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TWI772931B - Electronic device housings with chamfered edges - Google Patents

Electronic device housings with chamfered edges Download PDF

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TWI772931B
TWI772931B TW109136722A TW109136722A TWI772931B TW I772931 B TWI772931 B TW I772931B TW 109136722 A TW109136722 A TW 109136722A TW 109136722 A TW109136722 A TW 109136722A TW I772931 B TWI772931 B TW I772931B
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layer
metal substrate
surface portion
exposed surface
electronic device
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TW109136722A
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TW202129084A (en
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郭清勇
吳冠霆
張啟豪
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美商惠普發展公司有限責任合夥企業
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/04Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/026Anodisation with spark discharge
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00Electrophoretic coating characterised by the process
    • C25D13/12Electrophoretic coating characterised by the process characterised by the article coated
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00Electrophoretic coating characterised by the process
    • C25D13/20Pretreatment
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F1/00Details not covered by groups G06F3/00 - G06F13/00 and G06F21/00
    • G06F1/16Constructional details or arrangements
    • G06F1/1613Constructional details or arrangements for portable computers
    • G06F1/1633Constructional details or arrangements of portable computers not specific to the type of enclosures covered by groups G06F1/1615 - G06F1/1626
    • G06F1/1656Details related to functional adaptations of the enclosure, e.g. to provide protection against EMI, shock, water, or to host detachable peripherals like a mouse or removable expansions units like PCMCIA cards, or to provide access to internal components for maintenance or to removable storage supports like CDs or DVDs, or to mechanically mount accessories
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F1/00Details not covered by groups G06F3/00 - G06F13/00 and G06F21/00
    • G06F1/16Constructional details or arrangements
    • G06F1/1613Constructional details or arrangements for portable computers
    • G06F1/1633Constructional details or arrangements of portable computers not specific to the type of enclosures covered by groups G06F1/1615 - G06F1/1626
    • G06F1/1684Constructional details or arrangements related to integrated I/O peripherals not covered by groups G06F1/1635 - G06F1/1675
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F1/00Details not covered by groups G06F3/00 - G06F13/00 and G06F21/00
    • G06F1/16Constructional details or arrangements
    • G06F1/1613Constructional details or arrangements for portable computers
    • G06F1/1633Constructional details or arrangements of portable computers not specific to the type of enclosures covered by groups G06F1/1615 - G06F1/1626
    • G06F1/1684Constructional details or arrangements related to integrated I/O peripherals not covered by groups G06F1/1635 - G06F1/1675
    • G06F1/169Constructional details or arrangements related to integrated I/O peripherals not covered by groups G06F1/1635 - G06F1/1675 the I/O peripheral being an integrated pointing device, e.g. trackball in the palm rest area, mini-joystick integrated between keyboard keys, touch pads or touch stripes
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/033Pointing devices displaced or positioned by the user, e.g. mice, trackballs, pens or joysticks; Accessories therefor
    • G06F3/0354Pointing devices displaced or positioned by the user, e.g. mice, trackballs, pens or joysticks; Accessories therefor with detection of 2D relative movements between the device, or an operating part thereof, and a plane or surface, e.g. 2D mice, trackballs, pens or pucks
    • G06F3/03547Touch pads, in which fingers can move on a surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/06Coating on the layer surface on metal layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/28Multiple coating on one surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Theoretical Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • General Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Human Computer Interaction (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Electrochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
  • Laminated Bodies (AREA)

Abstract

In one example, a method for manufacturing an electronic device housing may include forming an oxide layer on a surface of a metal substrate. Further, an edge region of the metal substrate may be chamfered to form an exposed surface portion of the metal substrate. The exposed surface portion of the metal substrate may be electrocleaned. Upon electrocleaning the exposed surface portion, a transparent protective passivation layer may be formed on the exposed surface portion. Furthermore, an electrophoretic deposition layer may be formed on the transparent protective passivation layer.

Description

具有倒角邊緣之電子裝置外殼Electronic device enclosure with chamfered edges

本發明係有關於具有倒角邊緣之電子裝置外殼。The present invention relates to electronic device housings with chamfered edges.

由於可攜式電子產品發展得更輕且更小,具有輕量且高堅固特性的金屬外殼已漸盛行。在此等情況下,可使用諸如鎂合金、鋁合金等金屬基體來製造金屬外殼,其可具有低密度、高比強度、良好的散熱性、抗電磁干擾能力及良好的減震性。As portable electronic products have been developed to be lighter and smaller, metal casings with light weight and high robustness properties have become popular. In these cases, metal substrates such as magnesium alloys, aluminum alloys, etc. can be used to manufacture metal casings, which can have low density, high specific strength, good heat dissipation, electromagnetic interference resistance, and good shock absorption.

於本發明的一個態樣中,揭示一種用於製造一電子裝置外殼之方法,該方法包含: 在一金屬基體之一表面上形成一氧化物層;倒角該金屬基體之一邊緣區域以形成該金屬基體之一暴露表面部分;電清洗該金屬基體之該暴露表面部分;電清洗該暴露表面部分後,即在該暴露表面部分上形成一透明保護鈍化層;以及在該透明保護鈍化層上形成一電泳沉積層。In one aspect of the present invention, a method for fabricating an electronic device casing is disclosed, the method comprising: forming an oxide layer on a surface of a metal substrate; chamfering an edge region of the metal substrate to form An exposed surface portion of the metal substrate; electro-cleaning the exposed surface portion of the metal substrate; after electro-cleaning the exposed surface portion, a transparent protective passivation layer is formed on the exposed surface portion; and on the transparent protective passivation layer An electrophoretic deposition layer is formed.

用於如行動電話、膝上型電腦、音樂播放器、個人數位助理及全球定位系統裝置等電子裝置的外殼可由金屬形成。舉例而言,因為輕量及高機械強度,鎂合金可適合使用在該電子裝置外殼中。但是,鎂合金可能有較差的色彩穩定性、硬度及化學抗性。因此,可能難以在該鎂合金外殼之倒角表面作出金屬光澤感,畢竟鎂合金會在表面氧化。此外,舉例而言,可能難以使用噴塗程序在鎂合金外殼之倒角表面上獲得多種色彩或不同的光亮程度。Housings for electronic devices such as mobile phones, laptops, music players, personal digital assistants, and global positioning system devices may be formed of metal. For example, magnesium alloys may be suitable for use in the electronic device housing due to their light weight and high mechanical strength. However, magnesium alloys may have poor color stability, hardness and chemical resistance. Therefore, it may be difficult to create a metallic luster on the chamfered surface of the magnesium alloy shell, after all, the magnesium alloy is oxidized on the surface. Furthermore, for example, it may be difficult to obtain multiple colors or different brightness levels on the chamfered surfaces of magnesium alloy housings using spraying procedures.

本文所述範例可提供電子裝置外殼之製造方法。在一範例中,可在一金屬基體之一表面上形成一氧化物層。此外,可倒角該金屬基體之一邊緣區域以形成該金屬基體之一暴露表面部分。該金屬基體之該暴露表面部分可經電清洗。電清洗該暴露表面部分後,即可在該暴露表面部分上形成一透明保護鈍化層。 此外,可在該透明保護鈍化層上形成一電泳沉積層。Examples described herein may provide methods of manufacturing electronic device housings. In one example, an oxide layer may be formed on a surface of a metal substrate. Additionally, an edge region of the metal substrate may be chamfered to form an exposed surface portion of the metal substrate. The exposed surface portion of the metal substrate may be electrocleaned. After electrocleaning the exposed surface portion, a transparent protective passivation layer can be formed on the exposed surface portion. In addition, an electrophoretic deposition layer can be formed on the transparent protective passivation layer.

本文所述範例可在該電子裝置外殼之邊緣區域提供金屬光澤倒角表面(例如,亮面或天然金屬光澤表面)。此外,本文所述範例可藉由在該等金屬表面之倒角邊緣區域提供不同色彩來增加該電子裝置外殼之美感外觀。此外,本文所述之示例性透明保護鈍化層及電沈積層可防止或解決透過該暴露表面部分暴露之金屬基體的污斑及腐蝕問題且提供一耐用塗層。The examples described herein may provide a metallic luster chamfered surface (eg, a glossy or natural metallic luster surface) in the edge region of the electronic device housing. Furthermore, the examples described herein can enhance the aesthetic appearance of the electronic device housing by providing different colors in the chamfered edge regions of the metal surfaces. In addition, the exemplary transparent protective passivation layers and electrodeposited layers described herein can prevent or resolve stain and corrosion problems of metal substrates partially exposed through the exposed surface and provide a durable coating.

在接下來的敘述中,為便於說明而提出許多特定細節以供對本技術的透徹理解。然而,該等示例性設備、裝置及系統可在未具該等特定細節下實施。說明書所指「一範例」或類似用語意指所述之一特定特徵、結構、或特性至少含納於彼範例中,但可能未含於其他範例中。In the following description, for purposes of explanation, numerous specific details are set forth to provide a thorough understanding of the present technology. However, the exemplary apparatus, devices, and systems may be practiced without these specific details. Reference in the specification to "an example" or similar terms means that a particular feature, structure, or characteristic described is included in at least that example, but may not be included in other examples.

現請參圖式,圖1為說明用於製造具有倒角邊緣之電子裝置外殼的示例性方法100之流程圖。示例性電子裝置外殼可為智慧型手機外殼、平板電腦或筆記型個人電腦外殼、數位相機外殼等。此外,示例性電子裝置外殼可為容置顯示器之顯示器外殼、容置鍵盤之鍵盤外殼、或其組合。Referring now to the drawings, FIG. 1 is a flow chart illustrating an exemplary method 100 for fabricating an electronic device housing with chamfered edges. Exemplary electronic device housings may be smartphone housings, tablet or notebook PC housings, digital camera housings, and the like. Furthermore, exemplary electronic device housings may be display housings housing a display, keyboard housings housing a keyboard, or combinations thereof.

在步驟102,可在一金屬基體之表面上形成一氧化物層。金屬基體可包括:鋁、鎂、鋰、鋅、鈦、鋁合金、鎂合金、鋰合金、鋅合金、鈦合金或其組合。在一範例中,可藉由在該金屬基體表面上施加一微弧氧化處理及一第一鈍化處理中之一者來形成該氧化物層。例如,該微弧氧化處理及該第一鈍化處理可為用於在金屬基體上產生氧化物塗層之電化學表面處理程序。In step 102, an oxide layer may be formed on the surface of a metal substrate. The metal matrix may include: aluminum, magnesium, lithium, zinc, titanium, aluminum alloys, magnesium alloys, lithium alloys, zinc alloys, titanium alloys, or combinations thereof. In one example, the oxide layer may be formed by applying one of a micro-arc oxidation treatment and a first passivation treatment on the surface of the metal substrate. For example, the micro-arc oxidation treatment and the first passivation treatment may be electrochemical surface treatment procedures for producing oxide coatings on metal substrates.

在一範例中,該微弧氧化程序可指用於在金屬基體上產生氧化物塗層之一程序。在微弧氧化程序期間,可將金屬基體可置放於一電解質溶液中,該電解質溶液包括選自於由下列各物組成之群組的電解質:矽酸鈉、磷酸鈉、氟化鉀、氫氧化鉀、氫氧化鈉、氟鋯酸鹽、六偏磷酸鈉、氟化鈉、氧化鋁、二氧化矽、草酸鐵銨、膦酸鹽及聚氧乙烯烷酚醚。該電解質以該電解質溶液總重計可呈0.05至15重量%之濃度,且200至600伏特之範圍的電壓可藉由置於該電解質溶液中該金屬基體(例如鎂合金基體)穿過該電解質溶液,以形成一微弧氧化層(即,該氧化物層)。在一範例中,該電壓可施加大約3至20分鐘且該微弧氧化程序可在室溫與450℃間之一溫度下實行。該微弧氧化層之厚度可在3至15µm之範圍內。該微弧氧化性質可包括耐磨性、耐腐蝕性、高硬度及電絕緣性。In one example, the micro-arc oxidation procedure may refer to a procedure for producing an oxide coating on a metal substrate. During the micro-arc oxidation procedure, the metal substrate can be placed in an electrolyte solution comprising an electrolyte selected from the group consisting of: sodium silicate, sodium phosphate, potassium fluoride, hydrogen Potassium oxide, sodium hydroxide, fluorozirconate, sodium hexametaphosphate, sodium fluoride, alumina, silica, ferric ammonium oxalate, phosphonates and polyoxyethylene alkanol ethers. The electrolyte may be present at a concentration of 0.05 to 15% by weight, based on the total weight of the electrolyte solution, and a voltage in the range of 200 to 600 volts may be passed through the electrolyte by placing the metal matrix (eg, a magnesium alloy matrix) in the electrolyte solution solution to form a micro-arc oxide layer (ie, the oxide layer). In one example, the voltage may be applied for about 3 to 20 minutes and the micro-arc oxidation process may be performed at a temperature between room temperature and 450°C. The thickness of the micro-arc oxide layer may be in the range of 3 to 15 µm. The micro-arc oxidation properties may include wear resistance, corrosion resistance, high hardness, and electrical insulation.

類似地,該第一鈍化處理可指處理或塗布該金屬基體以減少該金屬基體表面之化學反應性的程序。例如,該鈍化處理可涉及產生環繞該金屬基體之一屏蔽材料外層以使該金屬基體「鈍化」,即比較不會受環境影響或腐蝕。在一範例中,由施加該第一鈍化處理形成的鈍化層(即該氧化物層)可包括鉬酸鹽、釩酸鹽、磷酸鹽、鉻酸鹽、錫酸鹽、錳鹽、或其組合。再者,該鈍化層的厚度可在1-5µm的範圍內。Similarly, the first passivation treatment may refer to a procedure of treating or coating the metal substrate to reduce the chemical reactivity of the surface of the metal substrate. For example, the passivation process may involve creating an outer layer of shielding material around the metal substrate to "passivate" the metal substrate, ie, be less susceptible to environmental influences or corrosion. In one example, the passivation layer (ie, the oxide layer) formed by applying the first passivation treatment may include molybdate, vanadate, phosphate, chromate, stannate, manganese salt, or a combination thereof . Furthermore, the thickness of the passivation layer may be in the range of 1-5 µm.

於步驟104,可倒角該金屬基體之一邊緣區域以形成該金屬基體之一暴露表面部分。在一範例中,該邊緣區域可包括該金屬基體之一外周緣、該金屬基體之一內周緣或其組合。該外周緣可指該金屬基體之一邊界區域或一側壁,且該內周緣可指界定該金屬基體內之開口的邊緣表面。例如,該開口可對應於一觸控板、鍵盤、指紋掃描器等。In step 104, an edge region of the metal substrate may be chamfered to form an exposed surface portion of the metal substrate. In one example, the edge region may include an outer perimeter of the metal substrate, an inner perimeter of the metal substrate, or a combination thereof. The outer perimeter may refer to a boundary region or a sidewall of the metal matrix, and the inner perimeter may refer to the edge surface that defines the opening in the metal matrix. For example, the opening may correspond to a touchpad, keyboard, fingerprint scanner, or the like.

在步驟106,該金屬基體之該暴露表面部分可經電清洗。在一範例中,電清洗係藉由預處理該金屬基體之該暴露表面部分、然後使該金屬基體於電解質溶液中作為電極承受電流,而可由該暴露表面部分移除有機化學品、殘留切削用液、鎂合金碎屑及其他污染物。在一範例中,電清洗該暴露表面部分可包括以一鹼性電解質溶液來鹼性電清洗該暴露表面部分。舉例而言,電解質溶液可包括約2至10重量百分比之氫氧化鈉水溶液、氫氧化鉀水溶液或其組合。因此,示例性電清洗可顯著地增強該電子裝置外殼之生產良率。At step 106, the exposed surface portion of the metal substrate may be electrocleaned. In one example, electrocleaning removes organic chemicals, residual cutting agents from the exposed surface portion by pretreating the exposed surface portion of the metal substrate and then subjecting the metal substrate to current as an electrode in an electrolyte solution. liquid, magnesium alloy chips and other contaminants. In one example, electrocleaning the exposed surface portion may include alkaline electrocleaning the exposed surface portion with an alkaline electrolyte solution. For example, the electrolyte solution may include about 2 to 10 weight percent of an aqueous sodium hydroxide solution, an aqueous potassium hydroxide solution, or a combination thereof. Thus, the exemplary electrocleaning can significantly enhance the production yield of the electronic device housing.

在步驟108,電清洗該暴露表面部分後,即可在該暴露表面部分上形成一透明保護鈍化層。在一範例中,可藉由在該暴露表面部分上施加一第二鈍化處理來形成該透明保護鈍化層。在一範例中,該第二鈍化處理之化學品可與該第一鈍化處理之化學品不同。示例性第二鈍化處理可包括以一金屬離子、一有機酸及一螯合劑的錯合物來處理該暴露表面部分。示例性螯合劑可包括:乙二胺四乙酸(EDTA)、乙二胺、氮基三乙酸(NTA)、二伸乙基三胺五(亞甲基膦酸)(DTPPH)、氮基參(亞甲基膦酸)(NTMP)、1-羥乙烷-1,1-二膦酸(HEDP)、硫酸、磷酸或其任何組合。示例性金屬離子可為:鋁離子、鎳離子、錫離子、銦離子、鉻離子、鋅離子或其任何組合。例示性有機酸可包括乳酸、乙酸、甲酸、草酸及其類似物。在一範例中,該透明保護鈍化層可具有在30nm至3µm之範圍內的厚度。此外,該透明保護鈍化層可具有大約3至5之pH值。In step 108, after the exposed surface portion is electro-cleaned, a transparent protective passivation layer can be formed on the exposed surface portion. In one example, the transparent protective passivation layer may be formed by applying a second passivation process on the exposed surface portion. In one example, the chemistry of the second passivation treatment can be different from the chemistry of the first passivation treatment. An exemplary second passivation treatment can include treating the exposed surface portion with a complex of a metal ion, an organic acid, and a chelating agent. Exemplary chelating agents may include: ethylenediaminetetraacetic acid (EDTA), ethylenediamine, nitrotriacetic acid (NTA), diethylenetriaminepenta(methylenephosphonic acid) (DTPPH), nitroparaffin ( methylenephosphonic acid) (NTMP), 1-hydroxyethane-1,1-diphosphonic acid (HEDP), sulfuric acid, phosphoric acid, or any combination thereof. Exemplary metal ions may be: aluminum ions, nickel ions, tin ions, indium ions, chromium ions, zinc ions, or any combination thereof. Exemplary organic acids can include lactic acid, acetic acid, formic acid, oxalic acid, and the like. In one example, the transparent protective passivation layer may have a thickness in the range of 30 nm to 3 μm. Additionally, the transparent protective passivation layer may have a pH of about 3 to 5.

在步驟110,可在該透明保護鈍化層上形成一電泳沉積層。在一範例中,該電泳沉積層可用於賦予該金屬基體某種所欲性質,例如硬度或韌性、或某種所欲外觀。因此,在該倒角邊緣區域上之該透明保護鈍化層及該電泳沉積層可提供一閃亮、平坦且平滑之金屬外觀。藉此,該倒角邊緣區域可為該電子裝置外殼提供一美學上具吸引力的外觀。In step 110, an electrophoretic deposition layer may be formed on the transparent protective passivation layer. In one example, the electrophoretically deposited layer can be used to impart a desired property to the metal substrate, such as hardness or toughness, or a desired appearance. Therefore, the transparent protective passivation layer and the electrophoretic deposition layer on the chamfered edge region can provide a shiny, flat and smooth metallic appearance. Thereby, the chamfered edge region can provide an aesthetically attractive appearance to the electronic device housing.

圖2為說明用於製造具有倒角邊緣之電子裝置外殼的另一示例性方法200之流程圖。示例性電子裝置外殼可為容置顯示器之顯示器外殼、容置鍵盤之鍵盤外殼、或其組合。在步驟202,可在一金屬基體之表面上形成一氧化物層。FIG. 2 is a flow chart illustrating another exemplary method 200 for fabricating an electronic device housing with chamfered edges. Exemplary electronic device housings can be a display housing housing a display, a keyboard housing housing a keyboard, or a combination thereof. In step 202, an oxide layer may be formed on the surface of a metal substrate.

在步驟204,可在該氧化物層上施加一塗裝層。在一範例中,在該氧化物層上施加該塗裝層可包括:在包括該氧化物層之金屬基體上施加一底漆塗層。示例性底漆塗層可包括:聚胺甲酸酯、環氧樹脂、環氧樹脂-聚酯、聚酯或其組合。在一範例中,底漆塗層可具有在5至20µm之範圍內的厚度。此外,施加該塗裝層可包括:在該底漆塗層上施加一基底塗層。示例性基底塗層可包括聚胺甲酸酯、聚酯及/或聚丙烯酸類並與至少一顏料組合,該顏料係選自於由碳黑、二氧化鈦、黏土、雲母、滑石、硫酸鋇、碳酸鈣、合成顏料、金屬粉末、氧化鋁、一有機粉末、一無機粉末、塑膠珠、有色顏料及染料構成之群組。在一範例中,基底塗層可具有在10至20µm之範圍內的厚度。At step 204, a coating may be applied over the oxide layer. In one example, applying the coating layer on the oxide layer may include applying a primer coating on the metal substrate including the oxide layer. Exemplary primer coatings may include: polyurethane, epoxy, epoxy-polyester, polyester, or combinations thereof. In one example, the primer coating may have a thickness in the range of 5 to 20 μm. Additionally, applying the finish can include applying a base coat over the primer coat. Exemplary base coats may include polyurethane, polyester and/or polyacrylic in combination with at least one pigment selected from the group consisting of carbon black, titanium dioxide, clay, mica, talc, barium sulfate, carbonic acid The group consisting of calcium, synthetic pigments, metal powders, alumina, an organic powder, an inorganic powder, plastic beads, colored pigments and dyes. In one example, the base coating may have a thickness in the range of 10 to 20 μm.

此外,施加該塗裝層可包括:在該基底塗層上施加一紫外線頂塗層及一熱固化聚酯、丙烯酸系及聚胺甲酸酯頂塗層中之一者。示例性紫外線頂塗層可包括:聚丙烯酸類、聚胺甲酸酯、胺甲酸酯丙烯酸酯、丙烯酸系丙烯酸酯、環氧丙烯酸酯或其任何組合。在一範例中,該紫外線頂塗層可具有在10至25µm之範圍內的厚度。示例性熱固化聚胺甲酸酯頂塗層可包括用於調製胺甲酸酯塗料之羥官能基丙烯酸系聚合物。在一範例中,塗裝層可包括該底漆塗層、該基底塗層及該頂塗層之任何組合。Additionally, applying the finish can include applying one of a UV topcoat and a thermally cured polyester, acrylic, and polyurethane topcoat over the basecoat. Exemplary UV topcoats can include: polyacrylic, polyurethane, urethane acrylate, acrylic acrylate, epoxy acrylate, or any combination thereof. In one example, the UV topcoat can have a thickness in the range of 10 to 25 μm. Exemplary thermally cured polyurethane topcoats can include hydroxy-functional acrylic polymers used to formulate urethane coatings. In one example, the finish layer can include any combination of the primer coat, the base coat, and the top coat.

在步驟206,可藉由施加水性抗腐蝕切削用液以形成該金屬基體之一暴露表面部分來倒角該金屬基體之一邊緣區域。例示性水性抗腐蝕切削用液可包括(例如以重量百分比計)諸如約5-40%之醇類試劑(例如磷酸鹽等)、約3-15%之有機胺(例如二乙醇胺、二甘醇胺、乙二胺、三乙醇胺等)、約5-30%之羧酸鹽(例如乙酸鹽、草酸鹽等)、約1-5%之表面活性劑、及約55-85%之水等組份。在一範例中,可使用一電腦數值控制(CNC)切削(例如CNC菱形切割程序)、一雷射雕刻程序等倒角該邊緣區域。在此範例中,可藉由該CNC切削來倒角該金屬基體之邊緣區域,同時施加或噴灑該水性抗腐蝕切削用液。At step 206, an edge region of the metal substrate may be chamfered by applying an aqueous anti-corrosion cutting fluid to form an exposed surface portion of the metal substrate. Exemplary aqueous anti-corrosion cutting fluids may include (eg, by weight) such as about 5-40% alcohol reagents (eg, phosphates, etc.), about 3-15% organic amines (eg, diethanolamine, diethylene glycol) amine, ethylenediamine, triethanolamine, etc.), about 5-30% of carboxylate (such as acetate, oxalate, etc.), about 1-5% of surfactant, and about 55-85% of water, etc. Component. In one example, the edge region may be chamfered using a computer numerical control (CNC) cutting (eg, a CNC diamond cutting program), a laser engraving program, or the like. In this example, the edge region of the metal substrate can be chamfered by the CNC cutting, while applying or spraying the aqueous anti-corrosion cutting fluid.

在一範例中,倒角可形成在該金屬基體之側壁(例如邊緣區域)上。另外,該倒角可具有任何適當形狀(例如,倒角、圓形或雙彎形等),就此賦予該金屬基體之該等邊緣區域任何適當橫截面形狀。舉例來說,該倒角可為該電子裝置外殼提供美學上及觸覺上令人愉悅的形貌。In one example, chamfers may be formed on sidewalls (eg, edge regions) of the metal substrate. In addition, the chamfer may have any suitable shape (eg, chamfer, round or double bend, etc.), thereby imparting any suitable cross-sectional shape to the edge regions of the metal substrate. For example, the chamfer can provide an aesthetically and tactilely pleasing topography to the electronic device housing.

在步驟208,該金屬基體之該暴露表面部分可經電清洗。在一範例中,電清洗該暴露表面部分可包括以一鹼性電解質溶液來鹼性電清洗該暴露表面部分。示例性鹼性電解質溶液可包括氫氧化鈉水溶液、氫氧化鉀水溶液或其組合。At step 208, the exposed surface portion of the metal substrate may be electrocleaned. In one example, electrocleaning the exposed surface portion may include alkaline electrocleaning the exposed surface portion with an alkaline electrolyte solution. Exemplary alkaline electrolyte solutions may include aqueous sodium hydroxide, aqueous potassium hydroxide, or combinations thereof.

在步驟210,電清洗該暴露表面部分後,即可在該暴露表面部分上施加一透明鈍化處理以形成一透明保護鈍化層。在一範例中,該透明鈍化處理的施加可藉由在該暴露表面部分上施加一鈍化溶液來進行,其中該鈍化溶液包括一錯合物,其係一金屬離子、一有機酸及一螯合劑的錯合物。示例性透明鈍化處理可於圖1中闡明。在步驟212,可在該透明保護鈍化層上施加電泳沉積以形成一電泳沉積層。該電泳沉積可為如下程序:將該金屬基體置於一流體中並施加一電位差以使該流體中之帶電粒子沉積在該透明保護鈍化層上。In step 210, after electrocleaning the exposed surface portion, a transparent passivation treatment may be applied to the exposed surface portion to form a transparent protective passivation layer. In one example, the application of the transparent passivation treatment can be performed by applying a passivation solution on the exposed surface portion, wherein the passivation solution includes a complex that is a metal ion, an organic acid, and a chelating agent the complex. An exemplary transparent passivation process can be illustrated in FIG. 1 . At step 212, electrophoretic deposition may be applied over the transparent protective passivation layer to form an electrophoretic deposition layer. The electrophoretic deposition may be a procedure of placing the metal substrate in a fluid and applying a potential difference to deposit charged particles in the fluid on the transparent protective passivation layer.

在一範例中,在該倒角邊緣區域上之電泳沉積層可包括一色彩其不同於形成在該金屬基體表面上之該氧化物層的色彩。在圖4中描繪具有在倒角邊緣區域上之色彩層的示例性殼體。In one example, the electrophoretically deposited layer on the chamfered edge region may include a color that is different from the color of the oxide layer formed on the surface of the metal substrate. An exemplary housing with a color layer on the chamfered edge region is depicted in FIG. 4 .

圖3為說明用於製造具有倒角邊緣之電子裝置外殼之又一示例性方法300的流程圖。在步驟302,一塗層可形成於一複合金屬基體上。示例性複合金屬基體可包括一金屬-塑膠複合基體、一金屬-碳纖維複合基體等。在一範例中,該塗層可形成在該複合金屬基體之一金屬層的表面上。示例性塗層可為一微弧氧化層、一鈍化層或一電泳沉積層。示例性微弧氧化層與鈍化層係描述於圖1中。示例性電泳沉積層可藉由在該金屬基體表面上施加一第一電泳沉積來形成。該第一電泳沉積可為如下程序:將該金屬基體置於一流體中並施加一電位差以使該流體中之帶電粒子沉積在該金屬基體上。FIG. 3 is a flowchart illustrating yet another exemplary method 300 for fabricating an electronic device housing with chamfered edges. At step 302, a coating may be formed on a composite metal substrate. Exemplary composite metal substrates may include a metal-plastic composite substrate, a metal-carbon fiber composite substrate, and the like. In one example, the coating may be formed on the surface of a metal layer of the composite metal matrix. Exemplary coatings may be a micro-arc oxide layer, a passivation layer, or an electrophoretic deposition layer. Exemplary micro-arc oxide and passivation layers are depicted in FIG. 1 . Exemplary electrophoretic deposition layers can be formed by applying a first electrophoretic deposition on the surface of the metal substrate. The first electrophoretic deposition may be a procedure of placing the metal substrate in a fluid and applying a potential difference to deposit charged particles in the fluid on the metal substrate.

在步驟304,可倒角該複合金屬基體之一邊緣區域以形成該複合金屬基體之一暴露表面部分。在一範例中,可在倒角該複合金屬基體之該邊緣區域前,在包括該塗層及一非金屬層之該複合金屬基體上施加一塗裝層。例如,該塗裝層可包括一粉末塗層、一底漆塗層、一基底塗層、一紫外線頂塗層或其任何組合。示例性塗裝層係描述於圖2與6中。At step 304, an edge region of the composite metal matrix may be chamfered to form an exposed surface portion of the composite metal matrix. In one example, a coating layer may be applied to the composite metal substrate including the coating and a non-metallic layer prior to chamfering the edge region of the composite metal substrate. For example, the finish can include a powder coat, a primer coat, a base coat, a UV top coat, or any combination thereof. Exemplary paint layers are depicted in FIGS. 2 and 6 .

在步驟306,該複合金屬基體之該暴露表面部分可經電清洗。在一範例中,電清洗該暴露表面部分可包括以一鹼性電解質溶液來鹼性電清洗該暴露表面部分。示例性鹼性電解質溶液可包括約2至10重量百分比之氫氧化鈉水溶液、氫氧化鉀水溶液或其組合。在步驟308,電清洗該暴露表面部分後,即可在該暴露表面部分上形成一透明保護鈍化層。At step 306, the exposed surface portion of the composite metal matrix may be electrocleaned. In one example, electrocleaning the exposed surface portion may include alkaline electrocleaning the exposed surface portion with an alkaline electrolyte solution. Exemplary alkaline electrolyte solutions may include about 2 to 10 weight percent aqueous sodium hydroxide, aqueous potassium hydroxide, or a combination thereof. In step 308, after electrocleaning the exposed surface portion, a transparent protective passivation layer can be formed on the exposed surface portion.

在步驟310,可在該透明保護鈍化層上形成一密封層。在一範例中,該密封層可利用一密封程序形成。舉例而言,密封程序可包括在約25℃至100℃之溫度下施加一密封材料,其含有約0.1-2重量百分比之表面活性劑。示例性密封材料可選自由氟化鋁、氟化鎳、氟化鈰、乙酸鈰、乙酸鋁及乙酸鎳所組成的群組。進一步地,該密封層可具有1-3µm範圍之厚度。因此,示例性密封程序可顯著地增強電子裝置殼體的耐腐蝕能力。在步驟312,可藉由施加一第二電泳沉積在該密封層上形成一色彩層。在一範例中,在該密封層上之該色彩層可具有一色彩其不同於形成在該複合金屬基體表面上之塗層色彩。在圖4中描繪在不同倒角邊緣區域上具有不同色彩層之示例性殼體。At step 310, a sealing layer may be formed on the transparent protective passivation layer. In one example, the sealing layer may be formed using a sealing process. For example, the sealing procedure may include applying a sealing material containing about 0.1-2 weight percent surfactant at a temperature of about 25°C to 100°C. Exemplary sealing materials can be selected from the group consisting of aluminum fluoride, nickel fluoride, cerium fluoride, cerium acetate, aluminum acetate, and nickel acetate. Further, the sealing layer may have a thickness in the range of 1-3 µm. Thus, the exemplary sealing procedure can significantly enhance the corrosion resistance of the electronic device housing. At step 312, a color layer may be formed on the sealing layer by applying a second electrophoretic deposition. In one example, the color layer on the sealing layer may have a color that is different from the color of the coating formed on the surface of the composite metal substrate. An exemplary housing with different color layers on different chamfered edge regions is depicted in FIG. 4 .

圖4繪示了一示例性電子裝置外殼或殼體400的俯視圖,其描繪倒角邊緣區域(例如402、404及406)。在圖4所示範例中,倒角邊緣區域402可對應於金屬基體408之外周緣,倒角邊緣區域404可對應於界定金屬基體408內之一指紋掃描器的邊界,而倒角邊緣區域406可對應於界定金屬基體408內之一觸控板的邊界。4 illustrates a top view of an exemplary electronic device housing or housing 400 depicting chamfered edge regions (eg, 402, 404, and 406). In the example shown in FIG. 4, chamfered edge region 402 may correspond to the outer perimeter of metal base 408, chamfered edge region 404 may correspond to a boundary defining a fingerprint scanner within metal base 408, and chamfered edge region 406 May correspond to a boundary defining a touchpad within metal matrix 408 .

在一範例中,該電泳沉積可提供在殼體400之倒角邊緣區域402、404及406的多色彩金屬光澤修整層。倒角邊緣區域402、404及406中之每一者可具有不同的色彩層,其係使用圖1至3中所述示例性方法形成。例如,該電泳沉積可在該配方中使用約0.3至15.0重量百分比之紅色染料(例如Alexa Fluor 594染料及德州紅(Texas Red))或紅色顏料(例如顏料紅168 MF),以在對應於側壁之倒角邊緣區域402上形成紅色金屬光澤。在另一範例中,該電泳沉積可在該配方中使用約0.3-15.0重量百分比之黃色染料(例如喹啉黃 WS)或黃色顏料(例如顏料黃191),以在例如對應於指紋掃描器之倒角邊緣區域404上形成黃色金屬光澤。類似地,透明金屬光澤可形成在對應於觸控板之倒角邊緣區域406上。因此,多個電泳沉積處理可施加在多個倒角邊緣區域以形成透明、半透明、閃亮、及不透明色彩。In one example, the electrophoretic deposition may provide a multi-colored metallic glossy finish on the chamfered edge regions 402 , 404 and 406 of the housing 400 . Each of the chamfered edge regions 402, 404, and 406 may have a different color layer formed using the exemplary methods described in FIGS. 1-3. For example, the electrophoretic deposition can use about 0.3 to 15.0 weight percent of red dyes (eg, Alexa Fluor 594 dyes and Texas Red) or red pigments (eg, Pigment Red 168 MF) in the formulation to create a surface corresponding to the sidewalls. A red metallic luster is formed on the chamfered edge region 402 . In another example, the electrophoretic deposition may use about 0.3-15.0 weight percent of a yellow dye (eg, Quinoline Yellow WS) or a yellow pigment (eg, Pigment Yellow 191) in the formulation, for example, in applications corresponding to fingerprint scanners. A yellow metallic luster is formed on the chamfered edge region 404 . Similarly, a transparent metallic sheen can be formed on the chamfered edge region 406 corresponding to the touchpad. Thus, multiple electrophoretic deposition processes can be applied to multiple chamfered edge regions to form transparent, translucent, shiny, and opaque colors.

圖5繪示用於在複合金屬基體之倒角邊緣區域上形成一透明保護鈍化層、一密封層及一電泳沉積層的示例性程序500。在步驟502,可預成形一金屬基體或金屬合金基體(例如,鎂合金基體)。例如,預成形該金屬合金基體可包括:將該金屬基體鍛造、模鑄或CNC切削成一所欲形狀,然後清潔該經鍛造、模鑄或CNC切削之金屬合金框架。該金屬基體之清潔可包括一預清潔程序,例如一鹼性清潔程序、除油清潔程序、一酸性清潔程序或其任何組合。FIG. 5 illustrates an exemplary process 500 for forming a transparent protective passivation layer, a sealing layer, and an electrophoretic deposition layer on the chamfered edge region of a composite metal substrate. At step 502, a metal substrate or metal alloy substrate (eg, a magnesium alloy substrate) may be preformed. For example, preforming the metal alloy matrix may include forging, die casting or CNC cutting the metal matrix into a desired shape and then cleaning the forged, die casting or CNC cutting metal alloy frame. Cleaning of the metal substrate may include a pre-cleaning procedure, such as an alkaline cleaning procedure, a degreasing cleaning procedure, an acid cleaning procedure, or any combination thereof.

在步驟504,可使用一嵌入成型程序在該金屬基體之一側上形成一塑膠層。示例性嵌入成型可指一塑膠注入模具之程序,且該模具內含預置之金屬基體。此外,可修整該塑膠層以移除延伸超出該金屬基體之額外塑膠材料以獲得一所欲形狀。At step 504, a plastic layer may be formed on one side of the metal substrate using an insert molding process. Exemplary insert molding may refer to a process in which plastic is injected into a mold containing a pre-set metal matrix. Additionally, the plastic layer can be trimmed to remove additional plastic material extending beyond the metal matrix to obtain a desired shape.

在步驟506,可在該金屬基體上施加一微弧氧化或第一鈍化處理以便在該金屬基體表面上形成一塗層。在一範例中,可形成該塗層以減少該金屬基體表面的化學反應性。在步驟508,可在包括該塗層之金屬基體上施加一底漆塗層。示例性底漆塗層可施加在該塗層及該塑膠層上。在步驟510,可在該底漆塗層上施加一基底塗層。在步驟512,可在該基底塗層上施加一紫外線頂塗層及一熱固化聚酯、丙烯酸系及聚胺甲酸酯頂塗層中之一者。一塗裝層係描述於圖2與6中。At step 506, a micro-arc oxidation or first passivation treatment may be applied to the metal substrate to form a coating on the surface of the metal substrate. In one example, the coating can be formed to reduce the chemical reactivity of the metal substrate surface. At step 508, a primer coating may be applied to the metal substrate including the coating. An exemplary primer coating can be applied over the coating and the plastic layer. At step 510, a base coat may be applied over the primer coat. At step 512, a UV topcoat and one of a thermally cured polyester, acrylic, and polyurethane topcoat may be applied over the basecoat. A coating layer is depicted in FIGS. 2 and 6 .

於步驟514,可倒角該金屬基體之一邊緣區域以形成該金屬基體之一暴露表面部分。在一範例中,可使用一CNC切削或一雷射雕刻程序等倒角該邊緣區域。在步驟516中,該暴露表面部分可藉一電清洗程序(即,電解清潔程序)來清潔。示例性電清洗係描述於圖1中。在步驟518,可藉由施加一透明鈍化處理而在該暴露表面部分上形成一第二透明保護鈍化層。在一範例中,可藉由施加一鈍化溶液而在該暴露表面部分上形成該透明保護鈍化層,該鈍化溶液包括一錯合物,其係一金屬離子、一有機酸及一螯合劑的錯合物。示例性透明保護鈍化層係敘明於圖1中。In step 514, an edge region of the metal substrate may be chamfered to form an exposed surface portion of the metal substrate. In one example, the edge region may be chamfered using a CNC cutting or a laser engraving procedure, or the like. In step 516, the exposed surface portion may be cleaned by an electrocleaning process (ie, an electrolytic cleaning process). An exemplary electrocleaning system is depicted in FIG. 1 . At step 518, a second transparent protective passivation layer may be formed on the exposed surface portion by applying a transparent passivation process. In one example, the transparent protective passivation layer can be formed on the exposed surface portion by applying a passivation solution that includes a complex that is a complex of a metal ion, an organic acid, and a chelating agent. compound. An exemplary transparent protective passivation layer is illustrated in FIG. 1 .

在步驟520,可在該透明保護鈍化層上形成一密封層。示例性密封層係敘明於圖3中。在步驟522,可藉由施加電泳沉積而在密封層上形成一電泳沉積層。該電泳沉積可包括與粒子組合的一聚合物,且該粒子選自於包括無機及金屬粒子之群組。At step 520, a sealing layer may be formed on the transparent protective passivation layer. Exemplary sealing layers are illustrated in FIG. 3 . At step 522, an electrophoretic deposition layer may be formed on the sealing layer by applying electrophoretic deposition. The electrophoretic deposition may include a polymer in combination with particles selected from the group comprising inorganic and metallic particles.

圖6繪示另一例示性程序600,其用於在一金屬基體之不同倒角區域上形成一透明保護鈍化層、一密封層及一電泳沉積層。在步驟602,可預成形一金屬基體或金屬合金基體(例如,鎂合金基體)。在步驟604,可使用一嵌入成型程序在該金屬基體之一側上形成一塑膠層。FIG. 6 shows another exemplary process 600 for forming a transparent protective passivation layer, a sealing layer, and an electrophoretic deposition layer on different chamfered regions of a metal substrate. At step 602, a metal substrate or metal alloy substrate (eg, a magnesium alloy substrate) may be preformed. At step 604, an insert molding process may be used to form a plastic layer on one side of the metal substrate.

在步驟606,可在該金屬基體上施加一微弧氧化處理或一鈍化處理以便在該金屬基體表面上形成一塗層。在步驟608,可在該塗層上施加一底漆塗層。例如,該底漆塗層可包括樹脂,諸如丙烯酸聚合物、聚胺甲酸酯、聚醯胺、氟聚合物、聚酯、環氧樹脂-聚酯及環氧樹脂等,且其可包含填料,諸如滑石、黏土、二氧化鈦、鋁粉、硫酸鋇、雲母、石墨烯、染料及有色顏料。該底漆塗層可具有在20至60µm之範圍內的厚度。在一範例中,施加該底漆塗層可包括:在該粉末塗層上施加聚胺甲酸酯混合物,接著在60至80℃之溫度下乾燥該聚胺甲酸酯混合物約15至40分鐘。該底漆塗層可具有在5至20µm之範圍內的厚度。At step 606, a micro-arc oxidation treatment or a passivation treatment may be applied to the metal substrate to form a coating on the surface of the metal substrate. At step 608, a primer coat may be applied over the coating. For example, the primer coating may include resins such as acrylic polymers, polyurethanes, polyamides, fluoropolymers, polyesters, epoxy-polyesters, and epoxy resins, and the like, and it may include fillers , such as talc, clay, titanium dioxide, aluminum powder, barium sulfate, mica, graphene, dyes and colored pigments. The primer coating may have a thickness in the range of 20 to 60 µm. In one example, applying the primer coat may include applying a polyurethane mixture over the powder coat, followed by drying the polyurethane mixture at a temperature of 60 to 80° C. for about 15 to 40 minutes . The primer coating may have a thickness in the range of 5 to 20 µm.

在步驟610,可在該底漆塗層上施加一基底塗層。例如,在該底漆塗層上施加該基底塗層可包括:施加聚胺甲酸酯、聚酯及/或聚丙烯與至少一顏料組合的混合物,該顏料係選自於由碳黑、二氧化鈦、黏土、雲母、滑石、硫酸鋇、碳酸鈣、合成顏料、金屬粉末、氧化鋁、一有機粉末、一無機粉末、塑膠珠、有色顏料及染料構成之群組;及接著在60至80℃之溫度下乾燥該混合物約15至40分鐘。該基底塗層可具有在10至20µm之範圍內的厚度。At step 610, a base coat may be applied over the primer coat. For example, applying the base coat over the primer coat may include applying a mixture of polyurethane, polyester and/or polypropylene in combination with at least one pigment selected from the group consisting of carbon black, titanium dioxide , clay, mica, talc, barium sulfate, calcium carbonate, synthetic pigments, metal powders, alumina, an organic powder, an inorganic powder, plastic beads, colored pigments and dyes; The mixture is dried at temperature for about 15 to 40 minutes. The base coat may have a thickness in the range of 10 to 20 µm.

在步驟612,可在該基底塗層上施加一紫外線頂塗層及一熱固化聚酯、丙烯酸系及聚胺甲酸酯頂塗層中之一者。例如,在該基底塗層上施加紫外線頂塗層可包括:施加一混合物,該混合物係選自於由聚丙烯酸類、聚胺甲酸酯、胺甲酸酯丙烯酸酯、丙烯酸系丙烯酸酯及環氧丙烯酸酯構成之群組;及接著在50至60℃之溫度下乾燥該混合物約10至15分鐘,然後進行範圍在700至1,200mJ/cm2 之紫外線曝光10至30秒。該紫外線頂塗層可具有在10至25µm之範圍內的厚度。示例性熱固化聚胺甲酸酯頂塗層可包括用於調製胺甲酸酯塗料之羥官能基丙烯酸系聚合物。At step 612, a UV topcoat and one of a thermally cured polyester, acrylic, and polyurethane topcoat may be applied over the basecoat. For example, applying a UV topcoat over the basecoat may include applying a mixture selected from the group consisting of polyacrylics, polyurethanes, urethane acrylates, acrylic acrylates, and cyclic oxyacrylate; and then drying the mixture at a temperature of 50 to 60° C. for about 10 to 15 minutes, followed by UV exposure in the range of 700 to 1,200 mJ/cm 2 for 10 to 30 seconds. The UV topcoat can have a thickness in the range of 10 to 25 µm. Exemplary thermally cured polyurethane topcoats can include hydroxy-functional acrylic polymers used to formulate urethane coatings.

在步驟614,可倒角該金屬基體之一第一邊緣區域以形成該金屬基體之一暴露表面部分。在步驟616,該暴露表面部分可藉電清洗來清潔。在步驟618,可藉由施加一第二透明鈍化處理而在該暴露表面部分上形成該透明保護鈍化層。At step 614, a first edge region of the metal substrate may be chamfered to form an exposed surface portion of the metal substrate. At step 616, the exposed surface portion may be cleaned by electrocleaning. At step 618, the transparent protective passivation layer may be formed on the exposed surface portion by applying a second transparent passivation process.

在步驟620,可在該透明保護鈍化層上形成該密封層。在步驟622,可藉由(例如在如圖4所示之倒角邊緣區域402)施加一第一電泳沉積而在該透明保護鈍化層上形成一第一色彩層。在步驟624、626、628、630及632,可重複步驟614、616、618、620及622所示程序以在一第二邊緣區域(例如在如圖4所示之倒角邊緣區域404)上形成一第二色彩層。該第二色彩層可與該第一色彩不同,且在方塊622之電泳沉積所用流體之配方可與在方塊632所用流體不同。At step 620, the sealing layer may be formed on the transparent protective passivation layer. At step 622, a first color layer may be formed on the transparent protective passivation layer by applying a first electrophoretic deposition (eg, in the chamfered edge region 402 as shown in FIG. 4). At steps 624, 626, 628, 630 and 632, the procedure shown in steps 614, 616, 618, 620 and 622 may be repeated for a second edge region (eg, the chamfered edge region 404 shown in FIG. 4). A second color layer is formed. The second color layer can be different from the first color, and the formulation of the fluid used in the electrophoretic deposition at block 622 can be different from the fluid used at block 632 .

圖7A繪示一示例性電子裝置外殼700之橫截面側視圖,描繪形成在倒角706上之一透明保護鈍化層708、一密封層710及一電泳沉積層712。示例性電子裝置外殼700可包括智慧型手機外殼、平板電腦或筆記型個人電腦外殼、數位相機外殼等。FIG. 7A shows a cross-sectional side view of an exemplary electronic device housing 700 depicting a transparent protective passivation layer 708 , a sealing layer 710 , and an electrophoretic deposition layer 712 formed on the chamfer 706 . Exemplary electronic device housings 700 may include smartphone housings, tablet or notebook PC housings, digital camera housings, and the like.

示例性電子裝置外殼700可包括形成在一複合金屬基體702之一第一表面上的一塗層704。在一範例中,塗層704可為一微弧氧化層、一鈍化層或一電泳沉積層。示例性第一表面可面向電子裝置外殼700的外部。Exemplary electronic device housing 700 may include a coating 704 formed on a first surface of a composite metal substrate 702 . In one example, the coating 704 may be a micro-arc oxide layer, a passivation layer, or an electrophoretic deposition layer. The exemplary first surface may face the exterior of the electronic device housing 700 .

另外,電子裝置外殼700可包括形成在複合金屬基體702之一邊緣區域上的倒角706。此外,電子裝置外殼700可包括形成在倒角706上之透明保護鈍化層708。此外,電子裝置外殼700可包括形成在透明保護鈍化層708上之密封層710。示例性密封層710可包括氟化鋁、氟化鎳、氟化鈰、乙酸鈰、乙酸鋁、乙酸鎳或其組合。Additionally, the electronic device housing 700 may include a chamfer 706 formed on an edge region of the composite metal matrix 702 . Additionally, the electronic device housing 700 may include a transparent protective passivation layer 708 formed on the chamfer 706 . Additionally, the electronic device housing 700 may include a sealing layer 710 formed on the transparent protective passivation layer 708 . Exemplary sealing layer 710 may include aluminum fluoride, nickel fluoride, cerium fluoride, cerium acetate, aluminum acetate, nickel acetate, or combinations thereof.

此外,電子裝置外殼700可包括形成在密封層710上之電泳沉積層712。在一範例中,電泳沉積層712可具有與塗層704之色彩不同的色彩。In addition, the electronic device housing 700 may include an electrophoretic deposition layer 712 formed on the sealing layer 710 . In one example, the electrophoretically deposited layer 712 may have a different color than the color of the coating 704 .

圖7B繪示圖7A之示例性電子裝置外殼700的橫截面側視圖,其描繪額外特徵。圖7B之類似命名的元件在功能及/或結構中可類似於圖7A中所述元件。如圖7B所示,複合金屬基體702可包括一金屬基體752及一形成在金屬基體752之第二表面上的非金屬層754。舉例來說,該第二表面可面向電子裝置外殼700的內部。示例性金屬基體752可包括鋁、鎂、鋁合金、鎂合金或其任何組合。示例性非金屬層754可包括塑膠、碳纖維複合材或其組合。7B depicts a cross-sectional side view of the exemplary electronic device housing 700 of FIG. 7A depicting additional features. The similarly named elements of Figure 7B may be similar in function and/or structure to the elements described in Figure 7A. As shown in FIG. 7B , the composite metal substrate 702 may include a metal substrate 752 and a non-metallic layer 754 formed on the second surface of the metal substrate 752 . For example, the second surface may face the interior of the electronic device housing 700 . Exemplary metal matrix 752 may include aluminum, magnesium, aluminum alloys, magnesium alloys, or any combination thereof. Exemplary non-metallic layers 754 may include plastic, carbon fiber composites, or combinations thereof.

依此方式,本文所述範例可提供用於電子裝置外殼之選擇性表面修整層以增強美感外觀。此外,本文所述範例可提供一可撓生產配置且對金屬基體沒有腐蝕顧慮。因此,本文所述範例可藉由在該金屬基體上提供具金屬光澤感之雙重表面修整形貌(例如,在不同倒角邊緣有不同色彩),而解決高反應性金屬表面問題。另外,本文所述範例可用以設計電子裝置外殼上之標誌。In this manner, the examples described herein can provide selective surface finish layers for electronic device housings to enhance aesthetic appearance. Furthermore, the examples described herein can provide a flexible production configuration without corrosion concerns for metal substrates. Thus, the examples described herein can solve the problem of highly reactive metal surfaces by providing a dual surface finish (eg, different colors at different chamfered edges) with a metallic sheen on the metal substrate. Additionally, the examples described herein can be used to design logos on electronic device housings.

以上所描述之範例係用於說明之目的。雖然以上範例係結合其示例性實作態樣加以描述,但仍可能有眾多並未實質背離本文所述標的之教示的修改方式。可在不背離本標的之精神下進行其他替代、修改及改變。此外,本說明書(包括任何隨附之申請專利範圍、摘要及圖式)中所揭露的特徵,及/或所揭任何方法或程序,可採任何組合方式來組合,除了有至少部份特徵互不相容的組合以外。The examples described above are for illustrative purposes. Although the above examples are described in conjunction with exemplary implementations thereof, numerous modifications are possible that do not materially depart from the subject teachings described herein. Other substitutions, modifications and changes may be made without departing from the spirit of this standard. Furthermore, the features disclosed in this specification (including any accompanying scope, abstract, and drawings), and/or any methods or procedures disclosed, may be combined in any combination, except that at least some of the features interact with each other. other than incompatible combinations.

在本文使用的「包括」、「具有」用語及其他變化型可具有與「包含」用語或其合適變化型相同的意義。此外,在本文使用的「基於」用語表示「至少部分基於」。因此,描述為基於一些刺激之一特徵可基於該刺激或包括該刺激之數種刺激的一組合。The terms "including", "having" and other variations as used herein may have the same meaning as the term "including" or suitable variations thereof. Furthermore, the term "based on" as used herein means "based at least in part on." Thus, a feature described as being based on some stimulus may be based on the stimulus or a combination of stimuli including the stimulus.

本說明書已參照前述範例來顯示和描述。然而,應理解的是,在不背離隨附請求項定義之本標的之精神和範疇下,可作出其他形式、細節和範例。This specification has been shown and described with reference to the foregoing examples. It should be understood, however, that other forms, details and examples may be made without departing from the spirit and scope of the subject matter as defined by the appended claims.

100,200,300:用於製造具有倒角邊緣之電子裝置外殼的方法 102,104,106,108,110,202,204,206,208,210,212,302,304,306,308,310,312,502,504,506,508,510,512,514,516,518,520,522,602,604,606,608,610,612,614,616,618,620,622,624,626,628,630,632:步驟,方塊 400:電子裝置外殼,殼體 402,404,406:倒角邊緣區域 408,752:金屬基體 500,600:程序 700:電子裝置外殼 702:複合金屬基體 704:塗層 706:倒角 708:透明保護鈍化層 710:密封層 712:電泳沉積層 754:非金屬層100,200,300: Method for manufacturing electronic device enclosures with chamfered edges 102,104,106,108,110,202,204,206,208,210,212,302,304,306,308,310,312,502,504,506,508,510,512,514,516,518,520,522,602,604,606,608,610,612,614,616,618,620,622,624,626,628,630,632:步驟,方塊 400: electronic device shell, shell 402, 404, 406: Chamfered edge area 408,752: Metal matrix 500,600: Procedure 700: Electronics enclosure 702: Composite metal matrix 704: Coating 706: Chamfer 708: Transparent protective passivation layer 710: Sealing layer 712: Electrophoretic deposition layer 754: Non-metallic layer

在後續的[實施方式]中會參照圖式說明範例,其中:Examples will be described with reference to the drawings in the subsequent [Embodiment], wherein:

圖1為說明用於製造具有倒角邊緣之電子裝置外殼的示例性方法之流程圖;1 is a flow chart illustrating an exemplary method for fabricating an electronic device housing with chamfered edges;

圖2為說明用於製造具有倒角邊緣之電子裝置外殼的另一示例性方法之流程圖;2 is a flow chart illustrating another exemplary method for fabricating an electronic device housing with chamfered edges;

圖3為說明用於製造具有倒角邊緣之電子裝置外殼之又一示例性方法的流程圖;3 is a flowchart illustrating yet another exemplary method for fabricating an electronic device housing with chamfered edges;

圖4繪示一描繪了倒角邊緣區域的示例性電子裝置外殼之俯視圖;4 depicts a top view of an exemplary electronic device housing depicting a chamfered edge region;

圖5與6繪示用於在複合金屬基體之倒角邊緣區域上形成一透明保護鈍化層、一密封層及一電泳沉積層的示例性程序;5 and 6 illustrate exemplary procedures for forming a transparent protective passivation layer, a sealing layer, and an electrophoretic deposition layer on the chamfered edge region of a composite metal substrate;

圖7A繪示一示例性電子裝置外殼之橫截面側視圖,描繪形成在倒角上之一透明保護鈍化層、一密封層及一色彩層;以及7A depicts a cross-sectional side view of an exemplary electronic device housing depicting a transparent protective passivation layer, a sealing layer, and a color layer formed on the chamfer; and

圖7B繪示圖7A之示例性電子裝置外殼的橫截面側視圖,其描繪額外特徵。7B depicts a cross-sectional side view of the exemplary electronic device housing of FIG. 7A depicting additional features.

100:用於製造具有倒角邊緣之電子裝置外殼的方法 100: Method for manufacturing electronic device housings with chamfered edges

102,104,106,108,110:步驟,方塊 102, 104, 106, 108, 110: steps, blocks

Claims (15)

一種用於製造一電子裝置外殼之方法,該方法包含: 在一金屬基體之一表面上形成一氧化物層; 倒角該金屬基體之一邊緣區域以形成該金屬基體之一暴露表面部分; 電清洗該金屬基體之該暴露表面部分; 電清洗該暴露表面部分後,即在該暴露表面部分上形成一透明保護鈍化層;以及 在該透明保護鈍化層上形成一電泳沉積層。A method for manufacturing an electronic device housing, the method comprising: forming an oxide layer on a surface of a metal substrate; chamfering an edge region of the metal substrate to form an exposed surface portion of the metal substrate; Electrocleaning the exposed surface portion of the metal substrate; After electrocleaning the exposed surface portion, a transparent protective passivation layer is formed on the exposed surface portion; and An electrophoretic deposition layer is formed on the transparent protective passivation layer. 如請求項1之方法,其中該金屬基體包含:鋁、鎂、鋰、鋅、鈦、鋁合金、鎂合金、鋰合金、鋅合金、鈦合金或其組合。The method of claim 1, wherein the metal matrix comprises: aluminum, magnesium, lithium, zinc, titanium, aluminum alloys, magnesium alloys, lithium alloys, zinc alloys, titanium alloys, or combinations thereof. 如請求項1之方法,其中該氧化物層係藉由在該金屬基體之表面上施加一微弧氧化處理及一第一鈍化處理中之一者而形成。The method of claim 1, wherein the oxide layer is formed by applying one of a micro-arc oxidation treatment and a first passivation treatment on the surface of the metal substrate. 如請求項1之方法,其中電清洗該暴露表面部分包含: 以一鹼性電解質溶液來鹼性電清洗該暴露表面部分。The method of claim 1, wherein electro-cleaning the exposed surface portion comprises: The exposed surface portion is alkaline electrocleaned with an alkaline electrolyte solution. 如請求項1之方法,其中該透明保護鈍化層係藉由在該暴露表面部分上施加一第二鈍化處理而形成,且其中施加該第二鈍化處理包含以一金屬離子、一有機酸及一螯合劑之一錯合物處理該暴露表面部分。The method of claim 1, wherein the transparent protective passivation layer is formed by applying a second passivation treatment on the exposed surface portion, and wherein applying the second passivation treatment comprises a metal ion, an organic acid, and a A complex of chelating agents treats the exposed surface portion. 一種用於製造一電子裝置外殼之方法,該方法包含: 在一金屬基體之一表面上形成一氧化物層; 在該氧化物層上施加一塗裝層; 藉由施加水性抗腐蝕切削用液以形成該金屬基體之一暴露表面部分來倒角該金屬基體之一邊緣區域; 電清洗該金屬基體之該暴露表面部分; 電清洗該暴露表面部分後,即在該暴露表面部分上施加一透明鈍化處理以形成一透明保護鈍化層;以及 在該透明保護鈍化層上施加一電泳沉積以形成一電泳沉積層。A method for manufacturing an electronic device housing, the method comprising: forming an oxide layer on a surface of a metal substrate; applying a coating on the oxide layer; chamfering an edge region of the metal substrate by applying an aqueous anti-corrosion cutting fluid to form an exposed surface portion of the metal substrate; Electrocleaning the exposed surface portion of the metal substrate; After electrocleaning the exposed surface portion, a transparent passivation treatment is applied on the exposed surface portion to form a transparent protective passivation layer; and An electrophoretic deposition is applied on the transparent protective passivation layer to form an electrophoretic deposition layer. 如請求項6之方法,其中在該氧化物層上施加該塗裝層係包含: 在包括該氧化物層之該金屬基體上施加一底漆塗層; 在該底漆塗層上施加一基底塗層;以及 在該基底塗層上施加一紫外線頂塗層及一熱固化聚酯、丙烯酸類樹脂及聚胺甲酸酯頂塗層中之一者。The method of claim 6, wherein applying the coating layer on the oxide layer comprises: applying a primer coating on the metal substrate including the oxide layer; applying a base coat over the primer coat; and A UV topcoat and one of a thermally cured polyester, acrylic, and polyurethane topcoat are applied over the basecoat. 如請求項6之方法,其中該水性抗腐蝕切削用液以重量百分比計包含以下組份: 醇類試劑5-40%; 有機胺3-15%; 羧酸鹽5-30%; 表面活性劑1-5%;以及 水55-85%。The method of claim 6, wherein the water-based anti-corrosion cutting fluid comprises the following components by weight: Alcohol reagent 5-40%; Organic amine 3-15%; Carboxylate 5-30%; Surfactant 1-5%; and Water 55-85%. 如請求項6之方法,其中電清洗該暴露表面部分包含: 以一鹼性電解質溶液來鹼性電清洗該暴露表面部分,其中該鹼性電解質溶液包含氫氧化鈉水溶液、氫氧化鉀水溶液或其組合。The method of claim 6, wherein electro-cleaning the exposed surface portion comprises: The exposed surface portion is alkaline electrocleaned with an alkaline electrolyte solution, wherein the alkaline electrolyte solution comprises aqueous sodium hydroxide solution, aqueous potassium hydroxide solution, or a combination thereof. 如請求項6之方法,其中該透明保護鈍化層上之該電泳沉積層具有一色彩,其不同於形成在該金屬基體表面上之該氧化物層的色彩。The method of claim 6, wherein the electrophoretic deposited layer on the transparent protective passivation layer has a color that is different from the color of the oxide layer formed on the surface of the metal substrate. 一種電子裝置外殼,其包含: 一塗層,其形成在一複合金屬基體之一第一表面上; 一倒角,其形成在該複合金屬基體之一邊緣區域上; 一透明保護鈍化層,其形成在該倒角上; 一密封層,其形成在該透明保護鈍化層上;以及 一電泳沉積層,其形成在該密封層上。An electronic device housing comprising: a coating formed on a first surface of a composite metal substrate; a chamfer formed on an edge region of the composite metal matrix; a transparent protective passivation layer formed on the chamfer; a sealing layer formed on the transparent protective passivation layer; and An electrophoretic deposition layer is formed on the sealing layer. 如請求項11之電子裝置外殼,其中該複合金屬基體包含: 一金屬基體;以及 一非金屬層,其形成在該金屬基體之一第二表面上,其中該第二表面係與該第一表面相對,且面向該電子裝置外殼之內部。The electronic device housing of claim 11, wherein the composite metal matrix comprises: a metal substrate; and A non-metal layer is formed on a second surface of the metal base, wherein the second surface is opposite to the first surface and faces the interior of the electronic device casing. 如請求項11之電子裝置外殼,其中該塗層為一微弧氧化層、一鈍化層、及一電泳沉積層中之一者。The electronic device casing of claim 11, wherein the coating is one of a micro-arc oxide layer, a passivation layer, and an electrophoretic deposition layer. 如請求項11之電子裝置外殼,其中該密封層包含氟化鋁、氟化鎳、氟化鈰、乙酸鈰、乙酸鋁、乙酸鎳或其組合。The electronic device housing of claim 11, wherein the sealing layer comprises aluminum fluoride, nickel fluoride, cerium fluoride, cerium acetate, aluminum acetate, nickel acetate, or a combination thereof. 如請求項11之電子裝置外殼,其中該電泳沉積層具有與該塗層之色彩不同的色彩。The electronic device housing of claim 11, wherein the electrophoretic deposition layer has a color different from that of the coating.
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