US20130309408A1

US20130309408A1 - Coating apparatus and coating method

Info

Publication number: US20130309408A1
Application number: US13/471,794
Authority: US
Inventors: Hidenori Miyamoto
Original assignee: Tokyo Ohka Kogyo Co Ltd
Current assignee: Tokyo Ohka Kogyo Co Ltd
Priority date: 2012-05-15
Filing date: 2012-05-15
Publication date: 2013-11-21
Also published as: JP2013237042A

Abstract

A coating apparatus including: a coating part having a nozzle which ejects a liquid material including a solvent and a plurality of metals to a substrate, a storing part which is connected to the nozzle and stores the liquid material, and an ultrasonic wave oscillating part which oscillates an ultrasonic wave to the liquid material stored in the storing part.

Description

FIELD OF THE INVENTION

The present invention relates to a coating apparatus and a coating method.

DESCRIPTION OF THE RELATED ART

A CIGS solar cell or a CZTS solar cell formed by semiconductor materials including a metal such as Cu, Ge, Sn, Pb, Sb, Bi, Ga, In, Ti, Zn, and a combination thereof, and a chalcogen element such as S, Se, Te, and a combination thereof has been attracting attention as a solar cell having high conversion efficiency (for example, see Patent Documents 1 to 3).
For example, a CIGS solar cell has a structure in which a film including four types of semiconductor materials, namely, Cu, In, Ga, and Se is used as a light absorbing layer (photoelectric conversion layer). Further, for example, a CZTS solar cell has a structure in which a film including four types of semiconductor materials, namely, Cu, Zn, Sn, and Se is used as a light absorbing layer (photoelectric conversion layer). In such solar cells, a configuration is known in which a back electrode made of molybdenum is provided on a substrate such a glass, and the aforementioned light absorbing layer is provided on the back electrode.
In a CIGS solar cell or a CZTS solar cell, since it is possible to reduce the thickness of the light absorbing layer compared to a conventional solar cell, it is easy to install the CIGS solar cell on a curved surface and to transport the CIGS solar cell. For this reason, it is expected that CIGS solar cells can be used in various application fields as a high-performance, flexible solar cell. As a method of forming the light absorbing layer, a method of forming the light absorbing layer through depositing or sputtering is conventionally known (for example, see Patent Documents 2 to 5).

DOCUMENTS OF RELATED ART

Patent Documents

[Patent Document 1] Japanese Unexamined Patent Application, First Publication No. Hei 11-340482
[Patent Document 2] Japanese Unexamined Patent Application, First Publication No. 2005-51224
[Patent Document 3] Published Japanese Translation No. 2009-537997 of the PCT International Publication
[Patent Document 4] Japanese Unexamined Patent Application, First Publication No. Hei 1-231313
[Patent Document 5] Japanese Unexamined Patent Application, First Publication No. Hei 11-273783

SUMMARY OF THE INVENTION

In contrast, as the method of forming the light absorbing layer, the present inventor proposes a method of coating the semiconductor materials in the form of a liquid material on a substrate. In such a method of forming the light absorbing layer by coating the semiconductor materials in the form of a liquid material, the following problems arise.
In the supply source of the liquid material, when the dispersion of the components in the solvent is unsatisfactory, the liquid material is coated on a substrate in a state where there is fluctuation in the concentration of the components. As a result, there is a possibility that the film property of the coating film varies.
The present invention takes the above circumstances into consideration, with an object of providing a coating apparatus and a coating method capable of preventing variation in the film property of the coating film.
A coating apparatus according to a first aspect of the present invention includes a coating part having a nozzle which ejects a liquid material containing a solvent and a plurality of metals to a substrate, a storing part which is connected to the nozzle and stores the liquid material, and an ultrasonic wave oscillating part which oscillates an ultrasonic wave to the liquid material stored in the storing part.
According to the present invention, by virtue of including a coating part having a nozzle which ejects a liquid material containing a solvent and a plurality of metals to a substrate, a storing part which is connected to the nozzle and stores the liquid material, and an ultrasonic wave oscillating part which oscillates an ultrasonic wave to the liquid material stored in the storing part, it becomes possible to provided a state where an ultrasonic wave is oscillated to the liquid material, so that the plurality of metals can be easily dispersed in the solvent. As a result, a liquid material in an excellent mixing state can be coated, thereby preventing variation in the film property of the coating film.
The coating apparatus may further include a stirring part which stirs the liquid material stored in the storing part.
In this embodiment, by virtue of including a stirring part which stirs the liquid material stored in the storing part, stirring can be conducted in addition to oscillation of an ultrasonic wave. As a result, the plurality of metals can be more easily dispersed in the solvent.
The coating apparatus may further include a temperature control part which controls the temperature of the liquid material.
In this embodiment, by virtue of including a temperature control part which controls the temperature of the liquid material, the temperature of the liquid material can be prevented from being changed by the oscillation of an ultrasonic wave or stirring.
In the coating apparatus, the temperature control part may include a jacket member which is provided at at least a portion around the storing part and has a flow path for a temperature control medium formed inside thereof, and a circulation part which allows the temperature control medium to flow through the flow path formed inside the jacket member.
In this embodiment, by virtue of the temperature control part including a jacket member which is provided at at least a portion around the storing part and has a flow path for a temperature control medium formed inside thereof, and a circulation part which allows the temperature control medium to flow through the flow path formed inside the jacket member, the temperature of the liquid material can be efficiently controlled.
In the coating apparatus, the ultrasonic wave oscillating part may include an emission part which is provided outside the jacket member and emits the ultrasonic wave to the storing part.
In this embodiment, by virtue of the ultrasonic wave oscillating part including an emission part which is provided outside the jacket member and emits the ultrasonic wave to the storing part, an ultrasonic wave can be efficiently oscillated to the liquid material, and the temperature of the liquid material can be efficiently controlled.
In the coating apparatus, the jacket member may be provided with an opening which exposes the storing part, and the emission part may be provided at the opening.
In this embodiment, by virtue of the jacket member being provided with an opening which exposes the storing part, and the emission part being provided at the opening, an ultrasonic wave can be more efficiently oscillated to the liquid material.
The coating apparatus may further include a detection part which detects the state of the liquid material.
In this embodiment, by virtue of including a detection part which detects the state of the liquid material, the plurality of metals can be efficiently dispersed in the solvent.
The coating apparatus may further include a control part which actuates the ultrasonic wave oscillating part depending on the detection results of the detection part.
In this embodiment, by virtue of including a control part which actuates the ultrasonic wave oscillating part depending on the detection results of the detection part, the plurality of metals can be efficiently dispersed in the solvent.
The coating apparatus may further include a solvent supplying part which supplies the solvent to the storing part, wherein the control part may supply the solvent from the solvent supplying part to the storing part depending on the detection results of the detection part.
In this embodiment, by virtue of including a solvent supplying part which supplies the solvent to the storing part, wherein the control part supplies the solvent from the solvent supplying part to the storing part depending on the detection results of the detection part, the state of the plurality of metals can be efficiently controlled.
In the coating apparatus, the detection part may detect the size of the particles contained in the liquid material as the state of the liquid material.
In this embodiment, by virtue of the detection part detecting the size of the particles contained in the liquid material as the state of the liquid material, a high precision data with respect to the state of the plurality of metals can be obtained.
A coating method according to a second aspect of the present invention includes a storing step in which a liquid material containing a solvent and a plurality of metals is stored in a storing part connected to a nozzle which ejects the liquid material to a substrate, an ultrasonic wave oscillating step in which an ultrasonic wave is oscillated to the liquid material stored in the storing part, and an ejection step in which the liquid material oscillated with the ultrasonic wave is ejected from the nozzle to the substrate.
According to the present invention, by virtue of storing a liquid material containing a solvent and a plurality of metals in a storing part connected to a nozzle which ejects the liquid material to a substrate, oscillating an ultrasonic wave to the liquid material stored in the storing part, and ejecting the liquid material oscillated with the ultrasonic wave from the nozzle to the substrate, it becomes possible to provide a state where the plurality of metals can be easily dispersed in the solvent by the oscillation of an ultrasonic wave to the liquid material. As a result, the liquid material can be ejected in an excellent state, and a liquid material in an excellent mixing state can be coated.
In the coating method, the ultrasonic wave oscillating step may include a stirring step in which the liquid material is stirred.
In this embodiment, by virtue of the ultrasonic wave oscillating step including a stirring step in which the liquid material is stirred, stirring can be conducted in addition to oscillation of an ultrasonic wave. As a result, the plurality of metals can be more easily dispersed in the solvent.
In the coating method, the ultrasonic wave oscillating step may include a temperature controlling step in which the temperature of the liquid material is controlled.
In this embodiment, by virtue of the ultrasonic wave oscillating step including a temperature controlling step in which the temperature of the liquid material is controlled, the temperature of the liquid material can be prevented from being changed by the oscillation of an ultrasonic wave or stirring.
The coating method may further include a detection step in which the state of the liquid material is detected.
In this embodiment, by virtue of further including a detection step in which the state of the liquid material is detected, the plurality of metals can be efficiently dispersed in the solvent.
In the coating method, the ultrasonic wave oscillating step may be performed depending on the detection results of the detection step.
In this embodiment, by virtue of performing the ultrasonic wave oscillating step depending on the detection results of the detection step, the plurality of metals can be efficiently dispersed in the solvent.
The coating method may further include a solvent supplying step in which the solvent is supplied to the storing part, wherein the solvent supplying step may be performed depending on the detection results of the detection step.
In this embodiment, by virtue of further including a solvent supplying step in which the solvent is supplied to the storing part, wherein the solvent supplying step is performed depending on the detection results of the detection step, the state of the plurality of metals can be efficiently controlled.
In the coating method, the detection step may include detecting the size of the particles contained in the liquid material as the state of the liquid material.
In this embodiment, by virtue of the detection step including detecting the size of the particles contained in the liquid material as the state of the liquid material, a high precision data with respect to the state of the plurality of metals can be obtained.

EFFECT OF THE INVENTION

According to the present invention, there are provided a coating apparatus and a coating method capable of preventing variation in the film property of the coating film.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a diagram showing an entire configuration of a coating apparatus according to one embodiment of the present invention.

FIG. 2 is a diagram showing an entire configuration of the coating apparatus according to the present embodiment.

FIG. 3 is a diagram showing a configuration of a nozzle according to the present embodiment.

FIG. 4 is a piping diagram showing a flow path configuration of the coating part according to the present embodiment.

FIG. 5 is a diagram showing a configuration of an air vent tank according to the present embodiment.

FIG. 6 is a diagram showing a configuration of a vacuum drying part according to the present embodiment.

FIG. 7 is a diagram showing a configuration of a portion of a baking part according to the present embodiment.

FIG. 8 is a diagram showing a step in a coating treatment performed by a coating apparatus according to the present embodiment.

FIG. 9 is a diagram showing a step in a coating treatment performed by a coating apparatus according to the present embodiment.

FIG. 10 is a diagram showing a step in a coating treatment performed by a coating apparatus according to the present embodiment.

FIG. 11 is a diagram showing a step in a coating treatment performed by a coating apparatus according to the present embodiment.

FIG. 12 is a diagram showing a step in a coating treatment performed by a coating apparatus according to the present embodiment.

FIG. 13 is a diagram showing a step in a vacuum drying treatment performed by a coating apparatus according to the present embodiment.

FIG. 14 is a diagram showing a step in a vacuum drying treatment performed by a coating apparatus according to the present embodiment.

FIG. 15 is a diagram showing a step in a vacuum drying treatment performed by a coating apparatus according to the present embodiment.

FIG. 16 is a diagram showing a step in a vacuum drying treatment performed by a coating apparatus according to the present embodiment.

FIG. 17 is a diagram showing a step in a baking treatment performed by a coating apparatus according to the present embodiment.

FIG. 18 is a diagram showing a step in a baking treatment performed by a coating apparatus according to the present embodiment.

FIG. 19 is a diagram showing a step in a baking treatment performed by a coating apparatus according to the present embodiment.

FIG. 20 is a diagram showing a step in a baking treatment performed by a coating apparatus according to the present embodiment.

FIG. 21 is a diagram showing a step in a baking treatment performed by a coating apparatus according to the present embodiment.

FIG. 22 is a diagram showing a step in supplying a liquid material performed by a coating apparatus according to the present embodiment.

FIG. 23 is a diagram showing a step in supplying a liquid material performed by a coating apparatus according to the present embodiment.

FIG. 24 is a diagram showing a configuration of a coating apparatus according to a modified example of the present invention.

FIG. 25 is a diagram showing a configuration of a coating apparatus according to a modified example of the present invention.

FIG. 26 is a diagram showing a configuration of an air vent tank according to a modified example of the present invention.

FIG. 27 is a diagram showing a configuration of an air vent tank according to a modified example of the present invention.

FIG. 28 is a diagram showing a configuration of an air vent tank according to a modified example of the present invention.

FIG. 29 is a diagram showing a configuration of an air vent tank according to a modified example of the present invention.

FIG. 30 is a diagram showing a configuration of an air vent tank according to a modified example of the present invention.

FIG. 31 is a diagram showing a configuration of an air vent tank according to a modified example of the present invention.

MODE FOR CARRYING OUT THE INVENTION

Hereinafter, one embodiment of the present invention will be described with reference to the accompanying drawings.
FIG. 1 is a schematic diagram showing a configuration of a coating apparatus CTR according to one embodiment of the present invention.
As shown in FIG. 1, the coating apparatus CTR is an apparatus which applies a liquid material to a substrate S. The coating apparatus CTR includes a substrate loading/unloading part LU, a first chamber CB1, a second chamber CB2, a connection part CN and a control part CONT. The first chamber CB1 has a coating part CT. The second chamber CB2 has a baking part BK. The connection part CN has a vacuum drying part VD.
The coating apparatus CTR is used, for example, by being disposed on a floor FL in a factory. The coating apparatus may have a configuration in which the coating apparatus is accommodated in one room, or a configuration in which the coating apparatus is divisionally accommodated in a plurality of rooms. In the coating apparatus CTR, the substrate loading/unloading part LU, the coating part CT, the vacuum drying part VD and the baking part BK are arranged in this order in one direction.
With respect to the configuration of the coating apparatus CTR, it is not particularly limited that the substrate loading/unloading part LU, the coating part CT, the vacuum drying part VD and the baking part BK are arranged in this order in one direction. For example, the substrate loading/unloading part LU may be divided into a substrate loading part (not shown) and a substrate unloading part (not shown). Further, the vacuum drying part VD may be omitted. Needless to say, the aforementioned parts may not be arranged in one direction, and a configuration may be employed in which the aforementioned parts are arranged to be stacked in a vertical or horizontal direction with a robot (not shown) disposed at a central position.
In the respective drawings as below, upon describing the configuration of a substrate treating apparatus according to the present embodiment, for the purpose of simple marking, an XYZ coordinate system is used to describe the directions in the drawings. In the XYZ coordinate system, the plane parallel to the floor is regarded as the XY plane. On the XY plane, the direction in which the components of the coating apparatus CTR (the substrate loading/unloading part LU, the coating part CT, the vacuum drying part VD and the baking part BK) are arranged is marked as the X direction, and the direction perpendicular to the X direction on the XY plane is marked as the Y direction. The direction perpendicular to the XY plane is marked as the Z direction. In the X, Y, and Z directions, the arrow direction in the drawing is the +direction, and the opposite direction of the arrow direction is the −direction.
In this embodiment, as the substrate S, for example, a plate-shaped member made of glass, resin, or the like may be used. Further, in this embodiment, molybdenum is sputtered on the substrate S as a back electrode. Needless to say, any other electroconductive material may be used as a back electrode. Explanation will be given below, taking an example of a substrate having a size of 330 mm×330 mm as viewed in the Z direction. The size of the substrate is not limited to 330 mm×330 mm. For example, as the substrate S, a substrate having a size of 125 mm×125 mm may be used, or a substrate having a size of 1 m×1 m may be used. Needless to say, a substrate having a size larger than the aforementioned sizes or a substrate having a size smaller than the aforementioned sizes may be appropriately used.
In this embodiment, as the liquid material to be applied to the substrate S, for example, a liquid composition is used which includes a solvent such as hydrazine and oxidizable metals such as a combination of copper (Cu), indium (In), gallium (Ga), and selenium (Se) or a combination of copper (Cu), zinc (Zn), tin (Sn) and selenium (Se). The liquid composition includes a metal material for forming a light absorbing layer (photoelectric conversion layer) of a CIGS solar cell or a CZTS solar cell.
In the present embodiment, the liquid composition contains a substance for obtaining the grain size of a light absorbing layer of a CIGS solar cell or a CZTS solar cell. Needless to say, as the liquid material, a liquid material in which another metal (such as metal nano particles) is dispersed in the solution may be used.
(Substrate Loading/Unloading Part)
The substrate loading/unloading part LU loads a substrate S prior to being treated on the coating part CT, and unloads the treated substrate S from the coating part CT. The substrate loading/unloading part LU has a chamber 10. The chamber 10 is formed in the shape of a rectangular box. Inside the chamber 10, an accommodation room 10 a capable of accommodating the substrate S is formed. The chamber 10 has a first opening 11, a second opening 12 and a lid portion 14. The first opening 11 and the second opening 12 communicates the accommodation room 10 a with the outside of the chamber 10.
The first opening 11 is formed on a +Z-side face of the chamber 10. The first opening 11 is formed to have a size larger than the size of the substrate S as viewed in the Z direction. The substrate S to be taken out of the chamber 10 or the substrate S to be accommodated in the accommodation room 10 a is placed into or taken out of the substrate loading/unloading part LU through the first opening 11.
The second opening 12 is formed on a +X-side face of the chamber 10. The second opening 12 is formed to have a size larger than the size of the substrate S as viewed in the X direction. The substrate S supplied to the coating part CT or the substrate S returned from the coating part CT is placed into or taken out of the substrate loading/unloading part LU through the second opening 12.
The lid portion 14 opens or closes the first opening 11. The lid portion 14 is formed in the shape of a rectangular plate. The lid portion 14 is attached to a +X-side edge of the first opening 11 via a hinge portion (not shown). Thus, the lid portion 14 is rotatable around the Y-axis, with the +X-side edge of the first opening 11 as the center. By rotating the lid portion 14 around the Y-axis, the first opening 11 can be opened or closed.
The accommodation room 10 a is provided with a substrate transporting part 15. The substrate transporting part 15 includes a plurality of rollers 17. The rollers 17 are arranged in a pair in the Y-direction, and a plurality of the pairs are arranged in the X-direction.
Each of the rollers 17 is adapted to be rotatable about the Y direction serving as the central axis. The plurality of rollers 17 are formed to have the same diameter, and the +Z-side end of the plurality of rollers 17 are arranged on a same plane parallel to the XY plane. Thus, the plurality of rollers 17 are capable of supporting the substrate S in a state where the substrate S is parallel to the XY plane.
The rotation of each of the rollers 17 is controlled, for example, by a roller-rotation control part (not shown). By rotating each of the rollers 17 clockwise or anti-clockwise around the Y-axis in a state where the substrate S is supported by the plurality of rollers 17, the substrate transporting part 15 can transport the substrate S in an X-direction (+X-direction or −X-direction). As the substrate transporting part 15, a float transporting part (not shown) may be used to lift the substrate for transportation.
(First Chamber)
The first chamber CB1 is mounted on the base BC placed on the floor FL. The first chamber CB1 is formed in the shape of a rectangular box. Inside the first chamber CB1, an accommodation room 20 a is formed. The coating part CT is provided in the treatment room 20 a. The coating part CT performs the coating treatment of the liquid material on the substrate S.
The first chamber CB1 has a first opening 21 and a second opening 22. The first opening 21 and the second opening 22 communicate the treatment 20 a with the outside of the first chamber CB1. The first opening 21 is formed on a −X-side face of the first chamber CB1. The second opening 22 is formed on a +X-side face of the first chamber CB1. The first opening 21 and the second opening 22 are formed to have a size which allows the substrate S to pass through. The substrate S is placed in or taken out of the first chamber CB1 through the first opening 21 and the second opening 22.
The coating part CT has an ejection part 31, a maintenance part 32, a liquid material supply part 33, a washing liquid supply part 34, a waste liquid storing part 35, a gas supply/exhaust part 37 and a substrate transporting part 25.
The ejection part 31 has a nozzle NZ, a treatment stage 28 and a nozzle actuator NA.
FIG. 3( a) is a diagram showing a configuration of the slit nozzle NZ.
As shown in FIG. 3( a), the nozzle NZ is formed to have an elongate shape, and is arranged such that the lengthwise direction thereof is in parallel to the X direction. The nozzle NZ has a main part NZa and a protruding part NZb. The main part NZa is a housing capable of accommodating the liquid material inside thereof. The main part NZa is made of, for example, a material containing titanium or a titanium alloy. The protruding part NZb is formed to protrude from the main part NZa on the +X-side and the −X-side. The protruding part NZb is held by part of the nozzle actuator NA.
FIG. 3( b) shows the configuration when the nozzle NZ is viewed from the −Z direction side thereof.
As shown in FIG. 3( b), the nozzle NZ has an ejection opening OP on the −Z-side end (tip TP) of the main part NZa. The ejection opening OP is an opening for ejecting a liquid material. The ejection opening OP is formed as a slit elonging in the X direction. The ejection opening OP is formed, for example, such that the longitudinal direction thereof is substantially equal to the X-direction dimension of the substrate S.
The nozzle NZ ejects, for example, a liquid material in which four types of metals, namely, Cu, Zn, Sn, and Se are mixed with a predetermined composition ratio. The nozzle NZ is connected to a liquid supply part 33 via a connection pipe or the like (not shown). The nozzle NZ includes a holding part which holds the liquid material therein. A temperature control part which controls the temperature of the liquid material held by the holding part may be provided.
Returning to FIG. 1 and FIG. 2, the substrate S to be subjected to a coating treatment is mounted on the treatment stage 28. The +Z-side face of the treatment stage 28 is a substrate mounting face where the substrate S is mounted. The substrate mounting face is formed to be in parallel with the XY plane. The treatment stage 28 is made of, for example, stainless steel.
The nozzle actuator NA moves the nozzle NZ in the X direction. The nozzle actuator NA has a stator 40 and a mover 41 which constitutes a linear motor mechanism. As the nozzle actuator NA, any other actuator having another configuration such as a ball screw configuration may be used. The stator 40 is elongated in the Y direction. The stator 40 is supported by a support frame 38. The support frame 38 has a first frame 38 a and a second frame 38 b. The first frame 38 a is provided on a −Y-side end portion of the treatment room 20 a. The second frame 38 b is provided in the treatment room 20 a such that the treatment stage 28 is positioned between the first frame 38 a and the second frame 38 b.
The mover 41 is movable along the direction where the stator 40 is elonged (Y direction). The mover 41 has a nozzle supporting member 42 and an elevator part 43. The nozzle supporting member 42 is formed in the shape of a gate, and has a holding part 42 a which holds the protruding part NZb of the nozzle NZ. The nozzle supporting member 42 integrally moves with the elevator part 43 along the stator 40 between the first frame 38 a and the second 38 b in the Y direction. Thus, the nozzle NZ held by the nozzle supporting member 42 moves in the Y direction over the treatment stage 28. The nozzle supporting member 42 moves along the elevation guide 43 a of the elevator part 43 in the Z direction. The mover 41 has an actuator source (not shown) which moves the nozzle supporting member 42 in the Y direction and the Z direction.
The maintenance part 32 is where the maintenance of the nozzle NZ is performed. The maintenance part 32 has a nozzle standby part 44 and a nozzle-tip control part 45.
The nozzle standby part 44 has a dipping part (not shown) where the tip TP of the nozzle NZ is dipped to prevent it from drying, and a discharge part (not shown) which discharges the liquid material held within the nozzle NZ when the nozzle NZ is changed or the liquid material to be supplied to the nozzle NZ is changed.
The nozzle-tip control part 45 adjusts the conditions of the nozzle tip by washing the tip TP of the nozzle NZ and the vicinity thereof, and conducting preliminary ejection from the ejection opening OP of the nozzle NZ. The nozzle-tip control part 45 has a wiping part 45 a which wipes the tip TP of the nozzle NZ and a guide rail 45 b which guides the wiping part 45 a. The nozzle-tip control part 45 is provided with a waste liquid accommodation part 35 a which accommodates the liquid material discharged from the nozzle NZ and the washing liquid used for washing the nozzle NZ.
FIG. 3( c) is a diagram showing the cross-sectional shape of the nozzle NZ and the nozzle-tip control part 45. As shown in FIG. 3( c), the wiping part 45 a is formed to cover the tip TP of the nozzle NZ and part of the inclined plane on the tip TP-side in the cross-sectional view.
The guide rail 45 b extends in the X direction to cover the opening OP of the nozzle NZ. The wiping part 45 a is adapted to be movable by an actuator source (not shown) along the guide rail 45 b in the X direction. By moving the wiping part 45 a in the X direction while being in contact with the tip TP of the nozzle NZ, the tip TP can be wiped.
The liquid material supply part 33 has a first liquid material accommodation part 33 a and a second liquid material accommodation part 33 b. The first liquid material accommodation part 33 a and the second liquid material accommodation part 33 b accommodate the liquid material to be applied to the substrate S. Further, the first liquid material accommodation part 33 a and the second liquid material accommodation part 33 b are capable of accommodating a plurality of different types of liquid materials.
The washing liquid supply part 34 accommodates a washing liquid which washes various parts of the coating part, such as the inside of the nozzle NZ and the nozzle-tip control part 45. The washing liquid supply part 34 is connected to the inside of the nozzle NZ and the nozzle-tip control part 45 via a pipe and a pump (which are not shown).
The waste liquid storing part 35 collects the liquid ejected from the nozzle NZ and is not reused. The nozzle-tip control part 45 may have a configuration in which the part which conducts the preliminary ejection and the part which washes the tip TP of the nozzle NZ are individually provided. Alternatively, the preliminary ejection may be conducted at the nozzle standby part 44.
The gas supply/exhaust part 37 has a gas supply part 37 a and a gas exhaust part 37 b. The gas supply part 37 a supplies an inert gas such as a nitrogen gas or an argon gas to the treatment room 20 a. The gas exhaust part 37 b suctions the treatment room 20 a, and discharges the gas in the treatment room 20 a outside the first chamber CB1.
The substrate transporting part 25 transports the substrate S inside the treatment room 20 a. The substrate transporting part 25 includes a plurality of rollers 27. The rollers 27 are arranged in the X-direction to be intersected into two lines by a central portion of the treatment room 20 a in the Y-direction. The rollers 27 arranged in each line support the +Y-side end and −Y-side end of the substrate S.
By rotating each of the rollers 27 clockwise or anti-clockwise around the Y-axis in a state where the substrate S is supported by the plurality of rollers 27, the substrate S supported by each of the rollers 27 is transported in an X-direction (+X-direction or −X-direction). A float transporting part (not shown) may be used to lift the substrate for transportation.
FIG. 4 is a piping diagram showing a flow path configuration of the liquid material, the washing liquid and the gas in the coating part CT.
As shown in FIG. 4, the coating part CT is provided with a supply system 100 and a recycle system 200. The supply system 100 supplies the liquid material to the nozzle NZ. The recycle system 200 recovers the liquid material from at least one of the supply system 100 and the nozzle NZ, and supplies the recovered liquid material to at least one of the supply system 100 and the nozzle NZ.
The supply system 100 supplies the liquid material from the liquid material supply part 33 to the nozzle NZ. In the supply system 100, the liquid material supply part 33 is on the upstream side, and the nozzle NZ is on the downstream side. The supply system 100 has a pipe 101, a pipe 121, an air vent tank 102, a pipe 103, a connection switch 104, a pipe 105, a discharge pump 106, a pipe 107, nozzle pipes 108 and 109, a pipe 110, a pipe 111, a chemical pump 112 and a pipe 113.
The upstream-side end of the pipe 101 is connected to the first liquid material accommodation part 33 a. The upstream-side end of the pipe 121 is connected to the second liquid material accommodation part 33 b. Each of the pipe 101 and the pipe 121 is provided with a liquid flow control part MFC which controls the flow of the liquid. Each liquid flow control part MFC controls the flow of the liquid material which passes through the pipe 101 and the flow of the liquid material which passes through the pipe 121. By this configuration, it becomes possible to avoid the state where the liquid material is separated in the liquid material supply part 33.
The downstream-side end of the pipe 101 is connected to the air vent tank 102 via an inlet 101 a. The downstream-side end of the pipe 121 is connected to the air vent tank via an inlet 121 a. Thus, the liquid material from the first liquid material accommodation part 33 a and the liquid material from the second liquid material accommodation part 33 b are mixed together in the air vent tank 102. The air vent tank 102 is disposed on a downstream side of the supply path of the liquid material, relative to the liquid material supply part 33 (first liquid material accommodation part 33 a). The air vent tank 102 removes any gas contained in the liquid material. The air vent tank 102 is provided with a nitrogen gas pressurizing line, a depressurizing line and a drain line which are omitted from the drawing. Each of these lines is provided with an air operated valve, and can be opened or closed by the air operated valve.
The pipe 103 is connected on a downstream side of the air vent tank 102. The pipe 103 is provided with a filter 103 a. The filter 103 a removes foreign matters from the liquid material which passes through the pipe 103. The downstream-side end of the pipe 103 is connected to the connection switch 104. A configuration in which the filter 103 a is omitted may be employed.
The connection switch 104 has a first port 104 a and a second port 104 b. The downstream side of the first port 104 a and the second port 104 b is connected to the pipe 105. The connection switch 104 is provided to be capable of switching the connection target of the pipe 105 between the first port 104 a and the second port 104 b. The pipe 103 is connected to the first port 104 a. The second port 104 is connected to the washing liquid supply part 34 via the pipe 110. Apart from the washing liquid supply part 34, the pipe 110 may be connected to a gas supply part (not shown). In this case, an example of the gas includes a nitrogen gas.
The pipe 105 connects the connection switch 104 with the discharge pump 106. The discharge pump 106 pushes the liquid material towards the nozzle NZ side. The downstream side of the discharge pump 106 is connected to the pipe 107. The downstream-side end of the pipe 107 is connected to nozzle pipes 108 and 109.
The nozzle pipes 108 and 109 are formed to branch from the downstream-side end of the pipe 107. The nozzle pipe 108 is connected to one end of the nozzle NZ in the lengthwise direction thereof via an inlet 108 a. The nozzle pipe 109 is connected to the other end of the nozzle NZ in the lengthwise direction thereof via an inlet 109 a. The inlet 109 a is provided with a valve which can open or close the nozzle pipe 109. The valve is provided to be switchable by the control part CONT. At the connection portion of the nozzle pipe 109 and the nozzle NZ, a manifold NZh is formed which communicates the inside of the nozzle NZ with the outside. The nozzle pipe 109 is connected to the nozzle NZ via the manifold NZh.
The pipe 111 connects the nozzle standby part 44 with the chemical pump 112. The pipe 111 is provided with an air operated valve 111 a. The air operated valve 111 a opens or closes the flow path of the liquid material accommodated in the nozzle standby part 44 from the pipe 111 to the chemical pump 112. The chemical pump 112 is connected to the waste liquid storing part 35 via the pipe 113. The chemical pump 112 suctions the liquid material from the pipe 111 to the pipe 113. By the suction force of the chemical pump 112, the liquid material passing through the pipe 111 flows into the pipe 113.
The recycle system 200 has a pipe 201, a chemical pump 202, a pipe 203 ad a pipe 204. The pipe 201 is provided to branch from the pipe 111 which connects the aforementioned nozzle standby part 44 and the waste liquid storing part 35. The pipe 201 is connected to the chemical pump 202 via an inlet 201 a.
The chemical pump 202 suctions the liquid material from the pipe 111 to the pipe 201. By the suction force of the chemical pump 202, the liquid material passing through the pipe 111 flows into the pipe 201. The pipe 203 connects the chemical pump 202 with the air vent tank 102.
The pipe 204 is connected to the nozzle pipe 109 between the inlet 109 a and the manifold NZh. The pipe 204 is connected to the pipe 203 via an air operated vent 204 a. By opening or closing the air operated vent 204 a, the liquid material held inside the nozzle NZ flows from the pipe nozzle 109 to the pipe 204.
In the present embodiment, a configuration is employed in which the liquid material ejected from the nozzle NZ is supplied to the air vent tank 102 via the pipe 201, the chemical pump 202 and the pipe 203. Thus, the pipe 201, the chemical pump 202 and the pipe 203 constitutes a first recovery part 205 which recovers the liquid material ejected from the nozzle NZ. Further, the pipe 204, the air operated valve 204 a and the pipe 203 constitutes a second recovery part 206 which recovers the liquid material held inside the nozzle NZ.
FIG. 5 is a diagram showing a configuration of the air vent tank 102.
As shown in FIG. 5, the air vent tank 102 has a container 91, an ultrasonic wave oscillator 92, a stirrer 93 and a temperature control part 94. The container 91 is formed, for example, in a cylindrical shape, and the lateral face (outer peripheral face) of the container 91 has a cylindrical surface. The container 91 accommodates the liquid material supplied from the pipe 101 and the pipe 121.
The ultrasonic wave oscillator 92 oscillates an ultrasonic wave to the liquid material accommodated in the container 91. A plurality of ultrasonic wave oscillators 92 are provided around the container 91. In FIG. 5, a configuration is shown in which two ultrasonic wave oscillators 92 are provided at positions separated about 180° along the outer periphery of the container 91. However, the present embodiment is not limited to this configuration, and any other configuration may be employed.
For example, a configuration in which three or more ultrasonic wave oscillators are provided may be employed. In such a case, a configuration may be employed in which a plurality of ultrasonic wave oscillators 92 are disposed with a predetermined pitch (e.g., an equal pitch) along the outer periphery of the container 91, so as to surround the container 91. Alternatively, a configuration in which only one ultrasonic wave oscillator 92 is provided may be employed.
The ultrasonic wave oscillator 92 has an emission face 92 a from which an ultrasonic wave is emitted. The ultrasonic wave oscillator 92 is disposed such that the emission face 92 a faces the container 91. By such a configuration, the ultrasonic wave emitted from each ultrasonic wave oscillator 92 is oscillated from the outside of the temperature control part 94 to the inside of the container 91. The emission face 92 a is formed to be capable of oscillating over approximately the entire region of the container 91 in terms of the depthwise direction of the liquid material Q.
The stirrer 93 is provided inside the container 91, and stirs the liquid material accommodated in the container 91. As the stirrer 93, for example, a magnetic stirrer is used. The stirrer 93 has a magnetic field generation part (not shown), and is moved or rotated in response to the magnetic field generated by the magnetic field generation part. By the movement or rotation of the stirrer 93, the liquid material accommodated in the container 91 is stirred.
The temperature control part 94 controls the temperature of the liquid material accommodated in the container 91. The temperature control part 94 has a jacket member 94 a. The jacket member 94 a is wound around the outer periphery of the container 91. Inside the jacket member 94 a, a flow path 94 c for a temperature control medium 94 b is formed. The flow path 94 c is formed in the shape of a ring along the outer periphery of the container 91. The flow path 94 c is connected to a circulation part 94 d which actuates the temperature control medium 94 b. The circulation part 94 d forms a flow of the temperature control medium 94 b within the flow path 94 c.
(Connection Part)
As shown in FIG. 1 and FIG. 2, the connection part CN connects the first chamber CB1 and the second chamber CB2. The substrate S is moved between the first chamber CB1 and the second chamber CB2 via the connection part CN. The connection part CN has a third chamber CB3. The third chamber CB3 is formed in the shape of a rectangular box. Inside the third chamber CB3, a treatment room 50 a is formed. In the present embodiment, the treatment room 50 a is provided with a vacuum drying part VD. The vacuum drying part VD dries the liquid material coated on the substrate S. The third chamber CB3 is provided with gate valves V2 and V3.
The third chamber CB3 has a first opening 51 and a second opening 52. The first opening 51 and the second opening 52 communicate the treatment room 50 a with the outside of the third chamber CB3. The first opening 51 is formed on a −X-side face of the third chamber CB3. The second opening 52 is formed on a +X-side face of the third chamber CB3. The first opening 51 and the second opening 52 are formed to have a size which allows the substrate S to pass through. The substrate S is placed in or taken out of the third chamber CB3 through the first opening 51 and the second opening 52.
The vacuum drying part VD has a substrate transporting part 55, a gas supply part 58, a gas exhaust part 59 and a heating part 53.
The substrate transporting part 55 includes a plurality of rollers 57. The rollers 57 are arranged in a pair in the Y-direction, and a plurality of the pairs are arranged in the X-direction. The plurality of rollers 57 supports the substrate S which is disposed in the treatment room 50 a via the first opening 51.
By rotating each of the rollers 57 clockwise or anti-clockwise around the Y-axis in a state where the substrate S is supported by the plurality of rollers 57, the substrate S supported by each of the rollers 57 is transported in an X-direction (+X-direction or −X-direction). A float transporting part (not shown) may be used to lift the substrate for transportation.
FIG. 6 is a schematic diagram showing a configuration of the vacuum drying part VD.
As shown in FIG. 6, the gas supply part 58 supplies an inert gas such as a nitrogen gas or an argon gas to the treatment room 50 a. The gas supply part 58 has a first supply part 58 a and a second supply part 58 b. The first supply part 58 a and the second supply part 58 b are connected to a gas supply source 58 c such as a gas bomb or a gas pipe. Supplying of a gas to the treatment room 50 a is performed mainly by using the first supply part 58 a. The second supply part 58 b makes a fine control of the amount of gas supplied by the first supply part 58 a.
The gas exhaust part 59 suctions the treatment room 50 a, and discharges the gas in the treatment room 50 a outside the third chamber CB3, thereby reducing the pressure inside the treatment room 50 a. By reducing the pressure inside the treatment room 50 a, evaporation of the solvent contained in the liquid material on the substrate S can be promoted, thereby drying the liquid material. The gas exhaust part 59 has a first suction part 59 a and a second suction part 59 b. The first suction part 59 a and the second suction part 59 b are connected to a suction source 59 c and 59 d such as a pump. Suction from the treatment room 50 a is performed mainly by using the first suction part 59 a. The second suction part 59 b makes a fine control of the amount of suction by the first suction part 59 a.
The heating part 53 heats the liquid material on the substrate S disposed in the treatment room 50 a. As the heating part 53, an infrared device or a hot plate is used. The temperature of the heating part 53 can be controlled, for example, from room temperature to about 100° C. By using the heating part 53, evaporation of the solvent contained in the liquid material on the substrate S can be promoted, thereby supporting the drying treatment under reduced pressure.
The heating part 53 is connected to a lifting mechanism (moving part) 53 a. The lifting mechanism 53 a moves the heating part 53 in the Z-direction. As the lifting mechanism, for example, a motor mechanism or an air-cylinder mechanism is used. By moving the heating part 53 in the Z-direction using the lifting mechanism 53 a, the distance between the heating part 53 and the substrate S can be adjusted. With respect to the heating part 53, the distance to be moved and the timing to be moved by the lifting mechanism 53 a can be controlled by the control part CONT.
(Second Chamber)
The second chamber CB2 is mounted on the base BB placed on the floor FL. The second chamber CB2 is formed in the shape of a rectangular box. Inside the second chamber CB2, a treatment room 60 a is formed. The baking part BK is provided in the treatment room 60 a. The baking part BK bakes the coating film coated on the substrate S.
The second chamber CB2 has an opening 61. The opening 61 communicates the treatment room 60 a with the outside of the second chamber CB2. The opening 61 is formed on a −X-side face of the second chamber CB2. The opening 61 is formed to have a size which allows the substrate S to pass through. The substrate S is placed in or taken out of the second chamber CB2 through the opening 61.
The baking part BK has a substrate transporting part 65, a gas supply part 68, a gas exhaust part 69 and a heating part 70.
The substrate transporting part 65 has a plurality of rollers 67 and an arm part 71. The rollers 67 are arranged in a pair in the Y-direction on the substrate guide stage 66, and a plurality of the pairs are arranged in the X-direction. The plurality of rollers 67 supports the substrate S which is disposed in the treatment room 60 a via the opening 61.
By rotating each of the rollers 67 clockwise or anti-clockwise around the Y-axis in a state where the substrate S is supported by the plurality of rollers 67, the substrate S supported by each of the rollers 67 is transported in an X-direction (+X-direction or −X-direction). A float transporting part (not shown) may be used to lift the substrate for transportation.
The arm part 71 is disposed on a platform 74, and transfers the substrate S between the plurality of rollers 67 and the heating part 70. The arm part 71 has a transport arm 72 and an arm actuator 73. The transport arm 72 has a substrate supporting part 72 a and a moving part 72 b. The substrate supporting part 72 a supports the +Y-side edge and −Y-side edge of the substrate S. The moving part 72 b is attached to the substrate supporting part 72 a, and is movable in the X-direction and the θZ-direction.
The arm actuator 73 actuates the moving part 72 b in the X-direction or the θZ-direction. When the moving part 72 b is moved in the +X-direction by the arm actuator 73, the substrate supporting part 72 a is inserted inside the heating part 70, and the substrate S is placed at a central portion of the heating part 70 as viewed in the Z-direction.
FIG. 7 is a cross-sectional view showing the configuration of the heating part 70.
As shown in FIG. 1 and FIG. 2, the heating part 70 is disposed on the platform 74. Further, as shown in FIG. 7, the heating part 70 has a first accommodation part 81, a second accommodation part 82, a first heating plate 83, a second heating plate 84, a lifting part 85, a sealing part 86, a gas supply part 87 and an exhaust part 88.
The first accommodation part 81 is formed in the shape of a rectangular open box as viewed in the Z-direction, and is mounted on the bottom of the second chamber CB2 such that the opening faces the +Z side. The second accommodation part 82 is formed in the shape of a rectangular open box as viewed in the Z-direction, and is disposed such that the opening faces the first accommodation part 81. The second accommodation part 82 is movable in the Z direction by using a lifting mechanism (not shown). By superimposing the edge portion 82 a of the second accommodation part 82 on the edge 81 a of the first accommodation part 81, the inside of the first accommodation part 81 and the second accommodation part 82 is closed.
The first heating plate 83 is accommodated in the first accommodation part 81. The first heating plate 83 heats a substrate S in a state where the substrate S is mounted on the first heating plate 83. The first heating plate 83 is formed of, for example, quartz or the like, and is provided with a heating device such as an infrared device or a hot plate inside thereof. The temperature of the first heating plate 83 is adjustable, for example, from about 200 to 800° C. The first heating part 83 has a plurality of through-holes 83 a formed thereon. The through-holes 83 a allow part of the lifting part 85 to penetrate therethrough.
The second heating plate 84 is accommodated in the second accommodation part 82. The second heating plate 84 is formed of, for example, a metal material, and is provided with a heating device such as an infrared device or a hot plate inside thereof. The temperature of the second heating plate 84 is adjustable, for example, from about 200 to 800° C. The second heating plate 84 is provided to be movable independently from the second accommodation part 82 in the Z direction by a lifting mechanism (not shown). By moving the second heating plate 84 in the Z direction, the interval between the second heating plate 84 and the substrate S can be adjusted.
The lifting part 85 moves the substrate S between the arm part 71 and the first heating plate 83. The lifting part 85 has a plurality of support pins 85 a and a moving part 85 b which is movable in the Z direction while holding the support pins 85 a. For easier discrimination of the drawings, in FIG. 7, a configuration is shown in which two support pins 85 a are provided. However, in practice, it is possible to provide, for example, sixteen support pins 85 a (see FIG. 7). The plurality of through-holes 83 a provided on the first heating plate 83 are arranged at positions corresponding to the plurality of support pins 85 a as viewed in the Z direction.
The sealing part 86 is formed on the edge portion 81 a of the first accommodation part 81. As the sealing part 86, for example, an O-ring formed by a resin material or the like can be used. The sealing part 86 seals the first accommodation part 81 and the second accommodation part 82 in a state where the edge portion 82 a of the second accommodation part 82 is superimposed on the first edge 81 a of the first accommodation part 81. In this manner, the inside of the first accommodation part 81 and the second accommodation part 82 can be closed.
The gas supply part 87 supplies a nitrogen gas or the like to the treatment room 60 a. The gas supply part 87 is connected to the +Z-side face of the second chamber CB2. The gas supply part 87 has a gas supply source 87 a such as a gas bomb or a gas pipe, and a connection pipe 87 b which connects the gas supply source 87 a with the second chamber CB2.
The exhaust part 88 suctions the treatment room 60 a, and discharges the gas in the treatment room 60 a outside the second chamber CB2. The exhaust part 88 is connected to the −Z-side face of the second chamber CB2. The exhaust part 88 has a suction source 88 a such as a pump, and a connection pipe 88 b which connects the suction source 88 a with the second chamber CB2.
Further, in the present embodiment, solvent concentration sensors SR3 and SR4 are provided. Like the aforementioned solvent concentration sensors SR1 and SR2, the solvent concentration sensors SR3 and SR4 detects the concentration of the solvent (in the present embodiment, hydrazine) for the liquid material in the ambient atmosphere, and sends the detection results to the control part CONT. The solvent concentration sensor SR3 is provided on the platform 74 on the +Y side of the heating part 70 within the treatment room 60 a. The solvent concentration sensor SR3 is provided at a position remote from the heating part 70. The solvent concentration sensor SR4 is provided outside the second chamber CB2. In the present embodiment, for detecting the concentration of hydrazine which has a larger specific gravity than air, like the solvent concentration sensors SR1 and SR2, the solvent concentration sensors SR3 and SR4 are disposed on the lower side of the transport path of the substrate S in the vertical direction. Further, by providing a solvent concentration sensor SR4 outside the second chamber CB2, it becomes possible to detect leakage of hydrazine from the second chamber CB2.
(Substrate Transport Path)
The second opening 12 of the substrate loading/unloading part LU, the first opening 21 and the second opening 22 of the coating part CT, the first opening 51 and the second opening 52 of the vacuum drying part VD and the opening 61 of the baking part BK are provided along a line in parallel to the X-direction. Thus, the substrate S is moved along a line in the X-direction. Further, in the path from the substrate loading/unloading part LU to the heating part 70 of the baking part BK, the position in the Z-direction is maintained. Thus, stirring of the gas around the substrate S can be suppressed.
(Anti-Chamber)
As shown in FIG. 1, the first chamber CB1 has anti-chambers AL1 to AL3 connected thereto.
The anti-chambers AL1 to AL3 are provided to communicate with the inside and outside of the first chamber CB1. Each of the anti-chambers AL1 to AL3 is a path through which a component of the treatment room 20 a is taken out of the first chamber CB1 or the component is placed into the treatment room 20 a from outside the first chamber CB1.
The anti-chamber AL1 is connected to the ejection part 31. The nozzle NZ provided in the ejection part 31 can be taken out of or placed into the treatment room 20 a via the anti-chamber AL1. The anti-chamber AL2 is connected to the liquid material supply part 33. The liquid material supply part 33 can be taken out of or placed into the treatment room 20 a via the anti-chamber AL2.
The anti-chamber AL3 is connected to a liquid material preparation part 36. In the liquid material preparation part 36, a liquid can be taken out of or placed into the treatment room 20 a via the anti-chamber AL3. The anti-chamber AL3 is formed to have a size which allows the substrate S to pass through. Therefore, for example, when a test coating of the liquid material is to be conducted in the coating part CT, a substrate S prior to treatment can be supplied to the treatment room 20 a from the anti-chamber AL3. Further, the substrate S after the test coating can be taken out from the anti-chamber AL3. Moreover, the substrate S can be taken out from the anti-chamber AL3 temporarily in emergency.
The second chamber CB2 has an anti-chamber AL4 connected thereto.
The anti-chamber AL4 is connected to the heating part 70. The anti-chamber AL4 is formed to have a size which allows the substrate S to pass through. Therefore, for example, when heating of the substrate S is to be conducted in the heating part 70, the substrate S can be supplied to the treatment room 60 a from the anti-chamber AL4. Further, the substrate S after the heat treatment can be taken out from the anti-chamber AL4.
(Glove Part)
As shown in FIG. 1, the first chamber CB1 has a glove part GX1 connected thereto. Further, the second chamber CB2 has a glove part GX2 connected thereto.
The glove parts GX1 and GX2 are parts where an operator accesses the inside of the first chamber CB1 and the second chamber CB2. By inserting the hands inside the glove parts GX1 and GX2, the operator can conduct maintenance inside the first chamber CB1 and the second chamber CB2. The glove parts GX1 and GX2 are formed to have a bag-like shape. The glove parts GX1 and GX2 are respectively provided at a plurality of portions on the first chamber CB1 and the second chamber CB2. A sensor may be provided inside the first chamber CB1 and the second chamber CB2 which detects whether or not an operator has put his hand in the glove part GX1 or GX2.
(Gate Valve)
Between the second opening 12 of the substrate loading/unloading part LU and the first opening 21 of the coating part CT, a gate valve V1 is provided. The gate valve V1 is provided to be movable in the Z-direction by an actuator (not shown). By moving the gate valve V1 in the Z-direction, the second opening 12 of the substrate loading/unloading part LU and the first opening 21 of the coating part CT are simultaneously opened or closed. When the second opening 12 and the first opening 21 are simultaneously opened, a substrate S can be moved through the second opening 12 and the first opening 21.
Between the second opening 22 of the first chamber CB1 and the first opening 51 of the third chamber CB3, a gate valve V2 is provided. The gate valve V2 is provided to be movable in the Z-direction by an actuator (not shown). By moving the gate valve V2 in the Z-direction, the second opening 22 of the first chamber CB1 and the first opening 51 of the third chamber CB3 are simultaneously opened or closed. When the second opening 22 and the first opening 51 are simultaneously opened, a substrate S can be moved through the second opening 22 and the first opening 51.
Between the second opening 52 of the third chamber CB3 and the opening 61 of the second chamber CB2, a gate valve V3 is provided. The gate valve V3 is provided to be movable in the Z-direction by an actuator (not shown). By moving the gate valve V3 in the Z-direction, the second opening 52 of the third chamber CB3 and the opening 61 of the second chamber CB2 are simultaneously opened or closed. When the second opening 52 and the opening 61 are simultaneously opened, a substrate S can be moved through the second opening 52 and the opening 61.
(Control Device)
The control part CONT is a part which has the overall control of the coating apparatus CTR. Specifically, the control part CONT controls the operations of the substrate loading/unloading part LU, the coating part CT, the vacuum drying part VD, the baking part BK and the gate valves V1 to V3. As an example of the adjusting operation, the control part CONT controls the amount of gas to be supplied from the gas supply part 37 a, based on the detection results of the solvent concentration sensors SR1 to SR4. The control part CONT has a timer or the like (not shown) for measuring the treatment time.
(Coating Method)
Next, a coating method according to one embodiment of the present invention will be described. In this embodiment, a coating film is formed on the substrate S by using the coating apparatus CTR having the above-described configuration. The operations performed by the respective parts of the coating apparatus CTR are controlled by the control part CONT.
Firstly, the control part CONT loads a substrate S on the substrate loading/unloading part LU from the outside. In this case, the control part CONT closes the gate valve V1, opens the lid portion 14 and accommodates the substrate S in the accommodation room 10 a of the chamber 10. After the substrate S is accommodated in the accommodation room 10 a, the control part CONT closes the lid portion 14.
After the lid portion 14 is closed, the control part CONT opens the gate valve V1, so as to communicate the accommodation room 10 a of the chamber 10 with the treatment room 20 a of the first chamber CB1 of the coating part CT. After opening the gate valve V1, the control part CONT transports the substrate S in the X-direction using the substrate transporting part 15.
After a portion of the substrate S has been inserted into the treatment room 20 a of the first chamber CB1, the control part CONT uses the substrate transporting part 25 to completely load the substrate S into the treatment room 20 a. After the substrate S has been loaded, the control part CONT closes the gate valve V1. After closing the gate valve V1, the control part CONT transports the substrate S to the treatment stage 28.
FIG. 8 is a diagram showing a simplified configuration of the coating part CT in which part of the components have been abbreviated. Herebelow, the same applies to FIG. 9 to FIG. 12. As shown in FIG. 8, when the substrate S is mounted on the treatment stage 28, a coating treatment is conducted by the coating part CT. Prior to the coating treatment, the control part CONT closes the gate valves V1 and V2, and conducts supplying and suctioning of an inert gas using the gas supplying part 37 a and the gas exhaust part 37 b.
By this operation, the atmosphere and the pressure of the treatment room 20 a can be adjusted. After adjusting the atmosphere and the pressure of the treatment room 20 a, the control part CONT uses the nozzle actuator NA (not shown in FIG. 8) to move the nozzle NZ from the nozzle standby part 44 to the nozzle-tip control part 45. Thereafter, during the coating treatment, the control part CONT continuously conducts the adjusting operation of the atmosphere and the pressure of the treatment room 20 a.
When the nozzle NZ reaches the nozzle-tip control part 45, as shown in FIG. 9, the control part CONT conducts a preliminary ejection operation of the nozzle NZ. In the preliminary ejection operation, the control part CONT ejects the liquid material Q from the ejection opening OP. After the preliminary ejection operation, as shown in FIG. 10, the control part CONT moves the wiping part 45 a along the guide rail 45 b in the X-direction, so as to wipe the tip TP of the nozzle NZ and the inclined part in the vicinity thereof.
After wiping the tip TP of the nozzle NZ, the control part CONT moves the nozzle NZ to the treatment stage 28. After the ejection opening OP of the nozzle NZ reaches the −Y-side end of the substrate S, as shown in FIG. 11, the control part CONT ejects the liquid material Q from the ejection opening OP to the substrate S while moving the nozzle NZ in the +Y-direction at a predetermined speed.
Herebelow, a series of operations for ejecting a liquid material Q from the ejection opening OP of the nozzle NZ will be described. Firstly, the control part CONT connects the first port 104 a with the pipe 105 in advance. In this state, the control part CONT applies pressure to the first liquid material accommodation part 33 a and the second liquid material accommodation part 33 b, so as to discharge the liquid material contained in the first liquid material accommodation part 33 a and the second liquid material accommodation part 33 b. By this operation, the liquid material accommodated in the first liquid material accommodation part 33 a flows into the container 91 of the air vent tank 102 via the pipe 101 and the inlet 101 a, and the liquid material accommodated in the second liquid material accommodation part 33 b flows into the container 91 of the air vent tank 102 via the pipe 121 and the inlet 121 a.
Further, the control part CONT uses the air vent tank 102 to remove any gas from the liquid material. Thereafter, the control part CONT discharges the liquid material to the pipe 103 on the downstream side of the air vent tank 102. The liquid material which flows through the pipe 103 reaches the first port 104 a in a state where foreign matters have been removed by the filter 103 a.
Since the first port 104 a is connected to the pipe 105 in advance by the control part CONT, the liquid material which reaches the first port 104 a flows into the pipe 105 via the first port 104 a. The liquid material which has flowed into the pipe 105 reaches the discharge pump 106.
After the liquid material reaches the discharge pump 106, the control part CONT actuates the discharge pump 106, and discharges the liquid material to the pipe 107. The liquid material discharged to the pipe 107 diverges and flows into the nozzle pipe 108 and the nozzle pipe 109, and flows into the inside of the nozzle NZ via the inlet 108 a and the inlet 109 a. The liquid material which passes through the nozzle pipe 109 flows into the inside of the nozzle NZ via the manifold NZh.
Thereafter, the control part CONT adjusts the pressure of the discharge pump 106, so as to eject the liquid material Q from the nozzle NZ. The ejected liquid material Q is disposed, for example, on a substrate S, and a coating film is formed.
After forming a coating film of the liquid material Q on a predetermined region of the substrate S, the control part CONT uses the substrate transporting part 25 to move the substrate S from the treatment stage 28 to the second stage 26B in the +X-direction. Further, the control part CONT moves the nozzle NZ in the −Y-direction, and returns the nozzle NZ to the nozzle standby part 44.
When the substrate S reaches the second opening 22 of the first chamber CB1, as shown in FIG. 13, the control part CONT opens the gate valve V2, and transports the substrate S from the first chamber CB1 to the second chamber CB2 (transporting step). In the transporting step, the substrate S passes through the third chamber CB3 disposed at the connection part CN. When the substrate S passes through the third chamber CB3, the control part CONT conducts a drying treatment of the substrate S using the vacuum drying part VD. Specifically, after the substrate S is accommodated in the treatment room 50 a of the third chamber CB3, as shown in FIG. 14, the control part CONT closes the gate valve V2.
After closing the gate valve V2, the control part CONT uses the lifting mechanism 53 a to adjust the position of the heating part 53 in the Z-direction. Thereafter, as shown in FIG. 15, the control part CONT uses the gas supply part 58 to adjust the atmosphere inside the treatment room 50 a and uses the gas exhaust part 59 to reduce the pressure inside the treatment room 50 a. When the pressure inside the treatment room 50 a is reduced by this operation, evaporation of the solvent contained in the coating film of the liquid material Q formed on the substrate S is promoted, and the coating film is dried. The control part CONT may adjust the position of the heating part 53 in the Z-direction using the lifting mechanism 53 a while reducing the pressure inside the treatment room 50 a using the gas exhaust part 59.
Further, as shown in FIG. 15, the control part CONT uses the heating part 53 to heat the coating film F on the substrate S. By this operation, evaporation of the solvent contained in the coating film F on the substrate S is promoted, so that the vacuum drying treatment can be conducted in a short time. The control part CONT may adjust the position of the heating part 53 in the Z-direction using the lifting mechanism 53 a while conducting the heating operation by the heating part 53.
After the vacuum drying treatment, as shown in FIG. 16, the control part CONT opens the gate valve V3, and transports the substrate S from the connection part CN to the second chamber CB2. After the substrate S is accommodated in the treatment room 60 a of the second chamber CB2, the control part CONT closes the gate valve V3.
As shown in FIG. 17, by the movement of the substrate supporting part 72 a, the substrate S is disposed above a central portion of the first heating plate 83. Thereafter, as shown in FIG. 18, the control part CONT moves the lifting part 85 in the +Z direction. By this operation, the substrate S leaves the substrate supporting part 72 a of the transport arm 72, and is supported by the plurality of support pins 85 a of the lifting part 85. In this manner, the substrate S is delivered from the substrate supporting part 72 a to the lifting part 85. After the substrate S has been supported by the support pins 85 a of the lifting part 85, the control part CONT withdraws the substrate supporting part 72 a outside the heating part 70 in the −X direction.
After withdrawing the substrate supporting part 72 a, as shown in FIG. 19, the control part CONT moves the lifting part 85 in the −Z direction, and also moves the second accommodation part 82 in the −Z direction. By this operation, the edge portion 82 a of the second accommodation part 82 is superimposed on the edge 81 a of the first accommodation part 81, so that the sealing part 86 is sandwiched between the edge portion 82 a and the edge portion 81 a. As a result, a closed baking room 80 is formed by the first accommodation part 81, the second accommodation part 82 and the sealing part 86.
After forming the baking room 80, as shown in FIG. 20, the control part CONT moves the lifting part 85 in the −Z direction and mounts the substrate S on the first heating plate 83. After the substrate S has been mounted on the first heating plate 83, the control part CONT moves the second heating plate 84 in the −Z direction, so that the second heating plate 84 approaches the substrate S. The control part CONT appropriately adjusts the position of the second heating plate in the Z direction.
After adjusting the position of the second heating plate 84 in the Z direction, as shown in FIG. 21, a nitrogen gas or a hydrogen sulfide gas is supplied to the baking room 80 by using the gas supply part 87, and the baking room is suctioned by using the exhaust part 88. By this operation, not only the atmosphere and pressure inside the baking room 80 are adjusted, but also a stream of the nitrogen gas or the hydrogen sulfide gas is formed from the second accommodation part 82 to the first accommodation part 81. In a state where the stream of the nitrogen gas or the hydrogen sulfide gas is formed, the control part CONT actuates the first heating plate 83 and the second heating plate 84, so as to perform the baking operation of the substrate S (heating step). By this operation, the solvent component is evaporated from the coating film F on the substrate S, and bubbles contained in the coating film F are removed. Further, by the stream of the nitrogen gas or the hydrogen sulfide gas, the solvent component evaporated from the coating films F and the bubbles are swept away, and suctioned by the exhaust part 88.
In addition, in the baking operation, at least one of the metal components contained in the coating films F is heated to its melting point or higher, so as to dissolve at least a portion of the coating film F. For example, in the case where the coating film F is used for a CZTS solar cell, among the components that constitute the coating film F, Sn, S and Se are heated to their melting points or higher, so as to liquefy these substances and aggregate the coating film F. Thereafter, the coating film F is cooled to a temperature at which the coating film F is solidified (cooling step). By solidifying the coating film F, the strength of the coating films F can be enhanced.
After the baking operation has been completed, the control part CONT transports the substrate S in the −X direction. Specifically, the substrate S is unloaded from the baking part BK via the heating part 70, the arm part 71 and the substrate guide stage 66, and is returned to the substrate loading/unloading part LU via the vacuum drying part VD and the coating part CT (second transporting step). After the substrate S has been returned to the substrate loading/unloading part LU, the control part CONT opens the lid portion 14 in a state where the gate valve V1 is closed. Thereafter, an operator collects the substrate S in the chamber 10, and accommodates a new substrate S in the accommodation room 10 a of the chamber 10.
In the case where, after the substrate S has been returned to the substrate loading/unloading part LU, another coating film is formed to be superimposed on the coating film F formed on the substrate S, the control part CONT transports the substrate S to the coating part CT again, and repeats the coating treatment, the vacuum drying treatment and the baking treatment. In this manner, coating film F is laminated on the substrate S.
In the aforementioned coating method, with respect to the liquid material Q supplied to the nozzle NZ, when the dispersion of the components in the solvent is unsatisfactory, the liquid material Q is coated on the substrate S in a state where the there is fluctuation in the concentration of the components. As a result, there is a possibility that the film property of the coating film varies.
Thus, after allowing the liquid material from the first liquid material accommodation part 33 a and the liquid material from the second liquid material accommodation part 33 b to flow into the container 91 of the air vent tank 102, as shown in FIG. 22, the control part CONT oscillates an ultrasonic wave from the ultrasonic wave oscillator 92 to the liquid material Q accommodated in the container 91 (ultrasonic wave oscillating step).
In the liquid material Q which has been subjected to oscillation of ultrasonic wave, the metals which are components of the liquid material Q becomes easier to be dispersed in the solvent by the energy of the ultrasonic wave. The timing to start the oscillation of ultrasonic wave and the oscillation time can be controlled, for example, by the control part CONT. The timing to start the oscillation and the oscillation time can be predetermined through experiment or simulation.
Subsequently, as shown in FIG. 23, the control part CONT uses the stirrer 93 to stir the liquid material Q while oscillating an ultrasonic wave to the liquid material Q (stirring step). In this step, since stirring is conducted in a state where the metals can be easily dispersed in the solvent, the plurality of metals are easily dispersed in the solvent.
However, when oscillation of an ultrasonic wave or stirring is conducted as described above, there is a possibility that the temperature of the liquid material Q is changed. As a countermeasure, upon conducting the oscillation of an ultrasonic wave and the stirring, the control part CONT controls the temperature of the liquid material Q. Specifically, the control part CONT actuates the circulation part 94 d of the temperature control part 94, so as to allow the temperature control medium 94 b to pass through the flow path 94 c formed in the jacket member 94 a (temperature controlling step). By virtue of this step, the change in the temperature of the temperature control medium 94 b can be suppressed, thereby maintaining the temperature of the liquid material Q at a desired temperature.
Further, by virtue of this step, the plurality of metals can be appropriately dispersed in the solvent, and the liquid material Q can be accommodated in the container 91 in a state where the temperature thereof is maintained at an appropriate temperature. Thus, when the liquid material Q in the container 91 is supplied to the nozzle NZ, and the liquid material is ejected from the ejection opening OP to the substrate S, a coating film can be formed with a stable film quality.
As described above, according to the present embodiment, by virtue of including a coating part CT having a nozzle NZ which ejects a liquid material Q containing a solvent and a plurality of metals to a substrate S, a container 91 which is connected to the nozzle NZ and stores the liquid material Q, and an ultrasonic wave oscillator 92 which oscillates an ultrasonic wave to the liquid material Q stored in the container 91, it becomes possible to provided a state where an ultrasonic wave is oscillated to the liquid material Q, so that the plurality of metals can be easily dispersed in the solvent. As a result, a liquid material Q in an excellent mixing state can be coated, thereby preventing variation in the film property of the coating film.
The technical scope of the present invention is not limited to the above-described embodiment, but may be appropriately modified into various forms without departing from the spirit of the present invention.
In the aforementioned embodiment, the coating part CT has a configuration which uses a slit-type nozzle NZ, but the present invention is not limited thereto. For example, a center-dripping-type coating part or an ink jet coating part may be used. Alternatively, for example, the liquid material disposed on the substrate S may be diffused by using a squeezer or the like so as to be coated thereon.
Further, in the aforementioned embodiment, when a configuration in which the coating apparatus CTR is accommodated in one room is employed, a gas supply/exhaust part which adjusts the atmosphere inside the room may be provided. In such a case, hydrazine present in the atmosphere inside the room may be discharged using the gas supply/exhaust part, thereby more reliably suppressing change in the coating environment.
In the aforementioned embodiment, explanation was given taking example of a configuration in which the baking operation is conducted by the baking part BK in the second chamber CB2. However, the present invention is not limited thereto. For example, as shown in FIG. 24, a configuration may be employed in which a fourth chamber CB4 is provided at a position different from the second chamber CB2, and the substrate S is heated by a heating part HT provided on the fourth chamber CB4.
In this case, for example, a coating film F is laminated on the substrate S, and then, a heat treatment can be conducted for baking the laminated coating film F by the heating part HT of the fourth chamber CB4. In the second heating step, the heat treatment for heating the coating film F is conducted at a heating temperature higher than that in the heat treatment by the baking part BK. By this heating treatment, the solid contents (metal components) of the laminated coating film F can be crystallized, thereby further enhancing the film quality of the coating film F.
The heating after laminating the coating film F on the substrate S may be performed by the baking part BK of the second chamber CB2. In such a case, in the baking part BK, the heating temperature for baking the laminated coating film F can be controlled to become higher than the heating temperature for baking each layer of the coating film F.
In the aforementioned embodiment, explanation was given taking example of a configuration in which a lifting mechanism 53 a moves the heating part 53 to adjust the distance between the substrate S and the heating part 53 within the third chamber CB3. However, the present invention is not limited thereto. For example, a configuration may be employed in which the lifting mechanism 53 a is capable of moving not only the heating part 53, but also the substrate S in the Z direction. Alternatively, a configuration in which the lifting mechanism 53 a is capable of moving only the substrate S in the Z direction may be employed.
In the aforementioned embodiment, explanation was given taking example of a configuration in which the heating part 53 is provided on the −Z side (lower side in the vertical direction) of the substrate S in the vacuum drying part VD. However, the present invention is not limited thereto. For example, a configuration in which the heating part 53 is provided on the +Z side of the substrate S may be employed. Alternatively, a configuration may be employed in which the heating part 53 is movable between a position on the −Z side of the substrate S and a position on the +Z side of the substrate S. In this case, the heating part 53 has a shape which enables the heating part 53 to pass through the plurality of rollers 57 constituting the substrate transporting part 55 (e.g., the heating part 53 is provided with openings).
Furthermore, with respect to the configuration of the coating apparatus CTR, as shown in FIG. 25 for example, a first chamber CB1 having a coating part CT, a connection part CN having a vacuum drying part VD and a second chamber CB2 having a baking part BK may be repeatedly arranged on the +X-side of the substrate loading/unloading part LU.
In FIG. 25, a configuration in which the first chamber CB1, the connection part CN and the second chamber CB2 are repeatedly arranged three times is shown. However, the present invention is not limited to this configuration, and a configuration in which the first chamber CB1, the connection part CN and the second chamber CB2 are repeatedly arranged twice, or a configuration in which the first chamber CB1, the connection part CN and the second chamber CB2 are repeatedly arranged four times may be employed.
According to this configuration, since the first chamber CB1, the connection part CN and the second chamber CB2 are repeatedly arranged in series in the X-direction, the substrate S can be transported in one direction (+X-direction), and there is no need to transport the substrate S back and forth. Therefore, the step of laminating the coating film on the substrate S can be continuously performed. As a result, coating films can be efficiently formed on the substrate S.
In the aforementioned embodiment, explanation was given taking example of a configuration in which the ultrasonic wave oscillator 92 is provided along the outer periphery of the container 91. However, the present invention is not limited thereto. For example, as shown in FIG. 26, a configuration in which the ultrasonic wave oscillator 92 is provided at a bottom portion of the container 91 may be employed. In FIG. 26, the ultrasonic wave oscillator 92 is disposed such that the emission face 92 a faces the bottom portion of the container 91. By virtue of this configuration, an ultrasonic wave can be oscillated to the inside of the container 91 without passing through the jacket member 94 a of the temperature control part 94 and the like. As a result, the oscillation efficiency of the ultrasonic wave can be enhanced.
Alternatively, for example, as shown in FIG. 27, a configuration may be employed in which an opening 94 e is formed at a portion of the temperature control part 94, and the ultrasonic wave oscillator 92 is inserted into the opening 94 e. The opening 94 e is formed to expose the outer periphery of the container 91. In FIG. 27, a configuration is shown in which an ultrasonic wave oscillator 92 formed in the shape of a rod is inserted into the opening 94 e. The emission face 92 a of the ultrasonic wave oscillator 92 is provided at a tip on the container 91 side. By virtue of this configuration, an ultrasonic wave can be efficiently oscillated to the liquid material Q in the container 91.
In addition to the configuration of the aforementioned embodiment, for example, as shown in FIG. 28, a detection part 95 which detects the state of the liquid material Q may be provided. As the detection part 95, a device which detects the size of the particles contained in the liquid material as the state of the liquid material Q (the dispersion state of the liquid material Q) can be used. The detection part is connected to, for example, the inside of the container 91 via a pipe 95 a, and is capable of collecting a portion of the liquid material Q in the container 91 as a sample. Further, the detection part 95 may have a configuration in which not only the particles, but also the viscosity of the liquid, the color of the liquid and the like are detected as the state of the liquid material Q.
In the aforementioned embodiment, explanation was given taking example of a configuration in which the timing of oscillating an ultrasonic wave and the oscillation time are controlled, based on the predetermined values. However, in the configuration shown in FIG. 28, the timing of oscillating an ultrasonic wave from the ultrasonic wave oscillator 92 and the oscillation time can be controlled depending on the detection results of the detection part 95. In this case, for example, when the size of the components of the liquid material Q is large, it can be presumed that the dispersion is unsatisfactory. Thus, the control part CONT actuates the ultrasonic wave oscillator 92 to form a state where the components can be easily dispersed.
Alternatively, for example, as shown in FIG. 29, a configuration may be employed in which a solvent supplying part 142 for supplying only the solvent of the liquid material Q to the container 91 is provided, and the control part CONT allows the solvent supplying part 142 to supply the solvent to the container 91 via a pipe 141, depending on the detection results of the detection part 95. Also in this case, it becomes possible to form a state where the components can be easily dispersed. The control part CONT may not only allow the solvent supplying part 142 to supply the solvent to the container 91 depending on the detection results of the detection part 95, but also control the timing of oscillating an ultrasonic wave from the ultrasonic wave oscillator 92 and the oscillation time.
In the aforementioned embodiment, explanation was given taking example of a configuration in which the temperature control part 94 is provided around the air vent tank 102, and the ultrasonic wave oscillator 92 is provided on the outer side of the temperature control part 94. However, the present invention is not limited thereto. For example, as shown in FIG. 30, a configuration may be employed in which the ultrasonic wave oscillator 92 is provided around the air vent tank 102, and the temperature control part 94 is provided on the outer side of the ultrasonic wave oscillator 92. In this case, the temperature control part can control the temperature of both the temperature control part 94 and the ultrasonic wave oscillator 92.
With respect to the ultrasonic wave oscillator 92, for example, as shown in FIG. 31, a configuration may be employed in which the ultrasonic wave oscillator 92 is provided over the entire periphery of the air vent tank 102. In FIG. 31, although the temperature control part 94 is omitted, the temperature control part 94 may be provided between the air vent tank 102 and the ultrasonic wave oscillator 92, or on the outer side of the ultrasonic wave oscillator 92.
While preferred embodiments of the invention have been described and illustrated above, it should be understood that these are exemplary of the invention and are not to be considered as limiting. Additions, omissions, substitutions, and other modifications can be made without departing from the spirit or scope of the present invention. Accordingly, the invention is not to be considered as being limited by the foregoing description, and is only limited by the scope of the appended claims.

Claims

What is claimed is:

1. A coating apparatus comprising:

a coating part having a nozzle which ejects a liquid material comprising a solvent and a plurality of metals to a substrate;

a storing part which is connected to the nozzle and stores the liquid material; and

an ultrasonic wave oscillating part which oscillates an ultrasonic wave to the liquid material stored in the storing part.

2. The coating apparatus according to claim 1, further comprising a stirring part which stirs the liquid material stored in the storing part.

3. The coating apparatus according to claim 1, further comprising a temperature control part which controls the temperature of the liquid material.

4. The coating apparatus according to claim 3, wherein the temperature control part comprises:

a jacket member which is provided at at least a portion around the storing part and has a flow path for a temperature control medium formed therein; and

a circulation part which allows the temperature control medium to flow through the flow path formed inside the jacket member.

5. The coating apparatus according to claim 4, wherein the ultrasonic wave oscillating part comprises an emission part which is provided outside the jacket member and emits the ultrasonic wave to the storing part.

6. The coating apparatus according to claim 5, wherein the jacket member is provided with an opening which exposes the storing part, and wherein the emission part is provided at the opening.

7. The coating apparatus according to claim 1, further comprising a detection part which detects the state of the liquid material.

8. The coating apparatus according to claim 7, further comprising a control part which actuates the ultrasonic wave oscillating part depending on the detection results of the detection part.

9. The coating apparatus according to claim 8, further comprising a solvent supplying part which supplies the solvent to the storing part, wherein the control part supplies the solvent from the solvent supplying part to the storing part depending on the detection results of the detection part.

10. The coating apparatus according to claim 7, wherein the detection part detects the size of the particles contained in the liquid material as the state of the liquid material.

11. A coating method, comprising:

a storing step in which a liquid material comprising a solvent and a plurality of metals is stored in a storing part connected to a nozzle which ejects the liquid material to a substrate;

an ultrasonic wave oscillating step in which an ultrasonic wave is oscillated to the liquid material stored in the storing part; and

an ejection step in which the liquid material oscillated with the ultrasonic wave is ejected from the nozzle to the substrate.

12. The coating method according to claim 11, wherein the ultrasonic wave oscillating step comprises a stirring step in which the liquid material is stirred.

13. The coating method according to claim 11, wherein the ultrasonic wave oscillating step comprises a temperature controlling step in which the temperature of the liquid material is controlled.

14. The coating method according to claim 11, further comprising a detection step in which the state of the liquid material is detected.

15. The coating method according to claim 14, wherein the ultrasonic wave oscillating step is performed depending on the detection results of the detection step.

16. The coating method according to claim 15, further comprising a solvent supplying step in which the solvent is supplied to the storing part, wherein the solvent supplying step is performed depending on the detection results of the detection step.

17. The coating method according to claim 14, wherein the detection step comprises detecting the size of the particles contained in the liquid material as the state thereof.