US20100025050A2 - Frangible Shape Memory Alloy Fire Sprinkler Valve Actuator - Google Patents
Frangible Shape Memory Alloy Fire Sprinkler Valve Actuator Download PDFInfo
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- US20100025050A2 US20100025050A2 US12/019,553 US1955308A US2010025050A2 US 20100025050 A2 US20100025050 A2 US 20100025050A2 US 1955308 A US1955308 A US 1955308A US 2010025050 A2 US2010025050 A2 US 2010025050A2
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- shape
- memory element
- bolt
- temperature
- linkage
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23P—METAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
- B23P15/00—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
- B23P15/001—Making specific metal objects by operations not covered by a single other subclass or a group in this subclass valves or valve housings
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C37/00—Control of fire-fighting equipment
- A62C37/08—Control of fire-fighting equipment comprising an outlet device containing a sensor, or itself being the sensor, i.e. self-contained sprinklers
- A62C37/10—Releasing means, e.g. electrically released
- A62C37/11—Releasing means, e.g. electrically released heat-sensitive
- A62C37/16—Releasing means, e.g. electrically released heat-sensitive with thermally-expansible links
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/1624—Destructible or deformable element controlled
- Y10T137/1632—Destructible element
- Y10T137/1654—Separable valve coupling or conduit
- Y10T137/1662—Tensile or sheer pin or bolt
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/1624—Destructible or deformable element controlled
- Y10T137/1797—Heat destructible or fusible
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49405—Valve or choke making
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49405—Valve or choke making
- Y10T29/49412—Valve or choke making with assembly, disassembly or composite article making
Definitions
- the present invention relates to fire safety devices, and more particularly to thermally actuated sprinklers commonly used in commercial and residential buildings.
- thermally-actuated fire sprinklers are installed in structures every year. These sprinklers, generally installed in the structure's ceiling, are connected to a pressurized water supply and are intended to release the water into the room when the temperature in the room indicates that a fire or conflagration is taking place.
- a second type of prior art sprinkler valve uses a sealed glass tube nearly filled with a liquid that boils at a low temperature. As ambient temperature increases, the liquid boils, thereby raising the pressure inside the tube. At a high enough temperature the tube ruptures, permitting the sprinkler valve to open. Premature failure may occur, however, if the sprinkler head is subjected to mechanical shock and the tube is cracked.
- Thermally-actuated fire safety devices must meet strict codes. Described herein are thermally-activated, frangible sprinkler valves including a shape-memory element that may meet these codes and address many of the problems identified above.
- thermally-activated valves and methods or making and using them.
- the thermally-activated valves described herein are particularly useful as part of a sprinkler head, though they may be used as part of any appropriate thermally-activated valve.
- these thermally-activated sprinkler valve assemblies include: a temperature-sensitive actuator having a frangible bolt coupled to a shape-memory element, and a fluid passageway with a valved outlet.
- the temperature-sensitive actuator activates the sprinkler valve when the temperature of the shape-memory element reaches or exceeds the pre-determined temperature.
- thermally-activated sprinkler valve assemblies including a fluid passageway having an outlet (configured to connect to a source of pressurized fluid), a valve over the outlet, where the valve is configured to releasably oppose the force of the pressurized fluid, and a temperature-sensitive actuator coupled to the valve.
- the temperature-sensitive actuator includes a frangible bolt and a shape-memory element capable of elongating at a pre-determined stress and temperature, wherein the frangible bolt applies compressive force to the shape-memory element.
- the temperature-sensitive actuator is configured to actuate the valve by breaking the frangible bolt when the temperature of the shape-memory element reaches or exceeds the pre-determined temperature.
- valve assemblies described herein may include a linkage that connects to the valve.
- the temperature-sensitive actuator may be coupled to the valve through a linkage that is configured to oppose the force of pressurized fluid and thereby maintain the valve closed.
- the temperature-sensitive actuator may be positioned in parallel with the linkage.
- a linkage links the actuator with the valve, and can be removed or displaced by the activation of the actuator.
- a linkage may be a linkage bracket, a strut, or the like.
- the linkage is a linkage bracket formed from two generally “T-shaped” brackets. The two linkages may connect to each other and to the valve along one axis (the top of the “T” shape); the actuator may be connected off-axis, between the bases of the “T” shape.
- the temperature-sensitive actuator may be configured so that force from the pressurized fluid is not substantially transmitted to the shape-memory element. Transferring force from the fluid pressure to the shape-memory element may affect the strain profile of the shape-memory element, and alter the actuation temperature.
- the plateau stress of the shape-memory element may be matched to the ultimate tensile strength of the frangible bolt.
- the ultimate tensile strength of the frangible bolt (at which the bolt will break) may be approximately equal to the plateau stress of the shape-memory element. Matching the plateau stress and the ultimate tensile strength in this way may help insure that the actuator acts in a predictable fashion at a predetermined temperature.
- the frangible bolt may be coupled or secured to the shape memory device by a nut or other securing means.
- the bolt may be an elongate bolt that passes through a cylindrical shape-memory element.
- the bolt may be secured against either end of the shape-memory element with a flange and/or nut, placing compressive stress on the shape-memory element.
- a valve assembly may also include a frame portion extending from the fluid passageway.
- a valve assembly may include one or more arms that extend from the fluid passageway.
- the frame portion may provide support for other valve assembly components, such as the linkage.
- the frangible bolt may be modified by including one or more notches or the like.
- the frangible bolt may be notched to set or determine the ultimate tensile strength of the bolt.
- a notch may be an annular notch or a side-notch (e.g., a notch on only one or more sides of the bolt). The notch is typically a small region (compared to the overall length of the bolt) that has a narrower diameter.
- a frangible bolt is typically an elongate shape, and may be cylindrical (e.g., columnar). Other elongate shapes may also be used. Commercially available bolts may also be used. For example, a titanium bolt (e.g., a Ti6Al4V bolt).
- bolts may also be used, including steel (stainless steel) or the like.
- the bolt may be threaded.
- the bolt may be threaded at one or both ends, or along the entire length).
- the bolt may have a head (e.g., a flange) or may be used with washers and one or more nuts.
- the shape-memory element may be made of any appropriate shape memory alloy. Shape-memory alloys capable of elongating up to 7%, 8% or 9% of their length are particularly useful in these actuators.
- the shape-memory element may be a single-crystal CuAlNi alloy or a single-crystal CuAlMn alloy. Shape-memory alloys capable of elongating greater than 7% (such as single-crystal SMAs) typically have a stress plateau that is longer than other (non single-crystal SMAs). This elongated stress plateau means that the actuator has a higher tolerance for breaking the frangible bolt and thereby actuating. In turn, this higher tolerance translates into a higher tolerance for the shape, type, orientation and compressive pressure applied by the frangible bolt component of the actuator.
- the shape-memory element may be a tempered single-crystal shape memory alloy. Tempering (e.g., heat treating to precipitate Al from the single-crystal shape memory alloy) may be used to set the stress profile, including the temperature at which the actuator will actuate.
- the shape-memory element may be any appropriate shape for coupling to the frangible bolt so that it can rupture (break) the bolt when actuation occurs.
- the shape-memory element may be a cylinder at least partially surrounding the frangible bolt.
- the cylinder may have any appropriate cross-section (e.g., circular, elliptical, square, etc.).
- the shape-memory element may be a strut or partial tube (e.g., a half-cylinder, etc.).
- thermally-activated sprinkler valve assemblies including a fluid passageway having a valved outlet and configured to connect to a source of pressurized fluid, a linkage coupled to the valved outlet and configured to oppose the force of pressurized fluid and thereby maintain the valve closed, and a temperature-sensitive actuator coupled to the linkage, wherein the temperature-sensitive actuator includes a frangible bolt, and a shape-memory element capable of elongating as much as eight percent at a pre-determined stress and temperature.
- the frangible bolt applies compressive force to the shape-memory element.
- thermally-activated sprinkler valve assemblies including a fluid passageway having a valved outlet and configured to connect to a source of pressurized fluid, a linkage bracket coupled to the valved outlet and configured to oppose the force of pressurized fluid and thereby maintain the valve closed, and a temperature-sensitive actuator coupled to the linkage bracket.
- the temperature-sensitive actuator includes a frangible bolt and a shape-memory element capable of elongating as much as eight percent at a pre-determined stress and temperature, wherein a length of the frangible bolt applies compressive force to the shape-memory element, an further wherein the plateau stress of the shape-memory element is approximately the same as the ultimate tensile strength of the bolt.
- Also described herein are methods of making a thermally-activated sprinkler valve assembly including the steps of: tuning a shape-memory element comprising single-crystal shape memory alloy to exert a pre-determined force at a pre-determined temperature; forming a temperature-sensitive actuator by coupling a frangible bolt to the shape-memory element so that the shape-memory element is compressed; and coupling the actuator to a linkage, wherein the linkage is configured to couple with the valve of a fluid passageway having a valved outlet to oppose fluid pressure and maintain the valve closed.
- the step of tuning may include tempering the shape-memory alloy by a heat treatment process that causes controlled partial precipitation of Al.
- the method may also include the step of coupling the linkage to the valve of the fluid passageway.
- the step of coupling the actuator to the linkage may comprise coupling the actuator between two brackets forming the linkage.
- the method may also include the step of matching the plateau stress of the shape-memory element to the ultimate tensile strength of the bolt.
- the method may also include the step of connecting the fluid passageway to a fluid source. This step may also be used as part of a method for installing a frangible, temperature-sensitive shape memory actuator for a sprinkler valve.
- FIG. 1A is a stress-strain-temperature plot for CuAlNi single crystal shape memory alloy.
- FIG. 1C is a correlation of A f with composition content of Al. The stress plateau increases 2.2 megapascals for each ° C. increase in ambient temperature.
- FIG. 2A is a stress-strain plot for a notched steel bolt showing its elongation to failure at the ultimate tensile stress of the steel. Tensile force reaches a maximum at the upper limit of elasticity, and diminishes as elongation continues, terminating in fracture at a fraction of one percent strain.
- FIG. 2B is a stress-strain plot for a notched titanium bolt, showing the elongation to failure at the ultimate tensile stress.
- the titanium bolt was a Ti-6Al-4V bolt notched to 0.056 inch.
- the maximum tensile stress is approximately 1999.4 MPa.
- a diamond-shape Carbide insert notching tool having 35° angle and 0.015′′ tip radius was used to form the notch.
- FIG. 3A shows a side view of one variation of a sprinkler including a thermally-activated sprinkler valve assembly.
- FIG. 3B is a front view of the same sprinkler shown in FIG. 3A .
- FIG. 4A shows a side perspective view of one variation of a temperature-sensitive actuator coupled to a linkage formed by two brackets.
- FIG. 4B shows the notched bolt of the actuator of FIG. 4A
- FIG. 4C shows the actuator and the linkage without the notched bolt.
- FIG. 5A is a perspective view of one variation of a notched frangible bolt.
- FIG. 5B is a side view of the frangible bolt of FIG. 5A , showing exemplary dimensions (inches).
- FIG. 5C is a detailed view of the notched region A indicated in FIG. 5B .
- FIG. 6A is a perspective view of one variation of a shape-memory element for an actuator.
- FIG. 6B is a cross-section through the shape-memory element of FIG. 6A , showing exemplary dimensions (inches).
- FIG. 6C is a top view of the shape-memory element of FIG. 6A .
- FIG. 7A is a perspective view of a first linkage bracket that may form a linkage.
- FIG. 7B is a first side view of the linkage bracket of FIG. 7A , with exemplary dimensions (inches), and
- FIG. 7C is another side view of the linkage bracket.
- FIG. 7D is a top view of the linkage bracket of FIG. 7A .
- FIG. 8A is a perspective view of a second linkage bracket that may form a linkage.
- FIG. 8B is a first side view of the linkage bracket of FIG. 8A , with exemplary dimensions (inches), and
- FIG. 8C is another side view of the linkage bracket.
- FIG. 8D is a top view of the linkage bracket of FIG. 8A .
- FIG. 9 illustrates forces acting on a portion of a linkage, and illustrates how a linkage may oppose the force of water pressure and impart direction to the actuator after activation.
- FIG. 10 is a phase diagram for CuAlNi(3%).
- thermally-activated sprinkler valve assemblies may be configured to meet any appropriate performance specifications, particularly those agreed upon by standard-setting bodies such as Underwriter Laboratories (UL).
- UL Underwriter Laboratories
- the thermally-activated sprinkler valve assemblies described herein may meet the UL Standards for Safety for Automatic Sprinklers for Fire Protection Service, US 199 (10 th edition, Apr. 8, 1997, revised Dec. 8, 2003).
- the thermally-activated sprinkler valves described herein may outperform currently available frangible glass, eutectic, and other shape-memory based sprinkler valves because they may be made particularly vibration-insensitive, stable, and predictable.
- the thermally-activated sprinkler valve assemblies described herein include a fluid passageway having an outlet that is valved (over the outlet), and a temperature-sensitive actuator that can be activated to open the valve and allow fluid to flow from the sprinkler.
- the temperature-sensitive actuator typically includes a frangible bolt and a shape-memory element that is coupled to the bolt. Actuation occurs when the shape-memory element expands at a predetermined temperature to break the bolt.
- the fluid passageway of the sprinkler may include a threaded tubular conduit portion which is adapted to be connected to a conduit network of a fire protection system.
- the conduit includes a fluid passage having an inlet for attachment to a pressurized fluid source, such as a pressurized water source, and an outlet.
- the fluid passageway may also be connected to a frame portion or body region, preferably made from a metal such as brass, stainless steel, or other durable, non-corroding conventional sprinkler frame material.
- the frame may extend from the fluid passageway region distally and may have one or more arms.
- a deflector plate assembly for dispersing water when the sprinkler is active may also be attached.
- the fluid passageway is valved, and may include a valve plug.
- the valve communicates with a temperature-sensitive actuator that can be activated to open the otherwise closed valve.
- the temperature-sensitive actuator communicates with the valve through a linkage element, also referred to as a linkage, which is configured to oppose the force applied by the water pressure until activation.
- activation of the sprinkler occurs when the actuator displaces the linkage, releasing the valve to open.
- the frangible bolt acts as the linkage element.
- the temperature-sensitive actuator (or just actuator) includes a frangible bolt and a shape-memory element that are coupled together so that expansion of the shape-memory element may result in breaking of the frangible bolt.
- the frangible bolt may also apply a compression stress on the shape-memory element.
- a shape-memory element may be made of a single-crystal shape-memory alloy (SMA) that has a very large recoverable strain.
- the recoverable strain may be more than nine percent.
- This shape-memory element is compressed and held under load by the frangible bolt.
- the frangible bolt may be notched or otherwise prepared to fracture at a preset stress and strain.
- Single crystal shape memory alloys in addition to having uniquely large recoverable strain, have a plateau in their stress-strain relationship that increases with increasing temperature in a highly predictable manner, as illustrated in FIGS. 1A and 1B .
- By adjusting composition, and by tempering to tune the temperature at which a specified stress (and hence force) is applied by the SMA element it is possible to precisely match the force exerted by a frangible bolt, and to elongate it to failure. See FIG. 2A , showing the stress/strain relationship for a notched steel bolt, and FIG. 2B showing the stress/strain relationship for a notched titanium bolt.
- a high-tolerance actuator may be made by matching the point on the stress/strain curve from the frangible bolt (the ultimate tensile strength) with the plateau stress of the shape-memory element. Matching these characteristics of the frangible bolt and the shape memory element allows selection of the precise temperature of actuation, which may be specified. Such precise actuators may therefore be manufactured at low cost, because this ‘tuning’ can be done only once per lot of material.
- the actuator including the shape-memory element and the frangible bolt may be connected to the valve opposing the fluid pressure so that the force of the fluid pressure is not substantially communicated to the shape-memory element.
- the SMA element and bolt may be offset from the force of the fluid pressure so that the fluid pressure force is not directly applied to either the bolt or the shape-memory element.
- the bolt may be pre-loaded to its optimum tension (for the shape-memory element) independent of the force applied by the pressurized liquid. Since the force applied to the shape-memory element is not dependent on the (potentially variable) fluid pressure, the fluid pressure force will not alter the activation temperature for the actuator.
- the stress plateau in a CuAlNi (or CuAlMn) single crystal is related to the austenite finish temperature, A f , of the material.
- the stress plateau is determined by the difference between A f and the actuation temperature multiplied by a constant (approximately 2.2 Mpa per ° C.). For example, see FIG. 1A-1C .
- a f is the temperature at which transformation from martensite (low temperature phase) to austenite is completed at zero stress.
- a f is determined primarily by the composition of the ingot from which the crystal is grown.
- FIG. 10 shows a phase diagram for the CuAlNi alloy system showing the phases that may exist in molten alloy at various temperatures. Since nanocrystalline Al does not participate in the phase transformation, controlled precipitation of Al is a method of precisely tuning the A f of the material. Controlled selective precipitation for the purpose of adjusting the actuation temperature of the SMA is a unique form of tempering.
- the shape-memory element provides the mechanical energy necessary to actuate the actuators described herein, and actuation occurs by breaking the frangible bolt and releasing the valve.
- a shape-memory element may be a cylinder of single-crystal, hyperelastic CuAlNi having a transition temperature above room temperature with a stress plateau at about 200 Mpa.
- Other examples of shape-memory elements that may be used are provided herein, and generally the properties of the shape-memory element are matched to the properties of the bolt.
- the shape-memory element is a cylinder with a cross-section that applies a force of 40 kg at the stress plateau to a bolt that fractures at 40 kg elongation force when elongated more than 3% of its length.
- the frangible bolt may be secured by a nut that pre-loads the bolt to a tensile 35 kg force (and thus applies an opposing compressive force to the shape memory element).
- the bolt applies this compressive force to the shape memory element.
- the shape-memory element may be compressed approximately 9 percent of its length while the SMA is in its martensitic state.
- FIGS. 3A and 3B shows one variation of a sprinkler having a thermally-activated sprinkler valve assembly as described.
- the sprinkler 300 includes a temperature-sensitive actuator 305 , connected to a linkage 315 , 315 ′, which is held in communication with a valve (the outside 301 of which is visible in FIGS. 3A and 3B ) and is supported by a frame 331 or body region.
- a deflector plate 333 is attached to (or integral with) the frame 331 .
- the frame 331 in this example includes two arms.
- the temperature-sensitive actuator 305 includes a frangible bolt 309 , the bottom of which is visible in FIGS. 3A and 3B , which is secured to (and compresses) a shape-memory element 321 formed as a cylinder.
- the bolt is secured to linkage 315 , 315 ′ and held within the cylinder by a nut 307 on one end, and is also attached to a washer 311 on the opposite end.
- the linkage is formed by an upper bracket 315 and a lower bracket 315 ′ that are held together between the valve 301 and the frame 331 .
- the shape-memory element When the temperature-sensitive actuator is activated by reaching or exceeding the pre-determined activation temperature, the shape-memory element will expand (e.g., greater than 5%, greater than 6%, greater than 7%, greater than 8% or greater than 9% of its compressed length), and break the frangible bolt 309 . Breaking the frangible bolt causes the upper and lower brackets of the linkage to separate under the force provided by the source of liquid (e.g., water) pressure, and thereby release the valve opposing the force of the liquid pressure, allowing water to flow out of the valve. The water may strike the deflector plate. After activation, the temperature-sensitive actuator and the linkage may fall way from the rest of the sprinkler.
- the source of liquid e.g., water
- FIG. 3B shows a partial cut-away view of the sprinkler of FIG. 3A (in which one of the “arms” of the frame 331 have been removed).
- the linkage is formed by an upper 315 and lower 315 ′ bracket that are configured so that the majority of the force of the liquid pressure is opposed by the linkage, and the temperature-sensitive actuator 305 is mounted in parallel to the linkage.
- the frangible bolt holds the two approximately right-angle-shaped linkage members secure until heat causes the SMA element to expand and fracture the frangible bolt, causing the linkage to collapse and release the fluid pressure.
- the compressive force on the shape-memory element is predominantly applied by the bolt 309 , and the shape-memory element does not receive a substantial amount of the force from the fluid pressure.
- the actuator consisting of the shape-memory element and frangible bolt
- the actuator can be tuned to actuate at a predetermined temperature (and force) independent of the force exerted by the fluid force. If this were not so, the actual force seen by the frangible bolt may depend on the sum of the (variable) fluid force and the (constant) pre-load force, and the result would be undesirable variation of the actuation temperature.
- FIG. 4A shows a perspective view of the temperature-sensitive actuator and linkage similar to that shown in FIGS. 3A and 3B .
- the shape-memory element 421 is a cylinder that is compressed by the frangible bolt 409 between two brackets 415 , 415 ′ forming a linkage.
- the two brackets in this example are nearly identical right-angle-shaped members 415 , 415 ′ that interconnect.
- One of the brackets 415 has a pointed (or male) end 416 that mates with concave (or female) end 417 on the other bracket 415 ′.
- the opposite ends of the brackets forming the linkage 418 , 418 ′ are also configured to releasably mate with the valve and/or the frame 331 .
- these ends are pointed, but they may be rounded, blunt, or any other appropriate shape.
- the two brackets may be identical, each having one convex end and one concave end.
- FIG. 4B shows the frangible pin from FIG. 4A removed from the temperature-sensitive actuator
- FIG. 4C shows the shape-memory element and linkage with the frangible pin removed.
- FIGS. 5A-5C also show greater detail of a frangible bolt.
- frangible bolt is an elongate member.
- the frangible bolt may be a cylindrical bolt (as shown in FIGS. 4B-5B ) including a threaded portion 422 .
- the threads may mate with a nut.
- the entire bolt may be threaded or just one or more regions may be threaded. In some variations, the thread mates with the linkage.
- Other bolt shapes may also be used.
- the bolt 409 may include a head region 413 that has a flanged portion extending outward from the elongate length of the bolt.
- the head region 413 in this example is slotted, but it may be otherwise configured for securing or gripping.
- a frangible bolt may also be notched.
- the notch 411 is shown as an annular cut-out region.
- FIG. 5C illustrates this region in greater detail.
- the notch may be formed by any appropriate manner, including removing material from the bolt after it has been formed, or it may be cast as an initial part of the bolt. In some variations the notch does not extend annularly, but may be present on only one side or region of the bolt. Such asymmetric notching may help direct the fracturing of the frangible bolt.
- the depth of the notch may help set the ultimate tensile strength of the frangible bolt (the stress at which the bolt will fracture), and may therefore help match the bolt to the shape-memory element, as described below.
- the notch may be located at any position along the length of the bolt, and the location of the notch along the bolt may also help determine the ultimate tensile strength.
- the bolt may include only one notch or multiple notches.
- the bolt may be made of any appropriate material, particularly metals including alloys.
- the bolt may be a titanium bolt, such as a Ti6Al4V bolt, a steel (e.g., stainless steel) bolt, or the like.
- FIGS. 6A-6C show one variation of a shape-memory element that may be used as part of a temperature-sensitive actuator, which is configured as a cylinder.
- FIG. 6A shows a perspective view of this cylindrical shape-memory element, which has a circular cross-sectional profile (shown in FIG. 6C ).
- the shape-memory element has a length that is slightly less than length of the bolt.
- the cylindrical shape-memory element in this example is hollow, so that it can surround the frangible bolt.
- a cylindrical shape-memory element may have a non-circular cross-section (e.g., an elliptical, cross-section, a square cross-section, etc.).
- the shape-memory element may be configured as a strut that is not hollow and which fastens to the bolt in two or more places.
- the shape-memory element may be a partial tube (e.g. a c-shaped tube).
- the shape-memory element may be made of a single-crystal shape memory alloy, such as a single-crystal CuAlNi alloy or a single-crystal CuAlMn alloy.
- the shape-memory element may be made of a shape-memory material capable of elongating up to 7%, 8% or 9% of their length, referred to as “hyperelastic” shape memory alloys.
- the exact composition (percent composition) of the shape-memory alloy may be modified or pre-determined to help match the stress plateau characteristics of the shape-memory element with the stress profile (e.g., ultimate tensile strength) of the frangible bolt.
- the temperature-sensitive actuator may include a frangible bolt whose peak strength is matched to the stress plateau of the shape-memory element.
- the temperature sensitive actuator may be made by first selecting a desired actuation temperature A t .
- the actuation temperature, A t may be selected from within the range of about ⁇ 200 to +200° C.
- An optimum stress plateau level (S p ) may then be chosen.
- S p may be between 50 and 600 Mpa.
- a f is the austenite finish temperature of the shape-memory element, as described above.
- percent elongation e.g., 5%, 6%, 7%, 8%, 9% elongation
- the ingot composition that will produce single crystal material with A f can be chosen in order to make the shape-memory actuator.
- the shape-memory actuator is a cylinder
- a cylinder with a cross-section X c , length L a , and an opening large enough to accommodate the bolt may be fabricated.
- the shape-memory element can then be compressed.
- a press can be used to compress the actuator to its 9 percent limit, and to maintain this shortened length by keeping the actuator well below A f .
- the bolt, shape-memory element, and any other elements in the joint can then be assembled.
- the nut can be tightened so that there is no slack in the joint.
- the remainder of the sprinkler valve body can be installed, including the linkage.
- any appropriate linkage may be used to connect the actuator to the sprinkler.
- a linkage that opposes the force of fluid (e.g., water pressure) when the device is connected to a source of fluid pressure and the valve is closed.
- linkages that do not transfer a substantial portion (if any) of the fluid pressure to the shape-memory element when the actuator is installed with the other components of the sprinkler.
- a linkage may connect or couple with the valve that opposes the fluid pressure from a source of pressurized fluid that is connected to the fluid passageway of the device.
- the linkage may abut or contact a portion of a valve (e.g., a valve plug), to prevent the fluid pressure from opening the valve.
- the linkage may also be connected or coupled to the body of the fluid passageway (or another portion of the sprinkler body that is connected to the body of the fluid passageway).
- the linkage is coupled to the frame 331 .
- the linkage may be configured to readily un-couple from the valve (and/or frame or sprinkler body) when the actuator triggers upon braking of the frangible bolt.
- the frangible bolt may act as the linkage.
- one end of the frangible bolt may be coupled to the valve, and the other end may be functionally coupled to a frame connected to the sprinkler body.
- FIGS. 7A-7D illustrate one variation of an upper linkage.
- FIG. 7A shows a perspective view of an upper linkage bracket 701 having a generally “T” shape.
- the bracket may be formed from a single (flat) piece of metal that is cut and bent to form the shape illustrated.
- the region of the bracket configured to hold the actuator 703 is formed by the base of the “T” shape, and may include a hole or passage 705 through which the actuator (e.g., the frangible bolt portion of the actuator) may pass.
- the top of the “T’ shape in this linkage forms three prongs.
- One of the prongs 709 is configured to communicate with the valve, and the other two prongs 711 are configured to communicate with (e.g., mate with) prongs extending from the lower linkage.
- three prongs are shown, two prongs may be used.
- the orientation of the prongs may be different; for example, the two prongs 711 may be configured to couple with the valve and the single prong may be configured to couple with the other linkage.
- FIG. 7B shows a top view
- FIGS. 7C and 7D show sides view of the upper bracket 701 .
- FIGS. 8A-8D show an example of a lower bracket linkage that may be used with the upper bracket linkage of FIGS. 7A-7D to couple with an actuator and the valve of a fluid passageway.
- the lower bracket is very similar to the upper bracket, except that the two prongs that mate with the upper bracket prongs 811 , 811 ′ are shaped to receive the upper bracket prongs.
- the linkage may be configured so that the activation of the temperature-sensitive actuator causes a predictable release.
- FIG. 9 illustrates the cross-section of another variation of an upper bracket that is configured so that activation of the actuator, and breaking of the frangible bolt, causes a predictable release.
- FIG. 9 shows only an upper bracket, a second, nearly identical lower bracket may have a similar design.
- the upper bracket linkage shown in FIG. 9 is similar in orientation to the upper bracket linkage shown in FIG. 7C , only rotated 90 degrees counterclockwise.
- the first prong 909 of the bracket is configured to communication with the valve and oppose the force of the fluid pressure (indicated by F water ).
- the opposite prong 911 or prongs are configured to mate with a lower bracket linkage which in turn mates with the frame (also referred to as a “yoke”) connected to the body of the fluid passageway.
- these prong(s) 911 receive the counter force, F yoke , to help balance the F water and thereby keep the valve closed while the linkage is intact.
- the bolt of the temperature-sensitive actuator also acts on the brackets by providing a force F bolt that is also opposed and balanced by the counterforce from the frame, F yolk .
- F water the force of the fluid pressure
- F bolt times the length of the lever arm L water (the length seen by the F water in relation to the opposing force F yolk ) is balanced by the force of the bolt, F bolt , times the lever arm L bolt , preventing the bracket from rotating and coming uncoupled.
- the ratio between the lengths of the lever arms and the forces applied by the bolt and the fluid (water) on the bracket are generally balanced as a 1:8 ratio, but any appropriate ration may be used.
- the force applied to the bracket will unbalance as the bolt breaks, resulting in the rotation and uncoupling of the bracket, removing the linkage and releasing the valve.
- a thermally-activated sprinkler valve assembly as illustrated may be made by any appropriate method, as mentioned above.
- this method of making a thermally-activated sprinkler valve may include first tuning a shape-memory element to exert a pre-determined force at a pre-determined temperature.
- tuning involves selecting the activation temperature (A t ), and setting the austenite finish temperature (A f ) based on that temperature. This may be accomplished in part by tempering.
- a shape-memory element comprising single-crystal shape memory alloy can be tempered by heat treating and controlling the partial precipitation of Al from the single-crystal material. Tweaking the concentration of Al will adjust the A f .
- Tuning may include matching the plateau stress of the shape-memory element to the ultimate tensile stress (the breaking point) of the frangible bolt. Stress profile may be examined periodically to determine the plateau stress (as shown in FIGS. 1A and 1B ), or it may be calculated.
- the shape-memory material may also be tuned by otherwise manipulating the composition of the shape-memory material (e.g., doping, etc.).
- the ultimate tensile strength of the bolt may also (or alternatively) be set based on the shape-memory element (e.g., the plateau stress). For example, the bolt shape and size may be selected to set the ultimate tensile strength. Thus, the bolt may be notched or otherwise treated to set the approximate ultimate tensile strength of the bolt.
- the temperature-sensitive actuator may then be formed by coupling the frangible bolt to the shape-memory element so that the shape-memory element is compressed by the frangible bolt.
- the actuator may be attached to the rest of the thermally-activated sprinkler by coupling the actuator to a linkage, wherein the linkage is configured to couple with the valve of a fluid passageway having a valved outlet to oppose fluid pressure and maintain the valve closed.
- the assembled sprinkler may then be attached to a fluid source.
- a temperature-sensitive actuator may be used as part of a release valve for pressurized fluids including gasses. While the methods and devices have been described in some detail here by way of illustration and example, such illustration and example is for purposes of clarity of understanding only. It will be readily apparent to those of ordinary skill in the art in light of the teachings herein that certain changes and modifications may be made thereto without departing from the spirit and scope of the invention.
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Abstract
Description
- This application claims the benefit under 35 U.S.C. §119 of U.S. Provisional Patent Application No. 60/897,708 (titled “SHAPE MEMORY ALLOY FIRE SPRINKLER VALVE ACTUATOR”), filed Jan. 25, 2007, which is incorporated by reference as if fully set forth herein.
- All publications, patents, and patent applications mentioned in this specification are herein incorporated by reference in their entirety as if each individual publication or patent application was specifically and individually indicated to be incorporated by reference in its entirety.
- The present invention relates to fire safety devices, and more particularly to thermally actuated sprinklers commonly used in commercial and residential buildings.
- Large numbers of thermally-actuated fire sprinklers are installed in structures every year. These sprinklers, generally installed in the structure's ceiling, are connected to a pressurized water supply and are intended to release the water into the room when the temperature in the room indicates that a fire or conflagration is taking place.
- Multiple techniques have been used to actuate prior art fire sprinkler heads. Some prior art sprinkler valves bond two components together with alloys that melt at low temperatures. When heated above the melting temperature of the eutectic alloy, the bond between the two components is released, and a control valve is permitted to open. This type of actuator is subject to failure as the solder ages and crystallizes, thereby weakening the bond.
- A second type of prior art sprinkler valve uses a sealed glass tube nearly filled with a liquid that boils at a low temperature. As ambient temperature increases, the liquid boils, thereby raising the pressure inside the tube. At a high enough temperature the tube ruptures, permitting the sprinkler valve to open. Premature failure may occur, however, if the sprinkler head is subjected to mechanical shock and the tube is cracked.
- Yet other prior art sprinkler valves incorporate shape memory components that change shape when a transition temperature is reached to actuate the sprinkler valve. Some such thermally actuated valves are described in U.S. Pat. No. 4,176,719; U.S. Pat. No. 4,549,717; U.S. Pat. No. 4,596,483; U.S. Pat. No. 4,706,758; U.S. Pat. No. 4,848,388; U.S. Pat. No. 4,896,728; U.S. Pat. No. 5,117,916; U.S. Pat. No. 5,494,113; U.S. Pat. No. 5,622,225; U.S. Pat. No. 5,924,492; U.S. Pat. No. 6,073,700; U.S. Pat. No. 6,840,329; and U.S. Pat. No. 6,843,465. However, these devices do not typically control the transition temperature of the shape memory alloy, and the valve structures may therefore be less reliable and overly complex.
- False triggering of sprinkler heads can cause damage that is expensive to repair and contributes to the cost of fire insurance. Thermally-actuated fire safety devices must meet strict codes. Described herein are thermally-activated, frangible sprinkler valves including a shape-memory element that may meet these codes and address many of the problems identified above.
- Described herein are thermally-activated valves and methods or making and using them. The thermally-activated valves described herein are particularly useful as part of a sprinkler head, though they may be used as part of any appropriate thermally-activated valve.
- In general, these thermally-activated sprinkler valve assemblies include: a temperature-sensitive actuator having a frangible bolt coupled to a shape-memory element, and a fluid passageway with a valved outlet. The temperature-sensitive actuator activates the sprinkler valve when the temperature of the shape-memory element reaches or exceeds the pre-determined temperature.
- For example, described herein are thermally-activated sprinkler valve assemblies including a fluid passageway having an outlet (configured to connect to a source of pressurized fluid), a valve over the outlet, where the valve is configured to releasably oppose the force of the pressurized fluid, and a temperature-sensitive actuator coupled to the valve. The temperature-sensitive actuator includes a frangible bolt and a shape-memory element capable of elongating at a pre-determined stress and temperature, wherein the frangible bolt applies compressive force to the shape-memory element. The temperature-sensitive actuator is configured to actuate the valve by breaking the frangible bolt when the temperature of the shape-memory element reaches or exceeds the pre-determined temperature.
- Any of the valve assemblies described herein may include a linkage that connects to the valve. For example, the temperature-sensitive actuator may be coupled to the valve through a linkage that is configured to oppose the force of pressurized fluid and thereby maintain the valve closed. The temperature-sensitive actuator may be positioned in parallel with the linkage.
- Any appropriate linkage may be used. In general, a linkage links the actuator with the valve, and can be removed or displaced by the activation of the actuator. For example, a linkage may be a linkage bracket, a strut, or the like. In one variation, the linkage is a linkage bracket formed from two generally “T-shaped” brackets. The two linkages may connect to each other and to the valve along one axis (the top of the “T” shape); the actuator may be connected off-axis, between the bases of the “T” shape.
- The temperature-sensitive actuator may be configured so that force from the pressurized fluid is not substantially transmitted to the shape-memory element. Transferring force from the fluid pressure to the shape-memory element may affect the strain profile of the shape-memory element, and alter the actuation temperature.
- The plateau stress of the shape-memory element may be matched to the ultimate tensile strength of the frangible bolt. For example, the ultimate tensile strength of the frangible bolt (at which the bolt will break) may be approximately equal to the plateau stress of the shape-memory element. Matching the plateau stress and the ultimate tensile strength in this way may help insure that the actuator acts in a predictable fashion at a predetermined temperature.
- The frangible bolt may be coupled or secured to the shape memory device by a nut or other securing means. For example, the bolt may be an elongate bolt that passes through a cylindrical shape-memory element. The bolt may be secured against either end of the shape-memory element with a flange and/or nut, placing compressive stress on the shape-memory element.
- A valve assembly may also include a frame portion extending from the fluid passageway. For example, a valve assembly may include one or more arms that extend from the fluid passageway. The frame portion may provide support for other valve assembly components, such as the linkage.
- The frangible bolt may be modified by including one or more notches or the like. The frangible bolt may be notched to set or determine the ultimate tensile strength of the bolt. A notch may be an annular notch or a side-notch (e.g., a notch on only one or more sides of the bolt). The notch is typically a small region (compared to the overall length of the bolt) that has a narrower diameter. A frangible bolt is typically an elongate shape, and may be cylindrical (e.g., columnar). Other elongate shapes may also be used. Commercially available bolts may also be used. For example, a titanium bolt (e.g., a Ti6Al4V bolt). Other bolts may also be used, including steel (stainless steel) or the like. The bolt may be threaded. For example, the bolt may be threaded at one or both ends, or along the entire length). The bolt may have a head (e.g., a flange) or may be used with washers and one or more nuts.
- The shape-memory element may be made of any appropriate shape memory alloy. Shape-memory alloys capable of elongating up to 7%, 8% or 9% of their length are particularly useful in these actuators. In particular, the shape-memory element may be a single-crystal CuAlNi alloy or a single-crystal CuAlMn alloy. Shape-memory alloys capable of elongating greater than 7% (such as single-crystal SMAs) typically have a stress plateau that is longer than other (non single-crystal SMAs). This elongated stress plateau means that the actuator has a higher tolerance for breaking the frangible bolt and thereby actuating. In turn, this higher tolerance translates into a higher tolerance for the shape, type, orientation and compressive pressure applied by the frangible bolt component of the actuator.
- The shape-memory element may be a tempered single-crystal shape memory alloy. Tempering (e.g., heat treating to precipitate Al from the single-crystal shape memory alloy) may be used to set the stress profile, including the temperature at which the actuator will actuate.
- The shape-memory element may be any appropriate shape for coupling to the frangible bolt so that it can rupture (break) the bolt when actuation occurs. For example, the shape-memory element may be a cylinder at least partially surrounding the frangible bolt. The cylinder may have any appropriate cross-section (e.g., circular, elliptical, square, etc.). The shape-memory element may be a strut or partial tube (e.g., a half-cylinder, etc.).
- Also described herein are thermally-activated sprinkler valve assemblies including a fluid passageway having a valved outlet and configured to connect to a source of pressurized fluid, a linkage coupled to the valved outlet and configured to oppose the force of pressurized fluid and thereby maintain the valve closed, and a temperature-sensitive actuator coupled to the linkage, wherein the temperature-sensitive actuator includes a frangible bolt, and a shape-memory element capable of elongating as much as eight percent at a pre-determined stress and temperature. The frangible bolt applies compressive force to the shape-memory element. Any of the features described above may also be included as part of this sprinkler valve assembly.
- Also described herein are thermally-activated sprinkler valve assemblies including a fluid passageway having a valved outlet and configured to connect to a source of pressurized fluid, a linkage bracket coupled to the valved outlet and configured to oppose the force of pressurized fluid and thereby maintain the valve closed, and a temperature-sensitive actuator coupled to the linkage bracket. The temperature-sensitive actuator includes a frangible bolt and a shape-memory element capable of elongating as much as eight percent at a pre-determined stress and temperature, wherein a length of the frangible bolt applies compressive force to the shape-memory element, an further wherein the plateau stress of the shape-memory element is approximately the same as the ultimate tensile strength of the bolt.
- Also described herein are methods of making a thermally-activated sprinkler valve assembly including the steps of: tuning a shape-memory element comprising single-crystal shape memory alloy to exert a pre-determined force at a pre-determined temperature; forming a temperature-sensitive actuator by coupling a frangible bolt to the shape-memory element so that the shape-memory element is compressed; and coupling the actuator to a linkage, wherein the linkage is configured to couple with the valve of a fluid passageway having a valved outlet to oppose fluid pressure and maintain the valve closed.
- The step of tuning may include tempering the shape-memory alloy by a heat treatment process that causes controlled partial precipitation of Al.
- The method may also include the step of coupling the linkage to the valve of the fluid passageway. For example, the step of coupling the actuator to the linkage may comprise coupling the actuator between two brackets forming the linkage.
- The method may also include the step of matching the plateau stress of the shape-memory element to the ultimate tensile strength of the bolt.
- The method may also include the step of connecting the fluid passageway to a fluid source. This step may also be used as part of a method for installing a frangible, temperature-sensitive shape memory actuator for a sprinkler valve.
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FIG. 1A is a stress-strain-temperature plot for CuAlNi single crystal shape memory alloy. The alloy is a CuAl(14.3%)Ni(4.5%), Af=−40° C.FIG. 1B is a stress-strain curve for CuAl(14.0%)Ni(4.5%), Af=+15° C.FIG. 1C is a correlation of Af with composition content of Al. The stress plateau increases 2.2 megapascals for each ° C. increase in ambient temperature. -
FIG. 2A is a stress-strain plot for a notched steel bolt showing its elongation to failure at the ultimate tensile stress of the steel. Tensile force reaches a maximum at the upper limit of elasticity, and diminishes as elongation continues, terminating in fracture at a fraction of one percent strain. -
FIG. 2B is a stress-strain plot for a notched titanium bolt, showing the elongation to failure at the ultimate tensile stress. The titanium bolt was a Ti-6Al-4V bolt notched to 0.056 inch. The maximum tensile stress is approximately 1999.4 MPa. A diamond-shape Carbide insert notching tool having 35° angle and 0.015″ tip radius was used to form the notch. -
FIG. 3A shows a side view of one variation of a sprinkler including a thermally-activated sprinkler valve assembly.FIG. 3B is a front view of the same sprinkler shown inFIG. 3A . -
FIG. 4A shows a side perspective view of one variation of a temperature-sensitive actuator coupled to a linkage formed by two brackets.FIG. 4B shows the notched bolt of the actuator ofFIG. 4A , andFIG. 4C shows the actuator and the linkage without the notched bolt. -
FIG. 5A is a perspective view of one variation of a notched frangible bolt.FIG. 5B is a side view of the frangible bolt ofFIG. 5A , showing exemplary dimensions (inches).FIG. 5C is a detailed view of the notched region A indicated inFIG. 5B . -
FIG. 6A is a perspective view of one variation of a shape-memory element for an actuator.FIG. 6B is a cross-section through the shape-memory element ofFIG. 6A , showing exemplary dimensions (inches).FIG. 6C is a top view of the shape-memory element ofFIG. 6A . -
FIG. 7A is a perspective view of a first linkage bracket that may form a linkage.FIG. 7B is a first side view of the linkage bracket ofFIG. 7A , with exemplary dimensions (inches), andFIG. 7C is another side view of the linkage bracket.FIG. 7D is a top view of the linkage bracket ofFIG. 7A . -
FIG. 8A is a perspective view of a second linkage bracket that may form a linkage.FIG. 8B is a first side view of the linkage bracket ofFIG. 8A , with exemplary dimensions (inches), andFIG. 8C is another side view of the linkage bracket.FIG. 8D is a top view of the linkage bracket ofFIG. 8A . -
FIG. 9 illustrates forces acting on a portion of a linkage, and illustrates how a linkage may oppose the force of water pressure and impart direction to the actuator after activation. -
FIG. 10 is a phase diagram for CuAlNi(3%). - Described herein are thermally-activated sprinkler valve assemblies. These thermally-activated sprinkler valve assemblies may be configured to meet any appropriate performance specifications, particularly those agreed upon by standard-setting bodies such as Underwriter Laboratories (UL). For example, the thermally-activated sprinkler valve assemblies described herein may meet the UL Standards for Safety for Automatic Sprinklers for Fire Protection Service, US 199 (10th edition, Apr. 8, 1997, revised Dec. 8, 2003). In particular, the thermally-activated sprinkler valves described herein may outperform currently available frangible glass, eutectic, and other shape-memory based sprinkler valves because they may be made particularly vibration-insensitive, stable, and predictable.
- In general, the thermally-activated sprinkler valve assemblies described herein include a fluid passageway having an outlet that is valved (over the outlet), and a temperature-sensitive actuator that can be activated to open the valve and allow fluid to flow from the sprinkler. The temperature-sensitive actuator typically includes a frangible bolt and a shape-memory element that is coupled to the bolt. Actuation occurs when the shape-memory element expands at a predetermined temperature to break the bolt.
- The fluid passageway of the sprinkler may include a threaded tubular conduit portion which is adapted to be connected to a conduit network of a fire protection system. The conduit includes a fluid passage having an inlet for attachment to a pressurized fluid source, such as a pressurized water source, and an outlet. The fluid passageway may also be connected to a frame portion or body region, preferably made from a metal such as brass, stainless steel, or other durable, non-corroding conventional sprinkler frame material. For example, the frame may extend from the fluid passageway region distally and may have one or more arms. A deflector plate assembly for dispersing water when the sprinkler is active may also be attached. The fluid passageway is valved, and may include a valve plug. The valve communicates with a temperature-sensitive actuator that can be activated to open the otherwise closed valve. In some variations the temperature-sensitive actuator communicates with the valve through a linkage element, also referred to as a linkage, which is configured to oppose the force applied by the water pressure until activation. In these variations, activation of the sprinkler occurs when the actuator displaces the linkage, releasing the valve to open. In some variations, the frangible bolt acts as the linkage element.
- The temperature-sensitive actuator (or just actuator) includes a frangible bolt and a shape-memory element that are coupled together so that expansion of the shape-memory element may result in breaking of the frangible bolt. The frangible bolt may also apply a compression stress on the shape-memory element.
- A shape-memory element may be made of a single-crystal shape-memory alloy (SMA) that has a very large recoverable strain. For example, the recoverable strain may be more than nine percent. This shape-memory element is compressed and held under load by the frangible bolt. As described in more detail below, the frangible bolt may be notched or otherwise prepared to fracture at a preset stress and strain.
- Single crystal shape memory alloys, in addition to having uniquely large recoverable strain, have a plateau in their stress-strain relationship that increases with increasing temperature in a highly predictable manner, as illustrated in
FIGS. 1A and 1B . By adjusting composition, and by tempering to tune the temperature at which a specified stress (and hence force) is applied by the SMA element, it is possible to precisely match the force exerted by a frangible bolt, and to elongate it to failure. SeeFIG. 2A , showing the stress/strain relationship for a notched steel bolt, andFIG. 2B showing the stress/strain relationship for a notched titanium bolt. - Thus, a high-tolerance actuator may be made by matching the point on the stress/strain curve from the frangible bolt (the ultimate tensile strength) with the plateau stress of the shape-memory element. Matching these characteristics of the frangible bolt and the shape memory element allows selection of the precise temperature of actuation, which may be specified. Such precise actuators may therefore be manufactured at low cost, because this ‘tuning’ can be done only once per lot of material.
- In assembling the valve, the actuator including the shape-memory element and the frangible bolt may be connected to the valve opposing the fluid pressure so that the force of the fluid pressure is not substantially communicated to the shape-memory element. For example, the SMA element and bolt may be offset from the force of the fluid pressure so that the fluid pressure force is not directly applied to either the bolt or the shape-memory element. This means that the bolt may be pre-loaded to its optimum tension (for the shape-memory element) independent of the force applied by the pressurized liquid. Since the force applied to the shape-memory element is not dependent on the (potentially variable) fluid pressure, the fluid pressure force will not alter the activation temperature for the actuator.
- In general, the stress plateau in a CuAlNi (or CuAlMn) single crystal is related to the austenite finish temperature, Af, of the material. The stress plateau is determined by the difference between Af and the actuation temperature multiplied by a constant (approximately 2.2 Mpa per ° C.). For example, see
FIG. 1A-1C . Af is the temperature at which transformation from martensite (low temperature phase) to austenite is completed at zero stress. Af is determined primarily by the composition of the ingot from which the crystal is grown. A composition of 81.2 weight percent Cu, 14.3 weight percent Al, and 4.5 weight percent Ni, for example, produces an Af transition temperature near −40° C. - Slight variations in composition, even of the order of 0.1 percent, can result in a significant variation of Af, as shown in
FIG. 1C . Such variations may result from weight measurement inaccuracies, or evaporation of metal from the melt before or during the crystal pulling operation, and so are difficult (if not impossible) to control with the precision necessary to meet sprinkler specifications. Actuation temperatures for sprinkler systems are preferably controlled within plus or minus about 3° C. This limitation may be overcome in the sprinkler valves described herein by tempering the SMA material used. - At elevated temperatures, Al gradually precipitates as nanocrystals.
FIG. 10 shows a phase diagram for the CuAlNi alloy system showing the phases that may exist in molten alloy at various temperatures. Since nanocrystalline Al does not participate in the phase transformation, controlled precipitation of Al is a method of precisely tuning the Af of the material. Controlled selective precipitation for the purpose of adjusting the actuation temperature of the SMA is a unique form of tempering. - The shape-memory element provides the mechanical energy necessary to actuate the actuators described herein, and actuation occurs by breaking the frangible bolt and releasing the valve. For example, a shape-memory element may be a cylinder of single-crystal, hyperelastic CuAlNi having a transition temperature above room temperature with a stress plateau at about 200 Mpa. Other examples of shape-memory elements that may be used are provided herein, and generally the properties of the shape-memory element are matched to the properties of the bolt. In this first example, the shape-memory element is a cylinder with a cross-section that applies a force of 40 kg at the stress plateau to a bolt that fractures at 40 kg elongation force when elongated more than 3% of its length. The frangible bolt may be secured by a nut that pre-loads the bolt to a tensile 35 kg force (and thus applies an opposing compressive force to the shape memory element). The bolt applies this compressive force to the shape memory element. For example the shape-memory element may be compressed approximately 9 percent of its length while the SMA is in its martensitic state.
-
FIGS. 3A and 3B shows one variation of a sprinkler having a thermally-activated sprinkler valve assembly as described. In this example, thesprinkler 300 includes a temperature-sensitive actuator 305, connected to alinkage FIGS. 3A and 3B ) and is supported by aframe 331 or body region. Adeflector plate 333 is attached to (or integral with) theframe 331. Theframe 331 in this example includes two arms. - The temperature-
sensitive actuator 305 includes afrangible bolt 309, the bottom of which is visible inFIGS. 3A and 3B , which is secured to (and compresses) a shape-memory element 321 formed as a cylinder. The bolt is secured tolinkage nut 307 on one end, and is also attached to awasher 311 on the opposite end. The linkage is formed by anupper bracket 315 and alower bracket 315′ that are held together between thevalve 301 and theframe 331. When the temperature-sensitive actuator is activated by reaching or exceeding the pre-determined activation temperature, the shape-memory element will expand (e.g., greater than 5%, greater than 6%, greater than 7%, greater than 8% or greater than 9% of its compressed length), and break thefrangible bolt 309. Breaking the frangible bolt causes the upper and lower brackets of the linkage to separate under the force provided by the source of liquid (e.g., water) pressure, and thereby release the valve opposing the force of the liquid pressure, allowing water to flow out of the valve. The water may strike the deflector plate. After activation, the temperature-sensitive actuator and the linkage may fall way from the rest of the sprinkler. -
FIG. 3B shows a partial cut-away view of the sprinkler ofFIG. 3A (in which one of the “arms” of theframe 331 have been removed). InFIG. 3B it is apparent that the linkage is formed by an upper 315 and lower 315′ bracket that are configured so that the majority of the force of the liquid pressure is opposed by the linkage, and the temperature-sensitive actuator 305 is mounted in parallel to the linkage. Thus, the force exerted by the liquid pressure is not transferred to the frangible bolt via the linkage. The frangible bolt holds the two approximately right-angle-shaped linkage members secure until heat causes the SMA element to expand and fracture the frangible bolt, causing the linkage to collapse and release the fluid pressure. The compressive force on the shape-memory element is predominantly applied by thebolt 309, and the shape-memory element does not receive a substantial amount of the force from the fluid pressure. - In this example, it is significant that the force due to fluid pressure is transferred to the linkage and not to the frangible bolt because the actuator, consisting of the shape-memory element and frangible bolt, can be tuned to actuate at a predetermined temperature (and force) independent of the force exerted by the fluid force. If this were not so, the actual force seen by the frangible bolt may depend on the sum of the (variable) fluid force and the (constant) pre-load force, and the result would be undesirable variation of the actuation temperature.
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FIG. 4A shows a perspective view of the temperature-sensitive actuator and linkage similar to that shown inFIGS. 3A and 3B . In this example, the shape-memory element 421 is a cylinder that is compressed by thefrangible bolt 409 between twobrackets members brackets 415 has a pointed (or male) end 416 that mates with concave (or female) end 417 on theother bracket 415′. The opposite ends of the brackets forming thelinkage frame 331. In this example, these ends are pointed, but they may be rounded, blunt, or any other appropriate shape. The two brackets may be identical, each having one convex end and one concave end. -
FIG. 4B shows the frangible pin fromFIG. 4A removed from the temperature-sensitive actuator, andFIG. 4C shows the shape-memory element and linkage with the frangible pin removed.FIGS. 5A-5C also show greater detail of a frangible bolt. - Any appropriate frangible bolt may be used. In general, a frangible bolt is an elongate member. The frangible bolt may be a cylindrical bolt (as shown in
FIGS. 4B-5B ) including a threadedportion 422. The threads may mate with a nut. The entire bolt may be threaded or just one or more regions may be threaded. In some variations, the thread mates with the linkage. Other bolt shapes (including unthreaded bolts) may also be used. Thebolt 409 may include ahead region 413 that has a flanged portion extending outward from the elongate length of the bolt. Thehead region 413 in this example is slotted, but it may be otherwise configured for securing or gripping. - A frangible bolt may also be notched. In
FIGS. 4B-5C thenotch 411 is shown as an annular cut-out region.FIG. 5C illustrates this region in greater detail. The notch may be formed by any appropriate manner, including removing material from the bolt after it has been formed, or it may be cast as an initial part of the bolt. In some variations the notch does not extend annularly, but may be present on only one side or region of the bolt. Such asymmetric notching may help direct the fracturing of the frangible bolt. The depth of the notch may help set the ultimate tensile strength of the frangible bolt (the stress at which the bolt will fracture), and may therefore help match the bolt to the shape-memory element, as described below. The notch may be located at any position along the length of the bolt, and the location of the notch along the bolt may also help determine the ultimate tensile strength. In some variations the bolt may include only one notch or multiple notches. - The bolt may be made of any appropriate material, particularly metals including alloys. For example, the bolt may be a titanium bolt, such as a Ti6Al4V bolt, a steel (e.g., stainless steel) bolt, or the like.
-
FIGS. 6A-6C show one variation of a shape-memory element that may be used as part of a temperature-sensitive actuator, which is configured as a cylinder.FIG. 6A shows a perspective view of this cylindrical shape-memory element, which has a circular cross-sectional profile (shown inFIG. 6C ). The shape-memory element has a length that is slightly less than length of the bolt. The cylindrical shape-memory element in this example is hollow, so that it can surround the frangible bolt. - Different configurations of shape-memory elements may be used. For example, a cylindrical shape-memory element may have a non-circular cross-section (e.g., an elliptical, cross-section, a square cross-section, etc.). The shape-memory element may be configured as a strut that is not hollow and which fastens to the bolt in two or more places. The shape-memory element may be a partial tube (e.g. a c-shaped tube).
- The shape-memory element may be made of a single-crystal shape memory alloy, such as a single-crystal CuAlNi alloy or a single-crystal CuAlMn alloy. In particular, the shape-memory element may be made of a shape-memory material capable of elongating up to 7%, 8% or 9% of their length, referred to as “hyperelastic” shape memory alloys. The exact composition (percent composition) of the shape-memory alloy may be modified or pre-determined to help match the stress plateau characteristics of the shape-memory element with the stress profile (e.g., ultimate tensile strength) of the frangible bolt.
- By matching the peak strength of the frangible bolt to the stress plateau of the shape-memory element, assured separation of the bolt is achieved in a narrow temperature range as the shape-memory element elongates much more than necessary to cause the frangible bolt to fracture.
- Thus, the temperature-sensitive actuator may include a frangible bolt whose peak strength is matched to the stress plateau of the shape-memory element. For example, the temperature sensitive actuator may be made by first selecting a desired actuation temperature At. For example, the actuation temperature, At, may be selected from within the range of about −200 to +200° C. An optimum stress plateau level (Sp) may then be chosen. For example, Sp may be between 50 and 600 Mpa. The relationship between the stress plateau level and the activation temperature may be described by the formula:
S p=2.3(A t −A f) - Where Af is the austenite finish temperature of the shape-memory element, as described above. By choosing a cross-sectional area Xc of the shape-memory element that applies force to the frangible bolt, the force exerted by the shape-memory element Fa can then be determined from the relationship:
F a =S p *X c - The ultimate strength of the frangible bolt (e.g., a notched frangible bolt) may then be matched to equal this force (Fa) and the elongation to failure=Ef, using a suitable margin of safety to determine the length of the shape-memory element La such that, at the appropriate percent elongation (e.g., 5%, 6%, 7%, 8%, 9% elongation), the actuator will break the bolt while maintaining the margin of safety. These calculations should also take into account the compliance of other elements in the joint.
- Based on this determination, the ingot composition that will produce single crystal material with Af can be chosen in order to make the shape-memory actuator. For example, if the shape-memory actuator is a cylinder, then a cylinder with a cross-section Xc, length La, and an opening large enough to accommodate the bolt may be fabricated.
- The shape-memory element can then be compressed. For example, a press can be used to compress the actuator to its 9 percent limit, and to maintain this shortened length by keeping the actuator well below Af.
- To complete assembly of the temperature-sensitive actuator, the bolt, shape-memory element, and any other elements in the joint, such as a nut, can then be assembled. The nut can be tightened so that there is no slack in the joint. Finally, the remainder of the sprinkler valve body can be installed, including the linkage.
- Any appropriate linkage may be used to connect the actuator to the sprinkler. In particular, it may be preferable to use a linkage that opposes the force of fluid (e.g., water pressure) when the device is connected to a source of fluid pressure and the valve is closed. In particular, it may be preferable to use linkages that do not transfer a substantial portion (if any) of the fluid pressure to the shape-memory element when the actuator is installed with the other components of the sprinkler.
- A linkage may connect or couple with the valve that opposes the fluid pressure from a source of pressurized fluid that is connected to the fluid passageway of the device. For example, the linkage may abut or contact a portion of a valve (e.g., a valve plug), to prevent the fluid pressure from opening the valve. The linkage may also be connected or coupled to the body of the fluid passageway (or another portion of the sprinkler body that is connected to the body of the fluid passageway). In the example shown in
FIG. 3A , the linkage is coupled to theframe 331. In some variations, the linkage may be configured to readily un-couple from the valve (and/or frame or sprinkler body) when the actuator triggers upon braking of the frangible bolt. In some variations, the frangible bolt may act as the linkage. For example, one end of the frangible bolt may be coupled to the valve, and the other end may be functionally coupled to a frame connected to the sprinkler body. - A two-piece linkage, such as that shown in
FIGS. 3A-3B , 4A and 4C may be particularly useful. In this example, the linkage includes an upper (or first) linkage bracket and a lower (or second) linkage bracket.FIGS. 7A-7D illustrate one variation of an upper linkage.FIG. 7A shows a perspective view of anupper linkage bracket 701 having a generally “T” shape. The bracket may be formed from a single (flat) piece of metal that is cut and bent to form the shape illustrated. The region of the bracket configured to hold theactuator 703 is formed by the base of the “T” shape, and may include a hole orpassage 705 through which the actuator (e.g., the frangible bolt portion of the actuator) may pass. The top of the “T’ shape in this linkage forms three prongs. One of theprongs 709 is configured to communicate with the valve, and the other twoprongs 711 are configured to communicate with (e.g., mate with) prongs extending from the lower linkage. Although in this example three prongs are shown, two prongs may be used. Also, the orientation of the prongs may be different; for example, the twoprongs 711 may be configured to couple with the valve and the single prong may be configured to couple with the other linkage.FIG. 7B shows a top view, andFIGS. 7C and 7D show sides view of theupper bracket 701. -
FIGS. 8A-8D show an example of a lower bracket linkage that may be used with the upper bracket linkage ofFIGS. 7A-7D to couple with an actuator and the valve of a fluid passageway. The lower bracket is very similar to the upper bracket, except that the two prongs that mate with the upper bracket prongs 811, 811′ are shaped to receive the upper bracket prongs. - The linkage may be configured so that the activation of the temperature-sensitive actuator causes a predictable release. For example,
FIG. 9 illustrates the cross-section of another variation of an upper bracket that is configured so that activation of the actuator, and breaking of the frangible bolt, causes a predictable release. AlthoughFIG. 9 shows only an upper bracket, a second, nearly identical lower bracket may have a similar design. - The upper bracket linkage shown in
FIG. 9 is similar in orientation to the upper bracket linkage shown inFIG. 7C , only rotated 90 degrees counterclockwise. In this orientation, thefirst prong 909 of the bracket is configured to communication with the valve and oppose the force of the fluid pressure (indicated by Fwater). Theopposite prong 911 or prongs are configured to mate with a lower bracket linkage which in turn mates with the frame (also referred to as a “yoke”) connected to the body of the fluid passageway. Thus, these prong(s) 911 receive the counter force, Fyoke, to help balance the Fwater and thereby keep the valve closed while the linkage is intact. In addition to the forces balance the fluid pressure, the bolt of the temperature-sensitive actuator also acts on the brackets by providing a force Fbolt that is also opposed and balanced by the counterforce from the frame, Fyolk. At equilibrium, the force of the fluid pressure Fwater times the length of the lever arm Lwater (the length seen by the Fwater in relation to the opposing force Fyolk) is balanced by the force of the bolt, Fbolt, times the lever arm Lbolt, preventing the bracket from rotating and coming uncoupled. In the example ofFIG. 9 , the ratio between the lengths of the lever arms and the forces applied by the bolt and the fluid (water) on the bracket are generally balanced as a 1:8 ratio, but any appropriate ration may be used. During activation, the force applied to the bracket will unbalance as the bolt breaks, resulting in the rotation and uncoupling of the bracket, removing the linkage and releasing the valve. - A thermally-activated sprinkler valve assembly as illustrated may be made by any appropriate method, as mentioned above. In general, this method of making a thermally-activated sprinkler valve may include first tuning a shape-memory element to exert a pre-determined force at a pre-determined temperature. In some variations, tuning involves selecting the activation temperature (At), and setting the austenite finish temperature (Af) based on that temperature. This may be accomplished in part by tempering. For example, a shape-memory element comprising single-crystal shape memory alloy can be tempered by heat treating and controlling the partial precipitation of Al from the single-crystal material. Tweaking the concentration of Al will adjust the Af.
- Tuning may include matching the plateau stress of the shape-memory element to the ultimate tensile stress (the breaking point) of the frangible bolt. Stress profile may be examined periodically to determine the plateau stress (as shown in
FIGS. 1A and 1B ), or it may be calculated. The shape-memory material may also be tuned by otherwise manipulating the composition of the shape-memory material (e.g., doping, etc.). The ultimate tensile strength of the bolt may also (or alternatively) be set based on the shape-memory element (e.g., the plateau stress). For example, the bolt shape and size may be selected to set the ultimate tensile strength. Thus, the bolt may be notched or otherwise treated to set the approximate ultimate tensile strength of the bolt. - The temperature-sensitive actuator may then be formed by coupling the frangible bolt to the shape-memory element so that the shape-memory element is compressed by the frangible bolt. Finally, the actuator may be attached to the rest of the thermally-activated sprinkler by coupling the actuator to a linkage, wherein the linkage is configured to couple with the valve of a fluid passageway having a valved outlet to oppose fluid pressure and maintain the valve closed.
- The assembled sprinkler may then be attached to a fluid source.
- Temperature-sensitive actuators were made by cutting shape-memory elements with an abrasive wheel from Cu-14.0Al-4.5Ni tubing (OD=0.235″, ID=0.115″). No subsequent machining was performed. The shape-memory elements were approximately 0.451″ to 0.478″ long. The shape-memory elements were compressed and constrained with the brass 4-40 button headed notched screws and brass nuts. Notch size was 0.070″+/−0.001″. Assemblies were individually tested by immersion in hot water, the temperature of which was monitored with alkaline thermometer. The average actuation temperature was 49.375° C. (standard deviation of 1.96).
- In another example, cylinders of shape-memory material were machined from 0.25″ diameter Cu-14.0Al-4.5Ni (OD=0.23″; ID=0.11″; L=0.483″). Machined cylinders were compressed to L=0.450″ and constrained with brass 4-40 button headed notched screws and brass nuts. Notch size is 0.070″+/−0.001″. On average, the devices actuated between 45-46° C. Afterwards, the cylinders were quenched from 950 C into salt water, compressed and constrained again, and actuated at an average temperature of 46.2° C. (standard deviation of 2.20). These shape-memory cylinders were compressed using frangible bolts made of 4-40 SS, having a notch of 0.070″. These actuated at approximately 62° C. (screw strength −2550N).
- In yet another example, shape-memory elements were machined from 0.25″ diameter Cu-13.9Al-4.5Ni rod (OD=0.23″; ID=0.11″; L=0.49″). These cylinders were quenched from 950° C. into salt water, compressed and constrained. In this example, lowering the Al content by 0.1% resulted in increase of actuation temperature by ˜15 C.
- Although the devices described herein are configured as sprinkler valves, other configurations may also be used with the temperature-sensitive actuators described. For example, a temperature-sensitive actuator may be used as part of a release valve for pressurized fluids including gasses. While the methods and devices have been described in some detail here by way of illustration and example, such illustration and example is for purposes of clarity of understanding only. It will be readily apparent to those of ordinary skill in the art in light of the teachings herein that certain changes and modifications may be made thereto without departing from the spirit and scope of the invention.
Claims (31)
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US12/019,553 US8684101B2 (en) | 2007-01-25 | 2008-01-24 | Frangible shape memory alloy fire sprinkler valve actuator |
US12/503,614 US8584767B2 (en) | 2007-01-25 | 2009-07-15 | Sprinkler valve with active actuation |
US14/230,881 US20150266141A1 (en) | 2007-01-25 | 2014-03-31 | Frangible shape memory alloy fire sprinkler valve actuator |
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US89770807P | 2007-01-25 | 2007-01-25 | |
US12/019,553 US8684101B2 (en) | 2007-01-25 | 2008-01-24 | Frangible shape memory alloy fire sprinkler valve actuator |
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US12/503,614 Continuation-In-Part US8584767B2 (en) | 2007-01-25 | 2009-07-15 | Sprinkler valve with active actuation |
US14/230,881 Division US20150266141A1 (en) | 2007-01-25 | 2014-03-31 | Frangible shape memory alloy fire sprinkler valve actuator |
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US20100025050A2 true US20100025050A2 (en) | 2010-02-04 |
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US14/230,881 Abandoned US20150266141A1 (en) | 2007-01-25 | 2014-03-31 | Frangible shape memory alloy fire sprinkler valve actuator |
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US14/230,881 Abandoned US20150266141A1 (en) | 2007-01-25 | 2014-03-31 | Frangible shape memory alloy fire sprinkler valve actuator |
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Citations (99)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US538593A (en) * | 1895-04-30 | Automatic fire-extinguisher | ||
US1136687A (en) * | 1914-03-02 | 1915-04-20 | Jay Litt | Muffler attachment for telephones. |
US1904828A (en) * | 1930-01-28 | 1933-04-18 | Pawtucket Screw Company | Thermoelectric sprinkler head |
US1913035A (en) * | 1929-03-01 | 1933-06-06 | Gen Fire Extinguisher Co | Sprinkler |
US2371614A (en) * | 1942-12-31 | 1945-03-20 | Packard Motor Car Co | Engine connecting rod and method of securing parts together |
US2586556A (en) * | 1946-11-23 | 1952-02-19 | Mullikin Alfred | Flexible binder post |
US2793036A (en) * | 1955-02-18 | 1957-05-21 | George B Hansburg | Pogo stick |
US3229956A (en) * | 1962-03-02 | 1966-01-18 | Stevens Mfg Co Inc | Diaphragm fluid valve |
US3435823A (en) * | 1966-04-11 | 1969-04-01 | Miles Lowell Edwards | Anastomotic coupling with anti-pulse ring means |
US3445086A (en) * | 1966-11-25 | 1969-05-20 | Zyrotron Ind Inc | Snap acting valve and control mechanism therefor |
US3559641A (en) * | 1968-09-30 | 1971-02-02 | Inutcodes Inc | Intrauterine device |
US3561537A (en) * | 1968-06-20 | 1971-02-09 | Fire Protection Co | Automatic sprinkler head |
US3659625A (en) * | 1970-02-16 | 1972-05-02 | Westinghouse Air Brake Co | Drain valve device |
US3668131A (en) * | 1968-08-09 | 1972-06-06 | Allied Chem | Dissolution of metal with acidified hydrogen peroxide solutions |
US3725835A (en) * | 1970-07-20 | 1973-04-03 | J Hopkins | Memory material actuator devices |
US3789838A (en) * | 1971-02-19 | 1974-02-05 | E Fournier | Force transmitting intrauterine device |
US3888975A (en) * | 1972-12-27 | 1975-06-10 | Alza Corp | Erodible intrauterine device |
US4072159A (en) * | 1975-02-22 | 1978-02-07 | Toyoki Kurosawa | Emergency valve incorporating thermal foamable plastic material |
US4096993A (en) * | 1977-01-21 | 1978-06-27 | Emerson Electric Co. | Compensated control valve |
US4145764A (en) * | 1975-07-23 | 1979-03-27 | Sumitomo Chemical Co., Ltd. | Endosseous implants |
US4151064A (en) * | 1977-12-27 | 1979-04-24 | Coulter Stork U.S.A., Inc. | Apparatus for sputtering cylinders |
US4243963A (en) * | 1979-04-02 | 1981-01-06 | Gte Automatic Electric Laboratories Incorporated | Construction of a printed wiring card mountable reed relay |
US4265684A (en) * | 1978-07-26 | 1981-05-05 | Vacuumschmelze Gmbh | Magnetic core comprised of low-retentivity amorphous alloy |
US4434855A (en) * | 1982-03-30 | 1984-03-06 | The United States Of America As Represented By The Secretary Of The Navy | Sprinkler valve |
US4501058A (en) * | 1979-08-27 | 1985-02-26 | Pda Engineering | Method of pre-stressing a structural member |
US4524343A (en) * | 1984-01-13 | 1985-06-18 | Raychem Corporation | Self-regulated actuator |
US4567549A (en) * | 1985-02-21 | 1986-01-28 | Blazer International Corp. | Automatic takeup and overload protection device for shape memory metal actuator |
US4585209A (en) * | 1983-10-27 | 1986-04-29 | Harry E. Aine | Miniature valve and method of making same |
US4589179A (en) * | 1984-09-10 | 1986-05-20 | Caterpillar Tractor Co. | Flexible positioner |
US4596483A (en) * | 1983-07-11 | 1986-06-24 | Leuven Research And Development | Temperature responsive linkage element |
US4654191A (en) * | 1984-06-09 | 1987-03-31 | Kernforschungszentrum Karlsruhe Gmbh | Pressure release arrangement for the safety containment of a pressurized water nuclear reactor |
US4753465A (en) * | 1986-04-11 | 1988-06-28 | James F. Dalby | Remotely operable locking mechanism |
US4821997A (en) * | 1986-09-24 | 1989-04-18 | The Board Of Trustees Of The Leland Stanford Junior University | Integrated, microminiature electric-to-fluidic valve and pressure/flow regulator |
US4824073A (en) * | 1986-09-24 | 1989-04-25 | Stanford University | Integrated, microminiature electric to fluidic valve |
US4823607A (en) * | 1987-05-18 | 1989-04-25 | Massachusetts Institute Of Technology | Released film structures and method of measuring film properties |
US4893655A (en) * | 1989-08-23 | 1990-01-16 | The United States Of America As Represented By The Secretary Of The Navy | Double valve mechanism for an acoustic modulator |
US4896728A (en) * | 1987-10-02 | 1990-01-30 | Thomas Bolton & Johnson Limited | Fire sprinklers with frangible body closing a flow passage and separate means for shattering same |
US4915773A (en) * | 1986-11-26 | 1990-04-10 | Kravetsky Dmitry Y | Process for growing shaped single crystals |
US5096419A (en) * | 1991-08-14 | 1992-03-17 | Kabushiki Kaisha Morita Seisakusho | Apparatus and method for detecting an apical position |
US5102276A (en) * | 1990-07-12 | 1992-04-07 | Ford Motor Company | Removable fastener with elastic linking means |
US5114504A (en) * | 1990-11-05 | 1992-05-19 | Johnson Service Company | High transformation temperature shape memory alloy |
US5116252A (en) * | 1991-08-02 | 1992-05-26 | Hartman Thomas A | In-line sleeve valve having velocity guide pressure equalization and drive assembly with improved drive pin mountings |
US5117916A (en) * | 1990-04-11 | 1992-06-02 | Hochiki Kabushiki Kaisha | Sprinkler head and operation monitor therefor |
US5119555A (en) * | 1988-09-19 | 1992-06-09 | Tini Alloy Company | Non-explosive separation device |
US5190546A (en) * | 1983-10-14 | 1993-03-02 | Raychem Corporation | Medical devices incorporating SIM alloy elements |
US5192147A (en) * | 1991-09-03 | 1993-03-09 | Lockheed Missiles & Space Company, Inc. | Non-pyrotechnic release system |
US5211371A (en) * | 1991-07-22 | 1993-05-18 | Advanced Control Technologies, Inc. | Linearly actuated valve |
US5218998A (en) * | 1992-04-01 | 1993-06-15 | Bakken Gary M | Linearly adjustable |
US5309717A (en) * | 1993-03-22 | 1994-05-10 | Minch Richard B | Rapid shape memory effect micro-actuators |
US5312152A (en) * | 1991-10-23 | 1994-05-17 | Martin Marietta Corporation | Shape memory metal actuated separation device |
US5312247A (en) * | 1992-05-21 | 1994-05-17 | Ormco Corporation | Transpalatal orthodontic appliance of superelastic or shape-memory alloy |
US5395238A (en) * | 1990-01-19 | 1995-03-07 | Ormco Corporation | Method of forming orthodontic brace |
US5494113A (en) * | 1994-02-01 | 1996-02-27 | Central Sprinkler Corporation | Sprinklers with shape-memory alloy actuators |
US5502982A (en) * | 1994-04-28 | 1996-04-02 | Liquid Carbonic Industries Corporation | Cryogenic tie pin |
US5605543A (en) * | 1994-03-10 | 1997-02-25 | Schneider (Usa) Inc. | Catheter having shaft of varying stiffness |
US5619177A (en) * | 1995-01-27 | 1997-04-08 | Mjb Company | Shape memory alloy microactuator having an electrostatic force and heating means |
US5622225A (en) * | 1992-04-23 | 1997-04-22 | Sundholm; Goeran | Quick response sprinkler head |
US5640217A (en) * | 1995-02-02 | 1997-06-17 | Fergaflex, Inc. | Eyeglass frame with very high recoverable deformability |
US5641364A (en) * | 1994-10-28 | 1997-06-24 | The Furukawa Electric Co., Ltd. | Method of manufacturing high-temperature shape memory alloys |
US5714690A (en) * | 1991-12-13 | 1998-02-03 | Honeywell Inc. | Piezoresistive silicon pressure sensor manufacture implementing long diaphragms with large aspect ratios |
US5722989A (en) * | 1995-05-22 | 1998-03-03 | The Regents Of The University Of California | Microminiaturized minimally invasive intravascular micro-mechanical systems powered and controlled via fiber-optic cable |
US5867302A (en) * | 1997-08-07 | 1999-02-02 | Sandia Corporation | Bistable microelectromechanical actuator |
US5903099A (en) * | 1997-05-23 | 1999-05-11 | Tini Alloy Company | Fabrication system, method and apparatus for microelectromechanical devices |
US6013854A (en) * | 1994-06-17 | 2000-01-11 | Terumo Kabushiki Kaisha | Indwelling stent and the method for manufacturing the same |
US6042374A (en) * | 1998-01-14 | 2000-03-28 | Ormco Corporation | Self ligating orthodontic bracket |
US6042553A (en) * | 1997-04-15 | 2000-03-28 | Symbiosis Corporation | Linear elastic member |
US6169269B1 (en) * | 1996-09-05 | 2001-01-02 | Medtronic Inc. | Selectively activated shape memory device |
US6195478B1 (en) * | 1998-02-04 | 2001-02-27 | Agilent Technologies, Inc. | Planar lightwave circuit-based optical switches using micromirrors in trenches |
US6203715B1 (en) * | 1999-01-19 | 2001-03-20 | Daewoo Electronics Co., Ltd. | Method for the manufacture of a thin film actuated mirror array |
US6224626B1 (en) * | 1998-02-17 | 2001-05-01 | Md3, Inc. | Ultra-thin expandable stent |
US6229640B1 (en) * | 1999-08-11 | 2001-05-08 | Adc Telecommunications, Inc. | Microelectromechanical optical switch and method of manufacture thereof |
US20020018325A1 (en) * | 1990-06-08 | 2002-02-14 | Hitachi, Ltd. | Magnetoresistance effect elements, magnetic heads and magnetic storage apparatus |
US6352494B2 (en) * | 2000-01-12 | 2002-03-05 | Mcalonan Mark | Bungee pole |
US6358380B1 (en) * | 1999-09-22 | 2002-03-19 | Delphi Technologies, Inc. | Production of binary shape-memory alloy films by sputtering using a hot pressed target |
US6379383B1 (en) * | 1999-11-19 | 2002-04-30 | Advanced Bio Prosthetic Surfaces, Ltd. | Endoluminal device exhibiting improved endothelialization and method of manufacture thereof |
US6386507B2 (en) * | 1999-09-01 | 2002-05-14 | Jds Uniphase Corporation | Microelectromechanical valves including single crystalline material components |
US20020062154A1 (en) * | 2000-09-22 | 2002-05-23 | Ayers Reed A. | Non-uniform porosity tissue implant |
US20030002994A1 (en) * | 2001-03-07 | 2003-01-02 | Johnson A. David | Thin film shape memory alloy actuated flow controller |
US6524322B1 (en) * | 1998-10-23 | 2003-02-25 | Eric Berreklouw | Anastomosis device |
US6533905B2 (en) * | 2000-01-24 | 2003-03-18 | Tini Alloy Company | Method for sputtering tini shape-memory alloys |
US6537310B1 (en) * | 1999-11-19 | 2003-03-25 | Advanced Bio Prosthetic Surfaces, Ltd. | Endoluminal implantable devices and method of making same |
US20030078465A1 (en) * | 2001-10-16 | 2003-04-24 | Suresh Pai | Systems for heart treatment |
US6672502B1 (en) * | 2000-11-28 | 2004-01-06 | The State Of Oregon Acting By And Through The State Board Of Higher Education On Behalf Of Oregon State University | Method for making devices having intermetallic structures and intermetallic devices made thereby |
US6688828B1 (en) * | 2000-12-01 | 2004-02-10 | Arizona Board Of Regents | Self-torquing fasteners |
US20040083006A1 (en) * | 2002-04-09 | 2004-04-29 | Astra Tech Ab | Medical prosthetic devices having improved biocompatibility |
US6729599B2 (en) * | 2001-06-26 | 2004-05-04 | Tini Alloy Company | Liquid microvalve |
US6840329B2 (en) * | 2002-03-06 | 2005-01-11 | Senju Sprinkler Company Limited | Cover assembly for a concealed sprinkler head |
US6843465B1 (en) * | 2003-08-14 | 2005-01-18 | Loren W. Scott | Memory wire actuated control valve |
US6849085B2 (en) * | 1999-11-19 | 2005-02-01 | Advanced Bio Prosthetic Surfaces, Ltd. | Self-supporting laminated films, structural materials and medical devices manufactured therefrom and method of making same |
US6852132B1 (en) * | 2000-07-05 | 2005-02-08 | Russell A Houser | Artificial limbs incorporating superelastic supports |
US20050113933A1 (en) * | 2003-11-24 | 2005-05-26 | Checkmed Systems, Inc. | Stent |
US7022173B2 (en) * | 2003-02-05 | 2006-04-04 | 3M Innovative Properties Company | Use of ceramics in dental and orthodontic applications |
US7040323B1 (en) * | 2002-08-08 | 2006-05-09 | Tini Alloy Company | Thin film intrauterine device |
US7044596B2 (en) * | 2004-02-02 | 2006-05-16 | Park Andrew Q | Hingeless eyeglasses frame |
US7201367B2 (en) * | 2002-12-12 | 2007-04-10 | Caterpillar Inc | Load-bearing resilient mount |
US20090035859A1 (en) * | 2007-07-30 | 2009-02-05 | Alfred David Johnson | Method and devices for preventing restenosis in cardiovascular stents |
US7524914B2 (en) * | 2002-10-11 | 2009-04-28 | The University Of Connecticut | Shape memory polymers based on semicrystalline thermoplastic polyurethanes bearing nanostructured hard segments |
US20100129766A1 (en) * | 2006-10-10 | 2010-05-27 | Ormco Corporation | Orthodontic retraction arch and spring |
US20120048432A1 (en) * | 2010-08-24 | 2012-03-01 | Alfred David Johnson | Shape setting a shape memory alloy dental arch |
Family Cites Families (150)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US368425A (en) * | 1887-08-16 | Alexander ross and cyrus abrom mcallister | ||
US1560335A (en) | 1924-03-27 | 1925-11-03 | American Lurgi Corp | Process of improving alloys and metals |
US1926925A (en) | 1931-04-07 | 1933-09-12 | Gulf Res & Dev Corp | Pin, bolt, and other connecting device |
GB425439A (en) | 1934-04-25 | 1935-03-14 | Erwin Glatte | Improvements in or relating to screw-threaded metal parts |
US2647017A (en) | 1951-04-19 | 1953-07-28 | Ind Res Inst | Nozzle |
US2610300A (en) | 1951-08-07 | 1952-09-09 | Wilson W Walton | Flow control |
US2608996A (en) | 1951-08-30 | 1952-09-02 | Forman Ralph | Glass valve |
US2911504A (en) | 1958-05-15 | 1959-11-03 | Sigmund Cohn Corp | Fuse member and method of making the same |
CH418759A (en) | 1964-12-23 | 1966-08-15 | Taco Heizungen Ag | Remote controlled valve for heating systems |
US3357432A (en) | 1965-02-09 | 1967-12-12 | Edwards Lab Inc | Anastomotic coupling |
US3351463A (en) | 1965-08-20 | 1967-11-07 | Alexander G Rozner | High strength nickel-base alloys |
US3408890A (en) | 1967-01-27 | 1968-11-05 | Hi Shear Corp | Separable fastener assembly |
US3454286A (en) | 1967-03-01 | 1969-07-08 | Us Navy | Thermally operated release mechanism |
US3546996A (en) | 1969-04-10 | 1970-12-15 | Atomic Energy Commission | Release latch actuated by temperature excursion |
US3613732A (en) | 1969-07-17 | 1971-10-19 | Robertshaw Controls Co | Temperature-responsive valve operators |
US3620212A (en) | 1970-06-15 | 1971-11-16 | Robert D Fannon Jr | Intrauterine contraceptive device |
US3918443A (en) | 1971-10-20 | 1975-11-11 | Ethyl Corp | Method for birth control |
US3974844A (en) | 1973-06-11 | 1976-08-17 | Texas Instruments Incorporated | Valve |
US3849756A (en) | 1973-06-14 | 1974-11-19 | American Thermostat Corp | Nitinol activated switch usable as a slow acting relay |
FR2279001A1 (en) | 1974-05-28 | 1976-02-13 | Mediterranee Const Navales Ind | DEVICE FOR QUICK DISASSEMBLY AND REASSEMBLY OF COVERS OF PRESSURE TANKS, ESPECIALLY OF NUCLEAR REACTOR TANKS |
US3913572A (en) | 1974-06-14 | 1975-10-21 | Us Government | Pleated membrane intrauterine contraceptive device |
US3991898A (en) | 1975-09-16 | 1976-11-16 | The United States Of America As Represented By The United States Energy Research And Development Administration | Vacuum foil insulation system |
US4176719A (en) * | 1976-03-12 | 1979-12-04 | Mather & Platt Limited | Heat sensitive release devices |
US4055955A (en) | 1976-08-16 | 1977-11-01 | Alfred Davis Johnson | Memory alloy heat engine and method of operation |
US4195773A (en) | 1977-03-21 | 1980-04-01 | Ralph Ogden | Programmable controller system for industrial process apparatus |
US4177327A (en) | 1978-11-20 | 1979-12-04 | P. R. Mallory & Co. Inc. | Metal-air battery having electrically operated air access vent cover |
US4279790A (en) | 1979-07-05 | 1981-07-21 | Kabushiki Kaisha Mikuni Seisakusho | Composite material compositions using wasterpaper and method of producing same |
US4279190A (en) | 1979-07-05 | 1981-07-21 | Hummel Philip H | Break away nail |
US4340049A (en) | 1979-10-18 | 1982-07-20 | Baxter Travenol Laboratories, Inc. | Breakaway valve |
SE444841B (en) | 1980-11-28 | 1986-05-12 | Gunnar Liljedahl | EXPANSION PIECE CONSISTS OF AN ELASTIC SHOULDER FOR INSTALLATION IN CYLINDRIC TILE, AND USE THEREOF |
US4553602A (en) | 1981-08-03 | 1985-11-19 | Pieczykolan George S | Automatic on-off sprinkler head |
LU84677A1 (en) | 1983-03-07 | 1984-11-14 | Leuven Res & Dev Vzw | THERMOSENSITIVE VALVE |
US4485545A (en) | 1983-07-07 | 1984-12-04 | Ford Motor Company | Method of attaching a metal shaft to a ceramic shaft and product thereby |
US4553393A (en) | 1983-08-26 | 1985-11-19 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Memory metal actuator |
FR2561743B1 (en) | 1984-03-21 | 1986-09-05 | Aerospatiale | PYROTECHNIC VALVE |
US4551974A (en) | 1984-04-27 | 1985-11-12 | Raychem Corporation | Shape memory effect actuator and methods of assembling and operating therefor |
US4706758A (en) | 1984-04-30 | 1987-11-17 | U.S. Fire Control Corporation | Automatic on-off sprinkler head |
US4558715A (en) | 1984-05-16 | 1985-12-17 | Kowatachi International, Ltd. | Apparatus for injecting measured quantities of liquid into a fluid stream |
AU6390586A (en) * | 1986-03-04 | 1987-09-10 | Total Walther Feuerschutz Gmbh | Sprinkler for automatic fire extinguishing |
US4684913A (en) | 1986-09-05 | 1987-08-04 | Raychem Corporation | Slider lifter |
US4943032A (en) | 1986-09-24 | 1990-07-24 | Stanford University | Integrated, microminiature electric to fluidic valve and pressure/flow regulator |
SU1434314A1 (en) | 1987-04-02 | 1988-10-30 | Институт Металлургии Им.А.А.Байкова | Joining device |
US4848388A (en) | 1987-10-19 | 1989-07-18 | Memory Metals, Inc. | Emergency valve with test capability |
US5245738A (en) | 1988-09-19 | 1993-09-21 | Tini Alloy Company | Method for securing together and non-explosively separating multiple components |
US4854797A (en) | 1988-10-05 | 1989-08-08 | Ford Motor Company | Threaded fastener with resilient linking means |
US4864824A (en) | 1988-10-31 | 1989-09-12 | American Telephone And Telegraph Company, At&T Bell Laboratories | Thin film shape memory alloy and method for producing |
US5072288A (en) | 1989-02-21 | 1991-12-10 | Cornell Research Foundation, Inc. | Microdynamic release structure |
FR2648199B1 (en) | 1989-06-09 | 1991-09-27 | Aerospatiale | TEMPORARY LINK DEVICE, PARTICULARLY FOR ARTIFICIAL SATELLITE APPENDIX, AND METHOD FOR RELEASING SUCH A LINK |
US5069419A (en) | 1989-06-23 | 1991-12-03 | Ic Sensors Inc. | Semiconductor microactuator |
US5061914A (en) | 1989-06-27 | 1991-10-29 | Tini Alloy Company | Shape-memory alloy micro-actuator |
US5447432A (en) | 1990-01-19 | 1995-09-05 | Ormco Corporation | Custom orthodontic archwire forming method and apparatus |
US5474448A (en) | 1990-01-19 | 1995-12-12 | Ormco Corporation | Low profile orthodontic appliance |
US5044947A (en) | 1990-06-29 | 1991-09-03 | Ormco Corporation | Orthodontic archwire and method of moving teeth |
US5129753A (en) | 1990-11-13 | 1992-07-14 | Trw Inc. | Shape memory wire latch mechanism |
US5061137A (en) | 1991-04-29 | 1991-10-29 | Ford Motor Company | Fastener with resilient linking means |
US5131843A (en) | 1991-05-06 | 1992-07-21 | Ormco Corporation | Orthodontic archwire |
US6107004A (en) | 1991-09-05 | 2000-08-22 | Intra Therapeutics, Inc. | Method for making a tubular stent for use in medical applications |
US5364046A (en) | 1992-02-24 | 1994-11-15 | Environmental Research Institute Of Michigan | Automatic compliant capture and docking mechanism for spacecraft |
US5160233A (en) | 1992-05-13 | 1992-11-03 | The United State Of America As Representd By The Administrator Of The National Aeronautics And Space Administration | Fastening apparatus having shape memory alloy actuator |
US5837394A (en) | 1992-05-20 | 1998-11-17 | Brooke Schumm, Jr. | Electric appliance and fluid depolarized cell with low parasitic usage microactuated valve |
DE4234237C2 (en) | 1992-10-10 | 2000-11-30 | Bosch Gmbh Robert | Temperature compensated micro actuator |
US5456600A (en) | 1992-11-09 | 1995-10-10 | Ormco Corporation | Coordinated orthodontic archwires and method of making same |
US5474563A (en) | 1993-03-25 | 1995-12-12 | Myler; Richard | Cardiovascular stent and retrieval apparatus |
US5325880A (en) | 1993-04-19 | 1994-07-05 | Tini Alloy Company | Shape memory alloy film actuated microvalve |
DE69420057T2 (en) | 1993-11-30 | 2000-02-03 | Kvaerner Tamturbine Oy, Tampere | FASTENING DEVICE FOR FASTENING ELEMENTS AND METHOD FOR TENSIONING A FASTENING ELEMENT |
KR950024146A (en) | 1994-01-31 | 1995-08-21 | 모리시타 요이찌 | Information recording and reproducing apparatus and information recording and reproducing method |
US5648665A (en) | 1994-04-28 | 1997-07-15 | Ngk Insulators, Ltd. | Semiconductor device having a plurality of cavity defined gating regions and a fabrication method therefor |
US5840199A (en) | 1994-06-01 | 1998-11-24 | Litton Systems, Inc. | Method for purging a multi-layer sacrificial etched silicon substrate |
US5645423A (en) | 1994-06-10 | 1997-07-08 | Collins, Jr.; John A. | Mandibular advancement appliance |
US5473944A (en) | 1994-08-18 | 1995-12-12 | Kulite Semi Conductor Products, Inc. | Seam pressure sensor employing dielectically isolated resonant beams and related method of manufacture |
DE19506188C2 (en) | 1995-02-22 | 2003-03-06 | Miladin Lazarov | Implant and its use |
US5695504A (en) | 1995-02-24 | 1997-12-09 | Heartport, Inc. | Devices and methods for performing a vascular anastomosis |
US6124523A (en) | 1995-03-10 | 2000-09-26 | Impra, Inc. | Encapsulated stent |
US5916178A (en) | 1995-03-30 | 1999-06-29 | Medtronic, Inc. | Steerable high support guidewire with thin wall nitinol tube |
US5771902A (en) | 1995-09-25 | 1998-06-30 | Regents Of The University Of California | Micromachined actuators/sensors for intratubular positioning/steering |
US5683245A (en) | 1995-05-30 | 1997-11-04 | Ormco Corporation | Shape memory orthodontic archwire having variable recovery stresses |
US5771742A (en) | 1995-09-11 | 1998-06-30 | Tini Alloy Company | Release device for retaining pin |
US5658515A (en) | 1995-09-25 | 1997-08-19 | Lee; Abraham P. | Polymer micromold and fabrication process |
US5825275A (en) | 1995-10-27 | 1998-10-20 | University Of Maryland | Composite shape memory micro actuator |
US5772864A (en) | 1996-02-23 | 1998-06-30 | Meadox Medicals, Inc. | Method for manufacturing implantable medical devices |
US5850837A (en) | 1996-03-21 | 1998-12-22 | Furukawa Electric Co., Ltd. | Device for correcting an ingrown nail |
WO1997044780A1 (en) | 1996-05-20 | 1997-11-27 | International Business Machines Corporation | Shape memory alloy recording medium, storage devices based thereon, and method for using these storage devices |
US5676356A (en) | 1996-05-30 | 1997-10-14 | The Boler Company | Flexible bolster |
JP3198458B2 (en) * | 1996-07-02 | 2001-08-13 | 千住スプリンクラー株式会社 | Sprinkler head |
US6072617A (en) | 1996-11-26 | 2000-06-06 | Texas Instruments Incorporated | Micro mechanical device with memory metal component |
US6080160A (en) | 1996-12-04 | 2000-06-27 | Light Sciences Limited Partnership | Use of shape memory alloy for internally fixing light emitting device at treatment site |
US7073504B2 (en) | 1996-12-18 | 2006-07-11 | Ams Research Corporation | Contraceptive system and method of use |
US5796152A (en) | 1997-01-24 | 1998-08-18 | Roxburgh Ltd. | Cantilevered microstructure |
JP3881741B2 (en) | 1997-03-19 | 2007-02-14 | Necトーキン株式会社 | NiMnGa alloy |
JP3161362B2 (en) | 1997-05-01 | 2001-04-25 | 富士ゼロックス株式会社 | Microstructure, its manufacturing method, its manufacturing apparatus, substrate and molding die |
JP3538000B2 (en) | 1997-07-25 | 2004-06-14 | ホーチキ株式会社 | Sprinkler head |
US5960812A (en) | 1997-07-25 | 1999-10-05 | Tini Alloy Company | Fluid flow control valve |
US6075239A (en) | 1997-09-10 | 2000-06-13 | Lucent Technologies, Inc. | Article comprising a light-actuated micromechanical photonic switch |
US6042606A (en) | 1997-09-29 | 2000-03-28 | Cook Incorporated | Radially expandable non-axially contracting surgical stent |
US6139143A (en) | 1997-12-11 | 2000-10-31 | Bausch & Lomb Incorporated | Temple for eyewear having an integrally formed serpentine hinge |
US6447478B1 (en) | 1998-05-15 | 2002-09-10 | Ronald S. Maynard | Thin-film shape memory alloy actuators and processing methods |
JP4741728B2 (en) | 1998-06-04 | 2011-08-10 | ニューヨーク・ユニバーシティ | Intravascular thin film device and stroke treatment |
US6096175A (en) | 1998-07-17 | 2000-08-01 | Micro Therapeutics, Inc. | Thin film stent |
US6354839B1 (en) | 1998-10-10 | 2002-03-12 | Orbital Research, Inc. | Refreshable braille display system |
US20020192617A1 (en) | 2000-04-25 | 2002-12-19 | Align Technology, Inc. | Embedded features and methods of a dental appliance |
FR2786790B1 (en) | 1998-12-04 | 2001-02-23 | Ecole Polytech | LASER PROCESSING OF AN OBJECT OF SHAPE MEMORY MATERIAL |
EP1144973B1 (en) | 1998-12-15 | 2006-01-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Method of producing calibration structures in semiconductor substrates |
JP2000185999A (en) | 1998-12-21 | 2000-07-04 | Tokin Corp | Production of alloy single crystal |
US6123153A (en) * | 1998-12-30 | 2000-09-26 | Grinnell Corporation | Fire protection sprinkle and release mechanism |
US6410360B1 (en) | 1999-01-26 | 2002-06-25 | Teledyne Industries, Inc. | Laminate-based apparatus and method of fabrication |
US6129153A (en) * | 1999-03-03 | 2000-10-10 | Joung; In Jin | Water spraying control unit for a fire extinguishing sprinkler head |
US6126371A (en) | 1999-04-05 | 2000-10-03 | Lockheed Martin Corporation | Shape memory metal alloy preload attenuation device |
US6406605B1 (en) | 1999-06-01 | 2002-06-18 | Ysi Incorporated | Electroosmotic flow controlled microfluidic devices |
US6284067B1 (en) | 1999-07-02 | 2001-09-04 | The University Of Tennessee Research Corporation | Method for producing alloyed bands or strips on pistons for internal combustion engines |
US6592724B1 (en) | 1999-09-22 | 2003-07-15 | Delphi Technologies, Inc. | Method for producing NiTiHf alloy films by sputtering |
US7736687B2 (en) | 2006-01-31 | 2010-06-15 | Advance Bio Prosthetic Surfaces, Ltd. | Methods of making medical devices |
JP3921320B2 (en) | 2000-01-31 | 2007-05-30 | 日本電気株式会社 | Thermal infrared detector and method for manufacturing the same |
US6247493B1 (en) | 2000-03-09 | 2001-06-19 | Richard C. Henderson | Miniature pulsatile flow controller |
US6277133B1 (en) | 2000-03-17 | 2001-08-21 | Nozomu Kanesaka | Connector for small conduits |
US6624730B2 (en) | 2000-03-28 | 2003-09-23 | Tini Alloy Company | Thin film shape memory alloy actuated microrelay |
US6771445B1 (en) | 2000-03-31 | 2004-08-03 | Hitachi Global Storage Technologies Netherlands B.V. | Assembly and method suitable for thermo-magnetic writing/reading of data |
US6470108B1 (en) | 2000-04-26 | 2002-10-22 | Tini Alloy Company | Optical switching device and method |
JP3782289B2 (en) | 2000-07-06 | 2006-06-07 | トキコーポレーション株式会社 | Method of processing shape memory alloy and shape memory alloy |
US6790298B2 (en) | 2000-07-10 | 2004-09-14 | Tini Alloy Company | Method of fabrication of free standing shape memory alloy thin film |
US6407478B1 (en) | 2000-08-21 | 2002-06-18 | Jds Uniphase Corporation | Switches and switching arrays that use microelectromechanical devices having one or more beam members that are responsive to temperature |
US6805898B1 (en) | 2000-09-28 | 2004-10-19 | Advanced Cardiovascular Systems, Inc. | Surface features of an implantable medical device |
US6614570B2 (en) | 2000-09-29 | 2003-09-02 | Tini Alloy Company | Shutter for fiber optic systems |
US6582985B2 (en) | 2000-12-27 | 2003-06-24 | Honeywell International Inc. | SOI/glass process for forming thin silicon micromachined structures |
EP1238600A1 (en) | 2001-03-08 | 2002-09-11 | Thierry Holemans | NA device using shape memory alloys and a bias element to reduce the thermal hysteresis of the phase change |
US6742761B2 (en) | 2001-04-10 | 2004-06-01 | Tini Alloy Company | Miniature latching valve |
US6454913B1 (en) | 2001-07-12 | 2002-09-24 | Delphi Technologies, Inc. | Process for deposition of sputtered shape memory alloy films |
FR2827502B1 (en) | 2001-07-17 | 2004-04-09 | Univ Joseph Fourier | MICROMUSCLE IN A BIOLOGICAL ENVIRONMENT |
US6811910B2 (en) | 2001-07-18 | 2004-11-02 | Evionyx, Inc. | Metal air cell incorporating air flow system |
DE10162296C1 (en) | 2001-12-19 | 2003-04-03 | Karlsruhe Forschzent | Producing and maintaining two- or three-dimensional curve in rod or band of super-elastic, monocrystalline copper alloy comprises heating it, pressing into heated mold, cooling, reheating and quenching |
US6669795B2 (en) | 2002-01-17 | 2003-12-30 | Tini Alloy Company | Methods of fabricating high transition temperature SMA, and SMA materials made by the methods |
US6620634B2 (en) | 2002-01-17 | 2003-09-16 | Tini Alloy Company | Method of accurately measuring compositions of thin film shape memory alloys |
DE10208202A1 (en) | 2002-02-26 | 2003-09-11 | Karlsruhe Forschzent | vein graft |
US20030170130A1 (en) | 2002-03-07 | 2003-09-11 | Johnson A. David | Micro-dosing pumps and valves |
US6908275B2 (en) | 2002-04-29 | 2005-06-21 | Charles Nelson | Fastener having supplemental support and retention capabilities |
US6854668B2 (en) * | 2002-04-29 | 2005-02-15 | Victaulic Company Of America | Extended coverage ordinary hazard sprinkler system |
US7823845B2 (en) | 2002-05-09 | 2010-11-02 | Dmr Holding Group, Llc | Corner climber |
US6918545B2 (en) * | 2002-05-10 | 2005-07-19 | The Viking Corporation | Sprinkler head trigger assembly |
US6746890B2 (en) | 2002-07-17 | 2004-06-08 | Tini Alloy Company | Three dimensional thin film devices and methods of fabrication |
US6920966B2 (en) | 2003-03-24 | 2005-07-26 | Honeywell International Inc. | Remotely releasable support strut |
US7972616B2 (en) | 2003-04-17 | 2011-07-05 | Nanosys, Inc. | Medical device applications of nanostructured surfaces |
US6955187B1 (en) | 2003-07-16 | 2005-10-18 | Tini Alloy Company | Zinc-air battery control valve |
WO2005097673A1 (en) | 2004-03-30 | 2005-10-20 | Toyo Advanced Technologies Co., Ltd. | Method for treating surface of base, surface-treated base, material for medical use and instrument for medical use |
US7632361B2 (en) | 2004-05-06 | 2009-12-15 | Tini Alloy Company | Single crystal shape memory alloy devices and methods |
JP2008506470A (en) | 2004-07-15 | 2008-03-06 | ミカーディア コーポレーション | Implant for forming a heart valve (implant) and method for forming the same |
US20060118210A1 (en) | 2004-10-04 | 2006-06-08 | Johnson A D | Portable energy storage devices and methods |
US7763342B2 (en) | 2005-03-31 | 2010-07-27 | Tini Alloy Company | Tear-resistant thin film methods of fabrication |
US20060240953A1 (en) | 2005-04-26 | 2006-10-26 | Mohsen Shahinpoor | Human lower limb performance enhancement outfit |
US20070173787A1 (en) | 2005-11-01 | 2007-07-26 | Huang Mark C T | Thin-film nitinol based drug eluting stent |
US20070246233A1 (en) | 2006-04-04 | 2007-10-25 | Johnson A D | Thermal actuator for fire protection sprinkler head |
WO2008045907A1 (en) | 2006-10-10 | 2008-04-17 | Ormco Corporation | Orthodontic auxiliary device having a swivel for adapting to implants |
-
2008
- 2008-01-24 WO PCT/US2008/051949 patent/WO2008092028A1/en active Application Filing
- 2008-01-24 US US12/019,553 patent/US8684101B2/en active Active
-
2014
- 2014-03-31 US US14/230,881 patent/US20150266141A1/en not_active Abandoned
Patent Citations (99)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US538593A (en) * | 1895-04-30 | Automatic fire-extinguisher | ||
US1136687A (en) * | 1914-03-02 | 1915-04-20 | Jay Litt | Muffler attachment for telephones. |
US1913035A (en) * | 1929-03-01 | 1933-06-06 | Gen Fire Extinguisher Co | Sprinkler |
US1904828A (en) * | 1930-01-28 | 1933-04-18 | Pawtucket Screw Company | Thermoelectric sprinkler head |
US2371614A (en) * | 1942-12-31 | 1945-03-20 | Packard Motor Car Co | Engine connecting rod and method of securing parts together |
US2586556A (en) * | 1946-11-23 | 1952-02-19 | Mullikin Alfred | Flexible binder post |
US2793036A (en) * | 1955-02-18 | 1957-05-21 | George B Hansburg | Pogo stick |
US3229956A (en) * | 1962-03-02 | 1966-01-18 | Stevens Mfg Co Inc | Diaphragm fluid valve |
US3435823A (en) * | 1966-04-11 | 1969-04-01 | Miles Lowell Edwards | Anastomotic coupling with anti-pulse ring means |
US3445086A (en) * | 1966-11-25 | 1969-05-20 | Zyrotron Ind Inc | Snap acting valve and control mechanism therefor |
US3561537A (en) * | 1968-06-20 | 1971-02-09 | Fire Protection Co | Automatic sprinkler head |
US3668131A (en) * | 1968-08-09 | 1972-06-06 | Allied Chem | Dissolution of metal with acidified hydrogen peroxide solutions |
US3559641A (en) * | 1968-09-30 | 1971-02-02 | Inutcodes Inc | Intrauterine device |
US3659625A (en) * | 1970-02-16 | 1972-05-02 | Westinghouse Air Brake Co | Drain valve device |
US3725835A (en) * | 1970-07-20 | 1973-04-03 | J Hopkins | Memory material actuator devices |
US3789838A (en) * | 1971-02-19 | 1974-02-05 | E Fournier | Force transmitting intrauterine device |
US3888975A (en) * | 1972-12-27 | 1975-06-10 | Alza Corp | Erodible intrauterine device |
US4072159A (en) * | 1975-02-22 | 1978-02-07 | Toyoki Kurosawa | Emergency valve incorporating thermal foamable plastic material |
US4145764A (en) * | 1975-07-23 | 1979-03-27 | Sumitomo Chemical Co., Ltd. | Endosseous implants |
US4096993A (en) * | 1977-01-21 | 1978-06-27 | Emerson Electric Co. | Compensated control valve |
US4151064A (en) * | 1977-12-27 | 1979-04-24 | Coulter Stork U.S.A., Inc. | Apparatus for sputtering cylinders |
US4265684A (en) * | 1978-07-26 | 1981-05-05 | Vacuumschmelze Gmbh | Magnetic core comprised of low-retentivity amorphous alloy |
US4243963A (en) * | 1979-04-02 | 1981-01-06 | Gte Automatic Electric Laboratories Incorporated | Construction of a printed wiring card mountable reed relay |
US4501058A (en) * | 1979-08-27 | 1985-02-26 | Pda Engineering | Method of pre-stressing a structural member |
US4434855A (en) * | 1982-03-30 | 1984-03-06 | The United States Of America As Represented By The Secretary Of The Navy | Sprinkler valve |
US4596483A (en) * | 1983-07-11 | 1986-06-24 | Leuven Research And Development | Temperature responsive linkage element |
US5190546A (en) * | 1983-10-14 | 1993-03-02 | Raychem Corporation | Medical devices incorporating SIM alloy elements |
US4585209A (en) * | 1983-10-27 | 1986-04-29 | Harry E. Aine | Miniature valve and method of making same |
US4524343A (en) * | 1984-01-13 | 1985-06-18 | Raychem Corporation | Self-regulated actuator |
US4654191A (en) * | 1984-06-09 | 1987-03-31 | Kernforschungszentrum Karlsruhe Gmbh | Pressure release arrangement for the safety containment of a pressurized water nuclear reactor |
US4589179A (en) * | 1984-09-10 | 1986-05-20 | Caterpillar Tractor Co. | Flexible positioner |
US4567549A (en) * | 1985-02-21 | 1986-01-28 | Blazer International Corp. | Automatic takeup and overload protection device for shape memory metal actuator |
US4753465A (en) * | 1986-04-11 | 1988-06-28 | James F. Dalby | Remotely operable locking mechanism |
US4821997A (en) * | 1986-09-24 | 1989-04-18 | The Board Of Trustees Of The Leland Stanford Junior University | Integrated, microminiature electric-to-fluidic valve and pressure/flow regulator |
US4824073A (en) * | 1986-09-24 | 1989-04-25 | Stanford University | Integrated, microminiature electric to fluidic valve |
US4915773A (en) * | 1986-11-26 | 1990-04-10 | Kravetsky Dmitry Y | Process for growing shaped single crystals |
US4823607A (en) * | 1987-05-18 | 1989-04-25 | Massachusetts Institute Of Technology | Released film structures and method of measuring film properties |
US4896728A (en) * | 1987-10-02 | 1990-01-30 | Thomas Bolton & Johnson Limited | Fire sprinklers with frangible body closing a flow passage and separate means for shattering same |
US5119555A (en) * | 1988-09-19 | 1992-06-09 | Tini Alloy Company | Non-explosive separation device |
US4893655A (en) * | 1989-08-23 | 1990-01-16 | The United States Of America As Represented By The Secretary Of The Navy | Double valve mechanism for an acoustic modulator |
US5395238A (en) * | 1990-01-19 | 1995-03-07 | Ormco Corporation | Method of forming orthodontic brace |
US5117916A (en) * | 1990-04-11 | 1992-06-02 | Hochiki Kabushiki Kaisha | Sprinkler head and operation monitor therefor |
US20020018325A1 (en) * | 1990-06-08 | 2002-02-14 | Hitachi, Ltd. | Magnetoresistance effect elements, magnetic heads and magnetic storage apparatus |
US5102276A (en) * | 1990-07-12 | 1992-04-07 | Ford Motor Company | Removable fastener with elastic linking means |
US5114504A (en) * | 1990-11-05 | 1992-05-19 | Johnson Service Company | High transformation temperature shape memory alloy |
US5211371A (en) * | 1991-07-22 | 1993-05-18 | Advanced Control Technologies, Inc. | Linearly actuated valve |
US5116252A (en) * | 1991-08-02 | 1992-05-26 | Hartman Thomas A | In-line sleeve valve having velocity guide pressure equalization and drive assembly with improved drive pin mountings |
US5096419A (en) * | 1991-08-14 | 1992-03-17 | Kabushiki Kaisha Morita Seisakusho | Apparatus and method for detecting an apical position |
US5192147A (en) * | 1991-09-03 | 1993-03-09 | Lockheed Missiles & Space Company, Inc. | Non-pyrotechnic release system |
US5312152A (en) * | 1991-10-23 | 1994-05-17 | Martin Marietta Corporation | Shape memory metal actuated separation device |
US5714690A (en) * | 1991-12-13 | 1998-02-03 | Honeywell Inc. | Piezoresistive silicon pressure sensor manufacture implementing long diaphragms with large aspect ratios |
US5218998A (en) * | 1992-04-01 | 1993-06-15 | Bakken Gary M | Linearly adjustable |
US5622225A (en) * | 1992-04-23 | 1997-04-22 | Sundholm; Goeran | Quick response sprinkler head |
US5312247A (en) * | 1992-05-21 | 1994-05-17 | Ormco Corporation | Transpalatal orthodontic appliance of superelastic or shape-memory alloy |
US5309717A (en) * | 1993-03-22 | 1994-05-10 | Minch Richard B | Rapid shape memory effect micro-actuators |
US5494113A (en) * | 1994-02-01 | 1996-02-27 | Central Sprinkler Corporation | Sprinklers with shape-memory alloy actuators |
US5605543A (en) * | 1994-03-10 | 1997-02-25 | Schneider (Usa) Inc. | Catheter having shaft of varying stiffness |
US5502982A (en) * | 1994-04-28 | 1996-04-02 | Liquid Carbonic Industries Corporation | Cryogenic tie pin |
US6013854A (en) * | 1994-06-17 | 2000-01-11 | Terumo Kabushiki Kaisha | Indwelling stent and the method for manufacturing the same |
US5641364A (en) * | 1994-10-28 | 1997-06-24 | The Furukawa Electric Co., Ltd. | Method of manufacturing high-temperature shape memory alloys |
US5619177A (en) * | 1995-01-27 | 1997-04-08 | Mjb Company | Shape memory alloy microactuator having an electrostatic force and heating means |
US5640217A (en) * | 1995-02-02 | 1997-06-17 | Fergaflex, Inc. | Eyeglass frame with very high recoverable deformability |
US5722989A (en) * | 1995-05-22 | 1998-03-03 | The Regents Of The University Of California | Microminiaturized minimally invasive intravascular micro-mechanical systems powered and controlled via fiber-optic cable |
US6169269B1 (en) * | 1996-09-05 | 2001-01-02 | Medtronic Inc. | Selectively activated shape memory device |
US6042553A (en) * | 1997-04-15 | 2000-03-28 | Symbiosis Corporation | Linear elastic member |
US5903099A (en) * | 1997-05-23 | 1999-05-11 | Tini Alloy Company | Fabrication system, method and apparatus for microelectromechanical devices |
US5867302A (en) * | 1997-08-07 | 1999-02-02 | Sandia Corporation | Bistable microelectromechanical actuator |
US6042374A (en) * | 1998-01-14 | 2000-03-28 | Ormco Corporation | Self ligating orthodontic bracket |
US6195478B1 (en) * | 1998-02-04 | 2001-02-27 | Agilent Technologies, Inc. | Planar lightwave circuit-based optical switches using micromirrors in trenches |
US6224626B1 (en) * | 1998-02-17 | 2001-05-01 | Md3, Inc. | Ultra-thin expandable stent |
US6524322B1 (en) * | 1998-10-23 | 2003-02-25 | Eric Berreklouw | Anastomosis device |
US6203715B1 (en) * | 1999-01-19 | 2001-03-20 | Daewoo Electronics Co., Ltd. | Method for the manufacture of a thin film actuated mirror array |
US6229640B1 (en) * | 1999-08-11 | 2001-05-08 | Adc Telecommunications, Inc. | Microelectromechanical optical switch and method of manufacture thereof |
US6386507B2 (en) * | 1999-09-01 | 2002-05-14 | Jds Uniphase Corporation | Microelectromechanical valves including single crystalline material components |
US6358380B1 (en) * | 1999-09-22 | 2002-03-19 | Delphi Technologies, Inc. | Production of binary shape-memory alloy films by sputtering using a hot pressed target |
US6379383B1 (en) * | 1999-11-19 | 2002-04-30 | Advanced Bio Prosthetic Surfaces, Ltd. | Endoluminal device exhibiting improved endothelialization and method of manufacture thereof |
US6849085B2 (en) * | 1999-11-19 | 2005-02-01 | Advanced Bio Prosthetic Surfaces, Ltd. | Self-supporting laminated films, structural materials and medical devices manufactured therefrom and method of making same |
US6537310B1 (en) * | 1999-11-19 | 2003-03-25 | Advanced Bio Prosthetic Surfaces, Ltd. | Endoluminal implantable devices and method of making same |
US6352494B2 (en) * | 2000-01-12 | 2002-03-05 | Mcalonan Mark | Bungee pole |
US6533905B2 (en) * | 2000-01-24 | 2003-03-18 | Tini Alloy Company | Method for sputtering tini shape-memory alloys |
US6852132B1 (en) * | 2000-07-05 | 2005-02-08 | Russell A Houser | Artificial limbs incorporating superelastic supports |
US20020062154A1 (en) * | 2000-09-22 | 2002-05-23 | Ayers Reed A. | Non-uniform porosity tissue implant |
US6672502B1 (en) * | 2000-11-28 | 2004-01-06 | The State Of Oregon Acting By And Through The State Board Of Higher Education On Behalf Of Oregon State University | Method for making devices having intermetallic structures and intermetallic devices made thereby |
US6688828B1 (en) * | 2000-12-01 | 2004-02-10 | Arizona Board Of Regents | Self-torquing fasteners |
US20030002994A1 (en) * | 2001-03-07 | 2003-01-02 | Johnson A. David | Thin film shape memory alloy actuated flow controller |
US6729599B2 (en) * | 2001-06-26 | 2004-05-04 | Tini Alloy Company | Liquid microvalve |
US20030078465A1 (en) * | 2001-10-16 | 2003-04-24 | Suresh Pai | Systems for heart treatment |
US6840329B2 (en) * | 2002-03-06 | 2005-01-11 | Senju Sprinkler Company Limited | Cover assembly for a concealed sprinkler head |
US20040083006A1 (en) * | 2002-04-09 | 2004-04-29 | Astra Tech Ab | Medical prosthetic devices having improved biocompatibility |
US7040323B1 (en) * | 2002-08-08 | 2006-05-09 | Tini Alloy Company | Thin film intrauterine device |
US7524914B2 (en) * | 2002-10-11 | 2009-04-28 | The University Of Connecticut | Shape memory polymers based on semicrystalline thermoplastic polyurethanes bearing nanostructured hard segments |
US7201367B2 (en) * | 2002-12-12 | 2007-04-10 | Caterpillar Inc | Load-bearing resilient mount |
US7022173B2 (en) * | 2003-02-05 | 2006-04-04 | 3M Innovative Properties Company | Use of ceramics in dental and orthodontic applications |
US6843465B1 (en) * | 2003-08-14 | 2005-01-18 | Loren W. Scott | Memory wire actuated control valve |
US20050113933A1 (en) * | 2003-11-24 | 2005-05-26 | Checkmed Systems, Inc. | Stent |
US7044596B2 (en) * | 2004-02-02 | 2006-05-16 | Park Andrew Q | Hingeless eyeglasses frame |
US20100129766A1 (en) * | 2006-10-10 | 2010-05-27 | Ormco Corporation | Orthodontic retraction arch and spring |
US20090035859A1 (en) * | 2007-07-30 | 2009-02-05 | Alfred David Johnson | Method and devices for preventing restenosis in cardiovascular stents |
US20120048432A1 (en) * | 2010-08-24 | 2012-03-01 | Alfred David Johnson | Shape setting a shape memory alloy dental arch |
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US20090095493A1 (en) | 2009-04-16 |
US8684101B2 (en) | 2014-04-01 |
US20150266141A1 (en) | 2015-09-24 |
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