TW201110999A - Hair dressing cosmetic - Google Patents

Abstract

Disclosed is a hair-dressing cosmetic which exerts good hair-dressing effect and hair-redressing effect, although being water-based and having a low viscosity, shows no stickiness and high smoothness and gives the sense of a favorable light finish. Specifically disclosed is a hair-dressing cosmetic containing (a) 0.1-10 mass% of a pressure-sensitive adhesive resin having pressure-sensitive adhesiveness, and (b) 0.1-10 mass% of a hair-setting resin, characterized in that said pressure-sensitive adhesive resin (a) has such properties that a film of 0.1 mm in thickness that is formed of a composition containing said resin substantially at a ratio of 50 mass% has, after drying for 1 day at 25 DEG C and humidity 50%, a pressure-sensitive adhesiveness of showing a ball number of 1-30 in the inclined ball tack test (inclination angle 30 DEG, measured at 25 DEG C, humidity 50%). Thus, a hair-dressing cosmetic, which exerts good hair-dressing effect and hair-redressing effect, shows no stickiness and high smoothness, gives the sense of a favorable light finish, and is suitable for application by mist-spraying, can be obtained.

Description

201110999 VI. Description of the Invention: [Technical Field to Which the Invention Is Along] The present invention relates to a cosmetic for finishing a hairstyle. In more detail, there is a cosmetic material for low-viscosity and excellent hair-lifting and hair-reforming ability, which is not sticky, smooth, and has a good lightness after finishing the hair. [Prior Art] Conventionally, in a cosmetic material for styling hair, a hair styling resin such as a hair fixing polymer or a film forming polymer is blended for the purpose of making a shape. However, hair styling resins have problems such as hardening, non-uniformity of the film, and poor retention of the shape under high humidity. Therefore, various countermeasures have been taken to solve this problem. For example, JP-A-2007-217314 (Patent Document 1) discloses that a polymer compound for hair fixing, a polyol, a monohydric alcohol, and a propellant (propellant) are used in combination. The powder cosmetic has good hair style refining and does not have a sticky feeling but has a natural sensation. Japanese Laid-Open Patent Publication No. Hei 11-100312 (Patent Document 2) discloses a hair cosmetic having a specific low-viscosity polyether compound and a polymer resin compound. The whole Wei holding power will not produce a sense of thief, and the hair can be groomed by hand to comb the hair. Japanese Patent Publication No. Hei 3_26m3 (Patent Document No.: It is described with a specific polyoxyalkylene group (ρ〇1γοχ> Λγ1_-based compound and/or polyoxyalkylene-glyc〇side). High-molecular-weight polyethylene glycol for hair fixing (molecular i 6_~3__ 敎 敎 敎 , , , , , 。 。 。 。 。 。 。 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古Bulletin (patent document $ describes: with a combination of two sexes «V knife, sugar yeast, sugar alcohol touch (for example, the base composition of sugar alcohol, which has a crane, stereotype (four) retention, no fine coffee ^ makeup Japanese Patent Publication No. 2_-5()59() No. 2 (Patent Document 5) discloses that a specific ratio of a hydrolyzable hydrocarbyl di-p-synthesis compound is blended in a specific ratio, and a liquid is fed with a liquid 201110999 carrier ( Mn (hai (10) 〇 composition, its remodeling and feel is good. However, in the above-mentioned bulletin, especially in the water system, the use of the degree of enthalpy is not in the silk / teach _ _ in the job The purpose or subject of the cosmetics of the whole material type can be fully satisfied by the ability to achieve the avoidance and hair reforming power. Degree, in addition to Ι 生 生 生 生 生 生 生 生 生 生 生 生 生 生 生 生 生 生 生 生 生 生 生 生 生 Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι Ι In the case of a sufficient styling power and a styling power, a cosmetic material for styling hair styling is used in a water-based low-viscosity. [Prior Art Document] [Patent Document 1] Japanese Patent Laid-Open No. 2007-217314 (Patent Document 2) Japanese Patent Japanese Patent Laid-Open No. Hei. No. 3 (Patent Document 3) Japanese Patent Laid-Open Publication No. Hei 20-II-Iran (Patent Document 5) Japanese Patent Special Table 2004- 505902 bulletin [Summary of the Invention] The problem of the above-mentioned knowledge of the ducks, the purpose of which is to provide a low viscosity and good hair styling and hair reforming, and will not be sticky, smooth, and hair styling. After the end, it is easy to organize the hairstyle. u [The way to solve the problem] Adhesive force research, found that: by a quantitative combination of the established '丨a and hair styling resin, you can Solve the above problems The present invention has been completed. P 'The present invention provides - _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Adhesive adhesive resin 1·1 to 10% by mass; and (b) hair-type resin 0.1~; [〇% by mass. [Effect of the invention] The invention is used for finishing hair styling Since the resin and the μ component are prepared to have a low viscosity, they are particularly suitable for spraying into a mist, and at the same time, exhibit excellent hair styling and hair reforming power, and are excellent in water resistance. 201110999 [Embodiment] Adhesively said that the test of the adhesiveness of the special-purpose silk-based resin according to the rolling test of the muscle coffee refers to the test method of the adhesion of the device shown in Fig. 1. Specifically, 'the sample to be measured (adhesive substance f) is placed on the top of the measuring device of the figure', and the non-adhesive sheet is covered from the top of the inclined surface to the running path of 1 coffee. (runway), when the ball of a predetermined material and size is buckled from the top of the inclined surface 4 in the county area - position stop _ middle 'special adhesion is specified by the number of the most A-size ball. The adhesive resin used in the present invention is a composition having a mass percentage of 5% by mass of the resin, and a thickness of G lmm is formed on the inclined surface of the layer 1 (4), and the pit is 50%. The next step is to use the fineness of the day and implement the rolling ball test. The adhesive having the following adhesiveness is used as the adhesive resin of the present invention: the measurement condition is such that the inclination of the inclined surface in the measuring apparatus shown in Fig. 设为 is 30 degrees ' at 25. (The measurement is carried out at a temperature of 50%, and the ball number is 丨~, for example, more preferably 3 to 25. The specific example of the adhesive resin used in the present invention is acryl-based Ucryl) resin. For example, Acron^YjMOD'Acron^vmap Acronai^^, AciOnal®V210, A_al®V212 (above is BASF), NC〇R38_〇88A,

Dur〇-Tak87-200A, Dur〇-Tak387-2054/87-2051 (above, manufactured by National Starch & Chemical Co., Ltd.), MG-0560, MG-0580 (above, manufactured by Dow Coming Co., Ltd.), alkyl acrylate DAITOSOL 5000AD (manufactured by Daito Kasei Co., Ltd.), YODOSOL AH955, PRIMAL PS83-D (manufactured by Rohm & HAAS Co., Ltd.), and the alkyl methacrylate/alkyl acrylate copolymer. Further, as the adhesive resin used in the present invention, an adhesive styling resin obtained by polymerizing the following monomer A and/or monomer B, monomer C and monomer D may be selected. Monomer A: by the following formula: 201110999 [Chemical 1]

(A) wherein R1 is Η or CH3' η is an integer from 0 to 30, and the monomer represented by (, OH, OCH3, OO^CH3 or phenyl) contains a branch, and R2 is a H monomer B. : The following formula: , less - species. [Chemical 2]

(6) (wherein R3 is Η or (3⁄4 ' R4 and R5 may be the same or may be an integer of 1 to 3, R, is Η, 或 or a NR, U,,,, R, and R, is (CH2 1R,, 1 is at least one of the monomers represented by H or an alkyl group of C1 to C3." The same or different, and the monomer C: is represented by the following formula: [Chemical 3] /6

H2C=CC=0 / (C), R7 (wherein R6 is H or CHyp is an integer from 1 to 100, and the integer π of mg〇~3〇 is h, OH, 〇CH3, OCH2CH3 or stupid, X is 氡At least one of the monomers represented by ethylene (E〇), oxypropylene (p〇), oxygen 201110999 butenyl (BO) or glyceryl. Monomer D: in the following formula:

(wherein R8 is Η or CH3, q is an integer of 1 to 1 ,, γ is an ethoxyethyl group (E〇), an oxypropylene group (PO), an oxybutyl group (B0), or a carbon number of 5 or more. At least one of the monomers represented by the linear or branched oxygen group (〇xyaikyiene) or the glyceryl group (when Y is an oxyalkenyl group having 5 or more carbon atoms, q is 丨)). 【化5】

In the above formula (I), R1 to size 9, 11, 111, and the composition of the constant-fat fat used in the present invention are difficult to be represented by the formula (1). 1 is the same meaning as the above formula VIII~0. In addition, the terms used in this specification are used in a general sense, for example, oxyethylene (E〇), intragastric (P0), and oxybutylene (BO) systems mean carbon numbers 2, 3, and 4, respectively. A linear or branched oxyalkenyl group. Further, a in the above formula (1) is 40 < a < 400, b is 80Sb < 300, c is 3 〇 < c < 300, and d is a number within the range of 〇 < d < 1 。. 201110999, the amount of the adhesive resin (the polymer of the formula (1)) on the foot is substantially as follows: 7.5 < A < 62_5, guilty B < 45, 7 5 < c < 6 (four) < d = 5 body quality The adhesive styling resin used in the present invention can be obtained by enthalpy and/or 8 of the above monomers. And 〇 〇 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当 适当For example, it can be obtained by using a polymerization initiator [2,2,-azobisisobutyronitrile (2), two azobisisobutyromtrile) in ethanol to carry out thermal polymerization 8' under about 赃, and can be obtained. The polymer is appropriately purified and used. Examples of the adhesive resin of the silicone type are SD4584, SD4560, SD4570, SD4580, SD4585, and SD4587L (the above is manufactured by Toray DOW SILICONE Co., Ltd.) and tsr of addition reaction type polyoxazine. ^2, Dingxun (5) 6 (the above is m〇mentive company system) and so on. In the present invention, the resin which satisfies the adhesive condition is not limited to the specific examples listed above, and one type or two or more types may be used in combination. The amount of the adhesive resin in the cosmetic of the present invention is 〇 〜1〇% by mass, more preferably 〇5 to 7.5% by mass. When it is less than 0.1% by mass, the desired effect cannot be obtained, and if it exceeds 1% by mass, a sticky feeling is generated. The cosmetic material for styling hair of the present invention, in addition to the above adhesive resin, also contains a hair styling resin, which can improve moisture resistance by being combined with a hair styling resin. The hair styling resin which can be combined with the cosmetic of the present invention means an anionic, cationic, amphoteric or nonionic film forming polymer which is also called a setting agent or a styling resin, and can be a conventional hair styling agent. Collocation. Specific examples include the following. Acryl and vinyl hair styling resins: Anionic materials are alkyl acrylate/diacetone acrylamide copolymers (Plus size L-53P, Plus size L —9909B, Plus size L—9948B, etc. (all manufactured by Mutual Chemical Industry Co., Ltd.), and mercaptopropionate (S)/octyl acrylamide copolymer (Dermacryl 79 (Japan NSC Limited) Company)), polyethylene glycol / polypropylene glycol-25 / polydimethyl oxime / acrylate copolymer (Luviflex SILK (manufactured by BASF)), acrylic acid / decyl acrylate / ethyl acrylate copolymer (Ultra Hold 8, Ultra Hold Strong (manufactured by BASF Corporation), alkyl acrylate (S-type) copolymer (Anicet NF-1000, Anicet HS-3000, etc. (manufactured by Osaka Organic Chemical Industry Co., Ltd.)). 201110999 Amphoteric substance is octylamine acrylate / hydroxypropyl acrylate / butyl methacrylate copolymer (AMPHOMER SH30, AMPHOMER LV - 71 (made by NSC Co., Ltd.)), 曱基丙佛Methacryloyl oxyethyl carboxylbetaine / alkyl acrylate copolymer (Yukaformer R205, Yukaformer 301, Yukaformer SM, Yukaformer 104, etc.), RAM resin 1000, RAM resin 2000, RAM resin 3000, RAM resin 4,000 (made by Osaka Organic Chemical Industry Co., Ltd.), dimethyl diallyl (alallyl) vaporized ammonium/acrylic acid copolymer (MERQUAT280, MERQUAT295 (made by NALCO) ), dimethyl diallyl vaporized ammonium / acrylamide / acrylic acid copolymer (MERQUAT plus 3330, MERQUAT plus 3331 (made by NALCO)). The cationic substance is vinylpyrrolidone/dimethylamine ethyl methacrylate copolymer diethyl sulfate (HC PolymerlS (M), HC Polymer 2 (manufactured by Osaka Organic Chemical Industry Co., Ltd.), Gafquart 755N (manufactured by ISP) )), vinylpyrrolidone / dimethylaminopropyl monomethacrylamide / dodecyl dimethylaminopropyl monodecyl acrylamide copolymer (STYLEZEW-20 (manufactured by ISP)), vinylpyrrolidone / hydrazine , Ν-dimethylamino methacrylate ethyl acrylate / alkyl acrylate / tripropylene glycol diacrylate copolymer (Cos-cut GA467, Cos-cut GA468 (Osaka Organic Chemical Industry Co., Ltd.), poly Gasified dimethylmethylene piperidine (MERQUAT 100 (manufactured by NALCO)), dimethyldiallyl vaporized/acrylamide copolymer (MERQUAT 550 (manufactured by NALCO)), gasified trimethylamine Propyl-acrylamide/dimethyl methacrylate copolymer, etc. The nonionic substance is polyethylene σ pirone (Luviskol K17, Luviskol K30, Luviskol K90 (manufactured by BASF), PVP K (ISP) Company)), vinylpyrrolidone / acetic acid Ester copolymer (PVP/VA S-630, PVP/VA E-735, PVP/VA E-335 (manufactured by ISP), Luviskol VA73W, Luviskol 37E (manufactured by BASF Corporation), PVA-6450 (Osaka Organic Chemical Industry Co., Ltd.)), methyl vinyl mystery / alkyl maleate copolymer (GANTREZA-425, GANTREZES II 225, GANTREZES - 335 (made by ISP)), vinylpyrrolidone / methacryl Amidoxime/ethyleneimidazole copolymer (Luviset Clear (manufactured by BASF)), polyethylene caprolactam (Luviskol Plus (manufactured by BASF)), etc. Urethane hair styling resin: 201110999 ... Yodosol PUD (Nippon NSC Co., Ltd.), pu r (Bna company), Japan Special (5) Mm3·, the polymer described in the bulletin, acrylic acid-carbamic acid vinegar is DynamX (made by NSC Co., Ltd.) ), the polymer described in Japanese Patent No. 183144. Polysaccharide hair styling resin: ° gum agabic, dextran, sucrose (succjn〇giyCan), carrageenan (carrageen), paulownia tree (gum karaya), sassafras (4) let & _), guar gum / 卜 槐 槐 胶 加 (10) ^ lion galactomannan xanthan gum, temple powder, carob gum (carob gum), 榲Alfalfa seeds (_ce ―), bristle protein, dextrin, gelatin, sodium pectinate, sodium sulphate, thiol cellulose, ethyl cellulose, methyl cellulose, hydroxyethyl cellulose, fine cellulose , microcrystalline cellulose, gasified 〇_[2_绿—3一(三甲叙)propyl] via ethyl cellulose, gasified 〇[[2_丝_3_(三甲叙)propyl] guar gum , gasification Ο - [2 - hydroxy - 3 - = formazan, Shilong Ί Ί 丨 一 一 一 一 一 一 一 一 一 一 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 〕 槐 槐 槐 槐 槐. (2) The hair styling resin to be used for the styling of the hair styling of the present invention is not particularly limited, and may be used in the case of selecting one or two or more types of the edging dough, as described above. A hair styling resin based on a base, an ethylene base, or a urethane vinegar. = The amount of the hair styling resin in the hair cosmetic of the Ming, "0" is generally 01 to 1 22 ίί ° 5~7.5 f amount%. If the amount is less than 1%, the moisture resistance is insufficient, and the right combination is more than 10% by mass. The secret of the lining hair style of the present invention is silk weaving, and when the hair is applied, the solvent is quickly volatilized to exhibit adhesiveness. Specifically, it is preferable to reduce the under-pit type to the IGOmPa·s when measured as the b-type viscous, and the effect of the present invention is exerted by the (four) fog-forming slit. If the viscosity is larger than IGGmPa · s, there is a case where the fog is uncomfortable (4), and a problem such as a nozzle that blocks the spray device is often caused. Further, in the case of the cosmetic material for finishing hair of the present invention, makeup === heavy nT. By creating a predetermined range, the stickiness applied to the hair can be suppressed, and the hair reforming power can be improved. Specifically, it is preferable that the side of the present invention has a thickness of qh after drying at 25t and a humidity of 50%, and the ball test (the measuring device shown in FIG. The angle is set to 1 G degree, and the ball age is u, more preferably 3 to 25, when measured under the machine. When the adhesion is as low as the ball number 1 does not stop, the hair styling force will be insufficient, and the ball with the adhesion higher than the ball 3G will stop the squama, and the hair age will be silky. Further, the cosmetic material for tidying up the hair of the present invention is preferably classified into an oil containing 〇〇1 to 5% by mass, more preferably 0.1 to 3% by mass. By containing oil, it gives the hair a smoother feel.

The oil-separating system used in the present invention is not particularly limited, and it is possible to select an oil component which has been affixed to a cosmetic material, particularly a hair cosmetic, since the prior art. For example, heayy isoparaffin (= hydrogenated polyisobutylene), light isoparaffin (for example IS〇pER a, same c, same E, same G, same H, same K, same L, The same as the above (all are made by EXXON), SHELLSOL 71 (made by SHELL), SALTROLL 100, the same 130, the same 220 (all of which are manufactured by Philip), etc., squalane, liquid sarcophagus (liquid) Paraffin) and other hydrocarbon oils; cetyl-2-ethylhexanoate, 2-ethylhexyl palmitate, octyl undecyl alcoholic acid vinegar (2-〇ctyldodecylmyristate), neopentyl Alcohol adipate vinegar, tetradecanoic acid isopropyl sulphate, nutmeg mellow bean acid and vegetable g (myristyimyrjst^e), pentaerythritol tetrakis (2-ethylhexanoic acid) vinegar and other vinegar; olive oil, crocodile Pear oil, jojoba oil, sunflower oil, red oyster sauce, tea oil, macadia nut oil, mink oil, lanolin oil, acetylated lanolin (acetylatedlanolin), castor oil and other oils; polydimethyl oxime, polymethyl phenyl oxalate, high degree of polymerization ( Gum) polydimethyl sylvestre, polyether modified silicone, amine modified polyoxy siloxane, low boiling eucalyptus oil, (hexamethylcyclotrisiloxane) ), octamethyltetracycline (including "EXECOLD-4" (made by Shin-Etsu SILICONE Co., Ltd.), "SH244", "SH344" (all manufactured by Toray Comw Silicone Co., Ltd.), etc. Pentaoxanes (such as "EXECOL D-5" (Shin-Etsu SILICONE), "SH245", "DC345" (all manufactured by Toray Corning Silicone Co., Ltd.), etc. For example, "DC246" (Dongly Dow Coming Silicone Co., Ltd., etc.), tetradecyl sulfoxide, etc., etc.; fluorinated polydidecyl fluorene, fluorine modified polymethyl Fluorine-based oils such as phenyloxane, perfluoropolyether, and perfluorocarbon, etc. Also, it can be exemplified by mono- to tetrahydric alcohol or EO of mono- to tri-valent tarenic acid. PO adduct 201110999

(adduct) UNILUBE 50 MB 168 &gt; UNILUBE MB370, TRIOL G-40, SAVON DOR SGP-7, SAVON DOR GP-9 (above for Nippon Oil Co., Ltd.). In the present month, it is preferable to use water and alcohol (alcohol) in addition to the above-mentioned adhesive resin and hair-type resin. The amount of the alcohol or the alcohol selected from the alcohols generally used in cosmetics, such as ethanol, may be appropriately selected as the alcohols to be used for the rinsing of the medicinal herbs. The definition ' can be appropriately adjusted in the above-mentioned established adhesion and weaving method. The cosmetic material for finishing hair of the present invention is Wei (four) 丨iquid), foaming _ foam) hair mousse, hair spray, hair _, hair, hair蠛 各种 各种 各种 各种 各种 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' Make (four) cranes. By using it as a filament, it is possible to accelerate the volatilization of (4) and quickly exert the adhesion/finishing power. The cosmetic material for tidying up the hair of the present invention can be used, for example, in accordance with the form thereof, in combination with other components conventionally used for finishing hair styling cosmetics, without damaging the effects of the present invention. <Examples> Hereinafter, the present invention will be described in more detail with reference to specific examples, but the present invention is not limited to the following examples. In addition, the amount of the collocation in the present specification means "mass% is wide" and "manufacturing example and comparative manufacturing example" are polymerized by the monomer composition shown in the following Table 1, and the modulation is not included and can be used in the present invention. Comparative Production Example i of the adhesive fixing resin (Production Examples 1 to 6) and the monomer c, and Comparative Production Example 2 without the monomer D. Specifically, 100 parts by weight of a monomer is mixed in advance. The mixture was placed in a dropping fiinnel to which the mixture was added, a reflux cooling gas, a thermometer, a nitrogen exchange tube, and a flask equipped with a stirrer having a capacity of 1 L, and 1 part by weight of ethanol was placed in the nitrogen gas. The temperature was raised under a stream of air and a reflux state was formed (about 80 Torr), and 1 part by weight of a polymerization initiator (2,2-mono-isobutyronitrile) was added to the ethanol, and the mixture was continuously dropped for 2 hours. Thereafter, it was allowed to stand under reflux for 8 hours to carry out polymerization. Secondly, the solvent content of the solution was adjusted by distilling off the solvent from the solution in the five flasks and adding ethanol, that is, 12 201110999 A cosmetic base solution having a solid content concentration of 50% [Table 1] Classification chemical structure (trade name) Manufacturer's manufacture example 1 Manufacturing example 2 Manufacturing example 3 Manufacturing example 4 Manufacturing example 5 Manufacturing example 6 Comparative manufacturing example 1 Comparative manufacturing Example 2 A butyl acrylate luminescence 40 35 30 15 40 A Ethyl acrylate East Asia synthesis 30 30 A octadecyl methacrylate (BLEMMERSMA) Nippon oil A hydroxyethyl acrylate (HEA) Osaka organic 15 30 A methacrylate Ethyl ethyl ester (ALIXC-1) East Asian synthesis 15 B Dimethyl acrylamide (DMAA) Xingrenhua 40 30 30 40 35 30 B Diamyl propyl acrylamide (DMAPAA) East Asian synthesis 20 C Acrylic polyoxyethylene Glycol ester (n= 10) (BLEMMER AE-400) Nippon oil 55 20 15 15 30 C Polyoxypropylene glycol acrylate (n=6) (BLEMMER AP-400) Nippon oil 20 20 30 55 D Dioxyethylene diacrylate Glycol m (n=23) (NK ESTER A-1000) Xinzhongcun Chemical 5 5 5 5 5 D Dioxyethylene glycol diacetate S (n=14) (NK ESTER 14G) Xinzhongcun Chemical 5 D Dioxane Glycerin (BLEMMER NDMA) Nippon Oil 5 &l t; Examples and Comparative Examples&gt; 13 201110999 The adhesiveness of the adhesive resin of the following Table 2 was measured by a ball test. In addition, the result of the ball test in the table is "one", indicating that the adhesion is low and the number 1 ball is not stopped. [Table 2] Adhesive resin ball test (30 degrees, 25. (: 'humidity 50%) type (manufacturer) trade name _ propylene fluorene system (BASF company) Acronal® YJ2720D 1 propylene fluorene system (BASF company ) Acronal® V215ap 12 da Vinyl acetoacetate DAITOSOL 5000AD 4 alkyl methacrylate n-butyl acrylate / ethyl hexyl acrylate / mercapto methyl acrylate copolymer emulsion ul) 1 矽 烷 ( Dow Coming Company) SD4584PSA 4 Adhesive Styling Resin for Production Example 3 - 5 Vinyl Acetate s-dine 5301 (*1) n-Butyl Acrylate / 2-Ethylhexyl Acrylate / Methyl Methacrylate Copolymer Emulsion ( Dadong Chemical Co., Ltd.), the resin solids in the resin emulsion: water = 1: 1. Next, the samples of the compositions disclosed in Tables 3 and 4 below are prepared, and the hair styling force, the fixing force, the surface reforming force, and the age resistance are used to evaluate the sample, and the results are shown in Tables 3 and 4 » In addition, the evaluation methods and evaluation criteria for each characteristic are as follows. 1. Hair styling in a black hair (virgin hair '2Gem, 2g mass) coated with a sample 〇 5g and dried at room temperature, based on a functional test conducted by a consulting expert The ease of finishing your hair. &lt;Scoring Criteria&gt; 5 points. Very easy to organize hairstyles 4 points: slightly easy to organize hairstyles 3 points: 2 points for ordinary: slightly difficult to organize hairstyles 1 point: difficult to organize hairstyles 201110999 &lt;evaluation criteria&gt; ◎: Total score 40 Points above: Total score of 30 or more and less than 40 points △: Total score of 20 points or more and less than 30 minutes X: Total score of less than 20 points 2. Fixing power on black natural hair (length 15cm, weight lg) The sample is coated and shaped to make it Μ, that is, * every 1 unit of sample contains 5 _ 丄 验 验 涂 ' ' ' 调 调 调 调 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 】 The bending length of the hair bundle (b) is produced by the hair of the hair that is bent at the temperature (a), and the length of the tuft of the test hair (a) is determined in advance according to the following 4 calories/曰 uncoated 3 material. Nail-type tree fixing force (the higher the fixing force is, the better the fish-resistance is better when it is close to 100%. The number of knots is not improved.) [Standards for evaluation] Hair style retention (%) is called (ab)/a}xlo〇 ◎ _·値 is more than 90% 〇: 値 is less than 70~90% △: 値 is less than 50~70% x : 値 is less than 50% 3. Hair styling force is on a black natural hair (length 20cm, Mass 2g) eclipse ^ After the hair bundle after drying, the hair immediately after the finishing touch of cloth, and then at room temperature G.5g material 4 can organize tests to evaluate their hair! = Hours entire official full force experts performed again). The easiness of the body t material (hair weight &lt;scoring benchmarks &gt; 5 points: very hair style re-strength force 4 points: slightly hair style re-strength force 3 points: ordinary 2 points: slightly no hair style re-strength force 1 point : No hair reforming power &lt;Evaluation Criteria&gt; 15 201110999 ◎: Total score of 40 points or more 总: Total score of 30 points or more and less than 40 points △: Total score of 20 points or more and less than 30 points X: Total Divided into less than 20 minutes 4. Moisture resistance 0.5 g of the coated sample (the hair cosmetic obtained in the example or the comparative example) on a black natural hair (length 20 cm, weight 2 g), immediately using a curl of 2 cm in diameter The curler made a curl 'was dried at 50 ° C for 1 hour, and then measured the length of the curled hair bundle, and took the length as an initial value (L0). The second 'dry hair bundle After hanging on a scaled plate and placing a constant temperature and humidity machine at a temperature of 3 〇 Qc and a twist of 90% RH for 3 hours, the length of the hair bundle was measured and the length was taken as the length after humidification (L2). As the length of the hair bundle, if it is in the state of curling, it is the maximum diameter of the curl, on the other hand, if the curl is partially or whole Pull|, is the maximum length from the end of the hair root side (for example, from the end of the hair root side to the length of the hair tip). Calculate the curl retention value according to the following formula, according to the following evaluation Evaluation of moisture resistance. Early retention of curling 値(〇/〇) = {(20-L2) / (20__L〇)} χ1〇〇 ί 为 以 is closer to the dirty curl, the stronger the retention rate, the moisture resistance Sex (ie, hair style retention &lt; evaluation criteria) ◎• Curl retention 値 is 90% or more. 卷曲. Curl retention 値 is 70% or more and less than 90%. △··Curl retention 値 is 50% or more 70%. Χ. Curl retention silk is 50% full. 16 201110999 [Table 3] Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 10 Water 100% of the total amount of ethanol 10 10 10 10 10 10 10 10 10 10 10 Acronal® V215ap 10 10 10 10 10 DAITOSOL 5000AD 10 10 10 10 10 (vinylpyrrolidone / vinyl acetate) copolymer 5 5 alkyl acrylate ) / diacetone acrylamide copolymer 5 5 season Ammonium salt 1 1 15 5 (mercapto propylene oxime oxy-rebellion 'base beet test / dazzle> acrylic acid (ester) type) copolymer 5 5 曰 特 2006 2006 2006-213706 Resin 5 5 Total 100 100 100 100 100 100 100 100 100 100 Fixing force 〇〇〇〇 ◎ 〇〇〇〇 ◎ 整 〇 〇〇〇〇 〇〇〇〇 〇〇〇 〇〇〇 Hair styling reform 〇〇〇〇〇〇 〇〇〇〇财湿〇 〇〇 〇〇◎ 〇◎ 〇〇◎ 17 201110999 [Table 4]

Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Water made 100% overall 1 Ethanol 10 10 10 10 10 10 10 10 10 Acronal® V215ap 10 DAITOSOL 5000AD 10 (B Dilute piroxanone/vinyl acetate) Copolymer 5 succinic acid (ester) / diacetone acrylamide copolymer 5 polyquaternium 1 5 5 (methacrylofluorene oxyethyl carboxyl beet test / succinic acid (ester) copolymer 5 胺 特 2006 2006 2006-213706 urethane resin 5 total 100 100 100 100 100 100 100 100 100% fixed force X Δ Δ 〇〇 0 〇 ◎ Hair styling X 〇〇 XXXXXX hair styling force X 〇〇 XXXXX 18 201110999 Moisture resistance XXX △ ◎ oo ® Other implementations are shown below. &lt;Example 11&gt; Liquid styling agent (1) Ion exchange water residue (2) PEG-6 5 (3) PEG-8 5 (4) PEG-32 5 (5) Sorbitol 1 (6) Ethanol 50 (7) Proper amount of perfume (8) Adhesive styling resin of Production Example 3 (9) Alkyl acrylate/diacetone acrylamide copolymer 2 (10) Amount of citric acid &lt;Preparation method&gt; (2)~ The water-soluble component of (5) is added to (1) water and stirred to dissolve to form water parts. Next, (7) is added to (6) and mixed, and after it is made soluble, (8) to (9) are added and stirred to prepare alcohol parts. The water portion and the alcohol portion are mixed, and (10) is added to obtain a liquid styling agent. &lt;Example 12&gt; Liquid styling agent (1) Ion exchange water residue (2) PEG-6 3 (3) PEG-8 3 (4) PEG-32 3 (5) Sorbitol 2 (6) Ethanol 40 (7) Proper amount of perfume (8) Adhesive styling resin of Production Example 3 (9) Alkyl acrylate/diacetone acrylamide copolymer 3 19 201110999 1 Appropriate amount (10) PPG-40 - Ding Zhen (U) Citric Acid &lt;Preparation Method&gt; The water-soluble component of (2) to (5) is added to (1) water and she is solubilized to prepare water 4. Next, (7) is added to (6) and _ to make it soluble, and (8) to (9) are added and stirred to prepare an alcohol portion. The water portion and the alcohol portion are mixed, and then added (type agent. Dan added U 〇) (11) to obtain a liquid solution &lt;Example 13&gt; Liquid styling agent (1) Ion exchange water residue 7 7 10 1 5 Appropriate amount 1 2 Moderate amount (2) PEG-6 (3) PEG-32 (4) Maltitol (5) PEG/PPG-55/28 Two shouts (6) Ethanol (7) Spice (8) Acronal® V215ap (9) Dilute acid (vinegar) / diacetone acrylamide (1 〇) citric acid (η) phenoxyethanol &lt; preparation method> Department. Next, (7) is added to (6) ethanol and stirred (, 2, mixed and dissolved, aged (3)) and mixed to prepare an alcohol portion. The water portion is mixed with the alcohol portion, and then j = (1), (9) liquid styling agent is added. σ added (8) (10) is the phase

[Simple diagram of the figure J Figure 1 shows the device used for the ball test. f main component symbol description] None 20

Claims (1)

201110999 VII. Application for Patent Fanyuan: 1. A cosmetic material for finishing hair, comprising (a) an adhesive adhesive resin 〇丨~chuan mass%; and (b) a hair styling resin (u~10% by mass) The cosmetic material is characterized in that: (a) the adhesive resin has a film having a thickness of 0.1 mm and a composition containing the resin in a mass percentage of 5% by mass, and is dried at 25 Torr and a twist of 5 〇%. Tilting ball test in the future (inclination angle 30 degrees, 25 (:, 50% of the fishing degree) + adhesion of the ball number 1 to 3 。. 2. As stated in the first item of the application scope A cosmetic material for finishing a hair style, wherein the viscosity of the cosmetic material is l〇〇mPa·s or less, and a B-type viscosity meter). 3. The hair style for finishing the hair as described in the second or second aspect of the patent application. A cosmetic material, wherein the cosmetic material has a film formed by using the cosmetic material to form a film having a thickness of Q lmm, and is subjected to a tilting ball test (inclination (four degrees), pit) after drying for one day at 25 degrees [5]. The number is the adhesion of Buchu. 4. As stated in Item 1 to Item 3 of the patent scope of claim 4 The cosmetic material of the lining finishing surface, wherein the cosmetic further contains 001 to 5% by mass of the oil component. ^, as claimed in claim 4, the cosmetics of the hair styling according to Item 1 to Item 4, wherein When the cosmetic is used, it is sprayed into a mist and used.