SU1255827A1 - Method of empoyment of heat of weak solution - Google Patents
Method of empoyment of heat of weak solution Download PDFInfo
- Publication number
- SU1255827A1 SU1255827A1 SU817771688A SU7771688A SU1255827A1 SU 1255827 A1 SU1255827 A1 SU 1255827A1 SU 817771688 A SU817771688 A SU 817771688A SU 7771688 A SU7771688 A SU 7771688A SU 1255827 A1 SU1255827 A1 SU 1255827A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- solution
- boiler
- weak
- heat
- strong
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000002826 coolant Substances 0.000 claims description 6
- 230000001172 regenerating effect Effects 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 31
- 238000000926 separation method Methods 0.000 description 5
- 238000009835 boiling Methods 0.000 description 3
- 239000003507 refrigerant Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000010754 BS 2869 Class F Substances 0.000 description 1
- 241000327852 Ompok pabo Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- WSWCOQWTEOXDQX-MQQKCMAXSA-N sorbic acid group Chemical group C(\C=C\C=C\C)(=O)O WSWCOQWTEOXDQX-MQQKCMAXSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B33/00—Boilers; Analysers; Rectifiers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/007—Energy recuperation; Heat pumps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Separation Of Gases By Adsorption (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Description
1one
Изобретение o l iiocmoii к тсп. кпч хи.ике и может быть iipuxieiKMio при спользоиа- нии теплосодержани слабых растворов, образующихс в процессе десорбции рабочей среды и;1и при термическом разде.чении, особенно при абсорб11,ионн1 1х или десорб- ционных процессах с парами рабочего вещества дл холодильной техники и в сорб- циопных тепловых насосах, примен емых дл отоплени и кондиционировани .Invention o l iiocmoii to tsp. kpc chi.icke and iipuxieiKMio can be used when using the heat content of weak solutions formed during desorption of the working medium and; 1 and during thermal separation, especially when absorbed 11, ion1x or desorption processes with vapor of the working substance for refrigeration and in sorbic heat pumps used for heating and air conditioning.
Известен способ использовани тепла слабого раствора путем осуществлени рециркул ции раствора в абсорбционных хо.чо- дильных установках, благодар чему устран етс избыток тепла в самом кип тильнике и предварительное испарение крепкого раствора Gesamte Kalteiridustrie, т. 20, 1913, с. 1-9. 114- -119, 150-161 и т: 21, 1914, с. 7-14, 21-24).A known method of using the heat of a weak solution by recirculating the solution in absorption chillers, thereby eliminating excess heat in the boiler itself and preliminary evaporation of the strong solution of Gesamte Kalteiridustrie, Vol. 20, 1913, p. 1-9. 114-111, 150-161 and t: 21, 1914, p. 7-14, 21-24).
Недостатком этого способа в;1 етс его 1п-1зка термодинамическа эффективность вследстнис возможности реализапли т()Л1,ко при сш ралеобразной павивк( груб, KOTOpiJC ненадежны в эксплуатации.The disadvantage of this method is that its 1p-1zka thermodynamic efficiency is due to the possibility of realizing () L1, as with the use of rallying pavivk (rude, KOTOpiJC are unreliable in operation.
Известен также способ ис.пользовапи тепла слабого раствора путем ocyiiiecTBJie- 1ШЯ противотока в фазе орон1ени при пленочном обтекании смеси внутри верти- кал1)Ных пучков труб и обогреве, осущест- в.л емом снаружи в межтрубпом простраг - стве { -li iUe, т. 2, 28-е изд., с. 244).There is also a known method of using the heat of a weak solution by ocyiiiecTBJie- 1 of the backflow in the oron phase during film flow around the mixture inside the vertical 1) of tube bundles and heated outside the interstitial pipeline {-li iUe, t 2, 28th ed., P. 244).
Недостатком этого способа вл етс , низка эффективность Бследст1 ие 1-;евысоко1-() коэффициента теплопередачи меж.ту слабым и крепким растворами.The disadvantage of this method is that the low efficiency of the Fewst 1-; evisoko1- () heat transfer coefficient between weak and strong solutions.
Наиболее б шзки.м к изобретению но технической супиюсти и достигаемому результату вл етс crioco6 использо1 ани тепла с.пабо1Ч) раствора путем регепера.тивпого теплообмена между слабым и крегп им растворами , имеюн1ими значительную разницу концентраций (патент ГДР № 1249.46, кл. F 25 J 3/02, оцублнк. 1977).The most important to the invention but technical support and the achieved result is crioco6 using the heat of C. pabo) solution by means of reheperative heat exchange between weak and cramped solutions, which have a significant difference in concentrations (GDR patent No. 1249.46, class F 25 J 3/02, Ozublnk. 1977).
Недостатки способа - or|)ain-ineH ie охлаждени теплоносител и бо;нлна разность температур между елаб|)м и крепким растворами.The disadvantages of the method - or |) ain-ineH ie cooling the coolant and bo; nlna temperature difference between the el | | m and strong solutions.
Цель изобретени поньппепие экопо- .мичности путем более no,:inoro испол1)3ова- пи тепла слабого раствора.The purpose of the invention is the understanding of ecopromicity by more no,: inoro ispol1) 3po-pipe heat of a weak solution.
Эта цель достигаетс тем, что еог.часпо способу использовани теп.ла c.-ia6oro раствора путем регенеративного теплообмена между слабым и крепким растворами., имеющими зпачительную раз1-пп.у концентраций, крепкий раствор раздел ют на два параллельных потока, один из которых направл ют в кип тильник, а другой -- в кип - тилышк частичного потока, орошают этими потоками соответственно один пучок обогрева в кип тильнике и одип или пееко.1ько пучков обогрева в кип тил1 нике частичного потока с образованием слабых растворов, объедин ют оба потока в общий ноток слабого раствора и подают в регенера This goal is achieved by the fact that our method of using a solution of c.-ia6oro solution by means of regenerative heat exchange between weak and strong solutions, having an impressive concentration of 1 pp, strong solution is divided into two parallel streams, one of which they are directed into the boiler and the other into the boiler of the partial flow, irrigate these streams, respectively, one heating beam in the boiler and one or more heating beams in the boiler of the partial flow with the formation of weak solutions, combine both flowsin the general note of a weak solution and served in the regenerator
55827.55827.
тивный теплообменник кип тильника частичного потока противоточно крепкому раетвору частичного потока. Кро.ме того, другой поток крепкого раствора дополнительно нодо- гревают посторонним теплоносителем в пучке 5 обогрева.The partial heat exchanger of the partial flow is countercurrent to a strong partial flow heat exchanger. In addition, another stream of strong solution is additionally heated by an external heat carrier in the beam 5 of heating.
На чертеже представлена схема установки , реализующей способ.The drawing shows the installation diagram that implements the method.
Установка содержит кип тильник 1, кип тильник 2 частичного потока, копцептра- 10 ционную колонну 3, нучки 4 и 8 обогрева , устройство 5 разделени , .массообмен- ное устройство 6, регенеративный теплооб- .меппик 7, вход 9 постороннего теп. юноси- тел , выход 10 ностороннего теплоносител , отвод 11 слабого раствора, подвод 12 креп- 5 кого раствора, отбор 13 паров хладагента , распределитель 14, подачу 15 охлаждающей среды, отбор 16 охлажда1оп;,ей среды и дефлегматор 17.The installation contains a boiling unit 1, a boiling unit 2 of a partial flow, a copreciprocal column 3, heating nooks 4 and 8, a separation device 5, a mass exchange device 6, a regenerative heat exchanger 7, an inlet 9 of extraneous heat. liquid collectors, 10-sided heat carrier output, withdrawal of a weak solution 11, supply of a 12 fixing solution 12, selection of 13 refrigerant vapors, distributor 14, supply of cooling medium 15, cooling selection 16, its medium and a reflux condenser 17.
Устарювка ргиТотает следующим образом.The adjustment is as follows.
Крепкий раствор после подвода 12 поступает в )ас11ре,ае. 1ите.ль 14 и раздел етс на два потока, один и:-; к(;то|)ых направ- .л етс в кип тильник 1, а втор.ой -- в па- ралле.льпо вк,110чепн1 1Й кинн гплыщк 2 частичного потока. 1- азделение происходит соот- 25 ветственпо тен;1осол,ержан1по c;ia6oro раствора , собирающе1 ос в нижних част х кип тильника 1, и кип тильника 2 частично- I -o потока ripn незначите.льных и экономически оправданньгх разност х те.мператур между общи.м потоком слабого раствора в 30 качестве средЕЛ обогрева в регенеративный теплообменник 7 кип тильника 2 и вторым потоко.м крепкого раствора. После этого крепкий раствор через устройство 5 разделени поетупает в кип тильник и кип тильник 2 частично1 о потока. Разделение креп- 35 кого раствора па потоки .может 1)оисх(,1дить и пос.. прохождени че)ез масс(}обменное устройство 6.A strong solution after the supply of 12 enters into) as11re, ae. 1.l. 14 and is divided into two streams, one and: -; to (; then |) they are sent to the boiler 1, and the second - to parallo vk, 110chipn1 1Y kinn gnlyshchk 2 partial flow. 1- separation takes place according to the relevant; 1 salt, Yergan1 to c; ia6oro solution, collecting in the lower parts of the boiler 1, and the boiler 2 partially - the I -o stream ripn of insignificant and economically justified differences in temperature. between the general flow of the weak solution in 30 as the medium of heating in the regenerative heat exchanger 7 of the boiler 2 and the second flow of the strong solution. After that, a strong solution through the separation device 5 will flow into the boiler and the boiler 2 partially in the flow. Separation of a solid solution 35 flows: it can 1) oisch (, 1dit and after .. passing through) without masses (} exchange device 6.
Крепкий раствор стекает в ниде пленки через устройство 6 и пучок 4 в кип тильнике 1, соответственно, через устройство 6 и теплообменник 7 или теп.юобменник 7 и пучок 8 н кип тильнике 2 частичного потока. Нри это.м термически отдел ютс легкие компо.че1гты, и образовавшийс слабый раствор собир етсн в нижних част х кип тил1 пиков 1 и 2. Затем оба потока слабого раетвора обл един ютс , и общий поток в качестве среды обогрева направл етс в теплообменник 7 кип тильника 2 про- тивоточ1 О поступающему сверху крепкому раствору и при этом ох.лаждаетс . После 50 с.табый раствор через отвод 1 удал етс из установки.A strong solution flows in the film nid through the device 6 and the beam 4 in the boiler 1, respectively, through the device 6 and the heat exchanger 7 or the heat exchanger 7 and the beam of the 8 n boiler 2 of the partial flow. The light components are thermally separated, and the resulting weak solution is collected in the lower parts of the boiling bodies of peaks 1 and 2. Then the two flows of the weak heating section are united, and the total flow as a heating medium is directed to the heat exchanger 7 The boiler 2 is counterflowed against the top-down strong solution and at the same time cools down. After 50 seconds, the solution through tap 1 is removed from the plant.
Отделетпле компоненты (хладагент) проход т также в противотоке к крепкому раствору , но в непосредственном с ним контакте , через массообменные устройства 6, где 55 повьпиают свою концентрацию, котора растет в направлении снизу вверх. В зависимости от концентрации подводимого креп40Separate components (refrigerant) are also passed in countercurrent to a strong solution, but in direct contact with it, through mass transfer devices 6, where 55 their concentration increases, which grows in the upward direction. Depending on the concentration of supplied crepe 40
4545
1255827 341255827 34
кого раствора или требуемой чистоты паровним теплоносителем, имеющим вход 9 и выхладагента на отборе 13 устанавливаетс кон-ход 10.Of which solution or the required purity, a steam coolant having an inlet 9 and a refrigerant at the selection 13 is set to conc. 10.
центрационна колонна 3, размещенна вы-Экономическа эффективность изобретете подачи крепкого раствора. Дл этой жени заключаетс в рациональном расходо- цели служит и дефлегматор 17 с подачей 15вании постороннего теплоносител , и отбором 16 охлаждающей среды. 5Признано изобретением по результатамA centric column 3, placed by you-Economic efficiency, will invent the supply of a strong solution. For this marriage, the reflux condenser 17 serves as a rational consumption, with the supply of foreign coolant and selection 16 of the cooling medium. 5Arranged by results
экспертизы, осуществленной ведомством поexamination carried out by the Office of
Обогрев пучка 4 кип тильника 1 и пучкаизобретательству Германской Демократичес8 кип тильника 2 осуществл етс посторон-кой Республики.Heating of the bundle 4 of the boiler 1 and the bundle of the German Democratic boiler of the boiler 2 is carried out by a foreign party.
Claims (2)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DD80220266A DD161076A3 (en) | 1980-04-08 | 1980-04-08 | METHOD FOR THE REGENERATIVE USE OF THE WET CONTENTS PURELY SOLUTIONS |
Publications (1)
Publication Number | Publication Date |
---|---|
SU1255827A1 true SU1255827A1 (en) | 1986-09-07 |
Family
ID=5523586
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SU817771688A SU1255827A1 (en) | 1980-04-08 | 1981-03-02 | Method of empoyment of heat of weak solution |
Country Status (6)
Country | Link |
---|---|
CS (1) | CS237415B1 (en) |
DD (1) | DD161076A3 (en) |
DE (1) | DE3101857A1 (en) |
FR (1) | FR2479701A1 (en) |
RO (1) | RO85236B (en) |
SU (1) | SU1255827A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2486944C2 (en) * | 2007-12-13 | 2013-07-10 | Альстом Текнолоджи Лтд | Plant and method for absorbent solution recovery |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2680116B1 (en) * | 1991-08-08 | 1994-05-06 | Institut Francais Petrole | PROCESS FOR SEPARATING A GAS MIXTURE BY ABSORPTION. |
FR2733162B1 (en) * | 1995-04-19 | 1997-06-06 | Inst Francais Du Petrole | METHOD AND DEVICE FOR REMOVING AT LEAST ONE SOLVENT-ACID GAS FOR THE PURIFICATION OF NATURAL GAS |
ES2194965T3 (en) * | 1996-10-09 | 2003-12-01 | Sulzer Chemtech Ag | DISTILLATION INSTALLATION. |
DE102011106423B4 (en) | 2011-07-02 | 2013-03-14 | Anno von Reth | Working method of a sorption plant for the two-substance mixture ammonia and water |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE499327C (en) * | 1928-11-29 | 1930-06-05 | Bruno Lehmann | Process for rectifying the steam mixture emerging from the expeller of an absorption refrigeration machine |
AT350515B (en) * | 1975-08-26 | 1979-06-11 | Veitscher Magnesitwerke Ag | CONTROL SYSTEM FOR ABSORPTION COLUMNS |
DD124936A1 (en) * | 1975-11-04 | 1977-03-23 |
-
1980
- 1980-04-08 DD DD80220266A patent/DD161076A3/en not_active IP Right Cessation
-
1981
- 1981-01-21 DE DE19813101857 patent/DE3101857A1/en not_active Ceased
- 1981-01-28 FR FR8101639A patent/FR2479701A1/en active Granted
- 1981-03-02 SU SU817771688A patent/SU1255827A1/en active
- 1981-03-11 CS CS811827A patent/CS237415B1/en unknown
- 1981-04-07 RO RO103952A patent/RO85236B/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2486944C2 (en) * | 2007-12-13 | 2013-07-10 | Альстом Текнолоджи Лтд | Plant and method for absorbent solution recovery |
Also Published As
Publication number | Publication date |
---|---|
CS237415B1 (en) | 1985-08-15 |
RO85236A (en) | 1984-09-29 |
RO85236B (en) | 1984-10-30 |
DD161076A3 (en) | 1984-09-19 |
FR2479701A1 (en) | 1981-10-09 |
DE3101857A1 (en) | 1982-01-14 |
CS182781A1 (en) | 1984-04-16 |
FR2479701B1 (en) | 1984-12-21 |
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