TW201721665A - Cable and liquid detector for use in cable - Google Patents
Cable and liquid detector for use in cable Download PDFInfo
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- TW201721665A TW201721665A TW105132345A TW105132345A TW201721665A TW 201721665 A TW201721665 A TW 201721665A TW 105132345 A TW105132345 A TW 105132345A TW 105132345 A TW105132345 A TW 105132345A TW 201721665 A TW201721665 A TW 201721665A
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01M—TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
- G01M3/00—Investigating fluid-tightness of structures
- G01M3/02—Investigating fluid-tightness of structures by using fluid or vacuum
- G01M3/04—Investigating fluid-tightness of structures by using fluid or vacuum by detecting the presence of fluid at the leakage point
- G01M3/16—Investigating fluid-tightness of structures by using fluid or vacuum by detecting the presence of fluid at the leakage point using electric detection means
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/32—Insulated conductors or cables characterised by their form with arrangements for indicating defects, e.g. breaks or leaks
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- General Physics & Mathematics (AREA)
- Examining Or Testing Airtightness (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
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Abstract
Description
本發明係關於一種發送電力或信號之纜線及纜線用液體檢測構件。The present invention relates to a liquid detecting member for a cable and a cable for transmitting electric power or signals.
先前,作為能夠檢測液體之滲入之纜線,有如專利文獻1~3者。專利文獻1揭示有如下構成,即,於覆蓋纜線芯之塑膠外覆之內側設置電性絕緣之複數根導電性塑膠條,根據導電性塑膠條間之電特性之變化而利用外覆位準檢測外傷或滲水。專利文獻2揭示有如下構成,即,於導體上積層內部半導電層、絕緣層、外部半導電層、遮蔽層、外部鞘,且設置有檢測滲入至外部鞘內之水分之被覆型感測器。專利文獻3揭示有如下構成,即設置有:將箔狀或帶狀金屬沿長度方向以螺旋狀捲繞於多芯纜線之芯部位之外周而構築成的電極;配置於該電極之周緣上之透水構造的絕緣層;及配置於該絕緣層之外周之電極。 [先前技術文獻] [專利文獻] [專利文獻1]日本專利特開平06-338227號公報 [專利文獻2]日本專利特開2010-286422號公報 [專利文獻3]日本專利特開平08-261862號公報Conventionally, as a cable capable of detecting penetration of a liquid, there are as disclosed in Patent Documents 1 to 3. Patent Document 1 discloses a configuration in which a plurality of electrically conductive plastic strips are electrically insulated on the inner side of a plastic outer covering of a cable core, and the outer covering level is utilized according to changes in electrical characteristics between the conductive plastic strips. Detection of trauma or water seepage. Patent Document 2 discloses a configuration in which an inner semiconductive layer, an insulating layer, an outer semiconductive layer, a shielding layer, and an outer sheath are laminated on a conductor, and a coated sensor that detects moisture permeating into the outer sheath is provided. . Patent Document 3 discloses a configuration in which a foil-shaped or strip-shaped metal is spirally wound around a core portion of a multi-core cable in a longitudinal direction, and is disposed on the periphery of the electrode. An insulating layer of a water permeable structure; and an electrode disposed on a periphery of the insulating layer. [PRIOR ART DOCUMENT] [Patent Document 1] Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Bulletin
[發明所欲解決之問題] 然而,於上述先前之構成中,必須檢測電極間之電阻值之較小之變化,因此,存在如下問題,即,難以以較高之可靠性檢測因外覆破損而滲入之液體,或難以調整受電極構件間之距離影響之液體之檢測感度。 本發明係鑒於上述問題而完成者,其目的在於提供一種能夠以較高之可靠性檢測滲入至纜線之外覆內側之液體,且能夠容易地調整液體之檢測感度之纜線及纜線用液體檢測構件。 [解決問題之技術手段] 為了解決上述課題,本發明之纜線之特徵在於具有:纜線芯;液體檢測構件,其與上述纜線芯一併設置;及外覆,其被覆上述纜線芯及上述液體檢測構件;且上述液體檢測構件具有:絕緣構件,其藉由與液體之接觸而發揮導電性;及複數個線狀之電極構件,其等以接觸狀態設置於上述絕緣構件之同一面上,且相互電性分離。 根據上述構成,於外覆破損而液體滲入至外覆之內側之情形時,絕緣構件藉由與液體之接觸而發揮導電性,藉此,以接觸狀態設置於絕緣構件之電極構件間自電性絕緣狀態變為導電狀態。藉此,可藉由檢測電極構件間之電阻值之較大變化而以較高之可靠性檢測因外覆破損而滲入的液體。 又,液體檢測構件藉由將線狀之電極構件配置於絕緣構件之同一面上,而相較於將電極構件配置於絕緣構件之厚度方向之情形,能夠使電極構件間之距離較大地變化。藉此,能夠容易地調整受電極構件間之距離影響之液體之檢測感度。 又,於本發明之纜線中,亦可為上述絕緣構件形成為片狀,於上述絕緣構件之表面,上述電極構件彼此相互並行地配置。根據上述構成,液體檢測構件具有片狀之外形,藉此,可根據纜線之用途或構造、設置場所等而選擇性地採用各種液體檢測構件之一併設置方法。 又,於本發明之纜線中,亦可為上述液體檢測構件呈螺旋狀配置於上述纜線芯之周圍。於例如與纜線芯之長度方向(延伸方向)平行地配置液體檢測構件之情形時,若滲入至外覆內側之液體僅於纜線芯之長度方向擴散,則有可能難以檢測液體。另一方面,於如上述構成般,將液體檢測構件呈螺旋狀配置於纜線芯之周圍之情形時,無論滲入至外覆內側之液體向哪一方向擴散,均能檢測液體,因此,相較於與纜線芯之長度方向平行地配置之情形,容易檢測滲入至外覆內側之液體。 又,於本發明之纜線中,亦可為上述液體檢測構件具有可剝離地被覆上述絕緣構件及上述電極構件之保護層。根據上述構成,於絕緣構件之被保護層被覆之部位,保護層阻止液體向絕緣構件滲入,因此,只要保護層正常地存在,則絕緣構件就不會發揮導電性。因此,於此情形時,液體檢測構件成為主要檢測絕緣構件之已剝離保護層之部位之液體滲入之構成。藉此,例如,僅對可能會因液體之滲入而引起重大故障等之必須進行監視之監視部位將保護層剝離,藉此於監視部位以外,只要未於纜線產生使保護層破損之程度之較大之破損,則可不檢測液體之滲入。如此,藉由於監視部位及監視部位以外使滲入液體之檢測感度不同,可抑制進行不必要之纜線之更換或修理。 又,於本發明之纜線中,亦可為上述液體檢測構件係使上述絕緣構件形成為片狀,且於上述絕緣構件之表面,上述電極構件彼此相互並行地配置,且具有被覆上述絕緣構件及上述電極構件之保護層,上述保護層相對於上述絕緣構件中之上述電極構件間之內側區域、及除上述內側區域及上述電極構件之配置區域以外之外側區域之各者的剝離強度為上述內側區域小於上述外側區域。根據上述構成,外側區域相較於內側區域而保護層更難以剝離,因此,液體檢測構件能抵抗來自外部之負載,從而可提高纜線之可靠性。又,於進行將保護層剝離而使絕緣構件露出至外部之作業時,若利用輔具切除被覆於容易確保作業空間之外側區域之保護層,則僅殘留以較小之剝離強度被覆於內側區域之保護層。因此,可容易地將保護層自絕緣構件剝離。藉此,於保護層中,即便被覆於絕緣構件之內側區域之部位之剝離強度相當小,例如即便為可用手作業剝離之程度之剝離強度,由於被覆於絕緣構件之外側區域之部位之剝離強度較大,故而可一面維持液體檢測構件之相對於機械負載之可靠性一面容易地進行剝離作業。 又,本發明之纜線用液體檢測構件之特徵在於:其係一併設置於纜線之外覆內側之纜線用液體檢測構件,且具有:絕緣構件,其藉由與液體之接觸而發揮導電性;複數個線狀之電極構件,其等以接觸狀態設置於上述絕緣構件,且相互電性分離;及保護層,其可剝離地被覆上述絕緣構件及上述電極構件。 根據上述構成,於絕緣構件之被保護層被覆之部位,保護層阻止液體向絕緣構件滲入,因此,只要保護層正常地存在,則絕緣構件不會發揮導電性。因此,於此情形時,纜線用液體檢測構件成為主要檢測絕緣構件之已剝離保護層之部位之液體滲入之構成。藉此,例如僅對可能會因液體滲入而導致產生重大故障等之必須進行監視之監視部位將保護層剝離,藉此於監視部位以外,只要未於纜線產生使保護層破損之程度之較大之破損,則可不檢測液體之滲入。如此,藉由於監視部位及監視部位以外使滲入液體之檢測感度不同,可抑制進行不必要之纜線之更換或修理。 又,於本發明之纜線用液體檢測構件中,亦可為上述絕緣構件形成為片狀,於上述絕緣構件之表面,上述電極構件彼此相互並行地配置,上述保護層相對於上述絕緣構件中之上述電極構件間之內側區域、及除上述內側區域及上述電極構件之配置區域以外之外側區域之剝離強度為上述內側區域小於上述外側區域。根據上述構成,由於外側區域相較於內側區域而保護層更難以剝離,故而液體檢測構件相對於來自外部之負載較強,從而可提高纜線之可靠性。又,於進行將保護層剝離而使絕緣構件露出至外部之作業時,若利用輔具將被覆於易於確保作業空間之外側區域之保護層切除,則僅殘留以較小之剝離強度被覆於內側區域之保護層。因此,可容易地將保護層自絕緣構件剝離。藉此,於保護層中,即便被覆於絕緣構件之內側區域之部位之剝離強度相當小,例如即便為可用手作業剝離之程度之剝離強度,由於被覆於絕緣構件之外側區域之部位之剝離強度較大,故而可一面維持液體檢測構件之相對於機械負載之可靠性,一面容易地進行剝離作業。 又,於本發明之纜線用液體檢測構件中,亦可為上述保護層具有片狀之保護片、及接著於上述絕緣構件之接著層,上述絕緣構件之相對於上述接著層之每單位面積之接觸面積係上述內側區域小於上述外側區域。根據上述構成,可藉由絕緣構件之相對於接著層之每單位面積之接觸面積之大小,而於保護層之被覆於絕緣構件之外側區域之部位及被覆於內側區域之部位使其剝離強度變化。 [發明之效果] 本發明能夠以較高之可靠性檢測滲入至纜線之外覆內側之液體,並且能夠容易地調整液體之檢測感度。[Problem to be Solved by the Invention] However, in the above-described prior art, it is necessary to detect a small change in the resistance value between the electrodes, and therefore, there is a problem that it is difficult to detect the damage due to the outer cover with high reliability. The liquid infiltrated, or it is difficult to adjust the detection sensitivity of the liquid affected by the distance between the electrode members. The present invention has been made in view of the above problems, and an object of the present invention is to provide a cable and a cable capable of detecting a liquid which is infiltrated to the inside of a cable with high reliability and which can easily adjust the detection sensitivity of the liquid. Liquid detecting member. [Means for Solving the Problems] In order to solve the above problems, the cable of the present invention is characterized by comprising: a cable core; a liquid detecting member which is provided together with the cable core; and an outer covering which covers the cable core And the liquid detecting member; wherein the liquid detecting member has an insulating member that exhibits conductivity by contact with a liquid; and a plurality of linear electrode members that are disposed in contact with each other on the same side of the insulating member Upper, and electrically separated from each other. According to the above configuration, when the outer covering is broken and the liquid infiltrates into the inner side of the outer covering, the insulating member exhibits conductivity by contact with the liquid, whereby the self-electricity is provided between the electrode members of the insulating member in the contact state. The insulated state changes to a conductive state. Thereby, it is possible to detect the liquid infiltrated by the outer covering damage with high reliability by detecting a large change in the resistance value between the electrode members. Further, the liquid detecting member can arrange the electrode member on the same surface of the insulating member, and the distance between the electrode members can be largely changed as compared with the case where the electrode member is disposed in the thickness direction of the insulating member. Thereby, the detection sensitivity of the liquid affected by the distance between the electrode members can be easily adjusted. Further, in the cable of the present invention, the insulating member may be formed in a sheet shape, and the electrode members may be arranged in parallel with each other on a surface of the insulating member. According to the above configuration, the liquid detecting member has a sheet-like outer shape, whereby one of the various liquid detecting members and the setting method can be selectively employed depending on the use, structure, installation place, and the like of the cable. Moreover, in the cable of the present invention, the liquid detecting member may be spirally disposed around the cable core. For example, when the liquid detecting member is disposed in parallel with the longitudinal direction (extension direction) of the cable core, if the liquid that has penetrated into the outer covering is diffused only in the longitudinal direction of the cable core, it may be difficult to detect the liquid. On the other hand, when the liquid detecting member is disposed in a spiral shape around the cable core as in the above configuration, the liquid can be detected regardless of which direction the liquid penetrating into the outer side is diffused, and therefore, the phase is detected. It is easier to detect the liquid that has penetrated into the outer side of the outer cover than when it is disposed in parallel with the longitudinal direction of the cable core. Moreover, in the cable of the present invention, the liquid detecting member may have a protective layer that can peelably cover the insulating member and the electrode member. According to the above configuration, the protective layer prevents the liquid from penetrating into the insulating member at the portion where the insulating member is covered by the protective layer. Therefore, if the protective layer is normally present, the insulating member does not exhibit conductivity. Therefore, in this case, the liquid detecting member is configured to mainly infiltrate the liquid infiltrated at the portion of the peeling protective layer of the insulating member. In this way, for example, the protective layer is peeled off only for the monitoring portion that is likely to be monitored due to the infiltration of the liquid, and the protective layer is not damaged by the cable. For larger breakage, the penetration of liquid may not be detected. In this way, since the detection sensitivity of the infiltrated liquid is different from the monitoring portion and the monitoring portion, it is possible to suppress unnecessary replacement or repair of the cable. Further, in the cable of the present invention, the insulating member may be formed in a sheet shape, and the electrode members may be arranged in parallel with each other on the surface of the insulating member, and may have the insulating member covered. And a protective layer of the electrode member, wherein a peeling strength of the protective layer with respect to an inner region between the electrode members of the insulating member and an outer region other than the inner region and the electrode member disposed region is The inner region is smaller than the outer region described above. According to the above configuration, the outer layer is more difficult to peel off than the inner region, and therefore, the liquid detecting member can withstand the load from the outside, and the reliability of the cable can be improved. In addition, when the protective layer is peeled off and the insulating member is exposed to the outside, when the protective layer is removed by the auxiliary tool and is easily secured to the outer side of the working space, only the inner region is covered with a small peeling strength. Protective layer. Therefore, the protective layer can be easily peeled off from the insulating member. Therefore, in the protective layer, even if the peeling strength of the portion covered in the inner region of the insulating member is relatively small, for example, the peeling strength of the portion which is covered by the outer side region of the insulating member is peeling strength even if it is peeled off by hand work. Since it is large, the peeling operation can be easily performed while maintaining the reliability of the liquid detecting member with respect to the mechanical load. Further, the liquid detecting member for a cable according to the present invention is characterized in that it is provided in a liquid detecting member for a cable which is disposed inside the cable, and has an insulating member which is brought into contact with the liquid. Conductivity; a plurality of linear electrode members which are provided in contact with each other in an insulating state and electrically separated from each other; and a protective layer which is capable of peelingly covering the insulating member and the electrode member. According to the above configuration, the protective layer prevents the liquid from penetrating into the insulating member at the portion where the insulating member is covered by the protective layer. Therefore, the insulating member does not exhibit conductivity as long as the protective layer is normally present. Therefore, in this case, the liquid detecting member for a cable is configured to mainly infiltrate the liquid in the portion of the peeling protective layer of the insulating member. Thereby, for example, the protective layer is peeled off only for the monitoring portion that must be monitored due to the infiltration of the liquid, which causes a major failure, and the like, as long as the protective layer is not damaged by the cable. If the damage is large, the penetration of the liquid may not be detected. In this way, since the detection sensitivity of the infiltrated liquid is different from the monitoring portion and the monitoring portion, it is possible to suppress unnecessary replacement or repair of the cable. Further, in the liquid detecting member for a cable of the present invention, the insulating member may be formed in a sheet shape, and the electrode members may be arranged in parallel with each other on a surface of the insulating member, and the protective layer may be opposed to the insulating member. The peeling strength of the inner region between the electrode members and the outer region other than the inner region and the electrode member is smaller than the outer region. According to the above configuration, since the outer layer is more difficult to peel off than the inner region, the liquid detecting member is stronger with respect to the load from the outside, and the reliability of the cable can be improved. In addition, when the protective layer is peeled off and the insulating member is exposed to the outside, when the protective layer is removed by the auxiliary tool and the area outside the working space is easily removed, only the small peeling strength is left on the inside. The protective layer of the area. Therefore, the protective layer can be easily peeled off from the insulating member. Therefore, in the protective layer, even if the peeling strength of the portion covered in the inner region of the insulating member is relatively small, for example, the peeling strength of the portion which is covered by the outer side region of the insulating member is peeling strength even if it is peeled off by hand work. Since it is large, the peeling work can be easily performed while maintaining the reliability of the liquid detecting member with respect to the mechanical load. Further, in the liquid detecting member for a cable of the present invention, the protective layer may have a sheet-shaped protective sheet and an adhesive layer subsequent to the insulating member, and the insulating member may have a unit area with respect to the adhesive layer. The contact area is such that the inner area is smaller than the outer area. According to the above configuration, the peeling strength can be changed in the portion of the protective layer covering the outer side region of the insulating member and the portion covering the inner region by the contact area per unit area of the insulating member with respect to the adhesive layer. . [Effect of the Invention] According to the present invention, it is possible to detect a liquid that has penetrated into the outer side of the cable with high reliability, and it is possible to easily adjust the detection sensitivity of the liquid.
(第1實施形態) 以下,一面參照圖式一面對本發明之第1實施形態進行說明。再者,以下將本發明之纜線應用於在送電線路、配電線路、配線線路等中使用之電力纜線進行說明,但本發明之纜線並不限定於此。本發明之纜線例如亦可應用於電話用纜線、光纖纜線、同軸纜線、海底光纜等通信纜線、或電氣機器配線或電子・通信機器配線之機器用纜線等各種纜線。 (纜線) 如圖1所示,本實施形態之纜線1為圓柱形狀,且具有纜線芯2、與纜線芯2一併設置之液體檢測構件5、及被覆纜線芯2及液體檢測構件5之外覆6。 液體檢測構件5具有:絕緣構件14,其藉由與液體之接觸而發揮導電性;及複數個(本實施形態中為2個)電極構件15a、15b,其等以接觸狀態設置於絕緣構件14之同一面上,且相互電性分離。該液體檢測構件5以藉由滲入至外覆6之內側之液體接觸於絕緣構件14而電極構件15a、15b間之電阻值變化的方式構成。 又,電極構件15a、15b連接於下述之測量裝置7。測量裝置7測量電極構件15a、15b間之電阻值,且基於所測量之電阻值而判別液體檢測構件5之狀態為「滲入狀態」及「非滲入狀態」之哪一者。 此處,「液體」係成為液體檢測構件5之檢測對象之液狀物,只要為液狀物,則並不受材質或物性限定。液狀物意味著具有含浸・積液於絕緣構件14之程度之流動性。作為「液體」之種類,除海水、純水、及含有雜質之水以外,亦可為酸、鹼、油、有機溶劑等有機物。又,「液體」之物性只要為於使用纜線1之環境溫度下液狀化之物質即可。 所謂「非滲入狀態」係絕緣構件14未發揮導電性之狀態。所謂「滲入狀態」係絕緣構件14發揮導電性之狀態。即,「滲入狀態」係如下狀態,即,藉由液體與絕緣構件14接觸而絕緣構件14發揮導電性,電極構件15a、15b間藉由絕緣構件14而電性連接。因此,絕緣構件14之電阻值為「滲入狀態」之情形小於「非滲入狀態」之情形之電阻值。藉此,測量裝置7能夠藉由測量電極構件15a、15b間之電阻值而判別「滲入狀態」及「非滲入狀態」。 再者,於液體檢測構件5之狀態為非滲入狀態之情形時,表示纜線1未產生必須更換或修理之異常。另一方面,於液體檢測構件5之狀態為滲入狀態之情形時,表示纜線1產生必須更換或修理之異常。測量裝置7藉由判別液體檢測構件5之狀態而亦可判別纜線1之上述異常之有無。 (纜線:纜線芯) 其次,對纜線1之各構成要素詳細地進行說明。纜線芯2係配置於外覆6之內側之纜線1之主要部分,且至少包含一個以上之絕緣心線3。該絕緣心線3包含導線3a及絕緣被覆3b,該導線3a包含銅等導體,該絕緣被覆3b被覆導線3a。 以下,作為纜線芯2,以將複數個絕緣心線3絞合而成者為例進行說明,但纜線芯2之構成並不限定於此。例如,纜線芯2亦可為未將複數個絕緣心線3絞合而平行地並列而成者。又,纜線芯2除絕緣心線3以外,亦可包含用以保持複數個絕緣心線3之相互之位置之間隔件等介置於絕緣心線3間之介隔物、或捲繞於絕緣心線3之外周之帶件。 纜線芯2之前端部(開始端或終止端)連接於用以連接纜線芯2與其他電力機器等之連接器8。此時,於纜線芯2之與連接器8連接之前端部,絕緣心線3之導線3a被剝去絕緣被覆3b而露出。又,纜線芯2之前端部及連接器8為了防止來自外部之衝擊等而收納於盒體9。再者,於盒體9形成有能夠供纜線1插通之貫通孔(未圖示),於該貫通孔與纜線1之間設置有用以防止液體向盒體9內滲入之密封材料。 (纜線:外覆) 外覆6係將纜線芯2與液體檢測構件5被覆為液密狀態之圓筒狀之被覆構件(外鞘)。該外覆6係以纜線芯2之機械防護、化學防護、防水等為目的而設置。作為外覆6之素材例如可採用聚氯乙烯組合物、熱塑性聚胺基甲酸酯組合物等各種樹脂材料。 (纜線:液體檢測構件) 液體檢測構件5係作為檢測因外覆6之破損等而滲入至外覆6之內側之液體的液體檢測感測器發揮功能之構件。以下,對液體檢測構件5之各構成要素詳細地進行說明。 (纜線:液體檢測構件:絕緣構件) 絕緣構件14係藉由與液體之接觸而發揮導電性之構件。即,絕緣構件14於未含浸液體之情形時為高電阻值之絕緣狀態,於與液體接觸之情形時藉由較小之電阻值而成為導電狀態。因此,於絕緣構件14中未含浸液體之情形時,電極構件15a、15b成為未相互電性連接之狀態。又,電極構件15a、15b於絕緣構件14與液體接觸之情形時,成為藉由該絕緣構件14而電性連接之狀態。再者,絕緣構件14之「高電阻值」為了於測量裝置7能夠判別「滲入狀態」與「非滲入狀態」而設定為較空氣之電阻值小之電阻值。 絕緣構件14係長條之片狀之構件,且具有可撓性。絕緣構件14藉由與液體之接觸而發揮導電性,並且具有吸收及保持液體之吸液・保持構造。即,絕緣構件14構成為藉由液體之滲透而整體自絕緣性變化為導電性。 絕緣構件14所具備之「吸液・保持構造」只要為滲透作為檢測對象物之液體之構造,則並不受材質或形狀限定。例如,例示不織布構造、具有連續氣泡等之多孔性構造、於無孔性材料形成有1個以上之孔之構造、於無孔性材料形成有1個以上之狹縫之構造。於絕緣構件14為不織布或紙之情形時,即便為微量之液體亦會藉由毛細管現象而滲透於絕緣構件14,從而使絕緣構件14自絕緣狀態變化為導電狀態,因此,可作為較高之檢測精度之液體檢測構件5。 絕緣構件14之材質只要為於與液體非接觸時具有高電阻值之材質則並無特別限定。例如,可於絕緣構件14使用不織布、紙等。 具體而言,作為絕緣構件14之材質例示布(棉、麻等)或紙等植物纖維(纖維素纖維)、化學纖維(嫘縈、銅氨等)、陶瓷、工程塑膠、多孔質素材(海綿等)。作為工程塑膠,可列舉聚丙烯、交聯聚乙烯、聚酯、聚苯并咪唑、芳族聚醯胺、聚醯亞胺、聚醯亞胺醯胺、聚醚醯亞胺、聚苯硫醚(PPS)、聚萘二甲酸乙二酯(PEN)、聚對苯二甲酸乙二酯(PET)等。 更具體而言,可將包含Unitika股份公司製造(註冊商標:MARIX)之聚酯樹脂之不織布用於絕緣構件14。該不織布因接著聚酯纖維之樹脂為水溶性之丙烯酸樹脂,因此具有親水性。再者,上述不織布之製造法為紡黏法。於不織布產品編號為#20507WTD中,單位面積重量為50 g/m2 ,平均厚度為155 μm。於不織布產品編號#20604FLD中,單位面積重量為60 g/m2 ,平均厚度為150 μm。於不織布產品編號#10606WTD中,單位面積重量為60 g/m2 ,平均厚度為215 μm(具有蓬鬆性)。 絕緣構件14之厚度較佳為10~500 μm。又,絕緣構件14較佳為相對於作為檢測對象物之液體具有親液性。例如,若設為檢測對象之液體為水,則較佳為親水性。若為具有親液性之構成,則即便為微量之液體亦會滲透至絕緣構件14內而使絕緣構件14自絕緣狀態變化為導電狀態。因此,即便為微量之液體亦可檢測,並且可縮短至檢測到液體為止之時間。 再者,絕緣構件14可為材質本身具有親液性者,亦可為於疏液性之材質之表面形成有親液性之層者。例如,絕緣構件14亦可於吸液・保持構造之與液體之接觸部分之至少一部分附著有相對於液體具有界面活性之界面活性劑。於此情形時,可藉由根據檢測對象之液體種類區別使用界面活性劑之種類,而形成能夠選擇水、油等檢測對象之液體檢測構件5。 進而,絕緣構件14亦可附著有溶解於液體中而離子化之溶解材料(無機鹽類:氯化鈉、硫酸鈉、氯化鈣、氫氧化鎂等)。於此情形時,即便為液體本身無導電性之液體(純水、油等),藉由該液體而離子化之溶解材料亦可使絕緣構件14變化為導電性。 (纜線:液體檢測構件:電極構件) 如圖2所示,電極構件15a、15b為線狀之形狀,且以接觸狀態設置於絕緣構件14之同一面上。該電極構件15a、15b各自之一端露出至外部,且連接於測量裝置7之下述之連接器構件71a、71b。電極構件15a、15b於絕緣構件14之表面沿著該絕緣構件14之長度方向相互並行地配置。電極構件15a、15b與絕緣構件14可藉由接著而成為接觸狀態,亦可僅藉由抵接而成為接觸狀態。 又,電極構件15a、15b相互隔開特定之間隔而配置。藉此,電極構件15a、15b相互電性分離。所謂特定之間隔係指不會對設置液體檢測構件5之環境之濕度產生反應而錯誤動作之程度之間隔。因此,可並行配置,亦可為梳狀或柵狀等。 且說,電極構件15a、15b間之電阻值依存於該等電極構件15a、15b間之距離。因此,藉由變更電極構件15a、15b間之距離,可變更液體檢測構件5之檢測感度。此處,於本實施形態中,由於線狀之電極構件15a、15b配置於絕緣構件14之同一面上,故而相較於將該等電極構件15a、15b配置於絕緣構件14之厚度方向之情形,可較大地改變電極構件15a、15b間之距離。如此一來,於本實施形態中,由於電極構件15a、15b間之距離之設定之自由度較大,故而可容易地調整液體檢測構件5之檢測感度。 又,電極構件15a、15b只要具有導電性則可為任何材質。例如,作為電極構件15a、15b之材料,可使用鎳、銅、銀、錫、金、鈀、鋁、鉻、鈦、及鋅之任一者或包含其等之2種以上之合金等。其中,較佳為鋁或銅等金屬。 又,作為電極構件15a、15b,可採用利用壓延加工所得之金屬箔、利用電解所得之金屬箔(特殊電解銅箔等),又,亦可採用利用真空蒸鍍、濺鍍、CVD(chemical vapor deposition,化學氣相沈積)法、MO(metal organic,金屬有機)、鍍覆、印刷法等形成之金屬薄膜。又,作為電極構件15a、15b,亦可採用銅漿、銀漿、碳漿等漿材料。 除此以外,電極構件15a、15b亦可設為積層金屬層及導電性接著劑層而成之構成。導電性接著劑層為包含樹脂及導電性粒子之接著劑層。作為樹脂之材料之例,可列舉丙烯酸系樹脂、矽系樹脂、熱塑性彈性體系樹脂、橡膠系樹脂、聚酯系樹脂等。 作為導電性粒子之材料之例,有銅粉、銀粉、鎳粉、塗銀銅粉(Ag coated Cu粉)、塗金銅粉、塗銀鎳粉(Ag coated Ni粉)、塗金鎳粉,該等金屬粉可利用水霧化法、羰化法等製作。又,除上述以外,亦可使用將樹脂被覆於金屬粉之粒子、將金屬粉被覆於樹脂之粒子。再者,導電性粒子較佳為塗銀銅粉、或塗銀鎳粉。其理由在於,可利用便宜之材料獲得導電性提昇之導電性粒子。 (纜線:液體檢測構件之配置態樣) 如上述般構成之液體檢測構件5呈螺旋狀捲繞於纜線芯2之周圍。 且說,於將液體檢測構件5沿纜線1(纜線芯2)之長度方向(延伸方向)平行地配置之情形時,電極構件15a、15b亦與纜線1之長度方向平行。此時,於外覆6破損而液體滲入至外覆6之內側,且該滲入之液體向纜線1之圓周方向擴散之情形時,因液體與電極構件15a、15b間之絕緣構件14接觸而使電極構件15a、15b間之電阻值變化。另一方面,於滲入之液體僅沿纜線1之長度方向擴散之情形時,有可能液體未與電極構件15a、15b間之絕緣構件14接觸而電極構件15a、15b間之電阻值未變化。因此,於將液體檢測構件5沿纜線芯2之長度方向平行地配置之情形時,其檢測精度變低。 相對於此,於如本實施形態般將液體檢測構件5呈螺旋狀捲繞於纜線芯2之情形時,電極構件15a、15b與纜線1之長度方向及圓周方向之任一者均交叉。因此,於滲入至外覆6之內側之液體向纜線1之長度方向及纜線1之圓周方向之任一者擴散之情形時,液體均與電極構件15a、15b間之絕緣構件14接觸,因此,電極構件15a、15b間之電阻值會確實地變化。其結果為,可使液體檢測構件5之檢測精度提昇。 又,若將液體檢測構件5呈螺旋狀捲繞於該纜線芯2,則於如本實施形態般纜線芯2係將複數根絕緣心線3絞合而成之情形時,可使該絞合之絕緣心線3不散開。即,亦可使液體檢測構件5作為壓繞帶件發揮功能。 又,於本實施形態中,捲繞於纜線芯2之液體檢測構件5之捲繞間距以液體檢測構件5之端彼此成為接觸之對接狀態之方式設定。亦即,構成為於將液體檢測構件5捲繞於纜線芯2時,纜線芯2不會露出至外部。 再者,液體檢測構件5之捲繞間距並不限定於此,能以纜線芯2之一部分露出至外部之方式將液體檢測構件5之端相互隔開間隔而捲繞,又,亦能以液體檢測構件5之一部分相互重疊之方式捲繞。又,亦可於纜線芯2之長度方向上之各部位使其捲繞間距彼此不同。又,亦可構成為於纜線1僅於欲提高檢測精度之部位利用液體檢測構件5呈螺旋狀捲繞於纜線芯2之全周,對於其他部位,將液體檢測構件5與纜線芯2之長度方向平行地配置。 如上所述,於本實施形態中,液體檢測構件5具有片狀之外形,藉此,可根據纜線1之用途或構造、設置場所等而選擇性地採用各種液體檢測構件5之一併設置方法。 再者,於本實施形態中,以於絕緣構件14形成有電極構件15a、15b之面成為纜線1之直徑外側之方式配置,但亦能以成為纜線1之直徑內側之方式配置。 (纜線之製造方法) 本實施形態之纜線1可利用先前之各種製造方法製造,以下,對其一例簡單地進行說明。 首先,藉由將包含樹脂組合物之絕緣體擠出覆膜至包含銅等之導體上而製作絕緣心線3。其次,藉由將複數根該絕緣心線3絞合而形成纜線芯2。 然後,使用公知之帶件捲繞機構,一方面使纜線芯2沿其長度方向移行,一方面將液體檢測構件5作為壓繞帶件一面於纜線芯2之圓周方向旋轉一面連續地供給至纜線芯2之外周面上,藉此,將液體檢測構件5呈螺旋狀捲繞於纜線芯2之全周。又,此時,可藉由於液體檢測構件5之外周面擠出成形包含樹脂組合物之外覆6(外鞘)而製造纜線1。 (測量裝置) 其次,對連接於液體檢測構件5之電極構件15a、15b之測量裝置7進行說明。如之前稍微涉及般,測量裝置7係如下裝置,即,用於測量液體檢測構件5中之電極構件15a、15b間之電阻值,並基於其測量結果而判別液體檢測構件5之狀態(非滲入狀態、及滲入狀態)。 (測量裝置之電性構成) 如圖3所示,測量裝置7具備連接器構件71a、71b、電阻值測量電路72、A/D(analog to digital,類比數位)轉換電路73、運算電路74、ROM(read only memory,唯讀記憶體)75、RAM(Random Access Memory,隨機存取記憶體)76、通信介面77、及電源電路78。 連接器構件71a、71b分別與液體檢測構件5之電極構件15a、15b之各者連接。電阻值測量電路72藉由來自電源電路78之電力供給而經由連接器構件71a、71b對電極構件15a、15b間施加特定之電壓。然後,電阻值測量電路72藉由電流計(未圖示)測量於電極構件15a、15b間流通之電流,並基於該電流及施加之電壓而算出電極構件15a、15b間之電阻值。電阻值測量電路72將該算出之電阻值以類比信號之形式輸出至A/D轉換電路73。A/D轉換電路73將自電阻值測量電路72輸出之類比信號轉換為數位信號並輸出至運算電路74。 運算電路74藉由來自電源電路78之電力供給而執行各種程式,並且控制各種致動器之動作。例如,運算電路74藉由執行儲存於ROM(Read Only Memory,唯讀記憶體)75或RAM(Random Access Memory,隨機存取記憶體)76等記憶機構之滲入判別程式,而基於自A/D轉換電路73輸出之表示電極構件15a、15b間之電阻值之數位信號而判別液體檢測構件5之狀態。具體而言,於ROM75或RAM76等預先記憶有特定之閾值。而且,運算電路74於電極構件15a、15b間之電阻值未達閾值之情形時,判別液體檢測構件5為「非滲入狀態」且纜線1未產生異常。另一方面,運算電路74於電極構件15a、15b間之電阻值為閾值以上之情形時,判別液體檢測構件5為「滲入狀態」,且纜線1產生異常而必須進行纜線1之更換・修理等。 又,運算電路74能夠經由通信介面77而將表示纜線1之異常之有無之異常資訊向外部輸出。即,通信介面77係至少能夠資料發送異常資訊之介面。具體而言,運算電路74經由通信介面77而將固有之ID(Identification,識別)資訊與異常資訊一同資料發送。所謂固有之ID資訊係用以個別地識別測量裝置7之資訊。於本實施形態中,測量裝置7將異常資訊向未圖示之監視裝置發送。藉此,監視裝置例如能夠進行異常時之自動應對(例如,自動停止經由纜線芯2之導線3a之電力送電)等。如此一來,可基於ID資訊而特定出資料發送源之測量裝置7。因此,可特定出產生異常之纜線1,因此,只要使ID資訊與設置場所對應即可自遠方監視複數個纜線1。再者,於本實施形態中,如上所述,藉由無線通信而將判別資訊信號向外部輸出,但亦可於測量裝置7進而設置有線用之外部接點輸出作為終端側通信部。藉此,終端側通信部以無線、有線之任一者均可應對。 作為變化例,亦可構成為測量裝置7具有揚聲器或顯示器等報告機構,且能夠藉由該報告機構而對處於測量裝置7之附近之使用者報告纜線1之異常資訊。 以上,根據本實施形態,於外覆6未破損而液體未滲入至外覆6之內側之情形時,絕緣構件14成為未發揮導電性之狀態。其結果為,電極構件15a、15b間之電阻值成為高電阻值,測量裝置7可判別液體檢測構件5之狀態為「非滲入狀態」,且纜線1未產生異常。另一方面,若外覆6破損而液體滲入至外覆6之內側,則絕緣構件14成為發揮導電性之狀態。其結果,電極構件15a、15b間之電阻值成為較小之電阻值,測量裝置7可判別液體檢測構件5之狀態為「滲入狀態」,且纜線1產生異常。如上所述,能夠藉由檢測電極構件15a、15b間之電阻值之較大之變化而以較高之可靠性檢測由外覆6之破損所致之滲水。 (第2實施形態) 其次,對第2實施形態之液體檢測構件進行說明。於第2實施形態中,與第1實施形態不同之方面為液體檢測構件具有保護層之方面。以下,對與上述第1實施形態相同之部位附註相同之符號並適當省略其說明。 如之前所涉及般,於絕緣心線3(纜線芯2)之前端部,自導線3a將絕緣被覆3b剝離而露出導線3a。因此,若液體與該露出之導線3a接觸,則於纜線芯2之複數個導線3a間產生短路,而成為產生重大故障之原因。如上所述,由於纜線芯2之前端部收納於盒體9中,故而通常液體不會與纜線芯2之前端部接觸。然而,因處於盒體9外之外覆6之破損而滲入之液體有可能會沿著纜線芯2之長度方向於外覆6之內側移動而到達至纜線芯2之前端部。除此以外,雖然於盒體9與纜線1之間設置有密封材料,但於該密封材料存在異常之情形時,液體可能會滲入至盒體9內並到達至纜線芯2之前端部。因此,纜線1之前端部係會因滲水而產生重大之部位,且係必須以亦能夠檢測微量之滲水之方式監視之監視部位。 另一方面,於纜線1之中央部,由於在導線3a被覆有絕緣被覆3b,故而即便微量之液體滲入至外覆6之內側,亦不會產生重大之故障,而可繼續使用纜線1。此處,若使該纜線1之中央部之液體檢測構件5之檢測感度為與纜線1之前端部同樣之檢測感度,則即便於纜線1尚可繼續使用之情形時,測量裝置7亦判別纜線1中產生異常。其結果,有可能會進行不必要之纜線1之更換或修理。 因此,如圖4及圖5所示,本實施形態之液體檢測構件50除具有絕緣構件14、及電極構件15a、15b以外,亦具有2個保護層20、30。保護層20可剝離地將絕緣構件14之形成有電極構件15a、15b之形成面、及電極構件15a、15b被覆為液密狀態。保護層30可剝離地將絕緣構件14之與上述形成面為相反側之面被覆為液密狀態。 保護層20、30係用以阻止滲入至外覆6之內側之液體前進至絕緣構件14之層。於本實施形態中,保護層20、30係包含PET(polyethylene terephthalate,聚對苯二甲酸乙二酯)等樹脂之無孔性材料。因此,保護層20、30之滲透性較絕緣構件14更低。又,保護層20、30藉由接著劑、熱壓接或熱熔接等而相對於絕緣構件14可剝離地接著。 而且,如圖5所示,於因纜線1之前端部等之滲水而產生重大之故障之監視部位,將保護層20、30自絕緣構件14剝離。藉此,可使液體檢測構件50之監視部位之液體之檢測感度提高。 另一方面,對於纜線1之中央部等除監視部位以外之監視外部位,設為不將保護層20、30剝離而直接被覆絕緣構件14或電極構件15a、15b之狀態。藉此,對於監視外部位,即便液體滲入至外覆6之內側,只要保護層20、30正常地存在,則絕緣構件14不會因液體之接觸而發揮導電性。藉此,可降低液體檢測構件50之監視外部位之液體之檢測感度。 如上所述,藉由於纜線1之監視部位及監視外部位使滲入至外覆6之內側之液體之檢測感度不同,可抑制進行不必要之纜線1之更換或修理。 再者,於纜線1中,若事先知道會因滲水而產生重大故障之監視部位之位置、必需之液體檢測構件50之長度、液體檢測構件50之配置態樣(捲繞方法等),則於液體檢測構件50之製造過程中,亦可僅於與監視外部位對應之絕緣構件14之部分被覆保護層20、30。然而,實際上,根據纜線1之設置場所或設置方法,監視部位有可能不同。例如,存在根據纜線1之設置場所或設置方法而必須監視纜線1之中央部分之情形。又,根據捲繞液體檢測構件50之纜線芯2之芯徑、或捲繞間距等,必需之液體檢測構件50之長度亦不同。因此,於液體檢測構件50中,難以事先把握與監視部位對應之部位。除此以外,於液體檢測構件50之製造過程中,於僅於絕緣構件14之一部分被覆有保護層20、30之情形時,使用態樣會受到限定。因此,於本實施形態中,於液體檢測構件50之製造過程中,將保護層20、30可剝離地被覆於絕緣構件14之整個面。而且,構成為根據纜線芯2之使用態樣,其後僅於與監視部位對應之部分將保護層20、30剝離。 (保護層之剝離強度) 且說,若為了使保護層20、30容易自絕緣構件14剝離而使保護層20、30之剝離強度遍及整個面均勻同樣地變小,則液體檢測構件50成為相對於來自外部之負載較弱者。因此,於監視外部位,保護層20、30可能會意外地自絕緣構件14剝離,因此,纜線1之可靠性降低。 又,若為了使液體檢測構件50成為相對於來自外部之負載為強而使保護層20、30之剝離強度遍及整個面均勻同樣地變大,則於監視部位難以將保護層20、30自絕緣構件14剝離。 因此,於本實施形態中,如圖6所示,將絕緣構件14之整個區域區分為電極構件15a、15b間之內側區域、電極構件15a、15b之配置區域、及除該等區域以外之外側區域。而且,以使保護層20、30相對於絕緣構件14之剝離強度為內側區域小於外側區域之方式構成。 例如,於利用接著劑將保護層20、30相對於絕緣構件14接著之情形時,於外側區域採用接著強度較強之材質之接著劑,於內側區域採用接著強度較弱之材質之接著劑。於利用熱壓接將保護層20、30相對於絕緣構件14壓接之情形時,例如,於絕緣構件14之外側區域,遍及長度方向之全域壓接保護層20、30,另一方面,於絕緣構件14之內側區域,於長度方向隔開特定間隔而壓接保護層20、30。又,於利用熱熔接將保護層20、30相對於絕緣構件14熔接之情形時,例如,於絕緣構件14之外側區域增高加熱溫度而將保護層20、30熔接,於絕緣構件14之內側區域降低加熱溫度而將保護層20、30熔接。於以上任一方法中,均可使保護層20、30相對於絕緣構件14之剝離強度為內側區域小於外側區域。再者,亦可構成為藉由上述以外之方法使保護層20、30相對於絕緣構件14之剝離強度為內側區域小於外側區域。 藉由以上構成,液體檢測構件50之絕緣構件14之外側區域相較於內側區域而保護層20、30更難以剝離,因此,液體檢測構件50相對於來自外部之負載較強,從而可提高纜線1之可靠性。 又,於監視部位,於進行將保護層20、30自絕緣構件14剝離而使絕緣構件14露出至外部之剝離作業時,首先,進行利用輔具切除絕緣構件14之外側區域、及保護層20之與該外側區域對應之部位之切除作業。藉此,於監視部位,僅殘留以較小之剝離強度被覆於內側區域之保護層20、30。其結果,可容易地將該監視部位之保護層20、30剝離。除此以外,保護層20、30之利用輔具切除之部位與絕緣構件14之內側區域不同,係被覆於外側區域之保護層,因此,容易確保作業空間,從而可容易地進行作業。 再者,於上述切除作業中,亦可不切除絕緣構件14而僅切除保護層20、30。又,亦可僅切除2個保護層20、30中之任一保護層。又,亦可將絕緣構件14之外側區域進而區分為電極構件15a、15b側之內區域、及與電極構件15a、15b為相反側之外區域,將保護層20、30之剝離強度構成為內區域小於該外區域。於此情形時,於上述切除作業中,即便未於絕緣構件14之外側區域與配置區域之交界進行切除,藉由將外側區域之內區域切除,亦可容易地進行該切除作業後之保護層20、30之自絕緣構件14之剝離。 以上,於保護層20、30中,即便被覆於絕緣構件14之內側區域之部位之剝離強度相當小,例如,即便為可用手作業而剝離之程度之剝離強度,由於被覆於絕緣構件14之外側區域之部位之剝離強度較大,故而亦可維持液體檢測構件50相對於機械負載之強度,並且容易地進行剝離之作業。 (第2實施形態之液體檢測構件之變化例) 以下,對第2實施形態之液體檢測構件之變化例進行說明。於圖7所示之液體檢測構件150中,被覆絕緣構件14之兩面之保護層120、130之寬度大於絕緣構件14之寬度。而且,該等保護層120、130之寬度方向之兩端彼此相互接著。藉此,絕緣構件14及電極構件15a、15b藉由保護層120、130而覆蓋全周。其結果,即便液體滲入至外覆6之內側,只要該等保護層120、130正常地存在,則可更確實地降低絕緣構件14因液體接觸而發揮導電性之可能性。其結果,可提昇纜線1之可靠性。 又,作為另一變化例,於圖8所示之液體檢測構件250中,僅絕緣構件214之形成有電極構件15a、15b之單面被覆有保護層220。如此一來,即便於僅於絕緣構件214之單面被覆有保護層220之情形時,亦可藉由使將液體檢測構件250以對接狀態捲繞於纜線芯2等之配置態樣最佳化而抑制液體向絕緣構件214之前進。 保護層220具有片狀之保護片220a、及將保護片220a接著於絕緣構件214之接著層220b。於本實施形態中,保護片220a係包含PET等樹脂之無孔性之片,滲透性較絕緣構件214更低。接著層220b由丙烯酸系樹脂、矽系樹脂、熱塑性彈性體系樹脂、橡膠系樹脂、聚酯系樹脂等樹脂材料構成。 又,於絕緣構件214中,外側區域之表面214a形成為凹凸狀。藉此,外側區域之表面214a相較於內側區域之表面214b而每單位面積之表面積更大。其結果,絕緣構件214之相對於接著層220b之每單位面積之接觸面積為內側區域小於外側區域。藉此,即便不改變相對絕緣構件214之內側區域之接著劑之材質、及相對外側區域之接著劑之材質,而以相同材質之接著劑形成接著層220b整體,於保護層220中,亦可使被覆於絕緣構件214之外側區域之部位較被覆於內側區域之部位而剝離強度更高。 (其他變化例) 於上述實施形態中,絕緣構件14、214形成為片狀,但並不特別限定於此。例如,如圖9所示之液體檢測構件350般,亦可為形成為圓筒狀之絕緣構件314。於此情形時,電極構件15a、15b亦可沿著絕緣構件314之圓柱軸平行地配置。又,亦可構成為如圖10所示之液體檢測構件450般,電極構件15a、15b呈螺旋狀捲繞於絕緣構件314之周圍。 又,於上述實施形態中,相對纜線芯設置有1個液體檢測構件,但亦可針對纜線芯之每一絕緣心線而設置液體檢測構件。又,於上述實施形態中,構成為使保護層20、30相對於絕緣構件14之剝離強度為內側區域小於外側區域,但亦可遍及絕緣構件14之整個面使剝離強度均勻。 又,如圖11及圖12所示,纜線芯2之前端部亦可連接於防水連接器。以下,對纜線芯2之前端部連接於防水連接器之母連接器500之構成進行說明。再者,該母連接器500能夠連接於成對之公連接器550(參照圖13)。 母連接器500具有包含橡膠或彈性體之殼體501。該殼體501於纜線1之前端部藉由模鑄成形而一體形成於該纜線1上。如圖12所示,殼體501具有外殼本體501a、及收容部501b。於外殼本體501a內插入有纜線芯2之複數條絕緣心線3。又,於外殼本體501a之前端部形成有與公連接器550之下述之抵接面551c密接(抵接)的大致矩形狀之抵接面501c。於該抵接面501c上突出配設有與絕緣心線3之個數對應之複數個端子502。該等複數個端子502於抵接面501c上構成2行端子行。端子502各自於外殼本體501a內與絕緣心線3之導線3a電性連接。收容部501b連接於外殼本體501a之抵接面501c之周緣,且能夠收容公連接器550之下述被收容部551b。 如圖13所示,公連接器550具有包含橡膠或彈性體之殼體551。殼體551具有外殼本體551a及被收容部551b。於外殼本體551a內配置有複數條導線(未圖示)。被收容部551b連接於外殼本體551a之前端部,於母連接器500與公連接器550連接時,收容於母連接器500之收容部501b。於該被收容部551b之前端部形成有抵接於母連接器500之抵接面501c的大致矩形狀之抵接面551c。而且,於該抵接面551c形成有供母端子502插入之複數個接觸孔552。該接觸孔552於抵接面551c上排列成2行。於接觸孔552各者配置有與母連接器500之端子502電性連接之端子(未圖示)、及連接於該端子之上述導線。 藉由以上構成,若將母連接器500與公連接器550連接,則母連接器500之端子502與公連接器550之端子電性連接。又,此時,公連接器550之被收容部551b收容於母連接器500之收容部501b,且抵接面501c與抵接面551c密接。藉此,防止液體滲入至母連接器500與公連接器550之間。再者,亦可構成為遍及被收容部551b之全周而設置密封材料,於與母連接器500連接時,藉由該密封材料而將被收容部551b與收容部501b之間密封。 又,上述中,連接纜線1之母連接器500、及連接該母連接器500之公連接器550分別為將端子配置為2行之種類之連接器,但並不限定於該種。例如,亦可為圖14及圖15所示之防水連接器之類型。具體而言,母連接器600之殼體601、及公連接器650之殼體651分別為大致圓筒之形狀。如圖14所示,母連接器600之殼體601具有外殼本體601a、及收容部601b。外殼本體601a之抵接面601c為大致圓狀之形狀,複數個端子602配置為以抵接面601c之圓心為中心之4次旋轉對稱。如圖15所示,公連接器650之殼體651具有外殼本體651a、及被收容部651b。被收容部651b之抵接面651c形成大致圓狀之形狀,複數個接觸孔652配置為以抵接面651c之圓心為中心之4次旋轉對稱。又,構成為於母連接器600與公連接器650連接時,抵接面601c與抵接面651c密接,並且收容部601b之前端與外殼本體651a之前端密接。又,構成為於該外殼本體651a之前端設置有襯墊材653,藉由該襯墊材653而將外殼本體651a與收容部601b之間密封。於以上構成中,亦防止液體滲入至母連接器600與公連接器650之間。 又,作為另一變化例,於將纜線1用作電氣機器配線用之纜線之情形時,如圖16所示,於纜線1之前端部,絕緣心線3之導線3a亦可相對於照明機器等電氣機器700直接連接。 於以上之詳細之說明中,為了使本發明更容易理解而以特徵性之部分為中心進行了說明,但本發明並不限定於以上之詳細之說明中記載之實施形態,亦可應用於其他實施形態,其適用範圍應儘可能地廣地解釋。 又,於本說明書中使用之用語及語法係為了準確地說明本發明而使用者,並非為用以限制本發明之解釋而使用者。又,認為若為業者則容易自本說明書中記載之發明之概念推測出本發明之概念所包含之其他構成、系統、方法等。因此,申請專利範圍之記載應看作於不脫離本發明之技術性思想之範圍內包含均等之構成者。又,為了充分地理解本發明之目的及本發明之效果,較理想的是充分參酌已揭示之文獻等。(First embodiment) Hereinafter, a first embodiment of the present invention will be described with reference to the drawings. In the following, the cable of the present invention will be described below for use in a power cable used for a power transmission line, a power distribution line, a wiring line, etc., but the cable of the present invention is not limited thereto. The cable of the present invention can be applied to, for example, various types of cables such as a telephone cable, an optical fiber cable, a coaxial cable, a submarine cable, and the like, or an electrical device wiring or a cable for an electronic/communication device wiring. (Cable) As shown in Fig. 1, the cable 1 of the present embodiment has a cylindrical shape, and has a cable core 2, a liquid detecting member 5 provided together with the cable core 2, and a coated cable core 2 and a liquid. The detecting member 5 is covered 6 . The liquid detecting member 5 has an insulating member 14 which exhibits conductivity by contact with a liquid, and a plurality of (two in the present embodiment) electrode members 15a and 15b which are provided in a contact state to the insulating member 14 On the same side, and electrically separated from each other. The liquid detecting member 5 is configured such that the liquid that has penetrated into the inner side of the outer cover 6 contacts the insulating member 14 and the resistance value between the electrode members 15a and 15b changes. Further, the electrode members 15a and 15b are connected to the measuring device 7 described below. The measuring device 7 measures the resistance value between the electrode members 15a and 15b, and determines which of the "infiltration state" and the "non-infiltration state" the state of the liquid detecting member 5 is based on the measured resistance value. Here, the "liquid" is a liquid material to be detected by the liquid detecting member 5, and is not limited to the material or physical properties as long as it is a liquid material. The liquid material means fluidity to the extent that the liquid or the liquid is impregnated into the insulating member 14. As the type of "liquid", in addition to seawater, pure water, and water containing impurities, it may be an organic substance such as an acid, a base, an oil, or an organic solvent. Further, the physical properties of the "liquid" may be those which are liquidified at the ambient temperature of the cable 1. The "non-infiltration state" is a state in which the insulating member 14 does not exhibit conductivity. The "infiltration state" is a state in which the insulating member 14 exhibits conductivity. In other words, the "infiltration state" is a state in which the insulating member 14 is electrically connected to the insulating member 14 by the liquid, and the electrode members 15a and 15b are electrically connected to each other by the insulating member 14. Therefore, the resistance value of the insulating member 14 is "infiltration state" and the resistance value is smaller than that in the case of "non-infiltration state". Thereby, the measuring device 7 can determine the "infiltration state" and the "non-infiltration state" by measuring the resistance value between the electrode members 15a and 15b. Further, when the state of the liquid detecting member 5 is a non-infiltrated state, it indicates that the cable 1 does not have an abnormality that must be replaced or repaired. On the other hand, when the state of the liquid detecting member 5 is the infiltrated state, it indicates that the cable 1 has an abnormality that must be replaced or repaired. The measuring device 7 can also determine the presence or absence of the abnormality of the cable 1 by discriminating the state of the liquid detecting member 5. (Cable: Cable Core) Next, each component of the cable 1 will be described in detail. The cable core 2 is a main portion of the cable 1 disposed inside the outer cover 6, and includes at least one insulating core wire 3. The insulating core wire 3 includes a wire 3a and an insulating coating 3b. The wire 3a includes a conductor such as copper, and the insulating coating 3b covers the wire 3a. Hereinafter, the cable core 2 will be described as an example in which a plurality of insulating core wires 3 are twisted, but the configuration of the cable core 2 is not limited thereto. For example, the cable core 2 may be formed by paralleling a plurality of insulating core wires 3 in parallel. Further, the cable core 2 may include a spacer interposed between the insulating core wires 3 such as a spacer for holding the mutual positions of the plurality of insulating core wires 3, or may be wound around the insulating core wire 3. The outer circumference of the insulating core wire 3 is a piece. The front end (starting end or terminating end) of the cable core 2 is connected to a connector 8 for connecting the cable core 2 to other electric machines and the like. At this time, at the end before the connection of the cable core 2 to the connector 8, the wire 3a of the insulating core wire 3 is exposed by peeling off the insulating coating 3b. Moreover, the front end portion of the cable core 2 and the connector 8 are housed in the casing 9 in order to prevent an impact or the like from the outside. Further, a through hole (not shown) through which the cable 1 can be inserted is formed in the casing 9, and a sealing material for preventing penetration of liquid into the casing 9 is provided between the through hole and the cable 1. (Cable: Overlay) The outer covering 6 is a cylindrical covering member (outer sheath) in which the cable core 2 and the liquid detecting member 5 are covered in a liquid-tight state. The outer cover 6 is provided for the purpose of mechanical protection, chemical protection, waterproofing, etc. of the cable core 2. As the material of the overcoat 6, for example, various resin materials such as a polyvinyl chloride composition and a thermoplastic polyurethane composition can be used. (Cable: Liquid Detection Member) The liquid detection member 5 functions as a liquid detecting sensor that detects a liquid that has penetrated into the inside of the outer cover 6 due to breakage of the outer cover 6 or the like. Hereinafter, each constituent element of the liquid detecting member 5 will be described in detail. (Cable: Liquid detecting member: insulating member) The insulating member 14 is a member that exhibits electrical conductivity by contact with a liquid. That is, the insulating member 14 is in an insulated state of high resistance value when it is not impregnated with a liquid, and becomes a conductive state by a small resistance value in the case of contact with a liquid. Therefore, when the liquid is not impregnated in the insulating member 14, the electrode members 15a and 15b are not electrically connected to each other. Further, when the insulating member 14 is in contact with the liquid, the electrode members 15a and 15b are electrically connected to each other by the insulating member 14. In addition, the "high resistance value" of the insulating member 14 is set to a resistance value smaller than the resistance value of the air in order to determine the "infiltration state" and the "non-infiltration state" in the measuring device 7. The insulating member 14 is a long sheet-like member and has flexibility. The insulating member 14 exhibits conductivity by contact with a liquid, and has a liquid absorption/holding structure for absorbing and retaining liquid. That is, the insulating member 14 is configured to change from the insulating property to the electrical conductivity by the penetration of the liquid. The "liquid absorption/holding structure" provided in the insulating member 14 is not limited to the material or shape as long as it is a structure that permeates the liquid as the object to be detected. For example, a non-woven structure, a porous structure having continuous bubbles, a structure in which one or more holes are formed in a non-porous material, and a structure in which one or more slits are formed in a non-porous material are exemplified. When the insulating member 14 is non-woven or paper, even a small amount of liquid permeates the insulating member 14 by capillary action, so that the insulating member 14 changes from an insulating state to a conductive state, and thus can be regarded as a higher one. The liquid detecting member 5 of the detection accuracy. The material of the insulating member 14 is not particularly limited as long as it has a high resistance value when it is not in contact with a liquid. For example, non-woven fabric, paper, or the like can be used for the insulating member 14. Specifically, examples of the material of the insulating member 14 are plant fibers (cotton, hemp, etc.) or plant fibers (cellulose fibers) such as paper, chemical fibers (嫘萦, copper ammonia, etc.), ceramics, engineering plastics, and porous materials (sponges). Wait). Examples of engineering plastics include polypropylene, crosslinked polyethylene, polyester, polybenzimidazole, aromatic polyamine, polyimine, polyamidamine, polyetherimide, and polyphenylene sulfide. (PPS), polyethylene naphthalate (PEN), polyethylene terephthalate (PET), and the like. More specifically, a nonwoven fabric comprising a polyester resin manufactured by Unitika Co., Ltd. (registered trademark: MARIX) can be used for the insulating member 14. This non-woven fabric is hydrophilic because the resin of the polyester fiber is a water-soluble acrylic resin. Furthermore, the manufacturing method of the above non-woven fabric is a spunbonding method. In the non-woven product number #20507WTD, the weight per unit area is 50 g/m. 2 The average thickness is 155 μm. In non-woven product number #20604FLD, the weight per unit area is 60 g/m. 2 The average thickness is 150 μm. In the non-woven product number #10606WTD, the weight per unit area is 60 g/m. 2 The average thickness is 215 μm (with bulkiness). The thickness of the insulating member 14 is preferably from 10 to 500 μm. Further, the insulating member 14 is preferably lyophilic with respect to the liquid as the object to be detected. For example, if the liquid to be detected is water, it is preferably hydrophilic. In the case of a lyophilic structure, even a small amount of liquid permeates into the insulating member 14 to change the insulating member 14 from an insulating state to a conductive state. Therefore, even a small amount of liquid can be detected and can be shortened until the time when the liquid is detected. Further, the insulating member 14 may have a lyophilic property as the material itself, or may be a layer having a lyophilic layer formed on the surface of the lyophobic material. For example, the insulating member 14 may have a surfactant having interface activity with respect to the liquid at least a part of the contact portion with the liquid in the liquid absorption/holding structure. In this case, the liquid detecting member 5 capable of selecting a detection target such as water or oil can be formed by distinguishing the type of the surfactant from the type of the liquid to be detected. Further, the insulating member 14 may have a dissolved material (inorganic salt: sodium chloride, sodium sulfate, calcium chloride, magnesium hydroxide, or the like) which is dissolved in a liquid and ionized. In this case, even if the liquid itself has no conductivity (pure water, oil, etc.), the dissolved material ionized by the liquid can change the insulating member 14 to conductivity. (Cable: Liquid Detection Member: Electrode Member) As shown in FIG. 2, the electrode members 15a and 15b have a linear shape and are provided on the same surface of the insulating member 14 in a contact state. One end of each of the electrode members 15a, 15b is exposed to the outside, and is connected to the following connector members 71a, 71b of the measuring device 7. The electrode members 15a and 15b are arranged in parallel with each other along the longitudinal direction of the insulating member 14 on the surface of the insulating member 14. The electrode members 15a and 15b and the insulating member 14 can be brought into contact with each other, or can be brought into contact only by abutting. Further, the electrode members 15a and 15b are arranged at a predetermined interval from each other. Thereby, the electrode members 15a and 15b are electrically separated from each other. The specific interval means an interval that does not cause a malfunction in response to the humidity of the environment in which the liquid detecting member 5 is provided. Therefore, it can be arranged in parallel, and can also be a comb shape or a grid shape. Further, the resistance value between the electrode members 15a and 15b depends on the distance between the electrode members 15a and 15b. Therefore, the detection sensitivity of the liquid detecting member 5 can be changed by changing the distance between the electrode members 15a and 15b. Here, in the present embodiment, since the linear electrode members 15a and 15b are disposed on the same surface of the insulating member 14, the electrode members 15a and 15b are disposed in the thickness direction of the insulating member 14 as compared with the case where the electrode members 15a and 15b are disposed on the same surface of the insulating member 14. The distance between the electrode members 15a, 15b can be largely changed. As described above, in the present embodiment, since the degree of freedom in setting the distance between the electrode members 15a and 15b is large, the detection sensitivity of the liquid detecting member 5 can be easily adjusted. Further, the electrode members 15a and 15b may be of any material as long as they have conductivity. For example, as the material of the electrode members 15a and 15b, any one of nickel, copper, silver, tin, gold, palladium, aluminum, chromium, titanium, and zinc, or an alloy containing two or more thereof may be used. Among them, a metal such as aluminum or copper is preferred. Further, as the electrode members 15a and 15b, a metal foil obtained by calendering, a metal foil obtained by electrolysis (special electrolytic copper foil, etc.) may be used, or vacuum deposition, sputtering, or CVD may be employed. Metal film formed by deposition, chemical vapor deposition, MO (metal organic), plating, printing, and the like. Further, as the electrode members 15a and 15b, a slurry material such as copper paste, silver paste or carbon paste may be used. In addition, the electrode members 15a and 15b may be formed by laminating a metal layer and a conductive adhesive layer. The conductive adhesive layer is an adhesive layer containing a resin and conductive particles. Examples of the material of the resin include an acrylic resin, a fluorene resin, a thermoplastic elastomer resin, a rubber resin, and a polyester resin. Examples of the material of the conductive particles include copper powder, silver powder, nickel powder, silver coated copper powder (Ag coated Cu powder), gold coated copper powder, silver coated nickel powder (Ag coated Ni powder), and gold coated nickel powder. The metal powder can be produced by a water atomization method or a carbonylation method. Further, in addition to the above, particles in which the resin is coated on the metal powder and the metal powder is coated on the resin may be used. Further, the conductive particles are preferably silver-coated copper powder or silver-coated nickel powder. The reason for this is that conductive particles having improved conductivity can be obtained by using an inexpensive material. (Cable: Arrangement of Liquid Detection Member) The liquid detecting member 5 configured as described above is spirally wound around the cable core 2. In other words, when the liquid detecting members 5 are arranged in parallel along the longitudinal direction (extension direction) of the cable 1 (cable core 2), the electrode members 15a and 15b are also parallel to the longitudinal direction of the cable 1. At this time, when the outer cover 6 is broken and the liquid infiltrates into the inner side of the outer cover 6, and the infiltrated liquid is diffused in the circumferential direction of the cable 1, the liquid is in contact with the insulating member 14 between the electrode members 15a and 15b. The resistance value between the electrode members 15a and 15b is changed. On the other hand, when the infiltrated liquid diffuses only in the longitudinal direction of the cable 1, there is a possibility that the liquid does not contact the insulating member 14 between the electrode members 15a and 15b, and the resistance value between the electrode members 15a and 15b does not change. Therefore, when the liquid detecting members 5 are arranged in parallel along the longitudinal direction of the cable core 2, the detection accuracy thereof is lowered. On the other hand, when the liquid detecting member 5 is spirally wound around the cable core 2 as in the present embodiment, the electrode members 15a and 15b cross each other in the longitudinal direction and the circumferential direction of the cable 1. . Therefore, when the liquid that has penetrated into the inner side of the outer cover 6 is diffused in the longitudinal direction of the cable 1 and the circumferential direction of the cable 1, the liquid is in contact with the insulating member 14 between the electrode members 15a and 15b. Therefore, the resistance value between the electrode members 15a and 15b is surely changed. As a result, the detection accuracy of the liquid detecting member 5 can be improved. When the liquid detecting member 5 is spirally wound around the cable core 2, the cable core 2 is formed by twisting a plurality of insulating core wires 3 as in the present embodiment. The stranded insulating core wire 3 does not spread. That is, the liquid detecting member 5 can also function as a crimping tape. Moreover, in the present embodiment, the winding pitch of the liquid detecting member 5 wound around the cable core 2 is set such that the ends of the liquid detecting members 5 are brought into contact with each other. That is, when the liquid detecting member 5 is wound around the cable core 2, the cable core 2 is not exposed to the outside. Further, the winding pitch of the liquid detecting member 5 is not limited thereto, and the ends of the liquid detecting members 5 may be wound at intervals from each other such that one of the cable cores 2 is exposed to the outside, and One of the liquid detecting members 5 is wound in such a manner as to overlap each other. Further, the winding pitches may be different from each other in the longitudinal direction of the cable core 2. Further, the cable 1 may be spirally wound around the entire circumference of the cable core 2 by the liquid detecting member 5 at a portion where the cable 1 is to be improved in accuracy, and the liquid detecting member 5 and the cable core may be used for other portions. The length direction of 2 is arranged in parallel. As described above, in the present embodiment, the liquid detecting member 5 has a sheet-like outer shape, whereby one of the various liquid detecting members 5 can be selectively used depending on the use, configuration, installation place, and the like of the cable 1. method. In the present embodiment, the surface of the insulating member 14 on which the electrode members 15a and 15b are formed is disposed outside the diameter of the cable 1, but it may be disposed so as to be inside the diameter of the cable 1. (Manufacturing Method of Cable) The cable 1 of the present embodiment can be manufactured by various conventional manufacturing methods, and an example thereof will be briefly described below. First, the insulating core wire 3 is produced by extruding a film including an insulator of a resin composition onto a conductor containing copper or the like. Next, the cable core 2 is formed by twisting a plurality of the insulating core wires 3. Then, using the known tape winding mechanism, the cable core 2 is moved along the longitudinal direction thereof, and the liquid detecting member 5 is continuously supplied as a crimping tape member while rotating in the circumferential direction of the cable core 2. The liquid detecting member 5 is spirally wound around the entire circumference of the cable core 2 to the outer peripheral surface of the cable core 2. Moreover, at this time, the cable 1 can be manufactured by extrusion-molding the outer surface of the liquid detecting member 5 including the resin composition cover 6 (outer sheath). (Measuring Device) Next, the measuring device 7 connected to the electrode members 15a and 15b of the liquid detecting member 5 will be described. As described slightly above, the measuring device 7 is a device for measuring the resistance value between the electrode members 15a, 15b in the liquid detecting member 5, and discriminates the state of the liquid detecting member 5 based on the measurement result thereof (non-infiltration) State, and infiltration state). (Electrical Configuration of Measuring Device) As shown in FIG. 3, the measuring device 7 includes connector members 71a and 71b, a resistance value measuring circuit 72, an A/D (analog to digital) conversion circuit 73, an arithmetic circuit 74, and A ROM (read only memory) 75, a RAM (Random Access Memory) 76, a communication interface 77, and a power supply circuit 78. The connector members 71a and 71b are respectively connected to each of the electrode members 15a and 15b of the liquid detecting member 5. The resistance value measuring circuit 72 applies a specific voltage between the electrode members 15a and 15b via the connector members 71a and 71b by power supply from the power supply circuit 78. Then, the resistance value measuring circuit 72 measures the current flowing between the electrode members 15a and 15b by an ammeter (not shown), and calculates the resistance value between the electrode members 15a and 15b based on the current and the applied voltage. The resistance value measuring circuit 72 outputs the calculated resistance value to the A/D conversion circuit 73 in the form of an analog signal. The A/D conversion circuit 73 converts the analog signal output from the resistance value measuring circuit 72 into a digital signal and outputs it to the arithmetic circuit 74. The arithmetic circuit 74 executes various programs by power supply from the power supply circuit 78, and controls the actions of various actuators. For example, the arithmetic circuit 74 is based on self-A/D by executing an infiltration discrimination program stored in a memory mechanism such as a ROM (Read Only Memory) 75 or a RAM (Random Access Memory) 76. The digital signal indicating the resistance value between the electrode members 15a and 15b outputted from the conversion circuit 73 determines the state of the liquid detecting member 5. Specifically, a specific threshold value is previously stored in the ROM 75 or the RAM 76 or the like. When the resistance value between the electrode members 15a and 15b does not reach the threshold value, the calculation circuit 74 determines that the liquid detecting member 5 is in the "non-infiltrated state" and the cable 1 is not abnormal. On the other hand, when the resistance value between the electrode members 15a and 15b is equal to or greater than the threshold value, the calculation circuit 74 determines that the liquid detecting member 5 is in the "infiltration state", and the cable 1 is abnormal, and the cable 1 must be replaced. Repair, etc. Moreover, the arithmetic circuit 74 can output the abnormality information indicating the presence or absence of the abnormality of the cable 1 to the outside via the communication interface 77. That is, the communication interface 77 is at least capable of transmitting an interface of abnormal information. Specifically, the arithmetic circuit 74 transmits the unique ID (Identification) information together with the abnormal information via the communication interface 77. The inherent ID information is used to individually identify the information of the measuring device 7. In the present embodiment, the measuring device 7 transmits the abnormality information to a monitoring device (not shown). Thereby, the monitoring device can automatically respond to an abnormality (for example, automatically stop power transmission via the wire 3a of the cable core 2). In this way, the measuring device 7 of the data transmission source can be specified based on the ID information. Therefore, the cable 1 that generates the abnormality can be specified. Therefore, the plurality of cables 1 can be monitored from a distance as long as the ID information is associated with the installation location. Further, in the present embodiment, as described above, the determination information signal is output to the outside by wireless communication. However, the measurement device 7 may further provide an external contact output for wiring as the terminal side communication unit. Thereby, the terminal side communication unit can cope with either wireless or wired. As a variant, the measuring device 7 may be configured to have a reporting mechanism such as a speaker or a display, and the reporting device may report the abnormality information of the cable 1 to a user in the vicinity of the measuring device 7. As described above, according to the present embodiment, when the outer cover 6 is not broken and the liquid does not penetrate into the inner side of the outer cover 6, the insulating member 14 is in a state in which the conductive member 14 does not exhibit conductivity. As a result, the resistance value between the electrode members 15a and 15b becomes a high resistance value, and the measuring device 7 can determine that the state of the liquid detecting member 5 is "non-infiltration state", and the cable 1 is not abnormal. On the other hand, when the outer cover 6 is broken and the liquid penetrates into the inner side of the outer cover 6, the insulating member 14 is in a state of exhibiting conductivity. As a result, the resistance value between the electrode members 15a and 15b becomes a small resistance value, and the measuring device 7 can determine that the state of the liquid detecting member 5 is "infiltration state" and the cable 1 is abnormal. As described above, it is possible to detect the water leakage caused by the damage of the outer cover 6 with high reliability by detecting a large change in the resistance value between the electrode members 15a and 15b. (Second Embodiment) Next, a liquid detecting member according to a second embodiment will be described. In the second embodiment, the liquid detecting member has a protective layer in a different aspect from the first embodiment. In the following, the same portions as those in the above-described first embodiment are denoted by the same reference numerals, and their description will be appropriately omitted. As previously described, at the end of the insulating core 3 (cable core 2), the insulating coating 3b is peeled off from the wire 3a to expose the wire 3a. Therefore, if the liquid comes into contact with the exposed wire 3a, a short circuit occurs between the plurality of wires 3a of the cable core 2, which causes a major failure. As described above, since the front end portion of the cable core 2 is housed in the casing 9, normally the liquid does not come into contact with the front end portion of the cable core 2. However, the liquid infiltrated by the damage of the cover 6 outside the casing 9 may move along the longitudinal direction of the cable core 2 on the inner side of the outer cover 6 to reach the front end of the cable core 2. In addition, although a sealing material is provided between the casing 9 and the cable 1, when the sealing material is abnormal, the liquid may penetrate into the casing 9 and reach the front end of the cable core 2. . Therefore, the front end of the cable 1 will have a significant portion due to water seepage, and it is necessary to monitor the monitored portion in such a manner that it can detect a small amount of water seepage. On the other hand, in the central portion of the cable 1, since the wire 3a is covered with the insulating coating 3b, even if a small amount of liquid permeates into the inner side of the outer cover 6, no major failure occurs, and the cable 1 can be continuously used. . Here, when the detection sensitivity of the liquid detecting member 5 at the central portion of the cable 1 is the same as the detection sensitivity of the front end portion of the cable 1, the measuring device 7 can be used even when the cable 1 can continue to be used. It is also discriminated that an abnormality is generated in the cable 1. As a result, it is possible to perform unnecessary replacement or repair of the cable 1. Therefore, as shown in FIGS. 4 and 5, the liquid detecting member 50 of the present embodiment has two protective layers 20 and 30 in addition to the insulating member 14 and the electrode members 15a and 15b. The protective layer 20 is detachably covered with the surface on which the electrode members 15a and 15b are formed, and the electrode members 15a and 15b are covered in a liquid-tight state. The protective layer 30 is detachably covered with a surface on the opposite side to the above-described formation surface of the insulating member 14 in a liquid-tight state. The protective layers 20, 30 are used to prevent liquid that has penetrated into the inner side of the outer cover 6 from advancing to the layer of the insulating member 14. In the present embodiment, the protective layers 20 and 30 are non-porous materials containing a resin such as PET (polyethylene terephthalate). Therefore, the permeability of the protective layers 20, 30 is lower than that of the insulating member 14. Further, the protective layers 20 and 30 are peelably adhered to the insulating member 14 by an adhesive, thermocompression bonding, heat welding or the like. Further, as shown in FIG. 5, the protective layers 20 and 30 are peeled off from the insulating member 14 at a monitoring portion where a major failure occurs due to water seepage at the end portion of the cable 1 or the like. Thereby, the detection sensitivity of the liquid at the monitoring portion of the liquid detecting member 50 can be improved. On the other hand, the monitoring external position other than the monitoring portion, such as the center portion of the cable 1, is in a state in which the insulating member 14 or the electrode members 15a and 15b are directly covered without peeling off the protective layers 20 and 30. Thereby, even if the liquid penetrates into the inside of the outer cover 6, even if the protective layers 20 and 30 normally exist, the insulating member 14 does not exhibit electroconductivity by the contact of liquid. Thereby, the detection sensitivity of the liquid of the liquid detecting member 50 for monitoring the external position can be reduced. As described above, since the detection sensitivity of the liquid penetrating into the inner side of the outer cover 6 is different due to the monitoring portion of the cable 1 and the monitoring external position, replacement or repair of the unnecessary cable 1 can be suppressed. Further, in the cable 1, if the position of the monitoring portion that causes a major failure due to water seepage, the length of the necessary liquid detecting member 50, and the arrangement of the liquid detecting member 50 (winding method, etc.) are known in advance, In the manufacturing process of the liquid detecting member 50, the protective layers 20, 30 may be covered only in portions of the insulating member 14 corresponding to the monitoring external position. However, actually, depending on the installation place or setting method of the cable 1, the monitoring portion may be different. For example, there is a case where it is necessary to monitor the central portion of the cable 1 in accordance with the installation place or setting method of the cable 1. Further, depending on the core diameter of the cable core 2 around which the liquid detecting member 50 is wound, the winding pitch, and the like, the length of the liquid detecting member 50 which is necessary is also different. Therefore, in the liquid detecting member 50, it is difficult to grasp the portion corresponding to the monitored portion in advance. In addition, in the manufacturing process of the liquid detecting member 50, the use form is limited only when one of the insulating members 14 is partially covered with the protective layers 20, 30. Therefore, in the present embodiment, the protective layers 20 and 30 are peelably covered over the entire surface of the insulating member 14 during the manufacturing process of the liquid detecting member 50. Further, the protective layers 20 and 30 are peeled off only in accordance with the use form of the cable core 2, and thereafter only in the portion corresponding to the monitored portion. (Removal strength of the protective layer) In order to make the protective layers 20 and 30 easily peel off from the insulating member 14 and to make the peeling strength of the protective layers 20 and 30 uniform uniformly over the entire surface, the liquid detecting member 50 becomes opposite to the entire surface. The load from the outside is weaker. Therefore, in monitoring the external position, the protective layers 20, 30 may be accidentally peeled off from the insulating member 14, and therefore, the reliability of the cable 1 is lowered. In addition, in order to make the liquid detecting member 50 stronger than the load from the outside, the peeling strength of the protective layers 20 and 30 is uniformly increased over the entire surface, and it is difficult to self-insert the protective layers 20 and 30 at the monitoring portion. The member 14 is peeled off. Therefore, in the present embodiment, as shown in Fig. 6, the entire region of the insulating member 14 is divided into an inner region between the electrode members 15a and 15b, an arrangement region of the electrode members 15a and 15b, and an outer side other than the regions. region. Further, the peeling strength of the protective layers 20 and 30 with respect to the insulating member 14 is configured such that the inner region is smaller than the outer region. For example, when the protective layers 20 and 30 are attached to the insulating member 14 by an adhesive, an adhesive having a stronger material is used in the outer region, and an adhesive having a lower strength is used in the inner region. When the protective layers 20 and 30 are pressure-bonded to the insulating member 14 by thermocompression bonding, for example, in the outer region of the insulating member 14, the protective layers 20 and 30 are crimped over the entire length direction, and on the other hand, The inner region of the insulating member 14 is crimped to the protective layers 20, 30 at a predetermined interval in the longitudinal direction. Further, when the protective layers 20 and 30 are welded to the insulating member 14 by heat fusion, for example, the heating temperature is increased in the outer region of the insulating member 14 to weld the protective layers 20 and 30 to the inner region of the insulating member 14. The protective layers 20, 30 are welded by lowering the heating temperature. In any of the above methods, the peeling strength of the protective layers 20, 30 with respect to the insulating member 14 can be made smaller than the outer region. Further, the peeling strength of the protective layers 20 and 30 with respect to the insulating member 14 may be made smaller than the outer region by the method other than the above. With the above configuration, the outer side region of the insulating member 14 of the liquid detecting member 50 is more difficult to peel off than the inner region, and therefore, the liquid detecting member 50 is stronger with respect to the load from the outside, thereby improving the cable. The reliability of line 1. In the peeling operation of peeling off the protective layers 20 and 30 from the insulating member 14 and exposing the insulating member 14 to the outside, first, the outer side region of the insulating member 14 and the protective layer 20 are cut by the auxiliary tool. The cutting operation of the portion corresponding to the outer region. Thereby, only the protective layers 20 and 30 which are covered in the inner region with a small peeling strength remain in the monitoring portion. As a result, the protective layers 20 and 30 of the monitoring portion can be easily peeled off. In addition, since the portions of the protective layers 20 and 30 which are removed by the auxiliary tool are different from the inner regions of the insulating member 14 and are covered by the protective layer of the outer region, it is easy to secure the working space, and the work can be easily performed. Further, in the above-described cutting operation, only the protective layers 20 and 30 may be cut without cutting the insulating member 14. Further, it is also possible to cut only one of the two protective layers 20 and 30. Further, the outer region of the insulating member 14 may be further divided into an inner region on the side of the electrode members 15a and 15b and a region on the opposite side to the electrode members 15a and 15b, and the peeling strength of the protective layers 20 and 30 may be formed as the inner region. The area is smaller than the outer area. In this case, in the above-described cutting operation, even if the boundary between the outer region and the arrangement region of the insulating member 14 is not cut off, the protective layer after the cutting operation can be easily performed by cutting the inner region of the outer region. 20, 30 peeling from the insulating member 14. As described above, in the protective layers 20 and 30, even if the peeling strength of the portion covering the inner region of the insulating member 14 is relatively small, for example, the peeling strength to the extent that it can be peeled off by hand can be applied to the outside of the insulating member 14 Since the peeling strength of the portion of the region is large, the strength of the liquid detecting member 50 with respect to the mechanical load can be maintained, and the peeling operation can be easily performed. (Variation of the liquid detecting member of the second embodiment) Hereinafter, a modification of the liquid detecting member of the second embodiment will be described. In the liquid detecting member 150 shown in FIG. 7, the width of the protective layers 120, 130 covering both sides of the insulating member 14 is larger than the width of the insulating member 14. Moreover, both ends of the protective layers 120, 130 in the width direction are adjacent to each other. Thereby, the insulating member 14 and the electrode members 15a and 15b cover the entire circumference by the protective layers 120 and 130. As a result, even if the liquid penetrates into the inside of the outer cover 6, as long as the protective layers 120 and 130 are normally present, the possibility that the insulating member 14 exhibits conductivity due to liquid contact can be more reliably reduced. As a result, the reliability of the cable 1 can be improved. Further, as another modification, in the liquid detecting member 250 shown in FIG. 8, only one surface of the insulating member 214 on which the electrode members 15a and 15b are formed is covered with the protective layer 220. In this case, even when only one side of the insulating member 214 is covered with the protective layer 220, it is preferable to arrange the liquid detecting member 250 in the butted state around the cable core 2 or the like. The liquid is inhibited from advancing toward the insulating member 214. The protective layer 220 has a sheet-like protective sheet 220a and a protective layer 220a followed by an adhesive layer 224. In the present embodiment, the protective sheet 220a is a non-porous sheet containing a resin such as PET, and has lower permeability than the insulating member 214. Next, the layer 220b is made of a resin material such as an acrylic resin, a lanthanum resin, a thermoplastic elastomer resin, a rubber resin, or a polyester resin. Further, in the insulating member 214, the surface 214a of the outer region is formed in a concavo-convex shape. Thereby, the surface 214a of the outer region has a larger surface area per unit area than the surface 214b of the inner region. As a result, the contact area per unit area of the insulating member 214 with respect to the adhesive layer 220b is smaller than the outer side region. Thereby, even if the material of the adhesive agent in the inner region of the insulating member 214 and the material of the adhesive in the outer region are not changed, the entire adhesive layer 220b is formed by the adhesive of the same material, and the protective layer 220 may be used. The portion covered in the outer region of the insulating member 214 is more covered than the portion covering the inner region, and the peeling strength is higher. (Other Modifications) In the above embodiment, the insulating members 14 and 214 are formed in a sheet shape, but are not particularly limited thereto. For example, as in the liquid detecting member 350 shown in FIG. 9, the insulating member 314 formed in a cylindrical shape may be used. In this case, the electrode members 15a and 15b may be arranged in parallel along the cylindrical axis of the insulating member 314. Further, as in the liquid detecting member 450 shown in FIG. 10, the electrode members 15a and 15b may be spirally wound around the insulating member 314. Further, in the above embodiment, one liquid detecting member is provided for the cable core, but a liquid detecting member may be provided for each of the insulating core wires of the cable core. Further, in the above-described embodiment, the peeling strength of the protective layers 20 and 30 with respect to the insulating member 14 is such that the inner region is smaller than the outer region, but the peeling strength may be made uniform over the entire surface of the insulating member 14. Further, as shown in FIGS. 11 and 12, the front end portion of the cable core 2 may be connected to the waterproof connector. Hereinafter, the configuration of the female connector 500 to which the front end portion of the cable core 2 is connected to the waterproof connector will be described. Furthermore, the female connector 500 can be connected to a pair of male connectors 550 (see FIG. 13). The female connector 500 has a housing 501 comprising a rubber or elastomer. The casing 501 is integrally formed on the cable 1 by die casting at the front end of the cable 1. As shown in FIG. 12, the casing 501 has a casing body 501a and a housing portion 501b. A plurality of insulating core wires 3 of the cable core 2 are inserted into the casing body 501a. Further, a substantially rectangular abutting surface 501c that is in close contact (contact) with the abutting surface 551c of the male connector 550 is formed at an end portion of the outer casing main body 501a. A plurality of terminals 502 corresponding to the number of the insulating core wires 3 are protruded from the abutting surface 501c. The plurality of terminals 502 form two rows of terminal rows on the abutting surface 501c. The terminals 502 are each electrically connected to the wire 3a of the insulating core wire 3 in the casing body 501a. The accommodating portion 501b is connected to the peripheral edge of the abutting surface 501c of the casing body 501a, and can accommodate the following accommodating portion 551b of the male connector 550. As shown in FIG. 13, the male connector 550 has a housing 551 containing rubber or an elastomer. The casing 551 has a casing body 551a and a accommodating portion 551b. A plurality of wires (not shown) are disposed in the casing body 551a. The accommodating portion 551b is connected to the front end portion of the casing main body 551a, and is housed in the accommodating portion 501b of the female connector 500 when the female connector 500 is connected to the male connector 550. A substantially rectangular abutting surface 551c that abuts against the abutting surface 501c of the female connector 500 is formed at an end portion of the accommodating portion 551b. Further, a plurality of contact holes 552 into which the female terminal 502 is inserted are formed in the contact surface 551c. The contact holes 552 are arranged in two rows on the abutting surface 551c. Each of the contact holes 552 is provided with a terminal (not shown) electrically connected to the terminal 502 of the female connector 500, and the above-mentioned lead wire connected to the terminal. According to the above configuration, when the female connector 500 is connected to the male connector 550, the terminal 502 of the female connector 500 is electrically connected to the terminal of the male connector 550. Moreover, at this time, the accommodating portion 551b of the male connector 550 is housed in the accommodating portion 501b of the female connector 500, and the abutting surface 501c is in close contact with the abutting surface 551c. Thereby, liquid is prevented from infiltrating between the female connector 500 and the male connector 550. Further, a sealing material may be provided over the entire circumference of the accommodating portion 551b, and when connected to the female connector 500, the accommodating portion 551b and the accommodating portion 501b may be sealed by the sealing material. Moreover, in the above, the female connector 500 that connects the cable 1 and the male connector 550 that connects the female connector 500 are connectors in which the terminals are arranged in two rows, but the invention is not limited thereto. For example, it may be of the type of waterproof connector shown in FIGS. 14 and 15. Specifically, the housing 601 of the female connector 600 and the housing 651 of the male connector 650 are each substantially cylindrical. As shown in FIG. 14, the housing 601 of the female connector 600 has a housing body 601a and a housing portion 601b. The abutting surface 601c of the casing body 601a has a substantially circular shape, and the plurality of terminals 602 are arranged in four rotational symmetry centering on the center of the abutting surface 601c. As shown in FIG. 15, the housing 651 of the male connector 650 has a housing body 651a and a accommodating portion 651b. The abutting surface 651c of the accommodating portion 651b has a substantially circular shape, and the plurality of contact holes 652 are arranged to have four rotational symmetry about the center of the abutting surface 651c. Moreover, when the female connector 600 is connected to the male connector 650, the abutting surface 601c is in close contact with the abutting surface 651c, and the front end of the accommodating portion 601b is in close contact with the front end of the casing main body 651a. Further, a gasket member 653 is provided at the front end of the casing main body 651a, and the casing member 651a and the accommodating portion 601b are sealed by the gasket member 653,. In the above configuration, liquid is also prevented from infiltrating between the female connector 600 and the male connector 650. Further, as another modification, when the cable 1 is used as a cable for electrical equipment wiring, as shown in Fig. 16, at the front end of the cable 1, the wire 3a of the insulating core wire 3 can also be relatively It is directly connected to an electrical machine 700 such as a lighting machine. In the above detailed description, the present invention has been described with respect to the features of the present invention, but the present invention is not limited to the embodiments described in the above detailed description, and may be applied to other embodiments. The scope of application should be interpreted as widely as possible. Further, the terms and grammars used in the present specification are intended to describe the present invention accurately, and the user is not intended to limit the explanation of the present invention. Further, it is considered that other configurations, systems, methods, and the like included in the concept of the present invention are easily inferred from the concept of the invention described in the specification. Therefore, the description of the scope of the patent application should be construed as including the constituents of the equivalents within the scope of the technical idea of the invention. Further, in order to fully understand the object of the present invention and the effects of the present invention, it is preferable to fully consider the disclosed documents and the like.
1‧‧‧纜線
2‧‧‧纜線芯
3‧‧‧絕緣心線
3a‧‧‧導線
3b‧‧‧絕緣被覆
5‧‧‧液體檢測構件
6‧‧‧外覆
7‧‧‧測量裝置
8‧‧‧連接器
9‧‧‧盒體
14‧‧‧絕緣構件
15a‧‧‧電極構件
15b‧‧‧電極構件
20‧‧‧保護層
30‧‧‧保護層
50‧‧‧液體檢測構件
71a‧‧‧連接器構件
71b‧‧‧連接器構件
72‧‧‧電阻值測量電路
73‧‧‧A/D轉換電路
74‧‧‧運算電路
75‧‧‧ROM
76‧‧‧RAM
77‧‧‧通信介面
78‧‧‧電源電路
120‧‧‧保護層
130‧‧‧保護層
150‧‧‧液體檢測構件
214‧‧‧絕緣構件
214a‧‧‧外側區域之表面
214b‧‧‧內側區域之表面
220‧‧‧保護層
220a‧‧‧保護片
220b‧‧‧接著層
250‧‧‧液體檢測構件
314‧‧‧絕緣構件
350‧‧‧液體檢測構件
450‧‧‧液體檢測構件
500‧‧‧母連接器
501‧‧‧殼體
501a‧‧‧外殼本體
501b‧‧‧收容部
501c‧‧‧抵接面
502‧‧‧母端子
550‧‧‧公連接器
551‧‧‧殼體
551a‧‧‧外殼本體
551b‧‧‧被收容部
551c‧‧‧抵接面
552‧‧‧接觸孔
600‧‧‧母連接器
601‧‧‧殼體
601a‧‧‧外殼本體
601b‧‧‧收容部
601c‧‧‧抵接面
602‧‧‧端子
650‧‧‧公連接器
651‧‧‧殼體
651a‧‧‧外殼本體
651b‧‧‧被收容部
651c‧‧‧抵接面
652‧‧‧接觸孔
653‧‧‧襯墊材
700‧‧‧電氣機器1‧‧‧ cable
2‧‧‧ cable core
3‧‧‧Insulated heart
3a‧‧‧Wire
3b‧‧‧Insulation coating
5‧‧‧Liquid detection components
6‧‧‧Overlay
7‧‧‧Measurement device
8‧‧‧Connector
9‧‧‧Box
14‧‧‧Insulating components
15a‧‧‧Electrode components
15b‧‧‧Electrode components
20‧‧‧Protective layer
30‧‧‧Protective layer
50‧‧‧Liquid detection components
71a‧‧‧Connector components
71b‧‧‧Connector components
72‧‧‧resistance measurement circuit
73‧‧‧A/D conversion circuit
74‧‧‧Operating circuit
75‧‧‧ROM
76‧‧‧RAM
77‧‧‧Communication interface
78‧‧‧Power circuit
120‧‧‧Protective layer
130‧‧‧Protective layer
150‧‧‧Liquid detection components
214‧‧‧Insulating components
214a‧‧‧ Surface of the outer area
214b‧‧‧ Surface of the inner area
220‧‧‧Protective layer
220a‧‧‧protection film
220b‧‧‧Next layer
250‧‧‧Liquid detection components
314‧‧‧Insulating components
350‧‧‧Liquid detection components
450‧‧‧Liquid detection components
500‧‧‧Female connector
501‧‧‧shell
501a‧‧‧Shell body
501b‧‧‧ Housing Department
501c‧‧‧ Abutment
502‧‧‧ female terminal
550‧‧‧ male connector
551‧‧‧Shell
551a‧‧‧Shell body
551b‧‧‧Resident Department
551c‧‧‧Abutment
552‧‧‧Contact hole
600‧‧‧Female connector
601‧‧‧shell
601a‧‧‧Shell body
601b‧‧‧ Housing Department
601c‧‧‧ Abutment
602‧‧‧ terminals
650‧‧‧ male connector
651‧‧‧Shell
651a‧‧‧Shell body
651b‧‧‧Resident Department
651c‧‧‧Abutment
652‧‧‧Contact hole
653‧‧‧Cushing material
700‧‧‧Electrical machines
圖1係表示第1實施形態之纜線之概要之說明圖。 圖2係表示圖1所示之液體檢測構件之剖面構造之說明圖。 圖3係表示圖1所示之測量裝置之電性構成之方塊圖。 圖4係表示第2實施形態之液體檢測構件之剖面構造之說明圖。 圖5係表示第2實施形態之纜線與連接器之連接態樣之圖。 圖6係第2實施形態之液體檢測構件之俯視圖。 圖7係表示變化例之液體檢測構件之剖面構造之說明圖。 圖8係表示變化例之液體檢測構件之剖面構造之說明圖。 圖9係變化例之纜線之立體圖。 圖10係變化例之纜線之立體圖。 圖11係表示纜線與防水連接器之連接關係之說明圖。 圖12係母連接器之立體圖。 圖13係公連接器之立體圖。 圖14係變化例之母連接器之立體圖。 圖15係變化例之公連接器之立體圖。 圖16係表示纜線與電氣機器之連接關係之說明圖。Fig. 1 is an explanatory view showing an outline of a cable of the first embodiment. Fig. 2 is an explanatory view showing a cross-sectional structure of the liquid detecting member shown in Fig. 1; Fig. 3 is a block diagram showing the electrical configuration of the measuring device shown in Fig. 1. Fig. 4 is an explanatory view showing a cross-sectional structure of a liquid detecting member according to a second embodiment. Fig. 5 is a view showing a connection state of a cable and a connector in the second embodiment. Fig. 6 is a plan view showing a liquid detecting member of a second embodiment. Fig. 7 is an explanatory view showing a cross-sectional structure of a liquid detecting member according to a modification. Fig. 8 is an explanatory view showing a cross-sectional structure of a liquid detecting member according to a modification. Figure 9 is a perspective view of a cable of a variation. Figure 10 is a perspective view of a cable of a variation. Fig. 11 is an explanatory view showing a connection relationship between a cable and a waterproof connector. Figure 12 is a perspective view of the female connector. Figure 13 is a perspective view of a male connector. Figure 14 is a perspective view of a female connector of a variation. Figure 15 is a perspective view of a male connector of a variation. Fig. 16 is an explanatory view showing a connection relationship between a cable and an electric machine.
1‧‧‧纜線 1‧‧‧ cable
2‧‧‧纜線芯 2‧‧‧ cable core
3‧‧‧絕緣心線 3‧‧‧Insulated heart
3a‧‧‧導線 3a‧‧‧Wire
3b‧‧‧絕緣被覆 3b‧‧‧Insulation coating
5‧‧‧液體檢測構件 5‧‧‧Liquid detection components
6‧‧‧外覆 6‧‧‧Overlay
7‧‧‧測量裝置 7‧‧‧Measurement device
8‧‧‧連接器 8‧‧‧Connector
9‧‧‧盒體 9‧‧‧Box
14‧‧‧絕緣構件 14‧‧‧Insulating components
15a‧‧‧電極構件 15a‧‧‧Electrode components
15b‧‧‧電極構件 15b‧‧‧Electrode components
Claims (8)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP??2015-198922 | 2015-10-06 | ||
JP2015198922A JP6471075B2 (en) | 2015-10-06 | 2015-10-06 | Cable and liquid detection member for cable |
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KR101884905B1 (en) * | 2017-05-26 | 2018-08-02 | (주)유민에쓰티 | Leak liquid sensing device and manufacturing method the same |
EP3728758B1 (en) * | 2017-12-18 | 2024-10-30 | "AUSTYROL" DÄMMSTOFFE Gesellschaft m.b.H. | Building material, in particular roof building material |
KR102009968B1 (en) * | 2018-08-06 | 2019-08-12 | 아머스 주식회사 | Flexible flat component detection sensor |
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JPS56106130A (en) * | 1980-01-28 | 1981-08-24 | Benkan Plant Kk | Detection of liquid leaking part in piping or the like |
CA1134920A (en) * | 1980-04-30 | 1982-11-02 | David E. Vokey | Cable assembly for detecting the ingress of water inside a cable |
JPS59117944U (en) * | 1983-01-31 | 1984-08-09 | 昭和電線電纜株式会社 | Water leak detection cable |
GB2230631B (en) * | 1989-04-04 | 1993-03-03 | Gore & Ass | A solvent responsive signal-carrying device |
JP2822468B2 (en) * | 1989-08-08 | 1998-11-11 | 富士写真光機株式会社 | Water leak detection device for waterproof housing |
JP3097627U (en) * | 2003-02-03 | 2004-02-05 | 井上 廣 | Water leak detection line |
JP4131231B2 (en) * | 2003-12-02 | 2008-08-13 | オムロン株式会社 | Leak detector |
JP4780970B2 (en) * | 2005-02-10 | 2011-09-28 | スリーエム イノベイティブ プロパティズ カンパニー | Leak sensor |
CN104769423B (en) * | 2012-10-19 | 2018-09-07 | 大自达电线股份有限公司 | Liquid-detecting, its electrode connector, liquid detecting system and liquid detecting method |
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JP6471075B2 (en) | 2019-02-13 |
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