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US2952450A - In situ exploitation of lignite using steam - Google Patents

In situ exploitation of lignite using steam Download PDF

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US2952450A
US2952450A US809931A US80993159A US2952450A US 2952450 A US2952450 A US 2952450A US 809931 A US809931 A US 809931A US 80993159 A US80993159 A US 80993159A US 2952450 A US2952450 A US 2952450A
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stratum
well
steam
lignite
wells
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Purre Heino
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Phillips Petroleum Co
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
    • E21B43/2405Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection in association with fracturing or crevice forming processes
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/25Methods for stimulating production
    • E21B43/26Methods for stimulating production by forming crevices or fractures
    • E21B43/2605Methods for stimulating production by forming crevices or fractures using gas or liquefied gas

Definitions

  • This invention relates to a process for recovery of hydrocarbon material from lignite strata by in situ methods.
  • In situ combustion techniques are being applied to tar sands, shale, Athabasca sand and other strata in virgin state, to coal veins by fracturing, and to strata partially depleted by primary and even secondary and tertiary recbvery methods.
  • This invention is concerned with a process for producing lignite strata which renders the lignite more permeable and simultaneously produces hydrocarbons therefrom before subjecting the same to in situ combustion.
  • an object of the invention to provide an improved process for producing hydrocarbon material from lignite strata.
  • Another object of the invention is to provide a process which raises the permeability of a lignite stratum and simultaneously produces hydrocarbqnmaten'al therefrom.
  • a further object is to increase the rate of production of a lignite stratum by in situ combustion.
  • a broad aspect of the invention comprises injecting saturated steam into a lignite stratum thru a well therein at sufficient pressure to fracture the stratum, continuing the injection of steam so as to heat a substantial annulus around the well to a temperature above vaporization temperature of water in the stratum at normal stratum pressure, suddenly releasing the steam pressure in the Well so as to cause shattering of the stratum by flash vaporization of liquid therein, whereby hydrocarbon material released by the heating of the annulus flows into the well, and recovering the hydrocarbons so released.
  • the sudden releasing of the steam pressure causes flash vaporization of condensed steam, connate water, and light hydrocarbon liquids and this sudden expansion and vaporization of these liquids shatters the lignite stratum, simultaneously producing chips and granules of lignite, some of which are produced in the well bore from which they are recovered by conventional means.
  • the recovered lignite chips and granules may be steam distilled above ground to recover valuable hydrocarbon material therefrom.
  • the shattering of the lignite around the borehole enlarges the same considerably upon each heating and pressure release step so that by repeating the steam injection (heating) and pressure release steps a large injection cavity in the wellbore at the level of the stratum is produced which greatly increases the steam injection area and hastens the steam injection and heating process with a given steam pressure.
  • a preferred embodiment of the invention comprises applying the process just described to a pair of spaced apart wells, a central well in a ring-type pattern and in the wells of the ring, and in wells in two parallel lines of wells for a line-drive process.
  • the spacedapart wells are subjected to steam injection pressure, heating and flash vaporization and release of pressure with attendant shattering and production of distilled hydrocarbon material.
  • the wells in the pattern utilized are positioned within fracturing distance from each other and fracturing is .efiected thru each of the wells so as to open up a steam passageway between wells.
  • This technique permits venting one of the wells or one set of wells while injecting high temperature and high pressure steam thru the other well or set of wells so as: to extend the heated volume of stratum between the wells, while distilling hydrocarbon material therefrom and rendering the same substantially more permeable.
  • the remaining lignite around one well or set of wells is ignited by con ventional means, such as by burning a fuel pack of char: coal or other solid fuel aggregates therein so as to heat the surrounding lignite to combustion-supporting temperature, and then contacting the hot lignite with combustion-supporting gas, such as air or air containing fuel gas in a concentration of about 1 to 3 volume percent.
  • combustion-supporting gas such as air or air containing fuel gas in a concentration of about 1 to 3 volume percent.
  • the resulting combustion front is moved toward the other well or set of wells by direct drive by means of air injected thru the ignition wells or by inverse drive by means of air injected thru the wells opposite the ignition wells.
  • direct drive produced gases are recovered thru the wells opposite the ignition wells and when utilizin'g inverse drive produced gases are recovered thru the ignition wells.
  • the lignite stratum may be produced by intermittently pressuring the stratum with steam, releasing the pressure, removing the debris from the well and continuing the operation. -In this manner a cavern Patented Sept. 13, 1960 of considerable size is produced around a well. The recovered lignite particles are then subjected to distillation above ground. In this manner the process provides a means for producing a. lignite stratum without a mine shaft and the equipment associated with recovery by this means.
  • the steam injection temperature. to be used is at least 400 F. and preferably in the'range of about 500 to 750 F.; and the pressure is in the range of 150 to 700 p.s.i.g. or higher, where greater fracturing pressures are re quired. Dry, greater heating is effected before condensation takes place. Heating an annulus of at least about 3 feet in radius adjacent the steam injection borehole to a temperature of at least 300 F. is snfiicient to obtain the benefits of the invention but heating to a greater distance from the hole and to a. higher temperature may be practiced to advantage before releasing the borehole presure. The second and successive heating and pressure release steps drive the heated zone farther into the stra tum. Downhole heating by means of downhole heaters may be used to reduce condensation in the borehole and in theadjacent stratum either before or during steam injection.
  • a lignite stratum is. disposed between overburden 12 and substratum 14.
  • a well 16 passes thru stratum l0 and is cased by casing 18 substantially to the upper level of the lignite.
  • Well 16 is also provided with a tubing string 20 extending thru well head 22 and a production line 24.
  • Fractures 26 and 28 are produced by injecting steam thru tubing 20 from any suitable source until the pressure within the stratum is sufficient to effect the fracturing. Fracturing at selected levels may be effected by conventional tech niques in oil field production.
  • steam is injected under pressure thru the resulting fractures into the lignite surrounding well 16 under pressure until a substantial section or annulus of the stratum is heated to at least 400 F.
  • pressure in the well and in the adjacent stratum. is suddenly released, as by opening the valve in line 24, so that shattering of the stratum is effected by flash vaporization of liquid therein.
  • the hydrocarbons produced by the heating and vaporization are then produced from the well in conventional manner.
  • a process for recoveringhydrocarbons from a subterranean lignite stratum which comprises injecting steam at a temperature of at least 400 F. into said stratum thru a well therein at suflicient pressure to fracture said stratum; continuing steam injection until a substantial annulus around said well is heated to substantially the steam temperature; thereafter, suddenly releasing the steam pressure in said well whereby shattering of said stratum is effected by flash vaporizing of liquid therein superheated steam is preferred since and hydrocarbons released by the heating of said annulus flow into said well; and recovering said hydrocarbons from said well.
  • a process for recovering hydrocarbons from a subterranean lignite stratum which comprises injecting steam at a temperature of at least 400 F. into said stratumthru a first well therein at sufficient pressure to fracture said stratum; continuing steam injection until a substantial annulus surrounding said first well is heated to a temperature of at least 300 F. and hydrocarbons are driven from said annulus, leaving same porous; thereafter, suddenly releasing the steam pressure in said well whereby shattering of said stratum is effected by flash vaporization of liquid in the porous stratum; performing the foregoing. steps in a second well in said stratum spaced at. least 10' feet from and sufliciently close to said first well that re-.
  • sulting fractures between the wells form a passageway for gases; shutting in said first well after steam-begins to flow from said second to said first well so as to permit build up of pressure and additional heating of said straturn around said second, well; thereafter, venting one of 7 said wells and injecting steam in the other so as to release ing and steam injection step.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Mining & Mineral Resources (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Description

Sept.- 13, 1960 H. PURRE 2,952,450 I IN SITU EXPLOITATION OF LIGNITE USING STEAM Filed April 30, 1959 H SUBSTRATUM INVENTOR. HE INO PU RR E A T TORNLT'KS United States Patent IN SITU EXPLOITATION OF LIGNITE USING STEAM lieino Purre, Bartlesville, Okla, assignor to Phillips Petroleum Company, a corporation of Delaware Filed Apr. 30, 1959, Ser. No. 809,931
Claims. (Cl. 262--3) This invention relates to a process for recovery of hydrocarbon material from lignite strata by in situ methods.
'In situ combustion in the recovery of hydrocarbons from underground strata containing carbonaceous material is becoming more prevalent in the petroleum industry. In this technique of production, combustion is initiated in the carbonaceous stratum and the resulting combustion zone is caused to move thru the stratum by either inverse or direct air drive whereby the heat of combustion of a substantial proportion of the hydrocarbon in the stratum drives out and usually upgrades a substantial proportion of the unburned hydrocarbon material.
, The ignition of carbonaceous material in a stratum around a borehole therein followed by injection of air thru the igition borehole and recovery of product hydrocarbons and combustion gas thru another borehole in the stratum is a direct air drive process for efiiecting in situ combustion and recovery of hydrocarbons from the stratum. 'In this type of operation the stratum usually plugs in front of the combustion zone because a heavy viscous liquid bank of hydrocarbon collects in the stratum in advance of the combustion zone which prevents movement of air to the combustion process. To overcome this difliculty and to permit the continued progress of the combustion zone thru the stratum, inverse air injection has been resorted to. By this technique, a combustion zone is established around an ignition borehole by any suitable means and air is fed thru the stratum to the combustion zone from one or more surrounding boreholes.
In situ combustion techniques are being applied to tar sands, shale, Athabasca sand and other strata in virgin state, to coal veins by fracturing, and to strata partially depleted by primary and even secondary and tertiary recbvery methods.
Attempts have been made to produce lignite by in situ combustion but the permeability of the average lignite stratum is so low that production by in situ combustion is particularly difficult and impractical. This invention is concerned with a process for producing lignite strata which renders the lignite more permeable and simultaneously produces hydrocarbons therefrom before subjecting the same to in situ combustion.
Accordingly, it is an object of the invention to provide an improved process for producing hydrocarbon material from lignite strata. Another object of the invention is to provide a process which raises the permeability of a lignite stratum and simultaneously produces hydrocarbqnmaten'al therefrom. A further object is to increase the rate of production of a lignite stratum by in situ combustion. Other objects of the invention will become apparent upon consideration of the accompanying disclosure.
A broad aspect of the invention comprises injecting saturated steam into a lignite stratum thru a well therein at sufficient pressure to fracture the stratum, continuing the injection of steam so as to heat a substantial annulus around the well to a temperature above vaporization temperature of water in the stratum at normal stratum pressure, suddenly releasing the steam pressure in the Well so as to cause shattering of the stratum by flash vaporization of liquid therein, whereby hydrocarbon material released by the heating of the annulus flows into the well, and recovering the hydrocarbons so released. The sudden releasing of the steam pressure causes flash vaporization of condensed steam, connate water, and light hydrocarbon liquids and this sudden expansion and vaporization of these liquids shatters the lignite stratum, simultaneously producing chips and granules of lignite, some of which are produced in the well bore from which they are recovered by conventional means. The recovered lignite chips and granules may be steam distilled above ground to recover valuable hydrocarbon material therefrom.
The shattering of the lignite around the borehole enlarges the same considerably upon each heating and pressure release step so that by repeating the steam injection (heating) and pressure release steps a large injection cavity in the wellbore at the level of the stratum is produced which greatly increases the steam injection area and hastens the steam injection and heating process with a given steam pressure.
A preferred embodiment of the invention comprises applying the process just described to a pair of spaced apart wells, a central well in a ring-type pattern and in the wells of the ring, and in wells in two parallel lines of wells for a line-drive process. In this maner the spacedapart wells are subjected to steam injection pressure, heating and flash vaporization and release of pressure with attendant shattering and production of distilled hydrocarbon material. The wells in the pattern utilized are positioned within fracturing distance from each other and fracturing is .efiected thru each of the wells so as to open up a steam passageway between wells. This technique permits venting one of the wells or one set of wells while injecting high temperature and high pressure steam thru the other well or set of wells so as: to extend the heated volume of stratum between the wells, while distilling hydrocarbon material therefrom and rendering the same substantially more permeable.
After increasing the permeability of a large section of stratum between the wells or sets of wells, the remaining lignite around one well or set of wells is ignited by con ventional means, such as by burning a fuel pack of char: coal or other solid fuel aggregates therein so as to heat the surrounding lignite to combustion-supporting temperature, and then contacting the hot lignite with combustion-supporting gas, such as air or air containing fuel gas in a concentration of about 1 to 3 volume percent. The fuel addition .is essential when initiating combustion in the lignite by injection of the combustion-supporting gas in the injection wells to cause flow to the hot area at the ignition wells. After ignition of the stratum, the resulting combustion front is moved toward the other well or set of wells by direct drive by means of air injected thru the ignition wells or by inverse drive by means of air injected thru the wells opposite the ignition wells. When utilizing direct drive, produced gases are recovered thru the wells opposite the ignition wells and when utilizin'g inverse drive produced gases are recovered thru the ignition wells.
It is not necessary to remove the shattered lignite from the well in order to produce the lignite in accordance with the invention since the lignite chips, granules, etc., form a very permeable bed in the well cavity adjacent the stratum. However, the lignite stratum may be produced by intermittently pressuring the stratum with steam, releasing the pressure, removing the debris from the well and continuing the operation. -In this manner a cavern Patented Sept. 13, 1960 of considerable size is produced around a well. The recovered lignite particles are then subjected to distillation above ground. In this manner the process provides a means for producing a. lignite stratum without a mine shaft and the equipment associated with recovery by this means.
I The steam injection temperature. to be used is at least 400 F. and preferably in the'range of about 500 to 750 F.; and the pressure is in the range of 150 to 700 p.s.i.g. or higher, where greater fracturing pressures are re quired. Dry, greater heating is effected before condensation takes place. Heating an annulus of at least about 3 feet in radius adjacent the steam injection borehole to a temperature of at least 300 F. is snfiicient to obtain the benefits of the invention but heating to a greater distance from the hole and to a. higher temperature may be practiced to advantage before releasing the borehole presure. The second and successive heating and pressure release steps drive the heated zone farther into the stra tum. Downhole heating by means of downhole heaters may be used to reduce condensation in the borehole and in theadjacent stratum either before or during steam injection.
In-order to illustrate the invention, reference may be had to the drawing which is a schematic elevation thru a lignite stratum in which a producing well is disposed.
Referring to the drawing, a lignite stratum is. disposed between overburden 12 and substratum 14. A well 16 passes thru stratum l0 and is cased by casing 18 substantially to the upper level of the lignite. Well 16 is also provided with a tubing string 20 extending thru well head 22 and a production line 24. Fractures 26 and 28 are produced by injecting steam thru tubing 20 from any suitable source until the pressure within the stratum is sufficient to effect the fracturing. Fracturing at selected levels may be effected by conventional tech niques in oil field production.
aIn accordance with the foregoing disclosure, steam is injected under pressure thru the resulting fractures into the lignite surrounding well 16 under pressure until a substantial section or annulus of the stratum is heated to at least 400 F. When this has been accomplished, pressure in the well and in the adjacent stratum. is suddenly released, as by opening the valve in line 24, so that shattering of the stratum is effected by flash vaporization of liquid therein. The hydrocarbons produced by the heating and vaporization are then produced from the well in conventional manner.
.When utilizing a plurality of wells, as described hereinbefore, fracturing between wells is effected in similar manner which is then followed by heating with steam and flash vaporization.
Certain modifications of the invention will become apparent to those skilled in the art and the. illustrative details disclosed are not to be construed as imposing unnecessary limitations on the invention;
1 claim:
1. A process for recoveringhydrocarbons from a subterranean lignite stratum which comprises injecting steam at a temperature of at least 400 F. into said stratum thru a well therein at suflicient pressure to fracture said stratum; continuing steam injection until a substantial annulus around said well is heated to substantially the steam temperature; thereafter, suddenly releasing the steam pressure in said well whereby shattering of said stratum is effected by flash vaporizing of liquid therein superheated steam is preferred since and hydrocarbons released by the heating of said annulus flow into said well; and recovering said hydrocarbons from said well.
2. The process of claim 1 wherein the steps of steam. injection, heating, and pressure releasing are repeated.
3. The process of claim 1 wherein said shattering produces chips and granules of lignite and same are recovered from said well and steam distilled to recover hydrocarbon material therefrom.
4. A process for recovering hydrocarbons from a subterranean lignite stratum which comprises injecting steam at a temperature of at least 400 F. into said stratumthru a first well therein at sufficient pressure to fracture said stratum; continuing steam injection until a substantial annulus surrounding said first well is heated to a temperature of at least 300 F. and hydrocarbons are driven from said annulus, leaving same porous; thereafter, suddenly releasing the steam pressure in said well whereby shattering of said stratum is effected by flash vaporization of liquid in the porous stratum; performing the foregoing. steps in a second well in said stratum spaced at. least 10' feet from and sufliciently close to said first well that re-.
sulting fractures between the wells form a passageway for gases; shutting in said first well after steam-begins to flow from said second to said first well so as to permit build up of pressure and additional heating of said straturn around said second, well; thereafter, venting one of 7 said wells and injecting steam in the other so as to release ing and steam injection step.
7. The process of claim 4 wherein said first well is in a first line of wells and the other wells in said first, line. are treated in the same manner; said second well is in a second line of wells generally parallel with said first line of wells and the other wells in said second line are treated in the same manner; and steam is passed from the wells in one line to the wells in the other line.
8. The process of claim 4 including continuingthe venting and steam injection until a substantial section ofsaid stratum between said wells is produced. sufliciently to render same permeable; igniting the remaining lig'n'ite around one of said wells; passing combustion-supporting gas to the resulting combustion zone thru one of said wells so as to move said zone thru said stratum toward the other well; and recovering produced hydrocarbons from one of said wells.
9. The process of claim 8 wherein said combustionsupporting gas is passed thru the well other than the ignited well to cause the combustion zone to move countercurrently to the gas and produced gases. are recovered thru the ignition well.
10. The process of claim 8 wherein said combustion supporting gas is passed thru the ignited welland produced gases are recovered thru the other well.
References Cited in the file of this patentv FOREIGN PATENTS 716,620 Great Britain u Oct. 13,1954

Claims (1)

1. A PROCESS FOR RECOVERING HYDROCARBONS FROM A SUBTERRANEAN LIGNITE STRATUM WHICH COMPRISES INJECTING STREAM AT A TEMPERATURE OF AT LEAST 400*F. INTO SAID STRATUM THRU A WELL THEREIN AT SUFFICIENT PRESSURE TO FRACTURE SAID STRATUM, CONTINUING STEAM INJECTION UNTIL A SUBSTANTIAL ANNULUS AROUND SAID WELL IS HEATED TO SUBSTANTIALLY THE STEAM TEMPERATURE, THEREAFTER, SUDDENLY RELEASING THE STEAM PRESSURE IN SAID WELL WHEREBY SHATTERING OF SAID STRATUM IS EFFECTED BY FLASH VAPORIZING OF LIQUID THEREIN AND HYDROCARBONS RELEASED BY THE HEATING OF SAID ANNULUS FLOW INTO SAID WELL, AND RECOVERING SAID HYDROCARBONS FROM SAID WELL.
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Cited By (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3034580A (en) * 1959-08-31 1962-05-15 Phillips Petroleum Co In situ combustion of lignite
US3284281A (en) * 1964-08-31 1966-11-08 Phillips Petroleum Co Production of oil from oil shale through fractures
US3330353A (en) * 1964-09-22 1967-07-11 Shell Oil Co Thermal soak zones by fluidized fractures in unconsolidated, petroleum producing reservoirs
US3379246A (en) * 1967-08-24 1968-04-23 Mobil Oil Corp Thermal method for producing heavy oil
US3455383A (en) * 1968-04-24 1969-07-15 Shell Oil Co Method of producing fluidized material from a subterranean formation
US4328995A (en) * 1980-04-25 1982-05-11 Phillips Petroleum Company Production of lignite from underground deposits
US5072990A (en) * 1990-07-12 1991-12-17 Mobil Oil Corporation Acceleration of hydrocarbon gas production from coal beds
US20070023186A1 (en) * 2003-11-03 2007-02-01 Kaminsky Robert D Hydrocarbon recovery from impermeable oil shales
US20080087426A1 (en) * 2006-10-13 2008-04-17 Kaminsky Robert D Method of developing a subsurface freeze zone using formation fractures
US20080087420A1 (en) * 2006-10-13 2008-04-17 Kaminsky Robert D Optimized well spacing for in situ shale oil development
US20080207970A1 (en) * 2006-10-13 2008-08-28 Meurer William P Heating an organic-rich rock formation in situ to produce products with improved properties
US20080230219A1 (en) * 2007-03-22 2008-09-25 Kaminsky Robert D Resistive heater for in situ formation heating
US20080271885A1 (en) * 2007-03-22 2008-11-06 Kaminsky Robert D Granular electrical connections for in situ formation heating
US20080290719A1 (en) * 2007-05-25 2008-11-27 Kaminsky Robert D Process for producing Hydrocarbon fluids combining in situ heating, a power plant and a gas plant
EP2098683A1 (en) 2008-03-04 2009-09-09 ExxonMobil Upstream Research Company Optimization of untreated oil shale geometry to control subsidence
US7631691B2 (en) 2003-06-24 2009-12-15 Exxonmobil Upstream Research Company Methods of treating a subterranean formation to convert organic matter into producible hydrocarbons
US7669657B2 (en) 2006-10-13 2010-03-02 Exxonmobil Upstream Research Company Enhanced shale oil production by in situ heating using hydraulically fractured producing wells
US20100282460A1 (en) * 2009-05-05 2010-11-11 Stone Matthew T Converting Organic Matter From A Subterranean Formation Into Producible Hydrocarbons By Controlling Production Operations Based On Availability Of One Or More Production Resources
US8082995B2 (en) 2007-12-10 2011-12-27 Exxonmobil Upstream Research Company Optimization of untreated oil shale geometry to control subsidence
US8122955B2 (en) 2007-05-15 2012-02-28 Exxonmobil Upstream Research Company Downhole burners for in situ conversion of organic-rich rock formations
US8146664B2 (en) 2007-05-25 2012-04-03 Exxonmobil Upstream Research Company Utilization of low BTU gas generated during in situ heating of organic-rich rock
US8151877B2 (en) 2007-05-15 2012-04-10 Exxonmobil Upstream Research Company Downhole burner wells for in situ conversion of organic-rich rock formations
US8151884B2 (en) 2006-10-13 2012-04-10 Exxonmobil Upstream Research Company Combined development of oil shale by in situ heating with a deeper hydrocarbon resource
US8230929B2 (en) 2008-05-23 2012-07-31 Exxonmobil Upstream Research Company Methods of producing hydrocarbons for substantially constant composition gas generation
US8616280B2 (en) 2010-08-30 2013-12-31 Exxonmobil Upstream Research Company Wellbore mechanical integrity for in situ pyrolysis
US8616279B2 (en) 2009-02-23 2013-12-31 Exxonmobil Upstream Research Company Water treatment following shale oil production by in situ heating
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US8641150B2 (en) 2006-04-21 2014-02-04 Exxonmobil Upstream Research Company In situ co-development of oil shale with mineral recovery
US8770284B2 (en) 2012-05-04 2014-07-08 Exxonmobil Upstream Research Company Systems and methods of detecting an intersection between a wellbore and a subterranean structure that includes a marker material
US8863839B2 (en) 2009-12-17 2014-10-21 Exxonmobil Upstream Research Company Enhanced convection for in situ pyrolysis of organic-rich rock formations
US9080441B2 (en) 2011-11-04 2015-07-14 Exxonmobil Upstream Research Company Multiple electrical connections to optimize heating for in situ pyrolysis
US9394772B2 (en) 2013-11-07 2016-07-19 Exxonmobil Upstream Research Company Systems and methods for in situ resistive heating of organic matter in a subterranean formation
US9512699B2 (en) 2013-10-22 2016-12-06 Exxonmobil Upstream Research Company Systems and methods for regulating an in situ pyrolysis process
US9644466B2 (en) 2014-11-21 2017-05-09 Exxonmobil Upstream Research Company Method of recovering hydrocarbons within a subsurface formation using electric current

Citations (1)

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GB716620A (en) * 1951-08-30 1954-10-13 Mini Of Fuel And Power Improvements relating to the underground gasification of coal

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB716620A (en) * 1951-08-30 1954-10-13 Mini Of Fuel And Power Improvements relating to the underground gasification of coal

Cited By (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3034580A (en) * 1959-08-31 1962-05-15 Phillips Petroleum Co In situ combustion of lignite
US3284281A (en) * 1964-08-31 1966-11-08 Phillips Petroleum Co Production of oil from oil shale through fractures
US3330353A (en) * 1964-09-22 1967-07-11 Shell Oil Co Thermal soak zones by fluidized fractures in unconsolidated, petroleum producing reservoirs
US3379246A (en) * 1967-08-24 1968-04-23 Mobil Oil Corp Thermal method for producing heavy oil
US3455383A (en) * 1968-04-24 1969-07-15 Shell Oil Co Method of producing fluidized material from a subterranean formation
US4328995A (en) * 1980-04-25 1982-05-11 Phillips Petroleum Company Production of lignite from underground deposits
US5072990A (en) * 1990-07-12 1991-12-17 Mobil Oil Corporation Acceleration of hydrocarbon gas production from coal beds
US20100078169A1 (en) * 2003-06-24 2010-04-01 Symington William A Methods of Treating Suberranean Formation To Convert Organic Matter Into Producible Hydrocarbons
US7631691B2 (en) 2003-06-24 2009-12-15 Exxonmobil Upstream Research Company Methods of treating a subterranean formation to convert organic matter into producible hydrocarbons
US8596355B2 (en) 2003-06-24 2013-12-03 Exxonmobil Upstream Research Company Optimized well spacing for in situ shale oil development
US7441603B2 (en) 2003-11-03 2008-10-28 Exxonmobil Upstream Research Company Hydrocarbon recovery from impermeable oil shales
US20090038795A1 (en) * 2003-11-03 2009-02-12 Kaminsky Robert D Hydrocarbon Recovery From Impermeable Oil Shales Using Sets of Fluid-Heated Fractures
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