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US2994327A - Articles of reinforced foam material - Google Patents

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Publication number
US2994327A
US2994327A US503861A US50386155A US2994327A US 2994327 A US2994327 A US 2994327A US 503861 A US503861 A US 503861A US 50386155 A US50386155 A US 50386155A US 2994327 A US2994327 A US 2994327A
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United States
Prior art keywords
foam material
articles
hair
reinforcing element
article
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Expired - Lifetime
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US503861A
Inventor
Otto Carl Louis
Otto La Nelle Burnham
Briton Joan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CARONELLE Inc
CHARLES C SCHWARTZ
Original Assignee
CARONELLE Inc
CHARLES C SCHWARTZ
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Priority to US503861A priority Critical patent/US2994327A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/20Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length
    • B29C44/22Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length consisting of at least two parts of chemically or physically different materials, e.g. having different densities
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/32Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
    • B29C48/335Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles
    • B29C48/336Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles the components merging one by one down streams in the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S138/00Pipes and tubular conduits
    • Y10S138/09Cellular
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1376Foam or porous material containing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987With nonvoid component of specified composition
    • Y10T428/249991Synthetic resin or natural rubbers
    • Y10T428/249992Linear or thermoplastic
    • Y10T428/249993Hydrocarbon polymer

Definitions

  • the present invention relates to articles of reinforced foam material and to the manufacture thereof, and has particular reference to such articles in which the foam material is of resiliently elastic nature, while the reinforcement is provided by stiffer material.
  • articles to which the invention is particularly applicable are the core members, usually cylindrical, of hair curlers around which strands of hair to be curled are wound and then clamped in place by retaining members engaging the strands of hair and the core member.
  • foam material of various synthetic resins such as various vinyl derivatives and other polymers such as polyesters and polyurethane derived from isocyanate, also various forms of foam rubber both natural and synthetic, all of which materials may be generically termed plastic foam, satisfy the requirements, but such materials do not have the requisite physical strength in resistance to bending to provide the axial stiffness necessary for a satisfactory core member of a hair curler or similar devices requiring a certain minimum degree of longitudinal structural strength.
  • the present invention contemplates to provision of a new article of the character described comprised of an elongated circumferential continuous hollow body of resiliently elastic foam material longitudinally stiffened by a central hollow reinforcing element of other more dense and structurally stiffer material, preferably relatively light and non-frangible synthetic plastic material, which liner is advantageously in the form of a cylindrical tube but which may be in the form of a solid core.
  • a central hollow reinforcing element of other more dense and structurally stiffer material, preferably relatively light and non-frangible synthetic plastic material, which liner is advantageously in the form of a cylindrical tube but which may be in the form of a solid core.
  • both the body and the reinforcing element are tubular.
  • numerous of the known synthetic thermoplastic materials may be employed, polyethylene being noted by way of example but without limitation, as a suitable material of that class.
  • the invention contemplates the provision of a core member formed by a body of foam material of relatively large diameter, particularly as compared with the diameter of the internal reinforcing element, and said body provides what is in effect a soft pillow of foam material of bolster-like form upon which the hair is to be wound, the bolster-like body being highly compressible under the tension applied by winding the hair thereon, so that it may readily be manipulated by the user to Wind coils of different diameter, depending upon the tension applied.
  • the high degree of compressibility of the body insures the maintenance of the desired tension on the hair that has been wound, even though after winding the hair, some slippage of the hair on the coil member may occur because of failure of the clip or other fastening means to hold the hair against any movement relative to the supporting body.
  • Such advantageous functions can as a practical atent ice matter be attained only when, as noted, the body of foam material is of relatively large diameter as compared with the central reinforcing element which is substantially incompressible.
  • the outer diameter of the body of foam material should be at least twice that of the relatively stiff and incompressible reinforcing element, and preferably should be at least three or more times the diameter of the reinforcing element, so that the wall thickness of the foam pillow will be at least as great as the diameter of the reinforcing element, as illustrated in FIG. 3.
  • FIG. 1 is a fragmentary sectional view of extrusion apparatus for producing the desired article.
  • FIG. 2 is a fragmentary vertical sectional view of extrusion apparatus for producing the desired article
  • FIG. 3 is a perspective view of a core member for a hair curler or the like formed by a length of the article as extruded from the apparatus shown in FIGS. 1 and 2.
  • 10 indicates generally a compound extrusion apparatus embodying a first extruder indicated generally at A and a second extruder indicated generally at B.
  • extruder A is shown as being provided with a feed screw 12 for feeding liner material such as polyethylene around the mandrel 14 so as to extrude an annular tube 16 of relatively thin wall section around the mandrel, the tube progressing into the chamber of the extruder B to which latter chamber foam material is fed by means of the feed screw 18.
  • liner material such as polyethylene
  • FIG. 2 shows foam material, produced in the foaming machine diagrammatically illustrated at 20 and fed by means of the feed screw 22 to the feed screw 18 of the extruder B.
  • the feed screws advantageously may be synchronized by means of gears 24 connecting the drive shaft of the screw 22 with the power input shaft 26 constituting the drive shaft for the extruder B.
  • the feed screws 12 and 18 may also be interconnected so that a common source of power may be utilized to drive the entire apparatus.
  • the foam material will be extruded in the form of a sheath 28 around the liner 16 and with the foams of polymers such as those enumerated above, which have a relatively short setting time, further treatment following the discharge from extruder B is ordinarily not required. With some materials, a certain amount of curing following extrusion of the foam material may be required, but the specific procedures to be followed will be dictated by the particular material employed, such specific procedures being generally known in the art.
  • the core member such as is shown in FIG. 3, may have an annular liner or a solid liner or core, and either form may advantageously be used in conjunction With retaining members of the kind embodied in the disclosure of U.S. application Serial No. 456,485, filed September 16, 1954, in the names of Carl L. Otto and La Nelle Burnham Otto, now US. Patent No. 2,842,- 140 granted July 8, 1958.
  • a core member for a hair curler comprising an elongated circumferentially continuous hollow body of highly compressible elastically resilient foam material and a central hollow reinforcing element of elastically yieldable non-metallic material substantially stiffer than said foam material extending through said body, said reinforcing element being open at both of its ends, said element and said body being substantially coextensive longitudinally and the diameter of said body of foam material being at least a plurality of times the diameter of said reinforcing element, whereby to provide a soft pillow of foam material of bolster-like form the outer circumference of which may easily be materially reduced by the winding of a tress of hair thereon under desired tension to thereby permit coils of hair of difierent diameters to be formed on like core members as desired by the user in accordance with the tension under which the hair is Wound and to insure maintenance of the desired tension of the hair While coiled on said member.
  • both the body of foam material and the central reinforcing element are tubular in form, and the radial thickness of the wall of said body of foam material is at least as great as the outer diameter of said reinforcing element.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Hair Curling (AREA)

Description

Aug. 1, 1961 c. L. OTTO ET AI. 2,994,327
ARTICLES OF REINFORCED FOAM MATERIAL Filed April 26, 1955 II "II [HIM f da zZ M ATTORNEY 26, 1955, Ser. No. 503,861 Claims.
The present invention relates to articles of reinforced foam material and to the manufacture thereof, and has particular reference to such articles in which the foam material is of resiliently elastic nature, while the reinforcement is provided by stiffer material.
By way of example, but without limitation, articles to which the invention is particularly applicable are the core members, usually cylindrical, of hair curlers around which strands of hair to be curled are wound and then clamped in place by retaining members engaging the strands of hair and the core member.
For such articles to be satisfactory they must be light, elastically resilient, and should be porous to the extent required to afford the substantial degree of ventilation required to secure the relatively rapid drying of hair wound thereon that is desirable. Additionally, the articles, to have practical commercial acceptance and value, must be relatively very cheap.
From the standpoint of the above mentioned physical characteristics, foam material of various synthetic resins such as various vinyl derivatives and other polymers such as polyesters and polyurethane derived from isocyanate, also various forms of foam rubber both natural and synthetic, all of which materials may be generically termed plastic foam, satisfy the requirements, but such materials do not have the requisite physical strength in resistance to bending to provide the axial stiffness necessary for a satisfactory core member of a hair curler or similar devices requiring a certain minimum degree of longitudinal structural strength. Accordingly the present invention contemplates to provision of a new article of the character described comprised of an elongated circumferential continuous hollow body of resiliently elastic foam material longitudinally stiffened by a central hollow reinforcing element of other more dense and structurally stiffer material, preferably relatively light and non-frangible synthetic plastic material, which liner is advantageously in the form of a cylindrical tube but which may be in the form of a solid core. Preferably, both the body and the reinforcing element are tubular. For the intended purpose, numerous of the known synthetic thermoplastic materials may be employed, polyethylene being noted by way of example but without limitation, as a suitable material of that class.
As will be observed from the drawings, the invention contemplates the provision of a core member formed by a body of foam material of relatively large diameter, particularly as compared with the diameter of the internal reinforcing element, and said body provides what is in effect a soft pillow of foam material of bolster-like form upon which the hair is to be wound, the bolster-like body being highly compressible under the tension applied by winding the hair thereon, so that it may readily be manipulated by the user to Wind coils of different diameter, depending upon the tension applied. Also, the high degree of compressibility of the body insures the maintenance of the desired tension on the hair that has been wound, even though after winding the hair, some slippage of the hair on the coil member may occur because of failure of the clip or other fastening means to hold the hair against any movement relative to the supporting body. Such advantageous functions can as a practical atent ice matter be attained only when, as noted, the body of foam material is of relatively large diameter as compared with the central reinforcing element which is substantially incompressible.
Core members embodying the structure herein disclosed have been sold and used and are now being sold and used in commercial production quantities and it has been found that in order to secure the beneficial results that are presently to be obtained the outer diameter of the body of foam material should be at least twice that of the relatively stiff and incompressible reinforcing element, and preferably should be at least three or more times the diameter of the reinforcing element, so that the wall thickness of the foam pillow will be at least as great as the diameter of the reinforcing element, as illustrated in FIG. 3.
As previously noted, an important requirement for articles of the kind under consideration is low cost, and accordingly in another of its aspects the invention contemplates the production of such articles by methods and means resulting in a continuous compound extrusion process by virtue of which low costs are achieved through high rates of production with relatively simple apparatus and from substantially entire elimination of waste of the component materials.
For a better understanding of the nature Of the inven tion and the manner in which it may advantageously be carried into effect, reference may best be had to the ensuing portion of this specification in which suitable apparatus and operation thereof for producing articles embodying the inventionare described in conjunction with the accompanying drawings in which:
FIG. 1 is a fragmentary sectional view of extrusion apparatus for producing the desired article.
FIG. 2 is a fragmentary vertical sectional view of extrusion apparatus for producing the desired article and FIG. 3 is a perspective view of a core member for a hair curler or the like formed by a length of the article as extruded from the apparatus shown in FIGS. 1 and 2.
Referring now more particularly to the figures, 10 indicates generally a compound extrusion apparatus embodying a first extruder indicated generally at A and a second extruder indicated generally at B. The specific forms of the extruders may be of any desired known type and by way of diagrammatic illustration, extruder A is shown as being provided with a feed screw 12 for feeding liner material such as polyethylene around the mandrel 14 so as to extrude an annular tube 16 of relatively thin wall section around the mandrel, the tube progressing into the chamber of the extruder B to which latter chamber foam material is fed by means of the feed screw 18. By way of illustration, FIG. 2 shows foam material, produced in the foaming machine diagrammatically illustrated at 20 and fed by means of the feed screw 22 to the feed screw 18 of the extruder B. The feed screws advantageously may be synchronized by means of gears 24 connecting the drive shaft of the screw 22 with the power input shaft 26 constituting the drive shaft for the extruder B. The feed screws 12 and 18 may also be interconnected so that a common source of power may be utilized to drive the entire apparatus.
As will be evident from FIG. 1, the foam material will be extruded in the form of a sheath 28 around the liner 16 and with the foams of polymers such as those enumerated above, which have a relatively short setting time, further treatment following the discharge from extruder B is ordinarily not required. With some materials, a certain amount of curing following extrusion of the foam material may be required, but the specific procedures to be followed will be dictated by the particular material employed, such specific procedures being generally known in the art.
For making articles such as cores for hair curlers and similar articles, frictional contact between the foam material and the liner is sutlicient to hold alone the components against relative axial displacement and for the purpose of making such articles the only step required after the extrusion is ordinarily to cut the extruded material to desired length to produce an article of the kind desired, such as the core for a hair curler indicated generally at 30 in FIG. 3.
As previously noted, the core member such as is shown in FIG. 3, may have an annular liner or a solid liner or core, and either form may advantageously be used in conjunction With retaining members of the kind embodied in the disclosure of U.S. application Serial No. 456,485, filed September 16, 1954, in the names of Carl L. Otto and La Nelle Burnham Otto, now US. Patent No. 2,842,- 140 granted July 8, 1958.
While for purposes of disclosing the invention various examples have been given by Way of illustration, it will be understood that the invention is not to be considered as limited to such examples, but is to be considered as embracing all products falling within the scope of the appended claims.
What is claimed:
1. A core member for a hair curler comprising an elongated circumferentially continuous hollow body of highly compressible elastically resilient foam material and a central hollow reinforcing element of elastically yieldable non-metallic material substantially stiffer than said foam material extending through said body, said reinforcing element being open at both of its ends, said element and said body being substantially coextensive longitudinally and the diameter of said body of foam material being at least a plurality of times the diameter of said reinforcing element, whereby to provide a soft pillow of foam material of bolster-like form the outer circumference of which may easily be materially reduced by the winding of a tress of hair thereon under desired tension to thereby permit coils of hair of difierent diameters to be formed on like core members as desired by the user in accordance with the tension under which the hair is Wound and to insure maintenance of the desired tension of the hair While coiled on said member.
2. An article as defined in claim 1, in which both the body of foam material and the central reinforcing element are tubular in form, and the radial thickness of the wall of said body of foam material is at least as great as the outer diameter of said reinforcing element.
3. An article as defined in claim 1, in which said body of foam material consists of a synthetic polymeric resin.
4. An article as defined in claim 3, in which said central reinforcing element consists of a synthetic thermo plastic material.
5. An article as defined in claim 3, in which said body of foam material is of polyurethane.
6. An article as defined in claim 5, in which said central reinforcing element is of polyethylene.
References Cited in the file of this patent UNITED STATES PATENTS 1,726,359 Martell et al Aug. 27, 1929 1,751,844 Schanz Mar. 25, 1930 1,919,600 Seward July 25, 1933 1,974,924 MacDonald Sept. 25, 1934 2,061,817 Van Cleef Nov. 24, 1936 2,526,311 Wilson Oct. 17, 1960 2,594,348 Rockofi Apr. 29, 1952 2,600,727 Berman et al June 17, 1952 2,602,783 Simon et al. July 8, 1952 2,690,769 Brown Oct. 5, 1954 2,747,585 Allen May 29, 1956 2,759,475 Swaay Aug. 21, 1956 FOREIGN PATENTS 716,422 Great Britain Oct. 6, 1954 OTHER REFERENCES German Plastics Practice, copyright 1946 by Debell and Richardson, pp. 463-465.
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Cited By (29)

* Cited by examiner, † Cited by third party
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US3285795A (en) * 1962-06-18 1966-11-15 Stefan M Stein Heat curable plastic sheets and laminates
US3420725A (en) * 1965-06-23 1969-01-07 Monsanto Co Joining fabric seams with thermoplastic materials
US3420277A (en) * 1964-11-04 1969-01-07 Routiere Et D Entreprise Gener Heat-insulated conduit of utility in the transport of fuels over long distances
US3421551A (en) * 1965-05-21 1969-01-14 Gerald F Currier Destructible article for reserving a recess in concrete
US3461197A (en) * 1963-03-22 1969-08-12 Jerome H Lemelson Method for producing composite articles
US3528458A (en) * 1968-10-07 1970-09-15 Union Carbide Canada Ltd Tubular insulation formed by an extrusion process
US3546325A (en) * 1968-11-19 1970-12-08 Celfil Co Method of manufacturing filter ropes
US3712343A (en) * 1970-12-21 1973-01-23 W Sparks Hand grips
US3806568A (en) * 1970-03-23 1974-04-23 Steel Corp Method of making a variable weight cable
US4143105A (en) * 1976-04-17 1979-03-06 Bayer Aktiengesellschaft Rod for supporting plants and process for its manufacture
US4146562A (en) * 1976-06-22 1979-03-27 Sumitomo Chemical Company, Limited Extrusion coating method with polyolefin foam
US4289716A (en) * 1978-02-16 1981-09-15 Kabel- Und Metallwerke Gutehoffnungshutte A.G. Thermally insulating tubes
US4374079A (en) * 1981-03-04 1983-02-15 Hancor, Inc. Method and apparatus for manufacturing expanded and layered semiround plastic tubings
EP0115288A2 (en) * 1983-01-24 1984-08-08 Henkel Kommanditgesellschaft auf Aktien Curler body and method of manufacture
US4592375A (en) * 1984-01-27 1986-06-03 Beier John K Hair curling roller
US4753841A (en) * 1985-11-19 1988-06-28 Noel, Marquet & Cie. S.A. Air-borne and footstep noise insulating panels of synthetic resin foam for floating plaster floors or floating wooden floors
US4755408A (en) * 1985-11-19 1988-07-05 Noel, Marquet & Cie. S.A. Foam panels and blocks of hollow profiles
US4823458A (en) * 1983-12-21 1989-04-25 Henkel Kommanditgesellschaft Auf Aktien Foam bodied hair curler
US4837060A (en) * 1987-09-22 1989-06-06 Packaging Industries Group, Inc. Tubing plank
US5259112A (en) * 1987-04-30 1993-11-09 Caoutchouc Manufacture Et Plastiques Method of making a connector
US5356132A (en) * 1991-08-21 1994-10-18 Mcewan Charles Versatile playground and flotation device
US5482060A (en) * 1994-08-26 1996-01-09 Barradas; George Hair curler roller
US5557900A (en) * 1995-09-15 1996-09-24 The Shane Group, Inc. Playground structural member using recycled plastic
US6017477A (en) * 1996-07-23 2000-01-25 The Gillette Company Extrusion apparatus and process
US6368000B1 (en) 2000-05-23 2002-04-09 Berol Corporation Writing instrument and method of making same
US20080090707A1 (en) * 2006-07-18 2008-04-17 Dye Kipp K Therapeutic, fitness, and sports enhancement device
US20090131234A1 (en) * 2006-07-18 2009-05-21 Dye Kipp K Therapeutic, fitness, and sports enhancement device
US9345921B2 (en) 2007-07-11 2016-05-24 Performance Solutions, Llc Therapeutic, fitness, and sports enhancement device
US20170173830A1 (en) * 2015-12-18 2017-06-22 Troy Lewis Closed cell foam article and manufacturing method

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US1751844A (en) * 1927-07-11 1930-03-25 Goodrich Co B F Extruding machine
US1919600A (en) * 1932-11-30 1933-07-25 Zotos Corp Hair waving device
US1974924A (en) * 1934-01-20 1934-09-25 Macdonald James Method of and apparatus for waving hair
US2061817A (en) * 1935-04-24 1936-11-24 Cleef Bros Van Hair curler
US2526311A (en) * 1943-09-24 1950-10-17 Ncr Co Porous body
US2594348A (en) * 1947-01-18 1952-04-29 Dayton Rubber Company Rubber covered roll
US2600727A (en) * 1949-08-15 1952-06-17 Jean S Berman Fountain curling rod
US2602783A (en) * 1949-01-14 1952-07-08 Lockheed Aircraft Corp Cellular foamed alkyd-diisocyanate resins
US2690769A (en) * 1950-03-29 1954-10-05 Goodyear Tire & Rubber Laminated structure
GB716422A (en) * 1949-08-11 1954-10-06 Peter Hoppe Synthetic foam-like body and methods of manufacturing the same
US2747585A (en) * 1950-10-06 1956-05-29 Foster D Snell Inc Curling rod for use in the cold permanent waving of hair
US2759475A (en) * 1953-04-17 1956-08-21 Henri Van Swaay Form for making splints and the like

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US1726359A (en) * 1927-06-08 1929-08-27 Western Electric Co Apparatus for applying material to cores
US1751844A (en) * 1927-07-11 1930-03-25 Goodrich Co B F Extruding machine
US1919600A (en) * 1932-11-30 1933-07-25 Zotos Corp Hair waving device
US1974924A (en) * 1934-01-20 1934-09-25 Macdonald James Method of and apparatus for waving hair
US2061817A (en) * 1935-04-24 1936-11-24 Cleef Bros Van Hair curler
US2526311A (en) * 1943-09-24 1950-10-17 Ncr Co Porous body
US2594348A (en) * 1947-01-18 1952-04-29 Dayton Rubber Company Rubber covered roll
US2602783A (en) * 1949-01-14 1952-07-08 Lockheed Aircraft Corp Cellular foamed alkyd-diisocyanate resins
GB716422A (en) * 1949-08-11 1954-10-06 Peter Hoppe Synthetic foam-like body and methods of manufacturing the same
US2600727A (en) * 1949-08-15 1952-06-17 Jean S Berman Fountain curling rod
US2690769A (en) * 1950-03-29 1954-10-05 Goodyear Tire & Rubber Laminated structure
US2747585A (en) * 1950-10-06 1956-05-29 Foster D Snell Inc Curling rod for use in the cold permanent waving of hair
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US3285795A (en) * 1962-06-18 1966-11-15 Stefan M Stein Heat curable plastic sheets and laminates
US3461197A (en) * 1963-03-22 1969-08-12 Jerome H Lemelson Method for producing composite articles
US3420277A (en) * 1964-11-04 1969-01-07 Routiere Et D Entreprise Gener Heat-insulated conduit of utility in the transport of fuels over long distances
US3421551A (en) * 1965-05-21 1969-01-14 Gerald F Currier Destructible article for reserving a recess in concrete
US3420725A (en) * 1965-06-23 1969-01-07 Monsanto Co Joining fabric seams with thermoplastic materials
US3528458A (en) * 1968-10-07 1970-09-15 Union Carbide Canada Ltd Tubular insulation formed by an extrusion process
US3546325A (en) * 1968-11-19 1970-12-08 Celfil Co Method of manufacturing filter ropes
US3806568A (en) * 1970-03-23 1974-04-23 Steel Corp Method of making a variable weight cable
US3712343A (en) * 1970-12-21 1973-01-23 W Sparks Hand grips
US4143105A (en) * 1976-04-17 1979-03-06 Bayer Aktiengesellschaft Rod for supporting plants and process for its manufacture
US4146562A (en) * 1976-06-22 1979-03-27 Sumitomo Chemical Company, Limited Extrusion coating method with polyolefin foam
US4289716A (en) * 1978-02-16 1981-09-15 Kabel- Und Metallwerke Gutehoffnungshutte A.G. Thermally insulating tubes
US4374079A (en) * 1981-03-04 1983-02-15 Hancor, Inc. Method and apparatus for manufacturing expanded and layered semiround plastic tubings
EP0115288A2 (en) * 1983-01-24 1984-08-08 Henkel Kommanditgesellschaft auf Aktien Curler body and method of manufacture
EP0115288A3 (en) * 1983-01-24 1985-11-13 Henkel Kommanditgesellschaft Auf Aktien Curler body and method of manufacture
US4823458A (en) * 1983-12-21 1989-04-25 Henkel Kommanditgesellschaft Auf Aktien Foam bodied hair curler
US4592375A (en) * 1984-01-27 1986-06-03 Beier John K Hair curling roller
US4753841A (en) * 1985-11-19 1988-06-28 Noel, Marquet & Cie. S.A. Air-borne and footstep noise insulating panels of synthetic resin foam for floating plaster floors or floating wooden floors
US4755408A (en) * 1985-11-19 1988-07-05 Noel, Marquet & Cie. S.A. Foam panels and blocks of hollow profiles
US5259112A (en) * 1987-04-30 1993-11-09 Caoutchouc Manufacture Et Plastiques Method of making a connector
US4837060A (en) * 1987-09-22 1989-06-06 Packaging Industries Group, Inc. Tubing plank
US5356132A (en) * 1991-08-21 1994-10-18 Mcewan Charles Versatile playground and flotation device
US5482060A (en) * 1994-08-26 1996-01-09 Barradas; George Hair curler roller
US5557900A (en) * 1995-09-15 1996-09-24 The Shane Group, Inc. Playground structural member using recycled plastic
US6017477A (en) * 1996-07-23 2000-01-25 The Gillette Company Extrusion apparatus and process
US6368000B1 (en) 2000-05-23 2002-04-09 Berol Corporation Writing instrument and method of making same
US8002682B2 (en) 2006-07-18 2011-08-23 Performance Solutions, Llc Therapeutic, fitness, and sports enhancement device
US9656112B2 (en) 2006-07-18 2017-05-23 Performance Solutions, Llc Therapeutic, fitness, and sports enhancement device
US7918774B2 (en) * 2006-07-18 2011-04-05 Performance Solutions, Llc Therapeutic, fitness, and sports enhancement device
US20110105286A1 (en) * 2006-07-18 2011-05-05 Dye Kipp K Therapeutic, fitness, and sports enhancement device
US20080090707A1 (en) * 2006-07-18 2008-04-17 Dye Kipp K Therapeutic, fitness, and sports enhancement device
US12133825B2 (en) 2006-07-18 2024-11-05 Performance Solutions, Llc Therapeutic, fitness, and sports enhancement device
US9539167B2 (en) 2006-07-18 2017-01-10 Performance Solutions, Llc Therapeutic, fitness, and sports enhancement device
US20090131234A1 (en) * 2006-07-18 2009-05-21 Dye Kipp K Therapeutic, fitness, and sports enhancement device
US10695260B2 (en) 2006-07-18 2020-06-30 Performance Solutions, Llc Therapeutic, fitness, and sports enhancement device
US10278890B2 (en) 2006-07-18 2019-05-07 Performance Solutions, Llc Therapeutic, fitness, and sports enhancement device
US10265238B2 (en) 2006-07-18 2019-04-23 Performance Solutions, Llc Therapeutic, fitness, and sports enhancement device
US9345921B2 (en) 2007-07-11 2016-05-24 Performance Solutions, Llc Therapeutic, fitness, and sports enhancement device
US10207437B2 (en) * 2015-12-18 2019-02-19 Troy Lewis Closed cell foam article and manufacturing method
US20170173830A1 (en) * 2015-12-18 2017-06-22 Troy Lewis Closed cell foam article and manufacturing method

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