SA521422220B1 - عملية للاستخلاص الانتقائي للمعادن الانتقالية من البقايا العضوية - Google Patents
عملية للاستخلاص الانتقائي للمعادن الانتقالية من البقايا العضويةInfo
- Publication number
- SA521422220B1 SA521422220B1 SA521422220A SA521422220A SA521422220B1 SA 521422220 B1 SA521422220 B1 SA 521422220B1 SA 521422220 A SA521422220 A SA 521422220A SA 521422220 A SA521422220 A SA 521422220A SA 521422220 B1 SA521422220 B1 SA 521422220B1
- Authority
- SA
- Saudi Arabia
- Prior art keywords
- liquid
- mixture
- ionic
- transition metals
- extractor
- Prior art date
Links
- 229910052723 transition metal Inorganic materials 0.000 title abstract 3
- 150000003624 transition metals Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000011084 recovery Methods 0.000 title abstract 2
- 239000002608 ionic liquid Substances 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 5
- 239000007788 liquid Substances 0.000 abstract 3
- 150000001450 anions Chemical class 0.000 abstract 2
- 238000000622 liquid--liquid extraction Methods 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 238000000638 solvent extraction Methods 0.000 abstract 2
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 230000002051 biphasic effect Effects 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0488—Flow sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0492—Applications, solvents used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/005—Selection of auxiliary, e.g. for control of crystallisation nuclei, of crystal growth, of adherence to walls; Arrangements for introduction thereof
- B01D9/0054—Use of anti-solvent
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
- C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
- C10G21/12—Organic compounds only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
- C10G21/28—Recovery of used solvent
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/20—Obtaining niobium, tantalum or vanadium
- C22B34/22—Obtaining vanadium
- C22B34/225—Obtaining vanadium from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/30—Obtaining chromium, molybdenum or tungsten
- C22B34/34—Obtaining molybdenum
- C22B34/345—Obtaining molybdenum from spent catalysts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
يتعلق الاختراع الحالي بعملية الاستخلاص الانتقائي للمعادن الانتقالية transition metals من تيار عضوي يحتوي على معادن انتقالية. يتم صهر التيار العضوي وربما المستخرِج الأول إذا كان صلبًا إلى الحالة السائلة. يتكون المستخرِج من سائل أيوني ionic liquid أو خليط من سائلين أيونيين أو أكثر، حيث يحتوي السائل الأيوني المذكور على ملح أمونيوم ammonium salt في صورة كاتيون cation وفي صورة أنيون anion له خصائص مخلبية chelating properties. تتم تغذية تيار عضوي مذاب ومستخرِج extractor أول، مصهور اختياريًا، إلى وحدة استخراج extraction unit سائل عن سائل أولى تعمل عند درجة حرارة لا تقل عن 150 درجة مئوية حيث يتم إجراء استخراج السائل عن السائل للحصول على خليط سائل يحتوي على سائل أيوني، أو خليط من اثنين أو أكثر من السوائل الأيونية والمعادن. بعد الاستخراج، يتم تبريد الخليط السائل عند درجة حرارة بين صفر درجة مئوية و70 درجة مئوية ويصبح ثنائي الطور؛ ثم يتم إرسال الخليط المبرد إلى وحدة فصل separation unit أولى، لفصل الطور السائل الذي يحتوي على سوائل أيونية ومعادن، وطور صلب مستنفد المعدن. بعد الفصل الأول، يتم إرسال ال
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT201800010955 | 2018-12-11 | ||
PCT/IB2019/060668 WO2020121220A1 (en) | 2018-12-11 | 2019-12-11 | Process for the selective recovery of transition metals from organic residues |
Publications (1)
Publication Number | Publication Date |
---|---|
SA521422220B1 true SA521422220B1 (ar) | 2023-12-11 |
Family
ID=65861546
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SA521422220A SA521422220B1 (ar) | 2018-12-11 | 2021-06-09 | عملية للاستخلاص الانتقائي للمعادن الانتقالية من البقايا العضوية |
Country Status (5)
Country | Link |
---|---|
US (1) | US20210388462A1 (ar) |
EP (1) | EP3894037B1 (ar) |
CN (1) | CN113260440B (ar) |
SA (1) | SA521422220B1 (ar) |
WO (1) | WO2020121220A1 (ar) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114272862B (zh) * | 2021-12-23 | 2022-09-09 | 江苏省特种设备安全监督检验研究院 | 一种钌基金属离子液体聚合物微球人工酶及其制备方法和应用 |
CN114836632B (zh) * | 2022-06-14 | 2023-07-21 | 桐乡市思远环保科技有限公司 | 一种用离子液体萃取镉的方法 |
CN115198117A (zh) * | 2022-07-25 | 2022-10-18 | 华北理工大学 | 一种利用双功能基离子液体从酸性溶液中萃取分离钒的方法 |
CN115821072A (zh) * | 2022-12-08 | 2023-03-21 | 山东金鸾科技开发有限公司 | 利用季铵盐类离子液体萃取回收溶液中六价铬的萃取溶剂及萃取方法 |
CN116814990B (zh) * | 2023-08-31 | 2023-11-10 | 中国科学院过程工程研究所 | 利用疏水性低共熔溶剂萃取分离钒砷溶液中钒的方法 |
CN118724141A (zh) * | 2024-09-04 | 2024-10-01 | 东北大学 | 萃取铜离子用离子液体及提金氰化废水中铜离子的萃取脱除方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4518484A (en) * | 1984-02-16 | 1985-05-21 | Phillips Petroleum Company | Metals removal with a light hydrocarbon and an organophosphorous compound |
US6190542B1 (en) * | 1996-02-23 | 2001-02-20 | Hydrocarbon Technologies, Inc. | Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds |
DE10155281A1 (de) * | 2001-11-08 | 2003-06-05 | Solvent Innovation Gmbh | Verfahren zur Entfernung polarisierbarer Verunreinigungen aus Kohlenwasserstoffen und Kohlenwasserstoffgemischen durch Extraktion mit ionischen Flüssigkeiten |
ITMI20032207A1 (it) * | 2003-11-14 | 2005-05-15 | Enitecnologie Spa | Procedimento integrato per la conversione di cariche contenenti carbone in prodotti liquidi. |
US7485267B2 (en) * | 2005-07-29 | 2009-02-03 | Chevron U.S.A. Inc. | Process for metals recovery from spent catalyst |
FR2909667B1 (fr) * | 2006-12-12 | 2009-02-20 | Inst Francais Du Petrole | Elimination de l'acetonitrile dans la charge olefinique des procedes de production d'ethers par mise en oeuvre de liquides ioniques. |
CA2706957C (en) * | 2007-11-28 | 2016-07-19 | Chevron U.S.A. Inc. | Process for recovering base metals from used hydroprocessing catalyst |
GB0905896D0 (en) * | 2009-04-06 | 2009-05-20 | Univ Belfast | Process for removing metals from hydrocarbons |
FR2958656B1 (fr) * | 2010-04-13 | 2012-05-11 | Inst Francais Du Petrole | Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape d'extraction. |
FR2958658B1 (fr) * | 2010-04-13 | 2012-03-30 | Inst Francais Du Petrole | Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape de lixiviation. |
US8608950B2 (en) * | 2009-12-30 | 2013-12-17 | Uop Llc | Process for removing metals from resid |
US8608951B2 (en) * | 2009-12-30 | 2013-12-17 | Uop Llc | Process for removing metals from crude oil |
US8608949B2 (en) * | 2009-12-30 | 2013-12-17 | Uop Llc | Process for removing metals from vacuum gas oil |
GB2478332A (en) * | 2010-03-04 | 2011-09-07 | Grimley Smith Associates | Method of metals recovery from refinery residues |
DE102011013470A1 (de) * | 2010-07-26 | 2012-01-26 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren und Mittel zur Entfernung von Metallen aus hochsiedenden Kohlenwasserstofffraktionen |
CN103260758B (zh) * | 2010-11-11 | 2015-09-02 | 雪佛龙美国公司 | 加氢转化多金属催化剂及其制备方法 |
US8912351B2 (en) * | 2011-12-15 | 2014-12-16 | Uop Llc | Process for removing metals from tallow oil |
US9133400B2 (en) * | 2012-06-29 | 2015-09-15 | Uop Llc | Hydrocarbon conversion process to remove carbon residue contaminants |
US9328295B2 (en) * | 2013-09-27 | 2016-05-03 | Uop Llc | Extract recycle in a hydrocarbon decontamination process |
DE102014107374A1 (de) * | 2014-05-26 | 2015-11-26 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zur Entfernung von Metallen aus hochsiedenden Kohlenwasserstofffraktionen |
WO2018141067A1 (en) * | 2017-02-03 | 2018-08-09 | Uti Limited Partnership | Deconstruction of oilsand materials using ionic liquids |
-
2019
- 2019-12-11 WO PCT/IB2019/060668 patent/WO2020121220A1/en active Application Filing
- 2019-12-11 CN CN201980082656.3A patent/CN113260440B/zh active Active
- 2019-12-11 US US17/413,068 patent/US20210388462A1/en active Pending
- 2019-12-11 EP EP19823818.0A patent/EP3894037B1/en active Active
-
2021
- 2021-06-09 SA SA521422220A patent/SA521422220B1/ar unknown
Also Published As
Publication number | Publication date |
---|---|
WO2020121220A1 (en) | 2020-06-18 |
EP3894037B1 (en) | 2024-07-24 |
EP3894037A1 (en) | 2021-10-20 |
CN113260440B (zh) | 2023-07-14 |
US20210388462A1 (en) | 2021-12-16 |
CN113260440A (zh) | 2021-08-13 |
EP3894037C0 (en) | 2024-07-24 |
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