» 84111485號專利申請案中文说明書修正贾 民_ 85年7月罢 A 7 ------ 、發明説明（1) 修正 年月曰/ 85.7. -6' f 斛件二 S02271 (請先閱讀背面之注意事項再填寫本頁) 本發明係關於調味組成物。更特定言之，本發明係關 於包含新橙皮鹼二氫査耳酮（neohesperidine dihydeoc， halcone)和3 —經基—2 —甲基一 4 Η—耻喃一 4 —嗣 (maltol)或3 -羥基一2 —甲基一4 Η —吡喃一4 一酮 乙酯（ethyl maltol)之調味組成物。 基本上，加工食品及添入加工食品中的調味劑不具有 特別能吸引顧客的强烈氣味。因此可以添加調味强化劑來 提高味道。除了提高氣味之外，此調味强化劑亦增强調味 劑或食品的質感及口感。 兩種最常用的氣味增强劑是3 _羥基一 2 —甲基一4 H -妣喃一 4 一_和3 —經基一 2 —甲基一 4 H — Dtt晡一 4 一酮乙酯。3 —羥基一2 —甲基一 4H —吡喃一4 -酮 是取自落葉松樹、松針和菊苣樹皮的天然物質。早期的3 一經基—2 —甲基一 4 H — D比喃一 4 —嗣市售產品是取自 木材的破壞性蒸餾法。上述方法通常只能取得非常少量的 3 _羥基一2 —甲基一 4 Η —吡喃一 4 —酮。 經*部中央搮隼局Μ工消f合作社印策 人工合成的3 —羥基一2 -甲基一4 Η—吡喃一 4 — 酮及他種r -吡喃酮（如：3 -羥基對吡喃酮）之合成法 述於 U n i t e d S t a t e s p a t e n t N 〇 . 3，1 3 0 , 2 0 4、3，1 3 3，0 8 9、 3,140,239、 3,159,652、 2,365,469、 3,376,317、 3,468, 915、3 , 440，183和 3 , 4 46,629。 使用糠醇作爲起始物以合成3 —羥基一 2 _甲基一4 H —吡喃一4 -酮和3 —羥基一 2 -甲基一 4 H —吡喃一 本紙張尺度適用中!II國家標準（CNS ) Λ4規格（：Ζ10Χ21Π公廑）-4 - A7 ___B7_ 五、發明説明（2 ) 4 —酮乙酯及他種r_吡喃酮之方法述於United States patent Νο. 4, Ο 82, 7 1 7和 4, 28 9, 7 Ο 4 β (請先閲讀背面之注意事項再填寫本頁) 新橙皮鹼二氫査耳酮是一種由柚甙（葡萄柚中的黃酮 烷甙）製得的甜化劑，其製法述於»Amendment to the Chinese Specification of Patent Application No. 84111485 Jia Min _ July 7th, A 7 ------ 、 Instructions for invention (1) Amendment date / 85.7. -6 'f 斛 件 二 S02271 (Please first Read the precautions on the back and fill in this page) The present invention is about seasoning composition. More specifically, the present invention relates to a neohesperine dihydrochalcone (neohesperidine dihydeoc, halcone) and 3-methan-2-methyl-4H-sharan-4-malto (maltol) or 3 -Hydroxy-2-methyl-4H-pyran-4-ethyl ketone (ethyl maltol) flavoring composition. Basically, processed foods and flavoring agents added to processed foods do not have a strong odor that is particularly attractive to customers. Therefore, flavor enhancers can be added to enhance the taste. In addition to enhancing the odor, this flavor enhancer also enhances the texture and mouthfeel of the flavor or food. The two most commonly used odor enhancers are 3_hydroxy-2-methyl-4H-biran-4-4- and 3-hydroxyl-2-methyl-4H-Dtt 陡 -4-ketone ethyl ester. 3-Hydroxy-2-methyl-4H-pyran-4-one is a natural substance taken from larch, pine needles and chicory bark. The early 3-methyl-2-methyl-4H-Dpyran-4-shi commercial products were obtained from the destructive distillation of wood. The above method can usually only obtain a very small amount of 3-hydroxy-2-methyl-4H-pyran-4-one. 3-Hydroxy-2-methyl-4H-pyran-4-ketone and other species of r-pyrone (such as 3-hydroxy Pyrone) is described in U Nited Statespatent N 0.3, 1 3 0, 2 0 4, 3, 1 3 3, 0 8 9, 3,140,239, 3,159,652, 2,365,469, 3,376,317, 3,468, 915, 3, 440, 183 and 3, 4 46,629. Use of furfuryl alcohol as a starting material to synthesize 3-hydroxy-2-methyl-4H-pyran-4-ketone and 3-hydroxy-2-methyl-4H-pyran-paper standard is applicable! II countries Standard (CNS) Λ4 specification (Z10Χ21Π 公 廑) -4-A7 ___B7_ V. Description of invention (2) 4-The method of ethyl ketone and other kinds of r_pyrones are described in United States patent Νο. 4, Ο 82 , 7 1 7 and 4, 28 9, 7 Ο 4 β (Please read the precautions on the back before filling this page) Neohesperidin dihydrochalcone is a naringin (flavonoid glycoside in grapefruit) The prepared sweetener, the preparation method is described in
United States patent No. 3, 087, 821 和 3, 375, 242。. U n i t e d S t a t e s p a t e n t Ν ο. 4，0 8 7, 5 8 8 提出使用新橙 t ί 皮鹼二氫査耳酮作爲甜化劑。.United States patent No. 3, 087, 821 and 3, 375, 242. U n i t e d S t a t e s p a t e n t Ν ο. 4, 0 8 7, 5 8 8 Proposed the use of new orange t piperine dihydrochalcone as a sweetener. .
European Patent Application .No. 500977提出使用 新橙皮鹼二氫査耳酮來增進食物和飮料的質感及口感。European Patent Application No. 500977 proposes to use neohesperidin dihydrochalcone to enhance the texture and taste of food and food.
United States patent No. 3，6 5 3，923 提出使新橙皮 鹼二氫査耳酮和糖精類的甜味劑併用來作爲甜化劑》 E u r o p e a n p a t e n t a p p 1 i c a t i ο η Ν 〇. 5 0 7 5 9 8 提出使蔗 糖和新橙皮鹼二氫査耳酮併用作爲甜化劑。United States patent No. 3, 6 5 3, 923 proposes the use of new hesperidin dihydrochalcone and saccharin sweeteners as sweeteners "E uropeanpatentapp 1 icati ο η Ν 〇. 5 0 7 5 9 8 It was proposed to use sucrose and neohesperidin dihydrochalcone as a sweetener.
United States patent No.4,581, 3·78 提出以新植皮 鹼二氫查耳酮作爲滅鼠組成物的甜化劑。 經濟部中央標準局員工消費合作社印製 在一個實施例中，本發明係關於包含3 —羥基—2 -甲基一4 Η —吡喃-4 -酮和新橙皮鹼二氫査耳酮的調味 組成物。 較佳的組成物是含有約5至約1 0 0 p pm 3 -羥基 一 2 —甲基一4H —吡喃一4 —酮和約0. 1至約 10. Op pm新橙皮鹼二氫査耳酮者· 本發明亦係關於包含此3 —羥基一 2 —甲基一4 H-吡喃-4 -酮-新橙皮鹼二氫査耳酮組成物的食品。 本發明亦係關於在食品中添加3 —羥基一 2 —甲基一-本紙張尺度適用中國國家揉準（CNS ) A4規格（210X：297公釐） ~~~ 經濟部中央標準局貝工消费合作社印装 A7 B7 五、發明説明（3 ) 4 Η -妣喃一 4 -酮-新橙皮鹼二氫査耳酮組成物以修飾 食品之氣味、質感和口感的方法。 較佳的方法是該食品選自不含酒精的碳酸類飲料、不 含酒精的非碳酸類水果調味飮料、不含酒精的非碳酸類飮 料、餐油 '飯後甜點、肉類產品、家禽產品、動物飼料、 糕餅類、烘烤食品、含酒精飮料、鹹餅、奶製品、佐料和 肉湯。 在另一個實施例中，本發明译關於包含3 _羥基_ 2 —甲基一4 Η —吡喃一 4 一酮乙酯和新橙皮鹼二氫査耳酮 的調味組成物》 較佳的組成物是含有約〇 . 1至約2 〇 p pm.3 —經 基一 2 —甲基一4H —吡喃一4 一酮乙酯和約〇. i至約 10. 00 ppm新橙皮鹼二氫査耳酮者。 本發明亦係關於包含此3 —羥基—2 —甲基一 4*H — 妣喃-4 -酮乙酯-新橙皮鹼二氫查耳酮組成物的食品。 本發明亦係關於在食品中添加3 —羥基一2 —甲基一 4 H —吡喃一 4 —酮乙酯一新橙皮鹼二氫査耳酮組成物以 修飾食品之氣味、質感和口感的方法^ 較佳的方法是該食品選自不含酒精的碳酸類飮料、不 含酒精的非碳酸類水果調味飮料、不含酒精的非碳酸類飮 料、醬油、飯後甜點、肉類產品、家禽產品、動物飼料、 糕胼類、烘烤食品、含酒精飲料、鹹餅、奶製品、佐料和 肉湯· · 在另一個實施例中’本發明係關於包含3 —羥基-2 本紙張尺度適用中國國家標準（CNS }八4说格（210X297公釐） '--- (請先閲讀背面之注意事項再填寫本瓦) .裝. 訂 A7 B7 經濟部中央標準局員工消費合作社印製 五、 發明説明 (4 ) 1 | — 甲 基 一 4 Η — D比喃 一 4 — 酮 3 — 羥 基 一 2 — 甲 基 — 4 1 Η — 吡 喃 — 4 — 酮 乙 酯 和 新 橙 皮 驗 氫 査 耳. .酮 的 sm 調 味 組 成 1 I 物 〇 1 I 較 佳 的 組 成 物 是 含 有 約 5 至 約 1 0 0 Ρ Ρ m 3 — 羥 基 請 先 閱 1 I — 2 一 甲 基 —— 4 Η — 吡 喃 4 一 酮 約 0 1 至 約 2 0 讀 背 1 1 I Ρ Ρ m 3 — 羥 基 — 2 — 甲 基 — 4 Η — 吡 喃 — 4 — 酮 乙 酯 和 之 注 意 1 1 約 0 1 至 約 1 0 0 Ρ Ρ m 新 橙 皮 鹼 二 氫 査 耳 酮 者 〇 事 項 1 I 再 美*、 本 發 明 亦係 關 於 包 含 此 3 — ρ 基 — 2 — 甲 基 — 4 Η — 寫 本 裝 I 妣 喃 — 4 — 酮 、 3 — 羥 基 — 2 — 甲 基 — 4 Η — 吡 喃 — 4 — 頁 1 酮 乙 酯 、 新 橙 皮 驗 二 氫 査 耳 酮 組 成 物 的 食 品 〇 1 I 本 發 明 亦 係 關 於 在 食 品 中 添 加 3 — 羥 基 一 2 一 ¥ 基 — I 4 Η — 吡 喃 — 4 — 酮 — 3 — 羥 基 — 2 — 甲 基 一 4 Η — 吡 1 訂 喃 — 4 — 酮 乙 酯 — 新 桓 皮 驗 二 氫 査 耳 酮 組 成 物 以 修 飾 食 品 1 1 之 氣 味 質 感 和 □ 感 的 方 法 0 1 1 較 佳 的 方 法 是 該 食 品 選 白 不 含 酒 精 的 碳 酸 類 飮 料 、 不 1 JL 含 酒 精 的 非 碳 酸 類 水 果 調 味 飮 料 、 不 含 酒 精 的 非 碳 酸 類 飮 1 料 醬 油 飯 後 甜 點 肉 類 產 品 家 禽 產 品 動 物 飼 料 I 糕 餅 類 烘 烤 食 品 含 酒 精 飮料 、 滅 餅 奶 製 品 佐 料 和 1 I 肉 湯 〇 1 1 本 發 明 亦 係 關 於 在 藥 物 中 添 加 味 道 增 強 劑 以 降 低 藥 用 1 1 組 成 物 中 之 令 人 不 悅 的 味 道 的 方 法 » 該 調 味 強 化 劑 選 白 1 1 ( a ) 3 — 羥 基 — 2 一 甲 基 — 4 Η 一 吡 喃 — 4 — 酮 1 1 一 新 橙 皮 鹼 二 氫 査 耳 酮 » 和 1 ( b ) 3 — 羥 基 — 2 一 甲 基 一 4 Η — 吡 喃 一 4 一 酮 - 1 1 本紙張尺度適用中國國家梯準（CNS ) A4規格（210X297公釐） A7 經濟部中央標準局貝工消費合作社印製 f Β7 五、 發明説明（5 ) 1 1 一 新橙 皮 鹼一 氫 査耳 酮 1 和 1 1 ( C )3 — 羥基 — 2 一 甲 基 — 4 Η — 吡 喃 — 4 — 酮 1 1 — 3 - 羥 基- 2 -甲 基 一 4 Η — 吡 喃 — 4 — 酮 乙 酯 /«—V 1 | — 新橙 皮 鹼一 氫 査耳 酮 0 請 先 閲 I 本 發 明的 某 些調 味 組 成 物 中 的 組 份 之 一 是 3 一 羥 基 — 讀 背 面 1 1 I 2 一甲 基 -4 Η -吡 喃 — 4 — 酮 〇 天 然 或 人 工 合 成 的 3 — 之 注 意 1 1 I 羥 基一 2 -甲 基 -4 Η — 吡 喃 — 4 — 酮 都 可 用 於 本 發 明 中 事 項 再 1 1 、 所謂 的 3 - 羥 基— 2 一 甲 基 一 4 Η — 吡 喃 — 4 一 酮 含 括 % 寫 本 裝 此 二者 〇 人工 合 成的 3 — 羥 基 — 2 — 甲 基 — 4 Η — 吡 喃 一 % 1 1 4 —酮 爲 Food S c i e nc e Gr 0U Ρ 0 f Pf i ze r In C . 以 註 冊 名 1 1 稱 V e 11 〇 t®售於市面上者《 a ；1 I 本 發 明的 某 些調 味 組成 物 中 的 另 — 組 份 是 3 — 羥 基 — 1 訂 2 -甲 基 -4 Η -吡 喃 一 4 — 酮 乙 酯 〇 人 工 合 成 的 3 一 羥 1 1 I 基 -2 一 甲基 — 4 Η — 吡 喃 一 4 — 酮 乙 酯 爲 Fo od 1 1 Sc i ence Grooup of Pf i Z e r I nc. 以 註 冊 名 稱 Ve 1 ΐ 〇 1 % 1 丄 P1 us售於市面上者。 I 本 發 明的 某 些調 味 組 成 物 中 的 另 — 組 份 是 新 橙 皮 驗 一 1 I 氫 査耳 酮 。它 以 Link e 和 Expu i m 名 稱 售 於 市 面 上 〇 1 1 1 在 含 有3 — 羥基 — 2 — 甲 基 一 4 Η — 吡 喃 — 4 — 酮 的 1 1 調 味組 成 物中 3 - 羥 基 一 2 — 甲 基 — 4 Η — 吡 喃 — 4 — 1 1 酮 含量 爲 約5 至 約1 0 0 P Ρ m 0 1 1 在 含 有3 — 羥基 — 2 一 甲 基 — 4 Η 一 吡 喃 — 4 — 酮 乙 1 1 酯 的調 味 組成 物 中， 3 一 羥 基 — 2 — 甲 基 一 4 Η 一 吡 喃 — 1 | 4 -酮 乙 酯含 量 爲約 0 1 至 約 2 0 Ρ P m 〇 - 1 1 本紙浪尺度速用中國國家標準（CNS ) A4说格（2丨OX297公釐） 經濟部中央標隼局Η工消費合作社印製 ^〇227ι 五、發明説明“）丨胍7.d 新1檀皮鹸二氫査耳酮在調味組成物中之含置爲約 〇· 1 至 10. Oppm0 可添加此調味組成物的非限制性實例包括不含酒精的 碳酸類飲料、不含酒精的非碳酸類水果調味飮料、不含酒 精的非碳酸類飲料、醬油、飯後甜點、肉類產品、家禽產 品、動物飼料、糕餅類、烘烤食品、含酒精飲料、鹹餅、 奶製品、佐料和肉湯。 亦可將本發明的調味組成物添入藥用組成物（處方薬 和非處方藥）中。 亦可將本發明的調味組成物添入動物飼料中。 已經對本發明作一般的描述，現將參考特定的實例。 不欲以這些實例限制本發明，本發明之目的定於所附的申 請專利範圍中。 窗例1 健恰可樂 以添加或未添加調味强化劑之市售以阿斯巴甜（ a s p a r t a ra e )甜化的健恰可樂作爲樣品，由感覺評估者所 組成的專家品評委員會對這兩種樣品進行評估： a .未添加調味强化劑的對照組之甜度品質佳、主要 的味道來自可樂，嚐試之後稍帶苦味。 b .含有3 p pm Veltol Plus的樣品的甜度和味 道都比對照組來得好。 c ·含有 1 P pm Veltol Plus 和 1 p pm 新橙皮 本紙張尺度通用中國國家標準（CNS ) A4规格（210X*：97公釐） ^n m «m (m 1^1 ^^^1 m I i. 1 - I (彡 (請先閲讀背面之注意事項再填寫本f) 訂 修正 年月曰 A7 sn 補充 B7 五、發明説明（7 ) 經濟部中央標準局負工消費合作社印製 鹸二氫査耳酮（NHDC)的樣品的甜度最高也 最持久，味道最吸引人，苦味比對照組來得低。 實例2 紅橘香料 在含有0. 1 %紅橘香料、5%蔴糖和〇. 15%棒 様酸的水溶液中添加或不添加調味强化劑，以感覺評估專 家品評委員會對這兩種樣品進行評估： a .未添加調味强化劑具有酸香、酸味，基本上爲紅 橘味。 b ·含有5 p pm Veltol的樣品的酸度稍微淡一 些Ο c _含有2 p pm Veltol Plus的樣品帶有甜度， 比較不酸，果汁味比對照組璺富。 d.含有 2ppm NHDC、3ppm Veltol 和 1 ppm Veltol Plus的樣品最具有果汁味。 賨例3 脫脂型的烤肉醬 對標準的脫脂烤肉醬進行評估。 在此烤肉番中添加不同量的Veltol、Veltol Plus 及NHDC與Vel to丨和Veltol PI us之合併物。然後與標準 烤肉轚相比較： a 標準烤肉轚帶酸味、香味澳郁且稠厚。 本紙張尺度適用中國國家標隼（CNS ) Λ4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) •裝_ 泉 10 經濟部中央標準局貝工消費合作社印製 A7 B7 五、發明説明（8 ) b . 5 0 P pm的Veltol可以提高其香味。 c . 1 〇 P pm的Veltol Plus提高其甜度並減少 酸澀感》 d . 2 ρ p m NHDC 和 30ppm Veltol 及 5 p p m Veltol Plus使其呈乳脂狀，調和調 味劑提高其香味並減少酸澀感。 實例4 : 黑（苦甜的）巧克力 在標準的黑（苦甜的）巧克力產品中添加Veltol ， 另一樣品則添加Η N DC及Veltol Plus合併物。g此產 品中含有 lOOppm Veltol,或 1 ppm HNDC 和100 ppm Veltol。 a .黑（苦甜的）巧克力具有典型的味道。 b . lOOppm Veltol提高奶油味、甜度和巧 克力特質。 c . 1 p p m H. NDC 和 lOOppm Veltol 亦提高其質感、口感及巧克力特質。含有 lOOppm Veltol的標準物並沒有明顯的 變化·。 本紙張尺度適用中國國家揉準（CNS ) A4说格（210X297公釐） .一¾^ , 訂 ^ ^ (請先閲讀背面之注意事項再填寫本頁) -11 A7 B7 經濟部中央樣準局員工消费合作社印裝 五、發明説明（ή ) 表1 I 斬檀皮敵一iOTP(NHDC)與 VLTOLeft VELTOLe-mJS(V~P)併用 1 圓 含量 HHDC (ppm) VELTOL® (ppm) VELTOL® PLUS (ppm) 註 |Apple Flavor WONF [Dargoco tt9/70F152 0.30¾ 3 50 5 NHDC:夕 獅， |Berry Flavor WONF Dargoco tt9/70E786 0.15¾ 3 60 30 NHDC : «MTfcS ° V :麵，«Μ卜 Chocolate WONF Universal ^837882 0.30¾ 3 40 4 nhdc : _，v:藝， V*P:_ N/A Chocolate Flv Tastemakertf274955 0.10% 2 3 3 NHDC:獅。V:麵，獅。1 V-P 擔。 1 Grape Flavor WOHF JDargoco tt9/7(£352 0.30% 1 0 5 HHDC ： 〇 I [Nat Lime Flavor |F8iF Ingredff94035 0.10% 2 30 3 NHDC ··獅，«KS爽。V :娜，舰雜° V-P:iiS朱較淡，賴。 ______ [Nat Tangerine Flv F8f Ingredtf94034 0.10¾ 3 5 2 NHDC :賴，趣昧略加重。V :比較^酸0 v-p ：· tmm · JN/A Vanilla Flavor D.Hichael»11967 0.30% 2 4 2 HHDC:獅，香 V : 魏。V-P :議酸!_ 〇 Nat flavor for Beef D.Michaelftl3460 0.60% 1 50 20 HHDC : 羊想味。V :甜，酿服件肉味。 V~P:雖？!嵌件肉味。 Sour Cream WONF D.HichaeItf7192 0.20¾ 2 20 6 :甜、較富奶油和酸昧〇 V :奶油床 V-P:麵，較具奶油、棚_〇 1 ^ .一裝 訂 ^ (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標芈（CNS ) M規格（2丨0X297公釐> Hv A7 B7 五、發明説明（l〇) 經濟部中央標準局貝工消費合作社印裝 新齡 满(二iOTaf與 VLTOL® 和 VELT0Le-PLIJS 併用 • ' ' ' ' ------------- mufil 含量 NHDC (ppm) VELTOL» (ppm) VELTOL®PLUS (ppm) (ppm) 註 Apple Flavor WONF Dargoco tt9/70F152 0.30¾ 3 50 5 2(HHDC),20(V),2(V-P) nBerry Flavor WOHF iDargoco tf9/70E786 0.15¾ 3 60 30 3(NHDC),30(V),10(V-P) 麵5，_， 1 JChocoIate WOHF Universal »837882 0.30¾ 3 40 4 2(NHDC),10(V),2(V-P) 高 JN/A Chocolate FIv jTastemakertf274955 0.10¾. 2 3 3 2(NHDC),2(V)，1(V-P) 賴觸 jGrape Flavor WONF IDargoco tt9/70E352 0.30¾ 1 0 5 0.8(NHDC),2(V-P) I Hat Lime Flavor F8f Ingredtt94035 0.10¾ 2 30 3 2(HHDC),10(V),1(V-P) Hat Tangerine FIv F8f Ingredtt94034 0.10% 3 5 2 2(NHDC),3(V).1(V-P) 獅且汁 ----------- H/A Vanilla Flavor D.Michaeltfll967 0.30% 2 4 2 2(HHDC),2(V),1(V-P) 香瓣提高 ——1 Hat flavor for Beef DJichael«13460 0.60% 1 50 20 1(HHDC),20(V).10(V-P) musmm ________ Sour Cream WONF D.Hichaelft7192 0.20¾ 2 20 6 aBBBaBssBBSssssass 1(NHDC),8(V),2(V-P) ---------^ 一裝-------訂-------{人一 (讀先閲讀背面之注意事項再填寫本頁) L紙張尺度適用中國國家標準（CNS > Μ規格（21〇X297公釐） 經濟部中央標隼局貝工消費合作社印裝 302271 λ7 Β7 五、發明説明（U ) 表2 新澄皮lift二儀ffi耳爾(HIIDC)與 VLT0L·和 VHJOLe-PUJS(V-P)併用 μ:___ NIIDC (ppm) VELTOL® (ppm) VELTOL® PLUS (ppm) -- 註 "clearly Canadian” 充了 丨 1 2 0 3 HHDC:獅，獅 1 VELTOL~PLUS :甜.較朗味 | 『’clearly Canadian” 充了 jwra?生娜 3 0 3 NHDC:獅♦獅》獅 I VELTOL-PUJS:獅，赌 "ocean spray” m-m 2 30 . 4 NHDC:獅，深黑feSim»麵縱 VELTOL:獅，VELTOL-PLUS :麵， "gatorade" 2 0 3 VELTOL-PUJS:麵 > 1 nfoIgersff 含有咖9晒的咖啡 2 50 丨 0 hhdc ： sm · msm I VELTOL ： Mkraft healthy |f avor丨te”原射綱發 3 50 10 Iniidc:略甜，比i V :鹽，V/P :獅，tb«坏酸 rfkraft healthy |f avor ί te”傲 3 50 0 NHDC ··麵•獅 v-p ： «st»imm 卜 aft" \mmm 3 75 10 NHDC :甜，調和味〇 VELTOL :奶油狀， tb«坏齡？。V/P :奶油狀，較艮味〇 l”kraft，· 卜纖沙拉醬 3 50 10 HHDC:獅，_,VELTOL:«»i^,獅。 V/P :甜•綱蛛 卜kraft” 1脚旨千紐《ΣΒ 3 50 0 NHDC :獅·獅 烈| VELTOL:獅,5»赚 (請先閲讀背面之注意事項再填寫本頁) 一裝· 訂 本紙張尺度適用中國國家橾準（CNS ) A4规格（210X297公釐） 五、發明説明c〆)United States patent No. 4,581, 3.78 proposes the use of the new skinning base dihydrochalcone as a sweetener for rodent control compositions. Printed by an employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. In one embodiment, the present invention relates to those containing 3-hydroxy-2-methyl-4-H-pyran-4-one and neohesperidin dihydrochalcone Seasoning composition. The preferred composition contains about 5 to about 100 p pm 3-hydroxy-2-methyl-4H-pyran-4-one and about 0.1 to about 10. Op pm neohesperidin dihydrogen Chalcone · The present invention also relates to a food containing the composition of 3-hydroxy-2-methyl-4H-pyran-4-one-nephelin dihydrochalcone. The present invention also relates to the addition of 3-hydroxy-2-methyl-1 to food. The paper size is applicable to China National Standard (CNS) A4 specification (210X: 297mm) Printed by cooperatives A7 B7 V. Description of the invention (3) 4 Method for modifying the odor, texture and mouthfeel of food by the composition of 4-H-bran-1-ketone-new hesperidin dihydrochalcone. The preferred method is that the food is selected from non-alcoholic carbonated beverages, non-alcoholic non-carbonated fruit seasonings, non-alcoholic non-carbonate seasonings, meal oils, desserts, meat products, poultry products, Animal feed, pastries, baked goods, alcoholic food, salty cakes, dairy products, condiments and broth. In another embodiment, the translation of the present invention relates to a flavoring composition containing 3_hydroxy-2-methyl-4H-pyran-4-oneketone ethyl ester and neohesperidin dihydrochalcone. The composition contains from about 0.1 to about 2 〇p pm. 3-keto-2-methyl-4H-pyran-4-pyrone ethyl ester and about 0.1 to about 10. 00 ppm neohesperidin Dihydrochalcone. The present invention also relates to a food containing the composition of 3-hydroxy-2-methyl-4 * H-carbofuran-4-ketoethyl-nepiperazine dihydrochalcone. The invention also relates to adding 3-hydroxy-2-methyl-4H-pyran-4-ketone ethyl ester-new hesperidin dihydrochalcone composition to food to modify the smell, texture and taste of food Method ^ The preferred method is that the food is selected from non-alcoholic carbonated non-alcoholic non-carbonated fruit seasoning, non-alcoholic non-carbonated non-alcoholic seasoning, soy sauce, after-meal dessert, meat products, poultry Products, animal feeds, cakes, baked goods, alcoholic beverages, salty cakes, dairy products, condiments, and broths. In another embodiment, the present invention relates to the paper size containing 3-hydroxy-2 Applicable to the Chinese National Standard (CNS) 八四 说 格 (210X297mm) '--- (please read the precautions on the back before filling in this tile). Packing. Order A7 B7 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Description of the invention (4) 1 | — Methyl 4 Η — D pyran 4 — ketone 3 — hydroxy one 2 — methyl — 4 1 Η — pyran — 4 — ketone ethyl ester and new orange peel hydrogen test Ear ... sm flavoring of ketone Form 1 I compound 〇1 I The preferred composition contains about 5 to about 1 0 0 Ρ Ρ m 3-hydroxyl please read 1 I-2 monomethyl-4 Η-pyran 4-one one about 0 1 To about 2 0 Read back 1 1 I Ρ Ρ m 3 — hydroxy — 2 — methyl — 4 Η — pyran — 4 — ethyl ketone and its attention 1 1 about 0 1 to about 1 0 0 Ρ Ρ m new orange Cortisone dihydrochalcone matters 1 I Zaimei *, the invention also pertains to the inclusion of this 3-ρ group-2-methyl-4 Η-writing equipment I-4-ketone, 3-hydroxy- 2 — Methyl — 4 Η — Pyran — 4 — Page 1 Foods consisting of ethyl ketone ethyl ester, new orange peel test dihydrochalcone composition 〇1 I The present invention also relates to the addition of 3-hydroxyl 2 in food ¥ base — I 4 Η — pyran — 4 — ketone — 3 — hydroxy — 2 — methyl — 4 Η — pyran 1 indan — 4 — ketone ethyl ester — neon The method of skin inspection of dihydrochalcone composition to modify the odor and texture of food 1 1 0 1 1 The preferred method is to select white non-alcoholic carbonated food for the food, not 1 JL alcoholic non-carbonated Fruit-like seasoning buns, non-alcoholic non-carbonated buns 1 soy sauce after-meal dessert meat products poultry products animal feed I pastry baked goods alcohol-containing buns, extinguisher dairy condiments and 1 I broth 〇1 1 The invention also relates to a method of adding a taste enhancer to the medicine to reduce the unpleasant taste in the composition of medicinal 1 1 »The flavor enhancer is selected to be white 1 1 (a) 3 — hydroxy — 2 monomethyl — 4 Η monopyran — 4 — ketone 1 1 a new hesperidin dihydrochalcone »and 1 (b) 3 — hydroxy — 2 monomethyl-4 Η — pyran-4-one-1 1 paper ruler Applicable to China National Standards (CNS) A4 specifications (210X297 mm) A7 Printed by Beigong Consumer Cooperative of Central Bureau of Standards of the Ministry of Economy f Β7 5. Description of invention (5) 1 1 A new hesperidin monohydrochalcone 1 and 1 1 (C) 3 — Hydroxy — 2 monomethyl — 4 Η — pyran — 4 — ketone 1 1 — 3-Hydroxy-2 — methyl — 4 Η — pyran — 4 — ketoethyl ester / «— V 1 | — Neohesperidin monohydrochalcone 0 Please read first I One of the components in certain flavoring compositions of the present invention is 3 monohydroxy — read the back 1 1 I 2 monomethyl-4 Η -pyridine Pyran-4-one ketones ○ Natural or synthetic 3- Note 1 1 I hydroxy 2- 2-methyl-4 Η-pyran -4- ketone can be used in the present invention matter 1 1, the so-called 3-hydroxy — 2 monomethyl-4 Η — pyran — 4 one ketone contains% written copy of both of them. Synthetic 3 — hydroxy — 2 — methyl — 4 Η — pyran 1% 1 1 4 — The ketone is Food S cie nc e Gr 0U Ρ 0 f Pf i ze r In C. It is sold under the registered name 1 1 and is known as V e 11 〇t® on the market "a; 1 I Certain flavoring compositions of the invention The other component in the 3-hydroxy group is 3-hydroxy-4 Η-pyran-4-ketone ethyl ester. The synthetic 3-hydroxyl 1 1 I group-2 monomethyl-4 Η -pyridine Nan-4 — Ketoethyl ester is Fo od 1 1 Sc Ience Grooup of Pf I Zer I nc. It is sold on the market under the registered name Ve 1 1 〇1% 1 丄 P1 us. I The other component of some flavoring compositions of the present invention is New Orange Peel Test 1 I Hydrochalcone. It is sold on the market under the names Link e and Expu im. 1 1 1 In 1 1 flavoring composition containing 3 — hydroxy — 2 — methyl — 4 Η — pyran — 4 — ketone 3 — hydroxy — 2 — A The base-4 Η-pyran-4-1 1 ketone content is about 5 to about 1 0 0 P Ρ m 0 1 1 contains 3-hydroxy-2 monomethyl-4 Η monopyran-4-ketone 1 1 In the ester flavoring composition, the content of 3-hydroxyl-2-methyl-4H-pyran-1 | 4-ketoethyl ester is about 0 1 to about 2 0 P P m 〇- 1 1 Printed with the Chinese National Standard (CNS) A4 (2 丨 OX297mm) Printed by the Central Standard Falcon Bureau of the Ministry of Economic Affairs, Hgong Consumer Cooperative Co., Ltd. ^ 〇227ι 5. Description of the invention ") guanidine 7.d new 1 sandalwood dihydrogen The content of chalcone in the flavoring composition is about 0.1 to 10. Oppm0. Non-limiting examples of the flavoring composition that can be added include non-alcoholic carbonated beverages and non-alcoholic non-carbonated fruit flavoring ingredients , Non-alcoholic non-carbonated drinks, soy sauce, After-meal desserts, meat products, poultry products, animal feed, cakes, baked goods, alcoholic beverages, salty cakes, dairy products, condiments and broths. The seasoning composition of the present invention can also be added to medicinal compositions Substances (prescription medicines and over-the-counter medicines). The seasoning composition of the present invention can also be added to animal feed. The present invention has been described in general, and reference will now be made to specific examples. It is not intended that these examples limit the invention. The purpose is set in the scope of the attached patent application. Window example 1 Jiancha Cola is a commercially available Jian Jia Cola sweetened with asparta ra e with or without added flavor enhancer as a sample The expert evaluation committee composed of the evaluators evaluated these two samples: a. The control group without added flavor enhancer has good sweetness quality, the main taste comes from Coke, and it is slightly bitter after trying. B. Contains 3 p pm Veltol Plus samples have better sweetness and taste than the control group. C · Contains 1 P pm Veltol Plus and 1 p pm New Orange Peel on Paper Standard General Chinese National Standard (CNS) A 4 Specifications (210X *: 97 mm) ^ nm «m (m 1 ^ 1 ^^^ 1 m I i. 1-I (彡 (please read the precautions on the back and fill in this f) to set the revision date A7 sn supplements B7 5. Description of the invention (7) The sample printed by the National Standards Bureau of the Ministry of Economic Affairs of the Negative Consumers Cooperative of NHDC samples has the highest sweetness and the longest lasting taste, the most attractive taste, and a bitter taste than the control group Come low. Example 2 Red tangerine flavor was added with or without the addition of flavor enhancer in an aqueous solution containing 0.1% red tangerine flavor, 5% hemp sugar and 0.15% clavulanic acid to evaluate these two samples by expert evaluation committee Evaluation: a. Without added flavor enhancer, it has a sour aroma and a sour taste, basically a red orange flavor. b. The acidity of the sample containing 5 p pm Veltol is slightly lighter. c _The sample containing 2 p pm Veltol Plus has sweetness and is less sour. The fruit juice taste is richer than the control group. d. Samples containing 2 ppm NHDC, 3 ppm Veltol and 1 ppm Veltol Plus have the most juice flavor. Example 3 Skimmed barbecue sauce The standard skimmed barbecue sauce was evaluated. In this roasted meat dish, different amounts of Veltol, Veltol Plus, and the combination of NHDC, Vel Tol and Veltol PI us are added. Then compare it with the standard roasted pork roast: a Standard roasted roast pork has a sour, savory and thick flavor. This paper scale is applicable to China National Standard Falcon (CNS) Λ4 specification (210X297mm) (please read the precautions on the back before filling in this page) • Install _ Quan 10 A7 B7 printed by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs , Description of the invention (8) b. 50 P pm Veltol can improve its fragrance. c. Velol Plus at 10 P pm improves its sweetness and reduces sourness. d. 2 ρ p m NHDC and 30 ppm Veltol and 5 pm Veltol Plus make it creamy, and blending flavoring agents enhances its fragrance and reduces sourness. Example 4: Dark (bitter sweet) chocolate Veltol is added to a standard dark (bitter sweet) chocolate product, and the other sample is a combination of H N DC and Veltol Plus. g This product contains 100 ppm Veltol, or 1 ppm HNDC and 100 ppm Veltol. a. Dark (bitter) chocolate has a typical flavor. b. 100ppm Veltol enhances creaminess, sweetness and chocolate qualities. c. 1 p p m H. NDC and lOOppm Veltol also improve its texture, taste and chocolate characteristics. Standards containing 100 ppm Veltol did not change significantly. This paper scale is applicable to the Chinese National Standard (CNS) A4 format (210X297mm). One ^^, order ^^ (please read the precautions on the back before filling this page) -11 A7 B7 Central Bureau of Standards Printed by the Employee Consumer Cooperative V. Description of the Invention (ή) Table 1 I cut the tantalid enemy iOTP (NHDC) and VLTOLeft VELTOLe-mJS (V ~ P) and use 1 round content HHDC (ppm) VELTOL® (ppm) VELTOL® PLUS (ppm) Note | Apple Flavor WONF [Dargoco tt9 / 70F152 0.30¾ 3 50 5 NHDC: Xishi, | Berry Flavor WONF Dargoco tt9 / 70E786 0.15¾ 3 60 30 NHDC: «MTfcS ° V: noodles,« Μ 卜 Chocolate WONF Universal ^ 837882 0.30¾ 3 40 4 nhdc: _, v: art, V * P: _ N / A Chocolate Flv Tastemakertf274955 0.10% 2 3 3 NHDC: lion. V: Face, lion. 1 V-P load. 1 Grape Flavor WOHF JDargoco tt9 / 7 (£ 352 0.30% 1 0 5 HHDC: 〇I [Nat Lime Flavor | F8iF Ingredff94035 0.10% 2 30 3 NHDC · Lion, «KS cool. V: Na, ship miscellaneous ° VP: iiS Zhu is relatively light, Lai. ______ [Nat Tangerine Flv F8f Ingredtf94034 0.10¾ 3 5 2 NHDC: Lai, slightly more amusing. V: Comparison ^ acid 0 vp: · tmm · JN / A Vanilla Flavor D. Hichael »11967 0.30 % 2 4 2 HHDC: lion, fragrant V: Wei. VP: neat sour! _ 〇Nat flavor for Beef D. Michaelftl 3460 0.60% 1 50 20 HHDC: sheep wants to taste. V: sweet, meaty flavor of brewing. V ~ P: Although ?! Meat flavor of insert. Sour Cream WONF D.HichaeItf7192 0.20¾ 2 20 6: Sweet, richer cream and sour 〇V: Cream bed VP: noodles, more creamy, shed_〇1 ^ .1 Binding ^ (Please read the precautions on the back before filling out this page) This paper size is applicable to the Chinese National Standard (CNS) M specifications (2 丨 0X297mm> Hv A7 B7 V. Description of invention (l〇) Central Ministry of Economic Affairs Bureau of Standards, Beigong Consumer Cooperative Printed New Age Full (two iOTaf and VLTOL® and VELT0Le-PLIJS are used together • '' '' ------------- mufil content NHDC (ppm) VELTO L »(ppm) VELTOL®PLUS (ppm) (ppm) Note Apple Flavor WONF Dargoco tt9 / 70F152 0.30¾ 3 50 5 2 (HHDC), 20 (V), 2 (VP) nBerry Flavor WOHF iDargoco tf9 / 70E786 0.15¾ 3 60 30 3 (NHDC), 30 (V), 10 (VP) Surface 5, _, 1 JChocoIate WOHF Universal »837882 0.30¾ 3 40 4 2 (NHDC), 10 (V), 2 (VP) High JN / A Chocolate FIv jTastemakertf274955 0.10¾. 2 3 3 2 (NHDC), 2 (V), 1 (VP) Lai Touch jGrape Flavor WONF IDargoco tt9 / 70E352 0.30¾ 1 0 5 0.8 (NHDC), 2 (VP) I Hat Lime Flavor F8f Ingredtt94035 0.10¾ 2 30 3 2 (HHDC), 10 (V), 1 (VP) Hat Tangerine FIv F8f Ingredtt94034 0.10% 3 5 2 2 (NHDC), 3 (V) .1 (VP) Lion and Juice- ---------- H / A Vanilla Flavor D. Michaeltfll967 0.30% 2 4 2 2 (HHDC), 2 (V), 1 (VP) Incense petals enhancement-1 Hat flavor for Beef DJichael «13460 0.60% 1 50 20 1 (HHDC), 20 (V) .10 (VP) musmm ________ Sour Cream WONF D.Hichaelft7192 0.20¾ 2 20 6 aBBBaBssBBSssssass 1 (NHDC), 8 (V), 2 (VP) --- ------ ^ One Pack ------- Order ------- {人 一 (Read the precautions on the back and then fill out this page) L paper size is applicable to Chinese national standards (CNS > Μ specifications (21〇X297 mm) Printed by the Central Standard Falcon Bureau Beigong Consumer Cooperative of the Ministry of Economic Affairs 302271 λ7 Β7 V. Description of Invention (U) Table 2 New Chengpi Lift II instrument ffi Earl (HIIDC) and VLT0L · Used with VHJOLe-PUJS (VP) μ: ___ NIIDC (ppm) VELTOL® (ppm) VELTOL® PLUS (ppm)-Note " clearly Canadian ”is filled with 丨 1 2 0 3 HHDC: Lion, Lion 1 VELTOL ~ PLUS : Sweet. Relatively sweet | "'clearly Canadian" is filled with jwra? Shengna 3 0 3 NHDC: lion lion "lion I VELTOL-PUJS: lion, betting " ocean spray" mm 2 30. 4 NHDC: lion, Deep black feSim »face vertical VELTOL: lion, VELTOL-PLUS: face, " gatorade " 2 0 3 VELTOL-PUJS: face > 1 nfoIgersff coffee with coffee 9 drying 2 50 丨 0 hhdc ： sm · msm I VELTOL ： Mkraft healthy | f avor 丨 te "original radiograph 3 50 10 Iniidc: slightly sweeter than i V: salt, V / P: lion, tb« bad acid rfkraft healthy | f avor ί te ”proud 3 50 0 NHDC · · Noodles lion vp: «st» imm bu aft " \ mmm 3 75 10 NHDC: sweet, harmonious taste VELTOL: creamy, tb «bad age? . V / P: creamy, more flavorful 〇l ”kraft, · Bo fiber salad dressing 3 50 10 HHDC: lion, _, VELTOL:« »i ^, lion. V / P: sweet • Gang spider kraft” 1 The purpose is thousands of New Zealand "ΣΒ 3 50 0 NHDC: lion · lion | VELTOL: lion, 5» earn (please read the precautions on the back and then fill out this page) One Pack · The standard paper size is applicable to the Chinese National Standard (CNS ) A4 specification (210X297mm) V. Description of the invention c〆)
A B 經濟部中央標隼局負工消費合作社印裝 新澄皮齡二氣査耳铜與VLTOL»和VHLTOLUJS併用 |產品 KfiDC (ppm) VELTOL» (ppm) VELTOLePLUS (ppm) 混钱 (ppm) 註 "clearly Canadian·’ ytimmm 2 0 3 HHDC ⑵，V/P ⑴ 娜》#1 『’clearly Canadian" mimmsmmm 3 0 3 NHDC(2),V/P(1) wm I 『ocean spray” |獅—灘 2 30 4 NHDC ⑴，V(10)，V/P ⑵ 藤·具點雜 |”gatorade’’ |赚-獅 2 0 3 HHDC(2),V/P(1) |”folgers” |含綱f因剛f 2 50 0 HHDC⑵.V(30> fcb*^ > 1 rVaft healthy |f a vor i te”JP制離IS 3 50 10 NHDC⑵，V(30),V/P ⑹ 奶職，獅，赚| 猶，#I "kraft healthy favodte”煙馈烤肉醬 3 50 0 HHDC ⑵，V(20)，V/P ⑶ 獅ι "kraft" 腳瞧路 3 75 10 HHDC ⑵,V(10),V/P ⑴ 娜且1 "kraft" |_脚蜜沙拉發 3 50 10 NHDC ⑴,V(10)，V/P ⑵ 麵》獅的寒^ 卜kraft” USSTf船拉路 3 50 0 HHDC ⑴,V (10) mm · mm - m s ---------J_<裝-- (请先Η讀背面之注$項再填寫本頁) 訂 302271 ^ 五、發明説明（a ) 表3 新措皮齡二氣査耳铜(NHDC)與VLTCLe* VELTOL.-PLUSOH»)併用 產品 NHDC ippm) VELTOL® (ppm) VELTOLePLUS (ppm) 註 ’’Lipton Iced Tea Mix” mmm 3 50 5 NHDC :觀》. V:獅•麵，V/P:香味更濟 "Lipton Iced Tea Mix” 3 50 5 NHDC ： · tbep^o VELTOL ： VELTOL-PLUS :獅，赌 Tipton Iced Tea Mixn nmm 0 0 0 "Lipton Iced Tea Mix'· 3 —~·_ 3 20 3 HHDC ： ' VELTOL:獅· TO · ¢038^3 · > v/p ： mm · <ss» "Lipton Iced Tea Mix" 20 0 VELTOL ： SWU | ----------J 裝-- (婧先閲讀背面之注意事項再填寫本頁). -訂 經濟部中央梂準局負工消费合作社印装 本紙張尺度適用中國國家橾隼（CNS ) A4規格（210X297公釐） 一| bAB The Ministry of Economic Affairs Central Standard Falcon Bureau Negative Work Consumer Cooperative Printed Xincheng Piling Erqi Charcoal Copper in combination with VLTOL »and VHLTOLUJS | Product KfiDC (ppm) VELTOL» (ppm) VELTOLePLUS (ppm) Mixed Money (ppm) Note " clearly Canadian · 'ytimmm 2 0 3 HHDC ⑵ ， V / P ⑴ 娜》 # 1 『' clearly Canadian " mimmsmmm 3 0 3 NHDC (2), V / P (1) wm I『 ocean spray ” 2 30 4 NHDC ⑴, V (10), V / P ⑵ Vine · with some miscellaneous | "gatorade" | Earn-Lion 2 0 3 HHDC (2), V / P (1) | "folgers" | with outline f because just f 2 50 0 HHDC⑵.V (30 > fcb * ^ > 1 rVaft healthy | fa vor i te ”JP system IS 3 50 10 NHDC⑵, V (30), V / P ⑹ Dairy, lion, Earn | Jewish, #I " kraft healthy favodte "smoke-fed barbecue sauce 3 50 0 HHDC ⑵, V (20), V / P ⑶ lion ι " kraft " foot and look at the road 3 75 10 HHDC ⑵, V (10) , V / P ⑴ Naqi 1 " kraft " | _foot honey salad hair 3 50 10 NHDC ⑴, V (10), V / P ⑵ noodles》 The cold of lion ^ bu kraft ”USSTf boat pull road 3 50 0 HHDC ⑴, V (10) mm · mm-ms --------- J_ < installation-- (please read the note $ item on the back before filling in this page) Order 3 02271 ^ V. Description of the invention (a) Table 3 Xincuoting Erqi Chaer Copper (NHDC) and VLTCLe * VELTOL.-PLUSOH ») combined product NHDC ippm) VELTOL® (ppm) VELTOLePLUS (ppm) Note` `Lipton Iced Tea Mix ”mmm 3 50 5 NHDC: View”. V: Lion • Noodle, V / P: Better fragrance " Lipton Iced Tea Mix ”3 50 5 NHDC: · tbep ^ o VELTOL: VELTOL-PLUS: Lion, Bet Tipton Iced Tea Mixn nmm 0 0 0 " Lipton Iced Tea Mix '· 3 — ~ · _ 3 20 3 HHDC:' VELTOL: Lion · TO · ¢ 038 ^ 3 · > v / p: mm · < ss »&Quot; Lipton Iced Tea Mix " 20 0 VELTOL: SWU | ---------- J outfit-(Jing first read the precautions on the back and then fill out this page). -Subscribe to the Central Bureau of Economic Affairs of the Ministry of Economic Affairs The size of the paper printed by the Negative Consumer Cooperative applies to the Chinese National Falcon (CNS) A4 specification (210X297mm) I | b