WO1996039048A1 - Dry mix texture modified beverage using gellan gum - Google Patents
Dry mix texture modified beverage using gellan gum Download PDFInfo
- Publication number
- WO1996039048A1 WO1996039048A1 PCT/US1996/008053 US9608053W WO9639048A1 WO 1996039048 A1 WO1996039048 A1 WO 1996039048A1 US 9608053 W US9608053 W US 9608053W WO 9639048 A1 WO9639048 A1 WO 9639048A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- dry
- gellan gum
- dry mix
- fluidized
- beverage
- Prior art date
Links
- 235000013361 beverage Nutrition 0.000 title claims abstract description 45
- 229920002148 Gellan gum Polymers 0.000 title claims abstract description 25
- 235000010492 gellan gum Nutrition 0.000 title claims abstract description 25
- 239000000216 gellan gum Substances 0.000 title claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003352 sequestering agent Substances 0.000 claims abstract description 7
- 239000000796 flavoring agent Substances 0.000 claims description 12
- 235000019634 flavors Nutrition 0.000 claims description 12
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 4
- 235000013882 gravy Nutrition 0.000 claims description 4
- 235000014438 salad dressings Nutrition 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 3
- 235000003599 food sweetener Nutrition 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 239000003765 sweetening agent Substances 0.000 claims description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- 239000001361 adipic acid Substances 0.000 claims description 2
- 235000011037 adipic acid Nutrition 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 235000011087 fumaric acid Nutrition 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 claims 1
- 239000001509 sodium citrate Substances 0.000 claims 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims 1
- 235000011083 sodium citrates Nutrition 0.000 claims 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims 1
- 235000013305 food Nutrition 0.000 abstract description 7
- 239000000546 pharmaceutical excipient Substances 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 2
- 239000000499 gel Substances 0.000 description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 238000009472 formulation Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 159000000007 calcium salts Chemical class 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000000416 hydrocolloid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000010443 alginic acid Nutrition 0.000 description 2
- 229920000615 alginic acid Polymers 0.000 description 2
- 150000005323 carbonate salts Chemical class 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- RBLGLDWTCZMLRW-UHFFFAOYSA-K dicalcium;phosphate;dihydrate Chemical compound O.O.[Ca+2].[Ca+2].[O-]P([O-])([O-])=O RBLGLDWTCZMLRW-UHFFFAOYSA-K 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000015122 lemonade Nutrition 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
- IWYGVDBZCSCJGT-UHFFFAOYSA-N 1-(2,5-dimethoxy-4-methylphenyl)-n-methylpropan-2-amine Chemical compound CNC(C)CC1=CC(OC)=C(C)C=C1OC IWYGVDBZCSCJGT-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 description 1
- 244000099147 Ananas comosus Species 0.000 description 1
- 235000007119 Ananas comosus Nutrition 0.000 description 1
- 108010011485 Aspartame Proteins 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 102000014171 Milk Proteins Human genes 0.000 description 1
- 108010011756 Milk Proteins Proteins 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 241000790234 Sphingomonas elodea Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010358 acesulfame potassium Nutrition 0.000 description 1
- 239000000619 acesulfame-K Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- 239000000605 aspartame Substances 0.000 description 1
- 235000010357 aspartame Nutrition 0.000 description 1
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 1
- 229960003438 aspartame Drugs 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 235000011850 desserts Nutrition 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 235000014654 dry sauces/powder mixes Nutrition 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000000989 food dye Substances 0.000 description 1
- 239000008369 fruit flavor Substances 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 239000008123 high-intensity sweetener Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000021239 milk protein Nutrition 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 235000013615 non-nutritive sweetener Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 235000019204 saccharin Nutrition 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 229940081974 saccharin Drugs 0.000 description 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/385—Concentrates of non-alcoholic beverages
- A23L2/39—Dry compositions
- A23L2/395—Dry compositions in a particular shape or form
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
- A23G9/04—Production of frozen sweets, e.g. ice-cream
- A23G9/045—Production of frozen sweets, e.g. ice-cream of slush-ice, e.g. semi-frozen beverage
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
- A23G9/52—Liquid products; Solid products in the form of powders, flakes or granules for making liquid products ; Finished or semi-finished solid products, frozen granules
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/269—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of microbial origin, e.g. xanthan or dextran
- A23L29/272—Gellan
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
- A23G2200/06—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing beet sugar or cane sugar if specifically mentioned or containing other carbohydrates, e.g. starches, gums, alcohol sugar, polysaccharides, dextrin or containing high or low amount of carbohydrate
Definitions
- the present invention relates generally to stabilized dry food and beverage powdered mixes which when hydrated produce a palatable beverage, salad dressing, gravy and the like. More specifically, the present invention relates to a dry beverage mix which, when added to water produces a fun to drink, fluidized gel beverage.
- Gellan gum beverages have unique mouthfeel, body, and flavor release properties and profiles which are distinct from the mouthfeel, body and flavor release properties obtained with beverages prepared with non-gelling hydrocolloids such as carboxymethylcellulose, xanthan gum, and polyethylene glycol alginates. Such non-gelling hydrocolloids are thickeners which linger in the mouth longer than a shattered gellan gum gel matrix.
- Beverages which can be prepared with gellan gum include lemonade beverages, fruit beverages, alcohol beverages, and coffee beverages.
- Gellan gum beverages can be prepared from concentrated flavor systems such as apple, orange, pineapple, daiquiri, or highly concentrated shelf stable flavor systems containing gellan gum.
- Beverages containing blends of gellan gum display rheological properties of a weak gel system when measured using dynamic viscoelastic measurements.
- One characteristic of a gelled system is a constant elastic
- the present invention is a dry powder mix for unique gelled beverages and fluidized foods consisting of minor amounts of gellan gum (400-800 ppm), a sequestrant, sugar and a number of excipients.
- the dry mix is a complete blend, shelf stable and immediately hydratable upon the addition of water.
- the fluidized gel formed imparts an extremely pleasant and lubricous mouthfeel upon consumption.
- the present invention comprises a gellan gum based dry mix for the preparation of a texture modified beverage.
- the gellan gum based mix may also be tailored or modified to serve as a dry mix for salad dressings, gravies, fluidized desserts and the like. Surprisingly, very small amounts of the gum and other excipients are needed to produce a unique and flavorful beverage or fluidized comestible.
- Gellan gum is a heteropolysaccharide prepared by the fermentation ol Pseudomonas elodea ATCC 31461. Gellan gum is available from Kelco Division of Monsanto, San Diego, CA, under various names, including KELCOGEL, KELCOGEL PC, and KELCOGEL F. Processes for preparing gellan gum include those described in United States Patents
- the gellan gum formulation of the present invention is a dry mix blend which can be added to cold or hot water and subsequently becomes a fluidized gelled beverage that can be eaten with a spoon or straw.
- the beverage dry mix is comprised primarily of a sweetener such as sugar in an amount of from about 95.0% to about 97.0% of the total weight of the composition.
- a low calorie beverage mix could be formulated using a high intensity sweetener such as aspartame, acesulfame-K or saccharin and the like together with a low calorie bulking agent but for the purposes of the present invention sugar is most preferred.
- Gellan gum will comprise a minor amount of the dry beverage mix such as from about 0.5 to 1.5 wt percent Preferably this will be about 1.0% of the total weight of the mix.
- One or more acidulents su * ch as fumaric acid, citric acid, malic acid, adipic acid, tartaric acid and mixtures thereof may be added to enhance any fruit flavor that is chosen for the drink. Again, these acids are added in relatively minor amounts of from about 1.0% to about 1.2%.
- a sequestering agent such as powdered sodium tripolyphosph- ate, FMC Corp., Philadelphia, PA, is added as a chelating agent which aids in gum hydration. Furthermore, it can also provide for the stabilization of the flavor, color and texture ingredients once the dry mix is dissolved in water.
- the sequestrant is added in an amount of from about 1.0% to about 1.5% and preferably in an amount of 1.125%.
- An alkaline salt such as calcium carbonate provides a source of calcium ions for gelation and further adds body and texture ot the gelled beverage when mixed with water. In this manner it functions as a gelling salt For a gelled beverage from a dry mix to be commercially successful, it must be stable in the concentrated and diluted finished beverage solutions.
- a calcium salt is also added to the mix.
- Suitable calcium salts useful in the practice of the present invention are characterized by the fact that they are insoluble in solutions at neutral pH and are soluble in solutions that possess an acidic pH.
- Particularly suitable calcium salts useful in the practice of the present invention comprise dicalcium phosphate dihydrate, calcium carbonate and mixtures thereof.
- the salt is added to the mixture in an amount of approximately 24% to about 40% by weight of the total weight of the concentrated texture modifier and suspension agent composition.
- Other carbonate salts may also be used but calcium carbonate is most preferred.
- the carbonate salt is added to the dry mix in powdered form in amounts of from about 0.05% to about 0.15% by weight and most preferably in an amount of about 0.10%.
- excipients such as clouding agents, flavors and coloring agents may be added to the mix depending on the type and flavor of beverage desired. For example, cherry or fruit punch flavors will incorpo ⁇ rate a red food dye coloring.
- Clouding agents such as Beatreme #3579 (Beatrice Foods, Chicago, EL) are added in order to give the visual appearance of the cellular constituents characteristically found in natural fruit juices.
- Example 1 is provided to more specifically teach and disclose that which Applicants claim to be their invention. They are for illustrative purposes only however, and it is recognized that there are many minor changes and variations that may be made with respect to the formulations that are not recited herein. It is to be understood that to the extent that any such variations do not materially alter or change the final product so conceived, such variations fall within the spirit and scope of the present invention as recited by the claims that follow:
- the dry mix gelled beverage composition was prepared using the following formulation to prepare a lemonade flavored gelled beverage.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Non-Alcoholic Beverages (AREA)
- Seasonings (AREA)
- Confectionery (AREA)
Abstract
The present invention is a dry powder mix for unique gelled beverages and fluidized foods consisting of minor amounts of gellan gum (400-800 ppm), a sequestrant, sugar and a number of excipients. The dry mix is a complete blend, shelf stable and immediately hydratable upon the addition of water. The fluidized gel formed imparts an extremely pleasant and lubricous mouthfeel upon consumption.
Description
DRY MIX TEXTURE MODIFIED BEVERAGE
USING GELLAN GUM
Field of the Invention
The present invention relates generally to stabilized dry food and beverage powdered mixes which when hydrated produce a palatable beverage, salad dressing, gravy and the like. More specifically, the present invention relates to a dry beverage mix which, when added to water produces a fun to drink, fluidized gel beverage.
Background of the Invention There are many commercially available dry powdered mixes which when mixed in water or other solvent yield numerous beverage, salad dressing, gravy and other fluidized comestible compositions. These diy mix products have been known for years and afford the benefits of long term shelf life and package stability, minimal space requirements compared to the finished, hydrated product and comparable taste, flavor and mouthfeel characteristics to those products manufactured and sold ready-to-eat or drink- In the past, hydrocolloids such as gum arabic, xanthan gum, alginates, pectin, starch, carrageenan, modified starch, and carboxymethylcellulose have been used to stabilize beverages and dry powder mixes used to make these beverages. Relatively large quantities of these materials are required in order to achieve an effective degree of stabilization. Moreover, while stabilizing the beverage, these materials
unfortunately affect beverage flavor and mouthfeel. Sometimes, as with xanthan gum, the beverage stabilizing material reacts with other beverage components, including proteins (such as milk proteins or beer proteins), affecting beverage flavor and stabilizer efficacy. Gellan gum beverages have unique mouthfeel, body, and flavor release properties and profiles which are distinct from the mouthfeel, body and flavor release properties obtained with beverages prepared with non-gelling hydrocolloids such as carboxymethylcellulose, xanthan gum, and polyethylene glycol alginates. Such non-gelling hydrocolloids are thickeners which linger in the mouth longer than a shattered gellan gum gel matrix. Beverages which can be prepared with gellan gum include lemonade beverages, fruit beverages, alcohol beverages, and coffee beverages. Gellan gum beverages can be prepared from concentrated flavor systems such as apple, orange, pineapple, daiquiri, or highly concentrated shelf stable flavor systems containing gellan gum.
Beverages containing blends of gellan gum display rheological properties of a weak gel system when measured using dynamic viscoelastic measurements. One characteristic of a gelled system is a constant elastic
(storage) modulus over a range of strain values up to a critical strain value, at which critical strain value the modulus drops significantly.
None of the known prior art powdered food and beverage dry mix compositions used to prepare beverages and other fluidized comestible have successfully utilized gellan gum in a stabilized ready to use composi¬ tion. None of the prior art has presented or disclosed a powdered dry mix containing minor amounts of gellan gum which, when hydrated, form a fluidized gel beverage or food product which has superior mouthfeel and taste characteristics as well as being aesthetically appealing.
Summary of the Invention The present invention is a dry powder mix for unique gelled beverages and fluidized foods consisting of minor amounts of gellan gum
(400-800 ppm), a sequestrant, sugar and a number of excipients. The dry mix is a complete blend, shelf stable and immediately hydratable upon the addition of water. The fluidized gel formed imparts an extremely pleasant and lubricous mouthfeel upon consumption. Detailed Description of the Invention
The present invention comprises a gellan gum based dry mix for the preparation of a texture modified beverage. The gellan gum based mix may also be tailored or modified to serve as a dry mix for salad dressings, gravies, fluidized desserts and the like. Surprisingly, very small amounts of the gum and other excipients are needed to produce a unique and flavorful beverage or fluidized comestible.
Gellan gum is a heteropolysaccharide prepared by the fermentation ol Pseudomonas elodea ATCC 31461. Gellan gum is available from Kelco Division of Monsanto, San Diego, CA, under various names, including KELCOGEL, KELCOGEL PC, and KELCOGEL F. Processes for preparing gellan gum include those described in United States Patents
4,326,052 and 4,326,053 to Kang et al. which are hereby incorporated by reference. It is useful for a variety of gelling, texturizing, stabilizing and film forming applications, particularly as a gelling agent in foods, personal care products and industrial applications. Gellan gum can be used to prepare fluid gels which are pourable fluid masses with a very short flowable texture.
By varying the gellan gum concentration, the shear rate, temperature, ion types and levels, different textures and flow properties can be obtained.
The gellan gum formulation of the present invention is a dry mix blend which can be added to cold or hot water and subsequently becomes a fluidized gelled beverage that can be eaten with a spoon or straw. The beverage dry mix is comprised primarily of a sweetener such as sugar in an amount of from about 95.0% to about 97.0% of the total weight of the composition. Conceivably, a low calorie beverage mix could be formulated using a high intensity sweetener such as aspartame, acesulfame-K or
saccharin and the like together with a low calorie bulking agent but for the purposes of the present invention sugar is most preferred.
Gellan gum will comprise a minor amount of the dry beverage mix such as from about 0.5 to 1.5 wt percent Preferably this will be about 1.0% of the total weight of the mix. One or more acidulents su * ch as fumaric acid, citric acid, malic acid, adipic acid, tartaric acid and mixtures thereof may be added to enhance any fruit flavor that is chosen for the drink. Again, these acids are added in relatively minor amounts of from about 1.0% to about 1.2%. A sequestering agent such as powdered sodium tripolyphosph- ate, FMC Corp., Philadelphia, PA, is added as a chelating agent which aids in gum hydration. Furthermore, it can also provide for the stabilization of the flavor, color and texture ingredients once the dry mix is dissolved in water. The sequestrant is added in an amount of from about 1.0% to about 1.5% and preferably in an amount of 1.125%.
An alkaline salt such as calcium carbonate provides a source of calcium ions for gelation and further adds body and texture ot the gelled beverage when mixed with water. In this manner it functions as a gelling salt For a gelled beverage from a dry mix to be commercially successful, it must be stable in the concentrated and diluted finished beverage solutions.
When gellan gum is used as a gelling agent, it is of paramount importance that the initial ionic concentration of the dry mix be balanced with the final drink formulation. In fruit beverages this balance is achieved with insoluble calcium and a slowly soluble acid (at neutral pH) such as fumaric acid pH. The concentrated fluid gel should be formulated such that upon dilution in a finished beverage, the gel remains homogeneous and not aggregated to become a "particle gel".
Optionally, and preferably, a calcium salt is also added to the mix. Suitable calcium salts useful in the practice of the present invention are characterized by the fact that they are insoluble in solutions at neutral
pH and are soluble in solutions that possess an acidic pH. Particularly suitable calcium salts useful in the practice of the present invention comprise dicalcium phosphate dihydrate, calcium carbonate and mixtures thereof. The salt is added to the mixture in an amount of approximately 24% to about 40% by weight of the total weight of the concentrated texture modifier and suspension agent composition. Other carbonate salts may also be used but calcium carbonate is most preferred. The carbonate salt is added to the dry mix in powdered form in amounts of from about 0.05% to about 0.15% by weight and most preferably in an amount of about 0.10%. Other excipients such as clouding agents, flavors and coloring agents may be added to the mix depending on the type and flavor of beverage desired. For example, cherry or fruit punch flavors will incorpo¬ rate a red food dye coloring. Clouding agents such as Beatreme #3579 (Beatrice Foods, Chicago, EL) are added in order to give the visual appearance of the cellular constituents characteristically found in natural fruit juices.
The following examples are provided to more specifically teach and disclose that which Applicants claim to be their invention. They are for illustrative purposes only however, and it is recognized that there are many minor changes and variations that may be made with respect to the formulations that are not recited herein. It is to be understood that to the extent that any such variations do not materially alter or change the final product so conceived, such variations fall within the spirit and scope of the present invention as recited by the claims that follow:
Example 1
The dry mix gelled beverage composition was prepared using the following formulation to prepare a lemonade flavored gelled beverage.
All the ingredients were thoroughly mixed in dry or powdered form insuring that no lumps were formed and a uniform blend is achieved. The mbc (3-4 teaspoons) was then added to 8 ounces of hot or cold water and stirred for about 2-3 minutes. The beverage was then cooled at about 40°F. in a refrigerator for thirty minutes at which time a fluidized gel formed which was consumable with a spoon, straw or straight from the glass.
Claims
1. A one step dry mix for the preparation of a fluidized gel comprising from about 0.5% to about 2.0% gellan gum.
2. The dry mix of claim 1 for the preparation of a fluidized gel comprising from about 0.75% to about 1.5% gellan gum.
3. The dry mix of claim 2 further comprising one or more sequestrants, gelling salts, sweeteners, flavors, acidυlents, stabilizers and colorants.
4. The dry mix of claim 3 wherein said sequestrant is selected from the group comprising sodium tripolyphosphate, sodium citrate, sodium hexametaphosphate and mixtures thereof.
5. The diy mix of claim 4 wherein said acidulent is selected from the group comprising fumaric acid, citric acid, malic acid, adipic acid and mixtures thereof.
6. The dry mix of claim 5 wherein said fluidized gel is a beverage prepared by the addition of said dry mix to water.
7. The dry mbc of claim 6 wherein said water is cold.
8. The dry mbc of claim 6 wherein said water is hot
9. A fluidized gelled beverage prepared from a dry mix comprising from about 0.5% to about 2.0% gellan gum.
10. The fluidized gelled beverage of claim 9 wherein said gellan gum comprises from about 0.75% to about 1.5% of said dry mbc.
11. The fluidized gelled beverage of claim 10 wherein said dry mix further comprises one or more sequestrants, sweeteners, acidulants stabilizers and colorants.
12. A salad dressing prepared from the dry mbc of claim 1.
13. A gravy prepared from the dry mbc of claim 1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU59554/96A AU5955496A (en) | 1995-06-06 | 1996-05-30 | Dry mix texture modified beverage using gellan gum |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US47113495A | 1995-06-06 | 1995-06-06 | |
US08/471,134 | 1995-06-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996039048A1 true WO1996039048A1 (en) | 1996-12-12 |
Family
ID=23870388
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1996/008053 WO1996039048A1 (en) | 1995-06-06 | 1996-05-30 | Dry mix texture modified beverage using gellan gum |
Country Status (3)
Country | Link |
---|---|
AR (1) | AR002318A1 (en) |
AU (1) | AU5955496A (en) |
WO (1) | WO1996039048A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8017168B2 (en) | 2006-11-02 | 2011-09-13 | The Coca-Cola Company | High-potency sweetener composition with rubisco protein, rubiscolin, rubiscolin derivatives, ace inhibitory peptides, and combinations thereof, and compositions sweetened therewith |
WO2011131976A1 (en) * | 2010-04-21 | 2011-10-27 | The University Of Birmingham | Comestible product |
EP2653494A1 (en) | 2012-04-20 | 2013-10-23 | RUDOLF WILD GmbH & CO. KG | Aqueous gellan dispersion |
US9101160B2 (en) | 2005-11-23 | 2015-08-11 | The Coca-Cola Company | Condiments with high-potency sweetener |
WO2022031158A1 (en) * | 2020-08-04 | 2022-02-10 | Barragan Espinoza Gerogina | Flavouring composition for beverages, foods, and desserts |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996000018A1 (en) * | 1994-06-24 | 1996-01-04 | Monsanto Company | Gellan gum beverage |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0130689A1 (en) * | 1983-05-31 | 1985-01-09 | Merck & Co. Inc. | Non-heated gellan gum gels |
JPS62130671A (en) * | 1985-12-03 | 1987-06-12 | San Ei Chem Ind Ltd | Instant food solid drink |
JPS63169948A (en) * | 1987-01-06 | 1988-07-13 | San Ei Chem Ind Ltd | Preparation of gelan gum soluble in cold water |
JPS6427445A (en) * | 1987-07-22 | 1989-01-30 | Sanei Kagaku Kogyo Kk | Preparation of gelatinous seasoning |
JPH0218487A (en) * | 1988-07-05 | 1990-01-22 | San Ei Chem Ind Ltd | Production of instantly thickened and gelatinized material |
JPH02145159A (en) * | 1988-11-25 | 1990-06-04 | San Ei Chem Ind Ltd | Production of thermally reversible gelan gum gel |
WO1996000018A1 (en) * | 1994-06-24 | 1996-01-04 | Monsanto Company | Gellan gum beverage |
-
1996
- 1996-05-30 WO PCT/US1996/008053 patent/WO1996039048A1/en active Application Filing
- 1996-05-30 AU AU59554/96A patent/AU5955496A/en not_active Abandoned
- 1996-06-05 AR ARP960102923A patent/AR002318A1/en unknown
Patent Citations (7)
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EP0130689A1 (en) * | 1983-05-31 | 1985-01-09 | Merck & Co. Inc. | Non-heated gellan gum gels |
JPS62130671A (en) * | 1985-12-03 | 1987-06-12 | San Ei Chem Ind Ltd | Instant food solid drink |
JPS63169948A (en) * | 1987-01-06 | 1988-07-13 | San Ei Chem Ind Ltd | Preparation of gelan gum soluble in cold water |
JPS6427445A (en) * | 1987-07-22 | 1989-01-30 | Sanei Kagaku Kogyo Kk | Preparation of gelatinous seasoning |
JPH0218487A (en) * | 1988-07-05 | 1990-01-22 | San Ei Chem Ind Ltd | Production of instantly thickened and gelatinized material |
JPH02145159A (en) * | 1988-11-25 | 1990-06-04 | San Ei Chem Ind Ltd | Production of thermally reversible gelan gum gel |
WO1996000018A1 (en) * | 1994-06-24 | 1996-01-04 | Monsanto Company | Gellan gum beverage |
Non-Patent Citations (5)
Title |
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DATABASE WPI Section Ch Week 8729, Derwent World Patents Index; Class D13, AN 87-202515, XP002010334 * |
DATABASE WPI Section Ch Week 8834, Derwent World Patents Index; Class D13, AN 88-237971, XP002010336 * |
DATABASE WPI Section Ch Week 9009, Derwent World Patents Index; Class D13, AN 90-064232, XP002010335 * |
PATENT ABSTRACTS OF JAPAN vol. 013, no. 208 (C - 596) 16 May 1989 (1989-05-16) * |
PATENT ABSTRACTS OF JAPAN vol. 014, no. 390 (C - 0751) 23 August 1990 (1990-08-23) * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9101160B2 (en) | 2005-11-23 | 2015-08-11 | The Coca-Cola Company | Condiments with high-potency sweetener |
US8017168B2 (en) | 2006-11-02 | 2011-09-13 | The Coca-Cola Company | High-potency sweetener composition with rubisco protein, rubiscolin, rubiscolin derivatives, ace inhibitory peptides, and combinations thereof, and compositions sweetened therewith |
WO2011131976A1 (en) * | 2010-04-21 | 2011-10-27 | The University Of Birmingham | Comestible product |
EP2653494A1 (en) | 2012-04-20 | 2013-10-23 | RUDOLF WILD GmbH & CO. KG | Aqueous gellan dispersion |
WO2022031158A1 (en) * | 2020-08-04 | 2022-02-10 | Barragan Espinoza Gerogina | Flavouring composition for beverages, foods, and desserts |
Also Published As
Publication number | Publication date |
---|---|
AU5955496A (en) | 1996-12-24 |
AR002318A1 (en) | 1998-03-11 |
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