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US3345195A - Method for imparting a permanent crease to wool - Google Patents

Method for imparting a permanent crease to wool Download PDF

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Publication number
US3345195A
US3345195A US309301A US30930163A US3345195A US 3345195 A US3345195 A US 3345195A US 309301 A US309301 A US 309301A US 30930163 A US30930163 A US 30930163A US 3345195 A US3345195 A US 3345195A
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United States
Prior art keywords
wool
silicon
fabric
weight
crease
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Expired - Lifetime
Application number
US309301A
Inventor
Billy G Simpson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Silicones Corp
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Dow Corning Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Corning Corp filed Critical Dow Corning Corp
Priority to US309301A priority Critical patent/US3345195A/en
Priority to FI641240A priority patent/FI42063C/en
Priority to DK301664AA priority patent/DK113213B/en
Priority to NL6406873A priority patent/NL6406873A/xx
Priority to CH795964A priority patent/CH496844A/en
Priority to CH795964D priority patent/CH795964A4/xx
Priority to FR983722A priority patent/FR1403434A/en
Priority to DED45197A priority patent/DE1298503B/en
Priority to AT737964A priority patent/AT248998B/en
Priority to BE653099D priority patent/BE653099A/xx
Priority to GB37659/64A priority patent/GB1015979A/en
Application granted granted Critical
Publication of US3345195A publication Critical patent/US3345195A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain

Definitions

  • the object of this invention is to provide an economical method of rendering wool permanently crease resistant Without imparting undesirable features to the wool.
  • This invention relates to a method of imparting a permanent crease to a wool fabric which comprises applying to the fabric a water solution of an organosilicon compound having on the average per silicon atom of from 1 to 2 inclusive aliphatic hydrocarbon radicals of from 1 to 3 carbon atoms inclusive attached to the silicon through silicon-carbon bond, there being on the average no more than 3 carbon atoms per silicon atom, the remaining valences of the silicon being satisfied by OH groups or SiOSi linkages, said solution containing from .1 to 10 percent by weight of the organosilicon compound based on the weight of the solution and thereafter creasing the fabric under heat and pressure.
  • an organosilicon compound having on the average per silicon atom of from 1 to 2 inclusive aliphatic hydrocarbon radicals of from 1 to 3 carbon atoms inclusive attached to the silicon through silicon-carbon bond, there being on the average no more than 3 carbon atoms per silicon atom, the remaining valences of the silicon being satisfied by OH groups or SiOSi linkages, said solution containing
  • the treated wool can be first dried and then creased but often it is advantageous to crease the fabric before drying.
  • the temperature and pressure applied to the fabric to obtain the crease is not critical and, in general, those obtained by steam irons or in commercial pressing establishments are sufiicient.
  • the water solutions employed in this invention are solutions of high hydroxylated silanols or siloxanols in Ice which there is sufficient silicon-bonded hydroxyl groups to maintain the organosilicon compound in solution.
  • the structure of these materials is not precisely known but the silyl units can be any having the defined hydrocarbon groups attached thereto such as CH SlE, C3H7SlE,
  • the remaining valences of the silicon atoms are essentially all satisfied by OH groups or combinations of OH groups and SiOSi.
  • the compositions can be made up of one type organosilicon compound or mixtures of two or more types.
  • solutions of this invention are readily prepared by adding the corresponding alkoxy or acyloxy silanes such as dimethyldimethoxysilane or propyltriactoxysilane to water and shaking until a uniform solution is obtained.
  • alkoxysilanes When alkoxysilanes are employed it is advantageous to use a small amount of a weak acid such as acetic acid in order to hasten hydrolysis of the alkoxysilane. This decreases the time necessary to obtain a homogeneous solution.
  • the treatment of this invention is applicable both to pure wool and to blends of wool with other fabrics.
  • the amount of organosilicon compound actually deposited on the wool runs about percent of the amount in the treating solution. Thus, if one employs a solution containing 2 percent by weight organosilicon compound, about 1.7 percent by weight of the organosilicon compound is actually deposited on the wool.
  • the solutions can be applied to the fabric in any convenient manner such as by dipping, padding or spraying.
  • the garments were worn by individuals and dry cleaned several times by commercial techniques. The crease remained intact for an equivalent of two or three seasons of wear. These tests show that the treatment was successful in giving a permanent crease to the wool.
  • Example 2 W001 gabardine and wool flannel fabrics were treated with 2 percent by weight solutions 1 and 2 of Example 1 in the following manner.
  • the fabrics were padded at 40 psi. from the aqueous baths.
  • the samples were dried 10 minutes at F.
  • Three days later the samples were sprayed with tap water, folded and steam pressed one minute to set a crease.
  • the samples were placed in an air circu lating oven and dried 30 minutes at 150 F.
  • Example 3 The procedure of Example 1 was repeated employing a solution prepared by dissolving two parts by weight ethyltrimethoxysilane in the place of the methyltrimethoxysilane. A permanent crease was obtained.
  • Example 4 Equivalent results are obtained when vinyltriacetoxysilane, allyltrimethoxysilane and ethylmethyldimethoxysilane are employed in the procedure of Example 1.
  • the method of imparting a permanent crease to a wool fabric which comprises applying to the fabric a water solution of an organosilicon compound selected from the group consisting of highly hydroxylated silanol and siloxanol organosilicon compounds in which there is an average per silicon atom of from 1 to 2 aliphatic hydrocarbon radicals of from 1 to 3 inclusive carbon atoms attached to the silicon through carbon-silicon bonds, there being on the average no more than 3 carbon atoms per silicon, the remaining valences of the silicon atom being satisfied by substituents selected from the group consisting of hydroxyl radicals and oxygen atoms of SiOSi linkages, there being from .1 to percent by weight of said organosilicon compound based on the weight of the solution and thereafter creasing the fabric under heat and pressure.
  • an organosilicon compound selected from the group consisting of highly hydroxylated silanol and siloxanol organosilicon compounds in which there is an average per silicon atom of from 1 to 2 aliphatic hydrocarbon radical
  • the method of imparting a permanent crease to a wool fabric which comprises applying to the fabric a water solution of an organosilicon compound selected from the group consisting of highly hydroxylated silanol and siloxanol organosilicon compounds in which there is an average per silicon atom of from 1 to 2 aliphatic hydrocarbon radicals attached to the silicon through carbon-silicon bonds, said radicals having from 1 to 3 inclusive carbon atoms and there being on the average no more than three carbon atoms per silicon, the remaining valences of the silicon atoms being satisfied by substituents selected from the group consisting of hydroxyl radicals and oxygen atoms of SiOSi linkages, there being from .1 to 10 percent by Weight of said organosilicon compound based on the weight of the solution and thereafter creasing the fabric under heat and pressure while still wet with the solution.
  • an organosilicon compound selected from the group consisting of highly hydroxylated silanol and siloxanol organosilicon compounds in which there is an average per silicon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Description

United States Patent 3,345,195 METHOD FOR IMPARTING A PERMANENT GREASE T0 WOOL Billy G. Simpson, Greensboro, N.C., assignor to Dow Corning Corporation, Midland, Mich., a corporation of Michigan No Drawing. Filed Sept. 16, 1963, Ser. No. 309,301 6 Claims. (Cl. 117-10) This invention relates to a method of rendering wool permanently crease resistant.
There are several products presently being employed to render wool garments permanently crease resistant. These materials are, in general, sulfites which apparently react with wool and cause a permanent deformation to take place when the wool is creased. However, such treatments suffer from several disadvantages in that the sulfites have objectionable odors and that they adversely affect certain dyes. In addition, the sulfite treatment does not impart any additional water repellency to the wool. Thus, it is highly advantageous to provide a treatment which will render wool permanently crease resistant without adverse odors or adverse effect on the color of the wool.
It has long been known that wool could be treated with various siloxanes or hydrolyzable silanes in order to render the wool water repellent or to reduce the shrinkage of the wool during washing. However, these previous organosilicon treatments imparted little or no permanent crease resistance. Apparently the slight amount of crease resistance which is often imparted is due to the fact that the siloxanes prevented the wool from wetting as fast as untreated wool. However, the present invention does not in any way relate to the phenomena of water repellency or improved shrink resistance. Thus, it is most unexpected when applicant found that the particular treatments shown below provide a crease resistance equal to or superior to the present sulfite treatments. This is accomplished without the deleterious effects above mentioned.
The object of this invention is to provide an economical method of rendering wool permanently crease resistant Without imparting undesirable features to the wool. Other objects and advantages will be apparent from the following description.
This invention relates to a method of imparting a permanent crease to a wool fabric which comprises applying to the fabric a water solution of an organosilicon compound having on the average per silicon atom of from 1 to 2 inclusive aliphatic hydrocarbon radicals of from 1 to 3 carbon atoms inclusive attached to the silicon through silicon-carbon bond, there being on the average no more than 3 carbon atoms per silicon atom, the remaining valences of the silicon being satisfied by OH groups or SiOSi linkages, said solution containing from .1 to 10 percent by weight of the organosilicon compound based on the weight of the solution and thereafter creasing the fabric under heat and pressure.
In carrying out the method of this invention one wets the wool fabric with the aqueous solution and thereafter creases the fabric in the desired places. It is not necessary that an entire garment be wet but only that area in which the garment is to be creased. The treated wool can be first dried and then creased but often it is advantageous to crease the fabric before drying.
The temperature and pressure applied to the fabric to obtain the crease is not critical and, in general, those obtained by steam irons or in commercial pressing establishments are sufiicient.
The water solutions employed in this invention are solutions of high hydroxylated silanols or siloxanols in Ice which there is sufficient silicon-bonded hydroxyl groups to maintain the organosilicon compound in solution. The structure of these materials is not precisely known but the silyl units can be any having the defined hydrocarbon groups attached thereto such as CH SlE, C3H7SlE,
CHFCHSi CH =CHCH SiE, CH CH=CHSiE (CH3)2Si and C2H5SlE. The remaining valences of the silicon atoms are essentially all satisfied by OH groups or combinations of OH groups and SiOSi. The compositions can be made up of one type organosilicon compound or mixtures of two or more types.
The solutions of this invention are readily prepared by adding the corresponding alkoxy or acyloxy silanes such as dimethyldimethoxysilane or propyltriactoxysilane to water and shaking until a uniform solution is obtained. When alkoxysilanes are employed it is advantageous to use a small amount of a weak acid such as acetic acid in order to hasten hydrolysis of the alkoxysilane. This decreases the time necessary to obtain a homogeneous solution.
The treatment of this invention is applicable both to pure wool and to blends of wool with other fabrics. The amount of organosilicon compound actually deposited on the wool runs about percent of the amount in the treating solution. Thus, if one employs a solution containing 2 percent by weight organosilicon compound, about 1.7 percent by weight of the organosilicon compound is actually deposited on the wool.
The solutions can be applied to the fabric in any convenient manner such as by dipping, padding or spraying.
The following examples are illustrative only and should not be construed as limiting the invention which is properly delineated in the appended claims.
Example 1 The following solutions were employed in this example:
(1) 2 parts by weight of dimethyldimethoxysilane were mixed with 98 parts by weight water containing .1 part by weight acetic acid until a homogeneous solution was obtained.
'(2) 2 parts by weight of propyltrimethoxysilane was mixed with 98 parts by weight water containing .1 part by weight acetic acid until a homogeneous solution was obtained.
Each solution was sprayed onto the various garments shown below and the garment was steam pressed While wet for one minute to set a crease and thereafter dried for one hour at 150 F. The garments treated were:
100 percent wool flannel dark olive trousers,
100 percent wool gabardine brown trousers,
100 percent worsted wool charcoal gray trousers,
100 percent wool novelty weave olive green skirt and 100 percent wool plain weave brown plaid skirt.
In each case there was no objectionable odor or undesirable color change in the fabric.
The garments were worn by individuals and dry cleaned several times by commercial techniques. The crease remained intact for an equivalent of two or three seasons of wear. These tests show that the treatment was successful in giving a permanent crease to the wool.
Example 2 W001 gabardine and wool flannel fabrics were treated with 2 percent by weight solutions 1 and 2 of Example 1 in the following manner. The fabrics were padded at 40 psi. from the aqueous baths. Immediately upon removal from the bath the samples were dried 10 minutes at F. Three days later the samples were sprayed with tap water, folded and steam pressed one minute to set a crease. The samples were placed in an air circu lating oven and dried 30 minutes at 150 F.
The permanence of the crease in each case was then checked and found to be satisfactory but not as good as in Example 1.
Example 3 The procedure of Example 1 was repeated employing a solution prepared by dissolving two parts by weight ethyltrimethoxysilane in the place of the methyltrimethoxysilane. A permanent crease was obtained.
Example 4 Equivalent results are obtained when vinyltriacetoxysilane, allyltrimethoxysilane and ethylmethyldimethoxysilane are employed in the procedure of Example 1.
That which is claimed is:
1. The method of imparting a permanent crease to a wool fabric which comprises applying to the fabric a water solution of an organosilicon compound selected from the group consisting of highly hydroxylated silanol and siloxanol organosilicon compounds in which there is an average per silicon atom of from 1 to 2 aliphatic hydrocarbon radicals of from 1 to 3 inclusive carbon atoms attached to the silicon through carbon-silicon bonds, there being on the average no more than 3 carbon atoms per silicon, the remaining valences of the silicon atom being satisfied by substituents selected from the group consisting of hydroxyl radicals and oxygen atoms of SiOSi linkages, there being from .1 to percent by weight of said organosilicon compound based on the weight of the solution and thereafter creasing the fabric under heat and pressure.
2. The method of imparting a permanent crease to a wool fabric which comprises applying to the fabric a water solution of an organosilicon compound selected from the group consisting of highly hydroxylated silanol and siloxanol organosilicon compounds in which there is an average per silicon atom of from 1 to 2 aliphatic hydrocarbon radicals attached to the silicon through carbon-silicon bonds, said radicals having from 1 to 3 inclusive carbon atoms and there being on the average no more than three carbon atoms per silicon, the remaining valences of the silicon atoms being satisfied by substituents selected from the group consisting of hydroxyl radicals and oxygen atoms of SiOSi linkages, there being from .1 to 10 percent by Weight of said organosilicon compound based on the weight of the solution and thereafter creasing the fabric under heat and pressure while still wet with the solution.
3. The method in accordance with claim 1 in which the hydrocarbon radical is methyl.
4. The method in accordance with claim 2 in which the hydrocarbon radical is methyl.
5. The method in accordance with claim 1 wherein the hydrocarbon radical is propyl.
6. The method in accordance with claim 2 wherein the hydrocarbon radical is propyl.
References Cited UNITED STATES PATENTS 2,634,285 4/1953 Rust et al 117139.4 X 2,974,432 3/1961 Warnock et a1. 11710 X 3,032,442 5/1962 Roth 1l7139.4 3,059,990 11/1962 Koenig et al. 117l1 X 3,065,111 11/1962 Reeves et al 11714l X WILLIAM D. MARTIN, Primary Examiner.
MURRAY KATZ, Examiner.
T. G. DAVIS, Assistant Examiner.

Claims (1)

1. THE METHOD OF IMPARTING A PERMANENT CREASE TO A WOOL FABRIC WHICH COMPRISES APPLYING TO THE FABRIC A WATER SOLUTION OF AN ORGANOSILICON COMPOUND SELECTED FROM THE GROUP CONSISTING OF HIGHLY HYDROXYLATED SILANOL AND SILOXANOL ORGANOSILICON COMPOUNDS IN WHICH THERE IS AN AVERAGE PER SILICON ATOM OF FROM 1 ALPHATIC HYDROCARBON RADICALS OF FROM 1 TO 3 INCLUSIVE CARBON ATOMS ATTACHED TO THE SILICON THROUGH CARBON-SILICON BONDS, THERE BEING ON THE AVERAGE NO MORE THAN 3 CARBON ATOMS PER SILICON, THE REMAINING VALENCES OF THE SILICON ATOM BEING SATISFIED BY SUBSTITUENTS SELECTED FROM THE GROUP CONSISTING OF HYDROXYL RADICALS AND OXYGEN ATOMS OF SIOSI LINKAGES, THERE BEING FROM 9U TO 10 PERCENT BY WEIGHT OF SAID ORGANOSILICON COMPOUND BASED ON THE WEIGHT OF THE SOLUTION AND THEREAFTER CREASING THE FABRIC UNDER HEAT AND PRESSURE.
US309301A 1963-09-16 1963-09-16 Method for imparting a permanent crease to wool Expired - Lifetime US3345195A (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
US309301A US3345195A (en) 1963-09-16 1963-09-16 Method for imparting a permanent crease to wool
FI641240A FI42063C (en) 1963-09-16 1964-06-09 A way to achieve permanent compression pleats in woolen fabrics
DK301664AA DK113213B (en) 1963-09-16 1964-06-16 Method for providing permanent press folds on fabric containing wool fibers.
CH795964A CH496844A (en) 1963-09-16 1964-06-17 Process for the production of permanent folds in woolen fabric
CH795964D CH795964A4 (en) 1963-09-16 1964-06-17
NL6406873A NL6406873A (en) 1963-09-16 1964-06-17
FR983722A FR1403434A (en) 1963-09-16 1964-07-31 Wrinkle-resistant wool
DED45197A DE1298503B (en) 1963-09-16 1964-08-14 Process for creating permanent folds in woolen fabrics
AT737964A AT248998B (en) 1963-09-16 1964-08-26 Process for creating permanent folds in woolen fabrics
BE653099D BE653099A (en) 1963-09-16 1964-09-15
GB37659/64A GB1015979A (en) 1963-09-16 1964-09-15 A method for imparting a permanent crease to wool fabrics

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US309301A US3345195A (en) 1963-09-16 1963-09-16 Method for imparting a permanent crease to wool

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US3345195A true US3345195A (en) 1967-10-03

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US309301A Expired - Lifetime US3345195A (en) 1963-09-16 1963-09-16 Method for imparting a permanent crease to wool

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US (1) US3345195A (en)
AT (1) AT248998B (en)
BE (1) BE653099A (en)
CH (2) CH795964A4 (en)
DE (1) DE1298503B (en)
DK (1) DK113213B (en)
FI (1) FI42063C (en)
FR (1) FR1403434A (en)
GB (1) GB1015979A (en)
NL (1) NL6406873A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3632423A (en) * 1969-01-10 1972-01-04 Wacom Ltd Process for giving shape-fitting property on a garment knitted with filament yarns
US3664864A (en) * 1968-07-27 1972-05-23 Basf Ag Durably shaping keratinous fibrous materials
US4005231A (en) * 1974-05-28 1977-01-25 Dow Corning Limited Treatment of fibres
US20090206296A1 (en) * 2008-02-14 2009-08-20 Bakul Dave Methods and compositions for improving the surface properties of fabrics, garments, textiles and other substrates
WO2018069528A1 (en) * 2016-10-14 2018-04-19 Commissariat A L'energie Atomique Et Aux Energies Alternatives Method for sol-gel coating of textile materials
CN110241534A (en) * 2019-04-16 2019-09-17 广东溢达纺织有限公司 Ready-made clothes stereotyped structure, ready-made clothes method for shaping and the clothes made using this method

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1543157A (en) * 1975-05-17 1979-03-28 Dow Corning Ltd Treatment of fibres

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2634285A (en) * 1947-03-27 1953-04-07 Montclair Res Corp Acyloxy silanes
US2974432A (en) * 1956-02-20 1961-03-14 Koret Of California Press-free crease retained garments and method of manufacture thereof
US3032442A (en) * 1955-04-15 1962-05-01 American Cyanamid Co Process of finishing textiles with silicone-colloidal melamine resin mixtures, composition and resultant article
US3059990A (en) * 1959-11-03 1962-10-23 Nathan H Koenig Method of setting wool textiles with ethanolamine
US3065111A (en) * 1959-05-07 1962-11-20 Wilson A Reeves Silane-silicone mixture, method of producing the mixture; textile treated with the mixture; and method of impregnating textile with the mixture

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE526786A (en) * 1953-02-27

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2634285A (en) * 1947-03-27 1953-04-07 Montclair Res Corp Acyloxy silanes
US3032442A (en) * 1955-04-15 1962-05-01 American Cyanamid Co Process of finishing textiles with silicone-colloidal melamine resin mixtures, composition and resultant article
US2974432A (en) * 1956-02-20 1961-03-14 Koret Of California Press-free crease retained garments and method of manufacture thereof
US3065111A (en) * 1959-05-07 1962-11-20 Wilson A Reeves Silane-silicone mixture, method of producing the mixture; textile treated with the mixture; and method of impregnating textile with the mixture
US3059990A (en) * 1959-11-03 1962-10-23 Nathan H Koenig Method of setting wool textiles with ethanolamine

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3664864A (en) * 1968-07-27 1972-05-23 Basf Ag Durably shaping keratinous fibrous materials
US3632423A (en) * 1969-01-10 1972-01-04 Wacom Ltd Process for giving shape-fitting property on a garment knitted with filament yarns
US4005231A (en) * 1974-05-28 1977-01-25 Dow Corning Limited Treatment of fibres
US20090206296A1 (en) * 2008-02-14 2009-08-20 Bakul Dave Methods and compositions for improving the surface properties of fabrics, garments, textiles and other substrates
WO2018069528A1 (en) * 2016-10-14 2018-04-19 Commissariat A L'energie Atomique Et Aux Energies Alternatives Method for sol-gel coating of textile materials
FR3057581A1 (en) * 2016-10-14 2018-04-20 Commissariat A L'energie Atomique Et Aux Energies Alternatives METHOD FOR COATING TEXTILE MATERIALS
US11408121B2 (en) 2016-10-14 2022-08-09 Commissariat A L'energie Atomique Et Aux Energies Alternatives Method for sol-gel coating of textile materials
CN110241534A (en) * 2019-04-16 2019-09-17 广东溢达纺织有限公司 Ready-made clothes stereotyped structure, ready-made clothes method for shaping and the clothes made using this method

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CH496844A (en) 1970-06-15
DK113213B (en) 1969-03-03
CH795964A4 (en) 1970-06-15
FI42063B (en) 1970-02-02
DE1298503B (en) 1969-07-03
AT248998B (en) 1966-08-25
FI42063C (en) 1970-05-11
FR1403434A (en) 1965-06-18
GB1015979A (en) 1966-01-05
NL6406873A (en) 1965-03-17
BE653099A (en) 1965-03-15

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