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WO2000046155A1 - Water softening - Google Patents

Water softening Download PDF

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Publication number
WO2000046155A1
WO2000046155A1 PCT/GB2000/000187 GB0000187W WO0046155A1 WO 2000046155 A1 WO2000046155 A1 WO 2000046155A1 GB 0000187 W GB0000187 W GB 0000187W WO 0046155 A1 WO0046155 A1 WO 0046155A1
Authority
WO
WIPO (PCT)
Prior art keywords
water
softening
water softening
iron
rate
Prior art date
Application number
PCT/GB2000/000187
Other languages
French (fr)
Inventor
Jonathan Lawrence Seccombe
Walid Abi Aoun
Original Assignee
Lifescience Biotech Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lifescience Biotech Limited filed Critical Lifescience Biotech Limited
Priority to AU21159/00A priority Critical patent/AU2115900A/en
Publication of WO2000046155A1 publication Critical patent/WO2000046155A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/484Treatment of water, waste water, or sewage with magnetic or electric fields using electromagnets
    • C02F1/485Treatment of water, waste water, or sewage with magnetic or electric fields using electromagnets located on the outer wall of the treatment device, i.e. not in contact with the liquid to be treated, e.g. detachable
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/48Devices for applying magnetic or electric fields
    • C02F2201/483Devices for applying magnetic or electric fields using coils
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/40Liquid flow rate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/22Eliminating or preventing deposits, scale removal, scale prevention

Definitions

  • the invention relates to water softening systems, and particularly to water softening systems using electrical water softening devices.
  • Limescale causes furring in many household appliances, such as kettles and showerheads. Scale also appears for example in baths, basins and toilets. Shampoos and detergents do not lather as they should and instead produce scum. These are the visual symptoms, but there are many hidden ones. Particular damage is caused to pipes and water heaters by internal limescale encrustation, which often results in a substantial waste of energy. For example, just 3mm of scale can cause up to 25% loss in heating efficiency. Eventually it is necessary to replace items such as pipes and hot water cylinders. However, at the same time, the minerals present in hard water are essential to humans and animals. Studies have shown that high levels of calcium in drinking water can reduce the incidence of heart attacks, compared to the incidence of heart attacks in areas having softer drinking water.
  • aerials ie. conducting wires
  • electronic watersoftening units are controlled by pre-programmed microchips to provide the aerials with electrical signals having a combination of different frequencies and amplitudes.
  • the electromagnetic radiation given off by such aerials interacts with the dissolved salts present in hard water, causing the formation of sub- microscopic clusters.
  • These clusters act as nucleation seeds for the precipitation of calcium carbonate when the water is heated. Precipitation, in the form of larger crystals, occurs on these seeds in the body of the water and not as a hard deposit of limescale on the inside of the pipes.
  • the treated water which contains less dissolved free calcium appears to behave much like chemically softened water. There is reduced encrustation, better lathering and less scum formation in the hot water. At the same time, but unlike chemically softened water where all the minerals are removed, the cold water from the tap can be safely used for drinking. There is no need for a separate "hard water tap" and no health risks whatsoever.
  • a typical test for hard water is to measure the amount of lather created by soap.
  • the poor lathering of soap associated with hard water is caused by the reaction of the soap's soluble compounds with dissolved free calcium.
  • the clusters created by an electronic water-conditioning unit convert more of the dissolved free calcium in the water into crystals in suspension than would otherwise occur.
  • the resulting water, with less dissolved free calcium now behaves as if it were chemically softened. Soap will create more lather despite the fact that the total amount of calcium, dissolved and suspended, remains the same.
  • the treated water is safe to drink. There is no need for a separate drinking source, no health risks and no salt effluent.
  • the method preferably includes raising the iron concentration of the water to at least about 70ppb (parts per billion) (or 70 micrograms per litre).
  • the method may further include the step of measuring the rate of flow of the water.
  • the method preferably includes controlling the rate at which the iron concentration is increased in accordance with the measured rate of flow of the water.
  • the invention also provides a water softening system for carrying out the above method, the system comprising a magnetic or alternating current electrical water softening device attached to a water supply at a first location, and dosing means attached to said water supply at a second location upstream of said first location for increasing the concentration of iron in the water reaching said water softening device.
  • said first and second locations may both lie within said house or building.
  • the dosing means may be a dosing pump or an electrolytic device.
  • the water softening device may be an electronic water softening unit provided with at least one aerial for producing electromagnetic radiation within the water supply.
  • Said water supply may be provided in a pipe, in which case the water softening device and dosing means may be connected or attached to said pipe.
  • the dosing means may be adapted to add a soluble iron salt, such as ferric chloride or ferric sulphate, to said water supply.
  • the water softening system may further comprise flow rate detection means for measuring the rate of flow of water in said water supply.
  • the dosing means may be adapted to add iron to said water supply in quantities which vary according to the measured rate of flow.
  • the water softening system 2 shown in the Figure comprises an electronic water softening unit 4 (for example Water King (RTM) WK1 available from the applicant, Lifescience Products Ltd) attached to a water pipe 8.
  • the pipe 8 directs water from a water supply 10 to a water user 12.
  • the electronic water softening unit 4 is provided- with two aerials 14, each of which is coiled around the pipe 8.
  • the aerials 14 are fed by an alternating electrical supply (not shown separately) provided by said electronic water softening unit 4, in order to radiate electromagnetic radiation into the water within the pipe 8, and thus soften the water in known fashion.
  • a magnetic water softening unit can be used as an alternative to the electronic water softening unit 4.
  • the dosing pump 6 is located upstream of said electronic water softening unit 4, and feeds one or more soluble iron salts (such as ferric chloride, or ferric sulphate) into the water within the pipe 8.
  • An electrolytic device shown schematically as 18 may be provided as an alternative to the dosing pump 6, and may use a sacrificial anode (not shown) to increase the iron concentration of the water.
  • the system 2 also comprises a flow rate detector 16 which measures the rate of flow of the water. This detector feeds signals to the dosing pump 6 so that the rate at which the water is dosed is increased if the flow rate increases.

Landscapes

  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

A method of softening water, comprising the steps of increasing the iron concentration of the water, and then softening the water using a magnetic or alternating current electrical water softening device. A water softening system (2) comprises an electrical or magnetic water softening device (4) attached to a water supply (8) at a first location, and dosing means (6) attached to said water supply at a second location upstream of said first location for increasing the concentration of iron in the water reaching said water softening device (4).

Description

Water Softening
The invention relates to water softening systems, and particularly to water softening systems using electrical water softening devices.
Limescale causes furring in many household appliances, such as kettles and showerheads. Scale also appears for example in baths, basins and toilets. Shampoos and detergents do not lather as they should and instead produce scum. These are the visual symptoms, but there are many hidden ones. Particular damage is caused to pipes and water heaters by internal limescale encrustation, which often results in a substantial waste of energy. For example, just 3mm of scale can cause up to 25% loss in heating efficiency. Eventually it is necessary to replace items such as pipes and hot water cylinders. However, at the same time, the minerals present in hard water are essential to humans and animals. Studies have shown that high levels of calcium in drinking water can reduce the incidence of heart attacks, compared to the incidence of heart attacks in areas having softer drinking water.
It is known to use electrical and magnetic devices to soften water. One particular known arrangement uses aerials (ie. conducting wires) wrapped around a water pipe and supplied by an alternating electrical supply provided by an electronic watersoftening unit. Such electronic water softening units are controlled by pre-programmed microchips to provide the aerials with electrical signals having a combination of different frequencies and amplitudes. The electromagnetic radiation given off by such aerials interacts with the dissolved salts present in hard water, causing the formation of sub- microscopic clusters.
These clusters act as nucleation seeds for the precipitation of calcium carbonate when the water is heated. Precipitation, in the form of larger crystals, occurs on these seeds in the body of the water and not as a hard deposit of limescale on the inside of the pipes.
Since the presence of nucleation seeds encourages the precipitation of calcium carbonate in the form of crystals in suspension. Limescale encrustation in hot water cylinders, on heating elements and other surfaces in contact with the water is substantially reduced. The crystals will either settle as a soft sludgy deposit, or be carried away with the flowing water. New appliances such as, showers, hot water cylinders and combi-boilers will remain clear. If the appliance is already encrusted, existing deposits will become soft and will either break off or be washed away in the flowing water.
To users, the treated water which contains less dissolved free calcium appears to behave much like chemically softened water. There is reduced encrustation, better lathering and less scum formation in the hot water. At the same time, but unlike chemically softened water where all the minerals are removed, the cold water from the tap can be safely used for drinking. There is no need for a separate "hard water tap" and no health risks whatsoever.
A typical test for hard water is to measure the amount of lather created by soap. The poor lathering of soap associated with hard water is caused by the reaction of the soap's soluble compounds with dissolved free calcium. However, the clusters created by an electronic water-conditioning unit convert more of the dissolved free calcium in the water into crystals in suspension than would otherwise occur. The resulting water, with less dissolved free calcium now behaves as if it were chemically softened. Soap will create more lather despite the fact that the total amount of calcium, dissolved and suspended, remains the same.
Unlike ion exchange softened water, where all the minerals are removed and replaced by sodium, the treated water is safe to drink. There is no need for a separate drinking source, no health risks and no salt effluent.
However, such electronic water-conditioning units do not always operate effectively, and a certain variation has been found in their ability to soften water in practice. It is an object of the invention to provide a method of softening water and a water softening system which improve on the prior art. According to the invention there is provided a method of softening water, comprising the steps of increasing the iron concentration of the water, and then softening the water using a magnetic or alternating current electrical water softening device.
The applicant has discovered that such water softening devices do not operate effectively when the concentration of iron is too low.
The method preferably includes raising the iron concentration of the water to at least about 70ppb (parts per billion) (or 70 micrograms per litre).
If the water forms part of a water supply, the method may further include the step of measuring the rate of flow of the water.
The method preferably includes controlling the rate at which the iron concentration is increased in accordance with the measured rate of flow of the water.
The invention also provides a water softening system for carrying out the above method, the system comprising a magnetic or alternating current electrical water softening device attached to a water supply at a first location, and dosing means attached to said water supply at a second location upstream of said first location for increasing the concentration of iron in the water reaching said water softening device.
If the water softening system is used to soften water in a given house or building, said first and second locations may both lie within said house or building.
The dosing means may be a dosing pump or an electrolytic device.
The water softening device may be an electronic water softening unit provided with at least one aerial for producing electromagnetic radiation within the water supply.
Said water supply may be provided in a pipe, in which case the water softening device and dosing means may be connected or attached to said pipe. The dosing means may be adapted to add a soluble iron salt, such as ferric chloride or ferric sulphate, to said water supply.
The water softening system may further comprise flow rate detection means for measuring the rate of flow of water in said water supply.
The dosing means may be adapted to add iron to said water supply in quantities which vary according to the measured rate of flow.
The invention will now be more particularly described, by way of example only, with reference to the single accompanying Figure, which shows a water softening system in accordance with the invention.
The water softening system 2 shown in the Figure comprises an electronic water softening unit 4 (for example Water King (RTM) WK1 available from the applicant, Lifescience Products Ltd) attached to a water pipe 8. The pipe 8 directs water from a water supply 10 to a water user 12.
The electronic water softening unit 4 is provided- with two aerials 14, each of which is coiled around the pipe 8. The aerials 14 are fed by an alternating electrical supply (not shown separately) provided by said electronic water softening unit 4, in order to radiate electromagnetic radiation into the water within the pipe 8, and thus soften the water in known fashion. As an alternative to the electronic water softening unit 4, a magnetic water softening unit can be used.
The dosing pump 6 is located upstream of said electronic water softening unit 4, and feeds one or more soluble iron salts (such as ferric chloride, or ferric sulphate) into the water within the pipe 8. An electrolytic device (shown schematically as 18) may be provided as an alternative to the dosing pump 6, and may use a sacrificial anode (not shown) to increase the iron concentration of the water.
The system 2 also comprises a flow rate detector 16 which measures the rate of flow of the water. This detector feeds signals to the dosing pump 6 so that the rate at which the water is dosed is increased if the flow rate increases.

Claims

CLAIMS:
1. A method of softening water, comprising the steps of increasing the iron concentration of the water, and then softening the water using a magnetic or alternating current electrical water softening device.
2. A method of softening water as claimed in claim 1, which includes raising the iron concentration of the water to at least about 70ppb.
3. A method of softening the water as claimed in any preceding claim, which further includes the step of measuring the rate of flow of the water.
4. A method of softening water as claimed in claim 3, which further includes controlling the rate at which the iron concentration is increased in accordance with the measured rate of flow of the water.
5. A water softening system for carrying out the method of any preceding claim, the system comprising a magnetic or alternating current electrical water softening device attached to a water supply at a first location, and dosing means attached to said water supply at a second location upstream of "said first location for increasing the concentration of iron in the water reaching said water softening device.
6. A water softening system as claimed in claim 5, wherein said first and second locations both lie within the same house or building.
7. A water softening system as claimed in claim 5 or 6, wherein the dosing means is a dosing pump.
8. A water softening system as claimed in claim 5 or 6, wherein the dosing means is an electrolytic device.
9. A water softening system as claimed in any one of claims 5 to 8, wherein the water softening device is an electronic water softening unit provided with at least one aerial for producing electromagnetic radiation within the water supply.
10. A water softening system as claimed in any one of claims 5 to 9, wherein said water supply is provided in a pipe, and the water softening device and dosing means are connected or attached to said pipe.
11. A water softening system as claimed in any one of claims 5 to 10, wherein the dosing means is adapted to add a soluble iron salt, such as ferric chloride or ferric sulphate, to said water supply.
12. A water softening system as claimed in any one of claims 5 to 11, which further comprises flow rate detection means for measuring the rate of flow of water in said water supply.
13. A water softening system as claimed in 12, wherein the dosing means is adapted to add iron to said water supply in quantities which vary according to the measured rate of flow.
PCT/GB2000/000187 1999-02-04 2000-01-24 Water softening WO2000046155A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU21159/00A AU2115900A (en) 1999-02-04 2000-01-24 Water softening

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9902345.9 1999-02-04
GB9902345A GB2339423B (en) 1999-02-04 1999-02-04 Water softening

Publications (1)

Publication Number Publication Date
WO2000046155A1 true WO2000046155A1 (en) 2000-08-10

Family

ID=10847002

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2000/000187 WO2000046155A1 (en) 1999-02-04 2000-01-24 Water softening

Country Status (3)

Country Link
AU (1) AU2115900A (en)
GB (1) GB2339423B (en)
WO (1) WO2000046155A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2395193B (en) * 2002-11-07 2004-10-20 Hotta Uk Ltd Electronic de-scalers
NL1031676C2 (en) * 2006-04-25 2007-10-26 Leonardus Franciscus H Vaessen Cleaning system for lines in beer tap installation, comprises coil for creating alternating electromagnetic field in liquid flowing along line and electrolysis cell for forming sodium hypochlorite

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE526503A (en) *
US4427544A (en) * 1980-04-11 1984-01-24 Ricardo Roch Magneto electrochemical reactor
FR2607574A1 (en) * 1986-12-01 1988-06-03 Niessen Philippe Electronic anti-scale device acting inductively
US4879045A (en) * 1986-01-13 1989-11-07 Eggerichs Terry L Method and apparatus for electromagnetically treating a fluid
US5074998A (en) * 1988-09-02 1991-12-24 Baat Doelman Jan P De Apparatus for treating liquid to prevent and/or remove scale deposits
WO1998049103A1 (en) * 1997-04-28 1998-11-05 Gianni Zangrando Device for the elimination of calcareous incrustations and deposits in pipelines, water systems and equipment connected thereto

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL85879C (en) * 1949-11-22
US5328572A (en) * 1991-02-20 1994-07-12 Ibbott Jack Kenneth Dual system using three electrodes to treat fluid
US5387324A (en) * 1992-07-21 1995-02-07 Ibbott; Jack K. Method for providing an ionic change in fluid

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE526503A (en) *
US4427544A (en) * 1980-04-11 1984-01-24 Ricardo Roch Magneto electrochemical reactor
US4879045A (en) * 1986-01-13 1989-11-07 Eggerichs Terry L Method and apparatus for electromagnetically treating a fluid
FR2607574A1 (en) * 1986-12-01 1988-06-03 Niessen Philippe Electronic anti-scale device acting inductively
US5074998A (en) * 1988-09-02 1991-12-24 Baat Doelman Jan P De Apparatus for treating liquid to prevent and/or remove scale deposits
WO1998049103A1 (en) * 1997-04-28 1998-11-05 Gianni Zangrando Device for the elimination of calcareous incrustations and deposits in pipelines, water systems and equipment connected thereto

Also Published As

Publication number Publication date
GB9902345D0 (en) 1999-03-24
GB2339423B (en) 2000-03-29
AU2115900A (en) 2000-08-25
GB2339423A (en) 2000-01-26

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