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WO2004044018A3 - Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby - Google Patents

Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby Download PDF

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Publication number
WO2004044018A3
WO2004044018A3 PCT/US2003/033244 US0333244W WO2004044018A3 WO 2004044018 A3 WO2004044018 A3 WO 2004044018A3 US 0333244 W US0333244 W US 0333244W WO 2004044018 A3 WO2004044018 A3 WO 2004044018A3
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WO
WIPO (PCT)
Prior art keywords
conjugated dienes
homo
copolymers
metal
copolymerization
Prior art date
Application number
PCT/US2003/033244
Other languages
French (fr)
Other versions
WO2004044018A2 (en
Inventor
Sven K-H Thiele
David R Wilson
Susanne Knoll
Gerhard Nord
Wilfried Leukefeld
Ina Pistor
Original Assignee
Dow Global Technologies Inc
Sven K-H Thiele
David R Wilson
Susanne Knoll
Gerhard Nord
Wilfried Leukefeld
Ina Pistor
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc, Sven K-H Thiele, David R Wilson, Susanne Knoll, Gerhard Nord, Wilfried Leukefeld, Ina Pistor filed Critical Dow Global Technologies Inc
Priority to AU2003282957A priority Critical patent/AU2003282957A1/en
Publication of WO2004044018A2 publication Critical patent/WO2004044018A2/en
Publication of WO2004044018A3 publication Critical patent/WO2004044018A3/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/083—Copolymers of ethene with aliphatic polyenes, i.e. containing more than one unsaturated bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/06—Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Metal complexes are disclosed containing at least one metal - nitrogen or metal - phosphorus bond, more particularly at least one metal - nitrogen or metal - phosphorus bond and at least one bond by the metal to an aromatic ring system. The preparation of the catalyst and the use of the prepared catalyst to produce homopolymers or copolymers of conjugated dienes or copolymers of conjugated dienes with alpha-olefins are also disclosed. In particular, the production of 1) polymer blends of a) homo- or copolymers of conjugated dienes through polymerization of 1,3-butadiene and/or isoprene with b) copolymers of conjugated dienes with alpha olefins through copolymerization of 1,3-butadiene or isoprene with ethylene, propene, octene or styrene and 2) polymer blends of a) homo- or copolymers of conjugated dienes through polymerization of 1,3-butadiene and/or isoprene with b) homopolymers or copolymers of alpha olefins through homo- or copolymerization of ethylene, propene, octene or styrene in the same reaction system using the catalyst system of the invention is described.
PCT/US2003/033244 2002-11-07 2003-10-20 Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby WO2004044018A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003282957A AU2003282957A1 (en) 2002-11-07 2003-10-20 Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US42467002P 2002-11-07 2002-11-07
US60/424,670 2002-11-07

Publications (2)

Publication Number Publication Date
WO2004044018A2 WO2004044018A2 (en) 2004-05-27
WO2004044018A3 true WO2004044018A3 (en) 2004-08-05

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Application Number Title Priority Date Filing Date
PCT/US2003/033244 WO2004044018A2 (en) 2002-11-07 2003-10-20 Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby

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AU (1) AU2003282957A1 (en)
TW (1) TW200413420A (en)
WO (1) WO2004044018A2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2542992C2 (en) * 2010-07-30 2015-02-27 Бриджстоун Корпорейшн Method of regulating copolymer chain structure
JP5917809B2 (en) * 2010-11-30 2016-05-18 株式会社ブリヂストン Copolymer, production method thereof, rubber composition, crosslinked rubber composition, and tire
BR112013019814B1 (en) 2011-02-05 2022-07-12 Bridgestone Corporation LANTHANIDE COMPLEX CATALYST AND POLYMERIZATION METHOD USING THE SAME
CN104903358B (en) 2012-09-30 2017-11-17 株式会社普利司通 Organo-metallic catalyst complex compound and use its polymerization
WO2014055868A1 (en) 2012-10-04 2014-04-10 Bridgestone Corporation Organometallic complex catalyst and polymerization method employing same
US10030092B2 (en) 2014-06-12 2018-07-24 Bridgestone Corporation Multicomponent copolymer, rubber composition, and tire
JP7097152B2 (en) * 2015-10-16 2022-07-07 株式会社ブリヂストン Multiple copolymers, rubber compositions, crosslinked rubber compositions and rubber articles
CN112745432B (en) * 2020-12-30 2023-05-05 中国科学院长春应用化学研究所 Copolymer of alpha-olefin and 2, 3-dimethyl-1, 3-butadiene and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0891993A1 (en) * 1997-07-18 1999-01-20 Mitsui Chemicals, Inc. Unsaturated copolymers, processes for preparing the same, and compositions containing the same
US6136936A (en) * 1994-06-20 2000-10-24 Montell Technology Company B.V. Ethylene copolymers, process for the preparation of ethylene-based polymers and catalyst system used therein
EP1092731A1 (en) * 1999-10-12 2001-04-18 Société de Technologie Michelin Catalytic system, process for its preparation and that of an ethylene-conjugated diene copolymer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6136936A (en) * 1994-06-20 2000-10-24 Montell Technology Company B.V. Ethylene copolymers, process for the preparation of ethylene-based polymers and catalyst system used therein
EP0891993A1 (en) * 1997-07-18 1999-01-20 Mitsui Chemicals, Inc. Unsaturated copolymers, processes for preparing the same, and compositions containing the same
EP1092731A1 (en) * 1999-10-12 2001-04-18 Société de Technologie Michelin Catalytic system, process for its preparation and that of an ethylene-conjugated diene copolymer

Also Published As

Publication number Publication date
AU2003282957A1 (en) 2004-06-03
TW200413420A (en) 2004-08-01
WO2004044018A2 (en) 2004-05-27

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