TW201224652A - Coloring composition, method for producing coloring composition, colored pattern, color filter, color display element and method for producing color filter - Google Patents

Abstract

The object of the present invention provides a coloring composition having both a storage stability and a low-temperature burning, a colored pattern excellent in development resistance, heat resistance, solvent resistance, voltage retentivity, etc., a color filter, a color display element having the color filter, and a method for producing the color filter. The present invention is a coloring composition which comprises [A] a compound having an epoxy group, [B] a coloring agent, [C] a compound having a hydroxyl group or a carboxyl group and [D] an amine compound, whose viscosity is 1.0 mPa.s to 50 mPa.s at 25 DEG C, wherein [D] the amine compound can be included in [C] the compound preferably, [C] the compound is at least one compound selected from the group consisting of the compound represented by the following formula (1) and formula (2), and [D] the amine compound is preferably an imidazole compound or a benzimidazole compound.

Description

201224652 /, the invention description: [Technical Field of the Invention] The present invention relates to a method for producing a coloring composition method, a coloring pattern, a color filter, and a Baguang sheet. The color filter T of the composition has a pigment dispersion type drying on the substrate, and then the ray is developed by a desired spectroscopy pattern to obtain respective colors and hearts. It is also known to use a composition of a pigment and obtain a pixel document 3) of each color by an inkjet method. ' έ . . Further, in order to achieve high definition of the high-resolution detector of the liquid crystal display element, a dye is used as a colorant β. Documents 4 to 6). A hardening system in which a combination of a polyfunctional acrylate and an alkoxymethyl melamine resin is combined in a dye-containing coloring composition. On the other hand, in recent years, electronic papers and the like have been used as substrates for s-changing displays, and plastic substrates such as β-alcohol esters are being researched. When the substrate is fired, it has a defect that impairs the function of the display, and further lowers the temperature (see Patent Document 7). However, in the case of a color filter which has been conventionally colored and hard-fired by a dye, there is a manufacturing method of heat resistance and resistance, and a color filter manufacturing method, and a dry matter is irradiated (exposure). Dispensing method (refer to the patent text: type of coloring resin method (refer to the patenting and image sensing effective (refer to the special 'mainly used with photopolymerization initiators are popular. Ethylene phthalate stretch or shrink, to burn The steps of the compound, and the low solvent solubility of the lack of * 4 - 201224652 trap. In addition, by the light sheet in the degree of development resistance. Therefore, the agent of the amine compound line of countermeasures, but will cause a drop with the composition from this situation and low temperature Preliminary document, patent document, patent document, patent document 2 patent document 3 patent document 4 patent document 5 patent document 6 patent document 7 [ SUMMARY OF INVENTION [ SUMMARY OF THE INVENTION [ [ According to the present invention, the storage stability and the hardening reactivity are insufficient, and thus the obtained color enthalpy, voltage retention ratio, and the like are not satisfactory. It is considered that by adding a hardening material which can be used as an epoxy-based material, the crosslinking reaction can be carried out into a general amine compound even at a low temperature, and the reaction of the epoxy group present in the substance is stable and stable over time. Under the circumstance, it is desired to develop a coloring composition capable of preserving stability, and a coloring pattern excellent in development resistance, heat resistance, pressure retention ratio, and the like.曰本特开平3-53-51号 曰本特开 2000-3 10706号曰本本开 2005-99584号曰本特开2007-219466号曰本本开20 07-3 16179号曰本JP-A-2009-4394. The present invention has been made in view of the above circumstances, and an object thereof is to provide a colored composition in which twins and low-temperature firing are coexisting, -5-201224652, developability, heat resistance, solvent resistance, Ray's wish to protect the electric seat retention rate and other excellent color patterns, color filters, color display elements with color sound umbrellas / light absorbers, and color filter manufacturing methods. Way] to understand The present invention is a coloring composition comprising: [A] a compound having an epoxy group (hereinafter referred to as "[a] epoxy compound,"), [B] colorant, [c] a compound having a trans group or a group (hereinafter, also referred to as "[c] compound"), and a [D] amine compound, and having a viscosity at 25 t or less. 忒 a coloring composition, by containing as a coloring The [B] coloring of the agent, and the [A] epoxy compound, the [C] compound, and the [D] amine compound can simultaneously improve the storage stability and the low temperature of the firing. Generally, an amine compound is known as a hardening accelerator for promoting crosslinking reaction of an epoxy compound. In the coloring composition, the epoxy group in the (9) amine compound has an effect, and when the crosslinking reaction 1 is promoted, the viscosity of the composition solution is increased, and it is difficult to control the film bonding and further coating at 5 〇 mPas. It cannot be used as a coloring composition, but the viscosity is controlled to be less than 50 mPa.s above 1.0 MgPa.s, and it is possible to store m, "stable stability and low-temperature firing coexist. In addition, the coloring-6-201224652 composition 'A color filter excellent in development resistance, heat resistance, solvent resistance, voltage holding ratio, etc. can be formed. [D] An amine compound is preferably contained by a [C; j compound. By [D] The amine compound is capable of forming an inclusion compound by at least a part of the compound containing the amine compound of the [c] compound and the coloring composition may contain an inclusion compound, which allows storage stability and low-temperature firing to coexist. Next, the amine compound which promotes hardening is improved in viscosity of the solution of the hardening reaction containing the epoxy group in the state of inclusion. Therefore, the coloring property is excellent. On the other hand, if it is to be Composition and does not make the group above, above the degree, including collapse, the resin cross-linking, promoting the hard [C] compound, is selected from the group consisting of compounds. Therefore, the preservation of the colored composition is stable if The colored composition is heated to a predetermined ρ to release the [D] amine compound, and the temperature is promoted to promote the hardening reaction. Further, the ring-containing gas compound, preferably an imidazole compound or benzene, is represented by the following formulas (1) and (2). At least one compound, a compound or a benzimidazole compound, 'as indicated and aminated

201224652 (In the formula (1), x is a single bond, a fluorenylene group or a carbon atom alkyl group. R1 to R8 are each independently a hydrogen group of 2 to 6 and a thiol group having an anatomical number of 1 to 12; a functional atom, an alkoxy group having 1 to 12 carbon atoms, or a phenyl group which may have a substituent. 4 j has an alkyl group having a carbon number of 丨 12 and 12 in the formula (2). ~12 of the hospital oxygen &, the base or the base). The number of anti-atoms is f. The compound of the [C] compound and the [D] amine compound are the above-mentioned specific & The compound represented by the above formula (1) is preferably a compound shown below, and 1 Π

In the S-colored composition, the fraction is contained by the [C] compound. At least one of the amine compounds may have a storage stability of at least a portion of the [D] amine compound in the colored composition, and the inclusion compound of the [C] compound is formed by forming the [D] component. Low temperature firing coexist. ° 201224652 The step contains a carboxy colored pattern inclusion compounding agent, a key which is dispersed in the product, and the carboxyl group is considered to be uniform, and the uniformly coated proton is formed and the synergistic effect of the [A] epoxy compound is preferably The polymer is more preferably a polymer based on a base. By making the [A] epoxy compound a polymer, the hardness of the color filter is further increased. Further, since the substance is usually in the form of a solid powder and when it is dissolved in a polar solvent such as an alcohol-soluble solvent, the inclusion may collapse, so that it is used in a composition solution or the like. However, in this coloring group, since the [A] epoxy compound further contains a carboxyl group, the interaction between the group and the inclusion compound suppresses the collapse of the inclusion to dissolve it in a polar solvent, and uniformity can be achieved. Further, it is considered that the thiol group is anionized and negatively carbonized by the above-mentioned interaction ', addition of a [D] amine compound such as carboxyimidazole. Since the carbanion has high nucleophilicity, the inclusion compound also serves to promote the epoxy group hardening reaction. The coloring composition preferably further contains [E] a polymerizable compound having an ethylenically unsaturated bond (hereinafter also referred to as "[E] polymerizable compound"), and the coloring composition further contains [E In the case of a polymerizable compound, a color filter having more excellent properties such as heat and acidity can be obtained even at a low exposure amount. The colored composition ' preferably further contains a [F] radiation sensitive polymerization initiator. When the coloring composition further contains [F] radiation sensitive polymerization initiator, a color filter having more excellent heat resistance and solvent resistance can be obtained even at a low exposure amount. At 25. (The coloring composition at a viscosity of 3.OmPa.s or more and 50 mPa.s or less at 3 hours is preferably a [D] aminated 201224652 compound-containing compound to be contained in the [C] compound, and [A] The epoxy compound and the [B] colorant are mixed and prepared. The colored composition containing the inclusion compound can be efficiently produced according to the above step'. Further, the present invention suitably includes a method for producing a colored composition, which has The following step: the [D] amine compound contained in the [c] compound is coated with the compound, mixed with the [A] epoxy compound and the colorant, and prepared to have a viscosity at 25 t of 丨〇mPa.s or more and 50 mPa*. The colored pattern formed by the coloring composition, the color filter, and the color display element having the color filter are also suitably included in the present invention. The method of manufacturing the color filter of the present invention, And (1) a step of applying the colored composition to form a ruthenium on the substrate, (2) a step of forming a colored pattern on the ruthenium film, and (3) a step of firing the colored pattern at 200 ° C or lower According to the hair using the coloring composition In the production method, it is possible to produce a color filter which satisfies heat resistance, chemical resistance, voltage holding ratio, etc. In addition, in the present specification, the viscosity is an E-type viscometer (made by Toki Sangyo Co., Ltd., VISCONIC) ELD. R) 'The value obtained by measuring the viscosity (mPa.s) of the composition at 25 ° C. "Burning" means heating to a hardness required to obtain a colored pattern and a color filter.疋 refers to a compound formed by a molecular unit containing another guest molecule in the space formed by the host molecule. The ''radiation' that is exposed during exposure refers to visible light, ultraviolet light, far ultraviolet light, X-ray, charged particle beam. [Effects of the Invention] -10- 201224652 [Effects of the Invention] The colored composition according to the present invention contains, as a coloring material, a storage stability and a low-temperature firing, and the guessing property, the heat resistance, and the solvent resistance. Excellent case such as voltage holding ratio and color filter. Therefore, the coloring composition can be color-filtered by the color filter of the color display element and the color of the image sensor. Manufacture of various color light-sensitive sheets such as color filters and electric color filters for organic EL display elements. [Embodiment] [Formation for carrying out the invention] <Coloring composition> Coloring composition of the present invention Containing [A] epoxidized into colorant, [C] compound and [d] amine compound, and at 2 $. (degrees below 1.0 MPaPa.s above 5 〇 mPa.s. In addition, the father also The [E] polymerizable compound and [F] sensitizing radiation may be contained as an appropriate component. Further, 'the coloring composition, the effect of the present invention' may contain other optional components. 'The components are described in detail. <[A]Epoxy compound> The dyeing resistance of the dyeing agent is used for the decomposition of the paper product, and the point of '[B]: The LAji^ oxygen compound is not particularly limited. The gas------------------------------------------ "Construction" and oxetanyl group (containing two or more glycidyl groups as the [A] epoxy compound, for example, in the fraction, having two or more groups in the molecule, and having four in the four , Cyclohexane-11- 201224652 Cyclohexyl-based polyfunctional epoxidized ^ bond, poly-didiol diglycidyl succinic acid diethylene glycol diglycidyl; sputum or more than two kinds of oxygen = more / drunk Polyglycidol, an aliphatic polyol such as triol, is added. "Ethylene glycerol, glycerol, glycerol, glycerol, glycerol, glycerol, glycerol = epoxy resin; a varnish-type epoxy resin; a multi-component r-di-lipid; a cyclic aliphatic cycloolefin resin; an aliphatic long-chain binary 3-mercapto- glycerin g-type $ by class, and a glycidyl ester of fatty acid; a cyclized soybean oil, an epoxidized linseed oil, etc. In the case of the [A] epoxy compound, it is preferred to have two or more in the molecule: an oil group, having a molecule Two or more 3, epoxycyclohexyl amide "t*% oxygen compound, phenol novolac type epoxy resin epoxy A compound having two or more glycidyl groups in a knife, and examples thereof include a double-aged A diglycidyl ether, a double-aged f-distilled oil ether bisphenol S-glycidyl ether, and a hydrogenated bisphenol a condensed water. Glycidyl ether, bismuth bisphenol F diglycidyl ether, hydrogenated bisphenol ad diglycidyl fluorescing, etc., polyglycidyl phthalate; M_butanediol diglycidyl ether, 1,6-hexanediol condensed water Glycerol ether, glycerol triglycidyl ether, trimethylolpropane triglycidyl ether, etc. Examples of the compound having two or more 3,4-epoxycyclohexyl groups in the molecule include, for example, 3, 4 _Epoxycyclohexylmethyl_3,,4,_epoxy% hexanecarboxylic acid® 曰, 2-(3,4-epoxycyclohexyl·5,5•spiro_3,4_epoxy Cyclohexane-Methyl-Dijin, bis(3,4-epoxycyclohexylmethyl)hexamethylene, bis(3,4-epoxy-6-methylcyclohexylmethyl) Adipate, 3,4_ -12- 201224652 Epoxy-6-fluorenylcyclohexyl-3,4'-epoxy-6,-nonylcyclohexanecarboxylate, fluorenylene double (3,4-epoxycyclohexane), dicyclopentadiene diepoxide, Bis(3,4-epoxycyclohexyldecyl)ether of ethylene glycol, ethylenebis(3,4-epoxycyclohexanecarboxylate), lactone-modified 34-epoxy ring Hexyl fluorenyl-3',4'-epoxycyclohexanecarboxylate, etc. For the commercial product of the [A] epoxy compound, for example, as the bisphenol A type epoxy resin, EPIKOTE 100 1 can be cited. , EPIKOTE 1002, EPIKOTE 1003, EPIKOTE 1004, EPIKOTE 1007, EPIKOTE 1009, EPIKOTE 1010, EPIKOTE 828 (above is Japan Epoxy Resin); as bisphenol F type epoxy resin, EPIKOTE 807 (Japan Epoxy Resin); Examples of the phenol novolac type epoxy resin (bisphenol A novolak type epoxy resin) include EPIKOTE 1 52, EPIKOTE 1 54, EPIKOTE 157S65 (above, Japan Epoxy Resin Co., Ltd.), EPPN201, and EPPN202 (the above are transcripts). Chemical company); as the phenolic novolak type epoxy resin, EOCN 102, EOCN103S, EOCN104S, 1020, 1025, 1027 (above is 曰本化制药社), EPIKOTE 180S75 (above is Japan Epoxy Resin company); As a polyphenol type epoxy resin, EPIKOTE 1032H60, EPIKOTEXY-4000 (above is Japan Epoxy Resin Co., Ltd.) can be cited; as the cyclic aliphatic epoxy resin, CY-175, CY-177, CY-179, araldite CY-182, araldite CY-192, 184 can be cited ( From -13-201224652 for ciba specialty chemicals), ERL-4234, 4299, 4221, 4206 (above for UCC) 'shodyne509 (Showa Denko), Epiclon200, Epiclon 400 (above is Otsuka ink company), EPIKOTE 871, EPIKOTE 872 (above is Japan Epoxy Resin), ED-5661, ED-5662 (above is celanese coating company); As an aliphatic polyglycidol puzzle, EPOLIGHT100MF (Kyoeisha Chemical Co., Ltd.), epi 〇1 TMp (Nippon Oil Company) and the like. The [A] epoxy compound is preferably a polymer, more preferably a polymer further containing a group. Further, as the polymer of the [A] epoxy compound, it is preferred to have a soluble alkali-soluble resin in the development treatment step, and from the viewpoint of solubility to the alkali developer, the obtained coloring pattern, and the hardness of the color filter. More preferably, it is a copolymer having a carboxyl group-containing structural unit and an epoxy group-containing structural unit (hereinafter, also referred to as "[A] copolymer"). As a method of synthesizing a copolymer having a carboxyl group-containing structural unit and an epoxy group-containing structural unit, for example, (a) can be imparted to a carboxyl group-containing structural unit (a carboxyl group also includes an acid anhydride group) by using a polymerization initiator in a solvent. An unsaturated carboxylic acid and/or an unsaturated carboxylic anhydride (hereinafter also referred to as σ) and (a2) a group-based polymerizable compound having an epoxy group-containing structural unit (hereinafter, also referred to as " (a2) The compound (a2) can be copolymerized with (a) a compound (a), and a (a) compound can be copolymerized as a compound (a3). 201224652 For the compound (a 1), for example, acrylic acid, methacrylic acid, crotonic acid, 2-acryloxyethyl succinic acid, 2-methylpropenyloxyethyl succinic acid , 2_ propylene oxyethyl hexahydrophthalic acid, 2_mercapto propylene oxyethyl hexahydrophthalic acid, etc.; monocarboxylic acid; maleic acid, fumaric acid, citraconic acid, etc. a carboxylic acid; a dicarboxylic anhydride such as maleic anhydride. These (al) compounds Among them, acrylic acid, methacrylic acid, 2-propenyloxyethyl succinic acid, and 2-methyl propylene oxy oxy group are preferable from the viewpoint of copolymerization reactivity and 'glutenability of the alkali developing solution. (a) compound, which may be used singly or in combination of two or more. As the [a] copolymer, the amount of the (al) compound used is 100% by mass relative to the total monomers used. It is preferably 5% by mass to 4% by mass, more preferably 7% by mass to 30% by mass, and particularly preferably 8% by mass to 25% by mass. The amount of the compound (4)) is 5 mass% to 4% by weight. 〇% by mass, a coloring composition which is optimized to a higher level, such as radiation sensitivity and storage stability, is obtained. For example, a radical polymerization having an oxetanyl group having an oxetanyl group is exemplified (a 2) A radically polymerizable compound such as a compound, etc. Examples of the oxopropyl group include, for example, a glycidyl acrylate, 3,4-epoxy butyl acrylate. Ester, 2-methylglycidyl acrylate, Acetyl 6,7-epoxyheptyl ester, acrylic acid 201224652 3.4- epoxycyclohexanacetone, acrylic acid 3,4-epoxycyclohexyl hydrazine vinegar, etc.; epoxy methacrylate Ester, methacrylic acid 2_methylglycidyl vinegar, 3,4-epoxybutyryl methacrylate, 6,7-epoxyheptyl methacrylate, 3,4-epoxy ring of methacrylic acid Hexyl ester, methacrylic acid 3.4-epoxycyclohexyl hydrazine vinegar, etc. methacrylic acid epoxy group §; α-ethyl acrylate glycidol brewing, α-n-propyl acrylate shrinking water, α-positive Alpha-alkyl acrylate ethoxylates such as butyl acrylate glycidol, α-ethyl acrylate, 6,7-glyoxy vine vinegar, etc.; : ethylene thioglycidyl ether, dilute The second bond, the glycidyl group such as the ethylene base group, the glycidol, etc. The freeness of having an oxetanyl group is exemplified by, for example, a 3-(methyl propylene oxide compound, a methoxymethyl group of a methacrylic acid)-3 ethyloxy group: an oxetane 3, oxymethyl)-2-methyloxeane, 3_(methyl propyl oxirane, 3-(methyl-propyl propylene oxyethyl) appearance, 2 _Ethyl...propylene oxyethylhexyloxycyclobutene oxymethyl)oxetane^ethyl)oxetane, 3-(propoxyphene, 3na: Base (: waking oxymethyl)·3·ethyl 3_(acrylic acid ethyl) oxa...-methyloxeane, ethyloxetane, 2_acetamidine , 3, propylene oxiranyl ethyl) _3_ propyl propyl ethoxylate ^) (^ oxyethyl) oxetanyl oxime oxirane oxetane, 1 s A m 7 group)虱 Heterocyclic 俨 2 subunit-2-( p oxetan, methyl methacrylate, 2·(2-(2ι武产(尹基醯 醯 醯oxy)) (IV) Cyclobutyl))ethinyl propylene;) -16- 201224652 A propylene (2 (3'methyl-heterobutyl))ethyl ketone = oxiranyl ethyl methyl oxo Ding on acrylic vinegar, 2- (methoxyethyl)-4·fluorenyl oxetane, 2-(mercapto propylene oxime, 2-methyl propyl oxyl oxymethyl) oxa propylene Methyl) gas heterocyclic firing:: 曱: cyclobutane, 3-methylindenyl) oxetane, 2 methyl-2-(propylene oxime acrylate, 2_(2_(3_ : _甲甲) Oxycyclohexyl))ethylmethyl propyl decyloxyethyl C}) ethyl methacrylic acid butyl ethyl hydrazine - methyl oxetane butane, 2- (acrylic hydrazine From the viewpoint of the obtained coloring pattern: acrylic vinegar, high adhesion, excellent heat resistance, and reliability in the substrate, it is more "in the display element", the acrylonitrile: dimethyl propylene oxide ^, 乙妇醯oxymethyl) oxadiyl: =^^ olefinoxymethyl) oxetane " Ethyloxetane, 2 Methyl propylene oxide oxy group) -3- (10) ^ base) oxetane. Polymeric method, μ, stomach or use of two or more. In terms of the amount of [A] total w J compound, relative to the use of all two V : preferably, it is 10% by mass to 70% by mass, and the amount of use of the :::: is 1% by mass. ~ 7. Mass %, easy to control (4) - Molecular weight, and can obtain a coloring composition that is optimized to a higher level such as sensitivity. (a3) A compound selected from the group consisting of alkyl (meth)acrylate, (methyl) Acrylic acid, hydroxyalkyl ester of unsaturated five- and six-membered heterocyclic (meth) propylene fluorene, methyl acrylate, (meth) acrylate 201224652 base, cis and 1,3 - butyl compound. At least one radical polymerizable group of the group consisting of imipenem compound, styrene, and α-fluorene basic acetonide is (meth) acrylate. For example, (mercapto) propylene 8 under-methyl ester, ethyl (meth) acrylate, n-butyl (meth) acrylate, secondary butyl (meth) acrylate, grade 3 (meth) acrylate Butyl ester and the like. The (meth) acrylate cyclic alkyl ester may, for example, be (cyclo)acrylic acid cyclopentyl ester, (mercapto)acrylic acid cyclohexyl ester, (methyl)propionic acid-2-methyl group. Cyclohexyl ester, tricyclo[5 2丨〇2,6]fluorenyl (meth)acrylate, isodecyl (decyl)acrylate, and the like. Examples of the (fluorenyl)acrylic acid having a five- and six-membered heterocyclic ring containing an oxygen atom include, for example, tetrahydrofurfuryl (meth) acrylate, 2- fluorenyl propylene oxy-propionic acid tetrahydrogenation. a (meth) acrylate containing a tetrahydrofuran skeleton such as an oxime ester or a tris(meth)acryloxytetrahydrofuran-2-one; 2-methyl-5-(3-furyl)_1-pentene_3_ Ketone, mercapto (mercapto) acrylate, bufuran-2-butyl-3-en-2-one, hydrazine-furan-2-butyl _3_decyloxy-3-en-2-one, 6 -(2-furyl)_2-methylhexene% ketone, 6-furan-2-yl-hex-1-en-3-one, acrylofuryl-2-yl hydrazine-methyl-ethyl ester, 6 a (meth) acrylate containing a furan skeleton such as (2-furyl)-6-methyl-1-hepten-3-one; (tetrahydropyran-2-yl)methyl decyl acrylate, 2,6-Dimethyl-8-(tetrahydropyran-2-yloxy)-oct-1-ene-3-enone- 2-mercapto-acrylic acid tetrahydropyran-2-yl ester, 1-( (Meth)acrylic acid containing tetrahydro 0-pyan skeleton, such as tetrahydropyran-2-oxy)-but-3-ene-2-one; 201224652 4-( 1,4-diox-5- Oxy-6-heptenyl)-6-methyl-2-pyran, 4-( 1,5-dioxa- 6-oxo-7-octenyl-yl-2-pyrylate, etc. (fluorenyl) acrylate having a 0-pyranyl skeleton, etc. Examples of the ester include 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 3-hydroxypropyl (meth)acrylate, and (mercapto)acrylic acid. 2,3_dipropyl propyl vinegar, etc. Examples of the (mercapto) aryl acrylate include phenyl (meth) acrylate, benzyl (meth) acrylate, and the like. Examples of the imine compound include N-phenylbutyleneimine, N-cyclohexylmethyleneimine, N-benzyldinimide, N-(4- Hydroxyphenyl) maleimide, N-(4-hydroxybenzyl) maleimide, N-succinimide, butadiene diimide benzoate, N-amber醯imino-4-butylindoleimine butyrate, N-succinimide-6-m-butyleneimine caproic acid, N_pooprene imino-3-cis Butadiene diimide propionate, N - (9 - ° ° ° base) maleimide, etc. (a3 The compound may be used alone or in combination of two or more. The amount of the compound (a3) used in the synthesis of the [A] copolymer is preferably from 1% by mass to 70% by mass based on 100% by mass of the total monomers used. More preferably, it is 15 mass% to 65 mass%. /〇. By using the compound (a3) in an amount of 10% by mass to 70% by mass, the molecular weight of the copolymer can be easily controlled, and sensitivity can be obtained. A coloring composition that is optimized to a higher level. The method for synthesizing the [A] copolymer may, for example, be a method of polymerizing an (al) compound, a (a2) compound or a (a3) compound by using a radical polymerization bow hair styling agent in the singularity. -19- 201224652 The radical polymerization initiator can be appropriately selected depending on the type of the polymerizable unsaturated compound to be used, and examples thereof include 2,2'-azobisisobutyronitrile and 2,2'-azo. Di-(2,4-dimethylvaleronitrile), 2,2'-azobis-(4-decyloxy-2,4-dimethylvaleronitrile), 4,4'-azobis ( 4-cyanovaleric acid), dimercapto-2,2'-azobis(2-methylpropionate), 2,2'-azobis(4-methoxy-2,4-di An azo compound or the like such as decyl valeronitrile. Among these radical polymerization initiators, 2,2'-azobisisobutyronitrile and 2,2'-azobis(2,4-dioxyl valeronitrile) are preferred. The radical polymerization initiator may be used singly or in combination of two or more. In the above polymerization, the amount of the radical polymerization initiator used is usually 0.1% by mass to 50% by mass, preferably 0.1% by mass to 20% by mass based on 100% by mass of the polymerizable unsaturated compound. Further, in the polymerization of the [A] copolymer, a molecular weight modifier can be used. Examples of the molecular weight modifier include halogenated hydrocarbons such as gas imitation and carbon tetrabromide; n-hexyl mercaptan, n-octyl mercaptan, n-dodecyl mercaptan, and tertiary dodecyl mercaptan. a mercaptan such as thioglycolic acid; a xanthogenate such as didecyl xanthate and diisopropyl xanthate; oleyl olefin, α-mercapto styrene dimer, etc. . The amount of the molecular weight modifier to be used is usually 0.1% by mass to 50% by mass, preferably 0.2% by mass based on 100% by mass based on the total of the (a1) compound, the (a2) compound and the (a.3) compound. % to 16% by mass, more preferably 0.4% by mass to 8% by mass. -20- 201224652 In terms of polymerization temperature, it is usually (TC 15 15 (TC, preferably 50 C to 1 2 0 C. In terms of polymerization time, it is usually 丨〇 minutes to 2 〇 hours, preferably 30 minutes to 6 hours. In terms of the polystyrene equivalent weight average molecular weight (Mw) of the copolymer [A], it is preferably 2χ103~1χι〇5, more preferably 5xl〇3~5xl04. A] The Mw of the total one is in the above specific range, and a sufficient development tolerance of the colored composition can be obtained. At the same time, the residual film ratio of the formed coating film (the ratio of the pattern film remaining properly) can be prevented from decreasing, and it is also good. The shape, heat resistance, and the like of the obtained color pattern are maintained, and a high degree of radiation sensitivity can be maintained to obtain a good pattern shape. In terms of the molecular weight distribution of the [A] copolymer (Mw/M[n), it is preferred. It is 5.0 or less, more preferably 3.0 or less. The pattern shape of the obtained color pattern can be favorably maintained by making the Mw/Mn of the [a] copolymer 5 Å or less. The Mw having such a preferred range is included. And a coloring composition of the [A] copolymer of Mw/Mn, which has high development resistance. In the developing step, development residue does not occur, and a prescribed pattern shape can be easily formed. In addition, the weight average molecular weight (Mw) in the present specification is the following apparatus and conditions, and by gel GPC-101 (Showa Denko Co., Ltd.) GPC-KF-802 804 mobile phase: tetrahydrofuran 201224652 The solvent used in the polymerization for producing the [A] copolymer may, for example, be an alcohol, an ether, a glycol ether, an ethylene glycol alkyl ether acetate, or a diethyl ester. Glycol alkyl ether, propylene glycol monoalkyl ether, propylene glycol monoalkyl ether acetate, propylene glycol monoalkyl ether propionate, aromatic hydrocarbons, ketones, other esters, etc. For example, decyl alcohol, ethanol, benzyl alcohol, 2-phenylethanol, 3-phenyl-1-propanol, etc.; and examples of the ethers include cyclic ethers, glycol ethers, and ethylene glycol alkyl ethers. Acetate, diethylene glycol alkyl ether, propylene glycol monoalkyl ether, propylene glycol monoalkyl ether acetate, C The alcohol monoalkyl ether propionate or the like. Examples of the cyclic ethers include tetrahydrofuran. Examples of the glycol ethers include ethylene glycol monomethyl ether and ethylene glycol monoethyl ether. In the case of ethylene glycol alkyl ether acetate, for example, methyl cyproterone acetate, ethyl cyproterone acetate, ethylene glycol monobutyl ether acetate, ethylene glycol single can be cited. Ethyl ether acetate, etc. Examples of the diethylene glycol alkyl ether include diethylene glycol monodecyl ether, diethylene glycol monoethyl ether, diethylene glycol didecyl ether, and Ethylene glycol diethyl ether, diethylene glycol ethyl methyl ether, and the like. The propylene glycol monoalkyl ether may, for example, be propylene glycol monodecyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether or propylene glycol monobutyl ether. Examples of the propylene glycol monoalkyl ether acetate include propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, and propylene glycol monobutyl ether acetate. Wait. -22- 201224652 In the case of propylene glycol monoalkyl ether propionate, for example, alcohol monodecyl ether propionate, propylene glycol monoethyl ether propionate, propylene dipropyl ether propionate, propylene glycol monobutyl group can be cited. Ether propionate and the like. Examples of the aromatic hydrocarbons include, for example, anthracene and quinone ketones, and examples thereof include mercaptoethyl ketone and cyclohexyl 4-hydroxy-4-indolyl-2-pentanone. Examples of other esters include decyl acetate, ethyl ester, propyl acetate, butyl acetate, ethyl 2-hydroxypropionate, 2-hydroxyl methacrylate, 2-hydroxy-2- Ethyl mercaptopropionate, ethyl hydroxyacetate, butyl hydroxyacetate, decyl lactate, propyl lactate, butyl lactate, methyl 3-hydroxypropionate, 3-hydroxypropyl ester, 3- Propyl hydroxypropionate, butyl 3-hydroxypropionate, decyl 2-hydroxy-3-butyrate, decyl methoxyacetate, ethyl decyloxyacetate, propyl acetate, butyl methoxyacetate Ethyl ethoxyacetate, ethyl acetoacetate, propyl ethoxyacetate, butyl ethoxyacetate, methyl propionate, ethyl propoxyacetate, propyl propoxyacetate, butyl propionate , methyl butoxyacetate, ethyl butoxide, propyl butyrate, butyl butoxyacetate, methyl 2-methoxypropionate, ethyl oxypropionate, 2-methoxypropane Acid propyl ester, 2-methoxyoxypropionic acid methyl 2-ethoxypropionate, ethyl 2-ethoxypropionate, 2-ethoxypropyl ester, butyl 2-ethoxypropionate, 2-butoxy propionate, 2-butoxy Ethyl acetate, propyl 2-butoxypropionate, butyl 2-butoxypropionate, methyl 3-propylpropionate, ethyl 3-methoxypropionate, 3-methoxypropionic acid 3-butyl methoxypropionate, methyl 3-ethoxypropionate, 3-ethoxypropyl ester, propyl 3-ethoxypropionate, butyl 3-ethoxypropionate, 3- Propoxypropanediol is monovalent.酉, 酸乙^ -2-酉' ester, acid ethoxylated oxyoxyoxy 2-methyl ester, acid propyl propionate, acid ethyl propyl-23- 201224652 acid Methyl ester, 3 bis-propionic acid butyl 1 propyl propionate, 3 - propoxy propionic acid propyl S, 3 · dioxy 3-butoxy AJ butoxy propionic acid methyl vinegar, 3 · butoxy Ethyl propyl propionate, propyl lactone, butyl 3-butoxypropionate, and the like. The coloring agent > and the coloring agent are not particularly limited in color as long as they have coloring property:: depending on the coloring pattern and the use of the color calendering sheet, natural pigment enamel is appropriately selected as a coloring agent, for example, for example, Any of the pigments, dyes, and dyes, but because of the coloring map, the high color, the color of the tea, the color of the tea, the color, the twist, the contrast, etc.乐 Music, better for dyes. The pigment and/or the pigment may be an organic pigment or a kind of organic pigment, and examples thereof may be exemplified.

Society of Dyers and c〇1〇u / chromophore bow | (CM· ; The compound of The. Specifically, it can be cited as an organic pigment classified as a pigment (C.I.). ', such a color cable C.I·Pigment Yellow 12, CM Pigment Yellow 13, Pigment Yellow 17, C·1. Pigment Yellow 20, C I Fine C.1. Pigment Yellow 14, C.I. Ο 1 P T • Unexpected! 1 / ..Pigment Yellow 5 5, c · I · Pigment Yellow 8 3, ,, c.1. Pigment Yellow Pigment Yellow 109, CI Pigment Yellow 11〇, c ι彦 C; .1·Pig Yellow 93, CI Yellow 139, CI pigment yellow 15 〇, cj pigment yellow " 1 material steam 138, cI pigment CI · pigment yellow 155, d pigment yellow 166, 53, CI pigment yellow 154, pigment yellow 180, CI pigment yellow 211; 168, CI c·1. Pigment Orange 5, ci Pigment Orange 13 Pigment Orange 24, CI·Pigment Orange 34, c Xia Yan; 1. Pigment Orange 14, CI 38 CI Pigment Orange 4〇, Cl Pigment Dial 4; 36, CI Pigment Orange

C.1·Pigment Orange 46, CI -24- 201224652 Pigment Orange 49, CI Pigment Orange 61, CI Pigment Orange 64, CI Pigment Orange 68, CI Pigment Orange 70, CI Pigment Orange 71, CI Pigment Orange 72, CI Pigment Orange 73, CI Pigment Orange 74; CI Pigment Red 1, CI Pigment Red 2, CI Pigment Red 5, CI Pigment Red 1 7, C · I. Pigment Red 3 1, C. I · Pigment Red 3 2, CI Pigment Red 4 1. CI Pigment Red 122, CI Pigment Red 123, CI Pigment Red 144, CI Pigment Red 149, CI Pigment Red 166, C丄 Pigment Red 168, CI Pigment Red 170, (:.1. Pigment Red 171, (:. 1. Pigment Red 175, (: 1. Pigment Red 176, CI Pigment Red 177, CI Pigment Red 178, CI Pigment Red 179, CI Pigment Red 180, CI Pigment Red 185, CI Pigment Red 187, CI Pigment Red 202, CI Pigment Red 206, CI Pigment Red 207, CI Pigment Red 209, CI Pigment Red 214, CI·Pigment Red 220, CI·Pigment Red 221, CI Pigment Red 224, CI Pigment Red 242, CI Pigment Red 243, CI Pigment Red 254, CI·Pigment Red 255, CI Pigment Red 262, CI Pigment Red 264, CI Pigment Red 272; CI Pigment Violet 1, CI Pigment Violet 19, C. I. Pigment Violet 23, CI Pigment Violet 29, CI Pigment Violet 32, CI Pigment Violet 36, CI Pigment Violet 38; C_I. Pigment Blue 15, CI Pigment Blue 15:3, CI Pigment Blue 15:4, CI Pigment Blue 15 : 6, CI Pigment Blue 60, CI Pigment Blue 80; CI Pigment Green 7, CI Pigment Green 36, CI Pigment Green 58; CI Pigment Brown 23, CI Pigment Brown 25; CI Pigment Black 1, CI Pigment Black 7, etc. The inorganic pigment may, for example, be titanium oxide, bismuth sulphate, physic acid, zinc oxide, sulfuric acid, chrome yellow, zinc yellow, iron oxide (red-25-201224652 color iron oxide (III)), Cadmium red, ultramarine blue, Prussian blue, chrome oxide green, cobalt green, brown earth, titanium black, synthetic iron black, carbon black, etc. In terms of the chemical structure of the dye, triphenyl decane, anthracene, a benzylidene group, a sheep heterozygous type, a cyanine type, a phenothiazine type, a pyrrolopyrazole azo methine group, a xanthene type, a phthalocyanine type, a benzopyran type, an indigo type, etc. Preferred are dyes of pyrazole azo, anilino azo, pyrazolyl triazole azo, pyridone azo, anthracene, anthrapyridoneAs the [B] coloring agent, a known dye can be used as long as it is soluble in an organic solvent, and examples thereof include an oil-soluble dye, an acid dye or a derivative thereof, a direct dye, a mordant dye, and the like. As the CI oil-soluble dye, for example, C_I. Solvent Yellow 4, CI Solvent Yellow 14, CI Solvent Yellow 15, CI Solvent Yellow 23, CI Solvent Yellow 24, CI Solvent Yellow 38, CI Solvent Yellow 62, CI Solvent Yellow 63, CI Solvent Yellow 68, CI Solvent Yellow 82, CI Solvent Yellow 88, CI Solvent Yellow 94, CI Solvent Yellow 98, CI Solvent Yellow 99, CI Solvent Yellow 162, CI Solvent Yellow 179; CI Solvent Red 45, CI Solvent Red 49, CI Solvent Red 125, CI Solvent Red 130; CI Solvent Orange 2, · C · I. Solvent Dial 7, C · I. Solvent Lamp 11, CI Solvent Orange 15, CI Solvent Orange 26, CI Solvent Orange 56; CI Solvent Blue 35, CI Solvent Blue 37, CI Solvent 59, CI Solvent 67; C · I · Solvent Green 1, CI Solvent Green 3, CI Solvent Green 4, CI Solvent Green 5, CI Solvent Green 7, CI Solvent Green 28 , CI Solvent Green 29, -26- 201224652 C. I · Solvent Green 3 2, C · I. Solvent Green 3 3, CI Solvent Green 3 4, CI Solvent Green 35, etc. As the CI acid dye, for example, CI acid yellow 1, CI acid yellow 3, CI acid yellow 7, CI acid yellow 9, CI acid yellow 1, CI acid yellow 17, CI acid yellow 23, CI acid yellow can be cited. 25, CI Acid Yellow 29, CI Acid Yellow 34, CI Acid Yellow 36, CI Acid Yellow 38, CI Acid Yellow 40, CI Acid Yellow 42, CI Acid Yellow 54, CI Acid Yellow 65, CI Acid Yellow 72, C Acidity Yellow 73, CI Acid Yellow 76, CI Acid Yellow 79, CI Acid Yellow 98, CI Acid Yellow 99, CI Acid Yellow 1 1 1 , CI Acid Yellow 1 12, CI Acid Yellow 113, CI Acid Yellow 114, CI Acid Yellow 1 16. CI Acid Yellow 1 19, CI Acid Yellow 123, CI Acid Yellow 128, CI Acid Yellow 134, CI Acid Yellow 1 3 5, C. I · Acid Yellow 1 3 8 , C. I · Acid Yellow 1 3 9 C. I _ Acid Yellow 140, CI Acid Yellow 144, CI Acid Yellow 150, CI Acid Yellow 155, CI Acid Yellow 157, CI Acid Yellow 160, CI Acid Yellow 16 Bu CI·Acid Yellow 163, CI Acid Yellow 168, CI Acid Yellow 169, CI Acid Yellow 172, CI Acid Yellow 177, CI Acid Yellow 178, CI·Acid Yellow 179, CI Acid Yellow 184, C. I. Acid Yellow 190, CI Acid Yellow 193, CI Acid Yellow 196, CI Acid Yellow 197, CI Acid Yellow 199, CI Acid Yellow 202, CI Acid Yellow 203, CI Acid Yellow 204, CI Acid Yellow 205, CI Acid Yellow 207 , CI Acid Yellow 212, CI Acid Yellow 214, CI Acid Yellow 220, CI Acid Yellow 221, CI·Acid Yellow 228, CI Acid Yellow 230, CI Acid Yellow 232, CI Acid Yellow 235, CI Acid Yellow 238, CI Acid Yellow 240, CI acid yellow 242, CI acid yellow 243, CI acid yellow 251; -27- 201224652

Valifast Yellow 1101, Valifast Yellow 1109, Valifast Yellow 1151' Valifast Yellow 3 1 08, Valifast Yellow 3 1 20, Valifast Yellow 3130, Valifast Yellow 3150, Valifast Yellow 3170, Valifast Yellow 4120; CI Acid Red 1, CI Acid Red 4, CI Acid Red 8, CI Acid Red 14, CI Acid Red 17, CI Acid Red 18, CI Acid Red 26, CI Acid Red 27, CI Acid Red 29, CI Acid Red 3 1 , CI Acid Red 34, CI Acid Red 35 , CI Acid Red 37, CI Acid Red 42, CI Acid Red 44, CI Acid Red 50, CI Acid Red 51, CI Acid Red 52, CI Acid Red 57, CI Acid Red 66, CI Acid Red 73, CI Acid Red 80 , CI Acid Red 87, CI Acid Red 88, CI Acid Red 91, CI Acid Red 92, CI Acid Red 94, CI Acid Red 97, CI Acid Red 103, CI Acid Red 111, CI Acid Red 114, CI Acid Red 129 , CI Acid Red 133, CI Acid Red 134, CI Acid Red 138, CI Acid Red 143, CI Acid Red 145, CI Acid Red 150, (: 1. Acid Red 151, (:.1. Acid Red 158, ( :.1. Acid red 176, (:.1. Acid red 182, CI acid red 1 83, CI acid red 198, CI acid red 206, CI acid red 211, CI acid red 215, CI acid red 216, CI acid red 217, CI acid red 227, CI acid red 228, CI acid red 249, CI acid red 252, CI Acid Red 257, CI Acid Red 258, CI Acid Red 260, CI Acid Red 26 Bu CI Acid Red 266, CI Acid Red 268, CI Acid Red 270, CI Acid Red 274, CI Acid Red 277, CI Acid Red 280, CI Acid Red 281, CI Acid Red 195, CI Acid Red 308, CI Acid Red 312, CI Acid Red 315, CI Acid Red 3 16, CI Acid Red 339, CI Acid Red 341, CI -28- 201224652 Acid Red 345, CI Acid Red 346 'CU Acid Red 349, c丨 Acid Red 382, CI Acid Red 383, ^• Acid Red 394, c丄 Acid Red 4〇 Bu CI Acid Red 412, C丄 Acid Red 417, c τ Acid Red 4i8, c丄西夂性红 4 2 2, C. I · Acid Red 4 2 6 ; CI Acid Orange 6, C·〗. Acid Orange 7, c丄 Acid Orange 8, c丄 Acid Orange 10, CI Acid Orange 丨 2, CI Acid Dial 26, CI Acid Orange 50, CI Acid Orange 51, CL Acid Orange 52, C I. Acid Orange 56, c-Citrate Sex Orange 62, CI Acid Orange 63, c·〗·Acid Orange 64, CI Acid Orange 74, CI Acid Orange 75, CL Acid Orange 94, c丄 Acid Orange 95, c丄 Acid Orange 107, CI·Acid Orange 108, ^•Acid Orange 169, c〗 Acid Orange 173; ^ CI Acid Blue i, c丄 Acid Blue 7, C] Acid Blue 9, C] Acid Blue 15, CI·Acid Blue 18, CI Acid Blue 23, C_I. Acidic Blue 25, CI Acid Blue 27, (M• Acid Blue 29, CI Acid Blue 4〇, c丄 Acid Blue 42, CI Acid Blue 45, CI Acid Blue 51, d• Acid Blue 62, CI Acid Blue 70, CI Acidity Blue 74, CI Acid Blue 80, cI Acid Blue 83, CI·Acid Blue 86, CI Acid Blue 87, CI Acid Blue 90, CI Acid Blue 92, CI Acid Blue 96, CI Acid Blue i〇3, CI Acid Blue 1 0 8 ' C · I, Acid Blue 11 2. CI Acid Blue 11 3, C · I. Acid Blue 1 2 0, C · I. Acid Blue 1 2 9 , C. I · Acid Blue 1 3 8 , C . I · Acid Blue 1 4 7 , CI Acid Blue 150 , CI Acid Blue 158 , CI Acid Blue 171 , CI · Acid Blue 1 8 2 , C _ I. Acid Blue 1 9 2, C. I · Acid Blue 2 1 0 , CI Acid Blue 242, CI Acid Blue 249, CI Acid Blue 2 43. CI Acid Blue 256, CI Acid Blue 2 5 9 , C _ I. Acid Blue 2 6 7 , C. I · Acid Blue 2 7 8 , C · I. Acid Blue 2 8 0, C · I. Acid Blue 2 8 5, CI Acid Blue 2 9 0, CI Acid Blue 296, CI Acid Blue 315, C_I. Acid Blue 324, CI· Acid Blue 335, CI Acid Blue 340; -29- 201224652 (:.1. Acid Violet 6 Ugly, (:.1. Acid Violet 7, (:.1. Acid Violet 9, (:.1. Acid Violet 17, CI Acid Violet 19, CI Acid Violet 49; CI Acid Green 1, CI Acid Green 3, CI Acid Green 5, CI Acid Green 9, CI Acid Green 16, CI Acid Green 25, CI Acid Green 27, CI Acid Green 50, CI Acid Green 58, CI Acid Green 63, CI Acid Green 65, CI Acid Green 80, CI Acid Green 104, CI Acid Green 105, CI Acid Green 106, CI Acid Green 109; CI Acid Black 24 and other dyes. For the CI direct dye, for example, 〇.1. Direct Yellow 2, (:.1. Direct Yellow 33, (:.1. Direct Yellow 34, (:.1. Direct Yellow 35, CI Direct Yellow 38,) CI Direct Yellow 39, C_I. Direct Yellow 43, CI Direct Yellow 47, CI Direct Yellow 50, CI Direct Yellow 54, CI Direct Yellow 58, CI Direct Yellow 68, CI Direct Yellow 69, CI Direct Yellow 70, CI Direct Yellow 71 , CI Direct Yellow 86, CI. Direct Yellow 93, CI Direct Yellow 94, CI Direct Yellow 95, C_I. Direct Yellow 98, CI Direct Yellow 102, CI Direct Yellow 108, CI·Direct Yellow 109, CI Direct Yellow 129, CI Direct yellow 136, CI direct yellow 138, CI direct yellow 141; CI direct red 79, CI direct red 82, CI direct red 83, CI direct red 84, CI direct red 91, CI direct red 92, CI direct red 96, CI Direct red 97, CI direct red 98, CI direct red 99, CI direct red 105, CI direct red 106, CI direct red 107, CI direct red 172, CI direct red 173, CI direct red 176, CI direct red 177, ( :.1. Direct red 179, (:.1. Direct red 181, (:.1. Direct red 182, (:.1. Direct red 184, CI straight) Red 204, CI Direct Red 207, CI Direct Red 21 Bu CI Direct Red 213, CI Direct Red 218, CI Direct Red 220, -30- 201224652 CI Direct Red 221, CI Direct Red 222, CI Direct Red 232, CI Direct Red 233, C.I_direct red 234, CI direct red 241, CI direct red 243, CI direct red 246, CI direct red 250; C.I_ direct dial 34, CI direct orange 39, CI direct orange 41, CI direct Orange 46, CI Direct Orange 50, cI Direct Orange 52, CI Direct Orange 56, CI Direct Dial 57, CI Direct Orange 61, CI Direct Orange 64, CI Direct Orange 65, C'I. Direct Orange 68, cI Direct Orange 70 , CI Direct Orange 96, CI Direct Orange 97, CI Direct Orange 106, CI Direct Orange 1〇7; CI Direct Blue 57, CI Direct Blue 77, CI Direct Blue 80, CI Direct Blue 81, C.I_ Direct Blue 84 , CI Direct Blue 85, CI Direct Blue 86, C.I_ Direct Blue 90, C_I. Direct Blue 93, CI Direct Blue 94, CI Direct Blue 95, CI Direct Blue 97, CI Direct Blue 98, C_I. Direct Blue 99 , CI Direct Blue 1〇〇, cI Direct Blue 101, CI Direct Blue 106' CI Direct Blue 107, CI Direct Blue 1〇8, CI Direct Blue 109, CI Direct Blue 113, CI Direct Blue 114, CI Direct Blue 115, CI Direct Blue 117, (:.1. Direct Blue 119, (:.1. Direct Blue 137, (:.1. Direct Blue 149, CI Direct Blue 150) , CI Direct Blue 153, CI Direct Blue 155, CI Direct Blue 156, CI Direct Blue 158, C_I· Direct Blue 159, CI Direct Blue 160, CI Direct Blue 16 Bu CI Direct Blue 162, CI Direct Blue 163, CI Direct Blue 164, CI Direct Blue 166, CI Direct Blue 167, CI Direct Blue 170, CI Direct Blue 171, CI Direct Blue 172, CI Direct Blue 173, CI Direct Blue 188, CI Direct Blue 189, CI Direct Blue 190, C_I_ Direct Blue 192, CI Direct Blue 193, CI Direct Blue 194, CI Direct Blue 196, CI Direct Blue 198, CI Direct Blue 199, CI Direct Blue 200, CI Direct Blue 207, CI Direct Blue 209, CI Direct Blue 210, -3 1 - 201224652 CI Direct Blue 212, CI Direct Blue 213, CI Direct Blue 214, CI Direct Blue 222, CI Direct Blue 228, CI Direct Blue 229, CI Direct Blue 237, CI Direct Blue 238, C.I_ Direct Blue 242 , CI Direct Blue 243, CI Direct Blue 244, CI Direct Blue 245, CI Direct Blue 247, CI Direct Blue 248, C.I_ Direct Blue 250, CI Direct Blue 251, CI Direct Blue 252, (:.1. Direct Blue 256' (:.1. Direct Blue 257' (:.1. Direct Blue 259, CI Direct Blue 260, CI Direct Blue 268, CI Direct Blue 274, CI Direct Blue 275, CI Direct Blue 293; C_I. Direct Purple 47, CI Direct Violet 52, CI Direct Purple Direct Violet 59, CI Direct Violet 60 CM. Direct purple 65, CI direct purple 66 C.I_ Direct Ί·, 79, CI direct purple 80, cI direct purple 81, Cl direct purple 82, CI direct purple 84, CI direct purple w'cj • direct purple 9 〇, C丄 direct purple 93, αι. direct purple 95, c” direct purple%, c direct purple 103, CI·direct purple 1〇4; ' · CI direct green 25, CI · direct green 27, c ! direct green η,. 】 Direct Green 32, CL Direct Green 34, cm. Direct Green & c · 63, C丄 Direct Green 65, c丄 Direct Green 66. Pick, Pro LI. Direct Green 67, C τ Direct Green 68, C.I _ Direct Green 69, CI Direct ·. And money green 7 2, c I said pile pull 77, CI direct green 79, CU • direct green 82 and so on. For the C _ I. mediated dyes, for example, CI mord yellow 5, CI mord yellow 8, c T 丄 Gan, Jiuyi hail, .1. mordant 10, CI pull 16, C. I_ mediated yellow 2〇, C_I· mordant dye, ,, 26, C;.I·media Biyin CI mordant yellow 31, c 丄 mediated yellow 33, c. fruit only 3 〇, screw dye 畀 4 2, CT pull , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , 201224652 CI mordant red 1, CI mordant red 2, CI mordant red 3, CI mordant red 4, CI mordant red 9, CI mordant red 11, CI mordant red 12, CI mordant red 14, CI mordant red 17, CI mordant red 18 , CI mordant red 19, CI mordant red 22, CI mordant red 23, CI mordant red 24, CI mordant red 25, CI mordant red 26, CI mordant red 30, CI mordant red 32, CI mordant red 33, CI mordant red 36 , CI mordant red 37, CI mordant red 38, CI mordant red 39, CI mordant red 41, CI mordant red 43, CI mordant red 45, CI mordant red 46, CI mordant red 48, CI mordant red 53, CI mordant red 56 CI Phyto-staining red 63, CI mordant red 71, CI mordant red 74, CI mordant red 85, CI mordant red 86, CI mordant red 88, CI mordant red 90, CI mordant red 94, CI mordant red 95; CI mordant dial 3 CI mordant orange 4, CI mordant orange 5, CI mordant orange 8, CI mordant orange 12, CI mordant orange 13, CI mordant orange 14, CI mordant dial 20, CI mordant orange 21, CI mordant dial 23, CI mordant orange 24, CI mordant orange 28, CI mordant orange 29, CI mordant orange 32, CI mordant dial 34, CI mordant dial 35, CI mordant dial 36, CI mordant orange 37, CI mordant orange 42, CI mordant orange 43, CI mordant orange 47, CI mordant orange 48; CI mord blue 1, CI mord blue 2, CI mord blue 3, CI mord blue 7, CI mord blue 8, CI mord blue 9, CI mord blue 12, CI mord blue 13, CI mord blue 15, CI mord blue 16, CI mord blue 19, CI mord blue 20, CI mord blue 21, CI mord blue 22, CI mord blue 23, CI mord blue 24, CI mord blue 26, CI mord blue 30, CI mord blue 31, CI mord blue 32, CI mord blue 39, CI -33- 201224652 mordant blue 40, CI mord blue 41, CI Dyeing Blue 43, CI mord blue 44, CI mord blue 48, CI mord blue 49, CI mord blue 53, CI mord blue 61, CI mord blue 74, CI mord blue 77, CI mord blue 83, CI mord blue 84; CI Medicament Violet 1, CI mordant purple 2, CI mordant purple 4, CI mordant purple 5, CI mordant purple 7, CI mordant purple 14, CI mordant purple 22, CI mordant purple 24, CI mordant purple 30, CI mordant purple 31, CI Phyto-staining purple 32, CI mordant purple 37, CI mordant purple 40, CI mordant purple 41, CI mordant purple 44, CI mordant purple 45, CI mordant purple 47, CI mordant purple 48, CI mordant purple 53, CI mordant purple 58 CI mord green 1, CI mord green 3, CI mord green 4, CI mord green 5, CI mord green 10, CI mord green 15, CI mord green 19, CI mord green 26, CI mord green 29, CI mord green 33 , CI mord green 34, CI mord green 35, CI mord green 41, CI mord green 43, CI mord green 5 3 and so on. The content of the [B] coloring agent is preferably 1 part by mass to 400 parts by mass, more preferably 1 part by mass to 300 parts by mass, per 100 parts by mass of the [A] epoxy compound. By setting the content of the [B] coloring agent to 1 part by mass to 400 parts by mass, the alkali developability of the colored composition, the heat resistance of the pixel, the solvent resistance, and the coloring pattern and color filter can be achieved at a high level. High brightness and high contrast of the light sheet. <[C] Compound> The compound [C] is not particularly limited as long as it is a compound having a hydroxyl group or a carboxyl group. The compound [C] is preferably a compound which may contain a [D] amine compound, and is preferably selected from the above formulas (1) and (2) from the viewpoint of appropriately forming an inclusion compound described later. Each m. At least one of the compounds in the group formed by the person and the person represented. In the above formula (1), X is a single bond, a methylene group or a carbon atom number "alkyl group. R to R8' are each independently a group of ",", 2 to 6: a group, a (four) group, and a number of carbon atoms, and a phenyl group which may have a substituent. The above formula (= base, or 1~12 of alkane, magnetic, 1 MTR is the anti-atomic number of the stone J, and the anti-atomic number of the alley stone is 1~i 2 as the A, f γ batch main thiol The nitro group or the hydroxy group. The number of carbon atoms represented by X is exemplified by, for example, an oxime group of an ethylene group, a W propylene group, etc. The above-mentioned Ri to r8 and the carbon number of the surface are 1 to 12 Examples of the base group of the alkylene group 12 include, for example, an anthracenyl group, a butyl group, etc. The above-mentioned R1 to r8 9 subunits are 碳~12I K and a carbon propropoxy group represented by R, etc. The compound represented by the formula (1) is preferably represented by the above formula (I 1). The compound represented by the above formula (1) is a force of the above formula. The four kinds of compounds with better symmetry and better symmetry can be considered as a package that can be used by you. Therefore, the storage stability is further improved and the hardening is carried out at a low temperature. The tetraphenol compound represented by V _ U can be exemplified by hydroxymei cage 'Dun 2, 2 - 4 (4-phenyl) phenyl, U, 2, 2 - 4 (3 fluorenyl-4) - work base) ethane , 1 alkane, 丨丨2 i,1,2,2·tetrakis(3,5-dimercapto-4-hydroxyphenyl)ethylenedioxide I via gas I phenyl), Y, 2, 2-tetrakis (3,5-burning, 丨土丞), Ethylene, bismuth, 2,2-tetrakis(3-bromo-4-hydroxyphenyl)ethene, ternary tau, lJ,5-monobromo-4-hydroxy Phenyl) ethane, 1,1,2,2-tetrakis(3-tert-butyl-4, phenyl), Ethylene, 1,1,2,2·4 (3,5_II·3) Butyl-35- 201224652 ;Ί=)5B-burning, U,2,2,-Fluorine-4, phenyl) Ethylene, Dioxa 2,2·4 (3,5-dimethoxy- 4-Phenylbenzene"",, '(3-chloro-5-methyl-4-hydroxyphenyl) ethyl, 1,1,2,2-tetra (3-bromo-5-methyl-4) · methoxy-----p-phenyl 5-methyl-4-phenylphenyl)ethyl, (a) secondary butyl ^ A w . t 〇,,, 2-tetra (3-虱_5 -Bromo-4-hydroxyindole 2,24 (3,6,5-phenyl- 4,pyridylphenyl), phenylene; phenyl = · benzyl 4' phenyl) 1,3,3-four (4, basic phantom,], ...-tetra (3-methyl-4, fluorenyl 4 phenyl) propyl, i-U, 3, 3_4 ( 3 winter 4_ via base phenyl) propane burn, c-burn, one (3 · benzene ... base benzene magic: ^ ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Heart = basic base) B, YW, UW. IV (3_3 butyl _4. phenyl) propyl 1 丨, 1,3,3-tetra (3,5-di-tertiary butyl- 4-Phenylphenyl)propane, = '"(4-phenylphenyl)butane, methyl-4)-based butane, 1,M,4-tetrakis(3,5.dimethyl _4_hydroxyphenyl)butane, H,4,4-tetrakis(3-aza-4-phenylphenyl)din, ^^-tetrazol-di-di-4-ylphenyl)butane, Methoxy ice via butyryl) butane, tetrakis(3,5.dimethoxy-4-phenyl)butane, tetrakis(3-bromo-4-perphenyl)butane, 3,5_二漠_4-Phenylphenyl) butadiene, 1,1,4,4·tetra(3·tris-butyl-4-yl-phenyl)butane, 1,1,4,4 - Tetrakis(3,5-di-tris-butyl-4-hydroxyphenyl)butane and the like. -36-201224652 When the inclusion compound is described at room temperature, the coloring group emits a hardening accelerator: Γ is more excellent' and is easy to heat when heated. b 乂 为 is preferably 1,1,2,2-tetrakis(4-hydroxyphenyl) B as a compound represented by the above formula, _) jin, for example, 5-crosyl dicarboxylic acid, 5 pelt ^ ^ 尨 本 本 本 本 本 5 5 5 5 5 5 5 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本Acid, 4-methylmethine _ m tert-dicarboxylic acid, 4-methoxy, isophthalic acid, and the like. /, Zhong's car father is 5 - stone teeth and it is poor - homogeneous base between - formic acid, 5-hydroxyisophthalic acid. The [α] α substance may be used singly or in combination of two or more. The content of the compound [c] in the coloring composition is from 1 part by mass to 10 parts by mass, more preferably from 0.2 part by mass to 5% by mass based on 10 parts by mass of the epoxy compound. It is preferably 1 to 2 times more than the [D] amine compound described later. σ <[D]amine compound> As the [D] amine compound, the right name is not particularly limited, but it is preferably an amine compound which can be contained in the compound [c], more preferably an amino acid compound or a vegetable dish. Compound. Among them, the rice saliva compound is easily preserved at room temperature because of the easy to be [C]==, and the compound is excellent in reactivity with the epoxy group. This contributes to the low-temperature hardening of 20 (TC or less. (There are, for example, the compound for the bite compound, etc.), for example, the following compounds, etc. -3(3) represents -3 7-201224652 d10 r\^n I V -R12 d1An (3) R11 | R13 In the above formula (3), R1() to R13 are each independently a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a naphthyl group, an anthracenyl group, a phenanthryl group, and 9- a base group, a halogen atom, an alkoxy group having 1 to 6 carbon atoms, a phenyl group, or a phenyl group which may be substituted with a halogen atom. In the case of a 17-molecular compound, for example, '^米α sits, 2 - mercapto. Miva, 2-ethyl-beta-salt, 2-isopropylidene. Rice. Sit, 2-n-propyl π m. Sit, 2-undecyl-1 Η-imidazole, 2-71 Alkyl-1 Η-imidazole, 1,2-dimethylimidazole, 2-ethyl-4-mercaptoimidazole, 2-phenyl-1 fluorene-imidazole, 4-mercapto-2-phenyl-1 fluorene-imidazole, 2-phenyl-4-methylimidazole, 1-benzyl-2-methylimidazole, 1-cyanoethyl-2-mercaptoimidazole, 1-cyanoethyl-2-ethyl-4-anthracene Imidazole, 1-cyanoethyl-2-undecylimidazole, 1-cyanoethyl-2-phenylimidazole, 2,4-diamino-indenyl group, sit-base - (1' )]-Ethyl-S _ II Well, 2,4-diamino-6-(2'-11x)-based σ-mercapto-)-ethyl-s-secondary, 2,4-diamino-6-[2' - Ethyl-4-0 m. Sodium-(1')]-ethyl-s-dioxin, 2,4-diamino-6-[2'-mercaptoimidazolyl-(1')] -ethyl-s-triterpene isocyanuric acid adduct, 2-phenylimidazole isocyanuric acid adduct, 2-mercaptoimidazole isocyanuric acid adduct, 2-phenyl-4,5 -dihydroxydecyl imidazole, 2-phenyl-4-methyl-5-hydroxymethylimidazole, 1-cyanoethyl-2-phenyl-4,5-bis(2-cyanoethoxy) Methylimidazole, 1-benzyl-2-phenylimidazole rust trimellitate, etc. Among them, 2-phenyl-4-methyl-5-hydroxyl group which is highly reactive and contains excellent stability is preferred. Isoimidazole, 2-methylimidazole, 2-ethyl-4-methyl-mouth m-sit. -38- 201224652 The above-mentioned rice-salt compound has more than one carbon atom of 1 to 0. Substituent. This kind of taste, because it can be stably contained, does not adversely affect the storage stability of the colored composition, A, and is excellent in responsiveness due to small steric hindrance. In containment collapse In the case of the above-mentioned rice-containing compound having one or more carbon A a & ', thousands of substituents of 1 to 6, 'for example, 2-methylimidazole, 2-stupid The taste of the substituent of the base beer. Sitting compound; special, has a carbon number of 1~6 2-ethyl-4-mercaptoimidazole, -yl-5-pyridylmethyl^ sit and have two in one An imidazole compound of sulphate methyl sulphate, 2 phenyl-4-methyl, and the like. The number of slave atoms is! Substituents of ～6 For the benzimidazole compound, a compound or the like which can be listed is listed. The cow is, for example, the following formula (4) (4) (ri4^Qcv^

In the above formula (4), Ri4 to Rl6 have a number of Λ 1 κ, each of which is a hydrogen atom, a carbon group having a number of 1 to 6, a naphthyl group, an onion-based group, and a ^^m-7 group. a 9-3⁄4 group, a halogen/, and an alkoxy group having a sub-number of 1 to fluorene, a phenyl group, or a substituted stupid group. Alternatively, the original tooth - Π1 may be an integer 0 of 0 to 4 and * a plurality of R14 may be phase η, and ^ π may be the same when nu is plural, or may be different. For the present imidazole compound, there may be mentioned imidazole, 4-methylbenzimidazole such as 2-methanemethylbenzazole, 6-benzoindole-39-201224652, 7-T-benzimidazole, 2-A Benzyl-6-methylbenzene..., phenylphenyl benzoate, m-f-benzophenone, 2-ethylidene-methylbenzoic acid = benzene-flavored saliva, 2-ethyl-5-methylbenzene咪 等 ' 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑 咪唑The benzoxanthene compound, preferably having a number of substituents of 1 to 6, is preferably a benzoxanthene compound. This smell. Since the compound is S, the storage stability of the coloring composition is not produced, and since the steric hindrance is small, the reactivity is excellent, and the low-temperature curability can be exhibited at the time of collapse. In the above, the one or more carbon atoms having a carbon number of 1 to 6 are taken. The compound may, for example, be benzimidazole methyl-6-mercaptobenzimidazole, 2-mercapto-5-methylbenzene having a substituent of 2 to phenylbenzene and having 1 to 6 carbon atoms. The cumamimidazole compound [D] amine compound having y substituents having 1 to 6 carbon atoms may be used singly or in combination of two or more. The content of the [D] amine compound in the coloring composition is 1 part by mass of the [A] cyclic hydrazine compound, preferably 0.05 psi, more preferably 〇丨 part by mass to 2.5 parts by mass, and is compatible. The article ' is preferably about 0.5 times to about 丨 times. Package, 2-methyl 2-methyl-5-yl-6-ethyl-ethylbenzoyl qualitative and hard squat, 2-upper carbon atom is stable enough to contain defects in the imidazole containing the collapse group Equivalent compound; 2 - etc. have two. The above is mixed, and the relative amount is ~5 mass. For [C]-40-201224652 <encapsulated compound> In the colored composition t, the comparative component is contained by the [c] compound. In the φ Λ 4 coloring composition of at least one amine compound of ▲# is a [D] amine compound, by forming [Dl, the accompanying compound can be included in the inclusion stability and C ^ is contained as a compound containing [C] [2 coats coexist. The method of 曰丄 = compound can be exemplified, and there is no specific method or the like. In the above-mentioned Japanese Patent Publication No. Hei. No. 071449, the coloring composition is viscous. One or more of the [D] amine compounds are included in the compound [C], ^, m, θ ^ ^ It is prepared by mixing with [Α] epoxy compound and colorant. Pepper ίβ] ^ . According to the above steps, it is possible to efficiently produce a coloring composition 16 of a human-containing compound. The seven-containing content is formed by pre-forming the inclusion of a ^ ^ ^ ^ σ, and is included in the coloring composition as the content of the splicing compound in the coloring composition, relative to the "epoxy compound" 100 parts by mass, seat, L], preferably 0.1 parts by mass to 10 parts by mass, more preferably 0.2 parts by mass to 5 parts of Zengfan #贝里仿> 质份. By making the proportion of the inclusion compound (Μ质量质量份至10质量份, the storage stability of the colored rented product and the hardening of the cured film can be promoted at a high level. <[Ε] polymerizable compound> Further, the [Ε] polymerizable compound is contained. The coloring composition further contains a [Ε] polymerizable compound, and a color filter which is more excellent in heat resistance and solvent resistance can be obtained even at a low exposure amount. The term "polymerizable compound having an ethylenically unsaturated bond" is not particularly limited, and examples thereof include -41 - 201224652 ω-carboxypolycaprolactone mono(indenyl) acrylate. Ethylene glycol (mercapto) acrylate 1,6-hexanediol bis(meth)acrylate, hydrazine, hexamethylene glycol bis(meth) acrylate, tetraethylene glycol bis(meth) acrylate, polyethylene glycol bis (methyl) Acetic acid vinegar, polypropanol bis(indenyl)acrylic acid S, diphenoxyethanol hydrazine bis(meth) acrylate, dimethylol tricyclodecane bis(indenyl) acrylate, 2-hydroxy-3-(methyl)allyloxypropyl methacrylate, 2-(2,-ethoxy)ethyl(indenyl)acrylate, trimethylolpropane tris(methyl) ) acrylate, pentaerythritol tris(decyl) acrylate, neopentyl alcohol tetrakis(meth) acrylate, diterpene tetraol penta (meth) acrylate, dipentaerythritol hexa(methyl) ) acrylate, tris(2-(indenyl) propylene methoxyethyl) sulphonate, ethylene oxide modified dipentaerythritol hexaacrylate, succinic acid modified neopentyl alcohol triacrylate, etc. Further, a compound having a linear stretchable group and an alicyclic structure and having two or more different acid groups can be cited, and has more than one hydroxyl group in the molecule and has 3 to 5 A urethane (meth) acrylate compound obtained by reacting a compound of a propylene oxy group with a thiol group. For the commercial item of the [E] polymerizable compound, for example, ARONIX M-400, ARONIX can be cited. M-402, ARONIX M-405, ARONIX M-450, ARONIX M-1310, ARONIX M-1 600, ARONIX M- 1 960, ARONIX M-7100, ARONIX M-8030, ARONIX M-8060, ARONIX M-8100 , ARONIX M-8530,

ARONIX M-8560, ARONIX M-9050, ARONIX TO-1450, ARONIX TO-1382 (above is East Asia Synthesis), KAYARAD DPHA, KAYARAD DPCA-20, KAYARAD DPCA-30, KAYARAD DPCA-60, KAYARAD DPCA-120, KAYARAD -42- 201224652 MAX-3510 (above is Nippon Kayaku Co., Ltd.), VISCOTE295, VISCOTE300, VISCOTE360, VISCOTEGPT, VISCOTE3PA, VISCOTE400 (above is Osaka Organic Chemical Industry Co., Ltd.), NEWFRONTIER as an amino phthalate acrylate compound R-1150 (First Industrial Pharmaceutical Company), KAYARAD DPHA-40H, UX-5 000 (Nippon Chemical Co., Ltd.), UN-9000H (Guanshang Industrial Co., Ltd.), ARONIXM-5300, ARONIXM-5600, ARONIXM-5700, ARONIXM- 210, ARONIXM-220, ARONIXM-240, ARONIXM-270, ARONIXM-6200, ARONIXM-305, ARONIXM-309, ARONIXM-310, ARONIXM-315 (above is East Asia Synthetic Company), KAYARAD HDDA, KAYARAD HX-220, KAYARAD HX-620, KAYARAD R-526, KAYARAD R-167, KAYARAD R-604, KAYARAD R-684, KAYARAD R-551, KAYARAD R-712, UX-2201, UX-2301, UX-3204, UX-330 1 , UX-4101, UX-6101, UX-7101 UX-8101, UX-0937, MU-2100, MU-4001 (above is 曰本化制药公司), art resin UN-9000PEP, art resin UN-9200A, art resin UN-76.00, art resin UN-333, art Resin UN -1003, art resin UN-1255, art resin UN-606OPTM, art resin UN-6060P (above is Roots Industrial Co., Ltd., VISCOTESH-500B, VISCOTE260, VISCOTE3 12, VISCOTE3 3 5HP (above is Osaka Organic Chemical Industry Co., Ltd.) Wait. [E] The polymerizable compound may be used singly or in combination of two or more. The ratio of use of the [E] polymerizable compound in the coloring composition is -43 to 201224652 5 ', preferably 1 part by mass to 490 parts by mass, more preferably 2 parts by mass based on 100 parts by mass of the [A] epoxy compound. 〇 mass parts ~ 3 〇〇 mass parts. The proportion of the mass fraction of the shellfish/polymerized [A] epoxy compound of the polymerized δ article is preferably 0.01 4.9, more preferably 〇.2 to 3. 〇. By containing the [e] polymerizable compound in such a mass ratio, the colored composition can form a color pattern and color filter having sufficient heat resistance, solvent resistance, and voltage holding ratio even at a low exposure amount. sheet. When the mass ratio of the mass fraction of the [E] polymerizable compound / the mass fraction of the [A]% oxygen compound is $ or more, it is 2 〇 〇. 〇 The following post:): The unreacted ethylenically unsaturated group in the film which does not participate in the polymerization reaction at the co-baking temperature increases. Therefore, upon heating, the unreacted ethylenically unsaturated group is further thermally polymerized, so that the hardening shrinkage is further produced by the ratio of the designed film thickness. If the film thickness changes greatly before and after heating, the color change of the colored pattern increases, and the color uniformity tends to decrease. <[F] Radiation-Temperature Polymerization Initiator> The coloring composition preferably further contains [F] a radiation-sensitive polymerization initiator. Further, when the coloring composition further contains a [F] radiation sensitive polymerization initiator, a coloring pattern and a color filter which are more excellent in heat resistance and solvent property can be obtained even at a low exposure amount. The [F] radiation-sensitive polymerization initiator ' contained in the colored composition of the present invention is a component which induces radiation to generate an active species capable of initiating polymerization of the [E] polymerizable compound. As such a [F] radiation-sensitive polymerization initiator, a ruthenium-based ruthenium compound or an acetophenone compound is preferred. With respect to the 0-fluorenyl hydrazine compound, for example, 1,2-octanedione-1-[4-(phenylthio)-2-(0-benzhydrylhydrazine)], ethyl ketone·ι_[ 9-ethyl-44- 201224652 -6-(2-mercaptophenylhydrazino)-9H-carbazol-3-yl]-1-(0-acetamidine), 1-[9-ethyl- 6-phenylhydrazino-9H-carbazol-3-yl]-oct-1-one oxime-0-acetate, 1-[9-ethyl-6-(2-mercaptophenylhydrazino) -9H-carbazol-3-yl]-ethan-1-one oxime-0-benzoate, 1-[9-n-butyl-6-(2-ethylbenzylidene)-9H-indole 0 sit-3 -yl]-B-1 - 嗣月亏-0 - Benzoic acid @旨,乙嗣-1 - [ 9 -ethyl-6 - (2 _ methyl-4-tetrahydrofuranylbenzamide) -9H-carbazol-3-yl]-1-(0-acetamidine), ethyl ketone-1-[9-ethyl-6-(2-methyl-4-tetrahydropyranylbenzene曱醯基)-9 Η -味 ° sit-3 -yl]-1-(0 - B-yield-yield), b-class-1-[9-ethyl-6 - (2 _indolyl-5-tetrahydrofuran Benzomethylene)-9H-indazol-3-yl]-1-(0-acetamidine), ethyl ketone-l-[9-ethyl-6-{2-methyl-4-(2 ,2-Dimethyl-1,3-dioxolanyl)nonyloxybenzimidyl}-9H-carbazol-3-yl]-1-(0-acetamidine) and the like. Among these 0-fluorenyl hydrazine compounds, preferred is 1,2-octanedione-1-[4-(phenylthio)-2-(0-phenylhydrazinyl)], ethyl ketone-l-[ 9-Ethyl-6 - (2-methylphenylhydrazino)-9 Η-carbazole-3-yl]-1 - (0-acetamidine), ethyl ketone-1-[9-ethyl- 6-(2-methyl-4-tetrahydrofuranyloxyphenyl fluorenyl)-9H-indazol-3-yl]-1-(0-acetamidine), ethyl ketone-l-[9-B -6-{2-methyl-4-(2,2-dimethyl-1,3-dioxolanyl)methoxybenzoin}}-9H-indazol-3-yl]- 1-(0-acetonitrile). Examples of the acetophenone compound include an α-amino ketone compound, an α-pyridyl ketone compound, and the like. The α-amino ketone compound may, for example, be 2-benzyl-2-didecylamino-1-(4-isolinyl)-but-1-indole, 2-didecylamine. 2-(4-methylindolyl)-1 -(4-furyl-4-yl-phenyl)-butan-1-indole, 2-indolyl-1-(4-indolylthiophenyl) )-2-northroline propan-1-one and the like. -45- 201224652 As the α-hydroxyketone compound, for example, 1-phenyl-2-hydroxy-2-methylpropan-1-one, 1-(4-isopropylphenyl)-2-hydroxy- 2-methylpropan-1-one, 4-(2-hydroxyethoxy)phenyl-(2-hydroxy-2-propyl) ketone, hydroxycyclohexyl phenyl ketone, and the like. Among these acetophenone compounds, an α-amino ketone compound is preferred, and 2-benzyl-2-dimethylamino-1-(4-morpholinylphenyl)-butan-one is more preferred. 2-Dimethylamino-2-(4-mercaptobenzyl)-1-(4- morpholinyl-4-yl-phenyl)-but-1-S is the same. [F] A radiation-sensitive polymerization initiator may be used singly or in combination of two or more. The use ratio of the [F] sensitizing radiation polymerization initiator is preferably from 5 parts by mass to 40 parts by mass, more preferably from 5 parts by mass to 30 parts by mass, per 100 parts by mass of the [A] epoxy compound. By using the ratio of the [F] radiation-sensitive polymerization initiator to 1 part by mass to 4 parts by mass, the colored composition can form a colored pattern and a color filter having high hardness and the like even at a low exposure amount. Light film. <Other optional components> . The coloring composition 'except for the above [A] epoxy compound, [b] colorant, [C] compound, [D] amine compound', and [E] polymerizability as an appropriate component In addition to the compound and the [F] radiation-sensitive polymerization initiator, [G] adhesion aid, [H] surfactant, and (1) preservation may be contained as other optional components, as long as the desired effect is not impaired. Stable back j [J] heat resistance improver, etc. These other optional components may be used singly or in combination of two or more. Hereinafter, each component will be described in detail. -46- 201224652 [[G] adhesion aid] [G] adhesion aid, which can be used to further improve the adhesion of the resulting color pattern and color filter to the substrate. The [G] adhesion aid is preferably a functional decane coupling agent having a reactive functional group such as a carboxyl group, a methacryloyl group, a vinyl group, an isocyanate group or an epoxy group. For example, trimethoxymethyl decyl benzoic acid, γ-methyl propyl oxypropyl trimethoxy sulphur, vinyl triethyl ethoxylate, and ethylene di methoxy sulphur And γ·isocyanate propyl triethoxy cerium oxide, hydral glycidoxypropyl trimethoxy decane, β—(3,4-epoxycyclohexyl)ethyltrimethoxy decane, and the like. The amount of the [G] adhesion aid to be used is preferably 20 parts by mass or less, more preferably 15 parts by mass or less based on 100 parts by mass of the [Α] epoxide. If the amount of the [G] adhesion aid used exceeds 2 parts by mass, there is a tendency that development residue tends to occur. [[Η] surfactant] [Η] A surfactant can be used to further improve the film formability of the coloring composition. The surfactant may, for example, be a fluorine-based interface lingual agent, an anthraquinone-based surfactant, or another surfactant. In the case of a fluorine-based surfactant, it is preferred to have a fluoroalkyl group and/or a fluoroalkylene group at any of the terminal, main chain and side chain to ν--for example, 112, 2 -tetrafluorom-octyl (1,1,2,2-tetrafluoropropyl)ether 1,1,2,2-tetrafluoro-n-octyl (n-hexyl) ether, hexaethylene glycol (^yi^6 Fluoryl-n-pentylmanate ethylene glycol double (1): ^yi tetra-n-butyl butyl) _, hexapropylene glycol bis (1 mountain 2,2,3,3 hexafluoro-n-pentyl) ether, octapropyl-alcohol double d '1'2'2-tetraqi-n-butyl (four), full defeat is twelve dazzling sodium, -47- 201224652 1,1,2,2,3,3-hexafluoro-n-decane, 1,1,2 , 2,8,8,9,9,10,10-decafluoro-n-dodecane, sodium fluoroalkylbenzenesulfonate, sodium fluoroalkylphosphate, sodium fluoroalkylcarboxylate, diglycerin tetrakis Alkyl polyoxyethylene ether), fluoroalkyl ammonium iodide, fluoroalkyl betaine, other fluoroalkyl polyoxyethylene ether, perfluoroalkyl polyoxyethylene, perfluoroalkyl alkoxylate, carboxylic acid Fluoroalkyl esters and the like. Examples of the commercially available product of the fluorine-based surfactant include BM-1000, BM-1100 (above, BM CHEMIE), MEGAFACF142D, MEGAFACF172, MEGAFACF173, MEGAFACF183, MEGAFACF178, MEGAFACF191, MEGAFACF471, MEGAFACF476 (above Japan Ink Chemical Industry Co., Ltd., FRORAIDFC-170C, FRORAIDFC-171, FRORAIDFC-430, FRORAIDFC-43 1 (above Sumitomo 3M), SurflonS-112, SurflonS-113, SurflonS-131, SurflonS-141, SurflonS-145 , SurflonS-3 82,

SurflonSC-101, SurflonSC-102, SurflonSC-103,

Surflon SC-104, Surflon SC-105 ' Surflon SC-106 (above is Asahi Glass), EFTOP EF301, EFTOP EF303, EFTOP EF352 (above is New Akita Chemical Co., Ltd.), FTERGENT FT-100, FTERGENT FT-11 0, FTERGENT FT-1 40A, FTERGENT FT-150, FTERGENT FT-250, FTERGENT FT-251, FTERGENT FT-300 > FTERGENT FT-310, FTERGENT FT-400S, FTERGENTF TX-218, FTERGENTF TX-251 (above NEOS). For the commercial products of the Shixi resin-based surfactant, for example, Toray Silicone DC3PA, Toray Silicone DC7PA, Toray -48-201224652

Silicone SH11PA, Toray Silicone SH21PA, Toray Silicone SH28PA, Toray Silicone SH29PA, Toray Silicone SH30PA, Toray Silicone SH-190, Toray Silicone SH-193, Toray Silicone SZ-6032, Toray Silicone SF-8428, Toray Silicone DC-57, Toray Silicone DC-190 (above to Toray Dow Corning Silicone), TSF-4440, TSF-4300, TSF-4445, TSF-4446, TSF-4460, TSF-4452 (above GE Toshiba Silicone), organic helium oxygen Alkane polymer KP34 1 (Shin-Etsu Chemical Industries, Inc.) and the like. Examples of other surfactants include polyoxyethylene alkylene ether such as polyoxyethylene lauryl slit, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, and polyoxyethylene n-octylphenyl group; Polyoxyethylene aryl ethers such as ether, polyoxyethylene n-decylphenyl; polyionic ethylene dialkyl esters such as polyoxyethylene dilaurate and polyoxyethylene distearate, etc. (fluorenyl) acrylic copolymer p〇lyfl〇 No. 57, polyflo Νο·95 (above is Kyoeisha Chemical Co., Ltd.), and the like. The amount of the [Η] surfactant to be used is preferably 1.0 part by mass or less or more preferably 0.7 parts by mass or less based on 100 parts by mass of the epoxide. If the amount of the [Η] surfactant is more than 1.0 part by mass, uneven coating film is likely to occur. [[I] Storage Stabilizer] Examples of the [I] storage stability agent include sulfur, benzoquinones, oxime compounds, amines, nitronitroso compounds, and the like, and more specifically, 4-methoxyphenol, hydrazine-nitroso-hydrazine-phenylhydroxylamine aluminum, and the like. In the case of [i] the amount of the stabilizer to be used, it is preferably 3 parts by mass or less, more preferably 〇 5 parts by mass or less, based on 100 parts by mass of the [A] epoxide. If the blending amount of the [I] storage stabilizer exceeds 3 Å by mass, there is a case where the sensitivity is lowered and the pattern shape is deteriorated. [[J] Heat resistance improving agent] The heat resistance improving agent [J] may, for example, be N-(alkoxymethyl)glycoluril or N-(alkoxymethyl)melamine compound. The N-(alkoxyindenyl) glycoluril compound may, for example, be Muza: ^'Mountain'-tetrakis-oxycarbonyl-urea-urea^, 仏^tetrakis-ethoxymethyl) glycoluril, N,N,N,,N,-tetra(n-propoxymethyl)glycoluril, n,n,n,,n,_tetrakis(isopropoxymethyl)glycoluril, N,N,N, , N'_tetra(n-butoxycarbonyl)glycine, N,N,N,,N'-tetrakis(tris-butoxymethyl)glycolil, etc. These (alkoxymethyl) glycolurils Among the compounds, n, n, n, n, and tetrakis(methoxymethyl) glycoluril are preferred. Examples of the N-(alkoxyindenyl)melamine compound include, for example, n, n, n',n',n,',n,,-hexa(methoxyindolyl)melamine, N,N,N',N',N'',N''-hexa(ethoxylated) ) melamine, n, n, n', n', n'', n, '-hexa(n-propoxy fluorenyl) melamine, N, N, N', N', N'', N ''-Hex (isopropoxy fluorenyl) melamine, n, n, n', n', n'', n''-hexa(n-butoxycarbonyl) melamine, 4', > ;1',:^'',:^''-six (three-stage butoxy Mercapto) melamine, etc. Among these N-(alkoxymercapto) melamine compounds, preferably N'W, N', N', N'', N''-hexa(methoxy fluorenyl) Melamine. As a commercial item, for example, NIKALAC N-2702, NIKALAC MW -30M (the above is Sanwa Chemical Co., Ltd.), etc. -50- 201224652 are used, and in terms of the amount of heat-resistant humectant used, 100 parts by mass of the [A] epoxy compound is preferably 50 parts by mass or less, more preferably 3 parts by mass or less. If the amount of the [J ] heat resistance improving agent is more than 5 parts by mass, there is sensitivity. When the degree is lowered and the pattern shape is deteriorated. <Modulation method of coloring composition> The coloring composition of the present invention is uniformly mixed by [A] epoxidized person, [B] colorant, [C] compound, [D The amine compound, the [E] polymerizable compound as a suitable component, and the [F] radiation-sensitive polymerization initiator, and other optional components are prepared. The colored composition is preferably used in a solution state dissolved in a suitable solvent. It can be used as a solvent for the preparation of the coloring composition, and can be used for uniform dissolution. Solving [A] epoxy compound, [B] colorant °, [C] human =, rigid compound, rigid compound, [f] sensitizing radio 2, initiator and other optional components as needed, and The substance to be reacted. In the case of this solvent, each is ffl ^ ^ Λ l· '+* ra π » 乂 exemplified as a solvent capable of < 4 [A] epoxy compound. The solvent exemplified in d is the same This type of solubility, coated ethylene glycol monoether ether, ethylene glycol monoethyl ether, ether, triethylene glycol methyl ether, propylene di-n-butyl ether, and the like The ease of use such as methyl ether, ethylene mono-n-butyl, diethylene glycol mono- and methyl, triol monoethyl ether, dipropylene glycol monoterpene solubility, point of view ——, ethylene glycol 〇〇 early methyl propyl ii | ethyl alcohol 〇〇 early ethyl propylene glycol 早 early n-propyl > C and the reverse of the ingredients to list, for example, ethylene glycol mono-n-propyl shrine, two ethylene Glycol mono-n-butyl hydrazine, propylene glycol single-base test, propylene glycol alcohol early ethyl bond, -5 1- 201224 652 dipropylene glycol mono-n-propyl ether, dipropylene glycol mono-n-butyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monoethyl ether, etc. (poly) alkyl glycol monoalkyl ether; ethylene glycol monoterpene Ethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol mono-n-propyl ether acetate, ethylene glycol mono-n-butyl ether acetate, diethylene glycol monodecyl ether Acid ester, diethylene glycol monoethyl ether acetate, diethylene glycol mono-n-propyl ether acetate, diethylene glycol mono-n-butyl ether acetate, propylene glycol monomethyl ether acetate, (poly)alkylene glycol monoalkyl ether acetate such as propylene glycol monoethyl ether acetate, 3-decyloxybutyl acetate, 3-mercapto-3-methoxy butyl acetate Ester; diethylene glycol dimethyl ether, diethylene glycol decyl ethyl ether, diethylene glycol diethyl bond, tetranitrocene and other mysteries; methyl ethyl ketone, cyclohexanone, 2-heptanone a ketone such as 3-heptanone, diacetone alcohol (4-hydroxy-4-mercaptopentan-2-one) or 4-hydroxy-4-mercaptohexan-2-one; propylene glycol diacetate, Diacetate such as 1,3 -butanediol diacetate or 1,6-hexanediol diacetate An alkyl lactate such as decyl lactate or ethyl lactate; ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, n-amyl decanoate, isoamyl acetate, 3 -decyloxybutyl acetate, 3-methyl-3-decyloxybutyl acetate, n-butyl propionate, 3-decyloxybutyl acetate, 3-methyl-3- Methoxybutyl propionate, ethyl butyrate, n-propyl butyrate, isopropyl butyrate, n-butyl butyrate, ethyl hydroxyacetate, ethyl ethoxyacetate, 3-methoxypropane Acid ester, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, decyl pyruvate, ethyl pyruvate, n-propyl pyruvate, Ethylacetate 曱-52- 5 201224652 Ester, ethyl acetate, ethyl 2-hydroxy-2-methylpropionate, 2-hydroxy-3-mercaptobutyrate, 2-oxobutyric acid Other esters such as esters; aromatic hydrocarbons such as toluene and dinonylbenzene; guanamines such as N-decylpyrrolidone, hydrazine, hydrazine-dimethyl decylamine and N,N-dimercaptoacetamide Wait. Among these solvents, propylene glycol monodecyl ether, propylene glycol monoethyl ether, ethylene glycol monomethyl ether acetate, and propylene glycol monomethyl ether B are preferred from the viewpoints of solubility, pigment dispersibility, and coating properties. Acid ester, propylene glycol monoethyl ether acetate, 3-methoxybutyl butyl acetate, diethylene glycol dimethyl ether, diethylene glycol decyl ethyl ether, cyclohexanone, 2-heptanone , 3-heptanone, 1,3 - butanediol diacetate, 1,6-hexanediol diacetate, ethyl lactate, ethyl 3-methoxyoxypropionate, 3-ethoxypropane Methyl ester, ethyl 3-ethoxypropionate, 3-methyl-3-decyloxybutyl propionate, n-butyl acetate, isobutyl acetate, n-amyl formate, isoamyl acetate, N-butyl propionate, ethyl butyrate, isopropyl butyrate, n-butyl butyrate, ethyl pyruvate. The solvent may be used singly or in combination of two or more. Further, benzyl ethyl ether, di-n-hexyl ether, acetone acetone, isophorone, hexanoic acid, octanoic acid, 1-octanol, diterpene alcohol, benzyl acetate, ethyl benzoate, oxalic acid can also be used. A high boiling point solvent such as ethyl ester, diethyl maleate, γ-butylimide, ethylene carbonate, propylene carbonate or ethylene glycol monophenyl ether acetate is used in combination with the above solvent. The above high boiling point solvents may be used singly or in combination of two or more. The content of the solvent is not limited, but it is preferably from 5% to 50% by mass based on the total concentration of each component other than the solvent of the coloring composition, from the viewpoints of applicability, stability, and the like of the obtained coloring composition. The amount is more preferably such that the total concentration is from 10% by mass to 40% by mass. -53-201224652 When the coloring composition is prepared in a solution state, the solid content concentration (component other than the solvent in the composition solution) can be set to an arbitrary concentration depending on the purpose of use, a desired film thickness value, or the like (for example, 5 mass% to 50 mass%). More preferably, the solid content concentration differs depending on the method of forming the coating film on the substrate, which will be described later. The composition solution thus prepared can be used after being subjected to the use of a microporous filter # with a pore diameter of about μ 5 μm. <Color filter, method of producing light sheet> The present invention also suitably includes a color pattern formed by the coloring composition and a color filter. The method for producing a color filter includes: (1) a step of applying the colored composition to form a coating film on a substrate, (2) a step of forming a colored pattern on the coating film, and (3) at 20 ( The step of firing the colored pattern below TC. Hereinafter, each step will be described in detail. [Step (1)] This step is a step of forming a coating film of the colored composition on a substrate. On the surface of the substrate, formation is performed. It is necessary to form a mask layer (black matrix) of the pixel portion. Then, the coloring composition containing, for example, a red color toner is applied onto the substrate, and then pre-baked, and the solvent is evaporated to form a coating film. In the method of forming a coloring pattern, a method of obtaining a color pixel by an inkjet method disclosed in Japanese Laid-Open Patent Publication No. Hei. No. Hei. First, a partition wall having a light-shielding function is formed on the surface of the substrate. Then, in the partition wall formed, the colored composition containing, for example, a red coloring agent is discharged by an inkjet device, and then into the *54-2012246 52 rows of pre-baked light, the shape has a covering will not be sour, vinegar, etc. This decane is sputtered, sprayed by the method of 'bar coating method, evaporated to red light image function, and also mixed color functional substrate material In addition to polyester and aromatic, the test gas phase reaction method such as the base agent is a coloring composition method, a roll coating method, etc., and the exposure is carried out, not only the color composition is 0, but the polycarbocarbimide is used for electroplating, and the mold can be used. The slit molding agent is applied. Then, the coating film pattern is applied as needed. Further, since the partition wall has a color which is discharged into the division, the film thickness is thicker than the black matrix, and examples thereof include glass and enamel. The polyamidoamine, the polyamidimide, and the polyplate may also be subjected to an appropriate pretreatment such as a solid treatment, a plasma treatment, an ion vacuum evaporation, or the like according to a desired condition. Rotary coating method (spin coating method), slit "preferably spray method, spin coating method, pre-baking, usually combined with vacuum drying and heat drying to dry under reduced pressure, usually at 5 Gpa~2 Under the conditions of Gopa, as a condition for heating and drying, it is usually about 1 minute to 10 minutes under the grasping step. The film thickness after drying is usually 0.1 μm to 8 0 μη1, which is 1.2 μΐΏ to 5.0 pm. [Step (2)] = Step is a step of forming a colored pattern on the above coating film. The coating film formed in the step (1) is exposed by a mask, and the developing portion is used to dissolve and remove the unexposed portion of the coating film. Thereby, a pixel array in which the red two patterns are arranged in a predetermined arrangement is formed, and a colored pattern is formed. -55- 201224652 Then, using the green or blue colored composition, steps (1) and (2) are repeated on the same substrate. A green pixel array and a blue pixel array are sequentially formed. Thereby, three primary color pixel arrays of red, green and blue are arranged on the substrate. However, in the present invention, the order of forming the pixels of each color and the number of colors ' are not limited to the above. Further, the 'black matrix can be formed by forming a desired pattern of a metal film such as chromium formed by sputtering or base plating by photolithography, but a coloring composition containing a black colorant can be used, and It is formed in the same manner as the case of forming the above-described pixels. Examples of the light source of the radiation include a xenon lamp, a light lamp, a tungsten lamp, a high pressure mercury lamp, a & high pressure mercury lamp, a metal toothed lamp, and a light source such as a mercury lamp or a low pressure mercury lamp, or an argon ion laser, YAG: Laser 5, XeCl excimer laser, nitrogen laser and other laser sources. The ruthenium is a radiation having a wavelength in the range of A 19 〇 nm to 45 〇 nm. As the exposure of the radiation, it is preferably 10 J/m 2 to l 〇, 〇〇〇 j / m 2 . In the case of a purine base developer, carbon: potassium, tetradecylammonium hydroxide, choline, 8-diazabicyclo-4, fluorene, -7-undecene, hydrazine, and bismuth are preferred. Azabicyclo-[4.3.〇5_decene. ^ W ” staff ~ liquid, you can add appropriate amounts of water such as sterol, ethanol, etc.: organic solvents or surfactants. In addition, after alkali development, usually ... 乍 is a 4-shirt treatment, can be applied to the shower development method , spray ml: method, dipping (impregnation) development method, immersion (liquid pool method) development method, etc. '~ conditions, preferably at room temperature for 5 seconds to 3 seconds. 56- 201224652 [Step (3)] In this step, the coloring is performed by firing at 2 〇rc or less: after the coloring pattern is formed in the step (7), the coloring pattern is fired (the coloring pattern is hardened, and the color enamel is produced. In the case of the heating condition, the temperature is 200 C or less. When the U paper is used, it is ~ ° ·, ', and the other is between 10 minutes and 60 minutes in the present invention, even if the post-baking temperature is in the knife. The temperature is low, and it is also possible to get a good coloring map of the Xuanzhao Temple. The ridge. * Body says 'even after the baking temperature is * * 。 0. (: below 'and further 18 〇Γ 〇Γ, again For less than 1 80 C of the horse, it is also possible to obtain a color light-emitting sheet such as the solvent of the ancient one. The film thickness of the pixel; 5 Γ 〜 〜 5 · 〇 ΐ ΐ 并 ' and preferably 1.0 μιη to 3 · 0 μηι ° ° 'Color < Color Display Element > ~ The present invention also suitably includes two 7C members having the color filter. The color display element can be formed into a suitable structure. For example, a driving substrate on which a thin film transistor (TFT) is disposed can be formed, for example, a color filter is formed on the substrate, and the substrate and shape for driving are formed. The substrate of the matte color filter is formed so as to be opposed to each other with the liquid crystal layer interposed therebetween. The substrate on which the color filter is formed on the driving surface on which the thin film transistor (TFT) is disposed may be formed. The substrate of the indium oxide-based electrode in which the Ιτ:: tin is formed is formed by a liquid crystal layer (the structure of the doped structure. The structure of the latter type can significantly increase the aperture ratio, and the junction is paid for. Advantages of the high-definition liquid crystal display element. The following is a detailed description of the present invention based on the embodiments, and the teachings are not intended to limit the invention. ' ～ 例 - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Synthesis of epoxy compound > [Synthesis Example 1] In a flask equipped with a condenser and a stirrer, 5 parts by mass of 2,2'-azobis(2,4-dimethylvaleronitrile) and 22 parts by mass of diethylene glycol methyl ethyl ether were added, and the addition was continued as (al) Compound white " 2 f parts of methacrylic acid, 28 parts by mass of the (a2) compound, 28 parts by mass of trimethoprimic [5.0.1.02'6] 癸-8-yl ester and 4 parts by mass of glycidol methacrylate Vinegar and 2 parts by mass of stupid ethylene as the compound (a3) were subjected to nitrogen substitution, and while stirring slowly, the temperature of the solution was raised to 7 Torr. 〇, the temperature was maintained for 5 hours, and polymerization was carried out. A solution containing the [A] copolymer as the [A] anthracene compound was obtained. The obtained polymer solution had a solid content concentration of 31 3%, and the copolymer (A 3) had a Mw of 12,000 ° [Synthesis Example 2] In a flask having a condenser and a stirrer, 5 parts by mass of 2,2-even was added. Nitrogen bis(2,4-dimethylvaleronitrile) and 220 parts by mass of diethylene glycol methyl ethyl bond. 18 parts by mass of methacrylic acid as the (a) compound, 23 parts by mass of the tricyclo[5.1.0''] fluorenyl-8-yl methacrylate, and 20 parts by mass of the fluorenyl group as the (a2) compound Glycidyl acrylate and 14 parts by mass of 2-methylglycidyl methacrylate, and 10 parts by mass of styrene and 5 parts by mass of methyl methacrylate as the (a3) compound, nitrogen-substituted, and slowly stirred, While raising the temperature of the solution to 70 C, the temperature was maintained for 5 hours, and polymerization was carried out to obtain a solution containing the copolymer (A-4) as the [A] epoxy compound. The obtained polymer solution had a solid content concentration of 315%, and the copolymer (A_4) had a M w of 10,100. 58-201224652 [Synthesis Example 3] In a flask having a condenser and a stirrer, 5 parts by mass of 2,2'-azobisisobutyronitrile and 220 parts by mass of 3-methoxybutyl acetate were added. Further, 18 parts by mass of methacrylic acid as the (al) compound, 36 parts by mass of the (a2) compound, 36 parts by weight of methacrylic acid-3,4-epoxycyclohexylmethanone, and 10 parts by mass as the compound (a3) are added. Styrene and 36 parts by mass of methacrylic acid ester's were stirred while stirring, and the temperature of the solution was raised to 80 ° C. The temperature was maintained for 5 hours, and polymerization was carried out to obtain [A] epoxy compound. a solution of the copolymer (A-5). The obtained polymer solution had a solid content concentration of 30.9%, and the copolymer (a-5) had a M w of 9,800. [Synthesis Example 4] In a flask having a condenser and a stirrer, 5 parts by mass of 2,2-diox-isobutyl and 220-mass propylene glycol monoterpene acetic acid were added. Continuing to add 80 parts by mass of benzyl methacrylate and 2 parts by mass of methacrylic acid, while slowly stirring, the temperature of the solution was raised to 8 Torr, and the temperature was maintained for 5 hours to carry out polymerization, thereby obtaining a copolymer containing ( A solution of CA-1). The obtained polymer solution had a solid content concentration of 31.0%'. The copolymer (CA-1) had an Mw of 1 Å. <Preparation of coloring composition> The details of the respective components for preparing each coloring composition are as follows. [A] Epoxy compound A-1 : 3,4-epoxycyclohexylmethyl_3,4,-epoxycyclohexanecarboxylate-59- 201224652 A-2 : Benzene is varnished Epoxy resin (Japan Epoxy Resin, EPIKOTE 152) [B] Colorant B-1 : CI Solvent Red 45 B-2 : CI·Solvent Yellow 98 B-3 : CI Solvent Blue 67 B-4 : CI Solvent Yellow 82 B-5 : C.I_Solvent Blue 35 B - 6 : C · I · Solvent Blue 5 9 B-7 : Valifast Yellow 1101 B-8 : CI Acid Black 24 [C] Compound Cl : represented by the following formula 5-nitroisophthalic acid

COOH

COOH C-2 : 5-hydroxyisophthalic acid represented by the following formula

COOH

C-3: 1,1,2,2-tetrakis(4-hydroxyphenyl)ethane-60-201224652 represented by the following formula

OH

OH

HO

HO

[D] Amine Compound Dl: 2-Phenyl-4-indolyl-5-hydroxyindolizole D-2: 2-mercaptoimidazole D-3: Ethyl-4-mercaptoimidazole D-4: 2 - Methylbenzimidazole D-5: Triethylamine-encapsulated compound Z-1 to Z-10 as an inclusion compound shown below, which is a [D] amine compound and the above [C] as a host compound, respectively. compound of. Z-1 : Cl (0_67 parts by mass) and D-1 (0.33 parts by mass) (2:1) Z-2 : C-2 (0.67 parts by mass) and D-1 (0.33 parts by mass) (2:1) Z-3 : C-3 (0_67 parts by mass) and D-1 (0.33 parts by mass) (2:1) Z-4 : C-1 (0.67 parts by mass) and D-2 (0_33 parts by mass) (2: 1) Z-5 : C-2 (0.67 parts by mass) and D-2 (0.33 parts by mass) (2:1) Z-6 : C-3 (0.67 parts by mass) and D-2 (0.33 parts by mass) ( 2: 1) Z-7 : Cl (0.67 parts by mass) and D-3 (0.33 parts by mass) (2:1) Z-8 : C-2 (0.67 parts by mass) and D-3 (0.33 parts by mass) ( 2:1) Z-9 : C-3 (0.67 parts by mass) and D-3 (0.33 parts by mass) (2:1) Z-10 : C-3 (0.50 parts by mass) and D-4 (0.50 parts by mass) (1:1) -6 1- 201224652 [E] Polymeric compound E-1: a mixture of dipentaerythritol pentaacrylate and dipentaerythritol hexaacrylate (KAYARAD DPHA, Sakamoto Chemical Co., Ltd.) E-2: a mixture of polyfunctional acrylate compounds (KAYARAD DPHA-40H, Nippon Kayaku Co., Ltd.) E-3: 1,9-nonanediol diacrylate, E-4: pentaerythritol tetraacrylate E- 5: Trihydroxydecylpropane triacrylate E-6 : ω-carboxypolycaprolactone monopropene Acid ester (ARONIX Μ-5300, East Asia Synthetic Co., Ltd.) Ε-7: succinic acid-modified neopentyl alcohol triacrylate (ARONIX TO-756, East Asia Synthesis Co., Ltd.) E-8: ethylene oxide-modified dipentaerythritol Hexaacrylate [F] Radiation-type linear polymerization initiator Fl : 1,2-octanedione-1-[4-(phenylthio)-2-(0-benzylidene)] (IRGACUREOXE01, ciba specialty Chemicals company)' F-2 : Ethylketone- l-[9-ethyl-6-(2-mercaptobenzylidene)-9H-carbazole-3_yl]-1-(0-acetamidine) (IRGACUREOXE02, ciba specialty chemicals) F-3 : 2-mercapto-1-(4-indolethiophenyl)-2-pyroline propan-1-one (IRGACURE 907, ciba specialty chemicals) F-4 : 2-Dimethylamino-2-(4-mercaptobenzyl)-1-(4-indololin-4-yl-phenyl)-butyl-1-(IRGACURE379, ciba specialty chemicals) -62 - 201224652 [G] adhesion aid Gl : γ-glycidoxypropyl trimethoxy decane [Η] surfactant Η-1 : fluorosurfactant (Ftx_21 8, NEOS) Η-2: stone夕 resin surfactant (T〇ray siliconeSH2 1 ΡΑ '

Toray Dow Corning Silicone Inc. [I] Preservation Stabilizer 1-1: 4-Methoxyphenol Solvent Sl: Propylene Glycol Monoacetate S-2: Cyclohexanone S-3: Ethyl Lactate [Examples] 1 to 15 and Comparative Examples 1 to 4] The kinds of the components shown in Table 1, the amount of the [A] component, the [B] colorant, the [C] inclusion compound, the [E] polymerizable compound, [F] Radiation-sensitive linear polymerization initiator, [G] adhesion aid, [H] surfactant, [I] storage stabilizer and solvent, added to the solvent to have a solid content concentration of 30% by mass, and a pore size of 0.5 μm The pore filter was filtered to prepare a coloring composition. In addition, the column indicates that the corresponding component is not used. Further, the results of measurement of the concentration (mPa.s) of each of the radiation sensitive resin compositions at 25 ° C are shown in Table 1. &lt;Evaluation&gt; The following coloring composition was subjected to the following evaluation. The results are shown together in Table 1. -63- 201224652 [Storage stability (%)] The obtained colored composition was placed in an oven at 40 ° C for 1 week, and the viscosity before and after heating was measured to determine the viscosity change rate (0/ ), \ ) as a preservation stability (° / .). When the viscosity change rate is 5% or less, the storage stability is good, and when it exceeds 5%, the storage stability is judged to be poor. Further, the viscosity was measured at 25 ° C using an E-type viscometer (VISC〇niceld R, Dongsei Industry Co., Ltd.). &lt;Formation of Coloring Pattern&gt; Each of the coloring compositions was applied onto a soda lime glass substrate on which a SiO 2 film for preventing elution of sodium ions was formed on the surface by a spin coater. Subsequently, prebaking was performed on a hot plate of 90 C for 2 minutes to form a coating film having a film thickness of 2.5 μm after prebaking. After cooling the substrates to room temperature, using a high-pressure mercury lamp' and using a photomask, 100 (J/m2), 3 〇〇 (J/m2), 500 (J/m2), 700 (J/m2), The exposure amount was exposed to the coating film by radiation including wavelengths of 365 nm, 405 nm, and 436 nm. Then, a developing pressure (kgf/cm 2 ) (nozzle diameter is used to eject the developing solution (23. (4 质量 〇 4 mass / 〇 氢氧化 potassium hydroxide aqueous solution) to the substrate, and then showering and developing A coloring pattern of 2 〇〇 x 2 〇〇 ^ m was produced on the substrate, and further baked at 180 ° (3: after 3 minutes). <Evaluation> The following coloring patterns were evaluated. In the formation of each of the above-described colored patterns, the development resistance (%) was evaluated from the film thickness ratio before and after development calculated by the following formula. -6 4- 201224652 Sex (%) = (the film after development is 95 〇 / 〇, good) 'It is less than 95% or think that the coloring pattern = good evaluation is "B" (it is judged that the draft is not good), and the pattern is two In the case of the absence of the condition, it is evaluated that the exposure amount of lusli is peeled off from the substrate [heat resistance] "this J Μ m2", and the formation of the color pattern is performed in the same manner, and the external exposure is performed, and the heating is performed at 180 ° C. 〇 〇 者 color pattern. Further in the color change AEab*. Spleen...: After finding additional heating before and after the additional AE ab * go, ; ft q λα t* is broken as good), the case where 3 is / is evaluated as "A" (determined to be slightly better), and the case where the hair is less than 5 is evaluated as "B," The above case was evaluated as "C" (it is judged that the solvent resistance is not [the solvent resistance] and the heat resistance evaluation substrate is formed at 60 ton of N_ ▼ 吡 ° 、, and the coloring pattern is formed. Crush for 30 minutes. The condition of the impregnation coloring was evaluated as "N-methylpyrrolidone after the second", and the N-methylpyrrolidone was completely absent (Hung, g, pattern, but N_A after immersion was good), after impregnation The coloring evaluation was evaluated as "B" (determined as good) = 2 arsenazolium was peeled off on the substrate, and after immersion, the coloring circle was observed as "c" after the immersion (determined as not 2 ^ N_ $ pyrrolidinone coloring case [voltage retention rate (%) j using a spin coater, on the surface

Si〇2 film, and further forming a coloring composition on the soda-lime glass substrate which is formed by vapor-depositing an IT〇 (indium tin oxide alloy)-65-201224652 electrode in a predetermined shape to prevent sodium ion elution on f-, and then 9〇. The film was pre-baked in a 清洁 cleaning oven for 10 minutes to form a film having a film thickness of 厶 (7). Next, the coating film was exposed at a exposure amount of 500 J/m 2 without using a photomask. Then, the substrate was at 23 . The developing solution formed of 〇〇4% by mass of potassium hydroxide aqueous solution was immersed for 丨 minutes for development, then washed with ultrapure water and air-dried, and further baked at 18 (rc for 60 minutes, and coated). The film is hardened to form a permanent cured film. Then, the substrate on which the colored pattern is formed and the substrate on which the IT electrode is vapor-deposited in a predetermined shape are bonded together with a sealant in which 8 mm of glass beads are mixed, and then injected into Merck. Liquid crystal cell (MLC66〇8), which is a liquid crystal cell. The liquid crystal cell is placed in a constant temperature layer of 6 〇t, and the liquid crystal cell is measured by a liquid crystal voltage retention measurement system (VHR_1A type, τ〇γ〇Technica). The voltage holding ratio at this time is a square wave of 5 5 V, and the measurement frequency is 60 Hz. Here, the voltage holding ratio is a value of (a liquid crystal cell potential difference after 16 7 ms / a voltage applied at 0 msec). When the cell's electric 1 retention rate is not @90%, it means that the liquid crystal cell cannot be specified: the time is kept for 16.7 milliseconds and the voltage is applied, and the liquid crystal cannot be sufficiently aligned, so that there is a high possibility that "aging" such as afterimage is generated. Production of Color Filters Using the coloring compositions of Examples 3 to 5 (Example 3 is a red material, Example 4 is a green material, and Example 5 is a blue material), a color filter was produced. First, the colored composition of Example 3 was applied onto a glass substrate on which a black matrix pattern was formed using a slit die coater, and pre-baked for 2 minutes on a hot plate to form a coating film. Then, the illuminating machine Can〇nPLA5〇iF (good ^ -66- 201224652) is irradiated with the exposure amount of LOOOJ/m2 by 1 line to the ghi line (wavelength 43 6nm, 40) 5 nm, 3 65 nm intensity ratio = 2.7 · · 2.5: 4.8), and developed with 0.05% potassium hydroxide aqueous solution, and then rinsed with ultrapure water for 6 〇 seconds, then further heat treated in a water tank at 18 (TC) After 30 minutes, a red striped pattern having a film thickness of 2. ΠμΠ1 was formed (the pattern width was ΙΟΟμπι). Then, similarly, the colored composition of Example 4 was used to form a green striped pattern. Further, Example 5 was used. a colored composition that forms a blue striped pattern and forms a red And a blue-colored stripe-shaped color filter (strip width 丨〇〇μιη). The above-mentioned three colors of red, green, and blue formed at a post-baking temperature of 18 (rc, 3 〇 minutes) The colored pattern has no problem of insufficient pattern and peeling off from the substrate due to insufficient curing, and can form a three-color strip-shaped color filter. Further, using a slit die coater, the obtained stripe-shaped color calender sheet is used. After coating a protective film-forming composition (JNPC 48GL JSR Co., Ltd.), it was pre-baked on a hot plate at 9 Torr for 5 minutes to form a coating film, and further heat-treated in an oven at 230 Torr. A protective film having a film thickness of 2.0 μm was formed on the upper surface of the shirt color filter. [Measurement of flatness] The surface of the protective film having a protective film is measured by using a contact-type film thickness measuring device a_step (Tenc〇r(10)). The surface roughness (flatness) of the protective film is measured. 2, 〇〇〇μηι, measurement range 2'〇〇〇μιη square 'measurement point η = 5). That is, the measurement direction is the short-axis direction of the stripe line in the red, ^blue direction, and the long-axis direction of the stripe line of red, green, and blue in the same color, and is measured in each direction by -67-201224652 η = 5 ( The total number of η is 1 0). The ear value of the 10th time difference between the height and the bottom (n m ) of the portion and the bottom portion is 220 nm. After the protective film was formed, the colored pattern protective film showed no surface unevenness, and showed the highest-average value of each measurement. At this time, the average case is not contracted, expanded, and flat. -6 8- 201224652 l&lt; Voltage guaranteed rate (%) § § fS 〇\ ON fN ON fM ON CN 〇(N On &lt;N On (Ν Ο 〇\ 〇\ (Ν » r»i O' § (S Ό S cs 00 Solvent resistance Ρ Ω CQ &lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;&lt;;&lt; • U CQ CQ Storage stability (%) inch «/&gt; in inch *Ti κη ττ *Ti S 〇 viscosity (mPa-s) 〇〇00 00 〇\ oo OO ON 00 OO 00 00 ΟΝ 〇\ ΟΟ 00 〇〇ΟΟ 00 Solvent 0) (/) ΕΛ s fS C-0 cn oo &lt;N ώ ΐλ (Ν cA fS (λ ΐλ S (Ν ζλ ΧΑ ώ 5 [1] Preservation of stabilizer usage (mass parts) ) dd W) d »r&gt; d •n 〇&gt;r&gt; 〇«η ο »〇ο Ο «η Ο ν*) Ο U-5 Ο ό W*) ό 〇d Category 1 - - - • 7 - 7 - I - 7 - *7 -7 7 [H] Surfactant usage (parts by mass) 1 1 o wn 〇«η od Vi 〇d «λ ο Ο «Λ Ο ν*ί Ο «Λ ο ο ο ο ο d u-&gt; d Category 1 1 Hl Hl ! X 5 X H-2 Η-2 Η-2 Η-1 Η-2 Η-2 I 1 Η-2 Η-2 Η-2 H-2 H -2 [G] Usage of bonding aids (mass parts) t 1 ooo 〇0 0 ο ο ο ο ο ο ο ο ο 0 0 t 5 ό 6 o 〇ό ό ό o o ό ό ό ό 6 si SI ^ TU: ^ Usage (parts by mass) 1 1 O oo &lt;N «r&gt; cs &lt;N »Λ CS 5/15 ο Ό rs tN 5/15 •Λ CS I ο o 〇1 u. Ξ UU (N U. tu uL F-1/F-3 fN U. CN ΰ. pi F-2/F-4 CS U. t U. cs uL &lt;N U. [E] Polymeric compound use Amount (parts by mass) 1 s 100 O o 80/20 i 60/40/10 50/50 0 ο Ο 80/20 1 30/30/40 40/40/20 30/30/40 Ο 500 〇〇 ώ UJ s ώ El/E-4 Hl/E-2/E-6| E-4/E-5 ώ 〇〇ώ 卜 U1 Ε-8/Ε-2 'Ε-3/Ε-4/Ε-5 Ε-3/Ε-4/Ε-5 Ε-1/Ε-2/Ε-8 ώ ώ ώ 包 Inclusion compound or [D] Amine compound usage (parts by mass) - — — — — 一 - - - » ο Ο ο (Ν 1 ΙΛ 种类 Category &lt;N ΙΝί N Z-4 : •rj NN 卜N 〇〇N Os Ν Ζ-10 Ν Ό Ν 〇\ Ν 〇s NJ Ζ-10 ' • • D-5 [B] Colorant usage (parts by mass) Gg 80/20 90/60 ; 40/40 0 0 80/20 90/60 1 40/40 Ο ο ο 40/40 ο g Ο 90/60 90/60 Type ώ B-2 Bl/B-2 B- 3/B-4 1 B-5/B-6 B-7 B-8 Bl/B-2 Β-3/Β-4 1 1 Β-5/Β-6 Β-7 Β-8 Β-7 Β -5/Β-6 Β-8 ώ Β-7 B-3/B-4 B-3/B-4 [A] Ingredient Usage (Parts by mass) Ο 80/20 ooo 0 0 0 ο ο ο ο ο 0 ο ο ο o 0 Category 5 Al/A-2 &lt;A-3; A-3 A: 3 1 A-3 A-4 Α-4 I Α-4 Α-4 Α-4 &lt; Α-5 Α-5 5 5 CJ A-4 A-5 Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8 1 Embodiment 9 1 Example 10 Example 11 Example 12 Example 13 Example 14 1 Example 15| Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 201224652 It is understood from the results of Table 1 that the colored composition of the present invention has good storage stability. In addition, it is understood that the colored pattern formed of the colored composition is formed by firing at a low temperature of 200 ° C or lower, but is excellent in developability, heat resistance, solvent resistance, and voltage holding ratio. Further, it is understood that the color filter having the colored pattern has excellent flatness. [Industrial Applicability] The colored composition of the present invention contains a dye as a coloring agent, and can also store storage stability and low-temperature firing, and obtain development resistance, heat resistance, solvent resistance, and voltage retention. Excellent color pattern and color filter. Therefore, the coloring composition can be suitably used for a color filter for a color display element, a color filter for color decomposition of an image sensor, a color filter for an organic EL display element, or a flexible display such as an electronic paper. It is manufactured by various color filters such as color filters. [Simple description of the diagram] None. [Main component symbol description] None. -70-

Claims (1)

201224652 VII. Patent application scope: 1. A colored composition comprising: [A] a compound having an epoxy group, [B] a colorant, [C] a compound having a hydroxyl group or a carboxyl group, and [D] amination &lt; The compound has a viscosity at 25 ° C of 1.0 mPa.s or more and 50 mPa or less. 2. The colored composition of claim 1, wherein the [D] amine compound can be included in the [C] compound. 3. The coloring composition of the first aspect of the invention, wherein the [C] compound is at least one compound selected from the group consisting of compounds represented by the following formulas (1) and (2), and The [D] amine compound is a microphone. Sit compound or benzo. Meter. Sitting on the compound, COOH -7 1- 201224652 (In the formula (1), χ is a single, ^ Α ρΙ ώ8 early bond, methylene or carbon atom is μ alkyl group, R1~R1 quoting xq Ζ~6 λαρ梵. An alkyl group independently a hydrogen atom, a carbon atom number Λι η , a halogen atom, a magnetic double horse 1 to 12 „ . ^ ^ A alkoxy group having 1 to 12 atoms, or a stupid group which may have a substituent J Μ In the formula (2), R2 is a rock Ε ^ , an alkyl group having an anatomical number of 1 to 12, an alkoxy group having a carbon number of 1 to 12 or a thiol group. For example, the color composition of the applicant's patent range &quot;J., the compound of the above formula is injured 4 8 U) 'Under the Μ Μ - 1, Μ t ά ^ ΐ / l · person (1-1) r7 V^oh R R6 (in the formula (1-1), Y ... patent r heart to: R8 and the above formula ("): meaning). The color composition of any one of the four items, which is called an amine compound, and the second part of the green patent, are partially contained by the [C] compound. The color composition of any one of the items 4, wherein the [A]% oxygen compound is a polymer. 7. The coloring composition of the eighth of the eight patents, wherein the above polymer further contains a carboxyl group. -72- 1 A coloring composition according to any one of items 1 to 4, wherein the step (5) contains a polymerizable compound having an ethylenically unsaturated bond. The colored composition according to any one of claims 1 to 4, further comprising a [F] sensitizing radiation polymerization initiator. A colored composition according to any one of claims 1 to 4, which comprises a [D] amine compound inclusion compound, [A] epoxy compound and [B] The colorant is mixed and prepared, and its viscosity at 25 t is 1.0 mPa.s or more and 50 mPa_s or less. A method for producing a colored composition, comprising the steps of: mixing an inclusion compound of a [D] amine compound contained in a compound [C] with an [A] epoxy compound and a [B] colorant, And the viscosity at 25 ° C is below 1.0 mPa.s or more below 50 mPa.s. 12. A coloring pattern formed by the colored composition of any one of claims 1 to 10. A color filter having a colored pattern as in item 12 of the patent application. 1 4. A color display element having a color filter as in claim 13 of the patent application. A manufacturing method of a color filter, comprising: (1) a step of coating a coloring composition according to any one of claims 1 to 10, and forming a coating film on a substrate (2) a step of forming a colored pattern on the coating film, and (3) a step of firing the colored pattern at 200 ° C or lower. -73- 201224652 IV. Designation of Representative Representatives (1) The representative representative of the case is: None. (2) A brief description of the symbol of the representative figure: 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: