US5468796A - Creeping chemical composition and method of use - Google Patents
Creeping chemical composition and method of use Download PDFInfo
- Publication number
- US5468796A US5468796A US08/291,804 US29180494A US5468796A US 5468796 A US5468796 A US 5468796A US 29180494 A US29180494 A US 29180494A US 5468796 A US5468796 A US 5468796A
- Authority
- US
- United States
- Prior art keywords
- weight percent
- creping adhesive
- dry weight
- creping
- acetylenic diol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/146—Crêping adhesives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/02—Homopolymers or copolymers of unsaturated alcohols
- C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/28—Non-macromolecular organic substances
- C08L2666/34—Oxygen-containing compounds, including ammonium and metal salts
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
Definitions
- aqueous suspensions of papermaking fibers are deposited onto a forming fabric to form an embryonic web.
- the embryonic web is dewatered, dried and thereafter creped to soften the resulting sheet.
- a creping adhesive is typically sprayed onto the surface of a rotating creping cylinder, such as a Yankee dryer, to help build an adhesive (dryer) coating to which the tissue sheet is adhered.
- the adhered tissue is dislodged from the surface of the creping cylinder by contact with a doctor blade.
- Crepe quality is maintained by regularly changing the doctor blades in order to maintain a uniform dryer coating, which becomes uneven due to skulch formation on the dryer surface.
- a non-uniform dryer coating is one of the major reasons for very frequent doctor blade changes. Blade life may be as short as 30 minutes in some instances. Necessary and frequent blade changes contribute to waste and delay and are also an expense to be minimized.
- creping adhesive formulations of this invention are particularly useful for use in throughdrying tissue making processes where skulch formation can be a significant problem, although wet pressing processes can also benefit from their use. While not being bound to any particular theory, it is believed that a particular class of surfactants, when added to an aqueous creping adhesive mixture, reduces the dynamic surface tension more effectively than other classes of surfactants. When the dynamic surface tension of a creping adhesive mixture is reduced to about 40 dynes per centimeter or less, the uniformity of the dryer coating is maintained for a longer period of operation before a doctor blade change is necessary.
- the invention resides in a creping adhesive composition
- creping adhesive compositions have a dynamic surface tension of about 40 dynes per centimeter or less, as measured by the maximum bubble pressure method, measured at 5 bubbles per second using an aqueous creping adhesive mixture having a solids content of 8-12 percent, wherein 10 percent of the solids is the surfactant.
- the creping adhesive formulation preferably comprises a semi-crystalline polymer, a polyamide or sorbitol, and a release agent.
- the ethoxylated acetylenic diol acts as the release agent or a component thereof.
- the amount of the ethoxylated acetylenic diol in the creping adhesive composition can be from about 0.05 to about 20 dry weight percent, more specifically from about 1 to about 10 dry weight percent, and still more specifically from about 1 to about 3 dry weight percent.
- dry weight percent refers to a percentage based solely on the amount of solids present in the composition.
- Suitable semi-crystalline polymers include polyvinyl alcohol, polyvinylpyrrolidone, hydroxyethylcellulose, carboxymethylcellulose, microcrystalline cellulose, and the like.
- the amount of the crystalline polymer component, if present, can be from about 50 to about 90 dry weight percent of the creping adhesive composition.
- Suitable polyamides possess an intrinsic viscosity of from about 10 to about 200 cubic centimeters per gram and, if present, can be from about 10 to about 50 dry weight percent of the creping adhesive composition.
- Specific polyamides include Crepeplus 97, available from Betz Paper Chemical Co., Jacksonville, Fla., and Creptrol 190, available from Hercules, Inc., Wilmington, Del.
- the amount of the release agent can be from about 0.05 to about 20 dry weight percent of the creping adhesive composition and preferably further comprises a cationic oligomer in the amount of from about 5 to about 95 weight percent of the amount of the release agent.
- Suitable cationic oligomers include quaternary amines, such as Quaker 2008, available from Quaker Chemical Company, Conshohocken, Pa.
- the invention resides in a method of making a creped tissue comprising the steps of: (a) depositing an aqueous suspension of papermaking fibers onto a forming fabric to form an embryonic web; dewatering and drying the embryonic web to form a tissue web; (c) applying a creping adhesive to the surface of a creping cylinder; (d) adhering the tissue web to the creping cylinder; and (e) dislodging th tissue web from the creping cylinder with a doctor blade to form a soft tissue sheet, wherein the creping adhesive comprises from about 0.05 to about 20 dry weight percent of the creping adhesive referred to above.
- the creping adhesive is suitably an aqueous suspension containing from about 0.1 to about 10 weight percent solids, more specifically from about 0.5 to about 2 weight percent solids, and still more specifically about 1 percent solids.
- the rate at which the creping adhesive is applied to the surface of the creping cylinder can be from about 2 to about 20 pounds per ton of fiber.
- the resulting dynamic surface tensions indicate that the ethoxylated acetylenic diol surfactant (Surfynol 420) was more efficient in lowering the dynamic surface tension than other surfactants such as Triton X-100 or Aerosol TO.
- creping adhesive formulations of this invention were conducted on a tissue machine producing bath tissue at a speed of about 3200 feet per minute.
- the trial matrix is shown in Table 2.
- the crepe quality was observed and evaluated on a scale of 1 to 4, with grade 1 being the best. Observations were also noted regarding creping blade life.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Biomedical Technology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
TABLE 1 __________________________________________________________________________ CHEMICAL STOCK SOLUTIONS FOR DYNAMIC SURFACE TENSION MEASUREMENTS Surface Form Chem #1 % Chem #1 Chem #2 % Chem #2 Chem #3 % Chem #3 Chem #4 % Chem Tension __________________________________________________________________________ 1 PVOH 60.00 Sorbitol 38.00 Triton X100 2.00 -- -- 52.8 2 PVOH 40.00 Sorbitol 58.00 Triton X100 2.00 -- -- 52.0 3 PVOH 60.00 Sorbitol 38.00 Surfynol 420 2.00 -- -- 44.2 4 PVOH 40.00 Sorbitol 58.00 Surfynol 420 2.00 -- -- 48.6 5 PVOH 60.00 Sorbitol 38.00 Aerosol OT 2.00 -- -- 50.6 6 PVOH 40.00 Sorbitol 58.00 Aerosol OT 2.00 -- -- 52.0 7 PVOH 60.00 Sorbitol 38.00 Quaker 2008 2.00 -- -- 62.2 8 PVOH 40.00 Sorbitol 58.00 Quaker 2008 2.00 -- -- 62.6 9 PVOH 80.00 Creptrol 190 18.00 Triton xlOO 2.00 -- -- 53.7 10 PVOH 80.00 Creptrol 190 18.00 Surfynol 420 2.00 -- -- 47.8 11 PVOH 80.00 Creptrol 190 18.00 Aeasol OT 2.00 -- -- 61.5 12 PVOH 80.00 Creptrol 190 18.00 Quaker 2008 2.00 -- -- 62.2 13 PVOH 48.00 Crepeplus 97 50.00 Triton X100 2.00 -- -- 56.0 14 PVOH 48.00 Crepeplus 97 50.00 Surfynol 420 2.00 -- -- 48.1 15 PVOH 48.00 Crepeplus 97 50.00 Aerosol OT 2.00 -- -- 61.9 16 PVOH 48.00 Crepeplus 97 50.00 Quaker 2008 2.00 -- -- 64.1 17 PVOH 60.00 Sorbitol 40.00 -- -- -- -- 63.9 18 PVOH 40.00 Sorbitol 29.00 Quaker 2008 1.00 Surfynol 504 10.00 33.7 19 PVOH 40.00 Sorbitol 29.00 Quaker 2008 1.00 Triton X-100 10.00 47.1 __________________________________________________________________________
TABLE 2 ______________________________________ CREPING FORMULATION CELLS Ingredient Flow Rate (gm/min) Crepeplus Quaker Surfynol Com- Cell PVA Sorbitol #97 2008 #504 ments ______________________________________ 1 51.00 8.40 3.00 Control 2 51.00 8.40 0.30 2.72 Unstable web 3 51.00 8.40 0.23 2.04 Same as #2 4 51.00 8.40 2.05 Un- accept- able creping Skutch at 1st roll 5 51.00 8.40 2.72 Same as #4 6 51.00 4.56 3.00 Excellent Crepe 3 rolls/ blade 7 51.00 4.56 2.63 Same as #6 8 51.00 5.00 0.30 2.72 Same as #6 9 51.00 4.56 0.45 4.08 Excellent crepe Excellent blade life ______________________________________ Referring to Table 2, the best formulation was Cell #9. The creping quality was grade 1 up to the 12th roll using only one single blade. This formulation was repeated at a later date and was run for three hours with the same blade. Every roll produced had a crepe quality of grade 1. By comparison, an adhesive formulation consisting of polyvinyl alcohol, Sorbitol and Quaker 2008 run for two hours and fifty-five minutes ended up with a crepe quality of grade 3.
Claims (32)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/291,804 US5468796A (en) | 1994-08-17 | 1994-08-17 | Creeping chemical composition and method of use |
US08/399,278 US5490903A (en) | 1994-08-17 | 1995-03-06 | Creping chemical composition and method of use |
CA002149590A CA2149590A1 (en) | 1994-08-17 | 1995-05-17 | Creping chemical compositions and method of use |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/291,804 US5468796A (en) | 1994-08-17 | 1994-08-17 | Creeping chemical composition and method of use |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08/399,278 Division US5490903A (en) | 1994-08-17 | 1995-03-06 | Creping chemical composition and method of use |
Publications (1)
Publication Number | Publication Date |
---|---|
US5468796A true US5468796A (en) | 1995-11-21 |
Family
ID=23121909
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08/291,804 Expired - Fee Related US5468796A (en) | 1994-08-17 | 1994-08-17 | Creeping chemical composition and method of use |
US08/399,278 Expired - Fee Related US5490903A (en) | 1994-08-17 | 1995-03-06 | Creping chemical composition and method of use |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08/399,278 Expired - Fee Related US5490903A (en) | 1994-08-17 | 1995-03-06 | Creping chemical composition and method of use |
Country Status (2)
Country | Link |
---|---|
US (2) | US5468796A (en) |
CA (1) | CA2149590A1 (en) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5858554A (en) * | 1995-08-25 | 1999-01-12 | The Procter & Gamble Company | Paper product comprising adhesively joined plies |
US5865950A (en) * | 1996-05-22 | 1999-02-02 | The Procter & Gamble Company | Process for creping tissue paper |
US5942085A (en) * | 1997-12-22 | 1999-08-24 | The Procter & Gamble Company | Process for producing creped paper products |
US5944954A (en) * | 1996-05-22 | 1999-08-31 | The Procter & Gamble Company | Process for creping tissue paper |
US6150002A (en) * | 1997-10-31 | 2000-11-21 | Kimberly-Clark Worldwide, Inc. | Creped nonwoven liner with gradient capillary structure |
US6187138B1 (en) | 1998-03-17 | 2001-02-13 | The Procter & Gamble Company | Method for creping paper |
US20030019597A1 (en) * | 2001-06-05 | 2003-01-30 | Hill Walter B. | Polymeric creping adhesives and creping methods using same |
US20040118534A1 (en) * | 2002-12-19 | 2004-06-24 | Anderson Ralph Lee | Low formaldehyde creping composition and product and process incorporating same |
US20050092450A1 (en) * | 2003-10-30 | 2005-05-05 | Hill Walter B.Jr. | PVP creping adhesives and creping methods using same |
US20080199501A1 (en) * | 2007-02-21 | 2008-08-21 | L'oreal | Article/composition combination |
US8246781B2 (en) | 2010-05-20 | 2012-08-21 | Georgia-Pacific Chemicals Llc | Thermosetting creping adhesive with reactive modifiers |
US8361278B2 (en) | 2008-09-16 | 2013-01-29 | Dixie Consumer Products Llc | Food wrap base sheet with regenerated cellulose microfiber |
WO2013019526A1 (en) | 2011-08-01 | 2013-02-07 | Buckman Laboratories International, Inc. | Creping methods using ph-modified creping adhesive compositions |
WO2013028648A2 (en) | 2011-08-22 | 2013-02-28 | Buckman Laboratories International, Inc. | Oil-based creping release aid formulation |
WO2013106170A2 (en) | 2012-01-12 | 2013-07-18 | Buckman Laboratories International, Inc. | Methods to control organic contaminants in fibers |
WO2015026507A1 (en) | 2013-08-20 | 2015-02-26 | Buckman Laboratories International, Inc. | Methods to control organic contaminants in fibers using zeolites |
WO2015069966A1 (en) | 2013-11-07 | 2015-05-14 | Georgia-Pacific Chemicals Llc | Creping adhesives and methods for making and using same |
WO2015088881A1 (en) | 2013-12-10 | 2015-06-18 | Buckman Laboratories International, Inc. | Adhesive formulation and creping methods using same |
WO2019183154A1 (en) | 2018-03-22 | 2019-09-26 | Buckman Laboratories International, Inc. | Modified creping adhesive formulation and creping methods using same |
WO2021050339A1 (en) | 2019-09-11 | 2021-03-18 | Buckman Laboratories International,Inc. | Grafted polyvinyl alcohol polymer, formulations containing the same and creping methods |
WO2021092363A1 (en) | 2019-11-07 | 2021-05-14 | Ecolab Usa Inc. | Creping adhesives and processes for making and using same |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6143135A (en) * | 1996-05-14 | 2000-11-07 | Kimberly-Clark Worldwide, Inc. | Air press for dewatering a wet web |
US6149767A (en) | 1997-10-31 | 2000-11-21 | Kimberly-Clark Worldwide, Inc. | Method for making soft tissue |
US6096169A (en) * | 1996-05-14 | 2000-08-01 | Kimberly-Clark Worldwide, Inc. | Method for making cellulosic web with reduced energy input |
US6083346A (en) * | 1996-05-14 | 2000-07-04 | Kimberly-Clark Worldwide, Inc. | Method of dewatering wet web using an integrally sealed air press |
FI108063B (en) * | 1997-09-09 | 2001-11-15 | Runtech Systems Oy | Method and apparatus for treating a web of material |
US6197154B1 (en) | 1997-10-31 | 2001-03-06 | Kimberly-Clark Worldwide, Inc. | Low density resilient webs and methods of making such webs |
US6187137B1 (en) | 1997-10-31 | 2001-02-13 | Kimberly-Clark Worldwide, Inc. | Method of producing low density resilient webs |
US6306257B1 (en) | 1998-06-17 | 2001-10-23 | Kimberly-Clark Worldwide, Inc. | Air press for dewatering a wet web |
US6280573B1 (en) | 1998-08-12 | 2001-08-28 | Kimberly-Clark Worldwide, Inc. | Leakage control system for treatment of moving webs |
US6318727B1 (en) | 1999-11-05 | 2001-11-20 | Kimberly-Clark Worldwide, Inc. | Apparatus for maintaining a fluid seal with a moving substrate |
US6562194B1 (en) * | 2000-03-30 | 2003-05-13 | Calgon Corporation | Method of creping paper webs |
US20040211534A1 (en) * | 2003-04-24 | 2004-10-28 | Clungeon Nancy S. | Creping additives for paper webs |
CA2534348C (en) * | 2003-08-05 | 2010-10-26 | The Procter & Gamble Company | Improved creping aid composition and methods for producing paper products using that system |
WO2014107329A1 (en) * | 2013-01-04 | 2014-07-10 | Georgia-Pacific Chemicals Llc | Additives with cloud points to improve efficiency of release agents |
WO2015095841A1 (en) * | 2013-12-20 | 2015-06-25 | Georgia-Pacific Chemicals Llc | Release aids with adjustable cloud points for creping processes |
US10851330B2 (en) * | 2015-07-29 | 2020-12-01 | Dubois Chemicals, Inc. | Method of improving paper machine fabric performance |
ES2978049T3 (en) | 2018-10-19 | 2024-09-04 | Valmet Oy | Yankee adhesive compositions and methods of using these compositions |
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US2426312A (en) * | 1945-07-20 | 1947-08-26 | Us Rubber Co | Carding machine attachment for controlling the web weight |
US2718142A (en) * | 1952-07-03 | 1955-09-20 | Johnson & Johnson | Softness tester for sheet material |
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US3164015A (en) * | 1961-11-16 | 1965-01-05 | Hans Biel | Apparatus for detecting surface imperfections on moving webs, especially of paper |
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US3528145A (en) * | 1968-10-31 | 1970-09-15 | Cluett Peabody & Co Inc | Split detector for fabrics undergoing incremental lateral stretching |
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US5297062A (en) * | 1990-12-21 | 1994-03-22 | Measurex Corporation | Sensor, system and method for determining Z-directional properties of a sheet |
-
1994
- 1994-08-17 US US08/291,804 patent/US5468796A/en not_active Expired - Fee Related
-
1995
- 1995-03-06 US US08/399,278 patent/US5490903A/en not_active Expired - Fee Related
- 1995-05-17 CA CA002149590A patent/CA2149590A1/en not_active Abandoned
Patent Citations (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2426312A (en) * | 1945-07-20 | 1947-08-26 | Us Rubber Co | Carding machine attachment for controlling the web weight |
US2718142A (en) * | 1952-07-03 | 1955-09-20 | Johnson & Johnson | Softness tester for sheet material |
US2978636A (en) * | 1957-04-30 | 1961-04-04 | Viking Instr Inc | Flaw detecting apparatus |
US3164015A (en) * | 1961-11-16 | 1965-01-05 | Hans Biel | Apparatus for detecting surface imperfections on moving webs, especially of paper |
GB1116392A (en) * | 1964-09-30 | 1968-06-06 | Basf Ag | Production of fast flowing polyamides |
US3529045A (en) * | 1964-10-30 | 1970-09-15 | Spunize Co Of America Inc | Method for controlling roll diameter |
US3546065A (en) * | 1967-12-29 | 1970-12-08 | Kimberly Clark Co | Corona discharge applied directly to creping surface to increase adhesion of web to surface |
US3528145A (en) * | 1968-10-31 | 1970-09-15 | Cluett Peabody & Co Inc | Split detector for fabrics undergoing incremental lateral stretching |
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