TW487771B - Exhaust gas catalytic converter - Google Patents
Exhaust gas catalytic converter Download PDFInfo
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- TW487771B TW487771B TW089104266A TW89104266A TW487771B TW 487771 B TW487771 B TW 487771B TW 089104266 A TW089104266 A TW 089104266A TW 89104266 A TW89104266 A TW 89104266A TW 487771 B TW487771 B TW 487771B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/9454—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific device
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2006—Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating
- F01N3/2013—Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means
- F01N3/2026—Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means directly electrifying the catalyst substrate, i.e. heating the electrically conductive catalyst substrate by joule effect
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
- F01N3/281—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
- F01N3/2814—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates all sheets, plates or foils being corrugated
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
- F01N3/281—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
- F01N3/2821—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates the support being provided with means to enhance the mixing process inside the converter, e.g. sheets, plates or foils with protrusions or projections to create turbulence
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2835—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support fibrous
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/10—Fibrous material, e.g. mineral or metallic wool
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/14—Sintered material
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/30—Honeycomb supports characterised by their structural details
- F01N2330/32—Honeycomb supports characterised by their structural details characterised by the shape, form or number of corrugations of plates, sheets or foils
- F01N2330/323—Corrugations of saw-tooth or triangular form
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/30—Honeycomb supports characterised by their structural details
- F01N2330/38—Honeycomb supports characterised by their structural details flow channels with means to enhance flow mixing,(e.g. protrusions or projections)
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Toxicology (AREA)
- General Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Exhaust Gas After Treatment (AREA)
- Catalysts (AREA)
Abstract
Description
487771 案號 89104266 年&月 a (f 五、發明說明(1) 本發明係有關於燃燒引擎觸媒轉換器’且更特別地係有 關於使用於汽車引擎之觸媒轉換器。 交叉參考相關之申請案及專利 具有相關性者包括Vogt等在1998年10月28日共同申請之 名為丨’Method and Apparatus for Making Catalyst carrier device Element” 之專利申請第09/181, 186號 案,Paikert等在1998年1月2日提出之名為n Catalyst ·%487771 Case No. 89104266 & month a (f V. Description of the invention (1) The present invention relates to a catalytic converter for a combustion engine 'and more particularly to a catalytic converter for a car engine. Cross-reference related Relevant applications and patents include the patent application No. 09/181, 186, Paikert, etc., which was jointly filed on October 28, 1998 and named "Method and Apparatus for Making Catalyst carrier device Element" by Vogt et al. Named n Catalyst on January 2, 1998
carrier device and Element Therfor” 之專利申請第 09/002539號案及與其相當之於1998年12月29日申請之 PCT/US98/27699號案,Schuh等在1998年9月17日中請之名 為”(:〇316(1 Products”之專利申請第0 9 / 1 5 6,0 2 3號案,美 國專利第6,217,732號(相應於?(:丁/11398/19811)及 Overbeek等在1998年5月29日提出之名為"Structuredcarrier device and Element Therfor "patent application No. 09/002539 and its equivalent PCT / US98 / 27699 filed on December 29, 1998. Schuh et al. "(: 〇316 (1 Products" Patent Application No. 0 9/15 6, 0 2 3, US Patent No. 6,217,732 (corresponding to? (: Ding / 11398/19811) and Overbeek et al. In May 1998 &Quot; Structured
Packing and Element Therefor"之專利中請第 60/087, 474 號案(相應於PCT/US99/10784)。 其他如美國專利11.3.?3七3^〇3.4,939,113、4,9 65,243 號案及國際專利申請第?(:口1]5 9 5/ 0 1 84 9號案公告第?0 9 5 / 3 5 1 5 2號案係揭露用於汽車燃燒引擎排氣三向式觸媒轉 換器之觸媒。美國專利11.3.?3七3.^〇3.5,304,330、 5, 080, 962 ;5, 102, 745及5, 0 9 6, 663號案係揭露網狀材料Packing and Element Therefor " Patent No. 60/087, 474 (corresponding to PCT / US99 / 10784). Others such as U.S. Patent 11.3.?3, 7 ^ 3, 3.4,939, 113, 4,9 65,243 and International Patent Application No.? (: Port 1) Case No. 5 9 5/0 1 84 9 Announcement No. 0 9 5/3 5 1 5 2 Case No. 2 discloses the catalyst used in the three-way catalytic converter of automobile combustion engine exhaust. United States Patent 11.3.?3 Seven 3. ^ 〇3.5, 304, 330, 5, 080, 962; 5, 102, 745 and 5, 0 9 6, 663 are cases where the mesh material is disclosed
之製作。上述所有之申請案及專利皆以完全參考納入本發 明中。 目前汽車燃燒引擎可使用之觸媒轉換器通常約丨2 〇公厘 且區分為兩種基本結構。一結構係使用包括譬如C 〇 r n i n g Corporation出品之Cordierite之鎂-鋁-氧陶瓷蜂巢式單Of production. All of the aforementioned applications and patents are incorporated herein by reference in their entirety. The catalytic converters currently available for automotive combustion engines are usually about 20 mm and are divided into two basic structures. One structure uses a magnesium-aluminum-oxygen ceramic honeycomb sheet including, for example, Cordierite by Corinite Corporation.
O:\63\63i38.ptc 第7頁 2001.08.02.007 - ^ 五、發明說明(2) 體構件,這種4 害結構。該;低之熱膨脹係數以防止熱陡震傷 竹料可由擠壓成型。 心辰、 材料之平行導管且通常巢式結構包括許多通過 觸媒即沈積於導管纟士 央吋中具有40 0個導管, 信導管中之紊流將;生一^:t前技藝中傳統之知識深 -較大之壓力降而非為吾人所期待即將在横:結構上產生 望之燃燒引擎效率降低及較背壓將 結構之問題在於 平又大之功羊知失。此類 中材料表面上之=非有效利用π觸媒。觸媒係塗覆於導管 可降低氣體—觸土復層。由於單體之窄直形通道將形成— 動氣體之間的觸媒作用缺乏層^達層而仏成觸媒與流 量之觸媒以彌補這種不需之轉換水準 觸媒轉換器需使用9 二率。譬如一般之 需要1180公克。 見 又铋大且重之結構則 “】第、一,觸媒载具包括鐵-鉻(Fe-Cr)合金 二:出 鋁係用於在高溫時與含氧大氣ί ί約5 %紹 面形成一作為保禮& 、反應而在金屬表 溫度高達1〇〇二;化紹質氧化皮:,層可防止合金在 米’且隨著沿平行二。一般之合金溥片厚度約40至50微 將覆蓋薄片之=才料延伸的波形彎波形薄片再 所有波形皆在板纏繞成具有-縱h螺旋形結構。 製成-量大質;;成平行通道。較緊密地纏繞薄片將 且可在橫向面it;;工中於陶究結構者 而,該結構亦使用M 央才中/、有大約δ 0 〇個通道。然 使用層流以將結構之壓力降最小化。O: \ 63 \ 63i38.ptc Page 7 2001.08.02.007-^ V. Description of the invention (2) Body structure, this kind of harmful structure. The low thermal expansion coefficient to prevent thermal shock damage bamboo materials can be extruded. Xinchen, a parallel duct of material and usually a nested structure includes a number of 40 ducts deposited in the duct through the catalyst, which is turbulent. The turbulence in the duct will be the traditional one in the art. Deep knowledge-the larger pressure drop is not what we expected is about to be overwhelming: the structure of the combustion engine that produces the desired efficiency is lower and the back pressure is the problem of the structure. In this class, the surface of the material = inefficient use of π catalyst. The catalyst is applied to the catheter to reduce the gas-clay contact layer. Because the narrow, straight channels of the monomer will be formed-the catalyst interaction between the moving gas lacks a layer ^ reaching the layer, and the catalyst between the catalyst and the flow is formed to compensate for this unnecessary conversion level. The catalyst converter needs to use 9 Second rate. For example, it usually takes 1180 grams. See the structure of bismuth which is large and heavy. "First, the catalyst carrier includes iron-chromium (Fe-Cr) alloy. Second: Aluminum is used for high temperature and oxygen-containing atmosphere. Forming a reaction as a blessing & reaction at a metal surface temperature of up to 100%; chemical oxide scale: a layer that prevents the alloy from being in the 'm' and along the parallel parallel. The thickness of the general alloy diaphragm is about 40 to 50 micron will cover the wave of the sheet = expected extension of the curved wave sheet and all the waves are wound on the board to have a -vertical h spiral structure. Made-large quantity and quality; into parallel channels. More closely wound the sheet will be and It can be used in the lateral plane to study the structure, and the structure also uses the M / C center, with about δ 0 0 channels. However, laminar flow is used to minimize the pressure drop of the structure.
五、發明說明(3) f ^ 2述蜂巢式單體結構之限制包括載具之一較大質量 3、、200么克/公升)(這將轉換成較高之熱質)而不可能 、巾Γ減少ί置,且高熱質亦非吾人所期待。大的質量將造 成慢的廢氣轉換。廢氣轉換係指物質到達塗覆於單體結構 t之觸媒之譬如30 0。〇的操作溫度時所需要之時間,此亦 指一引擎之冷起動時間。單體結構係由於其熱質而將在起 f期間緩慢的加熱至所需溫度。這種緩慢之廢氣轉換將在 /飞車的應用中造成不佳之觸媒反應且因此使得對某些孽如 Nox、不可轉換之HC及C0等污染氣體成份的轉換不佳一/而 在引擎冷起動且觸媒尚未到達臨界溫度期間將形成污染 物。因此觸媒到達工作溫度時廢氣中之污染水準將高到無 法接受的程度,這很明顯地無法滿足需求。藉由減少壁 =減少質量的解決方法成效有限。目前金屬薄板 度已限制到大約40微米。 千 、、先前技藝之觸媒轉換器單體結構之又—限制係其有限之 活性表面’此為結構之内立墓瞢中 少通道尺寸,㈣減少:::;:;::用之表面積。減 轉換器長度上之壓力降:=。加;面積但將增加沿 牛且廷如上所述亚非吾人所期待,所 品要者係橫跨結構且在介於輸入與輸 之電壓降。 w生土 非吊低 目前以2 0微米左 紊流加強器來改善 技術亦可加強這類 之橫向面積上之通 右'之金屬薄板製成的 觸媒與氣體之反應或 反應。又有其他的努 道數量增加為每平方 觸媒轉換器係使用 應用新的觸媒塗覆 力係將轉換器結構 英呎1 0 0 0 - 1 2 0 0個V. Description of the invention (3) The limitations of the honeycomb structure described in f ^ 2 include the larger mass of one of the carriers (3, 200 μg / L) (which will be converted into a higher thermal mass), The number of towels is reduced, and the high heat quality is not what I expected. A large mass will result in slow exhaust gas conversion. Exhaust gas conversion means that the substance reaches the catalyst coated on the monomer structure t, such as 300. The time required for an operating temperature of 0. This also refers to the cold start time of an engine. Due to its thermal mass, the monomer structure is slowly heated to the required temperature during f. This slow exhaust gas conversion will cause poor catalyst response in flying applications and therefore make poor conversion of certain pollutants such as Nox, non-convertible HC and CO. Contaminants will form during startup and when the catalyst has not reached a critical temperature. Therefore, when the catalyst reaches the operating temperature, the level of pollution in the exhaust gas will be unacceptably high, which obviously cannot meet the demand. The solution by reducing walls = reducing mass has limited effectiveness. The sheet metal thickness is currently limited to about 40 microns. Thousands, the single structure of the catalyst converter of the previous technology-the limitation is its limited active surface 'This is the structure of the internal tomb ridge with a small number of channels, which reduces: :::; . Pressure drop across the length of the converter: =. But the area will increase. Niu and Ting said that the Asian and African people expect that the product is across the structure and the voltage drop between input and output. W Raw soil Non-suspended low At present, the technology is improved by a 20 micron left turbulence enhancer. The technology can also strengthen the reaction or reaction between the catalyst and the gas made of such a thin metal plate in the lateral area. The number of other channels has been increased to use the catalytic converter system per square. Apply a new catalyst coating. Force system will transform the converter structure. Feet 1 0 0 0-1 2 0 0
第9頁 487771 五、發明說明(4) 左右。然而 遞而導致觸 發明人體 轉換器結構 一種用於 廢氣中某4b 其係 料, 通材 定至 成份 本 即在 觸媒 又 又 行, 波形 較 向彎 在 板具 包括 形成 具有一 其具有 料外部 村料的 反應。 發明之 係固定 一構想 —構想 且相鄰 係形成 佳地, 争習一介 & —構 #複數 複數個 一可提 ,這類 媒作用 認到亟 之問題 在引擎 成份反 引擎廢 之空洞 ,該接 觸媒係 結構仍 較無效 需一種 的改良 廢氣依 應的燃 氣接收 係複數 收之氣 當流體 將造 率〇 可克 式觸 據本 燒引 室; 個間 體係 流過 一構想中之多孔性 想中之多孔性材料 於該材料之間隙中 中之薄板材料包括 中之薄板材料係呈 薄板之波形係互相 流體之通道以使流 該波形形成流體通 於0。至大約75。之傾 想中,多孔性材料 平行通道以藉由通 延伸入每一通道之 供給定方向上之氣 成較高熱質與較低 服上述有關先·前技 媒轉換器。 發明之指定方向流 擎觸媒轉換器包^ 一位於該室中之多 隙以使流體互相連 流至外部與間隙中 該接收室及間隙時 材料包括燒結之金 係包括薄板材料。 〇 複數個渦流產生器 波形,每一薄板之 相對的傾斜,且相 體互相流通。 道,其係相對給定 斜角度。 係形成複數個薄板 道連結複數薄板, 滿流產生為以使每 體流動 的物質傳 蟄之單體 通時與該 一機殼, 孔性材 通並且連 以及—固 與該氣體 屬纖維, 較佳地, 波形係平 鄰薄板之 之流動方 ’ 每一薄 每一薄板 一該通道 大致扭曲之流體路Page 9 487771 V. Description of Invention (4). However, it has led to the invention of the human body converter structure. It is used for a certain 4b in the exhaust gas and its materials. The material is fixed to the component, which is both the catalyst and the line. Village response. The system of invention fixes a concept—conceived and the adjacent system forms a good place, and contends for an introduction & —construction #plurality, one can be mentioned. This type of media recognizes that the urgent problem lies in the void of engine components against engine waste. The structure of the contact medium system is still relatively ineffective, and a gas receiving system that requires one type of improved exhaust gas is required to collect the gas. When the fluid will have a production rate of 0 gram, the firing chamber will be touched; The thin plate material in the gap between the desired porous material and the material includes the thin plate material, which is a thin plate, and the wave shape of the system is a channel for mutual fluid flow, so that the wave forms a fluid through 0. To about 75. It is envisaged that the porous material will be in parallel with the channels in order to pass through the gas in a fixed direction extending into each channel to form a higher thermal mass and a lower temperature. The specified direction flow catalyst converter package of the invention ^ a plurality of gaps in the chamber to allow fluids to flow to the outside and the gaps. The receiving chamber and the gaps include materials including sintered metal and thin plates. 〇 The waveforms of a plurality of eddy current generators, the relative inclination of each thin plate, and the phases flowing through each other. Road, which is relative to a given oblique angle. A plurality of thin plate channels are formed to connect the plurality of thin plates, and the full flow is generated so that the monomers that transfer the material flowing in each body communicate with the one case, the porous material, and connect with the solid fiber, preferably The waveform is the flow side of the adjacent plates. Every thin plate has a fluid path whose channel is roughly twisted.
TT
第10頁 487771 五、發明說明(5) 徑。 較佳地,該 地大約1 - 5 0微 又一 具有一 板材料 之流動 構想中 廢氣接 包括複 中之成份反應 夾一大約3 0 - 1 在又 一角度 通。 在又 包括由 始彎摺 又一 個平行 流產生 之流體 在又 氣壓中 接。 在又 流通材 一構想 ,相鄰 一構想 薄板材 之翼片 構想中 通道係 器延伸 路徑而一構想 加熱使構想 料之電 材料大約至 # ’更佳地 之一燃燒引 收室;該室 數波形,該 生奮流,及 。較佳地, 50°之角度。 中,相鄰薄 薄板之波形 中’渦流產 料中形成貫 少85 % 直徑係 擎觸媒 中具有 波形係 一固定 該波形 板之波 形成流 生器係 穿孔處 之多孔性材料形成 用於連結複數薄板 進入每一通道以佶 影響給定方 中,金屬纖 得材料中之 中,金屬纖 流加熱以藉 向上之 維及觸 纖維接 維及觸 由燒結 ,空洞且纖維之直徑較佳 自8至2 5微米。 轉f器括-機殼,其係 複數個薄板材料,每一薄 彎向給定方向以使該室中 至材料之觸媒係舆該氣體 側壁係平坦且互相相對的 形之縱長方向係互相相對 體通道以使流體互相連 位於波形薄板中且較佳地 之相連溝板材料的平面開 设,板。每一板具有複數 丄每一薄板包括複數個渴 每一通道形成一大致扭曲 氣體流動。 某係在較佳為氫氣之降 觸點藉由燒結纖維而連 媒係在一流動氣壓中籍〜 方法而在材料之接觸點處Page 10 487771 V. Description of Invention (5) Path. Preferably, the ground is about 1 to 50 micrometers in another flow with a plate material in the concept of exhaust gas connection, including the compound reaction in the center, and about 30 to 1 at another angle. The fluid produced by another parallel flow including the initial bending is connected under the same pressure. In the concept of circulating material, the path of the channel system extends in the concept of the fins of an adjacent thin plate, and the concept of heating the electrical material that makes the material to about one of the better. Waveform, this life is struggling, and. Preferably, an angle of 50 °. In the wave form of adjacent thin plates, 85% less diameter is formed in the eddy current production material. The catalyst has a wave form in the catalyst. A porous material fixed to the wave form of the wave plate is formed by a porous material for connection. A plurality of thin plates enter each channel to influence the given square, the metal fiber is obtained from the material, the metal fiber stream is heated to touch the fiber by the upward dimension and contact the sintering, and the hole is preferably from 8 Up to 2 5 microns. The rotating device includes a casing, which is a plurality of thin plate materials, each of which is bent in a given direction so that the catalyst in the material in the chamber is a longitudinal direction system in which the side walls of the gas are flat and opposed to each other. Plates are formed on the plane of the body channels opposite to each other so that the fluids are located in the corrugated sheet and preferably connected to the groove plate material. Each plate has a plurality. Each plate includes a plurality of thirsts. Each channel forms a generally twisted gas flow. A certain contact is preferably a drop of hydrogen. The contact is connected to the material at a contact point of the material by sintering the fiber.
第11頁 抑7771 五、發明說明(6) 連接纖維。 ,另一構想中,金屬纖維及觸媒係藉一流通材料之 σ…、以有效地加熱結構至一可與廢氣反應之.特定溫度。机 機^據本發明m想的燃燒弓丨擎觸媒轉換器包括一 匕其係具有-廢氣接收室及該室中之觸媒裝置 肢之成份反應,以及使通過該室之氣體肩二矶 :過该室之壓力降保持於-足夠低之特定值以產 或小於某特定值之引擎背壓。 ♦於 一燃燒引擎觸媒轉換之又一構想包括一 一用於接收廢氣之氣體接收室及一包括古^ 係一有 媒載具,該觸媒係於一特定溫度下輿…;^至中之觸 份反應,言亥載具相對於氣體在至少該‘:、、西:收之氣體成 傳遞至該載具之熱能而言將顯現出一及二=又Z I熱接觸 載具顯出該特定溫度之時間小於約1分铲°。—之热質而使該 圖式說明 Μ 圖1係依據本發明一具體實施例之〜 圖; 觸媒轉換器透視 圖2係圖1之轉換器之主要轉換部透視圖· 圖3係為方便說明而以透視外蓋顯 θ 透視圖; 、不圖2之一部份更詳細 圖4係以側邊相互並列之方式顯示 構件透視圖; 圖3之稷數個波形轉換 圖5顯示圖4之一用於圖1至圖3具 的一部份更詳細透視圖; 私a靶例中之波形構件Page 11 777777 V. Description of the invention (6) Connecting fiber. In another idea, the metal fiber and catalyst are based on the σ of a circulating material to effectively heat the structure to a specific temperature that can react with the exhaust gas. The engine-driven catalytic converter according to the present invention includes a dagger which has an exhaust gas receiving chamber and components of the catalyst device in the chamber, and reacts the gas passing through the chamber. : The pressure drop across the chamber is kept at a certain value low enough to produce or less than the engine back pressure of a certain value. ♦ Another idea for the conversion of a combustion engine catalyst includes a gas receiving chamber for receiving exhaust gas and a vehicle containing a vehicle, the catalyst is at a specific temperature ...; to medium With regard to the contact response, the Yanhai vehicle will show one and two as far as the heat energy transferred to the vehicle at least the ': ,, and west: collected gas = ZI thermal contact vehicle shows that The time at the specified temperature is less than about 1 minute. —The thermal mass of the diagram illustrates the figure. Figure 1 is a drawing according to a specific embodiment of the present invention; perspective view of the catalyst converter 2 is a perspective view of the main conversion part of the converter of FIG. 1; FIG. 3 is for convenience The θ perspective view is shown with a perspective cover; not a part of FIG. 2 in more detail. FIG. 4 is a perspective view showing the components side by side; FIG. 3 shows several waveform transitions. A more detailed perspective view of a part used in Figs. 1 to 3; the waveform member in the private target example
第12頁 487771 五、發明說明(7) 圖6係一形成圖4之構件的薄 形前之等角視圖; "表於形成構件之波 圖7係由已形成波形及渦 ^a ”L產生杰之圖6之痛4 一構件之一部份等角視圖; 缚板所形成的 圖7a係圖7之區域7a中之一 圖8係圖7之構件的一部份#視a . D。之更詳細視圖; 圖8a係圖8之區域8a中之構而件之V ?9係在加工圖6之薄板之中間階段時,依摅坪細視圖; 貫施狀構件於產生圖7至圖8之渦流 ^:第二具體 形之W的平面圖; 之後且形成波 圖10係圖9之薄板的一部份等角視圖; 、圖η係形成本發明之-構件之薄板材 以放大材料之細部結構; 料、員微照片 圖1 2係形成本發明之— 於放大材料之細部結構;件之缚板材料的顯微照片,用 圖㈣係-用於形成圖9之薄板材料之褒置的側視剖面 圖14係—圖13之裝置的平面剖面圖; 圖1 5係沿圖1 6之获晉ψ a id之展置中的剖面線15 —丨 視剖面圖; J心入双輪廓的側 J1大6::用於形成圖4、5與圖7、8之薄板材料之波形事 置的大致輪廓圖; 丁〈渡开y衣 圖1 7係沿圖1 § $获詈ψ AA &, ^ 視剖面圖; 、 勺4面線17-17之大致輪廓的側Page 12 487771 V. Description of the invention (7) Figure 6 is a thin isometric view before forming the member of Figure 4; " The wave shown in the forming member is shown in Figure 7 by the formed waveform and vortex ^ a '' L A part of a component that produces the pain of Figure 6 is an isometric view; Figure 7a formed by the binding plate is one of the areas 7a of Figure 7; Figure 8 is a portion of the component of Figure 7 # 视 a. D Figure 8a is a detailed view of Figure 9a in the region 8a of Figure 8 in the middle stage of processing the sheet in Figure 6, according to a detailed view of the flat floor; Figure 8 eddy current ^: Plan view of the second specific shape of W; Figure 10 is a partial isometric view of the thin plate of Figure 9; Figure η is a thin plate forming the component of the present invention to enlarge the material Detailed structure of materials; micrographs of materials and members. Figures 12 and 2 form the detailed structure of the enlarged material of the present invention; photomicrographs of the plate binding material. 14 is a plan sectional view of the device of FIG. 13; FIG. 15 is a section line 15 during the deployment of FIG. Sectional view; J heart into the double-contour side J1 large 6: rough outline diagram for forming the wave shape of the sheet material of Figs. 4, 5 and 7, 8; Ding Along the diagram of Figure 1 § $ $ 詈 AA &, ^ A cross-sectional view of the side of the outline of the spoon 4 surface line 17-17
487771 五、發明說明(8) 圖18係圖17之裝置於形成圖4、5 廓後的大致輪廓圖; /、圖7、8之薄板材料輪 圖18a係一等角視圖,顯示應用 施例中之一代表的指狀物; ' 5至圖i 8之具體實 圖19係-觸媒轉換器之觸 的等角視圖; 構之又一具體實施例 圖20係一用於圖19之結構中之 圖; 構件之一部份的平面 圖21係沿著圖2〇之構件之剖面線2 — 圖22至圖27係用於說 21的前視圖;及 在圖1中之觸媒轉換器2__4=理之圖表。 圓柱形區段6,—前H设4,其又包括_ 器2之區段6包括—觸媒m—後錐形區段1〇。轉換 y =燒引擎(未顯示)排放/之塗覆一用於與譬如 化虱或其他污染物轉換 二軋反應的觸媒而將碳 具體實施例中之直徑大八,、、巧染氣體。區段6在此 段δ係連接至管子之、 刀且長約1 5 0公分。前端區 緣14係連接至燃燒而,於凸“緣14中截斷管子12,該凸 收引擎廢氣。轉換器2 顯示)以在方向16上接 緣20之管子18以連接Π域係連接至一截斷於凸 圖2中機殼4之中央 /轧=,.·充(未顯示)之氣體排放部。 之觸媒載具22係更詳二二=:叙6所包括之—觸媒轉換器 屬微纖維形成之多^也顯::於圖3中。區段6包括-由全 郎-、 几性網狀薄板材Μ从门 顯不),此將更詳盡地 J4的圓柱形襯墊23(未 ° Η 。溽板材料之襯墊23係提 48/771 五、發明說明(9) " '^---- 供震動阻尼且在組裝時以摩擦力軸向 *:該襯塾可選擇性地具有…所述型Ϊ;2觸2=4 機殼4可為不銹鋼材質且在縱向邊緣25焊接成一柘" 料。焊接機殼4之區段6時將使襯墊23壓縮至载且’ 一 屬網31係附加至载具22之每〆相對軸向端。一開口产_ 丈干接至網31外側之機殼4内側且夹於網31與载具μ 圖3中係透視區段6、機殼4及襯墊23以顯示載且22 ^ 部。載具22包括—波形構件24、26等之總成。每' 24、26係以相同於襯墊23之薄板材料製成,但每一構 ^㈣以形成㈣4區段6之核心的圓柱形外 冓牛24、26在圖式中由左至右具有相同之軸向縱長, 4區VT向之橫向寬度係不相同以配合襯墊23内之機殼 圓ί孔洞。構件24、26係以相同方式形成且包括 第麥閱已在本文介紹中提及之前述申請專利 用於& i,18 6號案中所敘述之已完全參考融入本發明之— 内要地,,、構件2 4、2 6的裝置。將參考以下之圖1 3至圖1 8來 間要地說明該裝置。 ^ 之係於橫向區段上彎㈣度時亦可依據給定實施 22 ;用I 2成波形或其他形狀。I此具體實施例中之載具 :;言如處理燃燒引擎廢氣中之NOx、HC及C0成份。 面I中一形成構件24、26(及圖2之襯墊23)之薄板28係一平 示)ΛΓ譬如3 X4英对薄板(〇·91公尺X1·22公尺)(未顯 錄剛二大薄板切割成此尺寸。薄板28包括多孔性燒結不 3 /、他洋述於後之其他金屬纖維。薄板28具有一高的487771 V. Description of the invention (8) Fig. 18 is a rough outline view of the device of Fig. 17 after the outlines of Figs. 4 and 5 are formed; /, the sheet material wheel of Figs. 7 and 8 is an isometric view showing application examples Fingers represented by one of them; '5 to Fig. 8 of the concrete figure 19 series-isometric view of the touch of the catalytic converter; another embodiment of the structure of Fig. 20 is a structure for Fig. 19 The plan view of a part of the component 21 is along the section line 2 of the component of FIG. 20 — FIGS. 22 to 27 are front views for speaking 21; and the catalyst converter 2__4 in FIG. 1 = Reasoning chart. The cylindrical section 6, the front H is set to 4, and the section 6 including the device 2 includes the catalyst m and the rear tapered section 10. Conversion y = Burning engine (not shown) emissions / coating-a catalyst used for conversion reaction with, for example, lice or other pollutants, and the carbon in the specific embodiment, the diameter of the carbon is 8% larger, and the gas is dyed. Section 6 in this section δ is connected to the pipe, knife and about 150 cm long. The front end edge 14 is connected to the combustion, and the tube 12 is cut off in the convex edge 14, which convexly exhausts the engine exhaust. The converter 2 is shown) to connect the tube 18 of the edge 20 in the direction 16 to the Π domain system to a Truncated to the center / roll of the casing 4 in convex figure 2 =, ··················································································· The number of microfibrils formed is also obvious :: In Figure 3. Section 6 includes-by Quan Lang-, a thin mesh sheet M (shown from the door), this will be a more detailed J4 cylindrical gasket 23 (Not ° Η. The gasket of the fascia material 23 is to mention 48/771 V. Description of the invention (9) " '^ ---- Provides vibration damping and axial force with friction during assembly *: This lining It can optionally have the said shape; 2 contact 2 = 4 The casing 4 can be made of stainless steel and welded into a single material at the longitudinal edge 25. The gasket 23 will be compressed when the section 6 of the casing 4 is welded To the load and 'a belonging net 31 is attached to each of the opposite axial ends of the carrier 22. An open product _ Zhang Qian is connected to the inside of the casing 4 outside the net 31 and sandwiched between the net 31 and the carrier μ Figure 3 Department of Perspective Section 6, Machine 4 and pad 23 to display the carrier and 22 ^. The carrier 22 includes-the assembly of the corrugated members 24, 26, etc. Each '24, 26 is made of the same sheet material as the pad 23, but each structure ^ The cylindrical outer yaks 24, 26 forming the core of section 4 of section 6 have the same axial length from left to right in the drawing, and the lateral width of the VT direction in zone 4 is different to match the pad 23 The inner casing is round and the holes are formed. The members 24, 26 are formed in the same way and include the aforementioned application patents which have been mentioned in the introduction of this document for & i, 18, 6 which are fully referenced. Incorporating the present invention—internally, the device of members 2, 4, 26. The device will be explained in detail with reference to FIGS. 13 to 18 below. ^ It is the degree of curvature on the transverse section It can also be implemented according to a given 22; I 2 is used to form a wave or other shape. I The carrier in this specific embodiment: I. For example, the NOx, HC, and C0 components in the exhaust of the combustion engine are treated. Sheets 28, 24, 26 (and pad 23 in Fig. 2 are shown in plain view) ΛΓ such as 3 X4 British pair sheet (〇 · 91m X1 · 22m) This plate was cut into the size of thin plates 28 does not include a porous sintered 3 /, the other of he foreign metal fibers are described in. Sheet 28 having a high
第15頁 487771 五、發明說明(ίο) 表面積與空洞體積之比,譬如較佳地一空洞體積係佔8 5 % 至9 5 %,且將針對此說明於後。薄板2 8提供一觸媒載體係 包括一多孔性網狀結構。此處使用之「支持於網狀物上 一詞係包括塗覆觸媒於網狀物上以及使觸媒陷於網狀物之 空隙中或兩者兼具。 觸媒之材料可包括任何一已知的燃燒引擎廢氣觸媒材 料。作為範例之材料可包括一分散於網狀物上或陷於其中 之微粒子r —氧化鋁載體。觸媒金屬可選自包括專利第、 4,9 3 9,113號案中所揭露之分散於r鋁之微粒子載體上的 姜巴、銳加上姥之化合物、以及韵、把與錯之混合物。 另’觸媒可由一包含鉑類元素、活性鋁、二氧化錦、一 鎖化合物與一锆化合物的泥漿並且鍛燒載體而沈積於網狀 物上,如美國專利第4, 96 5, 243號。在又一實施例中,、觸 媒可包括譬如第一層及第二層之複數層。第一層包括一載 體,其至少包括一鈀元素、選擇性地一較少量鉑、 ϊ I__jgi 释十生 也一言如二氧化鈽或氧化鍅與粗二氧化鈽之混合物等 5 混合物、選擇性地一氧化鍅成份、選擇性地至少一=, 屬成伤以及選擇性地至少一選自鑭金屬成份與敍金屬八 之稀土金屬成份。苐二層包括一載體、一翻成份、一 、 伤、—已於Pat·專利申請第W0 95/35152號案中揭霖之勺 括一儲存稀氧氣之成份及選擇性地一氧化锆成份包 合物。 j辟氣混 使用之觸媒亦可為一種已商品化並且由已完全參考s 本案之前述Pat· Nos. 4, 965, 243 ; 4, 93 9, 1 1 3 及PCT 1 入 寻利申Page 15 487771 V. Description of the invention (ίο) The ratio of the surface area to the volume of the cavity, for example, a cavity volume is preferably 85 to 95%, and it will be described later. The sheet 28 provides a catalyst carrier system including a porous network structure. As used herein, the term "supporting the mesh" includes coating the catalyst on the mesh and trapping the catalyst in the voids of the mesh or both. The catalyst material may include any A known combustion engine exhaust catalyst material. The material as an example may include a fine particle r-alumina carrier dispersed or trapped in a net. The catalyst metal may be selected from the group consisting of Patent Nos. 4,9 3 9,113 Disclosed in the case are the ginger, ruthenium plus osmium compound, and rhyme, erroneous, and erroneous compounds dispersed on the aluminum particle carrier. In addition, the catalyst can be composed of a platinum-containing element, active aluminum, and dioxide. A slurry of bromine, a lock compound, and a zirconium compound is calcined on a carrier and deposited on a mesh, such as US Patent No. 4,96 5, 243. In yet another embodiment, the catalyst may include, for example, the first Layer and a plurality of layers. The first layer includes a carrier including at least a palladium element, optionally a relatively small amount of platinum, and ϊ I__jgi Shi Shisheng also speaks of rhenium dioxide or rhenium oxide and crude two A mixture of osmium oxide, etc. 5 mixtures, optionally one Chemical element, selectively at least is a wound, and optionally at least one rare earth metal component selected from the group consisting of lanthanum metal component and Syria metal eight. The second layer includes a carrier, a component, a wound,- It has been disclosed in Pat. Patent Application No. WO 95/35152 that a spoon containing a component that stores dilute oxygen and a selective zirconia component inclusion compound. The catalyst used for gas mixing can also be a kind of Commercialized and incorporated into the profit application by the aforementioned Pat · Nos. 4, 965, 243; 4, 93 9, 1 1 3 and PCT 1 with full reference to this case
第16頁 五、發明說明(11) 請第W0 95/35 1 52號案中藉^ 亦可為本技藝中已知的任—種更二w述的型式,其 轉換杰之混合物。 /气燃燒引擎廢氣觸媒 更特別地,形成載具22及觀塾2 鐵線,譬如一鐵線或纖維網、一八凋狀材料包括纖維或 過濾器等。網狀結構可由單一屑蚝或絲網、金屬纖維 複數層可具有-譬如針織鐵線'4 c括複數層’其中 較佳地包括複數鐵線或二、,扁織結構的鐵線層且 體實施例中之載具钟播、I…/ 二維網路材料。在一具 之方向係屬隨機。可使^::丈纖維層或薄板且其中纖維 網。另,可由包括其他非:屬以;f來製作-金屬 金屬氧化物或一陶“形成結合金屬之譬如碳或 在一較佳具體實施例中 成三維之材料網路,此枓包括複數纖維層以形 超過1 〇公厘。化撼一 ^力、載,、之厚度至少5微米且通常不 微米且更佳地至% Γ〇〇=具體實施例^網路的厚度至少50 較佳地1公厘。 Λ /、,亚且通常不超過大約2公厘及 大 較仏地仏小於大約1 50微米及更佳地係小於 八二二/、。在一較佳具體實施例中之纖維厚度或直徑係 ;, 〔至大約3 0微米且較佳地為8 - 2 5微米。 可如同已麥考融入本發明之美國專利第Pat. Nos· 二 3()4’ 330、5’ 0 8 0,9 62 ; 5, 1 02, 74 5 或 5, 0 9 6, 6 6 3 號案中之 4田述來製作該三維網狀結構。然而應了解到,亦可由不同 487771 月 修正 案號 89104266 五、發明說明(12) 於前述專利所說明之步驟來形成此類網狀結構。 本發明中使用之網狀材料結構(網狀結構σ上不罝 具有至少45 %,且較佳地至少55 %及更佳地至少6觸媒) J佳地f少90%之空洞體積,通常空洞體積不致超過。又 ^。此處使用之「空洞體積」一詞係定義為開口社 積除以結構之總體積(開口與網狀枒料之和)再=體 在已完全參考融入本發明之前述於^⑽年工月曰^ ^利申請第6 0 / i i 6,6 4 9號案中亦對於網狀薄板2 8有特月別之描 j板28係使用已知的沈積程序來塗覆觸媒。支持於 、,、。構上之受支持的觸媒可藉一塗覆於用以形成網狀姓槿 鐵線或纖維上而出現在網狀結構、、。冓之 狀結構之空隙中。 稱上及/或表現或保持於網 在一具體實施例中。支持於一 現為塗覆於網狀纟士槿f» ' 載體上之觸媒係表 體再將觸媒加至子載::::構可先塗覆-微粒子載 亡。觸媒之微粒子表;=於,構 氧化鈦、氧化鋇及上述混合物。 一氧化鈽、 4,939, 1 1 3號美國專利及PCT卑:述之苐4,965, 243及 中揭露了特殊組成成份之範例。HW〇 95/仙2號案 上之觸媒可塗覆於網狀物上。=,支持於一微粒子載體 種技藝將具有或不具有觸媒之二吏用譬如浸泡或喷霧等各 上。在塗覆不具有觸媒之微粒=子載體塗覆於網狀結構 包含有觸媒前身之溶液浸透 、體於網狀結構上後,以 得到 教子載體並加熱處理後即可 O:\63\63138.ptc 苐18 2000.09. 26.018 五、發明說明(13) 觸媒。 右ΐ X目m施例中之網狀結構包括複數金屬纖維層,具 9 /l 7 /申β觸媒之微粒子載體可藉由本案所參考之1 998年 ^ -3 „ t t ,,, 網狀觸媒載體上:=觸媒之微粒子載體塗覆於 為-電極及嬖如依據有所: 一鐵線之網狀結構係作 媒之氧化鋁載體的微叙早:之粒子尺寸且具有或不具有觸 以促使較大之粒子黏著可包括溶膠型式之氧化铭 中。施加-橫跨電極之電系懸掛於-溶液 ;,複數纖維所形成的網狀結構;】= : =使 透或浸染結構(包括氧化鋁冷載舜體包括,某’則可藉由浸 或更多促進劑之適去、、容 土设)於包括觸媒及可能具有一 如上所述,ίί=而f觸媒加至觸媒結構上。 於網狀物之空隙中而支持:::::粒子载體陷入或保持 括複數層任意方向纖維之網狀往=上。譬如在製造一包 在製造網狀結構之混合物中,因。=微粒子載體已包括 中之微粒子载體製造^亥 ::持於網狀物空隙 如前述專利中所描述的加入如,網狀結構可 纖维及黏合劑之網狀物令以:f,准素之適當载體至包含 纖維及黏合劑之空隙中的觸構。接著將陷於 軋壓中加熱使得纖維經 ^於一譬如氫氣之降低 上互相連結。另,可在2;?:厂多孔性材料内之接觸點 在-動乳體塵力下將—電流通過材 ///1Page 16 V. Description of the invention (11) Please borrow from the case No. WO 95/35 1 52 ^. It can also be any of the more well-known forms known in the art, which can be converted into a mixture. / Gas combustion engine exhaust catalyst More specifically, the carrier 22 and the watch 2 iron wire are formed, such as an iron wire or fiber web, and eight withered materials including fibers or filters. The mesh structure can be composed of a single chip or wire mesh, and multiple layers of metal fiber can have-for example, knitted iron wires '4 c including multiple layers', which preferably includes multiple iron wires or two, flat iron wire layers and bodies. The carrier clock broadcast, I ... / two-dimensional network material in the embodiment. In one direction is random. It is possible to make a ^ :: fiber layer or sheet and a fiber web therein. In addition, it can be produced by including other than: affixed to-metal metal oxide or a ceramic "to form a combination of metals such as carbon or a three-dimensional network of materials in a preferred embodiment, which includes multiple fiber layers The shape is more than 10 mm. The thickness of the force, load, and thickness is at least 5 micrometers and usually not micrometers and better to% Γ〇〇 = specific embodiment ^ the thickness of the network is at least 50 preferably 1 Mm, Λ / ,, usually not more than about 2 mm, and less than about 150 microns, and more preferably less than 822 /, fiber thickness in a preferred embodiment Or diameter series ;, [to about 30 micrometers and preferably 8 to 25 micrometers. US Patent Pat. Nos. 2 3 () 4 '330, 5' 0 8 which can be incorporated into the present invention as McCaw incorporated. 0,9 62; 5, 1 02, 74 5 or 5, 0 9 6, 6 6 3 to make the three-dimensional network structure. However, it should be understood that different 487771 month amendments can also be made. 89104266 V. Description of the invention (12) The steps described in the aforementioned patent are used to form such a network structure. The network used in the present invention Material structure (with no less than 45%, and preferably at least 55% and more preferably at least 6 catalysts on the mesh structure σ) J Jiadi f less than 90% of the void volume, usually the void volume does not exceed. Again ^ The term "void volume" as used herein is defined as the total opening volume divided by the total volume of the structure (the sum of the openings and the mesh-like material), and then the body is fully incorporated into the present invention, which has been incorporated into the aforementioned year. The monthly application ^ ^ Lee application No. 60 / ii 6,6 4 9 also has a special description for the mesh sheet 28. The plate 28 is coated with a catalyst using a known deposition procedure. Supported by,,,. The supported catalysts on the structure can appear in the net structure by coating on the iron wire or fiber used to form the net surname. In the gaps of the structure of the cricket. Weighing and / or performing or maintaining on the net in a specific embodiment. It is supported on a catalyst-based surface that is now coated on a mesh-like hibiscus f »'carrier, and then the catalyst is added to the carrier :::: structure can be coated first-the particles are killed. Catalyst fine particle surface; = in the structure of titanium oxide, barium oxide and the above mixture. Thorium oxide, U.S. Patent No. 4,939, 113 and PCT: Hum. 4,965, 243 and No. 4, disclose examples of special constituents. The catalyst in HWO 95 / Sin 2 can be coated on the mesh. =, Supported on a microparticle carrier. This technique will be used with or without a catalyst, such as soaking or spraying. After coating the particles without catalyst = the sub-carrier is coated on the mesh structure containing the catalyst precursor and the solution is impregnated and the body is on the mesh structure to obtain the sub-carrier and heat treatment. O: \ 63 \ 63138.ptc 苐 18 2000.09. 26.018 V. Description of the invention (13) Catalyst. Right: The mesh structure in the X mesh example includes a plurality of metal fiber layers, and a fine particle carrier with a 9 / l 7 / sn beta catalyst can be referred to in this case 1 998 ^ -3 „tt ,,, net On the catalyst carrier: = the catalyst's fine particle carrier is coated on the -electrode and if the basis is as follows: a wire structure of the iron wire is used as a microstructure of the alumina carrier as a catalyst: the particle size and have or It does not have a touch to promote the adhesion of larger particles. It can be included in the oxidized inscription of the sol type. The electrical system of the applied-across electrode is suspended in a solution; a network structure formed by a plurality of fibers; The structure (including alumina cold-loaded sintered body includes, a 'can be removed by dipping or more accelerators, and soil containment) to include the catalyst and may have a catalyst as described above, and f catalyst Added to the catalyst structure. Supported in the interstices of the network ::::: The particle carrier is trapped or kept in a network including multiple layers of fibers in any direction toward =. For example, when manufacturing a package and manufacturing a network structure In the mixture, because. = The microparticle carrier is already included in the manufacture of the microparticle carrier The network voids are added as described in the aforementioned patents. For example, the network structure can be a network of fibers and adhesives, so that: f, a suitable carrier of the element to the contact structure in the voids containing the fibers and adhesives. .Then it will be heated in the rolling to make the fibers connect to each other through a reduction such as hydrogen. In addition, the contact point in the porous material of the 2;?: Factory will pass the current under the dynamic milk dust force. Wood /// 1
料來加熱金屬纖維及觸 ^ ^ 之输雊:&銷μ 4觸媒或載體使滅、准在多孔性材料内 、,'、,, 觸…,上相互連結。若f造完成之網狀钍槿勹# 掊於網貼钍搂rb > 右衣I 4狀&構包括保 之微粒子i 粒子載體,則需將保持.於網狀結構中 被拉子,胆次透於觸媒前身且加熱處理以得到 於圖ΐί ί貝:::之鐵線或網狀物鐵線之顯微照片係顯示The material is used to heat the metal fiber and touch the input: & pin μ 4 catalyst or carrier to make it extinguished, quasi-in the porous material, and ',,,, ..., are connected to each other. If the completed net-shaped 钍 hibi 勹 勹 掊 网 网 rb > right garment I 4 & & structure includes Bao's micro-particles i particle carrier, it needs to be maintained. In the net-like structure is pulled, The bile penetrated through the precursor of the catalyst and was heat treated to obtain the micrographs of the iron wire or wire wire in the picture:
彳鈍形成之一電泳塗覆之三向式觸媒之Q 厚的合金纖維薄板上满承 rb ^ir m JM · 屬盘觸拔e舌曰 千圖,其中觸媒之總重量佔金 屬兵觸媒之重$和2 〇 %。 在一範例中,若使用直徑約8—12微米之One of the bluntly formed electrophoretic coated three-way catalysts with a thickness of Q thick alloy fiber sheet is filled with rb ^ ir m JM. It belongs to the disk drawing and tongue diagram, in which the total weight of the catalyst accounts for the metal soldier contact The weight of the media is $ 20%. In an example, if a diameter of about 8-12 microns is used
『更度:易碎且容易永久變形及/或損傷。該薄板係1公尺X 時\ Λ如上所述的形成波形,並且係切割成波形化材料 私、而尺寸。再以譬如丙酮等溶劑清潔該材料以移除污 並且於加熱空氣中乾燥之。可選擇性地將材料於空 =熱至4 0 0 = 7 0 0 c以預先氧化金屬纖維。塗覆觸媒係於— 1 =載^或其中之觸媒懸於水中(膠狀懸浮、流態懸浮)之 匕水中貝轭且金屬薄板係浸於泥漿中。由於泥漿必須浸 產個網狀結構(塗覆空洞内之纖維),因此需具有適當之濕 >行為由於在纖維上產生少許氧化層可提供所需之濕潤 為’因此熱處理係提供了良好之濕潤特性。然而,根據 余才料特性在不需熱處理下僅依照纖維薄板之加工程序及纖 維之濕潤特性即可得到所需之濕潤。此外,在熱處理後需 要小心處理薄板材料以避免受到污染。"More severe: Fragile and easily deformed and / or damaged permanently. When the sheet is 1 meter X, the waveform is formed as described above, and the sheet is cut into a corrugated material with a size. The material is then cleaned with a solvent such as acetone to remove dirt and dried in heated air. Optionally, the material can be pre-oxidized in air = heat to 4 0 = 7 0 0 c. The coated catalyst is -1 yoke in which the catalyst is suspended in water (colloid suspension, fluid suspension) and the metal sheet is immersed in mud. Because the mud must be immersed in a network structure (coating the fibers in the cavity), it must have appropriate wet > behavior. As a little oxide layer on the fiber can provide the required wetting, so the heat treatment system provides a good Wetting characteristics. However, the required wetting can be obtained based on the characteristics of the surplus material without the need for heat treatment, only in accordance with the processing procedure of the fiber sheet and the wetting characteristics of the fiber. In addition, the sheet material must be handled carefully after heat treatment to avoid contamination.
第20頁 487771 五、發明說明(15) 塗覆係實施於& 觸媒粉末之組成係 專利申請案中。# 薄塗覆層於纖維上 明之共同申請之專 述一可用來完成這 空氣乾燥薄板並加 依據塗覆之特性而 2 0 0 - 9 0 0。〇。譬如々 C之熱處理。如此 著力且不致影響觸 在最終之熱處理 為、#殼。這可使用 薄板一齊壓入圖2戶 為形成波形,圖 矩形或菱形多邊形 之圓柱形機殼4中戶丨 有構件8、1〇皆為q 在薄板28上相對 34 °這些凹口及孔 時對正薄板,此係 且結合以下之圖1 3 13至圖18之裝置中 分重要。 含有觸媒粉末之泥漿中,該泥漿包含之 說明於介紹中與觸媒相關之專利及國際 佳地,此泥漿係沈積一譬如1〜1 〇微来之 。已於介紹部份中說明且參考融入本發 利申請第0 9/ 1 5 6, 023號案中更完整地描 種沈積之電泳程序。電泳塗覆後再以熱 以熱處理以使觸媒塗覆結合至纖維上。 在此熱處理期間將薄板材料加熱至大約 丨夺觸媒直接沈積於纖維上時即可實施5 〇 〇 可提供塗覆於纖維表面上時所需要之附 媒特性。 ' 後,單一之波形薄板係組合至觸媒轉換 譬如一靜態混合配置來完成。再將這些 斤示之鋼管機殼4中。 6之薄板28可依據給定之實施條件而為 ,其外圍尺寸可藉由譬如裝置於區段6 千需的尺寸疋義之。由於機殼區段6之所 1行,因此可決定構件之尺寸。 之邊緣處形成兩個四口 3 〇、3 2與孔洞 洞係用於在合模成型裝置中進一步加工 說明於前述申請專利第〇9/181,186號案 至圖18說明之。凹Q之位置與角度在圖 將所需形成之波形對齊薄板外圍時係十Page 20 487771 V. Description of the invention (15) The coating is implemented in the & catalyst powder composition patent application. # Thin coating layer on the fiber The specific description of the co-application can be used to complete the air-drying sheet and add 2 0-9 0 0 depending on the coating characteristics. 〇. For example, heat treatment of 々C. It is so hard and does not affect the heat treatment of the final shell. This can be done by pressing the sheet together into Figure 2 to form a wave shape. The rectangular or diamond-shaped cylindrical case 4 in Figure 4 has components 8, 10 are q. When these recesses and holes are relatively 34 ° on the sheet 28, For the alignment of the thin plate, this is important in combination with the following devices of FIGS. 1 13 to 18. Among the mud containing catalyst powder, the mud contained in the mud is explained in the introduction of the patents related to the catalyst and the best place in the world. This mud is deposited for example from 1 to 10 micrometers. The electrophoresis procedure for the deposition has been described more fully in the introduction section and incorporated into the present application No. 0 9/1 5 6, 023. Electrophoretic coating is followed by heat and heat treatment to bond the catalyst coating to the fibers. During this heat treatment, the sheet material is heated to about 丨 can be implemented when the catalyst is directly deposited on the fiber, which can provide the required catalyst characteristics when coated on the fiber surface. After that, a single corrugated sheet is combined to a catalyst conversion, such as a static hybrid configuration. These are shown in a steel pipe casing 4 again. The thin plate 28 of 6 can be according to the given implementation conditions, and its outer size can be defined by, for example, the size required for installation in the section 6 thousand. Since the casing section 6 is in one row, the size of the component can be determined. Two four holes 30, 32 and holes are formed at the edge of the hole for further processing in the mold clamping device, which are described in the aforementioned application patent No. 09 / 181,186 to FIG.18. The position and angle of the concave Q are ten when the waveforms to be formed are aligned with the periphery of the sheet.
487771 案號 89104266 月 修正 五、發明說明(出) 圖6之薄板2 8係於以下圖1 3至圖1 8所顯示並說明之裝置 中加工以在薄板2 8中形成波形5 〇而形成構件1 8 8。相鄰側 壁51、51’及53、5 3,等形成波形,且該波形定義出根部57 與頂點59。侧壁較佳地傾斜一大約90°之α角(圖8)。該根 部及頂點係沿著平行於軸6 1之線性方向延伸。 圖3及圖4中之構件24、26、54、56係以其軸61相對圖玉 中氣體通過機殼4之流動方向16旋轉一圖25所示之另一角 度P。波浪紋路之方向係與構件之軸6 1的方向一致。定義 之波紋角度P係軸61與流動方向16之間的夾角。p在圖25 中係)I於0。至90。之間且在流動之圖式中係45。,這意味著 相鄰構件之波形係相對旋轉一角度2 p且皆相對方向丨6旋 轉疋義之波紋角度p。在圖2 5左側中,相對於氣體軸向流 動方向1 6較佳地呈4 5〇之通道角度p係提供相鄰薄板之通 道互相相對旋轉2 φ或9〇。。 该波形形成穿透其中之氣體通道。這些通道可在機殼4 外圍表面處之構件邊緣上連通流體。流動之波紋角度$可 依據給定之實施條件而為任一需求之數值。沿方向丨6流入 機殼4之氣體係浸入構件之通道後先以角度ρ流散出再以 9 0°流入相鄰構件而使流向改變9〇。。這種在流動中產生一 紊流係違反了燃燒引擎觸媒轉換器技藝之傳統知識。在這 種表置中並無通過轉換器機殼4且用於產生層流之平行通 具體實施例中’圖2之排(管12之直徑可由大約 5 0公厘增加至大約1 2 〇 :庙B广 厘且區段6係大約長1 5 0公厘。 一般深信不應有爹流在力 /、μ存在之原因在於其將產生不需要之487771 Case No. 89104266 Amended in the fifth, the description of the invention (out) The thin plate 2 8 of FIG. 6 is processed in the device shown and described in the following FIG. 13 to FIG. 18 to form a waveform 50 in the thin plate 28 to form a component. 1 8 8. Adjacent side walls 51, 51 'and 53, 5 3, etc. form a waveform, and the waveform defines a root 57 and a vertex 59. The side walls are preferably inclined at an angle of about 90 ° (Figure 8). The root and apex extend in a linear direction parallel to the axis 61. The components 24, 26, 54, and 56 in Figs. 3 and 4 are rotated with their shafts 61 at another angle P shown in Fig. 25 with respect to the flow direction 16 of the gas passing through the casing 4 in the figure. The direction of the wavy pattern is consistent with the direction of the axis 61 of the component. Definition The corrugation angle P is the angle between the shaft 61 and the flow direction 16. p is in Figure 25) I is at 0. To 90. Between and in the flow pattern is 45. This means that the waveforms of adjacent components are rotated relative to each other by an angle of 2 p and both are rotated relative to the direction of the corrugated angle p. In the left side of Fig. 25, a channel angle p, preferably at 45 ° with respect to the gas axial flow direction 16, provides that the channels of adjacent sheets are rotated relative to each other by 2? Or 90. . This waveform forms a gas channel that penetrates it. These channels can communicate fluid on the edge of the component at the peripheral surface of the casing 4. The ripple angle $ of the flow can be any desired value according to the given implementation conditions. The gas system flowing into the casing 4 in the direction 丨 6 is immersed in the channel of the component, and then flows out at an angle ρ and then flows into the adjacent component at 90 ° to change the flow direction by 90. . This generation of turbulence in the flow violates the traditional knowledge of combustion engine catalyst converter technology. In this table arrangement, the parallel-through specific embodiment that does not pass through the converter housing 4 and is used to generate laminar flow, the row of FIG. 2 (the diameter of the tube 12 can be increased from about 50 mm to about 120: Temple B is wide and section 6 is about 150 mm in length. It is generally believed that the reason why there should be no flow of force /, μ exists because it will produce unnecessary
第22頁 2000.09.26. 023 曰 _案號89104266 c/汐皋么月 五、發明說明((γ) 背七 1 似社或了橫跨轉換器之高壓力降。先前技藝之蜂巢式及類 力g構係形成層流以使橫跨轉換器之壓力降減少,而高壓 依將造成引_動力之損失。在圖22至圖27中,MEC係指 ^ 本發明而使用上述及圖丨2所示之網狀材料的波形網狀 觸反構件結構。較佳地,觸媒「支持於網狀物上」包括使 % $陷於網中及塗覆觸媒於鐵線或纖維上。這可在氣體通 $、3】隙時增加觸媒暴露於氣體中之表面積。為使足夠之氣 辦通f =狀物之間隙而需要一些紊流。這種觸媒表面積之 日加可提高轉換器之工作效率,且相較於先前技藝中每英 寸具有4 0 〇個層流通道之蜂巢式結構而言僅需要較少之觸 媒。 該波形形成紊流產生器,使流過薄板材料孔洞之流體流 ,狀況達到隶佳。紊流產生器係具有數量、尺寸及間隔來 提供流體流過網狀材料大致整個表面上之網狀材料孔洞。 奮流產生器使流體有效地流過材料孔洞,此等孔洞可不大 =,50微米孔徑。若沒有紊流產生器,流體無法有效地流 過夕孔材料之孔洞,這是來自於流體動力學理論。因此, :能促進流過薄板材料相對側之流體之間接觸的結 包括一多孔材料,其平均孔洞尺寸可不大於約5〇微米、 孔材料包括紊流產生器,此紊流產生器可包 > 社 夕 渦流產生器,以促進流體順利流過薄板材=丄\ =結構及 上材料孔洞。 衬抖大致整個表面 比較一實心薄板與一具有9 5 %空洞之〇 · $公 、, 成圖5之構件4 4之1 0微米纖維Μ E C材料的簿 子用乂幵/ 呀,可古+瞀ψ MEC材料將因纖維之大表面積使MEC材料 〇, ^ m 〈表面積為實心材Page 22 2000.09.26. 023 _Case No. 89104266 c / Xiyue Mo Yue 5. Description of the invention ((γ) Beiqi 1 Sishe or high pressure drop across the converter. The honeycomb type and the like of the previous technology The force g system forms a laminar flow so that the pressure drop across the converter is reduced, and the high pressure will cause the loss of gravitational force. In Figure 22 to Figure 27, MEC refers to the invention and uses the above and Figure 丨 2 The wavy mesh-like anti-reverse member structure of the mesh material shown. Preferably, the catalyst "supports on the mesh" includes trapping the% $ in the mesh and coating the catalyst on iron wires or fibers. This may Increasing the surface area of the catalyst exposed to the gas when the gas flow gap is 3, some turbulence is needed in order to make enough gas flow to f = the gap. The increase of the surface area of this catalyst can increase the converter Compared with the honeycomb structure with 400 laminar flow channels per inch in the prior art, it requires less catalyst. This waveform forms a turbulence generator, which allows the flow through the holes of the sheet material. Fluid flow in perfect condition. Turbulence generators are available in quantity, size and spacing The fluid flows through the pores of the reticular material on the entire surface of the reticular material. The flow generator effectively flows the pores of the material, and these pores can be small, with a pore size of 50 microns. Without a turbulent generator, the fluid cannot be effective Ground flow through the pores of the pore material, which is derived from the theory of fluid dynamics. Therefore, the junction that can promote the contact between the fluids flowing through the opposite sides of the sheet material includes a porous material whose average pore size may not be greater than about 5 〇micron, pore material includes turbulence generator, this turbulence generator can be included> Shexi vortex generator, to promote the smooth flow of fluid through the thin plate = 丄 \ = structure and upper material holes. Comparison of the lining chattering about the entire surface A solid sheet and a 95% hollow hole. The component of Figure 4 is 4 to 10 micron fiber. The material for the EC material is 呀 / ,, 柯 古 + 瞀 ψ MEC material will be The large surface area makes MEC materials 0, ^ m <surface area is solid
第23頁Page 23
2001.08. 02.024 O:\63\63138.ptc 487771 案號 89104266 b年&月 曰 修正 / -t- 五、發明說明((7⑼ 料之5倍。增加MEC材料之厚度、減小纖維之直徑、及減少 空洞即可增加表面積。若僅完全塗覆5 0 %之纖維,則暴露 之表面積仍為金覆之實心薄板的2. 5倍。先前技藝之觸媒 轉換器皆提供實心表面而非具有貫穿孔之多孔性材料。 在範例中假設一先前技藝之單體基底具有一大約5 0 0平 方公尺/立方公尺之薄板表面積,而整體尺寸大致相等之 MEC材料轉換器的有效面積為25 0 0平方公尺/立方公尺。圖 2中區段6構件之前端堵塞面積根據使用之薄板厚度而通常 僅大約佔機殼4在區段6中定義之總前端面積的10 %-20 % 〇 m1*1 0 ❿2001.08. 02.024 O: \ 63 \ 63138.ptc 487771 Case No. 89104266 Year B & Month Amendment / -t- V. Description of the invention ((7 times 5 times the material. Increase the thickness of the MEC material, reduce the fiber diameter, And reducing the cavity can increase the surface area. If only 50% of the fiber is completely coated, the exposed surface area is still 2.5 times that of the solid sheet covered with gold. The catalyst converters of the previous technology all provide solid surfaces instead of having Porous material with through holes. In the example, it is assumed that a single substrate of the prior art has a thin plate surface area of about 500 square meters per cubic meter, and the effective area of the MEC material converter with an approximately equal overall size is 25. 0 0 m2 / m3. The blockage area at the front end of the member in section 6 in Figure 2 usually only accounts for about 10% -20 of the total front end area defined by the case 4 in section 6 depending on the thickness of the sheet used. % 〇m1 * 1 0 ❿
O:\63\63138.ptc 第2ia頁 2001.08.02.025 487771 五、發明說明(18) 陶瓷基底具有厚度〇· 2-0· 5公厘之較厚的障壁。一典型 的方形早體之每平方英吋具有2〇〇 — 4〇〇個單元且表面積介 於1 5 0 0至3 0 0 0平方公尺/立方公尺之 % 覆觸媒之2 0 0 0平方公尺/六十γ 口么— ^丄⑽义塗 堵塞大約25 %-30% 3么尺:有效面積。前端面積 薄金屬薄板、= i前技藝轉換器係使用 一層皆藉由一平蛔入屈度之弦波型波形、高1公厘且每 度及每平方英吋ί :單::ί隔之,其根據使用之薄板厚 方公尺/立方公尺之有1而社里而具有一大約20⑽―40 0 0平 塞。 々積及一大約10 — 20%之前端堵 用於汽車之觸媒之轉換本質上 氣態-固態之物質傳遞。先前技蓺::刀快速,但卻受限於 流/而在層流中傳遞物質係小於^ 換器中係表現出層 有效利用觸媒。圖2中區段6之^了 /泉中者一級,因此無法 高於層流配置的物質傳遞而加$ =型波形構件產生紊流及 傳遞之效果在達到廢氣轉換點媒之效能。較高之物質 使用譬如以下圖7至圖8所說明之诹別顯著。又,或另,可 在廢氣轉換點之前,塗覆之鐵二凌產生器來產生紊流。 廢氣轉換點之時間較短及大的、内、f狀物的主要優點係到達 的操作期間仍有較高之轉換。目二面積以允許在較無效率 器並非操作於紊流區域中,此=使用單體轉換器之轉換 以足夠低之壓力降流過而喪失許、^道之寬度足夠讓奮流 分之轉換㉗率。“發明之網⑼面積以致無法達成充 時,將特別利用到材料厚 :構中,倘若為紊流 主要^ 487771O: \ 63 \ 63138.ptc Page 2ia 2001.08.02.025 487771 V. Description of the invention (18) The ceramic substrate has a thick barrier with a thickness of 0.2-0.5 mm. A typical square-shaped early body has 200-400 units per square inch and has a surface area between 15 and 300 square meters per cubic meter. 0 square meters / sixty γ mouth — ^ Yi Yi clogged about 25% -30% 3 metric feet: effective area. The front end area is a thin metal sheet, and the front-end converter uses a layer of sinusoidal wave shape with a flat inclination, a height of 1 mm, and a degree and a square inch. : Single :: ί It has a thickness of about 20⑽-40 00 pin according to the thickness of the thin plate used per square meter / cubic meter. Accumulation and an end plug of about 10-20% before the conversion of catalysts used in automobiles is essentially a gas-solid material transfer. Previous technology :: The knife is fast, but it is limited by the flow / and the material transfer in the laminar flow is smaller than that in the converter, which shows that the layer uses the catalyst effectively. In Figure 2, section 6 is the first level of / spring, so it cannot be higher than the material transfer of the laminar flow configuration. The effect of the turbulence and transfer generated by the addition of the $ = wave-shaped component is to achieve the efficiency of the exhaust point conversion medium. The use of higher substances, such as those illustrated in Figures 7 to 8 below, is significant. In addition, or alternatively, a turbulent flow can be generated by a coated iron dipole generator before the exhaust gas switching point. The main advantage of the short exhaust gas switching point and the large, internal, and f-shaped objects is that there is still a high conversion during the operation period reached. The area of the mesh is to allow the less efficient device not to operate in the turbulent flow area. This = the conversion using a single converter flows at a sufficiently low pressure drop to lose the allowance, and the width of the channel is sufficient for the conversion of endurance points. Rate. "The area of the mesh of the invention is too large to achieve sufficient time, and will be especially used for material thickness: structure, if it is turbulent, mainly ^ 487771
五、發明說明(19) 暴露之纖維的表面積係足夠大以得到所需之轉換致率,若 氣體進入材料之空/同中’則必須藉由來自通道區域中之氣 體取代之,即通道之間必須有〜微小壓力矣·以利用主要 部,即材料内部之$媒。是以,需藉產生紊流來獲致所需 之壓力差及造成物質傳遞。在~單體中之通道之間並無氣 體流通。 形成構件之網狀材料在無塗覆時之每立方公分重量一般 為對應之典塑單體基底者(〇·5公克/立方公分)之半(〇·2公 克/立方公分),此量對一般之轉換器而言係減少3〇〇公 克。是以,網狀材料遠輕於此類單^。0 單體中之壓力損失依據層流之特徵幾平隨物質流動而韓 性增加,而波形MEC結構中之壓力損失則因紊流之特徵而 隨著物質流動率呈二次方增加(參閱圖。在中, ^ 4 50 ^^^^^^ ^^ 由至屬溥板衣成並呈4 5。,陶瓷綠里彳 — 具有4〇°個通道、-第二㈣=== m(r閱圖25中之波紋方向角度"p本說明中之角 :計算出的且夕數頂據/系表示mec波形材料在波、欲角度6〇。時之 n中:有二曲線。如圖26所示,45◦角於一速度區 線性之壓力降而一蜂巢式結構則具有-線性V. Description of the invention (19) The surface area of the exposed fiber is large enough to obtain the required conversion efficiencies. If the gas enters the space / uniformity of the material, it must be replaced by the gas from the channel area, that is, the channel There must be ~ slight pressure in order to use the main part, that is, the $ medium inside the material. Therefore, it is necessary to obtain the required pressure difference and cause material transfer by generating turbulence. There is no gas circulation between the channels in the ~ monomer. The weight per cubic centimeter of the mesh material forming the component when not coated is generally half of the corresponding standard plastic monomer base (0.5 g / cm3) (0.2 g / cm3). Generally speaking, the reduction is 300 grams. Therefore, the mesh material is much lighter than this kind of single ^. 0 The pressure loss in the monomer increases with the flow of the material, which increases with the flow of the material, while the pressure loss in the waveform MEC structure increases quadratically with the flow of the material due to the characteristics of the turbulence (see figure). In the, ^ 4 50 ^^^^^^ ^^ is made from the genus 溥 lining and is 45., ceramic green 彳 彳-has 40 ° channels,-second ㈣ === m (r See the angle of the corrugation direction in Fig. 25. The angle in this description: the calculated data and the data / means that the mec waveform material is at the wave and the desired angle is 60. In the time n, there are two curves. As shown in the figure As shown in Fig. 26, the linear pressure drop at 45 ° in a velocity zone and a honeycomb structure has -linearity.
五、發明說明(20) — ^广尺/秒。當然、’其他譬如材料厚度、構件數量、多孔 t復等因素亦與材料特徵有關,特別是對於塗覆時明 顯減少前端面積的單體而言。 換Ϊ 2接至圖4之MEC波形元件到達廢氣轉換點之時間,即轉 兩件於冷起動期間達到譬如大約3 0 0 - 3 5 0 °C之操作溫 二〇隹而且1日〔良係退小於單體結構者。P旬瓷之熱容量大約為 _κ,\耳2斤],而鋼及錄之熱容量則為46 0焦耳/公斤 公升且她二片系統之熱容量(4〇0通道/英吋)係3 75焦耳/Κ* 80- 1 0 0、ί =二相近之微細鐵線網狀轉換器之熱容量係 陶瓷基^之单升。MEC構件之總密度係小於目前使用之 而傳統轉換器則需赶j氣轉換點之時間少於1分鐘 僅能少呼或奸1 Γ 鐘。如此將大幅降低冷起動時 維較蜂巢單體高的導熱率& N〇X H(^C0。金屬纖 勺溫上: 將造成 之初始時藉電流二:3廢虱轉換點之時間,可在引擎啟動 結構至一特定、、w ^料來加熱纖維及觸媒以有效地加熱 -般用於C氣反應。 屬結合稀土族全屬i = t料包括譬如麵、鈀及铑等貴重金 需轉換之排放如二氧化錦、氧化錯等,典型上 係使用-暖機型觸=⑶及Hc。某些傳統之轉換器 期間吸收碳氫化合物=11杰、觸媒以在引擎及轉換器暖機V. Description of the invention (20) — ^ Wide feet / second. Of course, other factors such as material thickness, number of components, and porosity are also related to the characteristics of the material, especially for monomers that significantly reduce the front end area during coating. Change Ϊ 2 to the time when the MEC waveform element in Figure 4 reaches the exhaust gas switching point, that is, to turn two pieces to reach an operating temperature of about 300 ° C to 3 ° C during a cold start, and 1 day [good system Those who are smaller than the monomer structure. The thermal capacity of P Xun porcelain is about _κ, \ ear 2 kg], while the thermal capacity of steel and recording is 460 joules / kg liter and the thermal capacity of her two-chip system (400 channels / inch) is 3 75 joules. / Κ * 80- 1 0 0, ί = The heat capacity of two similar fine iron wire mesh converters is a single liter of ceramic substrate. The total density of MEC components is less than that currently used, while traditional converters need less than 1 minute to catch up to the gas switching point, and can only reduce the number of calls or 1 ^ clock. This will greatly reduce the thermal conductivity that is higher than the honeycomb monomer during cold start & NoxH (^ C0. On the temperature of the metal fiber spoon: It will cause the initial borrowing time of the current 2: 3 waste lice conversion point, which can be Engine starting structure to a specific, w ^ material to heat the fiber and catalyst for effective heating-generally used in the C gas reaction. It is a combination of rare earths and all i = t materials including precious metals such as noodles, palladium and rhodium. Emissions from conversions such as dioxide, oxidation, etc. are typically used-warm type contacts = ⑶ and Hc. Some traditional converters absorb hydrocarbons = 11 times, catalyst to warm the engine and converter machine
第26頁 487771 五、發明說明(21) 本發明之一轉換器重約1 5 0公克/公升而金屬單體轉換器 則為8 0 0公克/公升。本發明之塗覆纖維之可觸及的觸媒活 性表面在每公尺中大約有3平方公尺。 一具體實施例中之微細鐵線包括2 0微米粗、具有9 0 %空 洞之鐵-鉻-鋁合金鐵線及厚〇. 8公厘之薄板,這將造成一 載具結構具有一 〇. 3平方公尺/每公升結構體機之幾何表面 及3. 8平方公尺之纖維内表面。一傳統之單體薄片表面係 大約3平方公尺/每公升結構體積。觸媒糸統之體積活性係 根據可觸及之活性表面而定。此類結構在纖維直徑更小時 其内表面積將更大,這將增加每單位體積之塗覆面積。傳 統之轉換器係表現出一 3平方公尺/每公升結構體積之薄板 表面。參考表1係以一為細鐵線網狀轉換器材料之數值作 為範例。 表 1 纖維直徑 纖維表面 每公升之150公克纖維 /公升觸媒轉換器中的 纖維表面 20微米 26平方公尺/公斤 3. 9平方公尺 10微米 52平方公尺/公斤 7. 8平方公尺 5微米 105平方公尺/公斤 16平方公尺 由表1可歸納出,減少纖維之直徑將可大幅增加轉換器Page 26 487771 V. Description of the invention (21) One of the converters of the present invention weighs about 150 grams per liter and the metal monomer converter is about 800 grams per liter. The accessible catalytic active surface of the coated fiber of the present invention is approximately 3 square meters per meter. The fine iron wire in a specific embodiment includes a 20 micron thick iron-chromium-aluminum alloy iron wire with 90% voids and a thin plate with a thickness of 0.8 mm, which will result in a carrier structure with 0.1 The geometric surface of the structure machine of 3 square meters per liter and the inner surface of the fiber of 3.8 square meters. The surface of a conventional monolithic sheet is approximately 3 square meters per liter of structural volume. The volumetric activity of the catalyst system is based on the accessible active surface. Such structures will have a larger internal surface area at smaller fiber diameters, which will increase the coating area per unit volume. Traditional converters exhibit a thin plate surface of 3 square meters per liter of structural volume. Reference Table 1 is based on a numerical value of a thin iron wire mesh converter material as an example. Table 1 Fiber diameter Fiber surface of 150 grams per liter of fiber per liter of fiber in the catalyst converter 20 microns 26 square meters / kg 3. 9 square meters 10 microns 52 square meters / kg 7.8 square meters 5 micrometers 105 square meters / kg 16 square meters can be summarized in Table 1, reducing the fiber diameter will greatly increase the converter
第27頁 487771 修正 案號 89104266 五、發明說明(ϋ) _____ 之體積活性,如此可達成較佳之轉換特性及/或縮小 器之尺寸。 、 一用於形成 >皮形且選擇性地形成_流產生氣之裝置69係 顯示於圖13及圖14中。圖7及圖8之具體實施例中,除參 f 13 f圖“外亦可參考上述申請專利第〇9/i i案 卜薄板28(見圖6)係置於各別的上及下 隹貪杈板58與60之間,且該兩板分別具有相對之互相 的線性脊組62(由於圖式之比例過/ 者)(參閱上述專利申請中更詳細之朽、:^看出上方拉板中 η n η t 又#、·、田之圖式)以及切刀模6 4盥 。刀刀模64與66係在薄板28中形成 ^ 與63係在其中產生溝槽, L屋生15且含部62 形成波形。然而應了解至,卜薄板°;』後。該溝槽係輔助 僅形成波形。以下月之^ 形成渴流產生器且 卜辦5兄明之圖2 2至圖2 7之圖矣gp古μ # 不具有渦流產生器之波形薄板2 8。之S表即有關於— f置69於初始時形成之薄板28 產生器。該裝置包括 子^匕括溝槽及渦流 連接至基座72ί 具有—基座72之基座總成7G、-對 μ㈣成76之圓柱形導引及支 動操縱桿-ΪίΐίΪ成78支持於該支持柱上。藉由手 的操作裝置沿垂直方裝置或其他動力源(未顯示) 一氣壓裝置可藉提供二#;ς =上部總成π以變換位置。 基座總成70包括八#乱體緩衝以提供一阻尼作用。 座72之固定板G :定位導引銷82及螺栓84而固定至義 板82。每-導弓銷8::車列導引銷84係固定至基座72且穿5 導引_係以可滑動式安裝於一:過 O:\63\63138.ptc 第28頁 2000.09.26.029 4^7771Page 27 487771 Amendment No. 89104266 V. Description of the invention (ϋ) _____ Volume activity, so as to achieve better conversion characteristics and / or reducer size. A device 69 for forming > skin shape and selectively forming a stream-generating gas is shown in Figs. 13 and 14. In the specific embodiments of FIG. 7 and FIG. 8, in addition to the f 13 f drawing, reference may also be made to the above-mentioned application patent No. 09 / ii. The thin plate 28 (see FIG. 6) is placed on each of the upper and lower ridges. Between the fork plates 58 and 60, and the two plates respectively have linear ridge groups 62 opposite each other (because the scale of the figure is over) (see the above detailed patent application for details): Η n η t (# 、 · 、 田 之 Schematics) and the cutting die 64. The cutting die 64 and 66 are formed in the thin plate 28 and the 63 are formed in the groove, and L 屋 生 15 and含 部 62 forms a waveform. However, it should be understood that the thin plate °; ”. The groove system assists in forming only a waveform. The following month ^ forms a thirsty current generator and maps 5 to 2 of Figure 2 to Figure 2 of 7 Figure 矣 gp 古 μ # Wave sheet without eddy current generator 2 8. The S table is relevant-f set 69 is a thin plate 28 generator formed at the beginning. The device includes a dagger groove and eddy current connection to The base 72ί has—the base assembly 7G of the base 72, a cylindrical guiding and supporting joystick-ΪίΐίΪ 成 78 supporting the μ76, supported on the support column. The operating device is along a vertical device or other power source (not shown). A pneumatic device can provide two #; ς = upper assembly π to change the position. The base assembly 70 includes eight # chaos buffer to provide a damping effect. The fixing plate G of the seat 72 is fixed to the prosthetic plate 82 by positioning the guide pin 82 and the bolt 84. Each guide pin 8 :: the train guide pin 84 is fixed to the base 72 and wears 5 guides_system Sliding installation on one: Over O: \ 63 \ 63138.ptc Page 28 2000.09.26.029 4 ^ 7771
I"陣f =四個螺栓銷92係固定至固定板82且通過固定板 中心合至y 4 ’並且該銷9 2亦位於模板6 〇内之配合孔中。 一壓、=彈簧96係位於每一容室94中且沿方向8〇,垂直向上 推動模板60。銷85係配合於套筒88内之孔洞並在其中滑動 以在板60移動期間導引板6〇。 一陣列二角形切刀模6 6係固定於一相對固定板之一陣列 孔洞6 7内。該切刀模在形成一中間階段之薄板2 8,時於薄 板28(圖6)中形成渦流產生器36、36,(圖9至圖⑴。如上 述,渦流產生器係依據給定之實施條件而選擇是否裝設。 譬如另-型式之渦流產生器36、36,係為薄板28,之薄板材 料鏡射之三角形翼片。產生器36、36,係依據給定之構件 波形设汁排列成平行之線性陣列。該產生器之方向、形 狀、數量及;皮形係依據給定之實施條#而定且將顯示於圖 式辄例中。譬如圖5中之構件188包括在一波形5〇之一側上 之兩m產生器46、48及在波形之第二側上之兩列產 生器46,、48’。產生器46、46,係在一 件24 : 26 (圖3)上。自薄板材料朝一方向延伸如圖8之成單一列 t 產生㈣、48’係朝相&方向延伸如圖8之單- 列產生β 4 0。 -满流產生器切刀66包括一第一圓柱形柄,其係配合於I " array f = four bolt pins 92 are fixed to the fixing plate 82 and are joined to y 4 ′ through the center of the fixing plate, and the pin 9 2 is also located in a fitting hole in the template 60. A pressure == spring 96 is located in each container 94 and pushes the template 60 vertically upward in the direction of 80. The pin 85 fits into a hole in the sleeve 88 and slides therein to guide the plate 60 during the movement of the plate 60. An array of dichroic cutters 6 6 is fixed in an array hole 6 7 of an opposite fixed plate. The cutter die forms a vortex generator 36, 36 in the lamella 28 (Fig. 6) when forming a thin plate 28 in an intermediate stage (Fig. 9 to Fig. ⑴. As mentioned above, the vortex generator is based on the given implementation conditions. And choose whether to install. For example, another type of eddy current generators 36, 36 are thin plates 28, and the triangular mirrors of the thin plate material mirror. The generators 36, 36 are arranged in parallel according to the given component waveform. The linear shape of the generator. The direction, shape, number, and shape of the generator; the skin shape is determined according to the given implementation # and will be shown in the example of the figure. For example, the component 188 in FIG. 5 includes a waveform 50 Two m generators 46, 48 on one side and two rows of generators 46, 48 'on the second side of the waveform. The generators 46, 46 are tied to a piece of 24:26 (Figure 3). Since The sheet material extends in one direction as shown in FIG. 8 in a single column t to generate ㈣, 48 ′ is extended in the phase & direction as shown in FIG. 8-the column generates β 4 0.-The full-flow generator cutter 66 includes a first cylinder Shaped handle
2000.09.26. 030 487771 五、發明說明(24) 孔洞67中且可壓配入孔洞67 柄延伸者係一在平面圖中為二=固定至固定板82。自第一 第二柄之一側上逐漸縮小成形之第二柄。切刀邊緣在 錐形邊緣形成一具有又一錐形=且第二側之不同錐形上之 三個錐形切刀邊緣係突出至固a緣之一錐形切割表面。這 成圖9之渦流產生器36、3 6,=板82上方。該切刀係以形 板82。該第二柄及附加苴 而之陣列型式而固定至固定 方。 切刀邊緣延伸至固定板8 2上 可動式下方模板係以可 動。該可動式下方模板係二^至導引銷以垂直運 6。正常時係位於垂直上的;:=持=菁%上。可動板 ;"复數孔洞98 ’其中每-孔洞係配合1 = =!:陣 之上靜止位置時的頂面1〇〇下方。可動式下方:板㈣ 方薄板材料工作位置允許切割緣突出/ 方杈板之最下 上方。可動板60之位移量係取決於固定板心::1』0之 =凸Γ動ΐ具有相對於包含有切刀之頂面_的四: 卜圍凸起之三角形平頂區域1〇2。該凸起區域ι〇2使 100形成一菱形凹部以容納微細鐵線之薄板材料。、 可動板60之頂面100較佳地具有一陣列由此延伸之直立 =性脊62。脊部62係平行且㈣距,—陣列之切刀模 排=於相鄰脊部之間且切刀模亦在垂直脊部之方向上性 :背。脊部62之高度h較佳地大約〇. 4公厘或大約為薄板28 厚度之50 %。此具體實施例中之脊部62之較佳厚度大約 第30頁 五、發明說明(25) 〇邻4二。之平行側較佳地具有圓弧邊緣。然而。脊 向截面可為譬如矩形或三角形等其他形狀。 含於在薄板材料28’中形成下凹溝槽之表面特 Ϊ哎是在圖9至圖11之薄板28’的下側中形成摺 痕或l迢38。脊部62壓入薄板28,之量恰 =r;:6Trio°的高度。薄板28之寬闊== 表面100而不致在脊部62與形成之指痕 動期間=2 薄板28材料。導引銷係於可動板60移 此二二Γ至圖11之通道38可由切割裝置(未顯示)形成, 匕日,可選擇是否需要位於可動式模板上之脊部。)一第成 j(干 =:)係固持薄板材料,在該第二裝置中之長孔(未衣 料中切割出通切道剔裝置在不使材制縮變形之條件下於材 可動式模板6 0之運動|你彳# +77 π w 6〇之表面刚上方—段距里/以使*切f切割緣突出於板 器36、36,。此運動板8且形成渦流產生 的間隙設定之固定與可動式模板82、60之間 所^且3 Κ部,76係如前述專利中請第G9/181,186號宰 用: = :ί = ;104,其中該基板具有-凹部 示)。一手動操曰调整移動支持板104之機構(未顯 K。基板i 04係藉由轴=示成二:;f直方_ 成76之正常靜止::/總成78沿柱型件74垂直滑動。總 位置係位於方向80,上之最上方位置。 487771 五、發明說明(26) 上方模板5 8係以一可動式彈性地固定至基板1 〇 4以在方 向80上相對移動。一陣列孔洞68係位於上方模板58中。該 孔洞係垂直對齊下方可動模板中之切刀模66.。孔洞“之尺 寸與位置係設計成容納下方可動式模板中之切刀模66。一 相似於上方可動式模板中之孔洞的孔洞第二部係位於下方 可動式模板60中以容納固定於固定上方支持基板1〇4的切 刀模64。一相同於下方切刀模之上方切刀模第二部係固 的固ί上方板104。圖9至圖11中之下方可動式模板 刀刀杈係用於形成渦流產生器36,且上方板58中之 用於形成渦流產生器4。。切刀模較佳地係伸入相 十之上方及下方可動式模板中相對應的孔洞。 r ί :模板58係藉由螺栓導弓丨銷及配合之壓縮彈箬1〇6而 :固固定的基板104,且又-上方固定板115 陣列定位:二::相二於下部總 及115定位並導引可動】上方、1筒110係相對於上方板104 係固+ 板58。定位銷及螺栓112、 上方可動式模板58之表面iiR目 動式模板60之一陣列脊部63(由/、有從該表面朝向下方可 於圖中)。脊部6 3係線性且互相^圖式之比例而無法顯示 間距與下方板60之脊部62的間距7的等間距設置,且該 些脊部63亦於薄板材料28中形.=相等但垂直地交錯。這 特徵且其他使用切當裝置(未 ^如圖11中通道42之表面 ”、、、不)來切割出通道42時可選2000.09.26. 030 487771 V. Description of the invention (24) The hole 67 is press fit into the hole 67. The handle extension 1 is two in the plan view = fixed to the fixing plate 82. The formed second handle is gradually reduced from one side of the first second handle. The cutter edge forms a conical cutting surface with another cone on the tapered edge, and three tapered cutter edges on different cones on the second side protrude to one of the solid edges. This becomes the vortex generators 36, 36 in FIG. 9 above the plate 82. The cutter is attached to a shape plate 82. The second handle and the additional array are fixed to the fixed square. The edge of the cutter extends to the fixed plate 82. The movable lower template is movable. The movable lower template is moved to the guide pin for vertical transportation 6. Normally, it is located vertically;: = holding = percentage. Movable plate; " A plurality of holes 98 ', where each -hole system is fitted with 1 = = !: array at the top position below 100. Movable bottom: plate ㈣ square sheet material working position allows cutting edge to protrude / bottom of square plate. The amount of displacement of the movable plate 60 depends on the fixed plate center: 1′0 ′ = convex, which has four relative to the top surface containing the cutting blade_: a triangular flat-topped area of the raised periphery 102. The raised area ι02 forms a diamond-shaped recessed portion 100 to accommodate the thin plate material of the fine iron wire. The top surface 100 of the movable plate 60 preferably has an upright ridge 62 extending from the array. The ridges 62 are parallel and spaced apart from each other—the array of cutter patterns is arranged between adjacent ridges and the cutter patterns are also oriented in the direction of the vertical ridges: back. The height h of the ridge 62 is preferably about 0.4 mm or about 50% of the thickness of the thin plate 28. The preferred thickness of the ridge portion 62 in this embodiment is approximately page 30. V. INTRODUCTION TO THE INVENTION (25) 〇 Neighboring 42. The parallel sides preferably have rounded edges. however. The ridge section can be other shapes such as rectangular or triangular. Included in the surface forming recessed grooves in the sheet material 28 'is that a crease or 迢 38 is formed in the lower side of the sheet 28' in Figs. 9 to 11. The ridge 62 is pressed into the thin plate 28 by an amount equal to the height of r;: 6Trio °. The width of the sheet 28 == the surface 100 without the ridges 62 and the formed finger marks during the movement of the sheet 28 = 2 sheet 28 material. The guide pin is connected to the movable plate 60. The two channels Γ to FIG. 11 can be formed by a cutting device (not shown). On the day, you can choose whether a ridge on the movable template is needed. ) A first j (dry = :) is used to hold the sheet material, and the through hole (uncut material in the uncut material) is cut through the cutout device in the second device to move the template on the material without shrinking the material. 6 0 的 运动 | 你 彳 # +77 π w 6〇The surface is just above—in the span / to make the * cut f cutting edge protrude from the plates 36, 36. This movement plate 8 sets the gap created by the eddy current Between the fixed and movable formwork 82, 60, and 3K, 76 is as described in the aforementioned patent, please use No. G9 / 181, 186: =: ί =; 104, where the substrate has a -recessed part) . A manual operation is to adjust the mechanism of the mobile support plate 104 (not shown K. The base plate i 04 is shown by the axis = normal two :; f histogram _ into 76 normal stationary: / assembly 78 slides vertically along the column 74 The total position is located at the uppermost position in the direction 80. 487771 V. Description of the invention (26) The upper template 5 8 is fixed to the substrate 104 by a movable elasticity to relatively move in the direction 80. An array of holes The 68 series is located in the upper template 58. The hole is vertically aligned with the cutter die 66 in the lower movable template. The size and position of the hole "is designed to accommodate the cutter 66 in the lower movable template. A similar to the upper movable The second part of the hole in the template is located in the lower movable template 60 to accommodate the cutter die 64 fixed to the fixed upper support substrate 104. One is the same as the upper part of the lower cutter die. Fasten the upper plate 104. The lower movable template knife blades in Figs. 9 to 11 are used to form the eddy current generator 36, and the upper plate 58 is used to form the eddy current generator 4. The cutting die It is preferably extended above and below the movable mold of phase ten. The corresponding hole in the center. R ί: The template 58 is a bolt guide bow pin and a matched compression spring 106. The base plate 104 is fixed, and the upper fixing plate 115 is arrayed. Two in the lower total 115 position and guide the moveable] upper, 1 barrel 110 is fastened + plate 58 relative to the upper plate 104. Locating pins and bolts 112, one of the surface iiR eye-moving template 60 on the movable plate 58 above Array ridges 63 (from the surface to the bottom can be seen in the figure). The ridges 6 and 3 are linear and mutually proportional to each other and cannot display the distance between the ridges 63 and the ridges 62 of the lower plate 60. The distance is set, and the ridges 63 are also shaped in the sheet material 28. = equal but staggered vertically. This feature and others use a proper device (not ^ as in the surface of the channel 42 in Fig. 11, ",,, not) to Optional when cutting out channel 42
487771 五、發明說明(27) 擇是否需要該脊部。上部總成76中之一陣列切刀模64係排 列於相鄰脊部63之間。切刀模64係沿著一垂直於上可動式 模板58之脊部的方向線性排列。上方板之脊.部63之高度較 佳地大約為0. 4公厘或大約為圖6薄板28之厚度的5〇 % ^本 具體實施例之脊部63之厚度較佳地亦大約為〇· 4公厘,且 。亥脊。卩之平行側具有一較佳地圓弧邊緣。然而,脊部之端 部或橫向截面可為譬如矩形或三角形等其他形狀。下方及 上方可動式模板之脊部較佳地係相同。 之:Γ:i有其他尺寸,範例中之高度及寬度僅供-給定 材料使用,,中高度可設定為將壓縮程度最小化者 2 i:設定於一可將受壓縮之薄板材料2 8之表面積最小 化的數值。 上方可動式模板58具有相對於一中間表面丨丨6之四個外 圍三角形平頂區域118。該凸起區域使該中間表面 形成一愛形凹部以容納為細鐵線之薄板材料。凸起區域 1^8重疊於且對齊於下方可動式模板6〇上之凸起區域丨〇2。 ^咖及60之凸起區域鄰接時,上方及下方板之凹部將形 ^一早一$室。料室之垂直厚度足以使設置於室 中之薄板不致在該容室為了形成圖u之渴流產生器36、4〇 =通道38、42(圖⑴而閉合時遭受可動式模 面的壓縮。波形或摺痕通道42係由上方可動式模板Μ中之 脊部63形成。包含有切刀模之中間表面於型 ;生器期間僅接觸板28’。上方及下方模板之鄰接區域。限 制了脊部62與63為了形成圖11之摺痕38、42而壓縮進入薄487771 V. Description of Invention (27) Choose whether the spine is needed. One of the array cutters 64 in the upper assembly 76 is arranged between the adjacent ridges 63. The cutter dies 64 are linearly arranged along a direction perpendicular to the ridges of the upper movable die plate 58. The height of the ridge portion 63 of the upper plate is preferably approximately 0.4 mm or approximately 50% of the thickness of the thin plate 28 of FIG. 6 ^ The thickness of the ridge portion 63 of this embodiment is also preferably approximately 0. · 4 mm, and. Hai Ridge. The parallel sides of the cymbal have a preferably rounded edge. However, the ends or lateral cross sections of the ridges may be other shapes such as rectangular or triangular. The ridges of the lower and upper movable formwork are preferably the same. Of: Γ: i has other dimensions. The height and width in the example are only for a given material. The middle height can be set to minimize the compression degree 2 i: Set to a thin plate material that can be compressed 2 8 The minimum surface area. The upper movable formwork 58 has four peripheral triangular flat-top regions 118 with respect to a middle surface 6. The raised area forms a love-shaped recess on the intermediate surface to accommodate a thin plate material of thin iron wire. The raised area 1 ^ 8 overlaps and is aligned with the raised area 〇2 on the movable template 60 below. ^ When the raised areas of coffee and 60 are contiguous, the recesses of the upper and lower plates will be shaped ^ one morning and one room. The vertical thickness of the material chamber is sufficient to prevent the thin plate provided in the chamber from being compressed by the movable mold surface when the container is closed to form a thirst flow generator 36, 40 = channels 38, 42 (picture ⑴). The wavy or crease channel 42 is formed by the ridge 63 in the upper movable template M. The intermediate surface containing the cutter die is shaped; only the plate 28 'is contacted during the life. The adjacent areas of the upper and lower templates are restricted. The ridges 62 and 63 are compressed into thin portions in order to form the creases 38 and 42 of FIG. 11.
487771 五、發明說明(28) 板28中之深度。若 度。另,設置薄墊 脊部壓入薄板2 8之 下方及上方模板 板材料收納是表面 形成圖1 1之薄板2 8 量’這將造成模板 之高度,即當平頂 係受到限制且同時 2 8 ’壓縮變形。 提供調整螺絲(未顯示)目,丨了 ^ μ + θ 不;則可調整此深 未顯示)於這些平頂區域中亦可調整 置以形成所需之摺痕38及·42。 之平頂區域102及118高於各別之中間薄 ,1 〇:及1 1 6 w度值以限制上方模板5 8在 朝下方模板垂直移動期間的運動 脊。卩麼入薄板2 §之量恰好相等於脊部 區域鄰接時,脊部壓入薄板28,之深度 防止摺痕處之局部變形區域之間的薄板 圖9至圖11中薄板28,之寬闊表面52於型成摺痕通 ^ 與屑流產生器3 6及4 0時僅觸及且放置於可動式模 | Λ面上。沒種接觸不致在脊部與摺痕通道38及42之間的 品域中造成薄板2 8,材料任何壓縮及變形。渦流產生器係 如f 9至圖11所示位於渦流產生器3 6之交錯列且交錯地位 =f板2 8之相對侧。當一列產生器設置於如圖1 1中亦在 =回方向交錯之相鄰的摺痕通道38與42之間時,可依據上 5中一給定之一實施條件而提供更多列或者是更多或 /之產生器及列。產生器4〇、4〇,盥 36,之差異在於 其相對方位。 〃 ^ =下方及上方模板58、60使其在完成摺痕通道與渦流 、丨5好接觸》專板2 8係十分重要。如此即 < 避免在這種 成^過^中使易碎之網狀薄板2 8,發生變形。 回之專板2 8係藉由凹口 3 〇、3 2 (圖6 )定位於脊部之固定487771 V. Description of invention (28) Depth in plate 28. If degrees. In addition, the ridges of the thin pads are pressed below the thin plate 2 8 and the upper plate material storage is formed on the surface to form the thin plate 2 8 in Figure 11. This will cause the height of the template, that is, when the flat top system is restricted and at the same time 2 8 'Compression deformation. Adjustment screws (not shown) are provided. ^ Μ + θ No; you can adjust this depth (not shown). In these flat top areas, you can also adjust the settings to form the required creases 38 and 42. The flat-topped areas 102 and 118 are higher than the respective middle thin, 10: and 1 16 w degrees to limit the ridges of the upper template 58 during the vertical movement of the lower template. What is the amount of the thin plate 2 § The amount of § is exactly equal to the thickness of the thin plate 28 when the ridges are pressed into the thin plate 28 to prevent the local deformation of the creases. The wide surface of the thin plate 28 52 is only in contact with the crease pass ^ and the chip flow generator 36 and 40 and is placed on the movable mold | Λ surface. No contact will cause a thin plate 28 in the area between the ridge and the crease channels 38 and 42 and any compression and deformation of the material. The vortex generators are located in the staggered rows of vortex generators 36 and staggered positions as shown in f 9 to FIG. 11 on the opposite side of f plate 2 8. When a column generator is arranged between adjacent crease channels 38 and 42 that are also staggered in the = direction as shown in FIG. 1, more columns or more can be provided according to a given implementation condition in 5 above. Multiple or / of generators and columns. The generators 40, 40 and 36 are different in their relative positions. 〃 ^ = The lower and upper templates 58 and 60 make it very important to complete the crease channel and eddy current. 5 Special plates 2 and 8 are very important. This means < avoid deforming the fragile mesh sheet 28 in this process. The special plate 2 8 is fixed at the ridge by the notches 3 0 and 3 2 (Figure 6).
4S7771 五、發明說明(29) =5 f流產生裝置69中且一對配合導引銷係位於可動式下 禺反_中。由較大之薄板切割出薄板28時可使用其他裝置 ^未顯示)來形成圖6之薄板28中的凹口3〇、32及孔洞34。 =種成里及切剎不會使薄板2 8發生變形。圖j及 m係使用不同尺寸之薄板28,圖4中即顯示構件轉 π iQ、他構件54、56等之全部外圍尺寸並不相同但可 少成如圖9至圖11所示之相同結構。 孔洞係允許操作者適當地調整圖j 〇之最終完工薄板 ζ ΰ 之方位。 8之至皮此步27圖1圖1〇之薄板28, &準備來形成圖3、圖7及圖 板材料中形成摺4及:二需要產生波形即必須在薄 90。作亦可A复^ = 列。較佳地波形27之角度α大約 二一 Λ久其他所需之角度。每-波形27係由一包括一 片;I。圖广Μ、38’或另一列渦流產生器40、4〇,之細長 的面朝一;向及圖8顯示產生器38係從薄板28”之表面開始 一 °且產生器4 0係面朝相反方向。 在前述共同申請且已參考納入本案之申請專利第 形27的,及圖16中所示之裝置12〇。裝置 28產生任何水久變形即可形成波形27 縮,痕、I紋或易碎材料在圖i i之摺痕^又3 ^包括^ 的其他變形。 、迫Μ及4 2之間 裝置120包括_上方波形形成總成i ^及n❹μ4S7771 V. Description of the invention (29) = 5 In the f-flow generating device 69, a pair of matching guide pins is located in the movable lower part. When the sheet 28 is cut from the larger sheet, other devices (not shown) may be used to form the notches 30, 32 and holes 34 in the sheet 28 of FIG. 6. = Seeding and cutting brakes will not deform the thin plates 28. Figures j and m use thin plates 28 of different sizes. In Figure 4, all the outer dimensions of the display member to π iQ, other members 54, 56 and so on are not the same but can be reduced to the same structure as shown in Figures 9 to 11. . The hole system allows the operator to properly adjust the orientation of the final finished sheet ζ 图 of figure j 〇. From step 8 to step 27, the sheet 28 in FIG. 1 and FIG. 10 is prepared to form the sheets 4 and 7 in the sheet material of FIG. 3 and FIG. It can also be A complex ^ = column. It is preferable that the angle α of the waveform 27 is about two one to three other desired angles. Each-waveform 27 consists of one piece; I. Figure 8M, 38 'or another row of eddy current generators 40, 40, with the slender faces facing one; Figure 8 shows that generator 38 is one degree from the surface of sheet 28 "and generator 40 is facing The opposite direction. In the aforementioned co-application and which has been referred to the patent application No. 27 incorporated in the present application, and the device 12 shown in FIG. 16. The device 28 produces any long-term deformation to form a wave 27. The crease of the fragile material in Fig. Ii and 3 ^ include other deformations of ^. Between 120 and 120, the device 120 includes _ upper waveform forming assembly i ^ and n❹μ
第35頁 487771Page 487771
五、發明說明<3〇) — _________________________ 總成1 2 4。上方及下方總成互相配合而共同形成薄板2 8,,中 之波形27,如圖8所示。一控制器(未顯示)係以氣壓將該 上方總成由下方總成經過塊狀件1 5 1及柱型件垂直抬昇。 控制器釋放上方總成122使其藉由本身之重力向下方總成 1 2 4墜落。藉由一控制操縱器(譬如一未顯示之活塞)之氣 體動作所提俣之空氣緩衝來減緩該墜落動作。 上方總成122包括上方板134 ’及兩組126及128之相同且 鏡射的波形成型平行板構件130、132係以可滑動式固定至 板134下方且位於板1 34之相對兩端。構件組丨3〇、i 32係共 平面’且母一組具有五個波形成型板構件1 3 〇、1 3 2。每一 構件包括一平面金屬薄板,例如板丨36,該平面金屬薄板 具有線性板材剛性指狀物138。中央指狀物14〇係固定至板 134兩組126與128之間,其中指狀物142、143、144、145 及146係屬於一組126且1 47- 1 50及138係屬於另一組128。 =有指,物皆以相同於圖丨丨之摺痕通道42之間距而等距離 5又置。每一指狀物皆由對應構件丨3 〇與丨3 2之不同板垂下且 其尺寸係使之可容納於圖9之薄板28,所對應的摺痕通道42 内。 ,每一指狀物係橫向延伸相同程度,譬如沿著入及出圖i 5 紙面之方向完全地橫越對應之波形成型構件。固定指狀物 1 4 7—亦具有相同於其他指狀物的橫向延伸,譬如指狀物η 7 ^ = 一指所具有的圖18a所示之平面薄板金屬柄152係朝向 其垂懸邊緣154逐漸縮小成錐形。該邊緣之橫向寬度相等 於t痕通道42所需者使該邊緣丨54嚙合於摺痕通道42。所V. Description of the invention < 3〇) — _________________________ Assembly 1 2 4. The upper and lower assemblies cooperate with each other to form a thin plate 28, and a waveform 27 in the middle, as shown in FIG. A controller (not shown) vertically lifts the upper assembly from the lower assembly through the block 1 5 1 and the columnar part with air pressure. The controller releases the upper assembly 122 to cause it to fall to the lower assembly 1 2 4 by its own gravity. The fall action is slowed by the cushioning of the air by the gas movement of a control manipulator (such as a piston not shown). The upper assembly 122 includes an upper plate 134 'and two sets of identical and mirrored wave-shaped parallel plate members 130, 132 of 126 and 128 which are slidably fixed below the plate 134 and located at opposite ends of the plate 134. Component group 丨 30, i 32 are coplanar ', and the mother group has five corrugated shaped plate members 1300, 132. Each member includes a planar metal sheet, such as a plate 36, which has a linear sheet rigid finger 138. The central finger 14 is fixed between the two groups 126 and 128 of the plate 134, of which the fingers 142, 143, 144, 145, and 146 belong to one group 126 and 1 47 to 1 50 and 138 belong to the other group 128. = There are fingers, the objects are at the same distance as the crease channel 42 in the figure, and the equal distance 5 is set. Each finger is suspended from a different plate of the corresponding member 丨 30 and 丨 2 and its size is such that it can be accommodated in the corresponding crease channel 42 of the thin plate 28 of FIG. 9. Each finger extends laterally to the same extent, for example, it completely crosses the corresponding wave-shaped member along the direction of the paper surface in and out of Figure i5. Fixed fingers 1 4 7-also have the same lateral extension as other fingers, such as fingers η 7 ^ = one finger has a flat sheet metal handle 152 as shown in FIG. 18a towards its hanging edge 154 Taper to tapered. The lateral width of the edge is equal to that required for the t-slot channel 42 to engage the edge 54 with the crease channel 42. All
第36頁 2000.09. 26.037 487771 五、發明說明(31) 有指狀物皆垂懸一可使垂懸邊緣1 5 4皆共平面之距離以在 相同平面中均勻地响合至摺痕通道4 2。構件1 3 〇與1 3 2橫向 相對地在反方向1 5 6上水平滑動。 一組指狀物1 2 8中之1 4 7 - 1 5 0及1 3 8係喷合於圖11之薄板 28’之右半邊上的通道42且朝方向156往圖式左方滑動,以 及另一組指狀物1 2 6係嚙合於左半邊之通道4 2且向右滑 動。兩組指狀物在水瓶方向1 5 6上分離至最遠位置時,各 指狀物係位於相對中央固定指狀物丨4〇之最末端。指狀^ 在此位置時亦垂直分離至最遠位置,這即為開啟位置。 當指狀物閉合時,方向1 5 6上及垂直的間距將為最小, 此即為圖1 7及圖1 8所示之閉合位置。 類似於上方總成122之下方總成1 24包括一下方板125, 及兩組各五個鏡射且相同之波形成型板構件丨5 8及丨6 〇係以 可滑動式固定至板1 25。每組構件具有一分別對應該組之 五個指狀物1 5 8 ’及1 6 0 ’ 。每一指狀物係連接至每一板構 件。$構件158及160係分別以相對水平滑動且共平面的方 式固定之。每一下方總成組124具有五個波形成型板構 件。下方板構件1 5 8及1 6 0係大致相似且符合上方她成丨2 2 之板構件130及132,其中每一構件在方向156上最接近板 構件間之中央區域的構件内緣處包括一分別具有一線性直 角指狀物1 5 8 ’與1 6 0,之平面金屬薄板。 、下方總成1 24之指狀物組中為設置中央指狀物。所有指 狀物1 5 8與1 6 0在開啟時係以相等於圖丨丨之摺痕通道3 8之 間距而等距離設置。每一指狀物由其板構件158或16〇向上Page 36 2000.09. 26.037 487771 V. Description of the invention (31) All fingers are suspended-a distance that makes the hanging edges 1 5 4 all coplanar so as to evenly resonate to the crease channel 4 2 in the same plane . The members 1 3 0 and 1 2 2 are horizontally slid horizontally in the opposite direction 1 5 6. A group of fingers 1 2 8 1 4 7-1 50 and 1 3 8 are sprayed on the channel 42 on the right half of the sheet 28 ′ of FIG. 11 and slide to the left in the direction 156, and The other set of fingers 1 2 6 engages the channel 4 2 on the left half and slides to the right. When the two groups of fingers are separated to the farthest position in the direction of the water bottle 156, each finger is located at the extreme end of the fixed finger relative to the center. The finger ^ is also vertically separated to the farthest position at this position, which is the open position. When the fingers are closed, the distance in the direction 156 and vertical will be the smallest, which is the closed position shown in Figure 17 and Figure 18. The lower assembly 1 24 similar to the upper assembly 122 includes a lower plate 125, and two sets of five mirrored and identical wave-shaped plate members 丨 5 8 and 丨 6 are slidably fixed to the plate 1 25 . Each group of members has five fingers 15 8 'and 16 0' corresponding to the group. Each finger is connected to each plate member. The members 158 and 160 are fixed in a relatively horizontal sliding and coplanar manner, respectively. Each lower assembly group 124 has five corrugated molding plate members. The lower plate members 1 5 8 and 1 6 are generally similar and conform to the upper plate members 130 and 132, each of which includes the inner edge of the member closest to the central area between the plate members in the direction 156. A planar metal sheet with a linear right-angled finger 15 8 'and 16 0, respectively. The middle finger is set in the finger group of the lower assembly 1 24. All fingers 1 5 8 and 1 60 are set at equal distances at the same distance as the crease channel 3 8 in the figure when opened. Each finger is raised by its plate member 158 or 160.
第37頁 487771 五、發明說明(32) ---------- 延伸且其尺寸係使之可容納於圖11之薄板28,所對摩之指 痕通道38中。 π奵應之指 每:”橫向延伸相同之程度,譬如沿著入及出纸 指狀物皆垂直向上延伸一可使延伸邊緣皆共平 := 在開啟位置時於相同來 距_以 通道38,如圖薄板以’之摺痕 及ί=(Ϊ顯示)係抵住圖6及圖9中之各端的凹口3〇與32 =二,:D。這些突起物可準確地將薄板以,中:摺 m:a)上:方指狀物總成中對應各指狀物之邊緣 上= 指狀物總成122中亦將摺痕通道42對齊上方 如圖1 5所示,上方總成1 22之指狀物係垂直排列 總成1 24之指狀物φ „ , . . ^ ϋ<7打I置排列於下方 之對#摺中間, 為將指狀物對齊薄板28,中 t f痕通運38與42,如圖9至圖11所示。上方及下方 波形成型總成呈有足釣夕古疮允叫 ^ 万及下方 容納圖11所鞀:有 以在彎摺薄板28’期間 二ΰ 1所顯不之渦流產生器3 6及4 〇。 母、、且私狀物構件1 5 8與1 6 0皆可選摆妯旦士闰]ς :置=之關閉位置時沿互相==二啟 L工=應:1:對之 中兩组比你Α相對者可朝向右側滑動。圖Π 間距在位置。當指狀物定位於使 對水千及垂直方向上皆為最大的位置時,即係位Page 37 487771 V. Description of the invention (32) ---------- It is extended and its size can be accommodated in the thin plate 28 in FIG. 11 and the finger path 38 facing each other. π 奵 ying means each: "the horizontal extension extends to the same extent, for example, the fingers extend vertically upwards along the in and out of the paper to make the extended edges are flat: = at the same distance in the open position _ with channel 38 As shown in the figure, the creases of the thin plate and == (Ϊ show) are against the notches 30 and 32 = 2 at each end in Figure 6 and Figure 9: D. These protrusions can accurately turn the thin plate to, Middle: Fold m: a) Top: On the edges of the corresponding fingers in the square finger assembly = In the finger assembly 122, the crease channel 42 is also aligned upward as shown in Figure 15, the upper assembly The fingers of 1 22 are vertically arranged. The fingers of 24 are φ „,... ^ ≪ 7 and I are arranged in the middle of the opposite # fold, in order to align the fingers with the thin plate 28, and the middle tf mark. Transports 38 and 42 are shown in Figures 9 to 11. The upper and lower wave forming assemblies are full of fishing guts, and the lower part accommodates Figure 11: There are eddy current generators 3 6 and 4 that are not visible during the bending of the thin plate 28 '. . Female, and private components 1 5 8 and 1 6 0 can be selected. (妯) Set: the closed position of each other == two Kai L workers = should: 1: two groups in the pair Than your A counterpart can slide towards the right. Figure Π The spacing is in position. When the finger is positioned at the position where it is the largest in both vertical and horizontal directions, it is the position
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第38頁 487771Page 487771
第39頁 487771Page 487771
上方總成122具有軸承176。支持柱18〇係連接至軸承 176。又,柱型件wo係安裝於支持件丨82上。 在運作期間由控制器指示活塞操縱器(未顯示)抬昇至 方總成122。槓桿1 62及1 64在圖15中係位於開啟位置。上 方及下方組126、128與158,及160,之波形成型構件的指狀 物係,對於薄板28,中摺痕通道3 8及42之間隔(圖u )而分 離一最大距離。再將指狀物置於嚙合摺痕通道3 8 (圖丨丨)之 下方組158’及160’的上方。這種定位係藉由放置薄板28, 之凹口30及32(圖6)於每一組末端指狀物處之突起物(未顯 不)而得以完成。同時控制器不操縱槓桿馬達而使槓桿i 62 及1 6 4保持於開啟位置。 該控制器開啟一閥門以使操縱器(未顯示)釋放一活塞 (未顯示)。該活塞允許上方總成1 2 2藉重力墜落。當總成 122到達最低位置時,凸輪銷172將靜置於斜面174之底部 。此時指狀物係完全嚙合於相對應之摺痕通道薄板2 8,。 由於指狀物之間的距離設定為恰好配合薄板2 8,之厚度 而使指狀物間之區域或在指狀物處皆不致在薄板28,上產 生壓縮負荷。是以,在彎摺程序期間將不會在摺痕之間的 任一位置上發生薄板2 8,之壓縮變形。The upper assembly 122 has a bearing 176. The support post 180 is connected to the bearing 176. In addition, the post member wo is mounted on the support member 82. The piston manipulator (not shown) is instructed by the controller to lift to the square assembly 122 during operation. The levers 1 62 and 1 64 are in the open position in FIG. 15. The finger systems of the wave-formed members of the upper and lower groups 126, 128, 158, and 160, are separated by a maximum distance for the thin plate 28, the interval between the crease channels 38, and 42 (Figure u). The fingers are then placed above the groups 158 'and 160' that engage the crease channel 3 8 (Figures 丨 丨). This positioning is accomplished by placing the notches 30 and 32 (Fig. 6) of the sheet 28 at the ends of each set of protrusions (not shown). At the same time, the controller does not operate the lever motor to keep the levers i 62 and 1 6 4 in the open position. The controller opens a valve to cause the manipulator (not shown) to release a piston (not shown). This piston allows the upper assembly 1 2 2 to fall by gravity. When the assembly 122 reaches the lowest position, the cam pin 172 will rest on the bottom of the bevel 174. At this point, the fingers are fully engaged with the corresponding crease channel sheets 28 ,. Since the distance between the fingers is set to exactly match the thickness of the thin plates 28, the area between the fingers or at the fingers will not cause a compressive load on the thin plate 28 ,. Therefore, during the bending process, no compression deformation of the thin plate 28 will occur at any position between the creases.
O:\63\63138.ptc 第40頁 2000. 09. 26. 041 487771 五、發明說明(35) 此日守控制為開始操縱槓桿曲軸馬達。該曲軸將槓桿1 6 2 及164由圖16中之位置旋轉至圖18中之另一位置。當干横才曰 旋轉時,圖16之銷168及170 —環繞銷166旋轉。由二 ^# μ向距離並不相同而使每—銷皆環繞枢軸 166力疋轉一不同之角度範圍。 嚙合於不同銷168或17〇之構件132、13Q、158及16〇中 每一波形構件係藉由對應之銷朝向指狀物總成之中央運 而沿著方向156位移。相對組之構件係同時朝互相相反之 方向運動。同日夺,凸輪銷172將因上部總成之重量而 斜面丨74傾斜。此類傾斜運動將使上部總成逐漸垂 ^地向下方總成移動直到指狀物到達圖17之交錯位置為 ^種又錯運動可在摺痕通到處彎摺 8 工此,作將不致在摺痕通道以外之薄板上乍發= ^ ^ ^ 7fa1 ^^ ^ ^ 害先前形成之渦流產生:及二間:區域。這可防止傷 由於壓縮負荷僅中之薄板2δ’。 28,之其他部份的孔同將\先拉7^之摺痕通道,因此薄板 ¥19η „ ,匕,门將保持原狀而無傷害性之變形。 狀Ϊ $成l上方及下方總成122及124中具有不同之指 Λ 合不同尺寸之薄板28。該裝置可在不 使溥板2 8產生任何永久轡 牧+ 此類變形包括壓植摺/开缺之情形下形成圖3之波形”。 •t〇〇 P, t 祛痕、皺紋或介於圖11之任何摺痕通 迢38及42之間的其他型式之材料變形。 艮通 487771O: \ 63 \ 63138.ptc Page 40 2000. 09. 26. 041 487771 V. Description of the invention (35) This day guard is to start operating the lever crank motor. The crankshaft rotates the levers 16 2 and 164 from the position in FIG. 16 to another position in FIG. 18. When the stem is rotated, the pins 168 and 170 of FIG. 16 rotate around the pin 166. Since the two ^ # μ distances are not the same, each pin rotates around the pivot 166 with a different angle range. Each of the members 132, 13Q, 158, and 160 engaged with a different pin 168 or 170 is displaced in the direction 156 by the corresponding pin moving toward the center of the finger assembly. The members of the opposite group move simultaneously in opposite directions. On the same day, the cam pin 172 will be inclined due to the weight of the upper assembly. This type of tilting motion will gradually move the upper assembly to the lower assembly gradually until the fingers reach the staggered position in Figure 17. It is a wrong movement. It can be bent around the crease. 8 On the thin plate outside the crease channel = ^ ^ ^ 7fa1 ^^ ^ ^ Harm the previously formed eddy currents: and two: area. This prevents injury to the thin plate 2δ 'due to the compression load. The holes in the other parts are the same as the crease channel that will be pulled first 7 ^, so the thin plate ¥ 19η „, the door will remain intact without harmful deformation.。 Ϊ $ 成 l 上 上 和 下 下方 122 And 124 have different fingers and different sizes of thin plates 28. This device can form the waveform of Figure 3 without any permanent grazing on the cymbals 28 + this kind of deformation including pressing and folding / opening " . • t〇〇 P, t Deformation, wrinkles, or other types of material deformation between any creases 38 and 42 in Figure 11. Gentong 487771
圖22至圖27之圖表中已 ^ a M ^ ^ ^;EC ; ® 22/^ 壓力降之影響。摩擦因數枓之波形的波紋方向對 於流體之較小角度時(圖25中冒意味著當通道置於一相對 外,可發現使用多孔性材疋義者)將使壓力降增加。此 平坦薄板的行為。相關文獻中出一類似於相同厚度之 用於描述MEC觸媒支持網 田述一平坦薄板之行為可應 度為70 0 K、不同流速5、 ^之行為。圖23係顯示在溫 出口處之壓力降測量值。帝μ公尺/秒之下、於轉換器 用於計算一 400 cpsi(每 田」1右數為函數之壓力降計算係 換器之單體結構及具有相央寸之通迢數)之傳統觸媒轉 該轉換器之長度為〇·丨5公=^位6〇。之波形MEC材料封裝。^ A M ^ ^ ^; EC; ® 22 / ^ Influence of pressure drop in the graphs of Figure 22 to Figure 27. When the wave direction of the waveform of the friction factor 对 is relatively small with respect to the fluid (in Fig. 25, it means that when the channel is placed outside, it can be found that the porous material is used) will increase the pressure drop. This flat sheet behaves. A similar thin plate used in the related literature to describe the MEC catalyst support network described the behavior of a flat sheet with a response of 70 0 K, different flow rates 5, and ^. Figure 23 shows the measured pressure drop at the temperature outlet. The traditional touch for the converter to calculate a pressure drop of 400 cpsi (the pressure per digit of 1 field as a function of the unit's structure and the perforation number of phase center) below μm / s The length of the media converter is 0 · 5mm = ^ bit 60. Waveform MEC material package.
、圖2 6中係比較兩長度皆Figure 2 and Figure 6 compare the two lengths.
標準40 0 cps i蜂巢式結構:/厘之一⑽。MEC結構與-實驗中所指出之蜂巢式結:问速度下之結果係基於先 的假設而由實驗數據外插曰為層流且.13結構中為紊洁 之壓力降在流速(根據一直允"^。圖中顯示一60。MEC封裝 相等於一 4 0 0 cpsi之蜂巢官路)為16公尺/秒之下約味 引擎在一般滿載操作下者=了構者,但此速度遠高於燃 件下之壓力降應明顯低於=以,6〇。MEC在標準操作條 由於MEC結構中出現紊、、/ *式結構者。 態—固態物質傳遞通常係:认因此在給定壓力降之下的泰 MEC之觸媒表面積之使用=志蜂巢式結構者一級。是以,Standard 40 0 cps i honeycomb structure: one centimeter. The MEC structure and the honeycomb junction indicated in the experiment: the results at the speed are based on the previous assumptions and extrapolated from the experimental data to laminar flow. .13 The pressure drop in the structure is turbulent. " ^. The figure shows a 60. The MEC package is equivalent to a 4400 cpsi honeycomb official road) is under 16 meters / second. It means that the engine is under full load operation, but the speed is far. The pressure drop above the fuel part should be significantly lower than = 60%. MEC in the standard operation bar due to turbulence, / * structure in the MEC structure. State-solid material transfer is generally: the use of Thai MEC's catalyst surface area under a given pressure drop = chi honeycomb structure level. So,
如圖24所示的在一給定壓,队向於蜂巢式者,且因此MEC 1刀卩牛之下完成更多的轉換。在As shown in Figure 24, at a given pressure, the team tends to the hive, and therefore completes more conversions under the MEC 1. in
487771 五 L、發明說明(37) 將利用有關Sh之文獻(Focke,W· W·等在1 985年發表於Int. J. Heat Mass Transfer,28(8),1469-1479 中之"The Effect of Corrugation Inclination Angle on the Thermohydrau1i c Performance of Plate Heat Exchangers”)及測量壓力降取得之實驗數據來計算MEC與 標準蜂巢式封裝中之轉換。該計算係以流速1 〇公尺/秒(根 據真空管路)及溫度7 0 〇 K為計算條件。這些計算中假設該 反應係受限於主要通道中之大量物質傳輸。由於其係假設 内部纖維之表面積於高觸媒溫度之穩態操作中不發生作 用,因此可視為一較保守之計算。由於高強度紊流之緣 故’使得即使通道尺寸更大MEC轉換廢氣仍將更有效率。 傳統蜂桌式結構在六個汽車引擎上執行之實際測試中 產生譬如一 2 0 0毫巴之壓力降且60。波形角度之〇(:網狀裝 置中產生120毫巴之壓力降,該測試數值係使用4〇公克觸 ,之MEC網狀材料及9 〇公克觸媒之蜂巢式結構在六個汽車 單元中之平均值。§玄測试係在一 5公升保時捷9 2 8 v η引擎 工作於5 70 0 rpm時實施’且其工作溫度為85〇它。 娃圖26中係測量一每平方英吋4〇〇單元(Cpsi)之蜂巢式结 通道角度之MEC網狀材料的每公尺壓力降與 y秒)關係圖。蜂巢式結構之比壓力降係線 之,:? 氣體流動繼。嶋罔狀材料結構中 率範圍中顯現之比壓力降係非線性,顯示 圖24係清楚顯示45。波形之,材料之壓力降與_㈣487771 Five L, Invention Description (37) will use the literature about Sh (Focke, W · W ·, etc. published in Int. J. Heat Mass Transfer, 28 (8), 1469-1479 in 1985 " The Effect of Corrugation Inclination Angle on the Thermohydrau1c Performance of Plate Heat Exchangers ") and experimental data obtained by measuring pressure drop to calculate the conversion between the MEC and the standard honeycomb package. The calculation is based on a flow rate of 10 m / s (based on the vacuum tube Circuit) and temperature 700 K are the calculation conditions. These calculations assume that the reaction is limited by the mass transport in the main channel. Because it assumes that the surface area of the internal fibers does not occur during steady-state operation at high catalyst temperatures Therefore, it can be regarded as a more conservative calculation. Due to the high-intensity turbulence, even if the channel size is larger, the MEC conversion of the exhaust gas will be more efficient. The traditional bee-table structure was actually tested on six automobile engines A pressure drop of, for example, 200 mbar is generated and 60. The angle of the waveform is 0 °: a pressure drop of 120 mbar is generated in a mesh device, and the test value is 40 g The average value of the MEC mesh material and the honeycomb structure of 90 grams of catalyst in six automobile units. § The mysterious test is performed on a 5 liter Porsche 9 2 8 v η engine operating at 5 70 0 rpm 'And its operating temperature is 85 ° C. The relationship between the pressure drop per meter of MEC mesh material and the y second) of the honeycomb junction channel angle of 400 cells per square inch (Cpsi) measured in Figure 26 is shown in Figure 26. Figure. The specific pressure drop of the honeycomb structure is the line of:? Gas flow is followed. The specific pressure drop that appears in the rate range of the 嶋 罔 -shaped material structure is non-linear, shown in Figure 24 is clearly displayed 45. Of the waveform, the material Pressure drop and _㈣
蜂巢式陶瓷結構之壓力降之 圖27顯示不具有渦流產、j係。 較蜂巢材料輕、觸媒材。σ、之波BMEC網狀材料,即使 1 50公厘之圖2之轉換器6 ^少且顯現出紊流.,仍使一長 傳統知識無法預期的。一私、一良好轉換,此為本技藝之 之燃燒引擎的觸媒韓拖々I用於一汽缸容量大約1 0 0 0 cc 手〜啊烁轉換虱體積 圖1 9至圖2 〇顯示MEC網狀箄知从 毛 置結構的又一呈!專板材料形成之觸媒轉換器裝 方形但實際上;二二二::轉換器載具裝置186係呈 裝置186之構件在此可為开;^配合至圖2之機殼4區段6中。 殼而連接圖2至圖4中之為構不:尺壯寸以配合上述之圓柱形機 行通道内產…:^:。裳置186必須具有用於在平 鄰構件刑^f L產生器而非圖2具體實施例中相 mil男刀式交叉通道。裝置丨86之平行通道皆為 扭曲而不提供平行之氣體流通路徑。 “為 圖19之梦署 同觸媒恭2壯 匕括一陣列佔據一較大陣列之部份的相 據给定之二:ΐ構件188、190、192及194。實際上需要依 包括招條件使用或多或少之構件。譬如裝置186可 這# ^ ^ fr固此類構件。亦該陣列係呈一方形陣列。然, 具狀ί=僅作為說明。實際上該陣列在圖1之轉換器載 其:所需向?上的平面視圖中亦可為矩开卜圓形或 y狀。較佳地,該陣列係如同圖2及圖3中之圓 咖f構件係配合於圖1中機殼4之内部形狀以填充區段6之 内部。每一 4¾ /4- ^ η 攝件188、190、192及194係由相同之多孔性金Pressure drop of honeycomb ceramic structure Figure 27 shows the j-series without eddy current. Lighter than honeycomb material and catalyst material. σ, the wave BMEC mesh material, even if the converter 6 ^ shown in Figure 2 of 150 mm is small and shows turbulence, it still makes a long traditional knowledge unpredictable. One private, one good conversion, this is the technology of the combustion engine catalyst Han Tuo I for a cylinder capacity of about 1 0 0 0 cc hand ~ ah Shuo conversion lice volume Figure 19 to Figure 2 〇 Show MEC net The shape knows another appearance from the hair placement structure! The catalyst converter formed of the special plate material is square but actually; 22: 2: The converter carrier device 186 is a component of the device 186 which can be opened here; ^ fits to the casing 4 section 6 of FIG. 2 in. The shell is connected to the structure shown in Figures 2 to 4: the size is large to match the above-mentioned cylindrical machine channel production ...: ^ :. The dress 186 must have a mil male-knife-type cross-channel for a flat-pronged generator instead of the mil-shaped knife-shaped crossover in the specific embodiment of FIG. The parallel channels of the device 86 are twisted and do not provide parallel gas flow paths. "For the dream department of Figure 19 and the catalyst Gong 2 Zhuang, an array occupies a part of a larger array given two: ΐ members 188, 190, 192, and 194. In fact, it needs to be used in accordance with the conditions of inclusion More or less components. For example, the device 186 can fix such components. Also, the array is a square array. However, the shape is only for illustration. In fact, the array is shown in the converter of Figure 1. Here it is: in the plan view of the required direction, it can also be a rectangular circle or a y-shape. Preferably, the array is fitted to the machine in FIG. 1 like the round coffee f component in FIG. 2 and FIG. 3. The inner shape of the shell 4 fills the inside of the segment 6. Each of the 4¾ / 4- ^ η photographs 188, 190, 192, and 194 is made of the same porous gold
第44頁 487771 五、發明說明(39) 屬MEC微纖維之未加工基底以類似於上述之方式形成。參 考上述PCT專利申請第PCT/US98/27 6 9 9號案中對該構件有 更洋盡地描述。 每一構件包括複數個在譬如彎摺線1 9 6之彎摺線處形成 之直角。具有相同翼片1 9 8的第一頂部列1 9 7包括一第一頂 部列,其係具有位於每一構件1 8 8、1 9 0、1 9 2及1 9 4中相同 之貫穿方形孔2 0 0。翼片198係存在於每一構件之通道 2 1 0、2 1 2、2 1 4等中。這些翼片係沿著入及出圖2 1紙面且 在圖2 0中沿相反方向朝向圖式之頂部及底部。每一構件在 第一列197之通道壁209及平行於壁209(譬如壁211)之壁中 裝置一翼片1 9 8與孔洞2 0 0。翼片1 9 8係形成渦流產生器。 如圖2 1 ’每一列之孔洞2 0 0係與該列之翼片尖端2 2 2相鄰。 每一翼片198係位於一譬如通道210、212及214之通道中。 在譬如通道2 10及2 12之相鄰反向通道中之翼片係於通道中 朝向相當之相反方向。圖20中之連接至平行障壁2〇9、230 寺之翼片乂立而2 2 2係面朝向圖式頂部與底部的相反方向。 在這些圖式中加上撇號及多重撇號之參考代碼係代表相當 之不同列中的相同組件。 圖2 1中每一翼片1 9 8具有第一邊緣2 1 6其係與一薄板材料 中之彎摺線形成的譬如緣角2 〇 2、2 0 4、2 0 8等通道圓角共 同延伸。每一翼片1 9 8具有一第二邊緣2 1 8係由一彎摺線形 成之第二通道緣角2 2 0開始發散且相對於緣角2 〇 2及2 2 0傾 斜而終止於末端節尖端2 2 2。每一翼片198之邊緣2 16及2 18 係終結於平面228上之彎摺線22 6的翼片端。如圖2〇及圖21Page 44 487771 V. Description of the invention (39) Raw substrates that are MEC microfibers are formed in a manner similar to that described above. Reference is made to the above PCT patent application PCT / US98 / 27 6 9 9 for a more complete description of this component. Each member includes a plurality of right angles formed at a bend line such as a bend line 196. The first top row 1 9 7 with the same fins 1 9 8 includes a first top row having the same through square holes in each member 1 8 8, 19 0, 1 9 2 and 1 9 4 2 0 0. The fins 198 are present in the channels 2 10, 2 1 2, 2 1 4 and the like of each member. These fins move in and out of the paper surface of FIG. 21 and in opposite directions in FIG. 20 toward the top and bottom of the figure. Each member is provided with a flap 198 and a hole 2000 in the channel wall 209 of the first row 197 and a wall parallel to the wall 209 (such as the wall 211). The fins 198 and 8 form a vortex generator. As shown in FIG. 2 1 ′, the holes 2 0 0 in each row are adjacent to the tip 2 2 2 of the fins in the row. Each fin 198 is located in a channel such as channels 210, 212, and 214. The fins in adjacent reverse channels such as channels 2 10 and 2 12 are oriented in opposite directions in the channels. In Figure 20, the wings connected to the parallel barriers 209 and 230 are standing and the 2 2 2 planes face the top and bottom of the figure in opposite directions. The reference codes with apostrophes and multiple apostrophes in these figures represent the same components in quite different columns. Each of the fins 198 in FIG. 21 has a first edge 2 1 6 which extends along the channel fillet formed by a bending line in a thin plate material, such as edge angles 2 0 2, 2 0 4, 2 8. Each wing 198 has a second edge 2 1 8 is a second channel edge angle 2 2 0 formed by a bend line, begins to diverge, and is inclined relative to the edge angles 2 0 2 and 2 2 0 and terminates at the tip of the tip node 2 2 2. The edges 2 16 and 2 18 of each fin 198 terminate at the fin ends of the bend line 22 6 on the plane 228. Figure 20 and Figure 21
第45頁 487771 五、發明說明(40) 所示,尖端2 2 2具有一邊緣係與邊緣2 1 6共同延伸,並且兩 邊緣係呈一直線且位於一譬如緣角2 3 0之彎摺線的通道緣 角上。Page 45 487771 V. Description of the invention (40), the tip 2 2 2 has an edge system that extends with the edge 2 1 6 and both edges are in a straight line and located on a bend line such as the edge angle 2 3 0 On the corner.
翼片198之邊緣216及218皆由一圖21所示之共同橫向平 面2 2 8發散,且列1 9 7之所有翼片1 9 8的邊緣皆然。可選擇 是否裝設之每一尖端2 2 2較佳地係方形或矩形,可依據給 定之實施條件而為其他形狀。孔洞2 0 0略大於尖端2 2 2以允 許尖端222通過,如圖19底部之尖端222’ ’’’’及圖20中每 一通道突出之尖端2 22所示。列197之所有翼片198及孔洞 2 0 0皆定位於一平行於平面2 2 8之列中。 每一構件中將形成一包括相同翼片198’及方形孔20 0,之 第二列1 9 9。歹U1 9 9之翼片及孔相對於列1 9 7之翼片及孔成 正角。這些翼片及孔洞係從間隔之通道障壁延伸且位於相 隔之通道障壁中,且亦與翼片1 9 8及孔洞2 0 0所延伸及存在 之障壁交錯。譬如列1 9 9之翼片1 9 8 ’係位於與障壁2 0 9及 211呈直角之通道側壁213及215等。這些翼片198,在圖 1 9、圖2 0及圖2 1中係沿一方向朝右方與左方延伸。The edges 216 and 218 of the fins 198 are diverged by a common transverse plane 2 2 8 shown in FIG. 21, and the edges of all the fins 198 of the column 197 are the same. Each of the tips 2 2 2 which can be installed or not is preferably square or rectangular, and may be other shapes according to a given implementation condition. The hole 2 0 0 is slightly larger than the tip 2 2 2 to allow the tip 222 to pass, as shown by the tip 222 '' '' at the bottom of Fig. 19 and the tip 22 22 protruding from each channel in Fig. 20. All the fins 198 and the holes 2 0 of the row 197 are positioned in a row parallel to the plane 2 2 8. Each member will form a second column 199 including the same fins 198 'and square holes 200.歹 The wings and holes of U1 9 9 are at a positive angle with respect to the wings and holes of column 197. These fins and holes extend from and are located in the spaced apart channel barriers, and are also intersected with the barriers extended and existing by the wings 198 and the holes 200. For example, the wings 1 198 of column 199 are located on the side walls 213 and 215 of the channel at right angles to the barriers 209 and 211. These fins 198 extend rightward and leftward in one direction in FIGS. 19, 20 and 21.
圖2 1顯示其他之翼片及孔洞2 0 1及2 0 5。具有撇號之相當 代碼係平行於列1 9 7且方向相同並定位於譬如通道2 1 0及 2 1 2等相同之通道中。譬如翼片1 9 8 ’’係位於列2 0 1中且亦 片1 9 8 ’’’’係位於列2 0 5中。另一底部列2 0 7之翼片 1 9 8 ’ ’ ’ ’ ’及孔洞2 0 0 ’ ’ ’ ’ ’係定位於一平行於列1 9 9之列中 並且定位一相同之方向及同一通道中。另一中間列203之 翼片1 9 8 ’’’及孔洞2 0 0 ’’’係定位於一平行於另一列之列Figure 21 shows the other fins and holes 205 and 205. Equivalent codes with apostrophes are parallel to column 197 and have the same orientation and are located in the same channel, such as channels 2 10 and 2 1 2. For example, the fins 198 '' are located in the column 205 and the fins 198 '' 'are located in the column 205. The other bottom tab 2 0 7 wing 1 9 8 '' '' 'and the holes 2 0 0' '' '' are positioned in a parallel row to the 19 9 row and positioned in the same direction and the same channel in. The fins 1 9 8 ’’ and the holes 2 0 0 ’’ of the other middle row 203 are positioned in a row parallel to the other row
第46頁 487771 五、發明說明(41) .中’並且與列199及207之翼片定仞你円 反。列199係位於列197與2〇1之間且列口2〇^道中但方向相 205之間。依據給定之實施 ,、立於列201與 列及通道。圖19中之通道於或更少的此類 相鄰構件係包覆著通道。 』不之+面圖中係方形且 構件188如同所有之構件一般 著f摺線朝交錯之相反方向f #、口工之基底材料沿 13及圖14之工具來加工材料而形二=運用相似於上述圖 裝置1 86之通道在平面視圖中係相化半波形結構。 形成於不同之構件中且沿著每二‘方形。通道係 形成通道,因此構件188之通道21〇父錯之相反方向來 對觀察者且通道212、217等传a孤^等在圖21中係面 反〜方向。所有觸媒載具裝置186構由咸1者朝向圖式之相 成。 之構件皆由相同之通道構 列1 9 7之翼片1 9 8係沿相反於互相六/ =方向由圖式之平面向外彎摺。=二平形之通道障壁 翼片係沿著相同方向彎摺,辟 ,、運2 1 0、2 1 4等之 指。通細及m之翼片則面像觀察者彎 方向彎摺。每-通道之橫向側壁之通離觀察者的相反 U8,、198,,,及198,,,,,在你之翼片,及譬如翼片 方向序列。 使用—相似之互相交錯的彎摺 由圖1 9及圖2 1之頂部至底部 1 平面視圖中的翼片阻斷了每不士 口通這210縱長之 現出,且因此造成一通每廷可在圖2〇中清楚表 I母通逼之完全扭曲之氣體路 第47頁 487771P.46 487771 V. Description of the Invention (41). In the middle, and it is against the wings of columns 199 and 207. Column 199 is located between columns 197 and 201, and in the column mouth 20, but in the direction phase 205. According to the given implementation, stand in column 201 and column and channel. The channels in Figure 19 are covered with channels with fewer or fewer such adjacent members. 『不 之 + is square in the plan view, and the components 188 are like all the components. They follow the f-fold line in the opposite direction of the staggered f #. The channel of the above device 186 is a phased half-wave structure in a plan view. Formed in different members and along every two'square. The channel system forms a channel, so the channel 21 of the component 188 is opposite to the observer in the opposite direction to the observer and the channels 212, 217, etc. are transmitted in the opposite direction in FIG. 21. All of the catalyst carrier devices 186 are structured from one to the other. The components are all formed by the same channel. The wings of 197, 19, 8 are bent outward from the plane of the figure in opposite directions to each other. = Two flat-shaped channel barriers The fins are bent in the same direction, and the fingers are 2 1 0, 2 1 4 and so on. The fins and m wings are bent in the direction of the observer. U-, 198 ,, and 198 ,,,,, and the opposite side walls of each-channel are opposite to the viewer, in your fins, and for example, the fin direction sequence. Use—Similarly staggered bends from the top to bottom 1 of Figure 19 and Figure 21 in a plan view block the 210 lengthwise appearance of every taxi pass, and thus create a pass per court The completely distorted gas path of the mother I can be clearly shown in Figure 20, page 47 487771
五、發明說明(42) 徑。在任何通道之縱長中皆不具有連續之線性流辟取。 可在圖20中清楚看出真片在線性通道中造成之j 1 圖21中之每一通道具有一隶上方翼片198、一次一 片198’及一再次一下方翼片198’’等。如圖2〇所示下 翼片之一部份係覆蓋通道中其他翼片之一部怜不’母一 177 ,圖20之平 面圖中,翼片係沿垂直紙面之方向完全堵塞每一通道且所 有通道亦然。因此,沿著每一通道66縱長中皆無^ =流體 路徑而使氣體流動出現紊流。亦,於一給定通道中之每一 翼片具有一相鄰且鄰接一通道障壁之邊緣。 : 每一孔洞2 0 0係容納一對應翼片之一尖端2 2 2。嬖如圖J 9 及圖20中每一翼片之尖端222延伸通過相鄰通道之一孔\洞 2 2 2中。因此,所有翼片之尖端將延伸穿過該通道對應之 孔丨同2 〇 〇而進入相鄰通道中。 疋以,每一稱1干&呉A你用於大致僅配合該構件之通道 來提供所需之扭曲流體路徑。每一構件之翼片係與相鄰^ 件之通道大致獨立,但每一尖端2 2 2係穿過一與相鄰構件 共用之障壁上之孔洞2 〇 〇而進入相鄰構件之通道中。譬如 圖19中之一尖端222係穿過構件190及192之共同通道障壁 u 〇 u °5. Description of the invention (42) diameter. There is no continuous linear flow extraction in the length of any channel. It can be clearly seen in Fig. 20 that j 1 caused by a true film in a linear channel each channel in Fig. 21 has an upper fin 198, one at a time 198 ', and one lower fin 198' ', and so on. As shown in FIG. 20, a part of the lower fin covers one of the other fins in the channel, and it is a mother-177. In the plan view of FIG. 20, the fins completely block each channel along the direction of the vertical paper surface, and The same is true for all channels. Therefore, there is no ^ = fluid path along the length of each channel 66, causing turbulence in the gas flow. Also, each fin in a given channel has an edge adjacent to and adjacent to a channel barrier. : Each hole 200 is to receive a tip 2 2 2 of a corresponding fin.嬖 As shown in Figure J 9 and Figure 20, the tip 222 of each fin extends through a hole \ hole 2 2 2 of an adjacent channel. Therefore, the tips of all the fins will extend through the corresponding holes of the channel and enter the adjacent channel by 200. Thus, each scale is used to roughly match the channel of the component to provide the required twisted fluid path. The wing of each member is approximately independent of the passage of the adjacent member, but each tip 2 2 2 passes through a hole 2000 on a barrier wall shared with the adjacent member and enters the passage of the adjacent member. For example, one of the tips 222 in FIG. 19 passes through the common channel barrier of the members 190 and 192 u 〇 u °
叫 I I * 僅部份或完全不由鄰接或緊鄰譬如圖2中機殼4之機 二二之f逼障壁的未加卫材料平面向外彎摺。因此,結構 邊緣處之翼片可不超過結構以致不會干涉機殼内壁, ^不f要這些邊緣表面中之孔洞2〇〇。 形成異片時產生之孔洞及開口可使通道中之流體在垂直Called I I * only partly or completely not bent outward by the plane of unguarded material adjacent to or next to the machine such as the case 4 in Figure 2 to force the barrier. Therefore, the fins at the edges of the structure may not exceed the structure so as not to interfere with the inner wall of the cabinet, and the holes in the edge surfaces are not required to be 200. The holes and openings created when forming different pieces can make the fluid in the channel vertical
第48頁 發明說明(43) 於衣置1 8 6中流體流向之方^ 之平面彎摺出翼片時在薄板知上流通。當然,由薄板材料 於通道之間的橫向主要連、兩才料中形成之開口可提供流體 於每一内部通道之四個障$;這些開口及孔洞2〇〇係形成 可點焊通道之頂部及底部 相固定。當調整構件之尺皁列鈿之通道緣角而將構件互 換器機殼之區段6並且萨由声使^之緊密配合於圖2顯示之轉 的其他裝置(未顯示)而曰固定手祭:或著譬如扣件或類似物 埤接。亦可使用任何方便,殼時即可選擇是否使用該 件互相固定。 ° I k置或結合工具先行將構 為解例:通;:之翼片數量及其對應之方位僅作 應之側邊延伸進入一 翼片19「’之翼片自對 母一側壁延伸進人每、,只際上,可有超過一翼片由 -沿通道縱,。翼片方位之序列,譬如根據 範例,亦可仿摅自給疋之障壁延伸者亦僅作為一 又,可給定需求而使用其他之方位序列。 長度可由一二」及觸媒載具裝置陣列通道之長度。通道 力、流率、ϋ貝施條件所包含之氣體、體積與其中之壓 來決定之。/、他為執行所需轉換程序之相關參數等因數 網狀材料/ 特徵及纖ί置186之微纖維基底材料藉由其表面積之結構 ' 、、隹之間較大的間隙而增加接觸。(48) Description of the invention (43) When the flap is bent out of the plane where the fluid flows in the clothes 186, it flows on the sheet. Of course, the openings formed by the transverse main connection between the sheet material between the channels and the two materials can provide four barriers for each internal channel; these openings and holes 200 form the top of the spot-weldable channel. And the bottom is fixed. When adjusting the angle of the channel edge of the component ruler, the component interchanger casing section 6 and the sound of the sound are closely matched with other devices (not shown) shown in Figure 2 and fixed hand offering : Or, for example, a fastener or the like. It can also be used for any convenience, and you can choose whether to use the pieces to fix each other when the shell is used. ° I k set or combined tools will first be constructed as an example: through ;: the number of fins and their corresponding orientations only extend to the corresponding side edge into a fin 19 "'fins extend from the side wall to the mother Every time, there can be more than one flap from-along the channel. The sequence of the orientation of the flaps, for example according to the example, can also imitate the self-sufficient barrier extension. Use other orientation sequences. The length can be one or two "and the length of the array channel of the catalyst carrier device. The channel force, flow rate, and gas, volume, and pressure contained in the conditions are determined. / 、 Factors such as the relevant parameters for performing the required conversion procedures. Mesh materials / features and micro-fiber base materials of fiber 186 increase the contact through the large gap between the structure of the surface area and 隹.
第49頁 個轉換器中^用時提供大表面積(單位體積之面積)、整 觸。形乂均勻之氣體分佈、及其中表面積之均勻接 487771 五、發明說明(44) 一_. 較佳之:維網狀材料可由觸媒載具裝置構件之燒 薄板材料裝作以提供較大之觸媒表面積而使氣體最::: 觸觸媒。觸媒塗覆於纖維上及/或觸媒顆粒 妾 之多孔性網路中。在相對較迅速之化學反應中,多Λ科材 料内部表面積之使用率係依據氣體之傳遞速度而定。物Ϊ 交叉流動。 則土之裝置應可提供低壓力降之最佳 可=換?佳化,應如上所述的保持較低之μ力降,這 了由k供母早位體積較大介允 之氣體動力特性)及防又摩擦(良好 防止不而要之停沛氣囊來達成。 來p卩制太=i之技藝即可修飾揭露於上之用來說明而非用 + I炎制本發明$ 1 ^ ^ ^ 定義本發明。一肢貫施例。以下&附之申請專利範圍將On page 49, the converter provides a large surface area (area per unit volume) and full touch when used. Uniform gas distribution and uniform connection of its surface area 487771 V. Description of the invention (44) I. _. Better: The mesh material can be made of the sintered sheet material of the catalyst carrier device to provide greater contact. The surface area of the medium maximizes the gas ::: Catalyst. The catalyst is coated on the fibers and / or in a porous network of catalyst particles 妾. In a relatively fast chemical reaction, the utilization rate of the internal surface area of the Polyaceae material depends on the gas transfer rate. Matter cross flow. The earth device should provide the best low pressure drop. The optimization should keep the μ force drop low as described above, which is achieved by the aerodynamic characteristics of the large donor volume and the anti-friction (good prevention of unnecessary stoppage of the airbag). You can modify the technique of making Tai = i to modify and expose the above to explain rather than use + I to make the invention. $ 1 ^ ^ ^ Define the invention. One embodiment throughout. The following & attached patents Range will
487771 _ 案號8_4266 牙^7月拿I: 修正S 五、發明說明_ '…一-…二」玉 元件符號簡要說明 2 觸 媒 轉 換 器 4 機 殼 6 區 段 8 區 段 10 區 段 12 管 子 14 凸 緣 16 方 向 18 管 了 20 凸 緣 22 觸 媒 載 具 23 襯 墊 24 構件 25 縱 向 邊 緣 26 構 件 27 波 形 28 薄 板 29 開 α 環 30 凹 Π 31 網 32 凹 α 34 孔 洞 36 渦 流 產 生 器 36, 渦 流 產 生 器 38 通 道 40 渦 流 產 生 器 42 通 道 44 構件 46 /1¾ 流 產 生 器 48 渴 流 產 生 器 50 波 形 51 側 壁 52 表 面 53 側 壁 54, 5 6構件 57 根 部 58 模 板. 59 頂 點 60 模 板 61 軸 62 脊 部 63 脊 部 6 4,6 6 切 刀 模 67 孔 洞 68 孔 洞 69 裝 置 70 基 座 總 成 72 基 座487771 _ Case No. 8_4266 Take it in July I: Amend S. V. Description of the invention _ '...---2' Brief description of the jade element symbols 2 Catalyst converter 4 Case 6 Section 8 Section 10 Section 12 Pipe 14 flange 16 direction 18 tube 20 flange 22 catalyst carrier 23 gasket 24 member 25 longitudinal edge 26 member 27 wave 28 thin plate 29 open alpha ring 30 concave Π 31 net 32 concave α 34 hole 36 eddy current generator 36, Vortex generator 38 channel 40 Vortex generator 42 channel 44 member 46 / 1¾ flow generator 48 thirsty generator 50 waveform 51 side wall 52 surface 53 side wall 54, 5 6 member 57 root 58 template. 59 vertex 60 template 61 axis 62 ridge Parts 63 Ridges 6 4, 6 6 Cutter die 67 Hole 68 Hole 69 Device 70 Base assembly 72 Base
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487771 修正身 案號 89104266 系 五、發明說明鱗0 74 柱 76 上 部 總 成 78 車由 承 總成 80 垂 直 方 向 82 固 定 板 84 導 引 銷 85 銷 86 螺 栓 88 套 筒 90 肩 部 92 螺 栓 銷 94 容 室 96 彈 簧 98 孔 洞 100 頂 面 102 凸 起 區 域 104 支 持 基板 106 彈 簧 107 定 位 銷 108 導 引 銷 110 套 筒 112, 114定 位 銷 及 115 上 方 板 116 表 面 118 二 角 形平頂區: 威 120 裝 置 122 上 方 總成 123 上 方 板 124 下 方 總成 125 下 方 板 126 成 組 指狀物 128 成 組 指 狀 130 平 行 構件 132 平 行 構 件 134 上 方 板 136 板 138 指 狀 物 140 指 狀 物 142 指 狀. 物 144 指 狀 物 146 指 狀 物 147 指 狀 物 148 指 狀 物 150 指 狀 物 151 塊 件 152 柄 154 垂 懸 邊緣 156 方 向487771 Revised case No. 89104266 Series V. Description of the invention Scale 0 74 Column 76 Upper Assembly 78 Car Bearing Assembly 80 Vertical 82 Fixing Plate 84 Guide Pin 85 Pin 86 Bolt 88 Sleeve 90 Shoulder 92 Bolt Pin 94 Capacity Chamber 96 spring 98 hole 100 top surface 102 raised area 104 support base plate 106 spring 107 positioning pin 108 guide pin 110 sleeve 112, 114 positioning pin and 115 upper plate 116 surface 118 diagonal flat top area: Wei 120 device 122 above Assembly 123 Upper plate 124 Lower assembly 125 Lower plate 126 Group of fingers 128 Group of fingers 130 Parallel member 132 Parallel member 134 Upper plate 136 Plate 138 Finger 140 Finger 142 Finger. 144 Finger Object 146 Finger 147 Finger 148 Finger 150 Finger 151 Block 152 Handle 154 Overhanging edge 156 Direction
O:\63\63138.ptc 第50b頁 2000.09. 26.053 487771 案號 89104266 h舉9月外 日/i 修正 、發明說明 ΦΜό L 一―二」 162 槓桿 164 槓桿 166 樞軸銷 168 銷 170 銷 172 凸輪銷 174 傾斜面 176 車由承 178 支持件 180 支持柱 182 支持件 186 裝置 188 構件 190 構件 192 構件 194 構件 196 彎摺線 197 第一列 198 翼片 199 第二列 200 孔洞 201 列 202 緣角 203 列 204 緣角 205 孔洞 206 列 207 列 208 緣角 209 壁 210 通道 211 壁 212 通道 213 壁 214 通道 215 壁 216 第一邊緣 217 通道 218 第二·邊緣 220 緣角 222 尖端 226 彎摺線 228 平面 230 緣角 232 壁O: \ 63 \ 63138.ptc Page 50b 2000.09. 26.053 487771 Case No. 89104266 h September 9th / i Amendment, description of invention ΦΜό L 1-2 162 Lever 164 Lever 166 Pivot pin 168 Pin 170 Pin 172 Cam Pin 174 Inclined surface 176 Car bearing 178 Supporting piece 180 Supporting column 182 Supporting piece 186 Device 188 Component 190 Component 192 Component 194 Component 196 Bend line 197 First column 198 Fin 199 Second column 200 Hole 201 column 202 Edge corner 203 column 204 edge angle 205 hole 206 column 207 column 208 edge angle 209 wall 210 channel 211 wall 212 channel 213 wall 214 channel 215 wall 216 first edge 217 channel 218 second edge 220 edge angle 222 tip 226 bend line 228 plane 230 edge angle 232 wall
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Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US26516499A | 1999-03-09 | 1999-03-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
TW487771B true TW487771B (en) | 2002-05-21 |
Family
ID=23009293
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW089104266A TW487771B (en) | 1999-03-09 | 2000-03-09 | Exhaust gas catalytic converter |
Country Status (4)
Country | Link |
---|---|
AR (1) | AR022891A1 (en) |
AU (1) | AU3520000A (en) |
TW (1) | TW487771B (en) |
WO (1) | WO2000053904A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI782956B (en) * | 2017-02-28 | 2022-11-11 | 日商日鐵化學材料股份有限公司 | Honeycomb substrate for catalyst support, catalytic converter for exhaust purification |
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ATE350137T1 (en) * | 1999-10-15 | 2007-01-15 | Abb Lummus Global Inc | CONVERSION OF NITROGEN OXIDES USING A CATALYST IN THE SHAPE OF A MESH NETWORK |
US6667017B2 (en) | 1999-10-15 | 2003-12-23 | Abb Lummus Global, Inc. | Process for removing environmentally harmful compounds |
US6663839B2 (en) | 2001-02-26 | 2003-12-16 | Abb Lummus Global Inc. | Radial flow gas phase reactor and method for reducing the nitrogen oxide content of a gas |
US6706246B2 (en) | 2001-02-26 | 2004-03-16 | Abb Lummus Global Inc. | System and method for the selective catalytic reduction of nitrogen oxide in a gas stream |
US6821490B2 (en) * | 2001-02-26 | 2004-11-23 | Abb Lummus Global Inc. | Parallel flow gas phase reactor and method for reducing the nitrogen oxide content of a gas |
KR100809075B1 (en) * | 2002-01-12 | 2008-03-03 | 김태곤 | Apparatus for cleaning automobile exhaust gas to readily attach and remove |
DE10259034A1 (en) * | 2002-12-17 | 2004-07-15 | J. Eberspächer GmbH & Co. KG | The exhaust purification device |
JP3543969B1 (en) * | 2003-06-05 | 2004-07-21 | 株式会社オーデン | Metal filter, black smoke particulate removal device provided with the metal filter, and diesel vehicle |
ITMI20032210A1 (en) * | 2003-11-14 | 2005-05-15 | Getters Spa | EXHAUST GAS CONVERTER FOR INTERNAL COMBUSTION ENGINES. |
EP1685313B1 (en) * | 2003-11-14 | 2006-12-27 | SAES GETTERS S.p.A. | Converter for exhaust gases of internal combustion engines |
US8950173B2 (en) | 2010-12-22 | 2015-02-10 | Mahindra & Mahindra Limited | Integrated exhaust gas after-treatment system for diesel fuel engines |
CN102908973A (en) * | 2012-11-14 | 2013-02-06 | 上海化工研究院 | Peak valley window splicing type sawtooth-like corrugated packing |
DOU2014000190U (en) * | 2014-08-18 | 2016-08-31 | Inst Tecnológico De Santo Domingo Intec | AUTOMATIC HEATING CATALYST IN INTERNAL COMBUSTION ENGINES |
CN104912633B (en) * | 2015-06-09 | 2018-04-03 | 高志男 | Electrical heating heat riser for motor vehicle exhaust emission |
CN105582876A (en) * | 2016-02-26 | 2016-05-18 | 江苏华益科技有限公司 | Wire mesh corrugated packing with high specific surface area |
WO2018100537A1 (en) * | 2016-12-01 | 2018-06-07 | Basf Corporation | Catalytic metal fiber felt and articles made therefrom |
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US2539A (en) | 1842-04-06 | Beehive | ||
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US5080962A (en) | 1985-02-25 | 1992-01-14 | University Of Florida | Method for making silica optical devices and devices produced thereby |
JP2537239B2 (en) | 1987-08-28 | 1996-09-25 | エヌ・イーケムキヤツト 株式会社 | Exhaust gas purification catalyst for internal combustion engine excellent in heat resistance and method for producing the same |
US4939113A (en) | 1987-11-03 | 1990-07-03 | Engelhard Corporation | Hydrogen sulfide suppressing catalyst system using an oxide of copper, manganese, nickel or iron |
US5102745A (en) | 1989-11-13 | 1992-04-07 | Auburn University | Mixed fiber composite structures |
CN1048892A (en) | 1989-05-24 | 1991-01-30 | 奥本大学 | Blend fiber composite structure and method for making thereof and purposes |
DE3923094C2 (en) * | 1989-07-13 | 1993-11-25 | Ltg Lufttechnische Gmbh | Catalyst carrier body |
FR2651150B1 (en) * | 1989-08-30 | 1994-01-14 | Onera | ELEMENT FOR THE FILTRATION AND / OR PURIFICATION OF HOT GASES, AND ITS MANUFACTURING METHOD. |
US5096663A (en) | 1990-05-29 | 1992-03-17 | Auburn University | Method of optimizing composite preparation for electrical properties: maximum capacitance electrodes |
JP2722828B2 (en) * | 1991-03-06 | 1998-03-09 | 日産自動車株式会社 | Exhaust filter for internal combustion engine |
DE4137105A1 (en) * | 1991-11-12 | 1993-05-13 | Schwaebische Huettenwerke Gmbh | ARRANGEMENT OF A CATALYST FOR THE EXHAUST GAS FROM A COMBUSTION ENGINE |
EP0638711B1 (en) * | 1993-08-05 | 1997-06-04 | Sulzer Chemtech AG | Exhaust gas catalyst, in particular for cars |
WO1995035152A1 (en) | 1994-06-17 | 1995-12-28 | Engelhard Corporation | Layered catalyst composite |
WO1998042963A1 (en) * | 1997-03-25 | 1998-10-01 | Nippon Oil Co., Ltd. | Exhaust emission control catalyst, exhaust emission control catalyst manufacturing method, exhaust emission control filter, exhaust emission control filter manufacturing method, and exhaust emission control apparatus |
US6276045B1 (en) * | 1998-10-28 | 2001-08-21 | Abb Lummus Global, Inc. | Method and apparatus for making structured packing element |
-
2000
- 2000-03-08 WO PCT/US2000/006137 patent/WO2000053904A1/en active Application Filing
- 2000-03-08 AU AU35200/00A patent/AU3520000A/en not_active Abandoned
- 2000-03-09 TW TW089104266A patent/TW487771B/en active
- 2000-03-09 AR ARP000101060A patent/AR022891A1/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI782956B (en) * | 2017-02-28 | 2022-11-11 | 日商日鐵化學材料股份有限公司 | Honeycomb substrate for catalyst support, catalytic converter for exhaust purification |
Also Published As
Publication number | Publication date |
---|---|
AU3520000A (en) | 2000-09-28 |
WO2000053904A1 (en) | 2000-09-14 |
AR022891A1 (en) | 2002-09-04 |
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