TWI532899B - Low density non-woven material useful with acoustic ceiling tile products and methods for forming acoustic ceiling tiles - Google Patents
Low density non-woven material useful with acoustic ceiling tile products and methods for forming acoustic ceiling tiles Download PDFInfo
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該領域係關於一種不織布材料,且詳言之,係關於有效提供適於用作隔音天花板瓷磚之隔熱及隔音作用的低密度不織布材料。This field relates to a nonwoven material and, in particular, to a low density nonwoven fabric material effective to provide insulation and sound insulation suitable for use as a soundproof ceiling tile.
習知隔音天花板瓷磚為不織布結構,其包括由組合成型為天花板瓷磚結構之基質纖維、填充劑及黏合劑構成之核心。基質纖維通常為礦棉或玻璃纖維。填充劑可為珍珠岩、黏土、碳酸鈣、纖維素纖維及其類似物。黏合劑典型地為纖維素纖維、澱粉、乳膠及其類似物。乾燥後,黏合劑即與基質纖維及填充劑形成黏合以形成纖維網狀物,其提供瓷磚結構剛性且形成吸音之多孔結構。為用作典型天花板瓷磚,不織布結構或基質墊應為實質上平坦且自撐的以便懸浮於典型天花板瓷磚柵格或類似結構中。Conventional acoustical ceiling tiles are non-woven structures that include the core of matrix fibers, fillers, and adhesives that are combined into a ceiling tile structure. The matrix fibers are typically mineral wool or fiberglass. The filler may be perlite, clay, calcium carbonate, cellulose fibers, and the like. The binder is typically cellulosic fibers, starch, latex and the like. After drying, the binder forms a bond with the matrix fibers and filler to form a fibrous web that provides a porous structure in which the tile structure is rigid and forms a sound absorbing structure. For use as a typical ceiling tile, the nonwoven structure or substrate mat should be substantially flat and self-supporting for suspension in a typical ceiling tile grid or similar structure.
對於適於隔音天花板瓷磚應用之不織布結構而言,不織布結構亦需符合關於噪音降低及防火等級之各種工業標準及建築規範。舉例而言,工業標準需要天花板瓷磚具有根據ASTM E84之A級防火等級,其通常需要小於25之火焰蔓延指數(flame spread index)及小於50之煙氣發生指數(smoke development index)。關於噪音降低,工業標準典型地需要隔音天花板瓷磚具有根據ASTM C423至少為約0.55之噪音降低係數(noise reduction coefficient,NRC)。For non-woven structures suitable for soundproof ceiling tile applications, the non-woven structure also meets various industry standards and building codes for noise reduction and fire rating. For example, industry standards require ceiling tiles to have a Class A fire rating according to ASTM E84, which typically requires a flame spread index of less than 25 and a smoke development index of less than 50. Regarding noise reduction, industry standards typically require soundproof ceiling tiles having a noise reduction coefficient (NRC) of at least about 0.55 in accordance with ASTM C423.
隔音天花板瓷磚通常經由濕式佈層(wet-laid)製程形成,該製程使用水性介質輸送瓷磚組分且使其成型為所需結構。基本過程涉及首先將各種瓷磚成分摻合至水性漿料中,將漿料輸送至高位調漿箱(head box)成型台,且經由移動的多孔絲網將漿料分配至具有所需尺寸及厚度之均勻墊中。移除水且接著乾燥該墊。經乾燥之墊可藉由開槽、衝壓、塗佈及/或層壓表面修整至瓷磚而修整為天花板瓷磚結構。在濕式佈層製程中,水充當各種瓷磚成分之輸送介質。然而,雖然便利於高製造速度、及使用低成本原料(例如,再循環新聞紙纖維、再循環瓦楞紙、廢聚酯纖維、棉絨、廢織物及其類似物)之能力,但使用水製造隔音天花板瓷磚亦呈現許多缺點,使得該製程及所形成之產品較不合乎需要。Sound-insulating ceiling tiles are typically formed via a wet-laid process that uses an aqueous medium to transport the tile components and shape them into the desired structure. The basic process involves first blending various tile components into an aqueous slurry, delivering the slurry to a high head box forming station, and dispensing the slurry to a desired size and thickness via a moving porous screen. Uniform pad. The water is removed and the pad is then dried. The dried mat can be trimmed to a ceiling tile structure by grooving, stamping, coating, and/or laminating the surface to the tile. In a wet lay-up process, water acts as a transport medium for various tile components. However, while facilitating high manufacturing speeds and the ability to use low cost materials (eg, recycled newsprint fibers, recycled corrugated paper, waste polyester fibers, cotton linters, waste fabrics, and the like), the use of water to make soundproof ceilings Tiles also present a number of disadvantages that make the process and the resulting product less desirable.
濕式佈層製程使用大量水輸送組分且使其成型為天花板瓷磚結構。最終必須自產品移除大量水。因此,大多數濕式製程提供藉由自由或重力排水、高真空及低真空、壓縮及蒸發中之一或多個步驟進行水移除。令人遺憾的是,此等製程步驟需要較大能量需求來輸送及移除水。因此,處置大量水以形成瓷磚以及隨後移除及蒸發水可提供典型濕式佈層製程,其由於高設備及操作成本而相對昂貴。The wet cloth process uses a large amount of water to transport the components and shape them into a ceiling tile structure. Ultimately, a large amount of water must be removed from the product. Thus, most wet processes provide for water removal by one or more of free or gravity drainage, high vacuum and low vacuum, compression, and evaporation. Unfortunately, these process steps require greater energy requirements to transport and remove water. Thus, disposal of large amounts of water to form tiles and subsequent removal and evaporation of water can provide a typical wet-laid process that is relatively expensive due to high equipment and operating costs.
亦難以使用濕式佈層製程形成具有高吸音性質之隔音天花板瓷磚。在濕式佈層製程中,所形成之天花板瓷磚由於濕式佈層調配物中之成分的性質而趨向於具有密封表面。具有密封表面之天花板瓷磚通常具有有效性較低的聲屏障,因為瓷磚之多孔性較低,此使得瓷磚吸音之能力較差。密封之瓷磚表面可實際上反射聲音,此為隔音天花板瓷磚之非所需特徵。It is also difficult to form a soundproof ceiling tile having a high sound absorbing property using a wet cloth process. In a wet layup process, the resulting ceiling tile tends to have a sealed surface due to the nature of the ingredients in the wet laydown formulation. Ceiling tiles with a sealed surface typically have a less effective sound barrier because of the lower porosity of the tiles, which makes the tiles less able to absorb sound. The sealed tile surface can actually reflect sound, which is an undesirable feature of the acoustic ceiling tile.
咸信此等非所需隔音特徵由濕式佈層製程中典型地使用之瓷磚成分的親水性引起。常用作天花板瓷磚中之低成本黏合劑及填充劑的纖維素纖維(例如再循環新聞紙)具有高度親水性且吸收大量水。部分地由於該等親水性組分,濕式佈層瓷磚典型地具有約65%至約75%之高初始水分含量(亦即,在即將進入乾燥箱或乾燥室之前板之水分含量),此會增加乾燥期間對蒸發之需求。因此,在乾燥期間,由於自此等親水性組分移除水而在瓷磚成分上產生高表面張力。水為一種極性分子,賦予其他組分表面張力。此表面張力通常引起瓷磚表面由多孔性較低之結構密封。咸信在製程中表面張力將瓷磚中之組成部分拉得更靠攏,從而使結構緻密並閉合瓷磚孔隙。因此,濕式佈層製造之天花板瓷磚需要進一步處理以在瓷磚中打孔,以便達成可接受之噪音降低。因此,雖然濕式佈層製程可能由於製造速度增加及使用低成本材料之能力而為可接受的,但當隔音特徵為產品所需時,使用水作為輸送介質使得該製程及所得產品之成本效率較低。It is believed that these undesirable sound-insulating features are caused by the hydrophilicity of the tile components typically used in wet-laid processes. Cellulosic fibers (such as recycled newsprint), often used as low cost binders and fillers in ceiling tiles, are highly hydrophilic and absorb large amounts of water. Partly due to the hydrophilic components, the wet cloth tile typically has a high initial moisture content of from about 65% to about 75% (i.e., the moisture content of the plate just prior to entering the drying or drying chamber). It will increase the need for evaporation during drying. Therefore, during drying, high surface tension is generated on the tile composition due to the removal of water from the hydrophilic components. Water is a polar molecule that imparts surface tension to other components. This surface tension typically causes the tile surface to be sealed by a less porous structure. In the process, the surface tension pulls the components in the tile closer together, thereby making the structure dense and closing the tile pores. Therefore, wet tile-made ceiling tiles require further processing to perforate the tiles to achieve acceptable noise reduction. Thus, while wet lay-up processes may be acceptable due to increased manufacturing speed and the ability to use low cost materials, the use of water as the transport medium makes the process and the resulting product cost effective when the sound-damping feature is required for the product. Lower.
在一些情況下,乳膠黏合劑亦可用於隔音天花板瓷磚中且常常為使用礦棉作為基質纖維之濕式佈層製程中的首選。然而,乳膠通常為天花板瓷磚調配物中所用之最昂貴成分;因此,希望限制此相對較高成本成分之使用。常用於天花板瓷磚中之其他黏合劑為澱粉及如上文所述之纖維素纖維。然而,澱粉及纖維素具有親水性且在處理期間趨向於吸水並產生上述高表面張力問題。In some cases, latex adhesives can also be used in acoustical ceiling tiles and are often preferred in wet-laid processes using mineral wool as a matrix fiber. However, latex is often the most expensive ingredient used in ceiling tile formulations; therefore, it is desirable to limit the use of this relatively high cost component. Other binders commonly used in ceiling tiles are starch and cellulosic fibers as described above. However, starch and cellulose are hydrophilic and tend to absorb water during processing and create the aforementioned high surface tension problems.
使用濕式佈層製程製造之隔音天花板瓷磚的常見缺點為,該等所形成之瓷磚通常經由上述機制而導致較高密度。高密度常常會導致高氣流阻力,此會損害吸音作用。典型地,以習知配方製造之瓷磚的密度為約12 lbs/ft3至約20 lbs/ft3,視其組成而定。其亦具有約0.55至約0.80之噪音降低係數(NRC),視特定組成而定。對於具有類似組成之基質墊而言,較低密度通常導致較低氣流阻力或較高孔隙率,由此改良吸音作用。然而,若組成不同,則密度與孔隙率之相關性未必如上文所述。A common disadvantage of sound-insulating ceiling tiles made using a wet lay-up process is that the tiles formed are typically resulting in higher densities via the mechanisms described above. High density often results in high airflow resistance, which can impair sound absorption. Typically, tiles made in conventional formulations have a density of from about 12 lbs/ft 3 to about 20 lbs/ft 3 , depending on the composition. It also has a noise reduction factor (NRC) of from about 0.55 to about 0.80, depending on the particular composition. For matrix mats having similar compositions, lower densities typically result in lower airflow resistance or higher porosity, thereby improving sound absorption. However, if the composition is different, the correlation between density and porosity is not necessarily as described above.
已開發替代黏合纖維,但該等替代纖維仍使用親水性組分製造而成且因此將展現與現有天花板瓷磚成分中所見相同之缺點。舉例而言,美國專利第6,818,295號及第6,946,506號及美國公開案第2005/0026529號描述一種上方具有複數個微原纖維之微細纖維。此等參考文獻之發明者表明微原纖維在機械方面增強不織布材料以提供改良之抗張強度。然而,此等參考文獻中之纖維仍使用澱粉基質構成,該基質提供天然聚合物將各組分結合在一起。在此等情況下,因為澱粉使得任何所形成之材料均為生物可降解的,故其為重要的。然而,若使用此等參考文獻中所述之澱粉形成天花板瓷磚,則所形成之瓷磚將因澱粉之親水性而展現與濕式佈層瓷磚中所見相同之缺點。亦即,如上文所述,預期澱粉基質將在水移除期間形成高表面張力且趨向於形成密封表面,從而降低瓷磚吸音之能力。此等參考文獻進一步表明,可自纖維結構移除澱粉基質且僅使用微原纖維。然而,在此情況下,若天花板瓷磚中僅使用個別微原纖維而不利用基質纖維結構的優點,則該等微原纖維不會提供足以充當天花板瓷磚結構中之有效黏合劑的黏合基質及強度。Alternative adhesive fibers have been developed, but such replacement fibers are still made using hydrophilic components and will therefore exhibit the same disadvantages as seen in existing ceiling tile compositions. For example, U.S. Patent Nos. 6,818,295 and 6,946,506, and U.S. Pat. The inventors of these references indicate that microfibrils mechanically reinforce nonwoven materials to provide improved tensile strength. However, the fibers in these references still consist of a starch matrix that provides a natural polymer to bind the components together. In such cases, it is important because the starch makes any of the materials formed biodegradable. However, if the starch described in these references is used to form a ceiling tile, the resulting tile will exhibit the same disadvantages as seen in wet tile tiles due to the hydrophilicity of the starch. That is, as described above, it is contemplated that the starch matrix will form a high surface tension during water removal and tend to form a sealing surface, thereby reducing the ability of the tile to absorb sound. These references further indicate that the starch matrix can be removed from the fibrous structure and only microfibrils are used. However, in this case, if only the individual microfibrils are used in the ceiling tile without taking advantage of the matrix fiber structure, the microfibrils do not provide an adhesive matrix and strength sufficient to serve as an effective binder in the ceiling tile structure. .
因此,需要一種具有最少親水性組分之低密度不織布結構,其為平坦的,自撐的,且在工業標準下適用於符合使用者對於手動可切性之期望的隔音天花板瓷磚(亦即,熱性質與聲學性質)。Accordingly, there is a need for a low density nonwoven structure having minimal hydrophilic components that is flat, self-supporting, and that is suitable for use in industrial standards for soundproof ceiling tiles that meet the user's desire for manual cuttability (ie, Thermal properties and acoustic properties).
一般而言,提供一種包括無機基質纖維及合成熱黏合纖維之低密度不織布材料。藉由一種方法,該低密度不織布材料能夠成型為具有足以提供實質上平坦、剛性且自撐的材料之預定基本重量及低密度的核心或基質墊,該實質上平坦、剛性且自撐的材料能夠提供足以用作隔音天花板瓷磚之熱特徵與聲音特徵。本文中所用之術語平坦(flat)或平坦度(flatness)意謂當將2 ft長的面板置於柵格上時中間之撓曲度。舉例而言,實質上平坦的面板可具有約0.25吋或更小之撓曲度。如本發明中所使用,「低密度(low density)」通常指約10 lbs/ft3(pcf)或更小,且通常在約7 pcf至約13 pcf之範圍內。又,如本發明中所論述,「孔隙率(porosity)」由氣流阻力定量且可根據ASTM C423及C386進行測試。另外,本發明預期使用本文所述之製程製造之瓷磚的較佳厚度通常在約0.5吋至約1.0吋之範圍內。In general, a low density nonwoven material comprising an inorganic matrix fiber and a synthetic heat bonding fiber is provided. By one method, the low density nonwoven material can be formed into a core or matrix mat having a predetermined basis weight and a low density sufficient to provide a substantially flat, rigid and self-supporting material, the substantially flat, rigid and self-supporting material It is capable of providing thermal and acoustic features sufficient for use as a soundproof ceiling tile. The term flat or flatness as used herein means the degree of deflection in the middle when a 2 ft long panel is placed on a grid. For example, a substantially flat panel can have a degree of deflection of about 0.25 吋 or less. As used herein, "low density" generally refers to about 10 lbs/ft 3 (pcf) or less, and typically ranges from about 7 pcf to about 13 pcf. Again, as discussed in the present invention, "porosity" is quantified by airflow resistance and can be tested in accordance with ASTM C423 and C386. In addition, the present invention contemplates that the preferred thickness of the tile produced using the processes described herein will generally be in the range of from about 0.5 Torr to about 1.0 Torr.
舉例而言,不織布材料能夠形成實質上平坦、自撐、抗下垂的核心,該核心展現根據ASTM C423至少為約0.55之噪音降低係數及A級防火等級,根據ASTM E84,其火焰蔓延指數為約25或更小且煙氣發生指數為約50或更小。即使具有低密度,核心亦較佳展現高撓曲強度,但仍可手動切割,諸如使用普通美工刀以輕微或最小壓力切割。For example, the nonwoven material can form a substantially flat, self-supporting, sagging-resistant core that exhibits a noise reduction factor of at least about 0.55 and a Class A fire rating according to ASTM C423, which has a flame spread index of about ASTM E84. 25 or less and the smoke generation index is about 50 or less. Even with a low density, the core preferably exhibits high flexural strength, but can still be manually cut, such as using a conventional utility knife to cut with a slight or minimal pressure.
在各種具體實例中,無機基質纖維較佳為礦棉、渣棉、石棉或其混合物,其渣球含量較佳為最多約60重量%且最佳為約10重量%至約45重量%。如本文中所使用,礦棉渣球通常指礦棉製造製程之副產物,其包含直徑在約50微米至約500微米範圍內之非纖維礦物質微粒。適合之無機基質纖維為Thermafiber FRF牌纖維(USG Interiors公司,Chicago,Illinois);然而,亦可使用其他無機基質纖維,諸如玻璃纖維及其類似物。較佳地,無機纖維之平均長度為約0.1 mm至約4 mm且平均直徑為約1微米至約15微米。藉由一種方法,不織布材料之核心包括以重量計約30%至約95%之石棉或渣棉。In various embodiments, the inorganic matrix fibers are preferably mineral wool, slag wool, asbestos or mixtures thereof, preferably having a slag content of up to about 60% by weight and most preferably from about 10% to about 45% by weight. As used herein, mineral wool slag balls generally refer to by-products of the mineral wool manufacturing process comprising non-fibrous mineral particles having a diameter ranging from about 50 microns to about 500 microns. Suitable inorganic matrix fibers are Thermafiber FRF brand fibers (USG Interiors, Inc., Chicago, Illinois); however, other inorganic matrix fibers such as glass fibers and the like can also be used. Preferably, the inorganic fibers have an average length of from about 0.1 mm to about 4 mm and an average diameter of from about 1 micron to about 15 microns. By one method, the core of the nonwoven material comprises from about 30% to about 95% by weight of asbestos or slag wool.
在各種具體實例中,合成熱黏合纖維較佳為單組分或雙組分合成纖維,當加熱至適當溫度時,其熔化或與周圍材料黏合。較佳地,不織布合成材料包括以重量計約0.1%至約50%,且最佳為約1%至約25%之合成單組分或雙組分纖維。如本文中所使用,「合成(synthetic)」指使用非天然來源之組分製造的纖維。舉例而言,合成熱黏合纖維較佳由聚丙烯酸系物、乙烯乙酸乙烯酯、聚酯、聚烯烴、聚醯胺、酚-甲醛、聚乙烯醇、聚氯乙烯或其混合物構成。此等材料之熔點通常為約100℃至約250℃。某些可使用之合成熱黏合纖維由聚烯烴樹脂構成且至少一種組分展現約125℃至約136℃之熔點。亦可使用由除聚烯烴樹脂外之材料構成的纖維且該等纖維可提供諸如強度之良好性質,但可能較為昂貴。In various embodiments, the synthetic heat-bonded fibers are preferably one-component or two-component synthetic fibers that, when heated to a suitable temperature, melt or adhere to the surrounding material. Preferably, the nonwoven composite material comprises from about 0.1% to about 50% by weight, and most preferably from about 1% to about 25%, by weight of the synthetic one-component or bicomponent fibers. As used herein, "synthetic" refers to fibers made using components of non-natural origin. For example, the synthetic heat-bonded fiber is preferably composed of a polyacrylic acid, ethylene vinyl acetate, polyester, polyolefin, polyamine, phenol-formaldehyde, polyvinyl alcohol, polyvinyl chloride or a mixture thereof. The melting point of such materials is typically from about 100 °C to about 250 °C. Some of the synthetic heat-bondable fibers that can be used are composed of a polyolefin resin and at least one component exhibits a melting point of from about 125 ° C to about 136 ° C. Fibers composed of materials other than polyolefin resins can also be used and such fibers can provide good properties such as strength, but can be relatively expensive.
藉由一種方法,較佳之合成熱黏合纖維通常為非生物可降解的且基本上不含澱粉、蛋白質及其他天然存在之聚合物,此等物質大部分具有親水性且將導致先前技術纖維中所見的非所需表面張力性質。如下文進一步論述,本文中之合成熱黏合纖維通常保留疏水性,即使處理成具有親水性表面以改良分散穩定性。By one method, the preferred synthetic heat-bonded fibers are generally non-biodegradable and substantially free of starch, protein, and other naturally occurring polymers, most of which are hydrophilic and will result in what is seen in prior art fibers. Undesired surface tension properties. As discussed further below, the synthetic heat-bonded fibers herein generally retain hydrophobicity even when treated to have a hydrophilic surface to improve dispersion stability.
較佳之合成熱黏合纖維具有與纖維長度及直徑有關之高表面積以便提供高黏合表面積。舉例而言,較佳之合成黏合纖維之平均長度小於3 mm(較佳為約0.1 mm至約3 mm),平均直徑小於50微米(較佳為約5微米至約30微米),但具有大於約0.5平方公尺/公克且較佳介於約1平方公尺/公克與約12平方公尺/公克之間的大表面積。該表面積比市售單組分或雙組分熱黏合纖維大約一個至兩個量級,該等市售單組分或雙組分熱黏合纖維在1至6丹尼爾(denier)之纖維下通常具有約0.1平方公尺/公克至約0.4平方公尺/公克之表面積。Preferred synthetic heat bonded fibers have a high surface area associated with fiber length and diameter to provide a high bond surface area. For example, preferred synthetic binder fibers have an average length of less than 3 mm (preferably from about 0.1 mm to about 3 mm), an average diameter of less than 50 microns (preferably from about 5 microns to about 30 microns), but greater than about A large surface area of between 0.5 square meters per gram and preferably between about 1 square meter per gram and about 12 square meters per gram. The surface area is on the order of one to two orders of magnitude greater than the commercially available one-component or two-component heat-bonded fibers, which typically have from 1 to 6 denier fibers. A surface area of from about 0.1 square meters per gram to about 0.4 square meters per gram.
下表1展示標準市售未原纖化纖維以丹尼爾及密度計的一系列表面積。舉例而言,如圖表中所示,若纖維具有3丹尼爾長絲且密度為0.95 g/cm3,則標準未原纖化合成纖維之表面積將為0.199 m2/g。Table 1 below shows a range of surface areas of standard commercially available unfibrillated fibers in denier and densitometer. For example, as shown in the graph, if the fiber has 3 denier filaments and the density is 0.95 g/cm 3 , the surface area of the standard unfibrillated synthetic fiber will be 0.199 m 2 /g.
為達成該與纖維長度及直徑有關之高表面積,本文中之纖維較佳規定細長纖維基質或主體及許多自該細長纖維基質的外表面向外延伸之微分支或微原纖維,或微原纖維簇。舉例而言,單纖維可規定許多微原纖維,其直徑各為約0.1微米至約10微米。適合之高表面積原纖化纖維可獲自Mitsui Chemicals America(Rye Brook,New York)或Minifibers(Johnson City,Tennessee)。To achieve this high surface area associated with fiber length and diameter, the fibers herein preferably define an elongated fibrous matrix or body and a plurality of microbranches or microfibrils extending outwardly from the outer surface of the elongated fibrous substrate, or microfibril clusters. . For example, a single fiber can define a plurality of microfibrils each having a diameter of from about 0.1 microns to about 10 microns. Suitable high surface area fibrillated fibers are available from Mitsui Chemicals America (Rye Brook, New York) or Minifibers (Johnson City, Tennessee).
在較佳具體實例中,合成熱黏合纖維較佳具有疏水性,且因此通常不會導致先前技術濕式佈層形成之天花板瓷磚中所見的在乾燥期間之表面張力增加。較佳具體實例之合成熱黏合纖維形成通常多孔且膨鬆的結構,該結構能夠在低密度下提供所需之聲音降低特徵。咸信所得結構多孔性較高之一個原因在於與有較多纖維素之結構相比,當有疏水性較高之熱黏合纖維時,存在較少氫鍵。另一方面,原纖化合成纖維之高表面積使得黏合位點增加,從而改良強度而不損害可切性。In a preferred embodiment, the synthetic heat-bonded fibers are preferably hydrophobic, and thus generally do not result in an increase in surface tension during drying as seen in ceiling tiles of prior art wet-laid formations. The synthetic heat-bonded fibers of the preferred embodiment form a generally porous and bulky structure that provides the desired sound-reducing features at low densities. One reason for the higher porosity of the structure obtained by the salty letter is that there are fewer hydrogen bonds when there is a highly hydrophobic heat-bonding fiber than a structure having more cellulose. On the other hand, the high surface area of the fibrillated synthetic fibers increases the bonding sites, thereby improving the strength without impairing the cuttability.
在一些情況下,合成纖維之疏水性使其難以分散於水性漿料中。為改良分散穩定性,合成熱黏合纖維亦可經表面處理以使得外表面或外表面之一部分具有親水性。為使得外表面具有親水性,纖維製造商在用於形成纖維之聚合物中引入某些親水性官能基,諸如羧基(-COOH)或羥基(-OH)。在親水性外表面之情況下,合成熱黏合纖維在水性漿料中通常較為穩定。In some cases, the hydrophobic nature of the synthetic fibers makes it difficult to disperse in the aqueous slurry. To improve dispersion stability, the synthetic heat-bonded fibers may also be surface treated such that one of the outer or outer surfaces is hydrophilic. To make the outer surface hydrophilic, fiber manufacturers introduce certain hydrophilic functional groups, such as carboxyl (-COOH) or hydroxyl (-OH), into the polymer used to form the fibers. In the case of a hydrophilic outer surface, the synthetic heat-bonded fibers are generally relatively stable in aqueous slurries.
本文中之不織布材料通常產生至少0.55及更大之所要噪音降低係數。咸信至少兩種機制可負責約7至13 pcf之核心密度下的噪音降低特徵。首先,如上文所述,較佳之合成熱黏合纖維具有疏水性,此降低乾燥期間核心之表面張力。因此,疏水性纖維通常避免所形成核心的表面及主體中發生孔隙閉合,而此問題在先前技術之親水性纖維中會發生。另外,亦已觀察到,即使將纖維處理成具有親水性表面,合成原纖化熱黏合纖維總體上仍展現疏水性性質以降低乾燥後之表面張力。The nonwoven material herein generally produces a desired noise reduction factor of at least 0.55 and greater. At least two mechanisms are responsible for the noise reduction characteristics at a core density of about 7 to 13 pcf. First, as described above, the preferred synthetic heat-bonded fibers are hydrophobic, which reduces the surface tension of the core during drying. Thus, hydrophobic fibers generally avoid pore closure in the surface and body of the core being formed, and this problem can occur in prior art hydrophilic fibers. In addition, it has also been observed that even if the fibers are treated to have a hydrophilic surface, the synthetic fibrillated heat-bonded fibers generally exhibit hydrophobic properties to reduce the surface tension after drying.
咸信經親水性處理之纖維仍在乾燥期間展現疏水性傾向,因為經處理之纖維具有恰好足夠的連接於疏水性聚合物鏈之親水性官能基,使得其可懸浮於水中且與其他成分一起分散。然而,此等纖維整體仍具有疏水性,且其具有極低吸水性。當聚合物熔化時,其不會失去此等基團,因此保留疏水性傾向。The hydrophilically treated fiber still exhibits a hydrophobic tendency during drying because the treated fiber has just enough hydrophilic functional groups attached to the hydrophobic polymer chain so that it can be suspended in water and together with other ingredients. dispersion. However, these fibers as a whole are still hydrophobic and have extremely low water absorption. When the polymer melts, it does not lose these groups and therefore retains a hydrophobic tendency.
其次,合成熱黏合纖維之至少一部分係設定成在預定溫度下熔化,其中基質纖維與其他核心組分結合在一起。在原纖化合成熱黏合纖維之情況下,在此預定熔化溫度之前,任何核心組分之間較佳無黏合。因此,咸信即使利用濕式佈層製程,無機基質纖維及其他成分通常仍將呈現如空氣佈層製程中所見之更天然/膨鬆的組態或形式。詳言之,在使用礦棉之無機基質纖維的情況下,所形成之墊通常變得極其龐大或膨鬆,因為此等纖維相對較硬且形成膨鬆結構。因此,一旦乾燥後核心最後達到合成黏合纖維之熔點,則黏合材料會使硬礦棉之基質熔合至此膨鬆結構中。冷卻後,原纖化合成黏合纖維即固定瓷磚組分且使瓷磚具有剛性,同時具有膨鬆結構。因為合成纖維不展現先前技術黏合劑之增加的表面張力,故所形成之膨鬆結構通常保持原樣而不會因水蒸發所引起之表面張力而變緻密。Second, at least a portion of the synthetic heat-bonded fibers are set to melt at a predetermined temperature, wherein the matrix fibers are combined with other core components. In the case of fibrillated synthetic heat-bonded fibers, it is preferred that there is no bond between any of the core components prior to the predetermined melting temperature. Therefore, even with the wet-laid process, the inorganic matrix fibers and other components will generally exhibit a more natural/bulk configuration or form as seen in the air-laid process. In particular, in the case of inorganic matrix fibers using mineral wool, the mats formed generally become extremely bulky or bulky because the fibers are relatively hard and form a bulky structure. Therefore, once the core finally reaches the melting point of the synthetic binder fiber after drying, the binder will fuse the matrix of the hard mineral wool into the bulk structure. After cooling, the fibrillated synthetic binder fibers fix the tile components and impart rigidity to the tile while having a bulky structure. Because synthetic fibers do not exhibit the increased surface tension of prior art adhesives, the resulting bulky structure is typically left intact without densification due to surface tension caused by water evaporation.
視情況,不織布核心可包括其他組分。舉例而言,核心可按需要包括其他填充劑,諸如纖維素纖維(亦即新聞紙)、碳酸鈣、珍珠岩、玻璃珠、黏土、粒狀物、軟木及其類似物。若想要時,亦可將諸如沸石、活性碳及其類似物之功能化學品添加至基質墊中以通常提供空氣淨化能力。除無機基質纖維及合成熱黏合纖維外,核心亦可按需要包括其他視情況選用之纖維,諸如天然纖維(亞麻、竹、纖維素、劍麻及其類似物)、玻璃纖維、其他無機纖維、有機纖維及其混合物。若想要時,不織布材料亦可包括粉末狀、液體或乳膠樹脂,其塗覆於所形成之基質墊的一或多個表面上或滲透於所形成之基質墊中以提供額外剛性、結合、水屏障或其他功能性質。舉例而言,多達約30重量%之樹脂可塗覆於基質墊之一或兩個表面上。The nonwoven core may include other components as appropriate. For example, the core may include other fillers as needed, such as cellulosic fibers (i.e., newsprint), calcium carbonate, perlite, glass beads, clay, granules, cork, and the like. Functional chemicals such as zeolites, activated carbon, and the like can also be added to the matrix mat to provide air purifying capabilities, if desired. In addition to inorganic matrix fibers and synthetic heat-bonded fibers, the core may also include other fibers as appropriate, such as natural fibers (linen, bamboo, cellulose, sisal and the like), glass fibers, other inorganic fibers, Organic fibers and mixtures thereof. If desired, the nonwoven material can also include a powdered, liquid or latex resin applied to one or more surfaces of the formed matrix mat or infiltrated into the formed mat to provide additional rigidity, bonding, Water barrier or other functional properties. For example, up to about 30% by weight of the resin can be applied to one or both surfaces of the substrate mat.
另外,所形成之基質墊可包含一或多層不織布材料。若形成多層,則每一層可按特定應用之需要具有與其他層類似或不同之性質,諸如類似或不同的基本重量、密度及組成。多層可藉由將多個基質墊層壓在一起而形成或可使用多頭成型機聯機形成。Additionally, the matrix mat formed can comprise one or more layers of nonwoven material. If multiple layers are formed, each layer may have similar or different properties to other layers as desired for a particular application, such as similar or different basis weights, densities, and compositions. The multilayer can be formed by laminating a plurality of matrix mats together or can be formed in-line using a multi-head molding machine.
包含無機基質纖維及合成熱黏合纖維之不織布材料可成型為適於隔音天花板瓷磚之核心,其中使用諸如濕式佈層、乾式佈層或空氣佈層成型製程之任何標準製程形成不織布材料。舉例而言,若使用濕式佈層製程,則較佳地首先用液壓製漿機、高頻疏解機、精製機或其他適合之設備使合成熱黏合纖維脫纖維。接著將脫纖維之合成纖維摻合至水性漿料中。藉由一種方法,使得漿料之固體含量較佳為約1%至約15%。接著可使用該漿料,使用標準濕式佈層高位調漿箱形成具有約0.1重量%至約50重量%之合成熱黏合纖維及約50重量%至約95重量%之無機基質纖維(諸如礦棉、渣棉及/或石棉)之不織布核心。Nonwoven materials comprising inorganic matrix fibers and synthetic heat bonding fibers can be formed into a core suitable for soundproof ceiling tiles wherein the nonwoven material is formed using any standard process such as a wet cloth layer, a dry cloth layer or an air cloth layer forming process. For example, if a wet lay-up process is used, the synthetic heat-bonded fibers are preferably first de-fibered using a hydraulic pulper, a high-frequency disintegrator, a refiner, or other suitable equipment. The defibrated synthetic fibers are then blended into an aqueous slurry. By one method, the solids content of the slurry is preferably from about 1% to about 15%. The slurry can then be used to form from about 0.1% to about 50% by weight of the synthetic heat-bonded fibers and from about 50% to about 95% by weight of the inorganic matrix fibers (such as ore) using a standard wet-laid high-level headbox. Non-woven core of cotton, slag wool and/or asbestos).
形成核心後,接著按需要經由重力排水、真空及/或加熱來移除水。當施加約7吋汞至約10吋汞之真空時,本發明之不織布材料的典型初始水分含量(亦即,在即將進入乾燥箱或乾燥室之前的板之水分含量)為約60%。相比之下,由標準材料製成之板的典型水分含量為70%。因為合成纖維含量增加,故初始水分減少。若想要時,可使用壓力向墊提供光滑表面且幫助控制最終密度。較佳地,乾燥箱在約300℉下或在比合成黏合纖維之熔點高至少約5℉至約50℉下操作以確保瓷磚成分之充分熔化及黏合。若想要時,在加熱後,亦可冷卻核心或墊及/或將其封閉於空氣循環系統中。After the core is formed, the water is then removed by gravity drainage, vacuum, and/or heating as needed. The typical initial moisture content of the nonwoven material of the present invention (i.e., the moisture content of the sheet immediately before entering the drying or drying chamber) is about 60% when a vacuum of from about 7 Torr to about 10 Torr is applied. In contrast, boards made from standard materials typically have a moisture content of 70%. Since the synthetic fiber content is increased, the initial moisture is reduced. If desired, pressure can be used to provide a smooth surface to the pad and help control the final density. Preferably, the drying oven is operated at about 300 °F or at least about 5 °F to about 50 °F above the melting point of the synthetic bonded fibers to ensure adequate melting and bonding of the tile components. If desired, the core or pad can be cooled and/or enclosed in an air circulation system after heating.
為達成不織布墊之均勻分佈,充分分散之合成熱黏合纖維為較佳的。已發現,合成纖維及無機基質纖維之最佳分散液可使用約50℃之漿料溫度達成,但已顯示約30℃至約70℃之範圍起很好的作用。咸信此溫度範圍很重要,因為一些市售原纖化合成纖維以濕漿板(wet lap)形式出售,其要使用時需再製漿。較高溫度有助於縮短減水時間及分散。接著,混合漿料約10分鐘至約30分鐘,直至漿料為實質上均質的。較佳地,亦在添加其他漿料組分之前使合成熱黏合纖維分散於水中以確保良好分散品質。為檢驗分散,應用玻璃杯或藍色玻璃檢查漿料以確保合成纖維完全分散。In order to achieve a uniform distribution of the nonwoven mat, a fully dispersed synthetic heat-bonded fiber is preferred. It has been found that the optimum dispersion of synthetic fibers and inorganic matrix fibers can be achieved using a slurry temperature of about 50 ° C, but it has been shown to work well in the range of from about 30 ° C to about 70 ° C. It is important to believe that this temperature range is important because some commercially available fibrillated synthetic fibers are sold as wet laps, which require repulping when used. Higher temperatures help to reduce water reduction time and dispersion. Next, the slurry is mixed for about 10 minutes to about 30 minutes until the slurry is substantially homogeneous. Preferably, the synthetic heat-bonded fibers are also dispersed in water prior to the addition of other slurry components to ensure good dispersion quality. To verify dispersion, the glass or blue glass is used to inspect the slurry to ensure complete dispersion of the synthetic fibers.
確保花費足夠時間進行完全分散為何重要之一個原因在於,如剛才所提及之一些市售原纖化合成纖維呈墊之形式,其在使用之前需要分散。完全分散或再製漿確保纖維提供最大數目之黏合位點,因此改良機械強度及孔隙率。若分散不足,則纖維可能會自身黏合在一起,且其可能喪失作為黏合劑之有效性。另一方面,一些市售合成纖維為乾短纖且不需要大量時間來達成充分分散。One reason why it is important to ensure that sufficient time is spent on complete dispersion is that some of the commercially available fibrillated synthetic fibers, as just mentioned, are in the form of mats that need to be dispersed prior to use. Complete dispersion or repulping ensures that the fibers provide the greatest number of bonding sites, thus improving mechanical strength and porosity. If the dispersion is insufficient, the fibers may stick together and they may lose their effectiveness as a binder. On the other hand, some commercially available synthetic fibers are dry staple fibers and do not require a significant amount of time to achieve adequate dispersion.
另外,如上文所述,為改良分散品質,合成纖維亦可經表面處理以使其至少在其外表面上具有親水性。在雙組分纖維之情況下,機械預處理可使得纖維更適於製造天花板瓷磚。預處理包含乾燥纖維、研磨纖維及形成原纖維。乾式研磨製程自身亦產生足夠力及剪切作用以進一步使纖維原纖化。Further, as described above, in order to improve the dispersion quality, the synthetic fiber may also be surface-treated to have hydrophilicity at least on the outer surface thereof. In the case of bicomponent fibers, mechanical pretreatment can make the fibers more suitable for making ceiling tiles. The pretreatment comprises drying the fibers, grinding the fibers and forming the fibrils. The dry milling process itself also produces sufficient force and shear to further fibrillate the fibers.
本文所述之不織布材料的優點及具體實例進一步藉由以下實施例來說明;然而,此等實施例中所述之特定材料及其量以及其他條件及細節不應解釋為限制不織布材料。除非另有指示,否則上文及下文所提及之所有百分比均以重量計。The advantages and specific examples of the nonwoven materials described herein are further illustrated by the following examples; however, the particular materials and amounts thereof recited in such embodiments, as well as other conditions and details, should not be construed as limiting the nonwoven material. All percentages mentioned above and below are by weight unless otherwise indicated.
實施例Example
實施例1Example 1
將約75公克E 380F乾短纖聚乙烯漿(Minifibers)分散於水中且接著以約5%稠度與約425公克礦棉混合約4分鐘(以乾固體計約15%聚乙烯漿)。將漿料傾倒於14×14吋成型盒中。首先藉由重力排出過量水,接著進一步使用約7" Hg真空進行移除。在不進行壓製之情況下,在約300℉下將所形成之板直接置於乾燥箱中歷時3小時。冷卻後,該板即變得相對具有剛性。所形成之瓷磚展現以下特徵:Approximately 75 grams of E 380F dry staple polyvinyl syrup (Minifibers) was dispersed in water and then mixed with about 425 grams of mineral wool at about 5% consistency for about 4 minutes (about 15% polyethylene slurry on a dry solids basis). The slurry was poured into a 14 x 14 inch shaped box. The excess water was first drained by gravity and then further removed using a vacuum of about 7" Hg. The formed plates were placed in a dry box for about 3 hours at about 300 °F without pressing. The plate becomes relatively rigid. The resulting tile exhibits the following characteristics:
實施例2Example 2
與實施例1類似,將約75.6公克E 380F纖維分散於水中且以5%稠度與約428.4公克礦棉混合4分鐘(約15% E380F纖維)。如實施例1中,將原料傾倒於成型盒中。首先排出過量水,接著進一步使用約8" Hg真空進行移除歷時約30秒。接著將板壓至約0.45"厚,且在300℉烘箱中乾燥3小時。冷卻後,該板即變得相對具有剛性。所形成之板展現以下特徵:Similar to Example 1, about 75.6 grams of E 380F fibers were dispersed in water and mixed with about 428.4 grams of mineral wool for 4 minutes at a consistency of 5% (about 15% E380F fiber). As in Example 1, the raw materials were poured into a molded case. Excess water was first drained and then further removed using a vacuum of about 8" Hg for about 30 seconds. The plate was then pressed to about 0.45" thick and dried in a 300 °F oven for 3 hours. After cooling, the plate becomes relatively rigid. The resulting board exhibits the following characteristics:
實施例3Example 3
首先將呈濕漿板形式之Fybrel E790(Mitsui Chemicals America)以約4.8%稠度分散於液壓製漿機中。約47.1公克Fybrel790與約267公克礦棉混合4分鐘後,將漿料傾倒於14"×14"成型盒中(約15% Fybrel)。首先藉由重力排出過量水,接著進一步使用約8" Hg真空進行移除歷時約30秒。接著將板壓至約0.295"厚,且在300℉烘箱中乾燥3小時。冷卻後,該板即變得相對具有剛性。板展現以下特徵:Fybrel E790 (Mitsui Chemicals America) in the form of a wet lap was first dispersed in a hydraulic pulper at a consistency of about 4.8%. After mixing about 47.1 grams of Fybrel 790 with about 267 grams of mineral wool for 4 minutes, the slurry was poured into a 14" x 14" molded box (about 15% Fybrel). The excess water was first drained by gravity and then further removed using a vacuum of about 8" Hg for about 30 seconds. The plate was then pressed to about 0.295" thick and dried in a 300 °F oven for 3 hours. After cooling, the plate becomes relatively rigid. The board exhibits the following characteristics:
比較實施例4Comparative Example 4
將約47.1公克Fybrel E790(Mitsui Chemicals America)與約219.8公克礦棉、約47.1公克新聞紙及約25公克碳酸鈣混合約4分鐘(約13.8% Fybrel)。接著如實施例1中,將漿料傾倒於14"×14"成型盒中。首先藉由重力排出過量水,接著進一步使用約11" Hg真空進行移除。接著將板壓至約0.265"厚,且在300℉烘箱中乾燥約3小時。冷卻後,該板即變得相對具有剛性。板展現以下特徵:About 47.1 grams of Fybrel E790 (Mitsui Chemicals America) was mixed with about 219.8 grams of mineral wool, about 47.1 grams of newsprint, and about 25 grams of calcium carbonate for about 4 minutes (about 13.8% Fybrel). Next, as in Example 1, the slurry was poured into a 14" x 14" molded case. Excess water was first drained by gravity, followed by further removal using a vacuum of about 11" Hg. The plate was then pressed to about 0.265" thick and dried in a 300 °F oven for about 3 hours. After cooling, the plate becomes relatively rigid. The board exhibits the following characteristics:
應注意在比較實施例4中,調配物中使用13.5%纖維素纖維(新聞紙)。親水性纖維素纖維會產生高表面張力,從而在乾燥期間使板緻密。因此,密度高,孔隙率低,且NRC低。It should be noted that in Comparative Example 4, 13.5% cellulose fiber (newspaper) was used in the formulation. Hydrophilic cellulosic fibers produce high surface tension to densify the board during drying. Therefore, the density is high, the porosity is low, and the NRC is low.
比較實施例5Comparative Example 5
將約61.1公克SS 93510,一種親水性原纖化PE纖維(Minifibers)以4.5%稠度與約346公克礦棉混合約4分鐘(約15% PE纖維)。接著將漿料傾倒於12"×12"成型盒中。首先藉由重力排出過量水,接著進一步使用真空進行移除。接著使用真空牽引熱空氣穿過墊。當墊溫度達到300℉時,加熱該墊約8分鐘。冷卻後,板即變得相對具有剛性。About 61.1 grams of SS 93510, a hydrophilic fibrillated PE fiber (Minifibers), was mixed with about 346 grams of mineral wool at a consistency of 4.5% for about 4 minutes (about 15% PE fiber). The slurry was then poured into a 12" x 12" molded box. The excess water is first drained by gravity and then further removed using a vacuum. The vacuum is then used to draw hot air through the mat. When the pad temperature reached 300 °F, the pad was heated for about 8 minutes. After cooling, the plate becomes relatively rigid.
該板展現以下特徵:The board exhibits the following characteristics:
應注意在此比較實施例5中,所達成之高密度為通風乾燥(through-air drying)之結果。將墊置於真空下以使熱空氣穿過該墊,由此使墊緻密。此實施例亦展示通風乾燥有助於在乾燥期間保持孔隙率,由此在類似密度下保持較佳NRC。It should be noted that in this Comparative Example 5, the high density achieved was the result of through-air drying. The pad is placed under vacuum to allow hot air to pass through the pad, thereby densifying the pad. This example also demonstrates that venting drying helps maintain porosity during drying, thereby maintaining a better NRC at similar densities.
實施例6Example 6
首先將約108公克ESS50F,一種親水性原纖化PE纖維(Minifibers)以約2%稠度分散於水中。接著將所分散之纖維與約403公克礦棉混合約4分鐘(約21% PE纖維)。接著將漿料傾倒於14"×14"成型盒中。首先藉由重力排出過量水,接著進一步使用約6.8" Hg真空進行移除。接著將板壓至約0.49吋厚且在300℉烘箱中乾燥約3小時。冷卻後,該板即變得相對具有剛性。板展現以下特徵:First, about 108 grams of ESS50F, a hydrophilic fibrillated PE fiber (Minifibers), was dispersed in water at a consistency of about 2%. The dispersed fibers were then mixed with about 403 grams of mineral wool for about 4 minutes (about 21% PE fibers). The slurry was then poured into a 14" x 14" molded box. The excess water was first drained by gravity, followed by further removal using a vacuum of about 6.8" Hg. The plate was then pressed to about 0.49 inches thick and dried in a 300 °F oven for about 3 hours. After cooling, the plate became relatively Rigid. The board exhibits the following characteristics:
比較實施例7Comparative Example 7
首先將約75.6公克具有相對較長纖維長度(2.1 mm)之E990,一種原纖化PE纖維(Minifibers)分散於水中。與約428.4公克礦棉混合約4分鐘後,在混合結束時添加約151公克脹性珍珠岩(USG,Red Wing,MN)(約11.5% PE纖維)。接著將漿料傾倒於14"×14"成型盒中。首先藉由重力排出過量水,接著進一步使用約6.8" Hg真空進行移除歷時約30秒。壓至約0.71吋厚後,將板在300℉烘箱中乾燥約3小時。冷卻後,該板即變得相對具有剛性。所形成之板展現以下特徵:First, about 75.6 grams of E990 having a relatively long fiber length (2.1 mm), a fibrillated PE fiber (Minifibers), was dispersed in water. After mixing with about 428.4 grams of mineral wool for about 4 minutes, about 151 grams of swellable perlite (USG, Red Wing, MN) (about 11.5% PE fiber) was added at the end of the mixing. The slurry was then poured into a 14" x 14" molded box. The excess water was first drained by gravity, followed by further removal using a vacuum of about 6.8" Hg for about 30 seconds. After pressing to about 0.71 吋 thick, the plate was dried in a 300 °F oven for about 3 hours. After cooling, the plate was It becomes relatively rigid. The resulting board exhibits the following characteristics:
應注意在此實施例7中,顯示添加輕質填充劑脹性珍珠岩不會損害吸音作用。通常在典型濕式佈層製程中,愈多珍珠岩添加至基質墊中,NRC愈低。在此情況下,高密度為添加填充劑之結果。因為可將珍珠岩添加至天花板瓷磚組分中以改良表面燃燒及強度特徵,故此為重要的。It should be noted that in this Example 7, it was shown that the addition of the lightweight filler tumbling perlite did not impair the sound absorbing effect. Generally, in a typical wet-laid process, the more perlite is added to the matrix mat, the lower the NRC. In this case, the high density is the result of the addition of the filler. This is important because perlite can be added to the ceiling tile composition to improve surface burning and strength characteristics.
應瞭解,熟習此項技術者可使本文中已描述及說明以便解釋不織布材料之性質的細節、材料及製程條件中之各種變化處於如隨附申請專利範圍中所表述之原則及範疇內。另外,本文中所引用之任何參考文獻均亦以全文引用的方式併入本文中。It will be appreciated that those skilled in the art will be able to describe and describe the details, materials, and process conditions of the materials that are described herein in order to explain the nature of the non-woven material in the principles and scope as set forth in the appended claims. In addition, any references cited herein are also incorporated herein by reference in their entirety.
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