Nothing Special   »   [go: up one dir, main page]

US20100193156A1 - Liquid circulation heating system and method of controlling the same - Google Patents

Liquid circulation heating system and method of controlling the same Download PDF

Info

Publication number
US20100193156A1
US20100193156A1 US12/693,724 US69372410A US2010193156A1 US 20100193156 A1 US20100193156 A1 US 20100193156A1 US 69372410 A US69372410 A US 69372410A US 2010193156 A1 US2010193156 A1 US 2010193156A1
Authority
US
United States
Prior art keywords
refrigerant
liquid
radiator
heat
heat pump
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/693,724
Inventor
Kazuo Nakatani
Yasuhiko Isayama
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Intellectual Property Management Co Ltd
Original Assignee
Panasonic Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Panasonic Corp filed Critical Panasonic Corp
Assigned to PANASONIC CORPORATION reassignment PANASONIC CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ISAYAMA, YASUHIKO, NAKATANI, KAZUO
Publication of US20100193156A1 publication Critical patent/US20100193156A1/en
Assigned to PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD. reassignment PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: PANASONIC CORPORATION
Assigned to PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD. reassignment PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD. CORRECTIVE ASSIGNMENT TO CORRECT THE ERRONEOUSLY FILED APPLICATION NUMBERS 13/384239, 13/498734, 14/116681 AND 14/301144 PREVIOUSLY RECORDED ON REEL 034194 FRAME 0143. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Assignors: PANASONIC CORPORATION
Abandoned legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D11/00Central heating systems using heat accumulated in storage masses
    • F24D11/02Central heating systems using heat accumulated in storage masses using heat pumps
    • F24D11/0214Central heating systems using heat accumulated in storage masses using heat pumps water heating system
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D19/00Details
    • F24D19/10Arrangement or mounting of control or safety devices
    • F24D19/1006Arrangement or mounting of control or safety devices for water heating systems
    • F24D19/1009Arrangement or mounting of control or safety devices for water heating systems for central heating
    • F24D19/1039Arrangement or mounting of control or safety devices for water heating systems for central heating the system uses a heat pump
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D3/00Hot-water central heating systems
    • F24D3/18Hot-water central heating systems using heat pumps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H15/00Control of fluid heaters
    • F24H15/20Control of fluid heaters characterised by control inputs
    • F24H15/212Temperature of the water
    • F24H15/215Temperature of the water before heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H15/00Control of fluid heaters
    • F24H15/20Control of fluid heaters characterised by control inputs
    • F24H15/212Temperature of the water
    • F24H15/219Temperature of the water after heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H15/00Control of fluid heaters
    • F24H15/20Control of fluid heaters characterised by control inputs
    • F24H15/281Input from user
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H15/00Control of fluid heaters
    • F24H15/30Control of fluid heaters characterised by control outputs; characterised by the components to be controlled
    • F24H15/335Control of pumps, e.g. on-off control
    • F24H15/34Control of the speed of pumps
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H15/00Control of fluid heaters
    • F24H15/30Control of fluid heaters characterised by control outputs; characterised by the components to be controlled
    • F24H15/375Control of heat pumps
    • F24H15/385Control of expansion valves of heat pumps
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/12Hot water central heating systems using heat pumps

Definitions

  • the present invention relates to a liquid circulation heating system for performing air-heating using a liquid and to a method of controlling the system.
  • JP 2008-39306 A proposes a liquid circulation heating system for producing hot water by a heat pump and storing the produced hot water in a hot water storage tank.
  • the hot water stored in the hot water storage tank is fed to, for example, a heating radiator placed indoors to radiate its heat, and then returned to the hot water storage tank.
  • the heat pump has a heat pump circuit for circulating a refrigerant.
  • the heat pump circuit includes, for example, a compressor, a radiator, an expansion valve, and an evaporator, which are connected by pipes. Heat is exchanged between a refrigerant and water in the radiator so as to heat the water, and thereby hot water is produced.
  • the increased pressure may exceed the upper limit pressure for ensuring the normal operation of the components of the heat pump.
  • the inventors of the present invention have considered that the increase in the high pressure of the refrigeration cycle can be suppressed by actively taking advantage of the phenomenon that when a zeotropic refrigerant mixture of refrigerants having different boiling points is used as a refrigerant, the composition of the refrigerant circulating through the heat pump circuit changes.
  • the present invention has been made in view of the above circumstances.
  • the present invention provides a liquid circulation heating system for performing air-heating by heating a liquid to produce a heated liquid and releasing heat of the heated liquid from a heating radiator.
  • This system includes a heat pump circuit for circulating a refrigerant, and this heat pump circuit includes a refrigerant radiator for heating the liquid by radiating heat from the refrigerant to produce the heated liquid.
  • the heat pump circuit is charged with a zeotropic refrigerant mixture of at least two refrigerants having different boiling points, as the refrigerant.
  • the system is configured so that a composition ratio of a higher boiling point refrigerant in the refrigerant circulating through the heat pump circuit increases when the liquid supplied to the refrigerant radiator has a relatively high temperature.
  • the present invention also provides a method of controlling a liquid circulation heating system for performing air-heating by heating a liquid to produce a heated liquid and releasing heat of the heated liquid from a heating radiator.
  • the liquid circulation heating system includes a heat pump circuit for circulating a refrigerant, and the heat pump circuit includes: a refrigerant radiator for heating the liquid by radiating heat from the refrigerant to produce the heated liquid; a compressor for compressing the refrigerant; a decompressor for decompressing the refrigerant; an evaporator for evaporating the refrigerant; and a vapor-liquid separator for separating the refrigerant into a gas refrigerant and a liquid refrigerant.
  • the heat pump circuit is charged with a zeotropic refrigerant mixture of at least two refrigerants having different boiling points, as the refrigerant.
  • This method includes the step of controlling an operation of the decompressor to reduce an amount of the liquid refrigerant in the vapor-liquid separator when the liquid supplied to the refrigerant radiator has a relatively high temperature.
  • the present invention makes it possible to suppress the increase in the high pressure of the refrigeration cycle when the temperature of the liquid supplied to the refrigerant radiator rises.
  • FIG. 1 is a schematic configuration diagram of a liquid circulation heating system according to a first embodiment of the present invention.
  • FIG. 2 is a Mollier diagram of a heat pump.
  • FIG. 3 is a diagram for explaining the fact that an increase in the high pressure of the refrigeration cycle is suppressed due to a change in the composition of the refrigerant circulating through the heat pump circuit.
  • FIG. 4 is a schematic configuration diagram of a liquid circulation heating system according to a second embodiment of the present invention.
  • FIG. 5 is a schematic configuration diagram of a liquid circulation heating system according to a third embodiment of the present invention.
  • FIG. 6 is a schematic configuration diagram of a heat pump of a first modification.
  • FIG. 7 is a schematic configuration diagram of a heat pump of a second modification.
  • FIG. 1 shows a liquid circulation heating system 1 A according to a first embodiment of the present invention.
  • This liquid circulation heating system 1 A heats a liquid to produce a heated liquid, releases heat of the heated liquid from a heating radiator 3 , and thereby performs air-heating, for example, in a room.
  • the liquid circulation heating system 1 A includes the heating radiator 3 , a heat pump 2 for producing the heated liquid, and an overall controller 5 for controlling the entire system.
  • the heating radiator 3 is connected directly to the heat pump 2 by a supply pipe 31 and a recovery pipe 32 to be described later, so that the liquid flows without stopping.
  • the hot water produced can be used directly for air-heating. Therefore, heat radiation loss is reduced, and as a result, energy conservation can be achieved.
  • the liquid for example, an antifreeze liquid containing propylene glycol or the like dissolved in water can be used, but water is preferably used because it is available at low cost and in large quantities. The following description will be made on the assumption that the liquid is water and the heated liquid is hot water.
  • the heat pump 2 has a heat pump circuit 20 for circulating a refrigerant.
  • This heat pump circuit 20 includes a compressor 21 for compressing the refrigerant, a radiator (refrigerant radiator) 22 for radiating heat from the compressed refrigerant, an expansion valve 23 serving as a decompressor for decompressing the refrigerant that has radiated heat, and an evaporator 24 for evaporating the decompressed refrigerant.
  • These components 21 to 24 are connected in series by pipes.
  • the heat pump 2 includes a heat pump controller (corresponding to a controller of the present invention) 26 for controlling the compressor 21 and the expansion valve 23 according to an instruction from the overall controller 5 .
  • radiator 22 heat is exchanged between the refrigerant and the water flowing through the radiator 22 so as to heat the water, and thereby hot water is produced.
  • evaporator 24 heat is exchanged between the refrigerant and air blown by a fan 25 , and thereby the refrigerant absorbs heat.
  • the heat pump circuit 20 is charged with, as a refrigerant, a zeotropic refrigerant mixture of at least two refrigerants having different boiling points.
  • a zeotropic refrigerant mixture means a refrigerant in which the mixture composition of a gas refrigerant is different from that of a liquid refrigerant in a vapor-liquid equilibrium state (i.e., the mixture ratio between the at least two refrigerants in the gas refrigerant is different from that in the liquid refrigerant).
  • the gas refrigerant contains a higher percentage of a low boiling point refrigerant, while the liquid refrigerant contains a higher percentage of a high boiling point refrigerant.
  • a mixed refrigerant include R407C that is a mixture of R32, R125, and R134a, a mixture of R32 and HFO-1234yf (2,3,3,3-tetrafluoropropene), and a mixture of R32, HFO-1234yf, and R125.
  • a zeotropic refrigerant mixture including a high boiling point refrigerant and a low boiling point refrigerant, with a difference in boiling point therebetween being 20° C. or more.
  • a high boiling point refrigerant consisting of R32 (having a boiling point of ⁇ 52° C.) and R125 (having a boiling point of ⁇ 49° C.) and a low boiling point refrigerant that is R134a (having a boiling point of ⁇ 26° C.)
  • a difference in boiling point between these high and low boiling point refrigerants is 23° C.
  • an accumulator 27 is provided between the evaporator 24 and the compressor 21 .
  • This accumulator 27 separates the refrigerant evaporated in the evaporator 24 into a gas refrigerant and a liquid refrigerant, and serves as the vapor-liquid separator of the present invention.
  • a zeotropic refrigerant mixture is used. Therefore, a liquid refrigerant, which is rich in a high boiling point refrigerant, is accumulated in the bottom portion of the accumulator 27 .
  • the zeotropic refrigerant mixture is a mixture of R32 (having a boiling point of ⁇ 52° C.) and HFO-1234yf (having a boiling point of ⁇ 29° C.)
  • a liquid refrigerant, which is rich in HFO-1234yf is accumulated in the bottom portion of the accumulator 27 .
  • the heating radiator 3 is a device for radiating heat from hot water flowing therethrough, and has an inlet for allowing the hot water to flow thereinto, and an outlet for allowing the hot water that has radiated its heat to flow therefrom.
  • a radiator to be placed in a room of a building may be used.
  • a hot water panel to be laid on a floor also may be used.
  • the outlet of the heating radiator 3 is connected to the radiator 22 by the supply pipe 31 for supplying water to the radiator 22 .
  • the inlet of the heating radiator 3 is connected to the radiator 22 by the recovery pipe 32 for recovering hot water produced in the radiator 22 .
  • the supply pipe 31 is provided with an incoming water temperature sensor 72 for detecting the temperature of water (hereinafter referred also as an “incoming water temperature”) to be supplied to the radiator 22 .
  • the supply pipe 31 also is provided with a pump 61 on the upstream side of the incoming water temperature sensor 72 .
  • the incoming water temperature sensor 72 is connected to the heat pump controller 26 .
  • the recovery pipe 32 is provided with a hot water temperature sensor 71 for detecting the temperature of the hot water produced in the radiator 22 .
  • the overall controller 5 includes a microcomputer, a digital signal processor (DSP), or the like, and is connected to the above-mentioned heat pump controller 26 , the hot water temperature sensor 71 , and the pump 61 , respectively.
  • DSP digital signal processor
  • the overall controller 5 rotates the pump 61 and sends an operation start signal to the heat pump controller 26 . Thereby, water is heated in the radiator 22 to produce hot water, and the produced hot water is fed to the heating radiator 3 . Thus, air-heating is performed.
  • the overall controller 5 controls the rotational rate of the pump 61 to regulate the flow rate of the water flowing through the supply pipe 31 so that the temperature of the water detected by the hot water temperature sensor 71 becomes a specified temperature (for example, 70° C.).
  • the heat pump controller 26 When the temperature of the water (incoming water temperature) supplied to the radiator 22 is relatively high, the heat pump controller 26 performs a control operation to reduce the amount of the liquid refrigerant in the accumulator 27 . Specifically, when the temperature detected by the incoming water temperature sensor 72 is higher than a predetermined temperature (for example, 55° C.), the heat pump controller 26 reduces the opening of the expansion valve 23 . When the opening of the expansion valve 23 is reduced, the refrigerant absorbs heat efficiently in the evaporator 24 and the dryness of the refrigerant flowing into the accumulator 27 increases. Thereby, the amount of the liquid refrigerant remaining in the accumulator 27 decreases. As a result, the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, which thereby suppresses the increase in the high pressure of the refrigeration cycle.
  • a predetermined temperature for example, 55° C.
  • the above-described phenomenon is explained below by taking, as an example, the case where the zeotropic refrigerant mixture is a mixture of R32 and HFO-1234yf.
  • full lines indicate the case where the refrigerant is R32 alone and the case where the refrigerant is HFO-1234yf alone
  • a single-dashed line indicates the case where the composition ratio of HFO-1234yf in the mixed refrigerant circulating through the heat pump circuit 20 has a certain value
  • a double-dashed line indicates the case where the composition ratio of HFO-1234yf is higher than the certain value.
  • the high pressure of the refrigeration cycle is located at Point a on the single-dashed line when the incoming water temperature is low. If the amount of the liquid refrigerant in the accumulator 27 is fixed, the composition of the refrigerant circulating through the heat pump circuit 20 does not change. Therefore, when the incoming water temperature rises to, for example, 65° C., the high pressure of the refrigeration cycle shifts from Point a to Point b along the single-dashed line. In the present embodiment, however, the amount of the liquid refrigerant remaining in the accumulator 27 decreases.
  • the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, and thus the high pressure of the refrigeration cycle shifts from Point a to Point c on the double-dashed line. Accordingly, the increase in the high pressure of the refrigeration cycle can be suppressed when the incoming water temperature rises.
  • the liquid refrigerant in the accumulator 27 does not necessarily have to disappear completely.
  • the heat pump controller 26 may stop reducing the opening of the expansion valve 23 to maintain it.
  • FIG. 4 shows a liquid circulation heating system 1 B according to a second embodiment of the present invention.
  • the same components as those in the first embodiment are designated by the same reference numerals and no further description is given.
  • the liquid circulation heating system 1 B of the second embodiment has basically the same configuration as the liquid circulation heating system 1 A of the first embodiment, except that the heating radiator 3 and the radiator 22 are connected via the hot water storage tank 8 .
  • the hot water storage tank 8 is a vertically cylindrical closed casing and is filled with water.
  • the lower portion of the hot water storage tank 8 is connected to the radiator 22 by the supply pipe 31 , and the upper portion thereof is connected to the radiator 22 by the recovery pipe 32 .
  • the pump 61 When the pump 61 is rotated, the water is guided from the lower portion of the hot water storage tank 8 to the radiator 22 by the supply pipe 31 , and the hot water produced in the radiator 22 is guided from the radiator 22 to the upper portion of the hot water storage tank 8 by the recovery pipe 32 . Thereby, the produced hot water is stored in the hot water storage tank 8 from the top thereof.
  • hot water temperature sensors 74 On the peripheral surface of the hot water storage tank 8 , hot water temperature sensors 74 for determining how much hot water remains in the tank 8 are provided separately from each other in the vertical direction. The hot water temperature sensors 74 are connected to the overall controller 5 .
  • a heat exchanger 92 for hot water supply is provided at an upper position in the hot water storage tank 8 , and a water inlet pipe 91 and a hot water outlet pipe 93 are connected to this heat exchanger 92 . That is, in the present embodiment, the produced hot water can be used as a heat source for hot water supply.
  • a heater 85 for re-heating the hot water also is provided at an upper position in the hot water storage tank 8 .
  • the inlet of the heating radiator 3 is connected to the upper portion of the hot water storage tank 8 by a feed pipe 81 , and the outlet of the heating radiator 3 is connected to the lower portion of the hot water storage tank 8 by a return pipe 82 .
  • a circulation pump 66 is provided in the return pipe 82 , but the circulation pump 66 may be provided in the feed pipe 81 .
  • the circulation pump 66 is connected to the overall controller 5 . When the circulation pump 66 is rotated, the hot water stored in the hot water storage tank 8 is fed to the heating radiator 3 through the feed pipe 81 , and the hot water is returned to the hot water storage tank 8 through the return pipe 82 after radiating heat in the heating radiator 3 .
  • the overall controller 5 determines that the amount of hot water remaining in the tank is less than the required amount based on the temperature detected by the hot water temperature sensors 74 , for example, during nighttime hours (for example, from 23:00 to 7:00), it rotates the pump 61 , and sends an operation start signal to the heat pump controller 26 . Thereby, water is heated in the radiator 22 to produce hot water, and the produced hot water is stored in the hot water storage tank 8 .
  • the overall controller 5 also controls the rotational rate of the pump 61 to regulate the flow rate of the water flowing through the supply pipe 31 so that the temperature of the water detected by the hot water temperature sensor 71 becomes a specified temperature (for example, 70° C.).
  • the heat pump controller 26 When the temperature of the water (incoming water temperature) supplied to the radiator 22 is relatively high, the heat pump controller 26 performs a control operation to reduce the amount of the liquid refrigerant in the accumulator 27 . Specifically, when the temperature detected by the incoming water temperature sensor 72 is higher than a predetermined temperature (for example, 55° C.), the heat pump controller 26 reduces the opening of the expansion valve 23 . When the opening of the expansion valve 23 is reduced, the refrigerant absorbs heat efficiently in the evaporator 24 and the dryness of the refrigerant flowing into the accumulator 27 increases. Thereby, the amount of the liquid refrigerant remaining in the accumulator 27 decreases. As a result, the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, which thereby suppresses the increase in the high pressure of the refrigeration cycle.
  • a predetermined temperature for example, 55° C.
  • the liquid refrigerant in the accumulator 27 does not necessarily have to disappear completely.
  • the heat pump controller 26 may stop reducing the opening of the expansion valve 23 to maintain it.
  • the overall controller 5 rotates the circulation pump 66 .
  • the hot water stored in the hot water storage tank 8 is fed to the heating radiator 3 , where heat is radiated from the hot water.
  • air-heating is performed.
  • liquid circulation heating system 1 B of the second embodiment described above high-temperature hot water stored in the hot water storage tank 8 can be fed to the heating radiator 3 even during the early stage of the air-heating operation. Therefore, air-heating can be started immediately after the heating switch is turned on.
  • FIG. 5 shows a liquid circulation heating system 1 C according to a third embodiment of the present invention.
  • the same components as those in the first and second embodiments are designated by the same reference numerals and no further description is given.
  • hot water stored in the hot water storage tank 8 can be used directly for hot water supply.
  • the water inlet pipe 91 is connected to the lower portion of the hot water storage tank 8
  • the hot water outlet pipe 93 is connected to the upper portion of the hot water storage tank 8 .
  • a heat exchanger 83 for exchanging heat between the hot water stored in the hot water storage tank 8 and a heat transfer liquid (secondary liquid) is provided.
  • the heat exchanger 83 is connected to the heating radiator 3 by the feed pipe 81 and the return pipe 82 .
  • the heat transfer liquid heated in the heat exchanger 83 is fed to the heating radiator 3 through the feed pipe 81 , and the heat transfer liquid is returned to the heat exchanger 83 through the return pipe 82 after radiating heat in the heating radiator 3 .
  • the heat transfer liquid for example, an antifreeze liquid can be used, but water preferably is used because it is available at low cost and in large quantities.
  • the overall controller 5 performs control in the same manner as in the second embodiment, the description thereof is not repeated here. It should be noted, however, that during the air-heating operation, the heat transfer liquid that has exchanged heat with the hot water stored in the hot water storage tank 8 radiates heat in the heating radiator 3 , that is, the heat of the hot water is transferred to the heating radiator 3 by the heat transfer liquid, and thereby air-heating is performed.
  • the temperature in the lower portion of the hot water storage tank 8 can be kept low because of the water supplied from the water inlet pipe 91 . Therefore, the low-temperature water can be supplied to the radiator 22 , and thus the efficiency of the heat pump 2 can be enhanced.
  • a heat pump 2 A as shown in FIG. 6 also can be employed.
  • this heat pump 2 A when the temperature of the water (incoming water temperature) supplied to the radiator 22 is relatively high, the refrigerant to be fed to the accumulator 27 from the evaporator 24 is heated.
  • the heat pump circuit 20 includes a heat exchanger (heater) 29 between the evaporator 24 and the accumulator 27 , and a bypass passage 29 A that bypasses the expansion valve 23 so as to pass through the heat exchanger 29 .
  • the heat exchanger 29 exchanges heat between the refrigerant flowing through the bypass passage 29 A and the refrigerant to be fed to the accumulator 27 from the evaporator 24 .
  • the bypass passage 29 is provided with an open/close valve 29 B on the upstream side of the heat exchanger 29 .
  • the open/close valve 29 B is connected to the heat pump controller 26 , and usually is closed by the heat pump controller 26 .
  • the heat pump controller 26 opens the open/close valve 29 B.
  • the open/close valve 29 B is opened, the refrigerant that has been evaporated in the evaporator 24 is heated further in the heat exchanger 29 , and the dryness of the refrigerant flowing into the accumulator 27 increases. Thereby, the amount of the liquid refrigerant remaining in the accumulator 27 decreases. As a result, the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, which thereby suppresses the increase in the high pressure of the refrigeration cycle.
  • the liquid refrigerant in the accumulator 27 does not necessarily have to disappear completely.
  • the heat pump controller 26 may stop increasing the opening of the open/close valve 29 B to maintain it.
  • the open/close valve 29 B does not necessarily have to be closed completely in its initial state.
  • the heat exchanger 29 is used as the heater of the present invention, but the heater of the present invention is not limited to the heat exchanger.
  • the heater of the present invention may be an electric heater, or the like. If the heat exchanger 29 and the bypass passage 29 A are provided as in the case of the first modification, however, the refrigerant to be fed to the accumulator 27 from the evaporator 24 can be heated by utilizing the heat of the refrigerant that has passed through the radiator 22 .
  • a heat pump 2 B as shown in FIG. 7 also can be employed.
  • a first expansion valve 23 A and a second expansion valve 23 B are used as the decompressor of the present invention.
  • the refrigerant is decompressed by the first expansion valve 23 A after radiating heat in the radiator 22 , and further decompressed by the second expansion valve 23 B after being decompressed by the first expansion valve 23 A.
  • a receiver 28 is provided between the first expansion valve 23 A and the second expansion valve 23 B. This receiver 28 separates the refrigerant decompressed by the first expansion valve 23 A into a gas refrigerant and a liquid refrigerant, and serves as the vapor-liquid separator of the present invention.
  • the heat pump controller 26 reduces the opening of the first expansion valve 23 A and increases the opening of the second expansion valve 23 B.
  • the refrigerant absorbs heat efficiently in the evaporator 24 and the dryness of the refrigerant flowing into the receiver 28 increases. Thereby, the amount of the liquid refrigerant remaining in the receiver 28 decreases.
  • the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, which thereby suppresses the increase in the high pressure of the refrigeration cycle.
  • the liquid refrigerant in the receiver 28 does not necessarily have to disappear completely.
  • the heat pump controller 26 may stop controlling the openings of the first expansion valve 23 A and the second expansion valve 23 B to maintain them.
  • the heat pump controller 26 serves as the controller of the present invention.
  • the heat pump controller 26 and the overall controller 5 may serve as the controller of the present invention.
  • an expander for recovering power from the expanding refrigerant also can be used.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Pump Type And Storage Water Heaters (AREA)
  • Steam Or Hot-Water Central Heating Systems (AREA)
  • Other Air-Conditioning Systems (AREA)
  • Central Heating Systems (AREA)

Abstract

A liquid circulation heating system includes a heat pump for producing a heated liquid and a heating radiator. The heat pump has a heat pump circuit in which a compressor, a radiator, a decompressor, and an evaporator are connected in series. The heat pump circuit is charged with a zeotropic refrigerant mixture of at least two refrigerants having different boiling points. The system is configured so that the composition ratio of a higher boiling point refrigerant in the refrigerant circulating through the heat pump circuit increases when the liquid supplied to the radiator has a relatively high temperature.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention relates to a liquid circulation heating system for performing air-heating using a liquid and to a method of controlling the system.
  • 2. Description of Related Art
  • Conventionally, there has been known a liquid circulation heating system for producing hot water by a boiler or an electric heater and performing air-heating using the hot water produced. In recent years, the use of a heat pump capable of producing hot water with high efficiency has been considered as an alternative heat source to a boiler and an electric heater. For example, JP 2008-39306 A proposes a liquid circulation heating system for producing hot water by a heat pump and storing the produced hot water in a hot water storage tank. In this liquid circulation heating system, the hot water stored in the hot water storage tank is fed to, for example, a heating radiator placed indoors to radiate its heat, and then returned to the hot water storage tank.
  • The heat pump has a heat pump circuit for circulating a refrigerant. The heat pump circuit includes, for example, a compressor, a radiator, an expansion valve, and an evaporator, which are connected by pipes. Heat is exchanged between a refrigerant and water in the radiator so as to heat the water, and thereby hot water is produced.
  • SUMMARY OF THE INVENTION
  • In the liquid circulation heating system, when the flow rate of the hot water fed to the heating radiator is high, the temperature of the water that flows from the heating radiator presumably does not drop so much. In this case, the temperature of the water supplied to the radiator of the heat pump rises. When the temperature of the water supplied to the radiator rises, the high pressure of the refrigeration cycle increases, as shown by a dotted line in FIG. 2.
  • When the high pressure of the refrigeration cycle increases, however, the increased pressure may exceed the upper limit pressure for ensuring the normal operation of the components of the heat pump.
  • In view of the above circumstances, it is an object of the present invention to provide a liquid circulation heating system capable of suppressing an increase in the high pressure of the refrigeration cycle when the temperature of the liquid supplied to the refrigerant radiator rises.
  • When the temperature of the liquid supplied to the refrigerant radiator rises, a high boiling point refrigerant causes a smaller increase in the high pressure of the refrigeration cycle than a low boiling point refrigerant does. Moreover, when a mixture of these high and low boiling point refrigerants is used, how much the high pressure of the refrigeration cycle increases as the temperature of the liquid supplied to the refrigerant radiator rises is determined by the mixture ratio between these refrigerants. Accordingly, the inventors of the present invention have considered that the increase in the high pressure of the refrigeration cycle can be suppressed by actively taking advantage of the phenomenon that when a zeotropic refrigerant mixture of refrigerants having different boiling points is used as a refrigerant, the composition of the refrigerant circulating through the heat pump circuit changes. The present invention has been made in view of the above circumstances.
  • The present invention provides a liquid circulation heating system for performing air-heating by heating a liquid to produce a heated liquid and releasing heat of the heated liquid from a heating radiator. This system includes a heat pump circuit for circulating a refrigerant, and this heat pump circuit includes a refrigerant radiator for heating the liquid by radiating heat from the refrigerant to produce the heated liquid. The heat pump circuit is charged with a zeotropic refrigerant mixture of at least two refrigerants having different boiling points, as the refrigerant. The system is configured so that a composition ratio of a higher boiling point refrigerant in the refrigerant circulating through the heat pump circuit increases when the liquid supplied to the refrigerant radiator has a relatively high temperature.
  • The present invention also provides a method of controlling a liquid circulation heating system for performing air-heating by heating a liquid to produce a heated liquid and releasing heat of the heated liquid from a heating radiator. The liquid circulation heating system includes a heat pump circuit for circulating a refrigerant, and the heat pump circuit includes: a refrigerant radiator for heating the liquid by radiating heat from the refrigerant to produce the heated liquid; a compressor for compressing the refrigerant; a decompressor for decompressing the refrigerant; an evaporator for evaporating the refrigerant; and a vapor-liquid separator for separating the refrigerant into a gas refrigerant and a liquid refrigerant. The heat pump circuit is charged with a zeotropic refrigerant mixture of at least two refrigerants having different boiling points, as the refrigerant. This method includes the step of controlling an operation of the decompressor to reduce an amount of the liquid refrigerant in the vapor-liquid separator when the liquid supplied to the refrigerant radiator has a relatively high temperature.
  • The present invention makes it possible to suppress the increase in the high pressure of the refrigeration cycle when the temperature of the liquid supplied to the refrigerant radiator rises.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a schematic configuration diagram of a liquid circulation heating system according to a first embodiment of the present invention.
  • FIG. 2 is a Mollier diagram of a heat pump.
  • FIG. 3 is a diagram for explaining the fact that an increase in the high pressure of the refrigeration cycle is suppressed due to a change in the composition of the refrigerant circulating through the heat pump circuit.
  • FIG. 4 is a schematic configuration diagram of a liquid circulation heating system according to a second embodiment of the present invention.
  • FIG. 5 is a schematic configuration diagram of a liquid circulation heating system according to a third embodiment of the present invention.
  • FIG. 6 is a schematic configuration diagram of a heat pump of a first modification.
  • FIG. 7 is a schematic configuration diagram of a heat pump of a second modification.
  • DETAILED DESCRIPTION OF THE INVENTION
  • Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings. It should be noted, however, that the embodiments described below are merely examples of the present invention, and should not be construed to limit the scope of the present invention.
  • First Embodiment
  • FIG. 1 shows a liquid circulation heating system 1A according to a first embodiment of the present invention. This liquid circulation heating system 1A heats a liquid to produce a heated liquid, releases heat of the heated liquid from a heating radiator 3, and thereby performs air-heating, for example, in a room. Specifically, the liquid circulation heating system 1A includes the heating radiator 3, a heat pump 2 for producing the heated liquid, and an overall controller 5 for controlling the entire system.
  • In the present embodiment, the heating radiator 3 is connected directly to the heat pump 2 by a supply pipe 31 and a recovery pipe 32 to be described later, so that the liquid flows without stopping. In the liquid circulation heating system 1A having such a configuration, the hot water produced can be used directly for air-heating. Therefore, heat radiation loss is reduced, and as a result, energy conservation can be achieved. As the liquid, for example, an antifreeze liquid containing propylene glycol or the like dissolved in water can be used, but water is preferably used because it is available at low cost and in large quantities. The following description will be made on the assumption that the liquid is water and the heated liquid is hot water.
  • The heat pump 2 has a heat pump circuit 20 for circulating a refrigerant. This heat pump circuit 20 includes a compressor 21 for compressing the refrigerant, a radiator (refrigerant radiator) 22 for radiating heat from the compressed refrigerant, an expansion valve 23 serving as a decompressor for decompressing the refrigerant that has radiated heat, and an evaporator 24 for evaporating the decompressed refrigerant. These components 21 to 24 are connected in series by pipes. The heat pump 2 includes a heat pump controller (corresponding to a controller of the present invention) 26 for controlling the compressor 21 and the expansion valve 23 according to an instruction from the overall controller 5.
  • In the radiator 22, heat is exchanged between the refrigerant and the water flowing through the radiator 22 so as to heat the water, and thereby hot water is produced. In the evaporator 24, heat is exchanged between the refrigerant and air blown by a fan 25, and thereby the refrigerant absorbs heat.
  • In the present embodiment, the heat pump circuit 20 is charged with, as a refrigerant, a zeotropic refrigerant mixture of at least two refrigerants having different boiling points. A zeotropic refrigerant mixture means a refrigerant in which the mixture composition of a gas refrigerant is different from that of a liquid refrigerant in a vapor-liquid equilibrium state (i.e., the mixture ratio between the at least two refrigerants in the gas refrigerant is different from that in the liquid refrigerant). When a comparison is made between the gas refrigerant and the liquid refrigerant, the gas refrigerant contains a higher percentage of a low boiling point refrigerant, while the liquid refrigerant contains a higher percentage of a high boiling point refrigerant. Examples of such a mixed refrigerant include R407C that is a mixture of R32, R125, and R134a, a mixture of R32 and HFO-1234yf (2,3,3,3-tetrafluoropropene), and a mixture of R32, HFO-1234yf, and R125.
  • It is preferable to use a zeotropic refrigerant mixture including a high boiling point refrigerant and a low boiling point refrigerant, with a difference in boiling point therebetween being 20° C. or more. For example, in the case of R407C containing a high boiling point refrigerant consisting of R32 (having a boiling point of −52° C.) and R125 (having a boiling point of −49° C.) and a low boiling point refrigerant that is R134a (having a boiling point of −26° C.), a difference in boiling point between these high and low boiling point refrigerants is 23° C.
  • Further, in the present embodiment, an accumulator 27 is provided between the evaporator 24 and the compressor 21. This accumulator 27 separates the refrigerant evaporated in the evaporator 24 into a gas refrigerant and a liquid refrigerant, and serves as the vapor-liquid separator of the present invention. In the present embodiment, a zeotropic refrigerant mixture is used. Therefore, a liquid refrigerant, which is rich in a high boiling point refrigerant, is accumulated in the bottom portion of the accumulator 27. For example, in the case where the zeotropic refrigerant mixture is a mixture of R32 (having a boiling point of −52° C.) and HFO-1234yf (having a boiling point of −29° C.), a liquid refrigerant, which is rich in HFO-1234yf, is accumulated in the bottom portion of the accumulator 27.
  • The heating radiator 3 is a device for radiating heat from hot water flowing therethrough, and has an inlet for allowing the hot water to flow thereinto, and an outlet for allowing the hot water that has radiated its heat to flow therefrom. As the heating radiator 3, for example, a radiator to be placed in a room of a building may be used. A hot water panel to be laid on a floor also may be used.
  • The outlet of the heating radiator 3 is connected to the radiator 22 by the supply pipe 31 for supplying water to the radiator 22. The inlet of the heating radiator 3 is connected to the radiator 22 by the recovery pipe 32 for recovering hot water produced in the radiator 22. The supply pipe 31 is provided with an incoming water temperature sensor 72 for detecting the temperature of water (hereinafter referred also as an “incoming water temperature”) to be supplied to the radiator 22. The supply pipe 31 also is provided with a pump 61 on the upstream side of the incoming water temperature sensor 72. The incoming water temperature sensor 72 is connected to the heat pump controller 26. On the other hand, the recovery pipe 32 is provided with a hot water temperature sensor 71 for detecting the temperature of the hot water produced in the radiator 22. When the pump 61 is rotated, the water is guided from the heating radiator 3 to the radiator 22 by the supply pipe 31, and the hot water produced in the radiator 22 is guided from the radiator 22 to the heating radiator 3 by the recovery pipe 32.
  • The overall controller 5 includes a microcomputer, a digital signal processor (DSP), or the like, and is connected to the above-mentioned heat pump controller 26, the hot water temperature sensor 71, and the pump 61, respectively.
  • Next, the control operations performed by the overall controller 5 and the heat pump controller 26 are described specifically.
  • When a user turns on a heating switch (not shown), the overall controller 5 rotates the pump 61 and sends an operation start signal to the heat pump controller 26. Thereby, water is heated in the radiator 22 to produce hot water, and the produced hot water is fed to the heating radiator 3. Thus, air-heating is performed.
  • The overall controller 5 controls the rotational rate of the pump 61 to regulate the flow rate of the water flowing through the supply pipe 31 so that the temperature of the water detected by the hot water temperature sensor 71 becomes a specified temperature (for example, 70° C.).
  • When the temperature of the water (incoming water temperature) supplied to the radiator 22 is relatively high, the heat pump controller 26 performs a control operation to reduce the amount of the liquid refrigerant in the accumulator 27. Specifically, when the temperature detected by the incoming water temperature sensor 72 is higher than a predetermined temperature (for example, 55° C.), the heat pump controller 26 reduces the opening of the expansion valve 23. When the opening of the expansion valve 23 is reduced, the refrigerant absorbs heat efficiently in the evaporator 24 and the dryness of the refrigerant flowing into the accumulator 27 increases. Thereby, the amount of the liquid refrigerant remaining in the accumulator 27 decreases. As a result, the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, which thereby suppresses the increase in the high pressure of the refrigeration cycle.
  • With reference to FIG. 3, the above-described phenomenon is explained below by taking, as an example, the case where the zeotropic refrigerant mixture is a mixture of R32 and HFO-1234yf. In FIG. 3, full lines indicate the case where the refrigerant is R32 alone and the case where the refrigerant is HFO-1234yf alone, a single-dashed line indicates the case where the composition ratio of HFO-1234yf in the mixed refrigerant circulating through the heat pump circuit 20 has a certain value, and a double-dashed line indicates the case where the composition ratio of HFO-1234yf is higher than the certain value.
  • First, it is assumed that the high pressure of the refrigeration cycle is located at Point a on the single-dashed line when the incoming water temperature is low. If the amount of the liquid refrigerant in the accumulator 27 is fixed, the composition of the refrigerant circulating through the heat pump circuit 20 does not change. Therefore, when the incoming water temperature rises to, for example, 65° C., the high pressure of the refrigeration cycle shifts from Point a to Point b along the single-dashed line. In the present embodiment, however, the amount of the liquid refrigerant remaining in the accumulator 27 decreases. As a result, the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, and thus the high pressure of the refrigeration cycle shifts from Point a to Point c on the double-dashed line. Accordingly, the increase in the high pressure of the refrigeration cycle can be suppressed when the incoming water temperature rises.
  • That is, when the opening of the expansion valve 23 is reduced, Point A shifts to the right in the Mollier diagram of FIG. 2 and thus the dryness increases. Thereby, the amount of the liquid refrigerant remaining in the accumulator 27 decreases. As a result, the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, which thereby suppresses the increase in the high pressure of the refrigeration cycle.
  • It should be noted that the liquid refrigerant in the accumulator 27 does not necessarily have to disappear completely. When the amount of the liquid refrigerant in the accumulator 27 decreases to some extent, the heat pump controller 26 may stop reducing the opening of the expansion valve 23 to maintain it.
  • Second Embodiment
  • FIG. 4 shows a liquid circulation heating system 1B according to a second embodiment of the present invention. In the present embodiment, the same components as those in the first embodiment are designated by the same reference numerals and no further description is given.
  • The liquid circulation heating system 1B of the second embodiment has basically the same configuration as the liquid circulation heating system 1A of the first embodiment, except that the heating radiator 3 and the radiator 22 are connected via the hot water storage tank 8.
  • Furthermore, as a refrigerant charged in the heat pump circuit 20, the same refrigerant as that described in the first embodiment also is used in the present embodiment, and therefore the description of the zeotropic refrigerant mixture is not repeated here. The same description also is not repeated in the following embodiment and modifications.
  • The hot water storage tank 8 is a vertically cylindrical closed casing and is filled with water. The lower portion of the hot water storage tank 8 is connected to the radiator 22 by the supply pipe 31, and the upper portion thereof is connected to the radiator 22 by the recovery pipe 32.
  • When the pump 61 is rotated, the water is guided from the lower portion of the hot water storage tank 8 to the radiator 22 by the supply pipe 31, and the hot water produced in the radiator 22 is guided from the radiator 22 to the upper portion of the hot water storage tank 8 by the recovery pipe 32. Thereby, the produced hot water is stored in the hot water storage tank 8 from the top thereof. On the peripheral surface of the hot water storage tank 8, hot water temperature sensors 74 for determining how much hot water remains in the tank 8 are provided separately from each other in the vertical direction. The hot water temperature sensors 74 are connected to the overall controller 5.
  • In the present embodiment, a heat exchanger 92 for hot water supply is provided at an upper position in the hot water storage tank 8, and a water inlet pipe 91 and a hot water outlet pipe 93 are connected to this heat exchanger 92. That is, in the present embodiment, the produced hot water can be used as a heat source for hot water supply. In addition, a heater 85 for re-heating the hot water also is provided at an upper position in the hot water storage tank 8.
  • The inlet of the heating radiator 3 is connected to the upper portion of the hot water storage tank 8 by a feed pipe 81, and the outlet of the heating radiator 3 is connected to the lower portion of the hot water storage tank 8 by a return pipe 82. In the present embodiment, a circulation pump 66 is provided in the return pipe 82, but the circulation pump 66 may be provided in the feed pipe 81. The circulation pump 66 is connected to the overall controller 5. When the circulation pump 66 is rotated, the hot water stored in the hot water storage tank 8 is fed to the heating radiator 3 through the feed pipe 81, and the hot water is returned to the hot water storage tank 8 through the return pipe 82 after radiating heat in the heating radiator 3.
  • Next, the control operations performed by the overall controller 5 and the heat pump controller 26 are described specifically.
  • (Hot Water Storage Operation)
  • When the overall controller 5 determines that the amount of hot water remaining in the tank is less than the required amount based on the temperature detected by the hot water temperature sensors 74, for example, during nighttime hours (for example, from 23:00 to 7:00), it rotates the pump 61, and sends an operation start signal to the heat pump controller 26. Thereby, water is heated in the radiator 22 to produce hot water, and the produced hot water is stored in the hot water storage tank 8. The overall controller 5 also controls the rotational rate of the pump 61 to regulate the flow rate of the water flowing through the supply pipe 31 so that the temperature of the water detected by the hot water temperature sensor 71 becomes a specified temperature (for example, 70° C.).
  • When the temperature of the water (incoming water temperature) supplied to the radiator 22 is relatively high, the heat pump controller 26 performs a control operation to reduce the amount of the liquid refrigerant in the accumulator 27. Specifically, when the temperature detected by the incoming water temperature sensor 72 is higher than a predetermined temperature (for example, 55° C.), the heat pump controller 26 reduces the opening of the expansion valve 23. When the opening of the expansion valve 23 is reduced, the refrigerant absorbs heat efficiently in the evaporator 24 and the dryness of the refrigerant flowing into the accumulator 27 increases. Thereby, the amount of the liquid refrigerant remaining in the accumulator 27 decreases. As a result, the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, which thereby suppresses the increase in the high pressure of the refrigeration cycle.
  • That is, when the opening of the expansion valve 23 is reduced, Point A shifts to the right in the Mollier diagram of FIG. 2 and thus the dryness increases. Thereby, the amount of the liquid refrigerant remaining in the accumulator 27 decreases. As a result, the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, which thereby suppresses the increase in the high pressure of the refrigeration cycle.
  • It should be noted that the liquid refrigerant in the accumulator 27 does not necessarily have to disappear completely. When the amount of the liquid refrigerant in the accumulator 27 decreases to some extent, the heat pump controller 26 may stop reducing the opening of the expansion valve 23 to maintain it.
  • (Air-Heating Operation)
  • When a user turns on a heating switch (not shown), the overall controller 5 rotates the circulation pump 66. Thereby, the hot water stored in the hot water storage tank 8 is fed to the heating radiator 3, where heat is radiated from the hot water. Thus, air-heating is performed.
  • In the liquid circulation heating system 1B of the second embodiment described above, high-temperature hot water stored in the hot water storage tank 8 can be fed to the heating radiator 3 even during the early stage of the air-heating operation. Therefore, air-heating can be started immediately after the heating switch is turned on.
  • Third Embodiment
  • FIG. 5 shows a liquid circulation heating system 1C according to a third embodiment of the present invention. In the present embodiment, the same components as those in the first and second embodiments are designated by the same reference numerals and no further description is given.
  • In the liquid circulation heating system 1C of the third embodiment, hot water stored in the hot water storage tank 8 can be used directly for hot water supply. Specifically, the water inlet pipe 91 is connected to the lower portion of the hot water storage tank 8, and the hot water outlet pipe 93 is connected to the upper portion of the hot water storage tank 8. At an upper position in the hot water storage tank 8, a heat exchanger 83 for exchanging heat between the hot water stored in the hot water storage tank 8 and a heat transfer liquid (secondary liquid) is provided. The heat exchanger 83 is connected to the heating radiator 3 by the feed pipe 81 and the return pipe 82. When the circulation pump 66 is rotated, the heat transfer liquid heated in the heat exchanger 83 is fed to the heating radiator 3 through the feed pipe 81, and the heat transfer liquid is returned to the heat exchanger 83 through the return pipe 82 after radiating heat in the heating radiator 3. As the heat transfer liquid, for example, an antifreeze liquid can be used, but water preferably is used because it is available at low cost and in large quantities.
  • Since the overall controller 5 performs control in the same manner as in the second embodiment, the description thereof is not repeated here. It should be noted, however, that during the air-heating operation, the heat transfer liquid that has exchanged heat with the hot water stored in the hot water storage tank 8 radiates heat in the heating radiator 3, that is, the heat of the hot water is transferred to the heating radiator 3 by the heat transfer liquid, and thereby air-heating is performed.
  • In the liquid circulation heating system 1C having such a configuration, the temperature in the lower portion of the hot water storage tank 8 can be kept low because of the water supplied from the water inlet pipe 91. Therefore, the low-temperature water can be supplied to the radiator 22, and thus the efficiency of the heat pump 2 can be enhanced.
  • (First Modification)
  • In each of the above embodiments, a heat pump 2A as shown in FIG. 6 also can be employed. In this heat pump 2A, when the temperature of the water (incoming water temperature) supplied to the radiator 22 is relatively high, the refrigerant to be fed to the accumulator 27 from the evaporator 24 is heated.
  • Specifically, the heat pump circuit 20 includes a heat exchanger (heater) 29 between the evaporator 24 and the accumulator 27, and a bypass passage 29A that bypasses the expansion valve 23 so as to pass through the heat exchanger 29. With this configuration, the heat exchanger 29 exchanges heat between the refrigerant flowing through the bypass passage 29A and the refrigerant to be fed to the accumulator 27 from the evaporator 24. The bypass passage 29 is provided with an open/close valve 29B on the upstream side of the heat exchanger 29. The open/close valve 29B is connected to the heat pump controller 26, and usually is closed by the heat pump controller 26.
  • When the temperature detected by the incoming water temperature sensor 72 is higher than a predetermined temperature, the heat pump controller 26 opens the open/close valve 29B. When the open/close valve 29B is opened, the refrigerant that has been evaporated in the evaporator 24 is heated further in the heat exchanger 29, and the dryness of the refrigerant flowing into the accumulator 27 increases. Thereby, the amount of the liquid refrigerant remaining in the accumulator 27 decreases. As a result, the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, which thereby suppresses the increase in the high pressure of the refrigeration cycle.
  • That is, when the open/close valve 29B is opened, Point A shifts to the right in the Mollier diagram of FIG. 2 and thus the dryness increases. Thereby, the amount of the liquid refrigerant remaining in the accumulator 27 decreases. As a result, the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, which thereby suppresses the increase in the high pressure of the refrigeration cycle.
  • It should be noted that the liquid refrigerant in the accumulator 27 does not necessarily have to disappear completely. When the amount of the liquid refrigerant in the accumulator 27 decreases to some extent, the heat pump controller 26 may stop increasing the opening of the open/close valve 29B to maintain it.
  • When the incoming water temperature is relatively high, it is only desirable that the amount of the heating applied to the refrigerant to be fed to the accumulator 27 from the evaporator 24 by the heat exchanger 29 increase. The open/close valve 29B does not necessarily have to be closed completely in its initial state.
  • In the first modification, the heat exchanger 29 is used as the heater of the present invention, but the heater of the present invention is not limited to the heat exchanger. For example, it may be an electric heater, or the like. If the heat exchanger 29 and the bypass passage 29A are provided as in the case of the first modification, however, the refrigerant to be fed to the accumulator 27 from the evaporator 24 can be heated by utilizing the heat of the refrigerant that has passed through the radiator 22.
  • (Second Modification)
  • In each of the above embodiments, a heat pump 2B as shown in FIG. 7 also can be employed. In this heat pump 2B, a first expansion valve 23A and a second expansion valve 23B are used as the decompressor of the present invention. The refrigerant is decompressed by the first expansion valve 23A after radiating heat in the radiator 22, and further decompressed by the second expansion valve 23B after being decompressed by the first expansion valve 23A. A receiver 28 is provided between the first expansion valve 23A and the second expansion valve 23B. This receiver 28 separates the refrigerant decompressed by the first expansion valve 23A into a gas refrigerant and a liquid refrigerant, and serves as the vapor-liquid separator of the present invention.
  • When the temperature detected by the incoming water temperature sensor 72 is higher than a predetermined temperature, the heat pump controller 26 reduces the opening of the first expansion valve 23A and increases the opening of the second expansion valve 23B. When the opening of the first expansion valve 23A is reduced and the opening of the second expansion valve 23B is increased, the refrigerant absorbs heat efficiently in the evaporator 24 and the dryness of the refrigerant flowing into the receiver 28 increases. Thereby, the amount of the liquid refrigerant remaining in the receiver 28 decreases. As a result, the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 increases, which thereby suppresses the increase in the high pressure of the refrigeration cycle.
  • It should be noted that the liquid refrigerant in the receiver 28 does not necessarily have to disappear completely. When the amount of the liquid refrigerant in the receiver 28 decreases to some extent, the heat pump controller 26 may stop controlling the openings of the first expansion valve 23A and the second expansion valve 23B to maintain them.
  • (Other Modifications)
  • In each of the above embodiments and modifications, the heat pump controller 26 serves as the controller of the present invention. In the case where the incoming water temperature sensor 72 is connected to the overall controller 5, the heat pump controller 26 and the overall controller 5 may serve as the controller of the present invention.
  • As the decompressor of the present invention, an expander for recovering power from the expanding refrigerant also can be used.
  • Furthermore, it is also possible, by using fraction separation, membrane separation, or the like, to increase the composition ratio of the high boiling point refrigerant in the refrigerant circulating through the heat pump circuit 20 when the water supplied to the radiator 22 has a relatively high temperature.
  • The invention may be embodied in other forms without departing from the spirit or essential characteristics thereof. The embodiments disclosed in this specification are to be considered in all respects as illustrative and not limiting. The scope of the invention is indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are intended to be embraced therein.

Claims (12)

1. A liquid circulation heating system for performing air-heating by heating a liquid to produce a heated liquid and releasing heat of the heated liquid from a heating radiator, the system comprising a heat pump circuit for circulating a refrigerant,
wherein the heat pump circuit includes a refrigerant radiator for heating the liquid by radiating heat from the refrigerant to produce the heated liquid,
the heat pump circuit is charged with a zeotropic refrigerant mixture of at least two refrigerants having different boiling points, as the refrigerant, and
the liquid circulation heating system is configured so that a composition ratio of a higher boiling point refrigerant in the refrigerant circulating through the heat pump circuit increases when the liquid supplied to the refrigerant radiator has a relatively high temperature.
2. The liquid circulation heating system according to claim 1, wherein
the heat pump circuit further includes: a compressor for compressing the refrigerant; a decompressor for decompressing the refrigerant; an evaporator for evaporating the refrigerant; and a vapor-liquid separator for separating the refrigerant into a gas refrigerant and a liquid refrigerant, and
the liquid circulation heating system further comprises a controller for performing a control operation to reduce an amount of the liquid refrigerant in the vapor-liquid separator when the liquid supplied to the refrigerant radiator has a relatively high temperature.
3. The liquid circulation heating system according to claim 2, wherein the vapor-liquid separator is an accumulator provided between the evaporator and the compressor.
4. The liquid circulation heating system according to claim 3, wherein
the decompressor is an expansion valve, and
the controller reduces an opening of the expansion valve when the liquid supplied to the refrigerant radiator has a relatively high temperature.
5. The liquid circulation heating system according to claim 3, wherein
the heat pump circuit further includes, between the evaporator and the accumulator, a heater for heating the refrigerant to be fed to the accumulator from the evaporator, and
the controller increases an amount of the heating applied to the refrigerant by the heater when the liquid supplied to the refrigerant radiator has a relatively high temperature.
6. The liquid circulation heating system according to claim 5, wherein
the heat pump circuit further includes a bypass passage that bypasses the decompressor, and
the heater is a heat exchanger for exchanging heat between the refrigerant flowing through the bypass passage and the refrigerant to be fed to the accumulator from the evaporator.
7. The liquid circulation heating system according to claim 2, wherein
the decompressor includes: a first expansion valve for decompressing the refrigerant after the refrigerant radiates heat in the refrigerant radiator; and a second expansion valve for further decompressing the refrigerant after the refrigerant is decompressed by the first expansion valve,
the vapor-liquid separator is a receiver provided between the first expansion valve and the second expansion valve, and
the controller reduces an opening of the first expansion valve and increases an opening of the second expansion valve when the liquid supplied to the refrigerant radiator has a relatively high temperature.
8. The liquid circulation heating system according to claim 1, further comprising:
a supply pipe for guiding the liquid from the heating radiator to the refrigerant radiator; and
a recovery pipe for guiding the heated liquid from the refrigerant radiator to the heating radiator.
9. The liquid circulation heating system according to claim 1, further comprising:
a tank for storing the produced heated liquid;
a supply pipe for guiding the liquid from a lower portion of the tank to the refrigerant radiator;
a recovery pipe for guiding the heated liquid from the refrigerant radiator to an upper portion of the tank;
a feed pipe for feeding the heated liquid stored in the tank to the heating radiator; and
a return pipe for returning the heated liquid to the tank after the heated liquid radiates heat in the heating radiator.
10. The liquid circulation heating system according to claim 1, further comprising:
a tank for storing the produced heated liquid;
a supply pipe for guiding the liquid from a lower portion of the tank to the refrigerant radiator;
a recovery pipe for guiding the heated liquid from the refrigerant radiator to an upper portion of the tank;
a heat exchanger, disposed in the tank, for exchanging heat between the heated liquid stored in the tank and a heat transfer liquid;
a feed pipe for feeding the heat transfer liquid to the heating radiator after the heat transfer liquid is heated in the heat exchanger; and
a return pipe for returning the heat transfer liquid to the heat exchanger after the heat transfer liquid radiates heat in the heating radiator.
11. The liquid circulation heating system according to claim 1, wherein the liquid is water, and the heated liquid is hot water.
12. A method of controlling a liquid circulation heating system for performing air-heating by heating a liquid to produce a heated liquid and releasing heat of the heated liquid from a heating radiator,
wherein the liquid circulation heating system includes a heat pump circuit for circulating a refrigerant, and the heat pump circuit includes: a refrigerant radiator for heating the liquid by radiating heat from the refrigerant to produce the heated liquid; a compressor for compressing the refrigerant; a decompressor for decompressing the refrigerant; an evaporator for evaporating the refrigerant; and a vapor-liquid separator for separating the refrigerant into a gas refrigerant and a liquid refrigerant,
the heat pump circuit is charged with a zeotropic refrigerant mixture of at least two refrigerants having different boiling points, as the refrigerant, and
the method comprises the step of controlling an operation of the decompressor to reduce an amount of the liquid refrigerant in the vapor-liquid separator when the liquid supplied to the refrigerant radiator has a relatively high temperature.
US12/693,724 2009-01-30 2010-01-26 Liquid circulation heating system and method of controlling the same Abandoned US20100193156A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2009019233A JP5242434B2 (en) 2009-01-30 2009-01-30 Liquid circulation heating system
JP2009-019233 2009-01-30

Publications (1)

Publication Number Publication Date
US20100193156A1 true US20100193156A1 (en) 2010-08-05

Family

ID=42062557

Family Applications (1)

Application Number Title Priority Date Filing Date
US12/693,724 Abandoned US20100193156A1 (en) 2009-01-30 2010-01-26 Liquid circulation heating system and method of controlling the same

Country Status (5)

Country Link
US (1) US20100193156A1 (en)
EP (1) EP2213950B1 (en)
JP (1) JP5242434B2 (en)
CN (1) CN101793422B (en)
AU (1) AU2010200057A1 (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100193155A1 (en) * 2009-01-30 2010-08-05 Panasonic Corporation Liquid circulation heating system
US20100300143A1 (en) * 2007-11-05 2010-12-02 Bjorn Sollie Liquid Separator For An Evaporator System
US20120042673A1 (en) * 2010-08-17 2012-02-23 Jinhee Noh Heat pump
US20130152613A1 (en) * 2010-09-30 2013-06-20 Mitsubishi Electric Corporation Air-conditioning apparatus
CN103197624A (en) * 2013-03-05 2013-07-10 天津城市建设学院 Central heating system controller based on digital signal processor (DSP)
US20130192283A1 (en) * 2010-12-03 2013-08-01 Mitsubishi Electric Corporation Air-conditioning apparatus
US20130205812A1 (en) * 2010-12-03 2013-08-15 Mitsubishi Electric Corporation Method of part replacement for refrigeration cycle apparatus and refrigeration cycle apparatus
US20130312446A1 (en) * 2010-01-27 2013-11-28 Daikin Industries, Ltd. Refrigerant composition comprising difluoromethane (hfc32) and 2,3,3,3-tetrafluoropropene (hfo1234yf)
US20140260409A1 (en) * 2013-03-12 2014-09-18 General Electric Company Control system for a dual evaporator refrigeration system
US20140298854A1 (en) * 2013-04-04 2014-10-09 General Electric Company Dual evaporator refrigeration system with zeotropic refrigerant mixture
US20150330674A1 (en) * 2012-12-20 2015-11-19 Mitsubishi Electric Corporation Air-conditioning apparatus
WO2018221875A1 (en) * 2017-05-31 2018-12-06 Samsung Electronics Co., Ltd. Air conditioner and method for controlling the same
EP3587954A1 (en) 2018-06-28 2020-01-01 Electricité de France Facility for producing domestic hot water and method for controlling same

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102589101A (en) * 2011-01-12 2012-07-18 王清典 Directly-heated type warmer of air conditioner
JP5501282B2 (en) * 2011-04-07 2014-05-21 三菱電機株式会社 HEAT PUMP SYSTEM AND HEAT PUMP SYSTEM CONTROL METHOD
FR2979419B1 (en) * 2011-08-30 2018-03-30 Arkema France SUPERCRITICAL HEAT TRANSFER FLUIDS BASED ON TETRAFLUOROPROPENE
WO2013051177A1 (en) * 2011-10-03 2013-04-11 三菱電機株式会社 Outdoor machine, and air conditioner and hot water supply unit comprising said outdoor machine
CN103857976B (en) * 2011-10-03 2016-08-17 三菱电机株式会社 Refrigerating circulatory device
JP5759906B2 (en) * 2012-01-10 2015-08-05 リンナイ株式会社 Heating system
JP6013738B2 (en) * 2012-01-10 2016-10-25 リンナイ株式会社 Heating system
JP5793431B2 (en) * 2012-01-10 2015-10-14 リンナイ株式会社 Heating system
EP2940405B1 (en) * 2012-12-26 2018-06-06 Mitsubishi Electric Corporation Refrigeration cycle device and method for controlling refrigeration cycle device
CN106225319A (en) * 2016-07-27 2016-12-14 南京理工大学 A kind of double evaporating temperatures refrigeration and heat pump air conditioner unit and the method for back-heating type non-azeotropic mixed working medium
DE102019001639A1 (en) * 2019-03-08 2020-09-10 Stiebel Eltron Gmbh & Co. Kg Cooling circuit, heat pump
CN113865012B (en) * 2021-10-28 2023-01-17 珠海格力电器股份有限公司 Variable-load adjusting air conditioning system and control method thereof

Citations (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3813036A (en) * 1973-05-08 1974-05-28 G Lutz Heating system
US4012920A (en) * 1976-02-18 1977-03-22 Westinghouse Electric Corporation Heating and cooling system with heat pump and storage
US4190199A (en) * 1978-01-06 1980-02-26 Lennox Industries Inc. Combination heating system including a conventional furnace, heat pump and solar energy subsystem
US4256475A (en) * 1977-07-22 1981-03-17 Carrier Corporation Heat transfer and storage system
US4412581A (en) * 1981-03-14 1983-11-01 Danfoss A/S Heating installation comprising a boiler and a heat pump
US4514990A (en) * 1982-11-09 1985-05-07 Alfred Sulkowski Heat exchange system with space heating, space cooling and hot water generating cycles
US4522253A (en) * 1983-08-10 1985-06-11 The Bennett Levin Associates, Inc. Water-source heat pump system
US4722195A (en) * 1985-03-25 1988-02-02 Matsushita Electric Industrial Co., Ltd. Heat pump with a reservoir storing higher pressure refrigerant of non-azeotropic mixture
US4724679A (en) * 1986-07-02 1988-02-16 Reinhard Radermacher Advanced vapor compression heat pump cycle utilizing non-azeotropic working fluid mixtures
US4798240A (en) * 1985-03-18 1989-01-17 Gas Research Institute Integrated space heating, air conditioning and potable water heating appliance
US4840042A (en) * 1987-07-31 1989-06-20 Matsushita Electric Industrial Co., Ltd. Heat pump system
US5366153A (en) * 1993-01-06 1994-11-22 Consolidated Natural Gas Service Company, Inc. Heat pump system with refrigerant isolation and heat storage
US5551255A (en) * 1994-09-27 1996-09-03 The United States Of America As Represented By The Secretary Of Commerce Accumulator distillation insert for zeotropic refrigerant mixtures
US5709090A (en) * 1994-11-25 1998-01-20 Hitachi, Ltd. Refrigerating system and operating method thereof
US5848537A (en) * 1997-08-22 1998-12-15 Carrier Corporation Variable refrigerant, intrastage compression heat pump
US6327866B1 (en) * 1998-12-30 2001-12-11 Praxair Technology, Inc. Food freezing method using a multicomponent refrigerant
US6467288B2 (en) * 2000-06-28 2002-10-22 Denso Corporation Heat-pump water heater
US6668572B1 (en) * 2002-08-06 2003-12-30 Samsung Electronics Co., Ltd. Air conditioner having hot/cold water producing device
US20040119047A1 (en) * 2002-10-25 2004-06-24 Honeywell International, Inc. Compositions containing fluorine substituted olefins
US20050218240A1 (en) * 2003-01-13 2005-10-06 Sienel Tobias H Storage tank for hot water systems
US7024879B2 (en) * 2003-01-16 2006-04-11 Matsushita Electric Industrial Co., Ltd. Refrigerator
US20060243944A1 (en) * 2005-03-04 2006-11-02 Minor Barbara H Compositions comprising a fluoroolefin
US20060243945A1 (en) * 2005-03-04 2006-11-02 Minor Barbara H Compositions comprising a fluoroolefin
US7279451B2 (en) * 2002-10-25 2007-10-09 Honeywell International Inc. Compositions containing fluorine substituted olefins
US7316120B2 (en) * 2004-10-18 2008-01-08 Mitsubishi Denki Kabushiki Kaisha Refrigeration/air conditioning equipment
US20080099190A1 (en) * 2002-10-25 2008-05-01 Honeywell International, Inc. Heat transfer methods using heat transfer compositions containing trans-1,3,3,3-tetrafluoropropene
US20080190130A1 (en) * 2005-06-03 2008-08-14 Springer Carrier Ltda Heat Pump System with Auxiliary Water Heating
US20080314073A1 (en) * 2007-06-21 2008-12-25 E. L. Du Pont De Nemours And Company Method for leak detection in heat transfer systems
US20100050675A1 (en) * 2007-03-27 2010-03-04 Mitsubishi Electric Corporation Heat pump system
US20100108936A1 (en) * 2006-11-02 2010-05-06 Idemitsu Kosan Co., Ltd Lubricating oil composition for refrigerators
US20100193155A1 (en) * 2009-01-30 2010-08-05 Panasonic Corporation Liquid circulation heating system

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01212863A (en) * 1988-02-19 1989-08-25 Fujitsu General Ltd Hot-water supplying device
JPH07190515A (en) * 1993-11-19 1995-07-28 Sanyo Electric Co Ltd Freezer
JPH07269972A (en) * 1994-03-31 1995-10-20 Toshiba Corp Air conditioner and controlling method therefor
JPH08296908A (en) * 1995-04-24 1996-11-12 Matsushita Refrig Co Ltd Air conditioning equipment
JPH09318167A (en) * 1996-03-28 1997-12-12 Mitsubishi Electric Corp Refrigerating cycle using mixed refrigerant
JP3596347B2 (en) * 1998-04-15 2004-12-02 三菱電機株式会社 Refrigeration air conditioner and control method thereof
JP3737381B2 (en) * 2000-06-05 2006-01-18 株式会社デンソー Water heater
JP2002162121A (en) * 2000-11-20 2002-06-07 Fujitsu General Ltd Refrigerating device for air conditioner
JP2002257366A (en) * 2001-03-02 2002-09-11 Sekisui Chem Co Ltd Hot water supplying/heating system
JP2002349976A (en) * 2001-05-24 2002-12-04 Kobe Steel Ltd Cooling system
DE202005013499U1 (en) * 2005-08-26 2005-10-27 Wenzel, Bernhard Cooling medium circuit for a heat pump has compressor evaporator and expansion valve with two condensers operating at different temperatures
JP4743039B2 (en) 2006-08-07 2011-08-10 ダイキン工業株式会社 Hot water circulation heating system for heating by circulating hot water in buildings
JP2008082664A (en) * 2006-09-28 2008-04-10 Daikin Ind Ltd Hot water circulating heating system
CN201155820Y (en) * 2007-11-19 2008-11-26 郭洪雨 Water source heat pump heating device
CN100529553C (en) * 2008-02-19 2009-08-19 东南大学 Multifunctional heat pump device capable of cooling and heating by floor radialization
CN101303143A (en) * 2008-07-02 2008-11-12 高秀明 Variable flow enthalpy increasing heat pump heating system

Patent Citations (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3813036A (en) * 1973-05-08 1974-05-28 G Lutz Heating system
US4012920A (en) * 1976-02-18 1977-03-22 Westinghouse Electric Corporation Heating and cooling system with heat pump and storage
US4256475A (en) * 1977-07-22 1981-03-17 Carrier Corporation Heat transfer and storage system
US4190199A (en) * 1978-01-06 1980-02-26 Lennox Industries Inc. Combination heating system including a conventional furnace, heat pump and solar energy subsystem
US4412581A (en) * 1981-03-14 1983-11-01 Danfoss A/S Heating installation comprising a boiler and a heat pump
US4514990A (en) * 1982-11-09 1985-05-07 Alfred Sulkowski Heat exchange system with space heating, space cooling and hot water generating cycles
US4522253A (en) * 1983-08-10 1985-06-11 The Bennett Levin Associates, Inc. Water-source heat pump system
US4798240A (en) * 1985-03-18 1989-01-17 Gas Research Institute Integrated space heating, air conditioning and potable water heating appliance
US4722195A (en) * 1985-03-25 1988-02-02 Matsushita Electric Industrial Co., Ltd. Heat pump with a reservoir storing higher pressure refrigerant of non-azeotropic mixture
US4724679A (en) * 1986-07-02 1988-02-16 Reinhard Radermacher Advanced vapor compression heat pump cycle utilizing non-azeotropic working fluid mixtures
US4840042A (en) * 1987-07-31 1989-06-20 Matsushita Electric Industrial Co., Ltd. Heat pump system
US5366153A (en) * 1993-01-06 1994-11-22 Consolidated Natural Gas Service Company, Inc. Heat pump system with refrigerant isolation and heat storage
US5551255A (en) * 1994-09-27 1996-09-03 The United States Of America As Represented By The Secretary Of Commerce Accumulator distillation insert for zeotropic refrigerant mixtures
US5709090A (en) * 1994-11-25 1998-01-20 Hitachi, Ltd. Refrigerating system and operating method thereof
US5848537A (en) * 1997-08-22 1998-12-15 Carrier Corporation Variable refrigerant, intrastage compression heat pump
US6070420A (en) * 1997-08-22 2000-06-06 Carrier Corporation Variable refrigerant, intrastage compression heat pump
US6327866B1 (en) * 1998-12-30 2001-12-11 Praxair Technology, Inc. Food freezing method using a multicomponent refrigerant
US6467288B2 (en) * 2000-06-28 2002-10-22 Denso Corporation Heat-pump water heater
US6668572B1 (en) * 2002-08-06 2003-12-30 Samsung Electronics Co., Ltd. Air conditioner having hot/cold water producing device
US7279451B2 (en) * 2002-10-25 2007-10-09 Honeywell International Inc. Compositions containing fluorine substituted olefins
US20040119047A1 (en) * 2002-10-25 2004-06-24 Honeywell International, Inc. Compositions containing fluorine substituted olefins
US20040127383A1 (en) * 2002-10-25 2004-07-01 Pham Hang T. Pentafluoropropene-based compositions
US20080099190A1 (en) * 2002-10-25 2008-05-01 Honeywell International, Inc. Heat transfer methods using heat transfer compositions containing trans-1,3,3,3-tetrafluoropropene
US20050218240A1 (en) * 2003-01-13 2005-10-06 Sienel Tobias H Storage tank for hot water systems
US7024879B2 (en) * 2003-01-16 2006-04-11 Matsushita Electric Industrial Co., Ltd. Refrigerator
US7316120B2 (en) * 2004-10-18 2008-01-08 Mitsubishi Denki Kabushiki Kaisha Refrigeration/air conditioning equipment
US20060243945A1 (en) * 2005-03-04 2006-11-02 Minor Barbara H Compositions comprising a fluoroolefin
US20060243944A1 (en) * 2005-03-04 2006-11-02 Minor Barbara H Compositions comprising a fluoroolefin
US20080190130A1 (en) * 2005-06-03 2008-08-14 Springer Carrier Ltda Heat Pump System with Auxiliary Water Heating
US20100108936A1 (en) * 2006-11-02 2010-05-06 Idemitsu Kosan Co., Ltd Lubricating oil composition for refrigerators
US20100050675A1 (en) * 2007-03-27 2010-03-04 Mitsubishi Electric Corporation Heat pump system
US8015836B2 (en) * 2007-03-27 2011-09-13 Mitsubishi Electric Corporation Heat pump system
US20080314073A1 (en) * 2007-06-21 2008-12-25 E. L. Du Pont De Nemours And Company Method for leak detection in heat transfer systems
US20100193155A1 (en) * 2009-01-30 2010-08-05 Panasonic Corporation Liquid circulation heating system

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100300143A1 (en) * 2007-11-05 2010-12-02 Bjorn Sollie Liquid Separator For An Evaporator System
US10036583B2 (en) * 2007-11-05 2018-07-31 Alfa Laval Corporated Ab Liquid separator for an evaporator system
US20100193155A1 (en) * 2009-01-30 2010-08-05 Panasonic Corporation Liquid circulation heating system
US10619082B2 (en) 2010-01-27 2020-04-14 Daikin Industries, Ltd. Refrigerant composition comprising difluoromethane (HFC32) and 2,3,3,3-tetrafluoropropene (HFO1234yf)
US9758709B2 (en) * 2010-01-27 2017-09-12 Daikin Industries, Ltd. Refrigerant composition comprising difluoromethane (HFC32) and 2,3,3,3-tetrafluoropropene (HFO1234yf)
US20130312446A1 (en) * 2010-01-27 2013-11-28 Daikin Industries, Ltd. Refrigerant composition comprising difluoromethane (hfc32) and 2,3,3,3-tetrafluoropropene (hfo1234yf)
US20120042673A1 (en) * 2010-08-17 2012-02-23 Jinhee Noh Heat pump
US20130152613A1 (en) * 2010-09-30 2013-06-20 Mitsubishi Electric Corporation Air-conditioning apparatus
US9746223B2 (en) * 2010-09-30 2017-08-29 Mitsubishi Electric Corporation Air-conditioning apparatus
US9459013B2 (en) * 2010-12-03 2016-10-04 Mitsubishi Electric Corporation Air-conditioning apparatus with safety measure for ventilation of inflammable refrigerant from heat exchanger
US9476622B2 (en) * 2010-12-03 2016-10-25 Mitsubishi Electric Corporation Method of part replacement for refrigeration cycle apparatus and refrigeration cycle apparatus
US20130205812A1 (en) * 2010-12-03 2013-08-15 Mitsubishi Electric Corporation Method of part replacement for refrigeration cycle apparatus and refrigeration cycle apparatus
US20130192283A1 (en) * 2010-12-03 2013-08-01 Mitsubishi Electric Corporation Air-conditioning apparatus
US10054337B2 (en) * 2012-12-20 2018-08-21 Mitsubishi Electric Corporation Air-conditioning apparatus having indoor units and relay unit
US20150330674A1 (en) * 2012-12-20 2015-11-19 Mitsubishi Electric Corporation Air-conditioning apparatus
CN103197624A (en) * 2013-03-05 2013-07-10 天津城市建设学院 Central heating system controller based on digital signal processor (DSP)
US9453661B2 (en) * 2013-03-12 2016-09-27 Haier US Appliance Solutions, Inc Control system for a dual evaporator refrigeration system
US20140260409A1 (en) * 2013-03-12 2014-09-18 General Electric Company Control system for a dual evaporator refrigeration system
US20140298854A1 (en) * 2013-04-04 2014-10-09 General Electric Company Dual evaporator refrigeration system with zeotropic refrigerant mixture
WO2018221875A1 (en) * 2017-05-31 2018-12-06 Samsung Electronics Co., Ltd. Air conditioner and method for controlling the same
CN110945301A (en) * 2017-05-31 2020-03-31 三星电子株式会社 Air conditioner and method for controlling the same
KR20180131150A (en) * 2017-05-31 2018-12-10 삼성전자주식회사 Air conditioner and control method thereof
US10976086B2 (en) 2017-05-31 2021-04-13 Samsung Electronics Co., Ltd. Air conditioner and method for controlling the same
KR102354891B1 (en) * 2017-05-31 2022-01-25 삼성전자주식회사 Air conditioner and control method thereof
EP3587954A1 (en) 2018-06-28 2020-01-01 Electricité de France Facility for producing domestic hot water and method for controlling same
FR3083297A1 (en) 2018-06-28 2020-01-03 Electricite De France PLANT FOR THE PRODUCTION OF DOMESTIC HOT WATER AND METHOD FOR DRIVING SAME

Also Published As

Publication number Publication date
EP2213950A2 (en) 2010-08-04
JP2010175163A (en) 2010-08-12
EP2213950B1 (en) 2016-05-25
EP2213950A3 (en) 2012-09-19
CN101793422B (en) 2013-11-13
CN101793422A (en) 2010-08-04
AU2010200057A1 (en) 2010-08-19
JP5242434B2 (en) 2013-07-24

Similar Documents

Publication Publication Date Title
US20100193156A1 (en) Liquid circulation heating system and method of controlling the same
US8661840B2 (en) Liquid circulation heating system
EP2213710B1 (en) Liquid circulation heating system
US8769974B2 (en) Heat pump system
US20110302947A1 (en) Heat pump system
JP6320633B2 (en) Heat pump equipment
EP2530406B1 (en) Heat pump system
JP6161005B2 (en) Refrigeration cycle apparatus and hot water generating apparatus having the same
JP2011174672A (en) Refrigerating cycle device and hot water heating apparatus
US9810466B2 (en) Heat pump system
JP5300806B2 (en) Heat pump equipment
JP2014156987A (en) Heat pump system
JP2013127332A (en) Hydronic heating device
JP5788526B2 (en) Air conditioning and hot water supply system
KR101752974B1 (en) Heat pump system
JP2013104624A (en) Refrigeration cycle apparatus and hot water producing apparatus
JP2015215117A (en) Heat pump type air cooling device
JP6438765B2 (en) Thermal equipment
JP2016102636A (en) Air conditioning system
JP2010175164A (en) Liquid circulation type heating system
JP5802514B2 (en) Heat pump water heater
JP2008116184A (en) Refrigerating cycle device
EP3091293B1 (en) Heating device
KR101605909B1 (en) Method for controlling heating apparatus associated with heat pump
KR101184336B1 (en) Hybrid type heating system

Legal Events

Date Code Title Description
AS Assignment

Owner name: PANASONIC CORPORATION, JAPAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:NAKATANI, KAZUO;ISAYAMA, YASUHIKO;REEL/FRAME:024138/0339

Effective date: 20091214

AS Assignment

Owner name: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD., JAPAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:PANASONIC CORPORATION;REEL/FRAME:034194/0143

Effective date: 20141110

Owner name: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LT

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:PANASONIC CORPORATION;REEL/FRAME:034194/0143

Effective date: 20141110

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION

AS Assignment

Owner name: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD., JAPAN

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE ERRONEOUSLY FILED APPLICATION NUMBERS 13/384239, 13/498734, 14/116681 AND 14/301144 PREVIOUSLY RECORDED ON REEL 034194 FRAME 0143. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT;ASSIGNOR:PANASONIC CORPORATION;REEL/FRAME:056788/0362

Effective date: 20141110