C oil supplied respectively therefrom are mixed in the first mixer 25. Also, water is supplied with the opening of the water cutoff valve 16, and this supplied water is mixed with the fuel of mixed emulsifier and B-C oil in the mixing ejector 27.
- the raw materials in a state where they are all mixed, are supplied to the mixer pump 28, and emulsified fuel that is pre-mixed to 20 — 50% of the raw material oil is supplied to the mixer pump 28 from the emulsion tank
- the raw material oil mixed as described above is sent to the second mixer 29 by the mixer pump 28, and the oil is mixed to an emulsified state having uniform particles in the second mixer 29 and transmitted to the emulsion tank 30. If the temperature of the emulsion tank 30 is at or below a predetermined temperature as a result of the temperature of the emulsified fuel being low when supplied to the emulsion tank 30, the circulation electric heater 32 is turned On to raise the temperature of the emulsified fuel before supply. When the temperature of the emulsion tank is at or above a predetermined temperature, the power to the electric heater 32 is turned Off.
- the power to each pump is turned Off by the signals of the flow meters that discontinue supply. That is, if the predetermined amount of the B-C oil is supplied from the B-C oil flow meter 14, power to the B-C oil supply pump 12 is turned Off after this is sensed in the control panel. Also, if the predetermined amount of the emulsifier is supplied from the additive flow meter 23, power to the additive supply pump 21 is turned Off after this is sensed in the control panel. Finally, if the predetermined amount of the water is supplied from the water flow meter 18, the water cutoff valve 16 is closed after this is sensed in the control panel, thereby discontinuing the supply of water.
- the amount of the emulsified fuel in the emulsion tank 30 is reduced to at or below the second batch raw material supply amount. Also, the emulsified fuel in the emulsion tank 30 is circulated through the mixer pump 28 and the second mixer 29 so that continuous mixing is realized until emulsified fuel of as much as the first batch raw material supply amount is consumed depending on the boiler usage load. If the low level switch 34 is operated as a result of the continuous consumption of the emulsified fuel depending on the boiler fuel usage amount, the above process is repeated so that emulsified fuel is replenished.
- FIG. 5 is a structural view of an apparatus for producing and supplying water-in-oil emulsified fuel according to a second embodiment of the present invention.
- an apparatus 40 for producing and supplying water-in-oil emulsified fuel includes an additive storage tank 41 for storing an emulsifier; an emulsion tank 43 for storing water-in-oil emulsified fuel; a raw material supplier for supplying at a predetermined ratio and according to predetermined values B-C oil, an emulsifier, and water, which become the raw materials for water-in-oil emulsified fuel; a first mixing section for consecutively and uniformly mixing the supplied raw materials; and a second mixing section for mixing the primarily mixed raw material oil with pre-emulsified fuel to perform emulsion.
- the apparatus also includes a service tank 45 that stores water-in-oil emulsified fuel before the same is supplied to a boiler.
- the emulsion tank 43 is manufactured having a capacity of at least a two batch raw material supply amount.
- the service tank 45 receives the mixed water-in-oil emulsified fuel from the emulsion tank 43 through an emulsified fuel transporting pump 47, which is connected to a lower end of the emulsion tank 43.
- the service tank 45 temporarily stores the received water-in-oil emulsion tank 43, then supplies the same to the boiler through a boiler supply line Lb connected to a bottom end of the service tank 45.
- a level switch 49 is mounted in the service tank 45 to allow for adjustment of the amount of the water-in-oil emulsified fuel, which is established to correspond to a usage load of the boiler.
- the emulsified fuel transporting pump 47 operates when a LOW signal of the level switch 49 of the service tank 45 is sensed, and discontinues operation when a LOW signal of a level switch 46 of the emulsion tank 43 is sensed.
- a temperature retaining electric heater 48 is mounted to an outer circumference of the service tank 45 such that the temperature of the water- in-oil emulsified fuel stored therein may be maintained at a predetermined temperature.
- FIG. 6 is a structural view of an apparatus for producing and supplying water-in-oil emulsified fuel according to a third embodiment of the present invention.
- an apparatus 60 for producing and supplying water-in-oil emulsified fuel includes an additive storage tank 61 for storing an emulsifier; an emulsion tank 63 for storing water-in-oil emulsified fuel; a raw material supplier for supplying at a predetermined ratio and according to predetermined values B-C oil, an emulsifier, and water, which become the raw materials for water-in-oil emulsified fuel; a first mixing section for consecutively and uniformly mixing the supplied raw materials; and a second mixing section for mixing the primarily mixed raw material oil with pre-emulsified fuel to perform emulsion.
- a circulation electric heater 70 and a third mixer 69 are mounted in this sequence on a circulation line that extends from a mixer pump 68 to the emulsion tank 63. Accordingly, raw material oil mixed in the mixer pump 68 uniformly absorbs heat of a predetermined temperature in the circulation electric heater 70 and is supplied to the third mixer 69. After this raw material oil is emulsified in the third mixer 69 to uniform and minute particles, it is supplied to the emulsion tank 63.
- a single-type mixer is used for a first mixer 65, where an additive supply line La and a B-C oil supply line Lo meet to mix an emulsifier and B-C oil
- a single-type mixer is used for a second mixer 67, where raw material oil mixed in the first mixer 65 and water supplied from a water supply line Lw are mixed.
- a double-type mixer is used for a third mixer 69 that emulsifies mixed raw material oil.
- FIG. 7 is an apparatus for producing and supplying water-in-oil emulsified fuel according to a fourth embodiment of the present invention.
- an apparatus 80 for producing and supplying water-in-oil emulsified fuel includes an additive storage tank 81 for storing an emulsifier; an emulsion tank 83 for storing water-in-oil emulsified fuel; a raw material supplier for supplying at a predetermined ratio and according to predetermined values B-C oil, an emulsifier, and water, which become the raw materials for water-in-oil emulsified fuel; a first mixing section for consecutively and uniformly mixing the supplied raw materials; and a second mixing section for mixing the primarily mixed raw material oil with pre-emulsified fuel to perform emulsion.
- a mixing ejector and a single-type mixer are used for a first mixer 84, where an additive supply line La and a B-C oil supply line Lo meet to mix an emulsifier and B-C oil, and for a second mixer 86, where raw material oil mixed in the first mixer 84 and water supplied from a water supply line Lw are mixed.
- a double-type mixer is used for a third mixer 88 that emulsifies mixed raw material oil.
- raw material oil supplied from a mixer pump 85 is emulsified therein to uniform and minute particles, then supplied directly to the emulsion tank 83.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Feeding And Controlling Fuel (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Spray-Type Burners (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB028298861A CN1293937C (en) | 2002-10-16 | 2002-10-16 | Apparatus for producing water-in-oil emulsified fuel and supplying the same |
AU2002349561A AU2002349561A1 (en) | 2002-10-16 | 2002-10-16 | Apparatus for producing water-in-oil emulsified fuel and supplying the same |
JP2004545004A JP4084356B2 (en) | 2002-10-16 | 2002-10-16 | Apparatus for producing and supplying water-in-oil emulsion fuel |
US10/531,673 US20060143978A1 (en) | 2002-10-16 | 2002-10-16 | Apparatus for producing water-in-oil emulsifield fuel and supplying the same |
PCT/KR2002/001935 WO2004035716A1 (en) | 2002-10-16 | 2002-10-16 | Apparatus for producing water-in-oil emulsified fuel and supplying the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/KR2002/001935 WO2004035716A1 (en) | 2002-10-16 | 2002-10-16 | Apparatus for producing water-in-oil emulsified fuel and supplying the same |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004035716A1 true WO2004035716A1 (en) | 2004-04-29 |
Family
ID=32105544
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2002/001935 WO2004035716A1 (en) | 2002-10-16 | 2002-10-16 | Apparatus for producing water-in-oil emulsified fuel and supplying the same |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP4084356B2 (en) |
CN (1) | CN1293937C (en) |
AU (1) | AU2002349561A1 (en) |
WO (1) | WO2004035716A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007129809A1 (en) * | 2006-05-10 | 2007-11-15 | Il Ryong Kim | A burning system for emulsified fuel |
GB2441529A (en) * | 2006-09-06 | 2008-03-12 | Taiwan Wolmo Inc | Apparatus for providing fuel saving and low emission heavy fuel oil |
EP2340887A1 (en) * | 2009-12-30 | 2011-07-06 | ITI S.r.l. | Plant for the production of an emulsion of water in hydrocarbons |
CN106582458A (en) * | 2015-10-16 | 2017-04-26 | 世能华奇(北京)科技发展有限公司 | Manufacturing method of mixed diesel, mixed diesel manufactured through method and manufacturing device |
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JP2009085493A (en) * | 2007-09-28 | 2009-04-23 | Aitekku:Kk | Emulsion fuel feeder and mixer used therefor |
CN101607146B (en) * | 2009-07-07 | 2011-11-02 | 重庆明珠机电有限公司 | Oil and water separation system |
JP4878064B2 (en) * | 2010-01-18 | 2012-02-15 | 川崎重工業株式会社 | Fuel supply device with flash prevention device |
CN102242936A (en) * | 2010-05-12 | 2011-11-16 | 永彬(北京)科技发展有限公司 | Ejecting device and method of liquid additive for coal-fired boiler |
KR20120119292A (en) * | 2011-04-21 | 2012-10-31 | 전선아 | Burning device |
CN103244093B (en) * | 2013-04-23 | 2015-04-01 | 瑞实石油科技股份有限公司 | Method for generating combustion resonance steam from emulsified crude oil for heating oil wells |
KR101519882B1 (en) | 2013-09-17 | 2015-05-14 | (주)명성플로텍 | Apparatus for Generating Novel Recycling Energy with Treatment of Polymer Waste |
CN103706285B (en) * | 2013-12-25 | 2015-05-13 | 南海油脂工业(赤湾)有限公司 | Method and system for adding antioxidant for edible oil |
CN103908918A (en) * | 2014-04-23 | 2014-07-09 | 四川金堂海纳生物医药技术研究所 | Production process of novel fuel and fabrication method of system device for producing novel fuel |
CN106540619A (en) * | 2015-09-17 | 2017-03-29 | 张宇 | A kind of manufacturing system of energy-conserving and environment-protective emulsification, combustion oil |
CN108452558B (en) * | 2018-01-25 | 2020-04-14 | 安徽理工大学 | From ore dressing waste water treatment equipment of inhaling type turbulent flow spray tube and applied this spray tube |
CN108854641B (en) * | 2018-07-02 | 2021-09-07 | 东华工程科技股份有限公司 | Continuous pulping equipment and method for ultra-light fine materials |
CN109331674A (en) * | 2018-11-02 | 2019-02-15 | 江苏新美星包装机械股份有限公司 | Liquid formulation mixing arrangement |
CN109573932B (en) * | 2018-12-12 | 2024-01-26 | 山东隆泰石油装备有限公司 | Self-mixing skid-mounted oiling device |
CN112755827A (en) * | 2020-11-18 | 2021-05-07 | 广西金桂浆纸业有限公司 | Emulsification mechanism, switching method thereof and papermaking system |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62179596A (en) * | 1986-01-31 | 1987-08-06 | Hotsukou Kk | Device for production of water-containing emulsion fuel oil |
US6030424A (en) * | 1998-01-02 | 2000-02-29 | Matsumoto; Setsuo | Water-in-oil emulsion fuel oil production system |
US6368366B1 (en) * | 1999-07-07 | 2002-04-09 | The Lubrizol Corporation | Process and apparatus for making aqueous hydrocarbon fuel compositions, and aqueous hydrocarbon fuel composition |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57124611A (en) * | 1981-01-26 | 1982-08-03 | Nishiyama Kogyo Kk | Liquid fuel burning apparatus |
CN85107382A (en) * | 1985-09-28 | 1987-04-08 | 田中明雄 | Water in oil emulsion preparation and firing unit |
CN1088473A (en) * | 1992-12-25 | 1994-06-29 | 王广武 | Circulating emulsion device for viscous fuel oil |
-
2002
- 2002-10-16 CN CNB028298861A patent/CN1293937C/en not_active Expired - Fee Related
- 2002-10-16 WO PCT/KR2002/001935 patent/WO2004035716A1/en active Application Filing
- 2002-10-16 AU AU2002349561A patent/AU2002349561A1/en not_active Abandoned
- 2002-10-16 JP JP2004545004A patent/JP4084356B2/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62179596A (en) * | 1986-01-31 | 1987-08-06 | Hotsukou Kk | Device for production of water-containing emulsion fuel oil |
US6030424A (en) * | 1998-01-02 | 2000-02-29 | Matsumoto; Setsuo | Water-in-oil emulsion fuel oil production system |
US6368366B1 (en) * | 1999-07-07 | 2002-04-09 | The Lubrizol Corporation | Process and apparatus for making aqueous hydrocarbon fuel compositions, and aqueous hydrocarbon fuel composition |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007129809A1 (en) * | 2006-05-10 | 2007-11-15 | Il Ryong Kim | A burning system for emulsified fuel |
GB2441529A (en) * | 2006-09-06 | 2008-03-12 | Taiwan Wolmo Inc | Apparatus for providing fuel saving and low emission heavy fuel oil |
EP2340887A1 (en) * | 2009-12-30 | 2011-07-06 | ITI S.r.l. | Plant for the production of an emulsion of water in hydrocarbons |
CN106582458A (en) * | 2015-10-16 | 2017-04-26 | 世能华奇(北京)科技发展有限公司 | Manufacturing method of mixed diesel, mixed diesel manufactured through method and manufacturing device |
Also Published As
Publication number | Publication date |
---|---|
JP4084356B2 (en) | 2008-04-30 |
JP2006503254A (en) | 2006-01-26 |
AU2002349561A1 (en) | 2004-05-04 |
CN1694946A (en) | 2005-11-09 |
CN1293937C (en) | 2007-01-10 |
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