US8736066B2 - Stacked microelectronic assemby with TSVS formed in stages and carrier above chip - Google Patents
Stacked microelectronic assemby with TSVS formed in stages and carrier above chip Download PDFInfo
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- US8736066B2 US8736066B2 US13/051,424 US201113051424A US8736066B2 US 8736066 B2 US8736066 B2 US 8736066B2 US 201113051424 A US201113051424 A US 201113051424A US 8736066 B2 US8736066 B2 US 8736066B2
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- conductive
- microelectronic
- opening
- openings
- microelectronic assembly
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- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/151—Die mounting substrate
- H01L2924/153—Connection portion
- H01L2924/1531—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface
- H01L2924/15311—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface being a ball array, e.g. BGA
Definitions
- the present invention relates to packaging of microelectronic devices, especially the packaging of semiconductor devices.
- Microelectronic devices generally comprise a thin slab of a semiconductor material, such as silicon or gallium arsenide, commonly called a die or a semiconductor chip.
- Semiconductor chips are commonly provided as individual, prepackaged units. In some unit designs, the semiconductor chip is mounted to a substrate or chip carrier, which is in turn mounted on a circuit panel, such as a printed circuit board.
- the active circuitry is fabricated in a first face of the semiconductor chip (e.g., a front surface).
- the chip is provided with bond pads on the same face.
- the bond pads are typically placed in a regular array either around the edges of the die or, for many memory devices, in the die center.
- the bond pads are generally made of a conductive metal, such as copper, or aluminum, around 0.5 micron ( ⁇ m) thick.
- the bond pads could include a single layer or multiple layers of metal.
- the size of the bond pads will vary with the device type but will typically measure tens to hundreds of microns on a side.
- TSVs Through-silicon vias
- Conventional TSV holes may reduce the portion of the first face that can be used to contain the active circuitry. Such a reduction in the available space on the first face that can be used for active circuitry may increase the amount of silicon required to produce each semiconductor chip, thereby potentially increasing the cost of each chip.
- Size is a significant consideration in any physical arrangement of chips.
- devices commonly referred to as “smart phones” integrate the functions of a cellular telephone with powerful data processors, memory and ancillary devices such as global positioning system receivers, electronic cameras, and local area network connections along with high-resolution displays and associated image processing chips.
- Such devices can provide capabilities such as full internet connectivity, entertainment including full-resolution video, navigation, electronic banking and more, all in a pocket-size device.
- Complex portable devices require packing numerous chips into a small space.
- I/O's input and output connections
- the interconnections should be short and should have low impedance to minimize signal propagation delays.
- the components which form the interconnections should not greatly increase the size of the assembly. Similar needs arise in other applications as, for example, in data servers such as those used in internet search engines. For example, structures which provide numerous short, low-impedance interconnects between complex chips can increase the bandwidth of the search engine and reduce its power consumption.
- FIG. 1 is a sectional view illustrating a microelectronic package according to an embodiment of the invention, as attached to a circuit panel.
- FIG. 1A is a fragmentary sectional view further illustrating the microelectronic package shown in FIG. 1 .
- FIG. 2 is a fragmentary sectional view particularly illustrating a microelectronic assembly in accordance with the microelectronic package of FIG. 1 .
- FIG. 3 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiment shown in FIG. 1 .
- FIG. 3A is a sectional view illustrating a microelectronic package according to a variation of the embodiment shown in FIG. 1 .
- FIG. 4 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiment shown in FIG. 3 .
- FIG. 5 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiment shown in FIG. 3 .
- FIGS. 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 , and 16 are fragmentary sectional views illustrating stages in a method of fabricating a microelectronic assembly according to an embodiment of the invention.
- FIG. 17 is a fragmentary sectional view illustrating a microelectronic assembly in accordance with a variation of the embodiment of the invention shown in FIG. 3 .
- FIG. 18 is a fragmentary sectional view illustrating a microelectronic assembly in accordance with a variation of the embodiment of the invention shown in FIG. 17 .
- FIG. 19 is a fragmentary sectional view illustrating a microelectronic assembly in accordance with a variation of the embodiment of the invention shown in FIG. 17 .
- FIG. 20 is a fragmentary sectional view illustrating a microelectronic assembly in accordance with a variation of the embodiment of the invention shown in FIG. 19 .
- FIG. 21 is a fragmentary sectional view illustrating a microelectronic assembly in accordance with a variation of the embodiment of the invention shown in FIG. 3 .
- FIGS. 22 , 23 , 24 , 25 , 26 , 27 , 28 , 29 , 30 , 31 and 32 are fragmentary sectional views illustrating stages in a method of fabricating a microelectronic assembly shown in FIG. 21 , according to an embodiment of the invention.
- FIGS. 33 , 34 , and 35 are fragmentary sectional views illustrating stages in a method of fabricating a microelectronic assembly according to a variation of the embodiment shown in FIG. 21 .
- FIGS. 36 and 37 are fragmentary sectional views illustrating stages in a method of fabricating a microelectronic assembly according to a variation of the embodiment shown in FIG. 21 .
- FIG. 38 is a sectional view illustrating a microelectronic package positioned above a circuit panel to be joined therewith, in a variation of the embodiment shown in FIG. 3A .
- FIG. 39 is a sectional view illustrating a microelectronic assembly according to a variation of the embodiment shown in FIG. 21 .
- FIG. 40 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiment shown in FIG. 39 .
- FIG. 41 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiment shown in FIG. 21 .
- FIG. 42 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiment shown in FIG. 41 .
- FIG. 43 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiment shown in FIG. 42 .
- FIG. 44 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiment shown in FIG. 43 .
- FIG. 45 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiment shown in FIG. 2 .
- FIG. 46 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiments shown in FIG. 45 and FIG. 3 .
- FIG. 47 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiments shown in FIG. 46 .
- FIG. 48 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiments shown in FIG. 47 .
- FIG. 49 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiments shown in FIG. 48 .
- FIG. 50 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiments shown in FIG. 49 .
- FIG. 51 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiments shown in FIG. 18 .
- FIGS. 52 and 53 are fragmentary sectional views illustrating a microelectronic assembly according to a variation of the embodiments shown in FIG. 46 .
- FIGS. 54 , 55 , 56 , 57 , 58 , 59 , 60 , 61 , and 62 are fragmentary sectional views illustrating stages in a method of fabricating a microelectronic assembly shown in FIG. 45 , according to an embodiment of the invention.
- FIG. 63 is a fragmentary sectional view illustrating a microelectronic assembly according to a variation of the embodiments shown in FIG. 62 .
- FIG. 64 FIG. 23 is a schematic depiction of a system according to one embodiment of the invention.
- FIG. 1 illustrates a microelectronic package 100 in accordance with an embodiment of the invention.
- the microelectronic package includes a microelectronic element 102 , e.g., an integrated circuit embodied in a semiconductor chip, which can include silicon, an alloy of silicon, or other semiconductor material such as a III-V semiconductor material or II-VI semiconductor material.
- the chip 102 has a front face 104 , also referred to as a contact-bearing face, being a major surface of the chip, with a dielectric layer 105 of the chip exposed at the front face.
- the dielectric layer 105 overlies a semiconductor region 107 of the chip in which active semiconductor devices, e.g., transistors, diodes, or other active devices are provided. As further seen in FIG. 1 , a plurality of conductive pads 106 are exposed at the front face 104 .
- the dielectric layer 105 can include one or more layers of dielectric material having a low dielectric constant, i.e., a “low-k” dielectric layer, between and around the metal wiring patterns which provide electrical interconnection for the microelectronic element.
- Low-k dielectric materials include porous silicon dioxide, carbon-doped silicon dioxide, polymeric dielectrics, and porous polymeric dielectrics, among others.
- the dielectric layer can have substantial porosity, which reduces the dielectric constant of the dielectric material relative to a nonporous layer of the same material.
- Dielectric materials typically have a dielectric constant significantly above 1.0, but air which occupies open spaces within a porous dielectric material has a dielectric constant of about 1.0. In this way, some dielectric materials can achieve reductions in the dielectric constant by having substantial porosity.
- some low-k dielectric materials such as polymeric dielectric materials and porous dielectric materials, withstand much less mechanical stress than traditional dielectric materials.
- Particular types of operating environments and ways that the microelectronic element may be tested can present stress at or near a limit that the low-k dielectric material can tolerate.
- the microelectronic assemblies described herein provide improved protection for the low-k dielectric layer of a microelectronic element by moving the locations where stress is applied to the microelectronic element away from the low-k dielectric layer 105 . In this way, manufacturing, operation and testing can apply much reduced stresses to the low-k dielectric layer, thus protecting the low-k dielectric layer. As further seen in FIG.
- a surface 103 of a first element 110 is bonded to the front face 104 with a dielectric material 108 such as an adhesive.
- a dielectric material 108 such as an adhesive.
- Other possible bonding materials can include glass, which in a particular embodiment, can be doped and can have a glass transition temperature below 500° C.
- the first element can consist essentially of semiconductor material or an inorganic dielectric material or other material having a coefficient of thermal expansion (“CTE”) of less than 10 parts per million (“ppm”) per degree Celsius: i.e. less than 10 ppm/° C.
- the first element 110 consists essentially of the same semiconductor material as the chip or consists essentially of dielectric material which has a CTE at or close to the CTE of the chip.
- the first element can be said to be “CTE-matched” with the chip.
- the first element 110 can have a plurality of “staged vias” for providing electrically conductive connections with the conductive pads 106 of the chip.
- the first element can have a plurality of first openings 111 which extend from an exposed outwardly-facing surface 118 towards the chip front surface 104 .
- a plurality of second openings 113 can extend from respective first openings 111 to respective conductive pads 106 of the chip.
- interior surfaces 121 , 123 of the first and second openings extend at different angles 140 , 142 relative to a plane defined by the major surface 104 , which is the same as the angles 140 , 142 relative to any plane 125 parallel to the major surface.
- a plurality of conductive elements 114 extend within the first and second openings and are electrically coupled to the conductive pads 106 .
- the conductive elements 114 are exposed at an exposed outwardly-facing surface 118 of the first element.
- the conductive elements 114 can include metal features which are formed by depositing a metal in contact with exposed surfaces of the conductive pads 106 .
- Various metal deposition steps can be used to form the conductive elements, as described in further detail below.
- the first element can include one or more passive circuit elements, e.g., capacitors, resistors or inductors, or a combination thereof, which while not specifically shown in FIG. 1 , can further contribute to the function of the chip and package 100 .
- the first element can function as a carrier which mechanically supports the chip.
- the thickness 112 of the chip typically is less than or equal to the thickness 116 of the first element.
- the chip can be relatively thin in comparison to the first element.
- the thickness 112 of the chip may be only a few microns, because stresses applied to the conductive elements 114 are spread over the dimensions and thickness 116 of the first element, rather than being applied directly to the conductive pads 106 .
- the thickness 120 of the semiconductor region 107 of the chip may be less than one micron to a few microns.
- the conductive elements 114 can be conductively bonded, similar to flip-chip manner, to contacts 124 of a dielectric element 126 , such as through masses 128 of a bond metal, e.g., solder, tin, indium, or a combination thereof.
- the dielectric element can have a plurality of terminals 130 for further electrically connecting the package 100 to corresponding contacts 136 of a circuit panel 134 , such as through conductive masses 132 , e.g., solder balls, projecting away from the dielectric element 126 .
- FIG. 2 is a partial sectional view further illustrating a structure of the microelectronic assembly 122 .
- a dielectric layer 138 can be provided as a coating which may conform to contours of the interior surfaces 121 , 123 of the first and second openings 111 , 113 .
- such conformal dielectric layer 138 can be formed selectively by electrophoretic deposition on interior surfaces of the openings 111 , 113 , and on an exposed surface 148 of the first element, as will be described in further detail below.
- a conductive layer 114 A can thereafter be formed within the openings, e.g., such as by depositing a metal or a conductive compound of a metal in contact with the conductive pad 106 and the dielectric layer 138 . Thereafter, the volume remaining within the openings 111 , 113 after forming the conductive layer can be filled with a dielectric material 150 .
- a conductive contact 114 B then can be formed atop the dielectric material 150 by subsequently depositing a conductive material, e.g., a metal over the dielectric material 150 .
- FIG. 3 illustrates a variation of the embodiment shown in FIG. 2 .
- a second conductive element 154 is electrically coupled to the conductive pad 106 and is exposed at a major surface 152 of the chip, specifically a rear surface of the chip that is remote from the front surface 104 .
- An opening 153 can extend from the rear surface 152 of the chip and expose at least a portion of the conductive pad 106 .
- a dielectric layer 158 can line the opening 153 in the chip and electrically insulate the second conductive element 154 from the semiconductor region 107 of the chip.
- the dielectric layer 158 can conform to a contour of an interior surface 159 of the semiconductor region exposed within the opening 153 .
- the second conductive element can include a conductive layer 154 A extending along the dielectric layer 158 , which can also conform to a contour of the interior surface 159 of the semiconductor region within the opening 153 .
- dielectric material 160 can be deposited over the conductive layer 154 A and an exterior conductive contact 154 B can be provided which overlies the dielectric material.
- the second conductive contact 154 B may overlie at least a portion of the conductive pad 106 to which it is directly or indirectly electrically coupled.
- FIG. 3 Similar to the first conductive contact 114 described above ( FIG. 2 ), dielectric material 160 can be deposited over the conductive layer 154 A and an exterior conductive contact 154 B can be provided which overlies the dielectric material.
- the second conductive contact 154 B may overlie at least a portion of the conductive pad 106 to which it is directly or indirectly electrically coupled.
- interior surfaces 123 , 159 of the openings in the packaging layer and the wafer have contours to which dielectric layers 138 , 158 conform, and conductive layers 114 A, 154 A conform.
- the interior surfaces 123 , 159 can extend at substantially different angles 162 , 163 away from the front or major surface of the wafer, respectively.
- the widths 190 , 192 of the openings 113 , 153 where the conductive layers 114 A, 154 A meet the conductive pad can be smaller than the widths 191 , 193 of the openings 113 , 153 , respectively, at substantial distances in respective directions 181 , 183 from the conductive pad 106 .
- the openings 113 , 153 may have their smallest widths 190 , 192 where the openings meet the respective surfaces of the conductive pad 106 .
- the second conductive elements 154 B are exposed at a surface of the wafer 200 and can be available for forming electrically conductive interconnections between the microelectronic assembly ( FIG. 3 ) and a component external to the microelectronic assembly.
- some conductive pads 106 A of a chip 102 of the microelectronic assembly can have conductive elements 154 exposed at the rear surface of the chip and be electrically interconnected by a bond metal 155 , e.g., solder, with conductive features 194 such as conductive pads, on a second dielectric element 196 .
- the dielectric element 196 may further include other features such as conductive traces 198 which can be electrically connected with the pads.
- others 106 B of the conductive pads may not have conductive elements 154 connected thereto and exposed at a rear surface of the chip 102 .
- FIG. 4 illustrates a further variation in which the second conductive element 164 is provided as a solid conductive structure.
- the second conductive element 164 at least substantially fills a volume within the opening in the chip that remains after forming the conformal dielectric coating 158 .
- a conductive contact or pad portion 164 B of the second conductive element can extend beyond the opening 153 along the rear surface 152 of the chip.
- FIG. 5 illustrates yet another variation in which the second conductive element includes a conductive layer 166 extending along the dielectric layer 158 .
- the dielectric layer 158 and the conductive layer 166 may conform to a contour of the interior surface 159 of the opening.
- a conductive mass 168 which can be a bond metal, e.g., solder, tin, indium, or a combination thereof, may be joined to the conductive layer.
- the conductive mass 168 may at least substantially fill the opening and, as shown in FIG. 5 , may project beyond the rear surface 152 of the chip.
- a semiconductor wafer 200 or portion of a wafer can include a plurality of semiconductor chips 102 which are attached together at dicing lanes 201 .
- Each chip typically has a plurality of conductive pads 106 exposed at a front face 104 of the chip.
- a packaging layer 110 such as an unpatterned semiconductor wafer or glass wafer or other element having a CTE of less than 10 ppm/° C.
- the packaging layer 110 typically has a CTE which is close to or equal that of the semiconductor wafer 200 .
- the packaging layer 110 can consist essentially of silicon to be CTE-matched with the wafer 200 .
- a packaging layer 110 of doped glass can be CTE-matched with the semiconductor wafer 200 .
- the dielectric bonding material can also be CTE-matched with the wafer 200 .
- a thickness of the packaging layer 110 can be reduced from an original thickness to a reduced thickness 116 , as shown in FIG. 8 .
- the packaging layer 110 can be reduced in thickness by a process of grinding, lapping or polishing, or combination thereof.
- the reduced thickness 116 that is reached during this process can be a final thickness of the packaging layer 110 .
- a series of fragmentary sectional views are used to illustrate stages in a method of fabricating a microelectronic assembly according to an embodiment of the invention.
- the steps shown therein may typically be performed at wafer-level, i.e., prior to severing a semiconductor wafer ( FIG. 6 ) into individual chips 102 , although in each figure, only a portion of an individual chip may appear.
- the following description of a method of fabricating the microelectronic assembly should be understood to cover either chip-level or wafer-level fabrication techniques, whether or not the same is specifically described, and whether or not the following description makes reference to processes performed with respect to a wafer, or to a chip.
- FIG. 9 illustrates a stage of fabrication subsequent to the stage illustrated in FIG. 8 .
- an opening 170 is formed which extends from an exterior surface 148 of the packaging layer 110 to a surface 108 A of the dielectric bonding layer 108 overlying a conductive pad 106 .
- the opening 170 can be formed in a staged manner as a first opening 111 extending from the exposed surface 148 of the packaging layer 110 towards the chip front surface 104 , and a second opening 113 extending from the first opening further towards the chip front surface 104 .
- the first and second openings 111 , 113 can be formed by forming the first opening such as through etching, laser ablation, or by “sand-blasting”, i.e., by directing a stream of micro-abrasive particles toward the packaging layer. Thereafter, the process can further include forming a dielectric layer (not shown) lining an interior surface of the first opening 111 , forming a hole in such dielectric layer, and then forming the second opening 113 by etching the packaging layer through the hole until a surface of the bonding layer 108 is exposed.
- a dielectric layer not shown
- the dielectric layer in the first opening can function as a mask such that the packaging layer is etched where exposed within the hole in the dielectric layer and the dielectric layer protects portions of the packaging layer away from the hole from being etched. Thereafter, as illustrated in FIG. 10 , a portion of the bonding layer 108 exposed within the second opening 113 and overlying the conductive pad 106 is removed so as to expose at least a portion of an upper surface 172 of the pad which faces outwardly away from the chip 102 .
- first and second openings can be as generally described in any or all of United States Patent Publication No. 20080246136A1, or United States applications, each filed Jul. 23, 2010: application Ser. Nos. 12/842,717, 12/842,612, 12/842,669; 12/842,692; 12/842,587, the disclosures of which are incorporated herein by reference, with the exception that the first and second openings extend through a packaging layer and a bonding layer rather than through the chip, and the second opening exposes a portion of an outwardly-facing upper surface of a conductive pad rather than the lower pad surface.
- a dielectric layer 138 can be formed which extends along interior surfaces 121 and 123 of the first and second openings, respectively, and overlying an outwardly-facing surface 148 of the packaging layer 110 .
- an electrophoretic deposition technique can be used to form a dielectric coating 138 conformally with respect to the interior surfaces 121 , 123 of the openings and the packaging layer surface 148 .
- the conformal dielectric coating may be deposited only onto exposed conductive and semiconductive surfaces of the assembly.
- the semiconductor device wafer is held at a desired electric potential and an electrode is immersed into the bath to hold the bath at a different desired potential.
- Electrophoretic deposition occurs so long as a sufficiently strong electric field is maintained between the surface to be coated thereby and the bath.
- the electrophoretically deposited coating is self-limiting in that after it reaches a certain thickness governed by parameters, e.g., voltage, concentration, etc. of its deposition, deposition stops.
- Electrophoretic deposition forms a continuous and uniformly thick conformal coating on conductive and/or semiconductive exterior surfaces of the assembly.
- the electrophoretic coating can be deposited so that it does not form on the surface 108 A of the dielectric bonding layer 108 overlying the upper surface 172 of the conductive pad 106 , due to its dielectric (nonconductive) property.
- a property of electrophoretic deposition is that is does not form on a layer of dielectric material overlying a conductor provided that the layer of dielectric material has sufficient thickness, given its dielectric properties.
- electrophoretic deposition will not occur on dielectric layers having thicknesses greater than about 10 microns to a few tens of microns.
- the conformal dielectric layer 138 can be formed from a cathodic epoxy deposition precursor. Alternatively, a polyurethane or acrylic deposition precursor could be used.
- a variety of electrophoretic coating precursor compositions and sources of supply are listed in Table 1 below.
- the dielectric layer can be formed electrolytically. This process is similar to electrophoretic deposition, except that the thickness of the deposited layer is not limited by proximity to the conductive or semiconductive surface from which it is formed. In this way, an electrolytically deposited dielectric layer can be formed to a thickness that is selected based on requirements, and processing time is a factor in the thickness achieved.
- the dielectric layer 138 formed in this manner can conform to contours of the interior surfaces 121 , 123 of the first and second openings.
- a conductive layer 114 A ( FIG. 11 ) can be formed within the openings 111 , 113 , which, when formed over a conformal dielectric layer 138 , also can conform to contours of the interior surfaces 121 , 123 of the first and second openings.
- the deposition of an additional dielectric layer 150 and the forming of a metal layer 114 B overlying the dielectric layer 150 completes a conductive element 114 exposed at an outwardly-facing surface of the packaging layer.
- the conductive element extends within the first and second openings 111 , 113 and is electrically coupled to the conductive pad 106 .
- a plurality of such conductive elements 114 can be simultaneously formed within respective openings in the packaging layer, the conductive elements electrically coupled to respective conductive pads 106 of the wafer 200 .
- a temporary carrier 180 or handle wafer can be attached to the exposed surface of the packaging layer 110 overlying exposed contacts 114 B of the conductive elements 114 .
- the carrier 180 can be attached, for example, using an adhesive 182 which can be removed after subsequent processing as described below.
- a thickness of the wafer 200 can be reduced to a value which may be a final thickness 112 of the wafer. Grinding, lapping or polishing may be used to reduce the wafer thickness. In a particular embodiment, the reduced thickness may range from 0.5 microns to only a few microns. In one possible implementation, the final thickness 112 of the wafer 200 can be controlled by the presence of a dielectric layer 184 ( FIG. 12 ) buried within the wafer 200 which separates an upper portion 186 of the wafer adjacent the front surface, and having thickness 112 , from a lower portion 188 opposite therefrom.
- a dielectric layer 184 FIG. 12
- the buried dielectric layer 184 can be a buried oxide layer provided in a semiconductor-on-insulator or silicon-on-insulator wafer structure of wafer 200 before fabricating active semiconductor devices in the wafer 200 .
- the lower wafer portion 188 can be monocrystalline or polycrystalline semiconductor material. Then, after reaching the fabrication stage shown in FIG. 13 , the carrier 180 and adhesive 182 can be removed from the structure, resulting in the microelectronic assembly 122 shown in FIG. 2 .
- steps can be performed to fabricate a microelectronic assembly which further includes a second conductive element 154 as seen in FIG. 3 .
- an opening 153 can be formed which extends through the thickness of the semiconductor region of the wafer 200 .
- the opening can be formed in a manner selective to dielectric layer 105 of the wafer.
- the dielectric layer 105 can include a plurality of interlevel dielectric (“ILD”) layers in which metal wiring is provided, one or more passivation layers overlying the ILD layers, or both.
- ILD interlevel dielectric
- the opening 153 is extended through the dielectric layer 105 to expose at least a portion of a lower surface 174 of the conductive pad 106 .
- the lower surface 174 is opposite an upper surface 172 of the pad from which the first conductive element 114 extends, as illustrated in FIG. 15 .
- a conformal dielectric layer 158 and then a conformal conductive layer, typically of metal or a conductive metal compound, can be formed which extends at least partly within the opening so as to form a second conductive element 154 including a conductive layer which is electrically coupled to the conductive pad 106 and which typically is electrically insulated from the wafer 200 by the dielectric layer 158 .
- Further processing can include the forming of a dielectric layer 160 overlying the conductive layer 154 A, and a conductive contact 154 B, typically of a metal or conductive metal compound can then be formed which overlies the dielectric layer 160 .
- the carrier and bonding layer 182 can be detached, resulting in a microelectronic assembly as seen in FIG. 3 .
- a conductive layer 164 ( FIG. 4 ) can be formed so as to provide a conductive contact 164 exposed at the rear face 152 of the wafer and extending to the conductive pad 160 without the additional dielectric layer 160 separating the contact 164 from the conductive pad.
- FIG. 17 illustrates a variation of the embodiment seen in FIG. 16 , in which the second opening 213 within the packaging layer 110 exposes first and second conductive pads 206 .
- a plurality of conductive elements 214 can be formed which extend from respective conductive pads 206 to surfaces overlying an outwardly-facing exposed surface 218 of the packaging layer 110 .
- the conductive elements 214 may be electrically insulated from one another by the dielectric layer 138 extending along interior surfaces of the first and second openings 211 , 213 , and the additional dielectric layer 250 which may substantially or fully fill the remaining volume within the openings 211 , 213 .
- portions of the conductive elements 214 can extend as pads or traces over the additional dielectric layer 250 within opening 211 .
- the conductive elements may have portions which are only exposed at locations beyond the opening 211 in the packaging layer.
- optional second conductive elements 254 can extend from the conductive pads 206 and be exposed at a rear surface of the wafer or chip 102 to permit electrical interconnections to be formed to an external component.
- FIG. 18 illustrates a variation of the embodiment ( FIG. 17 ) in which the dielectric fill material is omitted when forming the second conductive elements, such that the conductive material is continuous between the conductive pads 206 and surfaces 254 A of the conductive material which are exposed for interconnection with an external component.
- the second conductive elements 254 A can have a structure as described above with reference to FIG. 5 in which a bond metal 168 is joined to a conductive layer 166 within the opening and is exposed at a surface 152 of the microelectronic assembly.
- FIG. 19 illustrates a further variation in which a plurality of second openings 313 A, 313 B extend from a particular first opening 311 in the packaging layer 110 .
- the second openings can be formed by laser drilling or other substantially vertical patterning method, e.g., a reactive ion etch (“RIE”), for example, after which dielectric layers 328 are formed to line interior surfaces of the second openings.
- RIE reactive ion etch
- the conductive elements 314 A, 314 B may substantially or fully fill the volume remaining within the second openings 313 A, 313 B after forming the dielectric layers 328 .
- the conductive elements 314 A, 314 B may contact edges of the conductive pads 306 exposed at the surface of the wafer 200 .
- the second conductive elements 354 which are exposed at a rear surface of the wafer can overlie a dielectric layer 360 within the opening, or the second conductive elements 356 can have a structure as seen in FIG. 20 which need not include a dielectric layer between the conductive pads and exposed surfaces of the conductive elements.
- FIG. 21 illustrates a microelectronic assembly according to another embodiment of the invention in which a conductive element 414 having a contact pad 416 exposed at an exterior surface 418 of packaging layer 410 has a reentrant profile.
- the conductive element 414 can have a shape which varies between a relatively large width 420 adjacent a conductive pad 406 of wafer 401 and a smaller width 421 adjacent an exposed surface 418 of the packaging layer.
- the packaging layer can consist essentially of a semiconductor material, with a dielectric layer 416 disposed between an interior surface of an opening 411 therein and the conductive element 414 . As further seen in FIG.
- a second conductive element 454 exposed at an exterior surface of wafer 401 can extend through the conductive pad 406 in a direction of a thickness 408 of the pad 406 .
- the second conductive element 454 can have a connecting portion 412 which electrically contacts the first conductive element 414 at a height of the assembly that is between adjacent surfaces of the wafer 401 and packaging layer 410 .
- FIG. 21 A process capable of forming the microelectronic assembly ( FIG. 21 ) will now be described.
- an opening 411 is formed which extends from a major surface of a packaging layer 410 such as a semiconductor wafer towards a second major surface 423 of the packaging layer opposite therefrom.
- a dielectric layer can be formed which lines an interior surface of the opening and overlies major surface 403 .
- a metal layer or conductive compound of a metal or both can be deposited therein to fill the opening and form a first conductive element 430 .
- a plurality of such conductive elements 430 can be formed simultaneously which extend from surface 403 of the wafer toward surface 423 .
- the packaging layer 410 can be bonded to a device wafer 400 which has active semiconductor devices therein and a plurality of conductive pads 406 exposed at a front face 404 thereof.
- the conductive elements 430 of the packaging layer 410 can be mated with corresponding conductive pads 406 of the device wafer such that the conductive elements 430 at least partially overlie the respective conductive pads 406 .
- a thickness of the device wafer 400 can be reduced to a thickness 416 , such as described above relative to FIG. 2 to provide a thinned wafer 401 .
- an opening 453 can be formed which extends through a semiconductor region of the wafer 401 .
- an etching process can be used which is performed selectively with respect to a dielectric layer (not shown), e.g., a series of ILD layers and a passivation layer which may underlie a lower surface 406 A of the conductive pad.
- a further opening can be formed which extends through the dielectric layer (not shown), the conductive pad 406 and a bonding layer 405 between the thinned wafer 401 and the packaging layer 410 .
- a dielectric layer 452 is formed within the opening, such as by an electrolytic technique as described in the foregoing.
- the second conductive element 454 can then be formed in contact with the first conductive element 430 .
- a portion of the second conductive element 454 may overlie the rear surface 452 of the thinned wafer 401 , with the dielectric layer 452 disposed between the semiconductor region and the second conductive element 454 .
- a temporary support wafer or carrier 440 can be bonded to the rear surface 453 of the wafer 401 using a temporary adhesive 418 .
- a thickness of the packaging layer 410 can be reduced, e.g., by grinding, lapping or polishing, until at least some of the first conductive elements 430 are at least partially exposed at an exposed surface 411 of the packaging layer 410 .
- an additional dielectric layer 434 and a conductive pad 432 FIG. 32
- the temporary carrier 440 can be detached from the device wafer 401 to provide a completed microelectronic assembly as seen, for example, in FIG. 21 .
- a wet etch step or other etch step can be performed in conjunction with the processing shown in FIG. 28 .
- the wet etch step can be performed in a manner which does not attack materials which are exposed at exposed surfaces of the first conductive elements 430 and the conductive pads 406 .
- the wet etch step can produce undercut regions 442 between the first conductive elements 430 and conductive pads 406 adjacent thereto.
- the dielectric layer 452 can then be formed and a region 464 of metal or a conductive compound of a metal can be deposited onto the first conductive element 430 , deposited within the undercut regions and onto surfaces of the conductive pads 406 and the dielectric layer 452 to produce a structure as seen in FIG. 34 .
- the metal regions 464 of the second conductive elements deposited within the undercut regions 442 the metal regions may have greater surface area in contact with the conductive pads 406 of the wafer 401 . In this way, it may be possible to achieve improved process tolerances or improved reliability in the final structural connection between the conductive pads 406 and the first and second conductive elements.
- further processing as described above FIGS. 31-32 ) can be performed to produce the microelectronic assembly as seen in FIG. 35 .
- the thickness 460 of the packaging layer can be reduced even further, such that the remaining height 462 of the packaging layer from the device wafer front surface 404 is below a maximum height 464 of the first conductive elements 430 from the device wafer front surface. Thereafter, portions of the dielectric layer 428 which are exposed above the reduced height 462 of the packaging layer can be removed from the structure to produce a structure as represented in FIG. 37 in which a plurality of conductive posts 470 have substantial portions projecting above an exposed surface 421 of the packaging layer.
- the posts 470 when the posts 470 are formed by electroplating or depositing a metal which has substantially rigidity at normal chip operating temperature ranges, e.g., such as copper, nickel, aluminum, etc., refractory metals, e.g., tungsten, titanium, and the like, the posts 470 can be substantially rigid.
- FIG. 38 further illustrates possible further interconnection arrangement of the microelectronic assembly resulting from such variation ( FIGS. 36-37 ).
- the substantially rigid conductive posts 470 of the microelectronic assembly 480 can be mounted via solder-masses 482 to corresponding contacts 484 on a dielectric element 426 to form a microelectronic package 490 .
- the contacts 484 can be electrically connected with joining units 486 , e.g., solder balls or other masses of a bond metal such as tin or indium or a combination thereof which are exposed at a lower surface 488 of the dielectric element 426 .
- the joining units 486 can be used to join the package 490 to corresponding contacts 492 exposed at a surface 493 of a circuit panel 494 .
- FIG. 39 illustrates a microelectronic assembly 590 according to a further variation, showing that not all of the conductive pads of a wafer 501 , particularly conductive pad 506 A, need to be connected with a first conductive element 530 .
- the first conductive element at a position corresponding to pad 506 A can be omitted when forming the first conductive elements of the packaging layer 510 .
- a blocking layer such as a resist pattern can be used to control the locations where conductive layers extend through the conductive pads 506 B, and other locations wherein the conductive pad 506 A should not be punctured.
- FIG. 40 illustrates yet another variation in which an electrically conductive redistribution layer (“RDL”) 640 can be formed overlying a surface of a dielectric layer disposed on the packaging layer 610 .
- the RDL can include electrically conductive traces 642 and pads 644 .
- traces 642 can electrically connect one or more of the first conductive elements 630 with one or more of the electrically conductive pads 644 , which in turn are connected to one or more of the second conductive elements 654 A.
- some of the second conductive elements 654 B may not be electrically connected with a first conductive element of the assembly 690 .
- FIG. 40 illustrates yet another variation in which an electrically conductive redistribution layer (“RDL”) 640 can be formed overlying a surface of a dielectric layer disposed on the packaging layer 610 .
- the RDL can include electrically conductive traces 642 and pads 644 .
- traces 642 can electrically connect one or more of the first conductive elements 630
- some of the second conductive elements can be electrically connected to a source of reference potential such as ground through an electrically conductive metal layer 656 in contact therewith.
- the metal layer 656 can be a joining layer of solder, tin, indium or a combination thereof.
- the metal layer 656 can be used to electrically connect and join one or more of the second conductive elements with a metal ground plane which can also function as a thermally conductive heat spreader for the microelectronic assembly 690 .
- a dielectric layer 658 can electrically insulate a second conductive element 654 A from the joining layer 656 of the assembly 690 .
- Microelectronic assemblies according to other variations of the above-described embodiment can be as further seen in FIGS. 41 and 42 in which two or more first conductive elements 714 A, 714 B extend along interior surfaces of an opening 711 in a packaging layer 710 , the first conductive elements including portions 716 A, 716 B extending through separate openings between the first opening 711 and an exposed surface 718 of a dielectric layer of the assembly 790 .
- the first conductive elements 714 A, 714 B may include respective electrically conductive pads 720 A, 720 B exposed at the surface 718 of the dielectric layer 718 , which as shown in FIGS. 41 and 42 may overlie the dielectric layer 718 .
- the second conductive elements 754 A, 754 B of the assembly shown in FIG. 41 vary from the second conductive elements 755 A, 755 B shown in FIG. 42 in the same way as the second conductive elements in the embodiments described above with respect to FIGS. 17 and 18 , specifically, that exposed contact surfaces of the pads 754 A, 754 B ( FIG. 41 ) overlie a dielectric layer above the respective pads 706 A, 706 B to which they are connected, whereas in the assembly of FIG. 42 , they do not.
- FIG. 43 illustrates a further variation in which a plurality of first conductive elements 814 A, 814 B extend along interior surfaces of a staged opening in the packaging layer 810 from connections to conductive pads 806 A, 806 B of the wafer and include exposed conductive pads 832 on the packaging layer.
- the staged opening includes a first opening 811 extending from a first major surface 812 of the packaging layer 810 adjacent the device wafer 801 , and a second opening 813 extending from the first opening 811 at least to a second major surface 816 of the packaging layer 810 remote from the first major surface.
- the first and second openings can have surfaces 821 , 823 which extend in different directions defining a vertex 826 where the surfaces 821 , 823 meet.
- a dielectric material 850 typically covers the first conductive elements 814 A, 814 B. Interconnection of the first conductive elements 814 A, 814 B to the conductive pads 806 A, 806 B can be as described above with reference to FIG. 41 .
- FIG. 44 illustrates a variation of the embodiment ( FIG. 43 ) similar to the above-described embodiment ( FIG. 42 ) in which the second conductive elements 855 A, 855 B have contact surfaces which are not separated from the conductive pads 806 A, 806 B by a dielectric material.
- FIG. 45 illustrates a microelectronic assembly 990 according to a variation of the embodiment described above with respect to FIG. 2 .
- the first electrically conductive elements 914 extending from conductive pads 906 of the device wafer 901 do not conform to contours of interior surfaces of the openings 911 , 913 , which together extend through the packaging layer 910 in a direction 922 of a thickness of the packaging layer.
- the first conductive elements can have portions which are cylindrical or frustoconical in shape extending in a direction of a thickness of the packaging layer to contact upper surfaces 907 of conductive pads 906 .
- a dielectric region 928 is provided within the openings 911 , 913 which typically contacts upper surfaces 907 of the conductive pads 906 , wherein the first conductive elements extend through the dielectric region.
- a portion 928 A of the dielectric region can overlie an outwardly-facing surface 926 of the packaging layer.
- Electrically conductive pads 916 exposed at a surface of the dielectric region 928 may be provided as portions of the conductive element 914 , and can be disposed atop the dielectric region 928 . Alternatively, the electrically conductive pads 916 can be omitted.
- the microelectronic assembly 990 can be fabricated by processing similar to that described above with reference to FIGS. 6 through 13 , except that the dielectric regions 928 are formed by depositing a dielectric material to fill the openings 911 , 913 .
- Such dielectric regions 928 typically consist essentially of a polymeric material, which may be compliant, as determined by a combination of the material's modulus of elasticity and the thickness of the dielectric region.
- apertures can be formed extending through the dielectric regions 928 to expose at least portions of the conductive pads 906 .
- the apertures can have at least one of cylindrical or frustoconical shape, among others.
- An electrically conductive layer or filling e.g., a metal or conductive compound of a metal, can then be provided in the apertures to form vertically extending portions of the first conductive elements 914 . Thereafter, exposed conductive pad portions 916 can then be formed above a surface of the dielectric layer 928 .
- FIG. 46 illustrates a variation of the embodiment shown in FIG. 45 in which second electrically conductive elements 954 , similar to the second conductive element 164 described above relative to FIG. 4 , are exposed at an exposed surface of the device wafer 901 and electrically contact the conductive pads 906 .
- FIG. 47 illustrates a variation of the embodiment shown in FIG. 46 in which second dielectric regions 938 overlie lower surfaces 909 of the conductive pads 906 which are opposite the upper surfaces 907 .
- vertically extending cylindrical or frustoconical portions 914 A of the first conductive elements may extend through the conductive pads 906 to electrically conductive pad portions 918 exposed at the outwardly-facing rear surface 950 of the device wafer 901 .
- the vertically extending portions 914 A may not conform to contours of interior surfaces of any of the openings 911 , 913 and 915 in the packaging layer and the device wafer, respectively. Fabrication of the microelectronic assembly ( FIG.
- dielectric regions 928 , 938 are formed in the openings 911 , 911 , 915 , after which cylindrical or frustoconical openings are formed extending through the conductive pads 906 and the dielectric regions 928 , 938 , such as by laser ablation, micro-abrasive particle stream (e.g., “sandblasting”), or other technique. Thereafter, in one embodiment, conductive pads 916 , 918 can be formed which can be exposed at opposite faces of the microelectronic assembly.
- FIG. 48 illustrates a microelectronic assembly 1090 according to a variation of the embodiment shown in FIG. 47 in which second conductive elements 1054 can extend through thicknesses of the conductive pads 1006 .
- the fabrication of the microelectronic assembly 1090 can include forming openings 1015 in the device wafer 1001 which includes patterning the conductive pads 1006 , e.g., by etching, laser ablation, micro-abrasive particle streaming, etc. in a direction from a lower surface 1050 of the device wafer 1001 . Such patterning can be limited by the presence of the bonding layer 1008 between the device wafer and packaging layer 1010 . After forming dielectric layers 1038 in the openings 1015 . The second conductive elements 1054 then can be formed extending within the openings 1015 .
- FIG. 49 illustrates a further variation in which the first and second electrically conductive elements 1114 , 1154 meet at locations within the thickness of the packaging layer 1110 .
- the second conductive elements 1154 extend through the electrically conductive pads 1106 of the device wafer 1101 .
- the second conductive elements 1254 may include portions 1254 B which conform to contours of interior surfaces of the openings 1215 in the device wafer 1201 .
- portions 1254 A which extend within the thickness of the packaging layer 1210 may not conform to contours of interior surfaces of the openings 1213 into which portions 1254 A extend.
- FIG. 51 illustrates a microelectronic assembly according to a variation of the embodiment described above ( FIG. 43 ) in which first and second conductive pads 1306 A, 1306 B of a microelectronic element 1301 are at least substantially exposed within a relatively wide through opening 1313 in the first element 1310 .
- Separate conductive elements 1314 A, 1314 B to the pads extend along interior surfaces of the opening and can be exposed within openings 1316 A, 1316 B in a dielectric layer 1318 which overlies a major surface 1320 of the first element.
- FIG. 52 illustrates a stage in a method of conductive elements in yet another variation of the above-described embodiment ( FIG. 51 ).
- opening 1313 is formed extending through a thickness of the first element and then is filled with a dielectric material 1318 , such as by one of the techniques described above.
- conductive elements 1314 similar to those described above can be formed extending through the dielectric region 1318 to contact the conductive pads 1306 A, 1306 B.
- electrically conductive pads 1315 A, 1315 B can be provided atop the conductive elements 1314 A, 1314 B, these typically being exposed for interconnection with an external component.
- FIG. 54 et seq., a method will now be described for fabricating a microelectronic assembly according to a variation of the above-described embodiment ( FIGS. 22-34 ).
- a first element 1410 e.g., an element having a CTE of less than 10 ppm/° C.
- the first element may consist essentially of semiconductor or dielectric material.
- the first element 1410 then is filled with a dielectric material 1418 , which can form a layer overlying a major surface 1420 of the first element.
- the first element 1410 then is assembled, e.g., bonded with a microelectronic element 1402 having electrically conductive pads 1406 thereon, one of which is illustrated in FIG. 55 .
- a reduced thickness 1411 of the microelectronic element can be achieved by grinding, lapping or polishing, or combination thereof, as described above, as seen in FIG. 56 .
- the structure can be assembled with a carrier 1430 ( FIG. 57 ), and a thickness of the first element 1410 above the opening 1413 can be reduced until the opening is exposed at a surface 1417 of the first element ( FIG. 58 ).
- a dielectric layer 1419 may then be formed atop the surface 1417 , as seen in FIG. 59 . Thereafter, an opening 1432 can be formed which extends through the dielectric material both above the surface 1417 ( FIG. 60 ) and within the opening 1416 to expose a portion of the conductive pad 1406 . Typically, a portion of the upper surface 1409 (i.e., the surface facing away from microelectronic element 1402 ) is exposed within opening 1432 . However, in some cases, the opening 1432 can extend through the pad 1406 such that interior surfaces of an opening in the pad 1406 can be exposed.
- FIG. 61 illustrates a subsequent stage in which a metal has been deposited in one or more steps to form an electrically conductive element 1414 and an electrically conductive pad 1420 overlying the conductive element 1414 .
- the pad 1420 may or may not overlie a surface of the first element 1417 and dielectric layer 1419 .
- FIG. 61 illustrates an example in which the conductive element is non-hollow, i.e., filled throughout with a metal.
- the carrier can be removed from the microelectronic element 1402 , resulting in a structure as seen in FIG. 62 .
- FIG. 63 illustrates a further variation of the embodiment seen in FIG. 62 in which the conductive element 1424 can be a hollow structure, such as formed by depositing a metal to line an interior surface of the opening 1432 .
- the conductive element in either the FIG. 62 or FIG. 63 variation will typically be in form of an annular structure which conforms to a contour of the opening 1432 in the dielectric material, but which does not conform to the opening 1413 that was first made in the first element 1410 .
- a conductive pad 1430 can overlie the conductive element 1424 and can extend in one or more lateral directions 1440 away therefrom, lateral being a direction in which the surface 1417 of the first element extends.
- the structure and fabrication of the microelectronic assemblies and incorporation thereof into higher-level assemblies can include structure, and fabrication steps which are described in one or more of the following commonly owned co-pending United States applications each filed on Dec. 2, 2010: U.S. Provisional Application No. 61/419,037; and U.S. Nonprovisional application Ser. No. 12/958,866; and the following U.S. applications each filed Jul. 23, 2010: application Ser. Nos. 12/842,717; 12/842,651; 12/842,612; 12/842,669; 12/842,692; and 12/842,587; the disclosures of all such applications being incorporated by reference herein.
- the structures discussed above provide extraordinary three-dimensional interconnection capabilities.
- a processor and memory used with the processor can be included in structures as discussed above: (i) a processor and memory used with the processor; (ii) plural memory chips of the same type; (iii) plural memory chips of diverse types, such as DRAM and SRAM; (iv) an image sensor and an image processor used to process the image from the sensor; (v) an application-specific integrated circuit (“ASIC”) and memory.
- ASIC application-specific integrated circuit
- the structures discussed above can be utilized in construction of diverse electronic systems.
- a system 1500 in accordance with a further embodiment of the invention includes a structure 1506 as described above in conjunction with other electronic components 1508 and 1510 .
- component 1508 is a semiconductor chip whereas component 1510 is a display screen, but any other components can be used.
- the structure 1506 as described above may be, for example, a microelectronic assembly 100 as discussed above in connection with FIG. 1 , or any of FIGS. 2-63 . In a further variant, both may be provided, and any number of such structures may be used. Structure 1506 and components 1508 and 1510 are mounted in a common housing 1501 , schematically depicted in broken lines, and are electrically interconnected with one another as necessary to form the desired circuit.
- the system includes a circuit panel 1502 such as a flexible printed circuit board, and the circuit panel includes numerous conductors 1504 , of which only one is depicted in FIG. 64 , interconnecting the components with one another.
- the housing 1501 is depicted as a portable housing of the type usable, for example, in a cellular telephone or personal digital assistant, and screen 1510 is exposed at the surface of the housing.
- structure 1506 includes a light-sensitive element such as an imaging chip
- a lens 1511 or other optical device also may be provided for routing light to the structure.
- FIG. 64 is merely exemplary; other systems, including systems commonly regarded as fixed structures, such as desktop computers, routers and the like can be made using the structures discussed above.
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- Semiconductor Integrated Circuits (AREA)
Abstract
Description
TABLE 1 | |||
ECOAT NAME | POWERCRON 645 | POWERCRON 648 | CATHOGUARD 325 |
MANUFACTURERS |
MFG | PPG | PPG | BASF |
TYPE | CATHODIC | CATHODIC | CATHODIC |
POLYMER BASE | EPOXY | EPOXY | EPOXY |
LOCATION | Pittsburgh, PA | Pittsburgh, PA | Southfield, MI |
APPLICATION DATA |
Pb/Pf-free | Pb-free | Pb or Pf-free | Pb-free |
HAPs, g/L | 60-84 | COMPLIANT | |
VOC, g/L (MINUS WATER) | 60-84 | <95 | |
CURE | 20 min/175 C. | 20 min/175 C. |
FILM PROPERTIES |
COLOR | Black | Black | Black |
THICKNESS, μm | 10-35 | 10-38 | 13-36 |
PENCIL HARDNESS | 2H+ | 4H |
BATH CHARACTERISTICS |
SOLIDS, % wt. | 20 (18-22) | 20 (19-21) | 17.0-21.0 |
pH (25 C.) | 5.9 (5.8-6.2) | 5.8 (5.6-5.9) | 5.4-6.0 |
CONDUCTIVITY (25 C.) μS | 1000-1500 | 1200-1500 | 1000-1700 |
P/B RATIO | 0.12-0.14 | 0.12-0.16 | 0.15-0.20 |
OPERATION TEMP., C. | 30-34 | 34 | 29-35 |
TIME, sec | 120-180 | 60-180 | 120+ |
ANODE | SS316 | SS316 | SS316 |
VOLTS | 200-400 | >100 | |
ECOAT NAME | ELECTROLAC | LECTRASEAL DV494 | LECTROBASE 101 |
MANUFACTURERS |
MFG | MACDERMID | LVH COATINGS | LVH COATINGS |
TYPE | CATHODIC | ANODIC | CATHODIC |
POLYMER BASE | POLYURETHANE | URETHANE | URETHANE |
LOCATION | Waterbury, CT | Birmingham, UK | Birmingham, UK |
APPLICATION DATA |
Pb/Pf-free | Pb-free | Pb-free | |
HAPs, g/L | |||
VOC, g/L (MINUS WATER) | |||
CURE | 20 min/149 C. | 20 min/175 C. | 20 min/175 C. |
FILM PROPERTIES |
COLOR | Clear (+dyed) | Black | Black |
THICKNESS, μm | 10-35 | 10-35 | |
PENCIL HARDNESS | 4H |
BATH CHARACTERISTICS |
SOLIDS, % wt. | 7.0 (6.5-8.0) | 10-12 | 9-11 |
pH (25 C.) | 5.5-5.9 | 7-9 | 4.3 |
CONDUCTIVITY (25 C.) μS | 450-600 | 500-800 | 400-800 |
P/B RATIO | |||
OPERATION TEMP., C. | 27-32 | 23-28 | 23-28 |
TIME, sec | 60-120 | ||
ANODE | SS316 | 316SS | 316SS |
VOLTS | 40, max | 50-150 | |
Claims (24)
Priority Applications (8)
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US13/051,424 US8736066B2 (en) | 2010-12-02 | 2011-03-18 | Stacked microelectronic assemby with TSVS formed in stages and carrier above chip |
JP2013541978A JP2013544444A (en) | 2010-12-02 | 2011-03-22 | Multilayer microelectronic assembly having a carrier above the chip and stepped silicon through-electrodes |
PCT/US2011/029394 WO2012074570A2 (en) | 2010-12-02 | 2011-03-22 | Stacked microelectronic assembly with tsvs formed in stages and carrier above chip |
CN201180066039.8A CN103339717B (en) | 2010-12-02 | 2011-03-22 | There is the stacking micromodule of carrier on the through silicon path and chip that segmentation formed |
EP11711722.6A EP2647040B1 (en) | 2010-12-02 | 2011-03-22 | Stacked microelectronic assembly with tsvs |
TW100144456A TWI479613B (en) | 2010-12-02 | 2011-12-02 | Stacked microelectronic assembly with tsvs formed in stages and carrier above chip |
US14/224,379 US9269692B2 (en) | 2010-12-02 | 2014-03-25 | Stacked microelectronic assembly with TSVS formed in stages and carrier above chip |
US15/047,295 US9620437B2 (en) | 2010-12-02 | 2016-02-18 | Stacked microelectronic assembly with TSVS formed in stages and carrier above chip |
Applications Claiming Priority (2)
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US41903310P | 2010-12-02 | 2010-12-02 | |
US13/051,424 US8736066B2 (en) | 2010-12-02 | 2011-03-18 | Stacked microelectronic assemby with TSVS formed in stages and carrier above chip |
Related Child Applications (1)
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US14/224,379 Division US9269692B2 (en) | 2010-12-02 | 2014-03-25 | Stacked microelectronic assembly with TSVS formed in stages and carrier above chip |
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US8736066B2 true US8736066B2 (en) | 2014-05-27 |
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US14/224,379 Active US9269692B2 (en) | 2010-12-02 | 2014-03-25 | Stacked microelectronic assembly with TSVS formed in stages and carrier above chip |
US15/047,295 Active US9620437B2 (en) | 2010-12-02 | 2016-02-18 | Stacked microelectronic assembly with TSVS formed in stages and carrier above chip |
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US15/047,295 Active US9620437B2 (en) | 2010-12-02 | 2016-02-18 | Stacked microelectronic assembly with TSVS formed in stages and carrier above chip |
Country Status (7)
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US (3) | US8736066B2 (en) |
EP (1) | EP2647040B1 (en) |
JP (1) | JP2013544444A (en) |
KR (1) | KR101122689B1 (en) |
CN (1) | CN103339717B (en) |
TW (1) | TWI479613B (en) |
WO (1) | WO2012074570A2 (en) |
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Also Published As
Publication number | Publication date |
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TWI479613B (en) | 2015-04-01 |
US9620437B2 (en) | 2017-04-11 |
US20160163620A1 (en) | 2016-06-09 |
TW201230258A (en) | 2012-07-16 |
WO2012074570A3 (en) | 2012-09-27 |
US20140206147A1 (en) | 2014-07-24 |
WO2012074570A2 (en) | 2012-06-07 |
CN103339717B (en) | 2016-09-07 |
CN103339717A (en) | 2013-10-02 |
US20120139082A1 (en) | 2012-06-07 |
US9269692B2 (en) | 2016-02-23 |
KR101122689B1 (en) | 2012-03-09 |
EP2647040A2 (en) | 2013-10-09 |
EP2647040B1 (en) | 2019-09-04 |
JP2013544444A (en) | 2013-12-12 |
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