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SU585187A1 - Space-network built-up polymer for cation exchangers and redoxites and method of preparing same - Google Patents

Space-network built-up polymer for cation exchangers and redoxites and method of preparing same

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Publication number
SU585187A1
SU585187A1 SU762322972A SU2322972A SU585187A1 SU 585187 A1 SU585187 A1 SU 585187A1 SU 762322972 A SU762322972 A SU 762322972A SU 2322972 A SU2322972 A SU 2322972A SU 585187 A1 SU585187 A1 SU 585187A1
Authority
SU
USSR - Soviet Union
Prior art keywords
polymer
redoxites
cation exchangers
meq
confirming
Prior art date
Application number
SU762322972A
Other languages
Russian (ru)
Inventor
Людмила Павловна Финн
Ирина Борисовна Слинякова
Михаил Григорьевич Воронков
Наталья Николаевна Власова
Флора Петровна Клецко
Original Assignee
Иркутский институт органической химии СО АН СССР
Институт Физической Химии Им. Л.В.Писаржевского Ан Украинской Сср
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Иркутский институт органической химии СО АН СССР, Институт Физической Химии Им. Л.В.Писаржевского Ан Украинской Сср filed Critical Иркутский институт органической химии СО АН СССР
Priority to SU762322972A priority Critical patent/SU585187A1/en
Application granted granted Critical
Publication of SU585187A1 publication Critical patent/SU585187A1/en

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  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Claims (2)

В их спектре имеетс  интенси полоса колебаний при 2560 , подтверждает наличие SH -групп полосы колебаний при 2920 и 298 подтверждают наличие метилеиово пы. Свойства полученного простра но-сшитого полимера, содержащег -H5CHj3iO,5-. Истинный удельный вес, Суммарный объем пор,см7г2,5 Предельно-сорбционный объем пор, смуг CgHj0,31 CHjOH0,30 ,12 Удельна  поверхг ность, tf/r 162 Теоретическа  емкость, мг-экв/г8,7 Обнаружена также избирательн сорбци .| атионов Ло, Hg , РЬ , , Ni , окислительно-восстановительна  емкость составл ет 7,6-8 мэкв/г ксерогел . Таким образом, вновь полученный пространственно-сшитый полимер может быть использован в качестре катионообменника и редоксита в цессах органического синтеза. Формула изобретени  1.Пространственно-сшитый полимер, содержащий звень  НЗСН &Ю - дл  катионообменников и редокситов. In their spectrum, there is an intense oscillation band at 2560, confirming the presence of SH - groups of oscillations at 2920 and 298 confirming the presence of methylanes. Properties of the resulting spliced polymer containing -H5CHj3iO, 5-. True specific gravity, Total pore volume, cm7 g2.5 Maximum sorption pore volume, cmr CgHj0.31 CHjOH0.30, 12 Specific surface area, tf / r 162 Theoretical capacity, mEq / g8.7 Selective sorption was also found. | Ations Lo, Hg, Pb, Ni, the redox capacity is 7.6-8 meq / g xerogel. Thus, the newly obtained spatially crosslinked polymer can be used as a cation exchanger and redoxite in organic chemical processes. Claim 1. Spatially-cross-linked polymer containing NZSN & Yu units for cation exchangers and redoxites. 2.Способ получени  полимера по п. 1, отличающийс  тем, что провод т гидролиз меркаптометилтриэтоксисилана в cпиptoдиoкcaнoвoй смеси в присутствии кислого катализатора с последующими конденсацией продукта гидролиза при рН 7,8-8,2 и сушкой при 100-110 С в вакууме. Источники информации, прин тые во внимание при экспертизе: IIАдсорбенты, их получение, свойства и применение Труды 3-го Всесоюзного совещани  по гщсорбентам, Л., Наука, 1971, с. 78-81.2. A method for producing a polymer according to claim 1, characterized in that the mercaptomethyltriethoxysilane is hydrolyzed in the ethylamine mixture in the presence of an acidic catalyst, followed by condensation of the hydrolysis product at pH 7.8-8.2 and drying at 100-110 ° C in vacuum. Sources of information taken into account in the examination: IIAbsorbents, their preparation, properties and applications Proceedings of the 3rd All-Union Conference on Absorbents, L., Nauka, 1971, p. 78-81.
SU762322972A 1976-02-11 1976-02-11 Space-network built-up polymer for cation exchangers and redoxites and method of preparing same SU585187A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU762322972A SU585187A1 (en) 1976-02-11 1976-02-11 Space-network built-up polymer for cation exchangers and redoxites and method of preparing same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU762322972A SU585187A1 (en) 1976-02-11 1976-02-11 Space-network built-up polymer for cation exchangers and redoxites and method of preparing same

Publications (1)

Publication Number Publication Date
SU585187A1 true SU585187A1 (en) 1977-12-25

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Family Applications (1)

Application Number Title Priority Date Filing Date
SU762322972A SU585187A1 (en) 1976-02-11 1976-02-11 Space-network built-up polymer for cation exchangers and redoxites and method of preparing same

Country Status (1)

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SU (1) SU585187A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0983969A3 (en) * 1998-08-31 2000-07-19 Dow Corning Corporation Method for removing metal contaminants from solution using mercapto-functional silica xerogels
EP1062031A4 (en) * 1998-02-09 2001-04-04 Ind Science & Technology Netwo ION SEPARATION WITH SURFACE TREATED XEROGEL

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1062031A4 (en) * 1998-02-09 2001-04-04 Ind Science & Technology Netwo ION SEPARATION WITH SURFACE TREATED XEROGEL
EP0983969A3 (en) * 1998-08-31 2000-07-19 Dow Corning Corporation Method for removing metal contaminants from solution using mercapto-functional silica xerogels

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