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US2489456A - Method of applying uniform coating by immersion - Google Patents

Method of applying uniform coating by immersion Download PDF

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Publication number
US2489456A
US2489456A US611885A US61188545A US2489456A US 2489456 A US2489456 A US 2489456A US 611885 A US611885 A US 611885A US 61188545 A US61188545 A US 61188545A US 2489456 A US2489456 A US 2489456A
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Prior art keywords
coating
composition
coated
bath
immersion
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US611885A
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Robert A Liebel
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/18Processes for applying liquids or other fluent materials performed by dipping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C3/00Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material
    • B05C3/02Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material
    • B05C3/04Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material with special provision for agitating the work or the liquid or other fluent material
    • B05C3/05Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material with special provision for agitating the work or the liquid or other fluent material by applying vibrations thereto
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C3/00Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material
    • B05C3/02Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material
    • B05C3/12Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material for treating work of indefinite length
    • B05C3/125Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material for treating work of indefinite length the work being a web, band, strip or the like
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14Removing excess of molten coatings; Controlling or regulating the coating thickness
    • C23C2/22Removing excess of molten coatings; Controlling or regulating the coating thickness by rubbing, e.g. using knives, e.g. rubbing solids

Definitions

  • This invention relates to a method and apparatus for applying a coating composition.
  • the material to be coated is immersed in an enamel or other liquid coating composition and then withdrawn through the upper exposed surface of the composition.
  • the film of fiowable liquid so applied is then hardened, as by evaporation of diluting solvent initially present in the composition, by polymerization or oxidation of the film forming material, or in some cases by cooling a composition originally softened by heat.
  • the coating composition is non-metallic and consequently of relatively low density, as
  • the invention comprises main-; taining the surface of the coating bath at a constantly fluctuating level and constantly changing slope where the object being coated emerges from the bath.
  • the invention com-. I prises causing the bath of fluctuating level also 1 to be in continuous motion laterally with respect to the surface of the object being coated.
  • the invention comprises the use of coating compositions of abnormally low viscosity as compared to those which have been with thin zones of the coating composition," ap-H pearing as striations upon the surface of the object being coated.
  • composition at levels on the object to which the surface momentarily adhered.
  • Included within the invention is the herein de-- scribed apparatus for causing the continually fluctuating level of upper surface of the coating.
  • I obtain a substantially uniform thickness of coat-I ing upon an object.
  • heat may be applied as by i electrical strip heaters to the coated object immediately after withdrawal from the coating bath, so that the elevation of temperature causes reduction of viscosity of the coating composition and promotes flow in the exposed surface of the composition. This feature is also included as part of the present invention.
  • Fig. 1 is a plan view partly in section of my improved apparatus.
  • Fig. 2 is an end view in section of the apparatus, the view being on line 2-2 of Fig. 1.
  • Fig. 3 is a sectional view on line 3-3 of Fig. 2.- The views are partly diagrammatic. Parts not shown or described in detail are conventional 1 when considered. individually.
  • container III for the coating bath l2.
  • the object to be coated such as the strip of flexible steel 14 is passed over guide rollerjlli into the bath and over the second guide roller 18.-- It is then withdrawn and passed between heaters 20.
  • the means for moving the strip are conventional andnot shown.
  • Disposed on opposite sides of the sheet l4 means for setting up waves of desired frequency are in the surface portions of the coating composition I2.
  • these wave-making agitators are parallel screws 22. One of them is driven by a usual type of motor and belt drive indicated at 26 and the other through gears 24.
  • the wavy surface of the coating bath is indicated generally at 28 in Fig. 3.
  • the flexible metal sheet I4 is passed through the coating composition, and withdrawn continuously through the upper surface of the composition.
  • the coating composition is one which is hardenable by heat
  • the coated object may be passed through a usual type of heated chamber (not shown) of proper temperature and size to cause evaporation of some volatile solvent, polymerization, or whatever change is required to cause setting of the film of coating composition to hard, durable condition.
  • the level of the bath which washes the surface of the object as withdrawn is caused to fluctuate constantly as by the setting up of waves or ripples at the surface by means of the agitators 22. Care is required in the design of the agitators and their method of opera tion to avoid introducing'air bubbles.
  • the agitators should be of kind to give an adequate wave effect without churning in air.
  • the fluctuation of the level of the coating com- I position prevents the level from becoming associated for any appreciable time with any particular spot on the article being withdrawn.
  • heat may be applied as by passing the coated object, at a level just above that of emergence from the bath, as between electrical heaters shown in the drawing at 2B.
  • These heaters cause a rise in temperature and a decrease in viscosity of the adhering coating solution. They promote run back of coating material. Also the heaters exert a maximum effect upon the surface of the coating film and thus make this the least viscous part of the film, so as to cause smoothin of the film surface.
  • compositions as used may be diluted, with-any conventional solvent or thinner for the selected composition, ,to the range of viscosities described.
  • solvents that may be used are toluene, naphtha, The solvents seturpentine, and butyl acetate. lected should be those that are compatible with the finishing compositions selected.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Description

Nov. 29, 1949 R. A. LIEBEL 6 METHOD OF APPLYING UNIFORM comma BY IMMERSION Filed Aug. 21, 1945 2a 1 H 22 I i i-E-E 2-; 14
' I INVENTOR F019? 14. [iefiel HTTORNEY Patented Nov. 29, 1949 UNITED STATES PIA-TENT orrlcs METHOD OF APPLYING UNIFORM COATING BY IMMI'JRSION Robert A. Liebel, Allentown, Pa.
Application August 21, 1945, Serial No. 611,885
2 Claims.
This invention relates to a method and apparatus for applying a coating composition.
In a common method of coating metal sheets, plates, and wire, for instance, the material to be coated is immersed in an enamel or other liquid coating composition and then withdrawn through the upper exposed surface of the composition.
The film of fiowable liquid so applied is then hardened, as by evaporation of diluting solvent initially present in the composition, by polymerization or oxidation of the film forming material, or in some cases by cooling a composition originally softened by heat.
When the coating composition is non-metallic and consequently of relatively low density, as
compared to galvanizing or most metal coatings,
special problems arise. One of these is the formation of nodes or overly thick bands alternating Briefly stated, the invention comprises main-; taining the surface of the coating bath at a constantly fluctuating level and constantly changing slope where the object being coated emerges from the bath. In one embodiment, the invention com-. I prises causing the bath of fluctuating level also 1 to be in continuous motion laterally with respect to the surface of the object being coated. In the preferred embodiment, the invention comprises the use of coating compositions of abnormally low viscosity as compared to those which have been with thin zones of the coating composition," ap-H pearing as striations upon the surface of the object being coated. When, for example, a metal sheet emerges from an enameling bath of the oleoresin type, the enamel alternately clings to and releases itself from the sheet.. The level of the liquid at the position of emergence is raised momentarily, then gives way, only to rise again in a moment, and then sink. This repeated alternation of lifting and sinking of the surface gives thickened bands or nodes of the coating:
composition at levels on the object to which the surface momentarily adhered.
This problem of the unevenness of coatingsso applied has been recognized for a long time. Various means have been proposed to correct the Sheets are sometimes economical method of applying a coating that is of the desired thickness in all areas without ob jectionable thickness in any zone. The invention I thusavoids unevenness and unnecessary consumption oi coating material.
used heretofore in coating objects by immersion; and withdrawal from baths of like coating material.
Included within the invention is the herein de-- scribed apparatus for causing the continually fluctuating level of upper surface of the coating.
bath.
Using the method and apparatus described, I obtain a substantially uniform thickness of coat-I ing upon an object. When it is desired to smooth additionally the surface of the applied fllm of coating composition, heat may be applied as by i electrical strip heaters to the coated object immediately after withdrawal from the coating bath, so that the elevation of temperature causes reduction of viscosity of the coating composition and promotes flow in the exposed surface of the composition. This feature is also included as part of the present invention.
The invention will be illustrated in greater detail by description in connection with the at-' tached drawing to which reference is made.
Fig. 1 is a plan view partly in section of my improved apparatus.
' Fig. 2 is an end view in section of the apparatus, the view being on line 2-2 of Fig. 1.
Fig. 3 is a sectional view on line 3-3 of Fig. 2.- The views are partly diagrammatic. Parts not shown or described in detail are conventional 1 when considered. individually.
There are shown container III for the coating bath l2. The object to be coated such as the strip of flexible steel 14 is passed over guide rollerjlli into the bath and over the second guide roller 18.-- It is then withdrawn and passed between heaters 20.
The means for moving the strip are conventional andnot shown. Disposed on opposite sides of the sheet l4 means for setting up waves of desired frequency are in the surface portions of the coating composition I2. In the illustrative form shown, these wave-making agitators are parallel screws 22. One of them is driven by a usual type of motor and belt drive indicated at 26 and the other through gears 24. The wavy surface of the coating bath is indicated generally at 28 in Fig. 3.
The flexible metal sheet I4 is passed through the coating composition, and withdrawn continuously through the upper surface of the composition. When the coating composition is one which is hardenable by heat, the coated object may be passed through a usual type of heated chamber (not shown) of proper temperature and size to cause evaporation of some volatile solvent, polymerization, or whatever change is required to cause setting of the film of coating composition to hard, durable condition.
As the object is withdrawn from the coating bath, the level of the bath which washes the surface of the object as withdrawn is caused to fluctuate constantly as by the setting up of waves or ripples at the surface by means of the agitators 22. Care is required in the design of the agitators and their method of opera tion to avoid introducing'air bubbles. The agitators should be of kind to give an adequate wave effect without churning in air.
I have used to advantage fluctuations of the surface level of frequency 20 or more a minute for speeds of movement of'the sheet it up to 300 linear feet a minute. Satisfactory resultswith most objects beingcoated are obtained when the rate of fluctuation of the surface level is made at or more per minute and preferably at least 20 to 140 for speeds of movement of the sheet 14 up to 560 linear feet a minute, fluctuations being figured as complete cycles from the crest of one wave to the crest of the succeeding wave.
At the frequency of 10 fluctuation-s for 500 feet of movement of the sheet, this is a ratio of l fluctuation from crest to crest of the wave for each 50 feet of emergence'of the'sheet. When it is considered that the depth :of the ripples or waves 'is ordinarily about 4; inch from top to bottom of the wave or within the range of A to 1 inch, it will be noted that the recoating effect, due to the washin of the enamel composition up and down on the surface of the sheet being coated, is a relatively minor influence. It is considered that a major part of the effect is due to the irregularity'of surface of the top oi. the enameling composition. There-is a constantly changing slope of surface of the enamel bath, that is, there is a continual change in the angle which-the surface of the bath at any point-- makes with the horizontal; As a result of this, there is at no time an appreciable extent of level surface of the composition in contact with the object being coated.
The fluctuation of the level of the coating com- I position prevents the level from becoming associated for any appreciable time with any particular spot on the article being withdrawn.
As a result there is no clinging of the surface of thecoating composition-to'the object being withdrawn. There is no pullingup of the surface followed by co1lapse.- There are no nodes of the coating compositionon the object coatecL- Also the lateral movement of the coating com- The invention makes possible, in a simple and economical operation, the application of a thicker coating of the given composition than heretofore obtained by the immersion and withdrawal method.
When a thin but uniform coating is desired, then heat may be applied as by passing the coated object, at a level just above that of emergence from the bath, as between electrical heaters shown in the drawing at 2B. These heaters cause a rise in temperature and a decrease in viscosity of the adhering coating solution. They promote run back of coating material. Also the heaters exert a maximum effect upon the surface of the coating film and thus make this the least viscous part of the film, so as to cause smoothin of the film surface.
" may be used conventional coating compositions position of continually fluctuating level (:On-
the surface of the of the following types: pigmented baking enamels of the common oleoresin type; alkyd, phenolformaldehyde, 7 and urea-formaldehyde resin varnishes and ename1s;- and finishing compost tions containing vinyl or styrene polymers of resinous consistency. These' compositions as used may be diluted, with-any conventional solvent or thinner for the selected composition, ,to the range of viscosities described. Among the solvents that may be used are toluene, naphtha, The solvents seturpentine, and butyl acetate. lected should be those that are compatible with the finishing compositions selected.
The problem of alternate pulling and release of the surface as the object emerges is serious with the relatively light Weight coating compositions of the kind described. This problem is not serious with metal coatings where the spe- The invention makes possible the use 'ofcoat ing compositions of abnormally low viscosity.
Other objects that may be coated with the "method and apparatus described, particularly with the light weight, non-metallic types of coatings, include wire, textile fabrics, woven wire gauze, paper, sheets and webs of plastic material, and like material. In addition to such strip material, thereby may be dip-coated, by the present method and apparatus; rigid articles such as castings, machine or radiator covers, lamp shades, novelties and toys. The strip steel, wire, and castings are examples of objects having anon-absorbent, smooth surface.
It will be understood from the description that has been given that there is relative movement between the liquid coating composition and the object being coated, this movement being in more than one direction at the position of emergence of the object from the upper surface of the coating composition. In the wave' motion referred to there is always some lateral movement. Also there is relative movement in a vertical direction between the object to be coated and the surface of the liquid throughwhich the object is being withdrawn.
It will be understood also that it intended to cover all changes and modifications of the exv5 amples of the invention herein chosen for the However,
purpose of illustration which do not constitute departures from the spirit and scope of the invention.
What I claim is:
1. The method of applying a coating of a liquid heat hardenable organic finishing composition of low viscosity to an object having a non-absorbent smooth surface which comprises immersing -the object in the said composition, withdrawing the object at a steady rate through the upper surface of the composition, and subjecting said composition to mechanical agitation applied at and immediately below the surface thereof, to cause alternations of rise and fall of the level of the said surface at predetermined regular frequency of at least complete cycles a minute and to cause also movement of the coating liquid at the said surface in direction generally lateral to the surface of the object being withdrawn through the surface.
6 2. The method described in claim 1, the frequency of said fluctuation being at least one for each feet of linear movement of the object being coated.
ROBERT A. LIEBEL.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS
US611885A 1945-08-21 1945-08-21 Method of applying uniform coating by immersion Expired - Lifetime US2489456A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3167308A (en) * 1961-07-21 1965-01-26 Sandvikens Jernverks Ab Springs and strip steel
US3252165A (en) * 1963-01-14 1966-05-17 Fmc Corp Coating apparatus
US3539385A (en) * 1968-07-29 1970-11-10 Gen Motors Corp Method of coating elongated articles by immersion
US3798880A (en) * 1972-05-25 1974-03-26 Peabody Engineering Corp Air cleaning apparatus
FR2208788A1 (en) * 1972-12-06 1974-06-28 Trefilunion Coating metal wires with plastics - using vibration of guide pulleys to enhance wire dip contact
US5278027A (en) * 1989-03-08 1994-01-11 R. R. Donnelley Method and apparatus for making print imaging media
US20110024043A1 (en) * 2009-07-02 2011-02-03 Dexcom, Inc. Continuous analyte sensors and methods of making same
US20110290180A1 (en) * 2008-10-07 2011-12-01 Kaindl Decor Gmbh Apparatus for impregnating web-like materials with thermally curable impregnating resin
WO2015143065A1 (en) * 2014-03-18 2015-09-24 Immunolight, Llc Improved adhesive bonding composition and method of use
US10087343B2 (en) 2007-08-06 2018-10-02 Immunolight, Llc Adhesive bonding composition and method of use

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1772743A (en) * 1927-01-05 1930-08-12 Gen Electric Coated metal article and process of applying coatings thereof
US2071685A (en) * 1935-01-21 1937-02-23 American Steel & Wire Co Fastening
US2135652A (en) * 1937-05-26 1938-11-08 Reynolds Metals Co Process for metal coating
US2156382A (en) * 1937-02-17 1939-05-02 Ferla John Method for treating composition boards
US2310162A (en) * 1939-11-25 1943-02-02 Aetna Standard Eng Co Apparatus for galvanizing
US2345058A (en) * 1939-11-25 1944-03-28 Aetna Standard Eng Co Method of galvanizing

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1772743A (en) * 1927-01-05 1930-08-12 Gen Electric Coated metal article and process of applying coatings thereof
US2071685A (en) * 1935-01-21 1937-02-23 American Steel & Wire Co Fastening
US2156382A (en) * 1937-02-17 1939-05-02 Ferla John Method for treating composition boards
US2135652A (en) * 1937-05-26 1938-11-08 Reynolds Metals Co Process for metal coating
US2310162A (en) * 1939-11-25 1943-02-02 Aetna Standard Eng Co Apparatus for galvanizing
US2345058A (en) * 1939-11-25 1944-03-28 Aetna Standard Eng Co Method of galvanizing

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3167308A (en) * 1961-07-21 1965-01-26 Sandvikens Jernverks Ab Springs and strip steel
US3252165A (en) * 1963-01-14 1966-05-17 Fmc Corp Coating apparatus
US3539385A (en) * 1968-07-29 1970-11-10 Gen Motors Corp Method of coating elongated articles by immersion
US3798880A (en) * 1972-05-25 1974-03-26 Peabody Engineering Corp Air cleaning apparatus
FR2208788A1 (en) * 1972-12-06 1974-06-28 Trefilunion Coating metal wires with plastics - using vibration of guide pulleys to enhance wire dip contact
US5278027A (en) * 1989-03-08 1994-01-11 R. R. Donnelley Method and apparatus for making print imaging media
US10087343B2 (en) 2007-08-06 2018-10-02 Immunolight, Llc Adhesive bonding composition and method of use
US8945679B2 (en) * 2008-10-07 2015-02-03 Kaindl Decor Gmbh Apparatus for impregnating web-like materials with thermally curable impregnating resin
US20110290180A1 (en) * 2008-10-07 2011-12-01 Kaindl Decor Gmbh Apparatus for impregnating web-like materials with thermally curable impregnating resin
US20110027453A1 (en) * 2009-07-02 2011-02-03 Dexcom, Inc. Continuous analyte sensors and methods of making same
US20110024043A1 (en) * 2009-07-02 2011-02-03 Dexcom, Inc. Continuous analyte sensors and methods of making same
WO2015143065A1 (en) * 2014-03-18 2015-09-24 Immunolight, Llc Improved adhesive bonding composition and method of use
US11345833B2 (en) 2014-03-18 2022-05-31 Immunolight, Llc Adhesive bonding composition and method of use

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