TW200826841A - An agro-horticultural pesticidal composition - Google Patents

Abstract

The subject of the present invention is to provide a novel agro-horticultural pesticide composition, the using method and the agro-horticultural pest controling method, which has an excellent pesticidal effect to the mites etc. harmful to the agro-horticultural plants, without the phytotoxicity to the plants to be treated and being safe to man and beast. The present agro-horticultural pesticide composition is characterized in that it contains, as the active component, a mitochondrial electron transfer inhibitor and ethiprole.

Description

200826841 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to fenpyroximate, tebufenpyrad, pyridaben, fenazaquin and diphene A cultivating insecticide composition comprising one or more compounds selected from the group consisting of mitochondria electron transport inhibitors and ethiprole as an active ingredient, and methods of using the same, and agricultural and horticultural Pest control methods. [Prior Art] Fenpuff (ISO name, chemical name: 4-({[(1,3-dimethyl-5-phenoxy-4-pyrazolyl)methylene]aminooxy)methyl) ) tert-butyl benzoate; tert-butyl 4-( {[ (1,3-dimethyl-5-phenoxy-4-pyrazolyl) methylidene]aminooxy}methyl)benzoate, mouth-to-manganese (ISO name, chemical name: N-(4-Tertibenzyl)-4-chloro-3-ethyl-1-methylpyrazole-5-nonylamine; N-(4-tert-butylbenzyl)-4-chloro-3-ethyl- 1-methylpyrazole-5-carboxamide), Pythaben (ISO name, chemical name: 2_t-butyl-5-(4-t-butylbenzylthio)-4-chloro-3(2H)-嗒2-tert-butyl -5-(4-tert-butylbenzylthio)-4-chloro-3(2H)-pyridazinone), fentan (ISO name, CAS name: 4-[4_(1,1- Dimethylethyl)phenyl]ethoxyquinazoline; 4-[[4-(1,l-dimethylethyl)phenyl]ethoxy]quinazoline), acetazone (ISO name, chemical name: 5-chloro- N-{2-[4-(2-ethoxyethyl)-2,3-dimethylphenoxy]ethyl}-6-ethylpyrimidin-4-amine; 5-chl〇:ro~ N-{2-[4_(2-ethoxyethyl)-2,3-dimethyl-phenoxy] 200826841 ethyl b 6-ethylpyrimidin-4-aiiiine) is well known The compound is known to have acaricidal activity or the like (see, for example, Non-Patent Document i). Although these compounds are structurally different, they all have a mechanism of action called METI: Mitochondrial Electron Transfer Inhibitors. A compound (see, for example, Non-Patent Document 2) is known to act on a mitochondrial respiratory chain complex I. A composition of agricultural and horticultural acaricides obtained by mixing fenfluramine with other compounds, etc. A mixture of agro-horticultural acaricide and fipronil, which is selected by a majority of pharmaceutical agents (see, for example, Patent Document 1), is multiplied with a drug-resistant leaf mites, and Fenpuri and gram A mixture of chlorphenapyr (see, for example, Patent Document 2) has a multiplication effect, but a compound selected by Fenflu, Pilomanil, Pitaben, Fenicide, and Pidifen is not known or 2 A composition of a mixture of the above compounds in combination with ethylpro. The above Epro (ISO name, CAS name: 5-amino-l-(2,6-dichloro-4-trifluoromethylphenyl)-4-ethylsulfinyl-1Η-Π than Π-3 - Residual nitrile; 5-amino-l-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-(ethylsulfinyl)-1H-pyrazole-3-carbonitrile) is a known compound itself, known to have arthropods The plant nematode, the protozoan pest, the termite, the agricultural pest, the animal parasite, etc. are characterized by the permeation effect, and have an insecticidal effect on the aphid of the sucking pest and the aphid parasitic on the animal (see, for example, Patent Document 3). It is also a compound that absorbs juice, but does not exert a killing effect on agricultural and horticultural mites such as leaf mites. Alan wood's website (h 11 p : / / w w w · alanwood.net/pesticides/index.html), which is not classified as pesticides, is not classified as 200826841 acaricide. In the above-mentioned document (Patent Document 3), which has an insecticidal effect, it is described as an example of a pesticide which can be mixed as a composition, but it is a case of a mitochondrial electron transport inhibitor. No specific pharmacy name is given. It is known that a mixed composition containing an insecticidal mixed composition of epropro and an indoxacarb having a high insecticidal effect against lepidoptera such as the diamondback moth, the noctuid, and the snail, etc. (see, for example, Patent Document 4), However, the mixed composition with the mitochondrial electron transport inhibitor is also unknown. [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei No. 2000-502095 (Patent Document 3) 6,492, 3 57 specification [Non-Patent Document 1]

The Pesticide Manual Thirteenth Edition 2003 [Non-Patent Document 2] "Pesticide Development in Japan, 1.2 mitochondrial electron transport inhibitor", Japan Institute of Pesticide, issued on January 10, 2005, p.170~175 】 【The subject to be solved by the invention】 -7- 200826841 Injury of fruit trees, vegetables, tea, other crops, horticultural plants or trees, etc. The leaf mites are very damaging to the harvest, and the price of the lost goods is very high, so the leaf mites are controlled. It is important to use a variety of agricultural and horticultural acaricides effective against spider mites to carry out their control. However, the use of the same agent frequently showed significant drug resistance in the leaf mites. It also has cross-resistance between the existing agrochemical horticultural acaricides, and it is more difficult to prevent leaf mites. In addition, the cockroaches and leaf mites of the damaging rice have been controlled by the ancient times, but the requirements for the new defensive method are still high. [Means for Solving the Problem] In view of the above-mentioned situation, the inventors of the present invention have made efforts to create a new combination of agro-horticultural acaricide compositions and various insecticides, and have been repeatedly researching for agricultural and horticultural mites such as leaf mites.乙 普 罗 殆 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , The effect of the cockroach was found to also enhance the insecticidal effect on the planthopper and leaf mites, and finally completed the present invention. The agricultural and horticultural use of the compound containing one or more selected from the group consisting of fenfluramine, pyridinamine, piracetin, fentanyl and chlorpheniramine as an active ingredient in the mitochondrial electron transport inhibitor of the present invention The insecticide composition is resistant to the drug-developing leaf mites, and has a synergistic effect that cannot be conceived by the effect of each agent alone, and has a multiplication effect on the planthopper and the leafhopper. That is, the present invention relates to: [1] A composition for agricultural and horticultural insecticides, characterized in that a mitochondrial electron transport inhibitor and ethiprole are contained as an active ingredient. [2] The agricultural and horticultural insecticide composition according to [1], wherein the mitochondrial electron transport 200826841 inhibitor is fenpyroximate, tebufenpyrad, pyridaben One or more compounds selected from the group consisting of fenazaquin and pyri midi fen. [3] A pesticide composition for agriculture and horticulture as in [1] or [2], which is an acaricide composition. [4] The agricultural and horticultural insecticide composition of [1] or [2], which is an insecticide composition of the planthopper and leafhopper. [5] A method of using a pesticide composition for agricultural and horticultural, characterized in that the agricultural and horticultural insecticide composition according to [1] or [2] is treated with an effective amount of the plant. [6] A method for controlling a drug-resistant mites, which comprises treating a plant with an agricultural and horticultural insecticide composition according to [1] or [2] in an effective amount. [7] A method for controlling a drug-resistant mites, characterized in that a compound selected from 1 or 2 or more selected from fenfluramine, piranol, piracetin, fentanyl and chlorpheniramine The plant is treated with a sufficient amount of the above compound and the dilution of ethyl prolacil containing the compound of the foregoing compound in an effect of multiplication. [8] A method for controlling a drug-resistant mites, characterized in that a compound selected from the group consisting of fenfluramine, piranol, piracetin, fentanyl and chlorpheniramine or a compound of 2 or more is used as an active ingredient. The composition was treated at the same time with the two dilutions diluted with the composition containing the ethylpren as an active ingredient. [9] A use of Epro Pro to enhance the acaricidal effect of mitochondrial electron transport inhibitors. [10] - a method for controlling planthoppers and spider mites, characterized in that it comprises a compound selected from 1 or 2 selected from fenfluxen, piranol, pidaben, fentanyl and diphenanthrene as 200826841 The plants were treated with a sufficient amount of the above compound and a dilution of ethyl prolacil in an amount of a mixture containing the aforementioned compound and epropro. [11] A method for controlling spider mites and leaf mites, characterized in that a compound containing one or more selected from the group consisting of fenfluramine, pyridinamine, piracetin, fentanyl and chlorpheniramine is used as an active ingredient The composition containing the composition and the two dilutions of each of the components containing the ethylpreo-containing active ingredient are treated at the same time. [Effects of the Invention] The agricultural and horticultural insecticide composition of the present invention is resistant to chemicals. For example, agricultural and horticultural mites such as leaf mites can exert synergistic effects that cannot be conceived by the effects of each medicinal agent alone, such as leaf mites on plants such as fruit trees, vegetables, tea, other crops, horticultural plants or trees. For the horticulture and horticulture of cockroaches, especially for the control of cockroaches, it is not necessary to invest a large amount of medicinal materials, and it is possible to prevent agricultural and horticultural mites, such as medicinal mites, especially for chemically resistant mites. Improve the productivity of the plant. Further, the agricultural and horticultural insecticide composition of the present invention of the present invention exerts an excellent multiplying effect on, for example, the planthoppers and leaf mites of the scorpion mites and the like which are harmful to rice, and can effectively prevent the mites and leaf mites. Plants such as rice can be developed to improve their productivity. Further, the agricultural and horticultural insecticide composition of the present invention has no phytotoxicity to the treated plants, and can be safely used for humans and animals. BEST MODE FOR CARRYING OUT THE INVENTION The agricultural and horticultural insecticide composition of the present invention can be used in combination with the granule electron transport inhibitor of the first active ingredient compound and the second active ingredient compound. . The mitochondrial electron transport inhibitor should preferably be fenfluramine. The amount of each active ingredient compound to be added to the agricultural and horticultural acaricide composition of the present invention can be appropriately selected from the range of about 0.1 to 50 parts by mass, and is preferably selected from the range of about 1 to 20 parts by mass. Further, in the agricultural and horticultural insecticide composition of the present invention, the ratio of the addition of the mitochondrial electron transport inhibitor to the ethyl pupro can be used in an amount of about 0.05 to 20 by mass of the granule electron transport inhibitor. The range is suitably selected, and it is preferred to use Epro Pro to be selected from the range of about 11. When the agricultural and horticultural insecticide composition of the present invention is used, it is dissolved, suspended, pulverized, mixed, and kneaded in an appropriate ratio with an appropriate inactive carrier and necessary auxiliary agents according to a conventional method on a pesticide preparation. , impregnation, sorption or adhesion, etc., according to the purpose of use, into a suitable dosage form, such as emulsions, emulsion suspensions, powders, granules, water and agents, floatables, granule water and agents, lozenges, giants or A bag or the like is used. The inactive carrier usable in the present invention may be solid or liquid, and the material which can be used as a solid carrier may be, for example, soybean powder, cereal flour, wood flour, bark powder, saw powder, tobacco stem powder, walnut shell powder, bran. , cellulose powder, residue after plant extraction, synthetic polymer such as pulverized synthetic resin, clay (such as kaolin, bentonite, acid white clay, etc.), talc powder (such as talc, pyrophyllite, etc.), tannins { For example, diatomaceous earth, strontium sand, mica, white carbon (water-containing micro-powder, also known as high-dispersion tannic acid of aqueous citric acid, which is mainly composed of calcium citrate according to the product)}, activated carbon, sulfur powder, Inorganic mineral powder such as pumice, sputum algae, brick pulverized material, fly ash, sand, sodium sulfate or magnesium carbonate, plastic carrier such as polyethylene, polypropylene, polyvinyl chloride, ammonium sulfate-11 - 200826841, ammonium phosphate, Chemical fertilizers such as ammonium nitrate, urea, ammonium chloride, etc., compost, etc., which are used alone or in combination of two or more. The material which can be used as the carrier of the liquid can be selected from those which have the ability to be solvent-free, but which are dispersed by the auxiliary component, such as the representative examples. It may be used singly or in combination of two or more kinds, such as water, alcohols (for example, methanol, ethanol, isopropanol, butanol, cyclohexanol, ethylene glycol, diethylene glycol, propylene glycol, hexanediol, polyethylene) Glycols, polypropylene glycols, etc.), ketones (such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, cyclohexanone, 7 - butyrolactone, etc.), ethers (such as diethyl ether, dioxane,赛路苏苏, dipropyl ether, tetrahydrofuran, etc.), aliphatic hydrocarbons (such as kerosene, mineral oil, etc.), aromatic hydrocarbons (such as benzene, toluene, xylene, mineral spirits, alkyl naphthalene, etc.), halogenated hydrocarbons (e.g., dichloroethane, chloroform, carbon tetrachloride, chlorobenzene, etc.), esters (e.g., ethyl acetate, diisopropyl phthalate, dibutyl phthalate, dioctyl phthalate, etc.), guanamine Classes (eg dimethylformamide, diethylformamide, dimethylacetamide, etc.), nitriles (eg acetonitrile, etc.), dimethyl hydrazines, nitrogen-containing carriers (N-alkylpyrroles) An ketone or the like, or a fat or oil (for example, vegetable oil, soybean oil, olive oil, corn oil, coconut oil, castor oil, etc.). Representative examples of the auxiliary agent are exemplified as follows. These auxiliary agents are used depending on the purpose, and it is also possible to use two or more kinds of auxiliary agents alone or in some cases without using an auxiliary agent at all. For example, polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene higher fatty acid ester, polyoxyethylene resin acid ester, polyoxygen can be used for the purpose of emulsification, solubilization and/or wetting of the active ingredient compound. Ethylene mono 12-12- 200826841 sour sorbate, polyoxyethylene sorbitan monooleate, polyoxyethylene phenylethyl phenyl ether, sodium dioctyl sulfonate, alkyl aryl sulfonate, naphthalene sulfonic acid A condensate (for example, a sodium salt of a β-naphthalenesulfonic acid formaldehyde condensate; a membrane road τ (Kao Yadola); etc.), a surfactant such as a lignosulfonate or a higher alcohol sulfate. For the purpose of dispersion stabilization, adhesion and/or binding of the active ingredient compound, for example, casein, gelatin, starch, methylcellulose, carboxymethylcellulose, xanthan gum, gum arabic, polyvinyl alcohol, pine root can be used. An auxiliary agent such as oil, eucalyptus oil, bentonite, and lignosulfonate. For the purpose of improving the fluidity of the solid product, an auxiliary agent such as a wax, a stearate or an alkyl phosphate may also be used. As the deagglomerating agent for the suspension product, for example, an auxiliary agent such as a naphthalenesulfonic acid condensate or a condensed phosphate can be used. As the antifoaming agent, an auxiliary agent such as an anthrone oil can be used. The preservative may be added with sodium formate, potassium sorbate, 1,2-benzoisothiazoline-3-one (trade name: Pro X el GXL), p-chloro-xylenol or butyl peroxybenzoate. If necessary, functional additives, antifreeze such as propylene glycol, BHT temple antioxidants, UV absorbers and other adjuvants may also be used. If necessary, an activity enhancer such as a functional exhibiting agent such as a fluorene, a polyamide resin or a polyoxyethylene/polyoxypropylene higher fatty acid ester, or a metabolic decomposition inhibitor such as a butyl oxidized sunflower base, ethylene glycol or the like may be added. Antifreeze such as ethylene glycol or propylene glycol, antioxidants such as butylated hydroxytoluene (BHT) or butylated hydroxymethoxybenzene (bha), hydroquinone-based ultraviolet absorbers, salicylic acid-based ultraviolet absorbers, and benzophenone-based ultraviolet absorbers Agent, benzotriazole-based ultraviolet absorber or acrylic acid cyanide-13-200826841 ultraviolet absorber such as ultraviolet absorber, or other auxiliary agent such as methyl cellulose, polyvinyl alcohol or sodium polyacrylate anti-drift agent, etc. . The agricultural and horticultural insecticide composition of the invention further prevents the target pests, expands the control period, or reduces the dose, as long as the preparation is stable, and can be combined with other agricultural and horticultural insecticides (acaricides), It can be mixed with agricultural and horticultural, nematicides, fungicides or biological pesticides, and can be mixed with herbicides, plant growth regulators or fertilizers according to the use scene. The agricultural and horticultural insecticide composition of the present invention can be used for controlling various mites of agricultural and horticultural plants, especially citrus leaf mites (Panonychus citri), apple leaf touches (Panonychus ulmi), cotton leaf mites (developed with resistance to medicinal plants) T e trany chus urticae Koch), Tetranychus kanzawai Kishida, Tetranychus cinnabarinus, Tetranychus viennensis Zacher, Brevipalpus phoenicis or Brevipalus lewisi ) Tea woven (Polyphagotarsonemus) in addition to rust, such as leaf contact, Calacorus carinatus, Aculops pelekassi, Epitrimerus pyri or Eriophyes chibaensis ) or cockroaches such as Tyrophagus piitrescentiae have significant synergistic effects, especially for the drug-resistant Aesthesia sinensis. The agricultural and horticultural insecticide composition of the present invention can also be used for controlling mites and leaf mites, for example, Arbo rid ia apical is, tea green ji, Taiwan black tail _ (Nephotettix virescens) ), stripe flying 51 -14· 200826841 (Laodelphax striatellus), rice brown squirrel (Nilaparvata lugens), back white locust (Sogate 11a furcifera) and other planthoppers and leaf mites have a multiplication effect 'special damage to the rice planthopper And leaf mites, especially for Nephotettix cincticeps. The useful plant for use in the agricultural and horticultural insecticide composition of the present invention has no limitation 'may be, for example, anthraquinones (for example, rice, barley, wheat, rye, oats, corn, etc.), beans (soybeans, red beans, broad beans, Peas, broad beans, peanuts, etc.), fruit trees, fruits (apples, roots, oranges, pears, grapes, peaches, plums, cherries, walnuts, chestnuts, almonds, candies, strawberries, etc.), leaves, fruits and vegetables (cabbage, tomatoes) , spinach, broccoli, lettuce, onion, onion, green pepper, eggplant, pepper, etc.), root vegetables (carrots, potatoes, sweet potatoes, artichokes, radishes, lotus roots, turnips, burdock, garlic, etc.), processed materials (cotton, Hemp, beets, hops, sugar cane, beets, olives, rubber, coffee, tobacco, tea, etc.), melons (pumpkin, courgette, melon, watermelon, cantaloupe, etc.), pasture (bluegrass, alfalfa, ladder grass, clover,苜蓿,), turf (Korean grass, pontoon, etc.), spices, etc. (Lavender, scented, thyme, parsley, pepper, ginger, etc.), flowers (Chrysanthemum, rose) , Carnations, orchids), Chamber wood (ginkgo, cherry, corals wood, etc.), trees (Sakhalin fir class, shrimp Yi Song category, conifers, Japanese cypress, cedar, guns, etc.) and other plants. Further, the useful plant can also be genetically recombined, etc., so that the insecticidal active ingredient is in the growth process. The insecticidal active ingredient may be, for example, a Bt (Bacillus thuringiensis; soil bacteria) toxin or the like. When the agricultural and horticultural insecticide composition of the present invention is used, the composition of the preparation according to the purpose can be diluted or used in water or the like, and the application amount thereof depends on the mixing ratio of the -15-200826841 effect component and the meteorological condition. The form of the preparation, the method of application, the place of application, the pest to be controlled, or the difference, usually a total of about 10 to 100 g per 1 000 acre of the two active ingredients. The agricultural and horticultural insecticide composition of the present invention can be applied to a perfumed proliferative body 'especially stems, leaves, seeds, bulbous seeds, bulbs or seeds referred to as seeds, or fruits, and the like. Such as spreading or spraying to the foliage or stems, seed treatment (such as seed coating, etc.), soil application (such as granules, etc.). In the treatment of the seed, the comparison with the seed quality is preferably in the range of about 0. 1 to 10 parts by mass of the total of the two active ingredients. In the case of emulsion or water and release application, the application concentration is from 0.02 to 0.1% by mass in the form of granules, powders or seeds, and it is usually applied without dilution. In the case of soil application, the agricultural product of the present invention can usually be made into a water spray or a natural rainfall action or the like throughout the field or crop cultivation area to be treated. It can also be spread or sprayed on the soil of the seedlings such as seeds or seedlings. It can also be used for spreading and spraying on the soil near the plant. The period of application of the soil may be pre-planting of seeds or seedlings, or before or after germination. The invention further relates to the treatment of fenfluxane, piranol, Pythaben, and crops, and the treatment of ~200g, to be repelled, etc.: sputum (the following method can be used as a soaking or granule cloth) Or a range of 100 parts by mass of a field spray, such as a water-based thinner, such as a liquid, such as a liquid, such as a liquid, such as a liquid, which is dispersed in the soil, or the like, is applied to the soil, or is sprayed or the like. Application, planting or planting, Fenicide or complete-16-200826841 Tern et al. The mitochondrial electron-contrast agent and the anti-defective method of the drug used in the treatment of acetaminophen. The form of the composition of the present invention containing the mitochondrial electron transport inhibitor and ethylpro is applied to the above-mentioned proliferator which is inhabited by, for example, a drug-resistant mites to be repelled, for example, the granules of the present invention. When the linear electron transport inhibitor is applied to the composition containing the active ingredient and the composition containing the ethylpren as an active ingredient, it may be mixed in the same ratio as the composition of the present invention, and diluted and mixed to prepare the mixed composition. The composition to be applied in combination with the mixture may be prepared by using a composition containing the granule electron transport inhibitor as an active ingredient and a composition containing Epropro as an active ingredient at any concentration, or may be separately applied at the same time. In this case, the application amount of the mitochondrial electron transport inhibitor and ethylpro is preferably the same as the application amount of the present invention. In the present specification, the term "control" means, for example, agricultural and horticultural pests (for example, mites). , planthoppers, spider mites and leaf mites), killing, inhibiting, inhibiting, preventing or preventing, protecting plants by damage from agricultural and horticultural pests. The present invention relates to the cultivation of agricultural and horticultural killers for enhancing the granule electron transport inhibitor The use of 普 之 。 。 。 。 。 。 。 。 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农 农The mitochondrial electrons of agricultural and horticultural mites enhance the killing effect of the inhibitors, so the mitochondrial electrons convey the inhibitors at low concentrations, such as the usual mitochondrial electrons to convey the inhibitors to the farmer's art. The effective amount of acaricidal mites can also exert a killing effect, and the mitochondrial electrons convey an inhibitor to obtain a drug resistance, and the drug resistant mites which can not exert their effects in the usual effective amount of acaricidal can also Play a killing effect. Granular electrons • 17 - 200826841 Conveying inhibitors such as Yifenpu, Pilomantan, Pitaben, Fenicide or Diphene. Epro Pro and the above-mentioned agricultural and horticultural killing of the present invention In the tanning agent composition, the same amount of the use of the mitochondrial electron-transporting inhibitor Eppro can enhance the agro-horticultural acaricidal action of the mitochondrial electron transport inhibitor. The prevention method of the class can also make the mitochondrial electron transport inhibitors such as fenfluramine, pyridinamine, piracetin, fentanyl or diphenanthrene in the same package as Epolo, and package the mitochondrial electrons. It is used to convey the killing kits for agricultural and gardening, which are mixed with the inhibitor and Eppro, especially for the kits for the resistance of cockroaches. The present invention relates to a method for controlling mitochondrial electron transport inhibitors such as fenfluramine, pyridinamine, piracetin, fentanyl or diphene phenanthrene, and fly mites and leaf mites for use in eprofen. The mitochondrial electron transporting inhibitor and the cyproterone can be used, for example, for the above-mentioned proliferating body inhabiting the planthopper and leaf mites to be repelled, and the composition of the present invention containing the mitochondrial electron transport inhibitor and ethylprolate is applied. form. The above-mentioned composition may be a composition containing the granule electron transport inhibitor as an active ingredient and a composition containing Epropro as an active ingredient, and mixed at the same ratio as the composition of the present invention at the time of application, by dilution In the form of applying the mixture, the composition of the granule electron transport inhibitor as an active ingredient and the composition containing the Epropro as an active ingredient can be separately prepared at any arbitrary concentration. The form of separate application at the same time. At this time, the application amount of the mitochondrial electron transport inhibitor and ethylpro is preferably adjusted to be the same as the application amount of the present invention described above. In order to carry out the method for controlling the spider mites and leaf mites in the present invention, the mitochondrial electron communication hindering of fenfluxen, pyridoxamine, piracetin, fentanyl or diphenanthrene is hindered by the -18-200826841 agent The package is packaged into the above-mentioned mitochondrial electron communication inhibitor and the mixture of the mites and leaf mites for use in the control of the mixture. The method for controlling the agricultural or horticultural insecticide composition or the agent resistant mites of the present invention, or the method for controlling the mites and spider mites, for example, in the field of veterinary medicine or animal industry or public health maintenance, for animals In particular, for example, human or livestock warm-blooded vertebrates, such as those that are parasitic on cattle, sheep, goats, horses, pigs, chickens, dogs or cats. The mites may be ticks (eg, Ixodes genus (wallworm), Boophilus genus (eg Boophilus microplus), Amb1y omma genus, Hya 1omma genus (transparent wall 13⁄4),

Rhipicephalus genus (eg Rhipicehalus appendiculatus), Haemaphysali s genus, Dermacentor genus, Ornithodorus genus (eg Ornithodorus moubata) and other genus (eg Damalinia genus (Dermahyssus gallinae),

Sarcoptes genus (such as Sarcotes scabiei), Psorotes genus, Chorioptes genus, Demodex genus (懦-shaped), Eutrobiccula genus, and the like. The control of the cockroaches in the animal can be carried out, for example, by oral administration or dispersion in animals. [Embodiment] Hereinafter, the present invention is exemplified by the examples, the test examples, and the like, but the present invention is not limited thereto. [Example 1] (Prescription 1) divided into 1 part by mass -19-200826841 Epro hydrated citric acid 5 parts by mass 3 〇 parts by mass

Hitenol N〇8 (trade name) (manufactured by Daiichi Kogyo Co., Ltd.) 5 parts by mass of 3 parts by mass of 47 parts by mass of calcium lignosulfonate water and agent for soil. In the above prescription 1, active ingredient compounds (Fenfen and Epro) After being impregnated with aqueous citric acid, it is uniformly mixed with other ingredients to form a water and a agent.

Hitenol N08 is a commercial example of polyoxyethylene nonylphenyl ether sulfate. [Example 2] (Prescription 2) Fenpucci 1 〇 part by mass of Eppro 1 〇 part by mass NPE_100 (trade name) (manufactured by Daiichi Kogyo Co., Ltd.) 20 parts by mass of propylene glycol 5 parts by mass of Rhodes Road 23 (trade name) (manufactured by Ronald Brown Co., Ltd.) 2 parts by mass of water 43 parts by mass, the entire components of the above prescription 2 are uniformly mixed into a floatable agent (water dispersant). NPE-100 is a commercial example of polyoxyethylene nonylphenyl ether, and Rhodes Road 23 is a commercial example of xanthan gum. [Example 3] (Prescription 3) 20 parts by mass of 10 parts by mass of 20 parts by mass of Pythaben hydrochloride phthalic acid-20-200826841 SP-3005X (trade name) (manufactured by Toho Chemical Industry Co., Ltd.) 3 0 quality Part of the film road τ (trade name) (made by Kao Yadola Co., Ltd.) 1 〇 parts by mass of xylene 1 〇 by mass The entire ingredients of the above prescription 3 are uniformly mixed and dissolved into an emulsion. S P · 3 0 0 5 X is a commercial example of a nonionic/anionic complex type surfactant 〇 [Example 4] (Prescription 4) Pidifen 1 〇 by mass Epppro 5 parts by mass Aqueous citric acid 30 parts by mass

Hitenol N 0 8 (trade name) (manufactured by Daiichi Kogyo Co., Ltd.) 5 parts by mass of calcium lignosulfonate 3 parts by mass of water and 47 parts by mass of soil for use in the above prescription 4, the active ingredient compound (difen and ethylpro After being impregnated with aqueous citric acid, it is uniformly mixed with other ingredients to form a water and a agent. [Example 5] (Prescription 5) Sodium dioctyl sulfonate 1 part by mass of polyoxyethylene styrene phenyl ether 2 parts by mass of propylene glycol 1 〇 by mass of fluorenone oxime-73 (trade name) (manufactured by Shin-Etsu Chemical Co., Ltd.) 0.5 parts by mass of 152-benzisothiazolin-3-one (trade name: iProxel GXL) 0.1 parts by mass of water 7 7.7 parts by mass - 21 - 26,826,1,1,1,3 parts by weight of dipyridamole, 2.5 parts by mass of xanthan gum 0.2 parts by mass Expanded soil 1 · 〇 mass parts of the above prescription 5; medium, sodium octyl sulfonate, polyoxyethylene styrene phenyl ether, propylene glycol, fluorenone KM-73, 1,2-benzisothiazolin-3-one The water was mixed and dissolved by a stirrer (Η 〇m 〇mi X er, manufactured by Special Machine Chemical Co., Ltd.), and sub-dipyridylamine and ethylprolate were added thereto, and fine pulverization was carried out by a wet pulverizer (Dynomill KDL type, manufactured by Buck Powder Co., Ltd.). . The pulverized material is further mixed with a ton of gum and a refined benton to form a milk-suspended pesticide composition. The above anthrone KM-73 is a commercial example of dimethyl fluorenone oil. [Test Example 1] The insecticidal test for the drug-resistant A. striata was filled with water in a plastic cup having a diameter of 8 cm, and a lid having a hole of 1 cm in diameter was placed, and the upper portion of the lid was placed by the lid hole to be suspended. The filter paper is trapped, and the cut portion of the filter paper is suspended from the hole of the cover to the water, and the filter paper is always wetted by the capillary phenomenon. The leaf of the diameter of 2 cm was prepared from the leaves of the bean (variety: t〇pcr〇P). After the female adult worms of the drug-resistant scorpion scorpion were inoculated into the leaf disc, the leaf discs were placed on the filter paper, and the medicinal preparations prepared in Table 1 were uniformly dispersed in the concentration of the active ingredient of Table 1. The leaf disc placed on the filter paper after the dispersion of the drug solution was allowed to stand in a constant temperature room at 25 °C. After 2 days, the number of living insects was investigated, and the rate of dead insects was calculated (2 consecutive systems). The results are shown in Table 1 below. In Fenpengman, Pilomantan, Pydabamide, Fenicide or Diphene, it was distributed separately. 22-200826841, all of which were resistant to the drug, Aesop's leafhopper, failed to get 100% mortality. The drug-resistance of the 25 ppm of Eppro Prodamine was 0%, and Eproxil had no acaricidal effect on the drug-resistant A. japonicus. However, the combination of Fenfen, Pipanamine, Pydabamide, Fenicide or Diphene and E. Profen 2 5 ppm is 1% of the drug-resistant A. sinensis. The acaricidal effect of Puman, Pirmonamide, Pydabamide, Fenicide or Diphene is significantly increased. This is the result of multiplication of Fenpucci, Pilmtolide, Pydabamide, Fenicide or Diphene with Epro. [Table 1] The active ingredient concentration of the drug is 2曰 (PPm) Dead insect rate (%) Fenpeng + Epro 50+25 100 25+25 100 12.5+25 100 6.25+25 100 3.125+25 100 Fenfen 50 60 25 5 12.5 5 Pilominis + Epro Pro 100+25 100 50+25 100 25+25 100 Piranolamine 100 95 50 45 25 45 Pythaben + Epro 200+25 100 100+25 100 25+25 100 Pythaben 200 75 50 60 25 65 Didifen + Epro 20+25 100 10+25 100 Diphene 20 95 10 70 Epro 25 0 Control (no treatment area) 0 -23· 200826841 The insecticidal activity of tomato rust was tested in a plastic cup with a diameter of 8 cm filled with water, and a lid of a hole of diameter 丨cm was added. The upper part of the lid was placed by the lid of the lid to suspend a part of the cut filter paper. The hole is suspended in the water, and the filter paper is often wetted by capillary phenomenon. A leaf disc of 2 cm in diameter was prepared from the primary leaves of Fanyuan (variety: P 〇 n t e 1. 〇 s a). After inoculation of 10 female adults of tomato rust (Hanoi from Nagano), the leaf disc was placed on the filter paper, and the medicament of Table 2 was prepared into the liquid of the active ingredient concentration of Table 2 ( Add a buried I right (exhibitor) 0 · 0 1 mass%) to spread evenly with a spray gun. After the liquid is dispersed, the liquid is dried and filtered, and the leaf disc placed on the paper is allowed to stand in a constant temperature room at 25 ° C (1 6 hours in the '8 hours dark period). After 2, 6 and 9 days, the number of normal parasites, the corrected dead insect rate, and the insecticidal effect were evaluated by the following grades (2 serial). Test reagents: Fenpeng 5 S C, Epro 1 0 S C. The results are shown in Table 2. S C is a float. , No treatment area normal parasite number - treatment area normal parasite number correction dead insect rate (〇 / 〇) = ---- X 100 no treatment area normal parasite number determination criteria: A ··· correction of death rate 1 0 0 0/. B···Remedy dead insect rate 99%~90% C · · · Corrected dead insect rate 89%~80% D · · · Corrected dead insect rate 79%~50% E· ·· Corrected dead insect rate 50%满-24- 200826841 [Table 2] Insecticidal activity against cockroach

Judgment of drug concentration (2) (ppm) 2 days after 6 days after 9 days Fenpeng + Epro 10+100 DD AA AA 5+100 EE AB AA 2.5+100 EE BD AC Fenpuff 10 EE AC AB 5 EE CD CD 2.5 EE EE EE Epson 100 EE EE EE Review the insecticidal activity of Fenpman SC, Epro Pro SC tomato parasitic tomato rust. As a result, it was found that since Fenpuff was mixed with Eppro, the quick-acting and insecticidal activities were enhanced by 2 to 4 times as compared with the case of single use. [Test Example 3] The insecticidal activity test of the parasitic courgette tea dust mite was carried out in a plastic cup having a diameter of 8 cm filled with water, and a lid having a hole of 1 cm in diameter was placed, and the upper portion of the lid was placed by the lid hole to be suspended. The filter paper is trapped, and the cut portion of the filter paper is suspended from the hole of the cover to the water, and the filter paper is always wetted by the capillary phenomenon. A leaf disc having a diameter of 2 cm was prepared from the primary leaves of the kidney bean (variety: t〇pCr〇p). 10 female adults of tea dust mites (naturally occurring insects from Nagano, Hanoi) were inoculated into the leaf discs, and the leaf discs were placed on the filter paper, and the medicament of Table 3 was prepared into the liquid medicine of the active ingredient concentration of Table 3 ( Buried 〇 〇 · 〇 1% by mass added) evenly spread with a spray gun. After the liquid is dispersed, the leaf disc placed on the filter paper is allowed to stand in a constant temperature room (16 hours, 8 hours dark period) at 25 °C. After 1, 2, 4, and 7 days, the number of normal parasites was investigated, and the test insect worm rate was calculated by the above test example 2 (no connection). Test reagents: Fenpeng 5SC, Epro 10SC. The results are shown in Table 3 below. -25- 200826841 [Table 3] Insecticidal activity against tea dust mites

Density || Concentration effect judgment _ (ppm) 1 曰 after 2 days 4 曰 after 7 days Fenpeng + Epro 5+50 AAAA 0.5+50 DDDB Fenpeng 5 BBBA 0.5 EEEE Epro 50 EEEE Review on Fenpu Mixed effect of tea dust mites with full s C and Epro s C. As a result, it was found that since Fenpuff was mixed with Eppro, the quick-acting and insecticidal activities were enhanced more than those in the case of single use. [Test Example 4] Insecticidal activity against the larvae of the black-spotted larvae of the parasitic rice. The fruit test of the leaf tip of the rice (variety: Jinnanfeng) was prepared into the liquid of the active ingredient concentration of Table 4 (buried) Reno 0.01% by mass added) immersion treatment for 20 seconds. After the leaf tip of the chemical solution was air-dried, a glass test tube containing 2 mL of water having a diameter of 16 mm was placed, and 5 pieces of the black-tailed leafhopper (2 larvae) were inoculated. After the inoculation, the test tube was covered with paper and allowed to stand in a constant temperature room at 25 ° C (1 6 hours, 8 hours dark period). After 1, 3, and 7 days, the number of normal parasites was investigated, and the corrected mortality rate (2 serial system) was calculated by the above test example 2. Test reagents: Fenpeng 5SC, Epro 10SC. The results are shown in Table 4 below. -26- 200826841 Insecticide activity against black larvae larvae concentration of parasites/10 only 113⁄4 worm rate (ppm) 1 曰 after 3 曰 7 days later (after 7 )) Fenpeng + Epro 10+50 10 2 0 100 3+50 10 9 2 80 Fen Pu Man 10 10 5 3 70 3 9 9 9 10 Epro 50 10 10 8 20 Control Area - 10 10 10 - Review the mixture of Fenfen and Epro The synergistic effect of the insecticidal effect of cockroaches. As a result, it was found that since Fenpuff was mixed with Eppro, the insecticidal activity against the black-tailed spider mites was enhanced. The activity is increased slightly later. In addition, it is known from the above-mentioned Test Examples 1 to 4 that the composition (chemical solution) containing the granule electron transport inhibitor as an active ingredient is mixed with the composition (chemical liquid) containing Epropro as an active ingredient, and it is confirmed that 両When the synergistic effect of the active ingredient is used, and the composition containing the granule electron transporting inhibitor and the ethylpyrazine as the active ingredient (for example, a premixed preparation of the mitochondrial electron transport inhibitor and ethylpro), The same multiplication effect. [Simple description of the diagram] 〇 y» nn -27-

Claims (1)

200826841 X. Patent application scope: 1. A pesticide composition for agricultural and horticultural, characterized in that a mitochondrial electron transport inhibitor and ethiprole are contained as an active ingredient. 2. The agricultural and horticultural insecticide composition according to claim 1, wherein the mitochondrial electron transport inhibitor is fenpyroximate, tebufenpyrad, pyridaben, One or more compounds selected from fenazaquin and pyrimidifen. 3. The agricultural and horticultural insecticide composition of claim 1 or 2, which is an acaricide composition. 4. The agricultural and horticultural insecticide composition according to claim 1 or 2, which is an insecticide composition of the planthopper and leafhopper. 5. A method for using a pesticide composition for agriculture and horticulture according to claim 1 or 2, which is characterized in that the agricultural and horticultural insecticide composition according to claim 1 or 2 is effective The amount of plants treated. A method for controlling a medicinal resistant cockroach, which is characterized in that the agricultural and horticultural insecticide composition according to claim 1 or 2 of the patent application is treated in an effective amount. 7. A method for controlling a medicinal resistant mites, characterized in that a compound selected from the group consisting of fenfluramine, pyridoxamine, piracetin, fentanyl and chlorpheniramine and acetoxib is contained in an ethyl pupro The compound of the above compound and the mixture of the above-mentioned compound and the ethyl flurox are treated with a sufficient amount of the above-mentioned compound and the diluted solution of the ethyl sulphate to treat the plant 〇 . . . 药剂 药剂 药剂 药剂 药剂 药剂 药剂 药剂 , , - - - - - - - - - - - - - - - - - A compound containing one or more selected from Manganese, Pydabamide, Fenicide, and Pidifen is an active ingredient-containing composition, and is diluted with two dilutions of each of the components contained in the composition containing Epropro Treat plants in the period. 9. A use of Epro Pro to enhance the acaricidal effect of mitochondrial electron transport inhibitors. 10. A method for controlling planthoppers and spider mites, characterized in that a compound containing one or more selected from the group consisting of fenfluramine, pyridoxamine, piracetin, fentanyl and diphenanthrene is used. The plants are treated with a sufficient amount of the above compound and a dilution of eprolate in a mixture containing the aforementioned compound and epropro. 11. A method for controlling mites and leaf mites, characterized in that a compound containing one or more selected from the group consisting of fenfluramine, pyridinamine, piracetin, fentanyl and diphenanthrene is used as an active ingredient The composition and the two dilutions of each of the components contained in the composition containing Epropro are used to treat the plants at the same time. -29- 200826841 VII. Designated representative map: (1) The representative representative of the case is: None. (2) A brief description of the symbol of the symbol of the representative figure Μ 八 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: