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SU133878A1 - The method of obtaining unsaturated alcohols - Google Patents

The method of obtaining unsaturated alcohols

Info

Publication number
SU133878A1
SU133878A1 SU660476A SU660476A SU133878A1 SU 133878 A1 SU133878 A1 SU 133878A1 SU 660476 A SU660476 A SU 660476A SU 660476 A SU660476 A SU 660476A SU 133878 A1 SU133878 A1 SU 133878A1
Authority
SU
USSR - Soviet Union
Prior art keywords
unsaturated alcohols
obtaining unsaturated
obtaining
carried out
catalyst
Prior art date
Application number
SU660476A
Other languages
Russian (ru)
Inventor
А.А. Баг
Н.В. Близняк
к Н.В. Близн
В.Г. Черкаев
Original Assignee
А.А. Баг
Н.В. Близняк
к Н.В. Близн
В.Г. Черкаев
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by А.А. Баг, Н.В. Близняк, к Н.В. Близн, В.Г. Черкаев filed Critical А.А. Баг
Priority to SU660476A priority Critical patent/SU133878A1/en
Application granted granted Critical
Publication of SU133878A1 publication Critical patent/SU133878A1/en

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  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

ПооПучение ненасыщенных спиртов путем гидрировани  сложных эфиров ненасыщенных кислот в присутствии различных катализаторов известно.Unsaturated alcohols are prepared by hydrogenating unsaturated acid esters in the presence of various catalysts.

Предложенный способ отличаетс  тем, что, с целью упрощени  процесса , в качестве катализатора примен ют окись цинка с добавками промоторов-соединений кальци  или кадми . Каталитически активна  окись цинка как свободна , так и содержаща  промотирующие добавки приготовл етс  прокаливанием химически неустойчивых соединений цинка (карбоната цинка) при температуре 300° и выше. При этом промотирующие добавки также переход т в окислы (CdCOseCdO) или остаютс  в неизмсином состо нии.The proposed method is characterized in that, in order to simplify the process, zinc oxide with the addition of calcium or cadmium promoters is used as a catalyst. The catalytically active zinc oxide, both free and containing promoter additives, is prepared by calcining chemically unstable zinc compounds (zinc carbonate) at a temperature of 300 ° and above. At the same time, the promoting additives also transfer to oxides (CdCOseCdO) or remain in the nonresin state.

Гидрирование сложных эфиров ненасыщенных кислот проводитс  во врап1ающемс  автоклаве при начальном давлении 110 атм в течение 3 час,Hydrogenation of esters of unsaturated acids is carried out in a rotating autoclave at an initial pressure of 110 atm for 3 hours,

Предмет изобретени Subject invention

1.Способ получени  ненасыщенных спиртов гидрированием эфиров иеиасыщенных кислот, отличак5щийс  тем, что, с целью упрощени  процесса, последний провод т в присутствии катализатора окиси цинка.1. A method for producing unsaturated alcohols by hydrogenating esters of i-saturated acids, which is different in that, in order to simplify the process, the latter is carried out in the presence of a zinc oxide catalyst.

2.Способ по и. 1, отличающийс  телг, что, с целью повыщени  активности катализатора, процесс осуществл ют с добавками в качестве промоторов соединений кальци  или кадми .2. Method for and. 1, characterized by a telg that, in order to increase the activity of the catalyst, the process is carried out with additives as promoters of calcium compounds or cadmium.

SU660476A 1960-03-28 1960-03-28 The method of obtaining unsaturated alcohols SU133878A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU660476A SU133878A1 (en) 1960-03-28 1960-03-28 The method of obtaining unsaturated alcohols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU660476A SU133878A1 (en) 1960-03-28 1960-03-28 The method of obtaining unsaturated alcohols

Publications (1)

Publication Number Publication Date
SU133878A1 true SU133878A1 (en) 1960-11-30

Family

ID=48404867

Family Applications (1)

Application Number Title Priority Date Filing Date
SU660476A SU133878A1 (en) 1960-03-28 1960-03-28 The method of obtaining unsaturated alcohols

Country Status (1)

Country Link
SU (1) SU133878A1 (en)

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