RU2807159C2 - Herbicidal composition containing r-pyridyloxycarboxylic acid and derivative, and its use - Google Patents

Abstract

FIELD: agriculture.

SUBSTANCE: invention relates to the technical field of pesticides and, in particular, to a herbicidal composition containing R-pyridyloxycarboxylic acid, a derivative thereof and its use. The herbicidal composition contains active ingredient A and active ingredient B in a herbicidal effective amount in a ratio of 1:30 to 100:1, where active ingredient A is one or more compounds selected from R-pyridyloxycarboxylic acid represented by formula I and a salt thereof, ester derivative,

where each of R₁, R₂ is independently chlorine or bromine; R₃ is hydrogen or fluorine; Q is either methyl, ethyl or phenyl; Y is amino; a salt is a metal salt, ammonium salt NH₄ ⁺, primary amine salt R”NH₂, secondary amine salt (R”)₂NH, tertiary amine salt (R”)₃N, quaternary amine salt (R”)₄N ⁺, polyamine salt, morpholine salt, N-methylmorpholine salt, piperidine salt, pyridine salt, aminopropylmorpholine salt, Jeff D-230 amine salt, 2,4,6-tri(dimethylaminomethyl)phenol and sodium hydroxide salt, C1-C16 alkylsulfonium salt, salt C1-C16 alkylsulfoxonium, C1-C16 alkylphosphonium salt or C1-C16 alkanolphosphonium salt; wherein R" is each independently C1-C16 alkyl, unsubstituted or substituted by one or more of the following groups: halogen, hydroxy, C1-C6 alkoxy, C1-C6 alkylthio, hydroxy C1-C6 alkoxy; C2-C12 alkenyl, C2-C12 alkynyl, C3-C12 cycloalkyl; or phenyl or benzyl, unsubstituted or substituted with C1-C6 alkyl;

ester is, where X is O or S; M is methyl, undecyl, tetrahydrofurylmethylene, furylmethylene,, ; or benzyl, substituted or unsubstituted with fluorine, methyl; active ingredient B is selected from the following one or more compounds or acids, or salts thereof, or ester derivatives, ALS inhibitor, ACCase inhibitor, PSII inhibitor, HPPD inhibitor, PDS inhibitor, DOXP inhibitor, PPO inhibitor, synthetic hormone, EPSPS inhibitor, inhibitor GS, PSI inhibitor.

EFFECT: proposed herbicidal composition demonstrates a wide range of weed control, is used in a reduced dose, can cause a synergistic effect and destroy resistant weeds.

10 cl, 218 tbl

Description

Field of technology

The present invention relates to the technical field of pesticides and, in particular, relates to a herbicidal composition containing R-pyridyloxycarboxylic acid and a derivative and its use.

State of the art

Chemical weed control is the most economical and effective means of controlling weeds in agricultural land, however, the continuous use of a single chemical herbicide or chemical herbicides with a single functional mechanism in high doses over a long period of time can cause problems associated with the development of drug resistance and tolerance in weeds . Proper complexation or formulation of herbicidal compounds can provide the following benefits: demonstrating broad spectrum weed control, improving weed control effect and delaying the emergence and development of drug resistance and tolerance in weeds, and is thus one of the most effective means to address the above problems. Accordingly, it is desirable to produce herbicidal compositions that have high safety and broad spectrum weed control and are capable of producing a synergistic effect and removing resistant weeds.

The essence of the invention

To solve the above-mentioned existing problems of the prior art, the present invention provides a herbicidal composition containing R-pyridyloxycarboxylic acid and a derivative and its use. The composition is capable of effectively controlling weeds such as grassy weeds or broadleaf weeds, etc., and has the following advantages: it has a broad spectrum of weed control, is used in a reduced dose, can cause a synergistic effect and remove resistant weeds.

A herbicidal composition containing R-pyridyloxycarboxylic acid and a derivative, which contains active ingredient A and active ingredient B in a herbicidal effective amount, where

active ingredient A is one or more compounds selected from R-pyridyloxycarboxylic acid represented by formula I and its ester derivative salt,

wherein each of R ₁ , R ₂ is independently halogen, C1-C6 alkyl, C1-C6 halogen alkyl or C3-C6 cycloalkyl;

R ₃ is hydrogen, halogen, C1-C6 alkyl or halogen C1-C6 alkyl;

Q is C1-C6 alkyl, halogen C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, halogen, cyano, amino, nitro, formyl, C1-C6 alkoxy, C1-C6 alkylthio, C1- C6 alkoxycarbonyl, hydroxy C1-C6 alkyl, C1-C6 alkoxy C1-C6 alkyl, cyano C1-C6 alkyl, C1-C6 alkylamino C1-C6 alkyl; or phenyl, benzyl, naphthyl, furyl, thienyl, thiazolyl, pyrazolyl, pyridyl or pyrimidinyl, unsubstituted or substituted by at least one group selected from the group consisting of C1-C6 alkyl, cyano, halogen C1-C6 alkyl, C1-C6 alkylamino, halogen, C1-C6 alkoxy;

Y is amino, C1-C6 alkylamino, C1-C6 alkylcarbonylamino; or phenylcarbonylamino, benzylamino or furylmethyleneamino, which is unsubstituted or substituted by at least one group selected from the group consisting of C1-C6 alkyl, halogen, cyano, C1-C6 alkylamino, C1-C6 alkoxy, halogen C1-C6 alkyl ;

salt is a metal salt, ammonium salt NH ₄ ⁺ , primary amine salt R''NH ₂ , secondary amine salt (R'') ₂ NH, tertiary amine salt (R'') ₃ N, quaternary amine salt (R'') ₄ N ⁺ , polyamine salt, morpholine salt, N-methylmorpholine salt, piperidine salt, pyridine salt, aminopropylmorpholine salt, Jeff D-230 amine salt, 2,4,6-tri(dimethylaminomethyl)phenol and sodium hydroxide salt, C1- salt C16 alkylsulfonium (preferably a C1-C6 alkylsulfonium salt), a C1-C16 alkylsulfoxonium salt (preferably a C1-C6 alkylsulfoxonium salt), a C1-C16 alkylphosphonium salt (preferably a C1-C6 alkylphosphonium salt) or a C1-C16 alkanolphosphonium salt (preferably C1-C6 alkanolphosphonium salt);

wherein R'' is each independently C1-C16 alkyl, C2-C12 alkenyl (preferably C2-C6 alkenyl), C2-C12 alkynyl (preferably C2-C6 alkynyl), C3-C12 cycloalkyl; or C1-C16 alkyl (preferably C1-C6 alkyl) substituted with one or more of the following groups: halogen, hydroxy, C1-C6 alkoxy, C1-C6 alkylthio, hydroxy C1-C6 alkoxy; or phenyl or benzyl, unsubstituted or substituted C1-C6 alkyl.

ester is , where X is O or S;

M is C1-C18 alkyl, C1-C8 halogen alkyl, C3-C6 cycloalkyl, unsubstituted or substituted C1-C6 alkyl, C2-C6 alkenyl, C2-C6 halogen alkenyl, C2-C6 alkynyl, C1-C6 alkoxy, C1- C6-alkoxycarbonyl, C1-C6 alkylsulfonyl, cyano C1-C6 alkyl, nitro C1-C6 alkyl, C1-C6 alkoxy C1-C6-alkyl, -(C1-C6-alkyl)-Z, ; or phenyl, , tetrahydrofuryl, pyridyl, naphthyl, furyl, thienyl, pyrrolyl, pyrazolyl or imidazolyl, unsubstituted or substituted by at least one group selected from the group consisting of C1-C6 alkyl, halogen C1-C6 alkyl, cyano, C1- C6 alkylamino, halogen, C1-C6 alkoxy;

Z is ; or phenyl, tetrahydrofuryl, pyridyl, pyrazolyl, thienyl, furyl or naphthyl, unsubstituted or substituted by at least one group selected from the group consisting of C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylamino, C1- halogen C6 alkyl, cyano, halogen;

R ₄ , R ₅ , R ₆ are each independently hydrogen, C1-C6 alkyl, C1-C6 alkoxycarbonyl; or phenyl, unsubstituted or substituted by at least one group selected from the group consisting of C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylamino, C1-C6 alkyl halogen, cyano, halogen;

R ₇ is C1-C6 alkyl, C2-C6 alkenyl or ;

active ingredient B is selected from the following one or more compounds, or acids, or salts thereof, or ester derivatives,

(1) an ALS inhibitor selected from: for example, penoxulam (CAS No.: 219714-96-2), bispiribac sodium (CAS No.: 125401-92-5), pyrazosulfuron-ethyl (CAS No.: 93697-74-6) , nicosulfuron (CAS No.: 111991-09-4), florasulam (CAS No.: 145701-23-1), rimsulfuron (CAS No.: 122931-48-0), imazethapyr (CAS No.: 81335-77-5), imazapic (CAS No.: 104098-48-8), imazamox (CAS No.: 114311-32-9), sulfometuron-methyl (CAS No.: 74222-97-2), cloransulam-methyl (CAS No.: 147150-35-4) ;

(2) an ACCase inhibitor selected from: for example, cyhalofop-butyl (CAS No.: 122008-85-9), clodinafop-propargyl (CAS No.: 105512-06-9), pinoxaden (CAS No.: 243973-20-8) , clethodim (CAS No.: 99129-21-2), sethoxydim (CAS No.: 74051-80-2), quizalofop-P-methyl (CAS No.: 100646-51-3), fluazifop-P-butyl (CAS No.: 79241-46-6), haloxyfop-p-methyl (CAS No: 72619-32-0);

(3) a PSII inhibitor selected from: for example, atrazine (CAS No.: 1912-24-9), isoproturon (CAS No.: 34123-59-6), chlortoluron (CAS No.: 15545-48-9), diuron (CAS No.: 330-54-1), bentazone (CAS No.: 25057-89-0), bromoxynil (CAS No.: 1689-84-5), propanil (CAS No.: 709-98-8);

(4) an HPPD inhibitor selected from: for example, cipirafluone (CAS No.: 1855929-45-1), bipyrazone (CAS No.: 1622908-18-2), phenpyrazone (CAS No.: 1992017-55-6), tripirasulfone (CAS No.: 1911613-97-2), Tefuryltrione (CAS No.: 473278-76-1), Mesotrione (CAS No.: 104206-82-8), Tembotrione (CAS No.: 335104-84-2), Topramesone (CAS No.: 104206-82-8) 210631-68-8), isoxaflutole (CAS No.: 141112-29-0), benzobicilone (CAS No.: 156963-66-5);

(5) a PDS inhibitor selected from: for example, diflufenican (CAS No.: 83164-33-4), fluorochloridone (CAS No.: 61213-25-0);

(6) DOXP inhibitor: for example, clomazone (CAS NO.: 81777-89-1);

(7) a PPO inhibitor selected from: for example, carfentrazone-ethyl (CAS No.: 128621-72-7), fomesafen (CAS No.: 72178-02-0), fluoroglycophene (CAS No.: 77501-60-1), oxyfluorfen (CAS No.: 42874-03-3), lactofen (CAS No.: 77501-63-4), acifluorfen sodium (CAS No.: 50594-66-6), flumioxazine (CAS No.: 103361-09-7), sulfentrazone (CAS No: 122836-35-5), saflufenacil (CAS No: 372137-35-4), oxadiazone (CAS No: 19666-30-9), oxadiargyl (CAS No: 39807-15-3);

(8) a synthetic hormone inhibitor selected from: for example, triclopyr (CAS No.: 55335-06-3), MCPA (CAS No.: 94-74-6), dicamba (CAS No.: 1918-00-9), picloram ( CAS No.: 1918-02-1), aminopyralide (CAS No.: 150114-71-9), fluroxypyr (CAS No.: 69377-81-7), florpyrauxifene benzyl (CAS No.: 1390661-72-9), halauxifene-methyl (CAS No.: 943831-98-9), quinclorac (CAS No.: 84087-01-4), clopyralid (CAS No.: 1702-17-6);

(9) EPSPS inhibitor: for example, glyphosate (CAS No.: 1071-83-6);

(10) a GS inhibitor selected from, for example, glufosinate ammonium (CAS No.: 77182-82-2);

(11) a PSI inhibitor selected from, for example, diquat dibromide monohydrate (CAS No.: 6385-62-2), paraquat dichloride (CAS No.: 1910-42-5).

Preferably, R ₁ , R ₂ are each independently fluorine, chlorine, bromine, iodine, methyl, ethyl, propyl, isopropyl, trifluoromethyl or cyclopropyl;

R ₃ is hydrogen, fluorine, chlorine, bromine, iodine, methyl or trifluoromethyl;

Q is methyl, ethyl, propyl, isopropyl, cyclopropyl, vinyl, ethynyl, fluorine, chlorine, bromine, cyano, amino, nitro, formyl, methoxy, methylthio, methoxycarbonyl, monochloromethyl, monofluoromethyl, difluoromethyl, trifluoromethyl, 2-chloroethyl, 2, 2,2-trifluoroethyl, hydroxymethyl, , benzyl, naphthyl ( or ), furyl ( or ), pyridyl ( , or ), pyrimidinyl ( , or ); thiazolyl ( , or ), which is not substituted or substituted with chlorine; thienyl ( or ), which is not substituted or substituted with fluorine; ( or ), which is unsubstituted or substituted with methyl or fluorine; or phenyl which is unsubstituted or substituted with at least one group selected from the group consisting of methyl, trifluoromethyl, chlorine, methoxy;

Y is NH ₂ , or ;

salt is an alkali metal salt (for example, sodium, lithium, potassium, cesium or rubidium), an alkaline earth metal salt (for example, calcium, magnesium, barium or strontium) and metal salts such as antimony, bismuth, cadmium, cerium, chromium, cobalt , scandium, titanium, manganese, copper, iron, silver, gold, zinc, aluminum, etc., amine salts such as ammonium salt, tetramethylammonium salt, tetraethylammonium salt, tetrapropylammonium salt, tetrabutylammonium salt, N-hexadecyltrimethylamine salt, salt N-benzyltrimethylammonium, benzyltriethylammonium salt, choline amine salt, monomethylamine salt, dimethylamine salt, trimethylamine salt, monoethylamine salt, diethylamine salt, triethylamine salt, n-propylamine salt, dipropylamine salt, tripropylamine salt, monoisopropylamine salt, diisopropylamine salt, triisopropylamine salt, salt n-butylamine, dibutylamine salt, tributylamine salt, isobutylamine salt, tert-butylamine salt, pentylamine salt, hexylamine salt, heptylamine salt, octylamine salt, dodecylamine salt, tetradecylamine salt, diallylamine salt, cyclohexylamine salt, cyclododecylamine salt, aniline salt, o salt -toluidine, m-toluidine salt, p-toluidine salt, dianiline salt, benzylamine salt, monoethanolamine salt, N-methylmonoethanolamine salt, N, N-dimethylethanolamine salt, N-ethylmonoethanolamine salt, N, N-diethylethanolamine salt, N-propylmonoethanolamine salt , N,N-di-n-propylethanolamine salt, N-butylmonoethanolamine salt, diethanolamine salt, N-methyldiethanolamine salt, N-ethyldiethanolamine salt, N-propyldiethanolamine salt, N-butyldiethanolamine salt, N,N-dibutylethanolamine salt, triethanolamine salt, tripropanolamine salt, triisopropanolamine salt, tri(2-hydroxypropyl)amine salt, diglycolamine salt, polyamine salt (e.g. hexamethylenetetramine salt, ethylene diamine salt, diethylenetriamine salt, dimethylaminopropylamine salt, 1,2-propyldiamine salt, triethylene diamine salt, triethylene tetramine salt, benzidine salt , N,N-bis[aminopropyl]methylamine salt), 2-methylthiopropylamine salt, 2-butoxyethylamine salt, AEPD salt ( ), tri(methylol)aminomethane salt ( ), morpholine salt, N-methylmorpholine salt, piperidine salt, pyridine salt, aminopropylmorpholine salt ( ),Jeff D-230 amine salt ( , n is 2 or 3), 2,4,6-tri(dimethylaminomethyl)phenol sodium hydroxide salt, sulfonium salt such as alkylsulfonium salt (e.g. trimethylsulfonium salt, triethylsulfonium salt), alkylsulfoxonium salt, phosphonium salt such as salt alkylphosphonium or alkanolphosphonium salt;

in Formula I-1, X is O or S;

M is methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, octadecyl, trifluoromethyl, pentafluoroethyl, 3-chlorobutyl, 2-fluoroethyl, 2-chloroethyl, 2-bromoethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 4,4,4-trifluorobutyl, 2,2,3,3,3-pentafluoropropyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, allyl, 2-propynyl, methoxy, ethoxycarbonyl, methylsulfonyl, , , , , , , , , tetrahydrofuryl ( or ), tetrahydrofurylmethylene ( or ), pyridyl ( or ), pyridylmethylene ( or ), naphthyl ( or ), naphthylmethylene ( or ), furyl ( or ), furylmethylene ( or ), thienyl ( or ), thienylmethylene ( or ), ( or ), ( or ), ( or ); ( , or ), which is unsubstituted or substituted with methyl; phenyl which is unsubstituted or substituted with methyl, dimethylamino, chlorine, methoxy, trifluoromethyl or isopropyl; or benzyl which is unsubstituted or substituted with trifluoromethyl, bromine, chlorine, fluorine, methoxy, cyano or methyl;

R' is hydrogen, methyl, ethyl or difluoromethyl.

More preferably, active ingredient A is one or more compounds selected from

The method for producing active ingredient A includes the following steps.

A compound of formula III is reacted with a compound of formula II to obtain a compound of formula I-1-1; The reaction scheme is as follows:

where W is hydrogen or an alkali metal, preferably K, Na; Hal is a halogen, preferably Br, Cl; the reaction is carried out in the presence of a catalyst and a solvent. Preferably, the catalyst is TBAB and the solvent is one or more solvents selected from the group consisting of DCM, DCE, ACN, THF, DMF.

The compound of formula I-1-1 is reacted in the presence of an aqueous solution of lithium hydroxide and a solvent to obtain a compound of formula I; The reaction scheme is as follows:

Preferably, the solvent is one or more solvents selected from the group consisting of methanol, ethanol and isopropanol.

The compound of formula I is reacted with M-SH to obtain the compound of formula I-1-2; The reaction scheme is as follows:

wherein the reaction is carried out in the presence of a dehydrating agent and a solvent, preferably the dehydrating agent is DCC, and the solvent is one or more solvents selected from the group consisting of dichloromethane, dichloroethane, acetonitrile, N,N-dimethylformamide, N,N-dimethylacetamide, dimethyl sulfoxide, tetrahydrofuran , toluene, xylene;

or, if Y is NR ₁ R ₂ (R ₁ and R ₂ are both not hydrogen), it is prepared by reacting the compound of formula I-2 or compounds of formula I-1-3 with the appropriate halide;

wherein the halide is preferably chloride or bromide; the reaction is carried out in the presence of a base and a solvent, where the base is one or more bases selected from the group consisting of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate and cesium carbonate; the solvent is one or more solvents selected from the group consisting of THF, 1,4-dioxane, toluene, 1,2-dichloroethane, ethyl acetate, acetonitrile, DMF, acetone, dichloromethane and chloroform; a catalyst, preferably DMAP, is optionally added during the reaction.

The salt is an agrochemically acceptable salt, which is preferably prepared by reacting the R-pyridyloxycarboxylic acid compound of the present invention with a chemically acceptable basic compound. The above agrochemically acceptable salt can be easily separated and purified by conventional separation methods such as solvent extraction, dilution, recrystallization, column chromatography and preparative thin layer chromatography.

In some embodiments, active ingredient A to active ingredient B is in a weight ratio of 1:100~100:1 or 1:50~50:1, preferably 1:30~30:1 or 1:20~20:1, more preferably, 1:10~10:1 or 1:8~8:1, even more preferably, 1:5~5:1 or 1:1~2:1 or 1:1~1:2.

In some embodiments, active ingredients A and B together constitute 1-95%, preferably 10-80%, of the total weight of the herbicidal composition.

The herbicidal composition may contain a conventional adjuvant, where the conventional adjuvant contains, for example, a carrier and/or a surfactant.

The term "carrier" as used herein refers to an organic or inorganic, natural or synthetic substance that facilitates the application of the active ingredients. Generally, the carrier is inert and must be agriculturally acceptable, especially acceptable to the plant being treated. The carrier may be a solid such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, etc.; or liquid, such as water, alcohol, ketone, petroleum fraction, aromatic or paraffinic hydrocarbon, chlorinated hydrocarbon, liquefied gas and so on.

The surfactant, which may be ionic or non-ionic, may include an emulsifier, dispersant or wetting agent. Examples that may be mentioned are a polyacrylic acid salt, a lignosulfonic acid salt, a phenolsulfonic acid or naphthalene sulfonic acid salt, a polymer of ethylene oxide with an aliphatic alcohol or with an aliphatic acid or with an aliphatic amine or with a substituted phenol (in particular an alkylphenol or arylphenol), sulfosuccinate , a taurine derivative (especially alkyl taurate) and phosphoric acid ester or polyhydroxyethylated phenol, alkyl sulfonate, alkylaryl sulfonate, alkyl sulfate, lauryl ether sulfate, fatty alcohol sulfate, sulfated hexadecanol, heptadecanol and octadecanol and sulfated fatty alcohol polyglycol ether, and also include naphthalene or naphthalene sulfonic acid condensate acids with phenol and formaldehyde, polyoxyethylene octyl phenyl ether, ethoxylated isooctyl phenol, octylphenol or nonylphenol, polyethylene glycol alkyl phenyl ether, polyethylene glycol tributyl phenyl ether, polyethylene glycol tristearyl phenyl ether, alkylaryl polyether alcohol, alcohol-fatty alcohol/ethylene oxide condensate, ethoxylated castor new oil, polyoxyethylene alkyl ether, ethoxylated polyoxypropylene, acetal lauryl alcohol polyglycol ether, sorbitol ether, lignin sulfite liquid waste, protein, denatured protein, polysaccharide (eg methylcellulose), hydrophobically modified starch, polyvinyl alcohol, polycarboxylate, polyalkoxylate, polyvinylamine, polyvinylpyrrolidone and copolymers thereof. At least one surfactant may be required to facilitate dispersion of the active ingredient in water and its proper application to the plant.

The composition may also contain various other components, such as a protective colloid, adhesive, thickener, thixotropic agent, penetrant, stabilizer, chelating agent, dye, pigment or polymer.

In addition, compositions that can be combined with active compounds are, for example, known active compounds as described, for example, in World Herbicide New Product Technology Handbook, China Agricultural Science and Farming Techniques Press, 2010.9 and literature cited therein. For example, the following active compounds may be referred to as herbicides (note: compounds are named either by their "common name" according to the International Organization for Standardization (ISO) or by their chemical name, if appropriate, along with a common code number): acetochlor, butachlor, alachlor, propisochlor, metolachlor, c-metolachlor, pretilachlor, propachlor, etachlor, napropamide, R-left-handed napropamide, propanil, mefenacet, difenamide, diflufenican, etaprochlor, beflubutamide, bromobutide, dimethenamid, dimethenamid-P, etobenzanide, flufen acetate, tenylchlor , meta-zoxaben, flammprop-m-methyl, flammprop-m-propyl, allihhlor, petoxamid, chlorocyl, tsiprazine, mefluidide, monalid, drawinger, prinnogor, terbuchlor, kilalor, diphtamlor, trimexanilor, clomoprop, prpisamid, pentanoclor , carbetamide , benzoylprop-ethyl, cyprazole, butenachlor, tebutam, benzipram, mogroton, dichlofluanid, naproanilide, dietathyl-ethyl, napthalam, flufenacet, benzadox, chlorothiamide, chlorophthalimide, isocarbamide, picolinafen, atrazine, simazine, prometrin, cyanathrine, symethrine, ameter in, propazin , dipropetrin, SSH-108, terbutrin, terbutylazine, triaziflam, cyprazine, proglinazine, triethazine, prometone, simeton, aziprothrin, desmethrin, dimethamethrin, procyazine, mesoprazine, sebutylazine, sebumetone, terbumetone, methoprothrin, cyanathrine, ipazine, chlorazine, atratone, pendimethalin , eglinazine, cyanuric acid, indaziflam, chlorsulfuron, metsulfuron-methyl, bensulfuron methyl, chlorimuron-ethyl, tribenuron-methyl, thifensulfuron-methyl, pyrazosulfuron-ethyl, mesosulfuron, iodosulfuron-methyl sodium, foramsulfuron, cinosulfuron, triasulfuron, sulfometuron methyl, nicosulfuron , etamethsulfuron-methyl, amidosulfuron, ethoxysulfuron, cyclosulfamuron, rimsulfuron, azimsulfuron, flazasulfuron, monosulfuron, monosulfuron-ester, flucarbazone-sodium, flupirsulfuron-methyl, halosulfuron-methyl, oxasulfuron, imazosulfuron, primisulfuron, propoxycarbazone, prosulfuron, sulfosulfuron, trifloxysulfuron, triflusulfuron-methyl, tritosulfuron, sodium methylsulfuron, flucetosulfuron, HNPC-C, orthosulfamuron, propyrisulfuron, metazosulfuron, acifluorfen, fomesafen, lactofen, fluoroglycofen, oxyfluorfen, chlornitrophen, aclonifen, ethoxyphene-ethyl, bifenox, nitrofluorfen, chloromethoxifen, fluorodi hair dryer, fluoronitrophen, furyloxyphene S K-85 , methobromuron, methoxuron, afesin, monuron, siduron, fenuron, fluotiuron, neburon, chloroxuron, noruron, isonoruron, 3-cyclooctyl-1, tiazfluron, tebuthiuron, difenoxuron, parafluron, methylamine tribunil, carbutylate, trimeturon, dimefuron, monisouron, anisu ron, methiuron, chloreturon, tetrafluron, phenmedipham, phenmedipham-ethyl, desmedipham, asulam, terbucarb, barban, profam, chlorpropham, roumate, swep, chlorbufam, carboxazole, chlorprocarb, fenasulam, BCPC, CPPC, carbasulam, butylate, benthiocarb, vernolate, molinate, triallate, dimepiperate, esprocarb, pyributicarb, cycloate, avadex, EPTC, etiolate, orbenecarb, pebulate, prosulfocarb, thiocarbazyl, CDEC, dimexano, isopolinate, methiobencarb, 2,4-D butyl ether, MCPA-Na, 2,4-D isooctyl ester, MCPA isooctyl ester, 2,4-D sodium salt, 2,4-D dimethylamine salt, MCPA-thioethyl, MCPA, 2,4-D propionic acid, 2,4-D propionic acid high salt, 2,4- D butyric acid, MCPA propionic acid, MCPA propionic acid salt, MCPA butyric acid, 2,4,5-D, 2,4,5-D propionic acid, 2,4,5-D butyric acid, MCPA amine salt, dicamba , erbon, chlorfenac, saison, TBA, chloramben, methoxy-TBA, diclofop-methyl, fluazifop-butyl, fluazifop-p-butyl, haloxyfop-methyl, haloxyfop-P, quizalofop-ethyl, quizalofop-p-ethyl, fenoxaprop-ethyl , fenoxaprop-p-ethyl, propakisafop, cygalofop-butyl, metamifop, clodinafop-propargyl, fentiaprop-ethyl, chlorazifop-propynyl, poppenate-methyl, trifopsim, isoxapirifop, paraquat, diquat, oryzalin, ethalfluralin, isopropalin, nitralin, profluralin, prodynamin , benfluralin, fluchloralin, dinitramine, dipropalin, chlornidine, metalpropalin, dinoprop, glyphosate, anilofos, ammonium glufosinate, amiprofos-methyl, sulfosate, piperophos, bialaphos-sodium, bensulide, butamiphos, focarb, 2,4-DEP, H-9201, zitron, imazapyr, imazethapyr, imazaquin, imazamox, imazamox ammonium salt, imazapic, imazamethabenz-methyl, fluroxypyr, fluroxypyr isooctyl ether, clopyralide, picloram, trichloropyr, dithiopyr, haloxidine, 3,5,6-trichloro-2-pyridinol, thiazopyr, fluridone, aminopyralide, diflufenzopyr, triclopyr-butotyl, cliodinate, sethoxydim, clethodim, cycloxydim, aloxydim, clefoxydim, butroxydim, tralkoxydim, tepraloxydim, butidazole, metribuzin, hexazinone, metamitron, etiosin, ametridione, amibusin, bromoxynil, bromoxynil ok tanoate, ioxynyl octanoate, ioxynil, dichlobenil, diphenatril, pyraclonil, chloroxynil, iodobonil, flumetsulam, florasulam, penoxsulam, methosulam, cloransulam-methyl, diclosulam, pyroxsulam, benfuresate, bispiribac-sodium, piribenzoxime, pyrifthalide, pyriminobac-methyl, pyrithiobac-sodium, benzobi cylon, mesotrione, sulcotrione, tembotrione, tefuryltrione, bicyclopyrone, ketopyradox, isoxaflutole, clomazone, fenoxasulfone, methiozolin, fluazolate, pyraflufen-ethyl, pyrazolinate, difensoquat, pyrazoxifene, benzophenap, nipyraclofen, pyrasulfotol, topramesone, pyroxasulfone, cafenstrol, flupoxam, aminotriazole, amicarbazone, azaphenidine, carfentrazone-ethyl, sulfentrazone, bencarbazone, benzphendizone, butafenacil, bromacil, isocyl, lenacyl, terbacil, flupropacil, cinidone-ethyl, flumiclorac-pentyl, flumioxazin, propyzamide, MK-129, flumesin, pentachlorophenol, dinoseb, dinoterb, di noterb acetate, dinosam K vinmerac, bentazone, pyridate, oxaziclomefone, benazoline, clomazone, cinmethylin, ZJ0702, piribambenz-propyl, indanofan, sodium chlorate, dalapon, trichloroacetic acid, monochloroacetic acid, hexachloroacetone, flupropanate, cyperquat, bromphenoxime, epronaz, methazol, flurtamone, benfuresate, ethofu mesate, thioclorim, chlorthal , fluorochloridone, tavron, acrolein, bentranil, tridifan, chlorfenpropmethyl, tidiarizonaimine, phenizofam, butoxinone, methoxyphenone, saflufenacil, clacifos, chloropon, alorak, dietamquat, etnipromide, iprimidam, ipfencarbazone, thiencarbazone-methyl, pyrimisulfan, chlorflurazole, tripropindan, sulglicapine, prosulfalin , cambendichlor, aminocyclopyrachlor, rodetanil, benoxacor, fenclorim, flurazole, fenchlorazole-ethyl, cloquintocet-mexyl, oxabetrinil, MG/91, ciometrinil, DKA-24, mefenpyr-diethyl, furilazole, fluxofenim, isoxadifen-ethyl, dichlormide, halauxifen- methyl , DOW florpyraxifene, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC-330, KH-218, DPX-N8189, SC-0744, DOWCO535, DK-8910, V-53482, PP -600, MBH-001, KIH-9201, ET-751, KIH-6127 and KIH-2023.

The herbicidal composition may further contain one or more antidotes, which are one or more compounds selected from,

a) compounds of the dichlorophenylpyrazoline-3-carboxylic acid (S1) type, preferably compounds such as ethyl 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylate ( S1 -1, mefenpyr-diethyl, PM, pages 594-595) and related compounds as described, for example, in WO 91/07874 and PM (pages 594-595).

b) dichlorophenylpyrazolecarboxylic acid derivatives, preferably compounds such as ethyl 1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylate (S1-2), ethyl 1-(2,4-dichlorophenyl)-5-isopropylpyrazole -3-carboxylate (Sl-3), ethyl 1-(2,4-dichlorophenyl)-5-(1,1-dimethyl-ethyl)pyrazole-3-carboxylate (S1-4), ethyl-1-(2 ,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylate (S1-5) and related compounds as described in EP-A-333 131 and EP-A-269 806.

c) compounds of the triazolecarboxylic acid (S1) type, preferably compounds such as fenchlorazole, i.e. ethyl 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1,2,4-triazole-3-carboxylate (S1-6) and related compounds (see EP-A-174562 and EP-A -346 620).

d) compounds of the 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid type or the 5,5-diphenyl-2-isoxazoline-3-carboxylic acid type, preferably compounds such as ethyl 5-(2, 4-dichlorobenzyl)-2-isoxazoline-3-carboxylate (S1-7) or ethyl 5-phenyl-2-isoxazoline-3-carboxylate (S1-8) and related compounds as described in WO 91/08202, or ethyl 5 ,5-diphenyl-2-isoxazoline-3-carboxylate (S1-9, isoxadifen-ethyl) or n-propyl 5,5-diphenyl-2-isoxazoline-3-carboxylate (S1-10) or ethyl 5-(4- fluorophenyl)-5-phenyl-2-isoxazoline-3-carboxylate (S1-11), as described in patent application (WO-A-95/07897).

e) compounds of the 8-quinolineoxyacetic acid (S2) type, preferably 1-methylhex-1-yl (5-chloro-8-quinolineoxy)acetate (S2-1, cloquintocet-mexyl, e.g. PM (pages 195-196), (1,3-dimethylbut-1-yl) (5-chloro-8-quinolinoxy)acetate (S2-2), 4-allyloxybutyl (5-chloro-8-quinolinoxy)acetate (S2-3), 1-allyloxyprop- 2-yl (5-chloro-8-quinolinoxy) acetate (S2-4), ethyl (5-chloro-8-quinolinoxy) acetate (S2-5), methyl (5-chloro-8-quinolinoxy) acetate (S2- 6), allyl (5-chloro-8-quinolinoxy) acetate (S2-7), 2-(2-propylideneiminooxy)-1-ethyl (5-chloro-8-quinolinoxy) acetate (S2-8), 2-oxoprop -1-yl (5-chloro-8-quinolinoxy) acetate (S2-9) and related compounds as described in EP-A-86750, EP-A-94349 and EP-A-191736 or EP-A-0492366.

f) compounds of the (5-chloro-8-quinolinoxy)malonic acid type, preferably compounds such as diethyl(5-chloro-8-quinolinoxy)malonate, diallyl(5-chloro-8-quinolinoxy)malonate, methylethyl(5- chloro-8-quinolineoxy)malonate and related compounds as described in EP-A-0582 198.

g) active compounds such as phenoxyacetic acids, phenoxypropionic acids or aromatic carboxylic acids, such as, for example, 2,4-dichlorophenoxyacetic acid (and its esters) (2,4-D), 4-chloro-2-methylphenoxypropionic esters (mecoprop ), MCPA or 3,6-dichloro-2-methoxybenzoic acid (and its esters) (dicamba).

i) active compounds of the pyrimidine type, such as, for example, "phenklorim" (RM, pp. 386-387) (= 4,6-dichloro-2-phenylpyrimidine).

i) active compounds of the dichloroacetamide type, which are often used as pre-emergence safeners (soil safeners), such as for example “dichloromide” (PM, pp. 270-271) (=N, N-diallyl-2,2-dichloroacetamide) , "AR-29148" (=3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidone from Stauffer), "benoxacor" (PM, pp. 74-75) (=4-dichloroacetyl-3,4 -dihydro-3-methyl-2H-1,4-benzoxazine), "APPG-1292" (= N-allyl-N[(1,3-dioxolan-2-yl)-methyl]dichloroacetamide from PPG Industries), " ADK-24" (=N-allyl-N-[(allylaminocarbonyl)methyl]-dichloroacetamide from Sagro-Chem), "AAD-67" or "AMON 4660" (=3-dichloroaceryl-1-oxa-3-aza- spiro[4,5]decane from Nirrokemia or Monsanto), "diclonone" or "ABAS145138" or "ALAB145138" (= (=3-dichloroacetyl-2,5,5-trimethyl-1,3-diazabicyclo[4.3.0] nonane from BASF) and "furylazole" or "AMON 13900" (see PM, 482-483) (= (RS)-3-dichloroacetyl-5-(2-furyl)-2,2-dimethyloxazolidone).

j) active compounds of the dichloroacetone derivative type, such as, for example, "AMG 191" (CAS Reg. No. 96420-72-3) (= 2-dichloromethyl-2-methyl-1,3-dioxolane from Nitrokemia).

k) active compounds of the type hydroxyimino compounds, which are known as etchants, such as, for example, "oxabetrinil" (RM, p. 689) (=(Z)-1,3-dioxolan-2-ylmethoxyimino(phenyl)acetonitrile), which known as a seed treatment antidote to prevent metolachlor damage, "fluxophenim" (PM, pp. 467-468) (= 1-(4-chlorophenyl)-2,2,2-trifluoro-1-ethanone O-(1,3 -dioxolan-2-ylmethyl)oxime, known as a seed antidote to prevent metolachlor damage, and "cyomethrinil" or "A-CGA-43089" (PM, p. 983) (= (Z)-cyanomethoxyimino(phenyl)acetonitrile ), which is known as an antidote in seed dressings to prevent metolachlor damage.

1) active compounds such as esters of thiazolecarboxylic acids, which are known as seed protectants, such as, for example, “flurazol” (RM, pp. 450-451) (= benzyl 2-chloro-4-trifluoromethyl-1,3-thiazol- 5-carboxylate), which is known as a seed dressing antidote to prevent damage by alachlor and metolachlor.

m) active compounds of the type of naphthalenedicarboxylic acid derivatives, which are known as seed dressings, such as, for example, "naphthalic anhydride" (RM, pp. 1009-1010) (= 1,8-naphthalenedicarboxylic acid anhydride), which is known as protectant for corn during seed dressing to prevent damage by thiocarbamate herbicides.

n) active compounds of the chromanacetic acid derivative type, such as for example "ACL 304415" (CAS Reg. No. 31541-57-8) (=2-84-carboxychroman-4-yl)acetic acid from American Cyanamid).

o) active compounds that, in addition to their herbicidal effect against harmful plants, also have a protective effect on crop plants, such as, for example, “dimepiperate” or “AMY-93” (PM, pp. 302-303) (= S -1-methyl-1-phenylethylpiperidine-1-carbothioate), "daimuron" or "ASK 23" (PM, p. 247) (=1-(1-methyl-1-phenylethyl)-3-p-tolylurea), "cumyluron" = "AJC-940" (=3-(2-chlorophenylmethyl)-1-(1-methyl-1-phenylethyl)urea, see JP-A-60087254), "methoxyphenone" or "ANK 049" ( =3,3'-dimethyl-4-methoxybenzophenone), "CSB" (=1-bromo-4-(chloromethylsulfonyl)benzene) (CAS Reg. No. 54091-06-4 from Kumiai).

In a preferred embodiment, the antidote is one or more compounds selected, for example, isoxadifen-ethyl (CAS No.: 163520-33-0), cyprosulfamide (CAS No.: 221667-31-8), mefenpyr-diethyl (CAS No.: 163520 -33-0). CAS No.: 135590-91-9), cloquintocet-mexyl (CAS No.: 99607-70-2), gibberellic acid (CAS No.: 77-06-5), furylazole (CAS No.: 121776-33-8), metcamifene (CAS No: 129531-12-0).

In the context of the present description, if the abbreviation of the group name of the active compound is used, it includes in each case all the usual derivatives, such as esters and salts, as well as isomers, in particular optical isomers, especially one or more commercially available forms. If the group name denotes an ester or a salt, it also includes, in each case, all other conventional derivatives, such as other esters and salts, free acids and neutral compounds, as well as isomers, in particular optical isomers, especially one or more commercially available available forms. The chemical name given to a compound means at least one compound covered by the group name, and generally the preferred compound. In the case of sulfonamides, such as sulfonylureas, salts also include salts formed by the exchange of cations with hydrogen atoms in the sulfonamide group. For example, 2-methyl-4-chloro derivatives include, but are not limited to: 2-methyl-4-chloro-sodium salt, -potassium salt, -dimethylammonium salt, -isopropylamine salt, etc., as well as 2-methyl -4-chloro-methyl ether, -ethyl ether, -isooctyl ether, -thioethyl, etc.; 2,4-D derivatives include, but are not limited to: 2,4-D salts such as sodium salt, potassium salt, dimethylammonium salt, triethanolammonium salt, isopropylamine salt, choline, etc., and 2,4-D esters such as methyl ester, ethyl ether, butyl ether, isooctyl ether, etc.

In the context of the present invention, the salts of the compounds are preferably in the form of the corresponding alkali metal salts, alkaline earth metal salts or ammonium salts, preferably in the form of the corresponding alkali metal salts, more preferably in the form of the corresponding sodium salts or potassium salts, most preferably in the form the corresponding sodium salt.

The composition of the present invention may be diluted before use or may be used directly by consumers. The composition can be prepared by a conventional processing method, that is, the active ingredient(s) are mixed with a liquid solvent or solid carrier, and then one or more surfactants such as a dispersant, stabilizer, wetting agent, adhesive or defoamer, etc. are added. d.

The herbicidal composition may be in the form of a composition selected from: dispersible oil suspension, aqueous suspension, soup emulsion, wettable powder, emulsifiable concentrate, water dispersible granules (dry suspension), aqueous emulsion and microemulsion.

Briefly, the composition of the present invention can be mixed with solid and liquid additives commonly used in prior art formulations. When external conditions change, the amount of active ingredients used also changes. External conditions are, for example, temperature, humidity, the nature of the herbicide used, etc. It can have a wide range of variations, for example, from 0.001 to 1.0 kg/ha or more active substances, but preferably from 0.005 to 750 g/ ha, especially from 0.005 to 500 g/ha.

In addition, the composition according to the invention can be sprayed onto the leaf of the plant to be treated, i.e. the composition of the invention can be applied to a weed, especially to a weed, and especially to the surface of the weed at the location where the weed is or may be invading the crop.

In addition, the present invention also provides the use of a herbicidal composition for controlling weeds; and provides a method of controlling undesirable plant growth, which includes applying a herbicidal composition to plants, plant parts, plant seeds, or a plant growing area; preferably, the herbicidal composition is used for selective control of weeds in a useful crop; more preferably, the useful crop is a genetically modified crop or a crop processed using gene editing technology.

The compounds of the invention are useful for treating all plants and plant parts. Plant varieties and cultivars can be obtained by traditional methods of propagation and selection or by genetic engineering methods. Genetically modified plants (transgenic plants) are plants in which a heterologous gene (transgene) is stably integrated into the plant genome. A transgene, which is defined by its specific location in the plant genome, is called a transformation or transgenic event.

Genetically modified plant varieties that can be processed in accordance with the invention include those that are resistant to one or more biotic stresses (pests such as nematodes, insects, mites, fungi, etc.) or abiotic stresses (drought, low temperatures, soil salinity, etc.), or which have other desirable characteristics. Plants can be genetically modified to exhibit traits such as herbicide resistance, insect resistance, modified oil profiles or drought resistance. Beneficial genetically modified plants containing single gene transformation events or combinations of transformation events are listed in Table 1. Additional information about the genetic modifications listed in Table 1 can be obtained from publicly available databases maintained, for example, by the US Department of Agriculture.

The following abbreviations T1 to T37 are used in Table 1 or characteristics. "-" means the entry is not available.

Property Description Property Description Property Description T1 Glyphosate tolerance E15 Cold tolerance T27 High tryptophan T2 High Lauric Acid Oil E16 Tolerance to imidazolinone herbicide T28 Semi-dwarfism of erect leaves T3 Glufosinate tolerance T17 Modified alpha amylase T29 Semi-dwarfism T4 Phytate breakdown T18 Pollination control T30 Low iron tolerance T5 Tolerance to oxynil T19 Tolerance to 2,4-D T31 Modified oil/fatty acid T6 Disease resistance T20 Elevated lysine T32 Tolerance to HPPD T7 Insect resistance T21 Drought tolerance T33 High oil T9 Modified flower color T22 Delayed destruction/aging T-34 Tolerance to aryloxyalkanoate T11 Tolerance to ALS herbicide T23 Modified Product Quality T35 Tolerance to mesotrione T12 Dicamba tolerance T24 High cellulose T36 Reduced nicotine T13 Antiallergic T25 Modified starch/carbohydrate T37 Modified Product T14 Salt tolerance T26 Resistance to insects and diseases

Genetically modified plants are shown in Table 1.

* Argentine (Brassica napus), ** Polish (B. rapa), # eggplant

When the herbicidal composition of the present invention is used, an unexpected synergistic effect is achieved and the herbicidal activity exceeds the individual or sum of the predicted activities of each herbicide. The synergistic effect results in reduced application rates, broader weed control, and faster and longer-lasting weeding action, all of which are essential for weed control. According to the described characteristics, the composition is significantly superior to existing herbicides in the field. It is more environmentally friendly because the composition is used in less quantity than the amount of herbicides existing in the art.

The synergistic herbicidal composition of the present invention also has the following advantages:

(1) The composition of the present invention is environmentally friendly and is easily degraded in the environment.

(2) The herbicidal composition of the invention is low cost and convenient to use, and has great economic and social benefits from its popularization and application.

Specific method for carrying out the invention

The following examples are not intended to limit the invention, but only to illustrate how the invention is carried out. These examples show particularly significant effectiveness against certain weeds. Examples are as follows.

A) Examples

1. Dispersible oil suspension of 10% penoxsulam A1 (2+8)

2% penoxsulam+8% A1+5% calcium dodecylbenzenesulfonate+7% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+5% 200# oil solvent+2.5% organobentonite+1.5% fumed silica+methyl oleate as balance.

2. Dispersible oil suspension 12% penoxsulam A2 (2+10)

2% penoxsulam+10% A2+5% calcium dodecylbenzenesulfonate+7% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+5% 200# oil solvent+2.0% organobentonite+1.5% fumed silica+methyl oleate as balance.

3. Dispersible oil suspension 14% penoxsulam A4 (2+12)

2% penoxsulam+12% A4+5% calcium dodecylbenzenesulfonate+7% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+5% 200# oil solvent+2.0% organobentonite+1.5% fumed silica+methyl oleate as balance.

4. Dispersible oil suspension 10% bispiribac-sodium A1 (2+8)

2% bispiribac sodium+8% A1+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+5% 200# oil solvent+2.5% organobentonite+1.5% fumed silica+methyl oleate as a balance.

5. Dispersible oil suspension 12% bispiribac-sodium A2 (2+10)

2% sodium bispiribac+10% A2+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+5% 200# oil solvent+2.0% organobentonite+1.5% fumed silica+methyl oleate as a balance.

6. Dispersible oil suspension 14% bispiribac-sodium A4 (2+12)

2% sodium bispiribac+12% A4+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+5% 200# solvent oil+2.0% organobentonite+1.5% fumed silica+ methyl oleate as balance.

7. Dispersible oil suspension 10% pyrazosulfuron-ethyl A1 (2+8)

2% pyrazosulfuron-ethyl+8% A1+1% urea+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+2.5% organobentonite+1.5% fumed silica+methyl oleate as balance .

8. Dispersible oil suspension 12% pyrazosulfuron-ethyl A2 (2+10)

2% pyrazosulfuron-ethyl+10% A2+1% urea+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+1.5% fumed silica+methyl oleate as residue .

9. Dispersible oil suspension 14% pyrazosulfuron-ethyl A3 (2+12)

2% pyrazosulfuron-ethyl+12% A3+1% urea+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+1.5% fumed silica+methyl oleate as balance .

10. Dispersible oil suspension 12% nicosulfuron A1 (4+8)

4% nicosulfuron + 8% A1 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 2.2% organobentonite + 1.5% fumed silica + methyl oleate as balance.

11. Dispersible oil suspension 14% nicosulfuron A2 (4+10)

4% nicosulfuron + 10% A2 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 2.0% organobentonite + 1.5% colloidal silicon dioxide + methyl oleate as balance.

12. Dispersible oil suspension 16% nicosulfuron A4 (4+12)

4% nicosulfuron + 12% A4 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 1.8% organobentonite + 1.5% colloidal silicon dioxide + methyl oleate as balance.

13. Dispersible oil suspension 8.3% florasulam A1 (0.3+8)

0.3% florasulam + 8% A1 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ester of dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ester of castor oil + 2.5% organobentonite + 1.5% fumed silica + methyl oleate as balance.

14. Dispersible oil suspension 10.3% florasulam A2 (0.3+10)

0.3% florasulam + 10% A2 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ester of dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ester of castor oil + 2.2% organobentonite + 1.5% fumed silica + methyl oleate as balance.

15. Dispersible oil suspension 12.3% florasulam A3 (0.3+12)

0.3% florasulam + 12% A3 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ester of dehydrated fatty acid ester of sorbitol + 4% polyoxyethylene ester of castor oil + 2.0% organobentonite + 1.5% fumed silica + methyl oleate as balance.

16. Dispersible oil suspension 10% rimsulfuron A1 (2+8)

2% rimsulfuron + 8% A1 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 2.5% organobentonite + 1.5% fumed silica + methyl oleate as balance.

17. Dispersible oil suspension 12% rimsulfuron A2 (2+10)

2% rimsulfuron + 10% A2 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate as balance.

18. Dispersible oil suspension 14% rimsulfuron A4 (2+12)

2% rimsulfuron + 12% A4 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate as residue.

19. Dispersible oil suspension 14% imazethapyr A1 (6+8)

6% imazethapyr + 8% A1 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate as balance.

20. Dispersible oil suspension 16% imazethapyr A2 (6+10)

6% imazethapyr + 10% A2 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate as balance.

21. Dispersible oil suspension 18% imazethapyr A4 (6+12)

6% imazethapyr + 12% A4 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 1.8% organobentonite + 1.5% fumed silica + methyl oleate as balance.

22. Dispersible oil suspension 18% imazapic A1 (10+8)

10% imazapic + 8% A1 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate as balance.

23. Dispersible oil suspension 20% imazapic A2 (10+10)

10% imazapic + 10% A2 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate as balance.

24. Dispersible oil suspension 22% imazapic A4 (10+12)

10% imazapic + 12% A4 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 1.8% organobentonite + 1.5% fumed silica + methyl oleate as residue.

25. Dispersible oil suspension 12% imazamox A1 (4+8)

4% imazamox+8% A1+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+2.2% organobentonite+1.5% fumed silica+methyl oleate as balance.

26. Dispersible oil suspension 14% imazamox A2 (4+10)

4% imazamox+10% A2+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+1.5% fumed silica+methyl oleate as balance.

27. Dispersible oil suspension 16% imazamox A4 (4+12)

4% imazamox + 12% A4 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 1.8% organobentonite + 1.5% fumed silica + methyl oleate as balance.

28. Dispersible oil suspension 18% sulfometuron-methyl A1 (10+8)

10% sulfometuron-methyl+8% A1+1% urea+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+1.5% fumed silica+methyl oleate as residue .

29. Dispersible oil suspension 20% sulfometuron-methyl A2 (10+10)

10% sulfometuron-methyl + 10% A2 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 1.8% organobentonite + 1.5% fumed silica + methyl oleate as residue .

30. Dispersible oil suspension 22% sulfometuron-methyl A4 (10+12)

10% sulfometuron-methyl + 12% A4 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 1.6% organobentonite + 1.5% fumed silica + methyl oleate as residue .

31. Dispersible oil suspension 10% chloransulam-methyl A1 (2+8)

2% chloransulam-methyl + 8% A1 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ester of dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether of castor oil + 2.5% organobentonite + 1.5% fumed silica + methyl oleate as balance .

32. Dispersible oil suspension 12% chloransulam-methyl A2 (2+10)

2% chloransulam-methyl + 10% A2 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ester of dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether of castor oil + 2.2% organobentonite + 1.5% fumed silica + methyl oleate as balance .

33. Dispersible oil suspension 14% chloransulam-methyl A3 (2+12)

2% chloransulam-methyl + 12% A3 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether of dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether of castor oil + 2.0% organobentonite + 1.5% fumed silica + methyl oleate as balance .

34. Dispersible oil suspension of 18% cyhalofop-butyl A1 (10+8)

10% cyhalofop-butyl+8% A1+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene ester of dehydrated sorbitol fatty acid ester+4% castor oil polyoxyethylene ether+2.0% organobentonite+1.5% fumed silica+15% 150# oil solvent + methyl oleate as balance.

35. Aqueous emulsion 20% cyhalofop-butyl A2 (10+10)

10% cyhalofop-butyl+10% A2+20% 150# oil solvent+3.5% phenylethylphenol polyoxyethylene ether phosphate triethanolamine salt+5% castor oil polyoxyethylene ether+3% ethylene glycol+deionized water as balance.

36. Dispersible oil suspension of 22% cyhalofop-butyl A4 (10+12)

10% cyhalofop-butyl+12% A4+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene ether of dehydrated sorbitol fatty acid ester+4% castor oil polyoxyethylene ether+2.0% organobentonite+1.5% fumed silica+15% 150# oil solvent + methyl oleate as balance.

37. Dispersible oil suspension 11% clodinafop-propargyl A1 (3+8)

3% clodinafop-propargyl+8% A1+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene ester dehydrated sorbitol fatty acid ester+4% castor oil polyoxyethylene ether+2.5% organobentonite+2.0% fumed silica+15% 150# solvent oil + methyl oleate as a balance.

38. Aqueous emulsion 13% clodinafope-propargyl A2 (3+10)

3% clodinafop-propargyl+10% A2+15% 150# oil solvent+5% cyclohexanone+3.5% phenylethylphenol polyoxyethylene ether phosphate triethanolamine salt+5% castor oil polyoxyethylene ether+3% ethylene glycol+deionized water as balance.

39. Dispersible oil suspension 15% clodinafop-propargyl A3 (3+12)

3% clodinafop-propargyl+12% A3+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene ester of dehydrated sorbitol fatty acid ester+4% castor oil polyoxyethylene ether+2.0% organobentonite+1.5% fumed silica+15% 150# oil solvent + methyl oleate as balance.

40. Aqueous suspension of 13% pinoxaden A1 (5+8)

5% pinoxaden + 8% A1 + 5% polycarboxylate + 2% propylene glycol block polyether + 2% polyoxyethylene fatty alcohol ether + 0.2% xanthan gum + 2.0% magnesium aluminum silicate + 3% ethylene glycol + 0.1% silicone as an antifoam +deionized water as balance.

41. Emulsifiable concentrate 15% pinoxaden A2 (5+10)

5% pinoxaden + 10% A2 + 15% tetrahydrofurfuryl alcohol + 1% triphenyl phosphate + 5% calcium dodecylbenzenesulfonate + 3.5% phenylethylphenol polyoxyethylene ether + 5% castor oil polyoxyethylene ether + 150# oil solvent as the residue.

42. Dispersible oil suspension 17% pinoxaden A3 (5+12)

5% pinoxaden+12% A3+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene ester dehydrated sorbitol fatty acid ester+4% castor oil polyoxyethylene ether+1.8% organobentonite+1.5% colloidal silica+10% 150# oil solvent + methyl oleate as balance.

43. Dispersible oil suspension 14% clethodim A1 (6+8)

6% clethodim+8% A1+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene ether dehydrated sorbitol fatty acid ester+4% polyoxyethylene ether castor oil+2.0% organobentonite+1.5% pyrogenic silica+5% 150# oil solvent + methyl oleate as balance.

44. Emulsifiable concentrate 16% clethodim A2(6+10)

6% clethodim + 10% A2 + 4% calcium dodecylbenzenesulfonate + 4% polyoxyethylene phenylethylphenol ether + 4% polyoxyethylene fatty alcohol ether + 150# oil solvent as balance.

45. Dispersible oil suspension 18% clethodim A4 (6+12)

6% clethodim + 12% A4 + 6% calcium dodecylbenzenesulfonate + 9% polyoxyethylene ether of dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether of castor oil + 1.8% organobentonite + 1.5% colloidal silica + 5% 150# oil solvent + methyl oleate as balance.

46. Dispersible oil suspension 23% sethoxydim A1 (15+8)

15% methoxydim+8% A1+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.2% organobentonite+1.5% pyrogenic silica+5% 150# oil solvent+methyl oleate as balance.

47. Emulsifiable concentrate 25% sethoxydim A2 (15+10)

15% methoxydim + 10% A2 + 4% calcium dodecylbenzenesulfonate + 6% polyoxyethylene phenylethylphenol ether + 3% polyoxyethylene fatty alcohol ether + 150# oil solvent as balance.

48. Dispersible oil suspension 27% sethoxydim A4 (15+12)

15% methoxydim + 12% A4 + 6% calcium dodecylbenzenesulfonate + 9% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.8% organobentonite + 1.5% fumed silica + 5% 150# oil solvent + methyl oleate as balance .

49. Dispersible oil suspension 12% quizalofop-R-methyl A1 (4+8)

4% quizalofop-P-methyl+8% A1+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.4% organobentonite+1.5% colloidal silica+20% 150# oil solvent +methyl oleate as balance.

50. Aqueous emulsion 14% quizalofop-R-methyl A2(4+10)

4% quizalofop-P-methyl+10% A2+6% cyclohexanone+20% 150# oil solvent+3.5% phenylethylphenol polyoxyethylene ether phosphate triethanolamine salt+4.5% polyoxyethylene castor oil ether+3% ethylene glycol+deionized water in as a balance.

51. Dispersible oil suspension 16% quizalofop-R-methyl A4 (4+12)

4% quizalofop-P-methyl+12% A4+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+1.5% colloidal silica+20% 150# oil solvent +methyl oleate as balance.

52. Dispersible oil suspension 12% fluazifop-R-butyl A1 (4+8)

4% fluazifop-P-butyl+8% A1+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.4% organobentonite+1.5% fumed silica+5% 150# oil solvent+ methyl oleate as balance.

53. Aqueous emulsion 14% fluazifop-R-butyl A2 (4+10)

4% fluazifop-R-butyl+10% A2+20% 150# oil solvent+3.5% triethanolamine phosphate phenylethylphenol polyoxyethylene ether+4.5% castor oil polyoxyethylene ether+3% ethylene glycol+deionized water as balance.

54. Dispersible oil suspension 16% fluazifop-R-butyl A4 (4+12)

4% fluazifop-R-butyl+12% A4+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+1.5% colloidal silica+5% 150# oil solvent +methyl oleate as balance.

55. Dispersible oil suspension 12% haloxyfop-R-methyl A1 (4+8)

4% haloxyfop-P-methyl+8% A1+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.4% organobentonite+1.5% colloidal silica+5% 150# oil solvent +methyl oleate as balance.

56. Aqueous emulsion 14% haloxyfop-R-methyl A2 (4+10)

4% haloxyfop-P-methyl + 10% A2 + 20% 150# oil solvent + 3.5% triethanolamine phosphate phenylethylphenol polyoxyethylene ether + 4.5% castor oil polyoxyethylene ether + 3% ethylene glycol + deionized water as balance.

57. Dispersible oil suspension 16% haloxyfop-R-methyl A4 (4+12)

4% haloxyfop-P-methyl+12% A4+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+1.5% colloidal silica+5% 150# oil solvent +methyl oleate as balance.

58. Dispersible oil suspension 29% atrazine A1 (25+4)

25% atrazine + 4% A1 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether castor oil + 1.0% organobentonite + 5% 150# oil solvent + methyl oleate as balance.

59. Dispersible oil suspension 30% atrazine A2 (25+5)

25% atrazine + 5% A2 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether castor oil + 1.0% organobentonite + 0.5% pyrogenic silica + 5% 150# oil solvent + methyl oleate as balance.

60. Dispersible oil suspension 31% atrazine A4 (25+6)

25% atrazine + 6% A4 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether of dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether of castor oil + 0.8% organobentonite + 5% 150# oil solvent + methyl oleate as balance.

61. Dispersible oil suspension 29% isoproturon A1 (25+4)

25% isoproturon + 4% A1 + 4% calcium dodecyl benzene sulfonate + 8% polyoxyethylene ether of dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether of castor oil + 1.0% organobentonite + 5% 150# oil solvent + methyl oleate as balance.

62. Dispersible oil suspension 30% isoproturon A2 (25+5)

25% isoproturon + 5% A2 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether castor oil + 1.0% organobentonite + 0.5% colloidal silica + 5% 150# oil solvent + methyl oleate as balance.

63. Dispersible oil suspension 31% isoproturon A3 (25+6)

25% isoproturon + 6% A3 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether of dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether of castor oil + 0.8% organobentonite + 5% 150# oil solvent + methyl oleate as balance.

64. Dispersible oil suspension 29% chlortoluron A1 (25+4)

25% chlortoluron + 4% A1 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether castor oil + 1.0% organobentonite + 5% 150# oil solvent + methyl oleate as balance.

65. Dispersible oil suspension 30% chlortoluron A2 (25+5)

25% chlortoluron + 5% A2 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether castor oil + 1.0% organobentonite + 0.5% colloidal silica + 5% 150# oil solvent + methyl oleate as balance.

66. Dispersible oil suspension 31% chlortoluron A3 (25+6)

25% chlortoluron + 6% A3 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether castor oil + 0.8% organobentonite + 5% 150# oil solvent + methyl oleate as balance.

67. Dispersible oil suspension 34% diuron A1 (30+4)

30% diuron + 4% A1 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether of dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether of castor oil + 0.6% organobentonite + 5% 150# oil solvent + methyl oleate as balance.

68. Dispersible oil suspension 35% diuron A2 (30+5)

30% diuron + 5% A2 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether of dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether of castor oil + 0.8% organobentonite + 8% 150# oil solvent + methyl oleate as balance.

69. Dispersible oil suspension 36% diuron A4 (30+6)

30% diuron + 6% A4 + 5% calcium dodecyl benzene sulfonate + 7% polyoxyethylene ether dehydrated sorbitol fatty acid ester + 4% polyoxyethylene ether castor oil + 0.4% organobentonite + 8% 150# oil solvent + methyl oleate as balance.

70. Aqueous solution of 48% bentazone A1 (40+8)

40% bentazone + 8% A1 + 5% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water as balance.

71. Dispersible oil suspension 25% bentazone A2 (20+5)

20% bentazone+5% A2+6% calcium dodecylbenzenesulfonate+8% polyoxyethylene sorbitol fatty acid ester dehydrated ester+4% polyoxyethylene castor oil ether+0.8% organobentonite+0.8% colloidal silica+8% 150# oil solvent + methyl oleate as balance.

72. Aqueous solution of 52% bentazone A3 (40+12)

40% bentazone + 12% A3 + 5.5% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water as balance.

73. Aqueous solution of 20% bromoxynyl A1 (12+8)

12% bromoxynyl + 8% A1 + 4% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water as balance.

74. Emulsifiable concentrate 22% bromoxynyl A2(12+10)

12% bromoxynyl + 10% A2 + 10% 1-octylpyrrolidin-2-one + 3% calcium dodecylbenzenesulfonate + 5% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 150# oil solvent as balance.

75. Aqueous solution of 24% bromoxynyl A3 (12+12)

12% bromoxynyl+12% A3+5% NaOH+5% polyoxyethylene fatty alcohol ether+15% C8-10 alkyl glucoside+deionized water as balance.

76. Dispersible oil suspension of 27% propanil A1 (25+2)

25% propanil + 2% A1 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether of cardanol + 4% polyoxyethylene ether of castor oil + 0.6% organobentonite + methyl oleate as balance.

77. Emulsifiable concentrate 27.5% propanyl A2 (25+2.5)

25% propanil+2.5% A2+10% 1-octylpyrrolidin-2-one+10% N, N-dimethylcapramide+2% calcium dodecylbenzenesulfonate+10% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+150# oily solvent as balance.

78. Dispersible oil suspension of 28% propanil A4 (25+3)

25% propanil + 3% A4 + 5% calcium dodecylbenzenesulfonate + 7% polyoxyethylene ether of cardanol + 4% polyoxyethylene ether of castor oil + 0.4% organobentonite + methyl oleate as balance.

79. Dispersible oil suspension 17% cipirafluon A1 (9+8)

9% cipirafluon+8% A1+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.5% organobentonite+1.5% pyrogenic silica+10% 150# oil solvent+methyl oleate as balance.

80. Dispersible oil suspension 19% cipirafluon A2 (9+10)

9% cipirafluon+10% A2+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+2.0% fumed silica+10% 150# oil solvent+methyl oleate as balance .

81. Dispersible oil suspension 21% cipirafluon A3 (9+12)

9% cipirafluon + 12% A3 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.2% organobentonite + 1.2% fumed silica + 10% 150# oil solvent + methyl oleate as balance .

82. Dispersible oil suspension 10% bipyrazone A1(2+8)

2% bipyrazone+8% A1+0.4% citric acid+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene ether of cardanol+4% polyoxyethylene ether of castor oil+1.5% organobentonite+1.5% pyrogenic silicon dioxide+8% 150 # oil solvent + methyl oleate as balance.

83. Dispersible oil suspension 12% bipyrazone A2 (2+10)

2% bipyrazone + 10% A2 + 0.4% citric acid + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether of cardanol + 4% polyoxyethylene ether of castor oil + 1.5% organobentonite + 1.5% pyrogenic silicon dioxide + 8% 150 # oil solvent + methyl oleate as balance.

84. Dispersible oil suspension 14% bipyrazone A3 (2+12)

2% bipyrazone + 12% A3 + 0.4% citric acid + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether of cardanol + 4% polyoxyethylene ether of castor oil + 1.2% organobentonite + 1.2% pyrogenic silicon dioxide + 8% 150 # oil solvent + methyl oleate as balance.

85. Dispersible oil suspension 17% phenpyrazone A1 (9+8)

9% phenpyrazone+8% A1+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.5% organobentonite+1.5% pyrogenic silica+5% 150# oil solvent+methyl oleate as balance.

86. Dispersible oil suspension 19% phenpyrazone A2 (9+10)

9% phenpyrazone + 10% A2 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 2.0% organobentonite + 2.0% fumed silica + 5% 150# oil solvent + methyl oleate as balance .

87. Dispersible oil suspension 21% phenpyrazone A3 (9+12)

9% phenpyrazone+12% A3+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.2% organobentonite+1.2% pyrogenic silica+5% 150# oil solvent+methyl oleate as balance.

88. Dispersible oil suspension 20% trypyrasulfone A1 (12+8)

12% tripyrasulfone+8% A1+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.5% organobentonite+1.5% pyrogenic silica+5% 150# oil solvent+methyl oleate as balance.

89. Dispersible oil suspension 22% trypyrasulfone A2 (12+10)

12% tripyrasulfone+10% A2+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+2.0% fumed silica+5% 150# oil solvent+methyl oleate as balance .

90. Dispersible oil suspension 24% trypyrasulfone A4 (12+12)

12% tripyrasulfone+12% A4+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.2% organobentonite+1.2% fumed silica+5% 150# oil solvent+methyl oleate as balance .

91. Dispersible oil suspension 14% tefuryltrione A1 (6+8)

6% tefuryltrione+8% A1+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.8% organobentonite+1.8% pyrogenic silica+5% 150# oil solvent+methyl oleate as balance.

92. Dispersible oil suspension 16% tefuryltrione A2 (6+10)

6% tefuryltrione+10% A2+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+2.0% fumed silica+5% 150# oil solvent+methyl oleate as balance .

93. Dispersible oil suspension 18% tefuryltrione A4 (6+12)

6% tefuryltrione+12% A4+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.2% organobentonite+1.0% fumed silica+5% 150# oil solvent+methyl oleate as balance .

94. Dispersible oil suspension 18% mesotrione A1 (10+8)

10% mesotrione+8% A1+0.5% citric acid+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.8% organobentonite+1.8% fumed silica+5% 150# oil solvent + methyl oleate as balance.

95. Dispersible oil suspension 20% mesotrione A2 (10+10)

10% mesotrione+10% A2+0.5% citric acid+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+2.0% fumed silica+5% 150# oil solvent + methyl oleate as balance.

96. Dispersible oil suspension 22% mesotrione A3 (10+12)

10% mesotrione+12% A3+0.5% citric acid+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.2% organobentonite+1.0% fumed silica+5% 150# oil solvent + methyl oleate as balance.

97. Dispersible oil suspension 14% tembotrione A1 (6+8)

6% tembotrione+8% A1+1% citric acid+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.8% organobentonite+1.8% fumed silica+5% 150# oil solvent +methyl oleate as balance.

98. Dispersible oil suspension 16% tembotrione A2 (6+10)

6% tembotrione+10% A2+1% citric acid+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+2.0% pyrogenic silica+5% 150# oil solvent + methyl oleate as balance.

99. Dispersible oil suspension 18% tembotrione A3 (6+12)

6% tembotrione + 12% A3 + 1% citric acid + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.2% organobentonite + 1.0% pyrogenic silica + 5% 150# oil solvent + methyl oleate as balance.

100. Dispersible oil suspension 11% topramesone A1 (3+8)

3% topramesone+8% A1+0.2% citric acid+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+2.0% fumed silica+5% 150# oil solvent + methyl oleate as balance.

101. Dispersible oil suspension 13% topramesone A2 (3+10)

3% topramesone + 10% A2 + 0.2% citric acid + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether of cardanol + 4% polyoxyethylene ether of castor oil + 2.0% organobentonite + 2.0% pyrogenic silicon dioxide + 5% 150 # oil solvent + methyl oleate as balance.

102. Dispersible oil suspension 15% topramesone A3 (3+12)

3% topramesone+12% A3+0.2% citric acid+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene ether castor oil+1.5% organobentonite+1.5% fumed silica+5% 150# oil solvent + methyl oleate as balance.

103. Dispersible oil suspension 14% isoxaflutole A1 (6+8)

6% isoxaflutole+8% A1+0.5% citric acid+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.8% organobentonite+1.8% pyrogenic silica+5% 150 # oil solvent + methyl oleate as balance.

104. Dispersible oil suspension of 16% isoxaflutol A2 (6+10)

6% isoxaflutole+10% A2+0.5% citric acid+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+2.0% pyrogenic silica+5% 150 # oil solvent + methyl oleate as balance.

105. Dispersible oil suspension 18% isoxaflutole A4 (6+12)

6% isoxaflutole+12% A4+0.5% citric acid+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.2% organobentonite+1.0% fumed silica+5% 150# oil solvent + methyl oleate as balance.

106. Dispersible oil suspension 28% benzobicilone A1 (20+8)

20% benzobicilone + 8% A1 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.0% organobentonite + 5% 150# oil solvent + methyl oleate as balance.

107. Dispersible oil suspension 30% benzobicilone A2 (20+10)

20% benzobicilone + 10% A2 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.2% organobentonite + 1.2% fumed silica + 5% 150# oil solvent + methyl oleate as balance .

108. Dispersible oil suspension 32% benzobicilone A4 (20+12)

20% benzobicilone + 12% A4 + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 0.5% organobentonite + 5% 150# oil solvent + methyl oleate as balance.

109. Dispersible oil suspension 18% diflufenican A1 (10+8)

10% diflufenican + 8% A1 + 4% calcium dodecyl benzene sulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.2% organobentonite + 1.2% pyrogenic silica + 5% 150# oil solvent + methyl oleate as balance.

110. Dispersible oil suspension of 20% diflufenican A2 (10+10)

10% diflufenican + 10% A2 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.5% organobentonite + 1.5% fumed silica + 5% 150# oil solvent + methyl oleate as balance .

111. Dispersible oil suspension 22% diflufenican A3 (10+12)

10% diflufenican + 12% A3 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 0.8% organobentonite + 5% 150# oil solvent + methyl oleate as balance.

112. Dispersible oil suspension 29% fluorochloridone A1 (25+4)

25% fluorochloridone+4% A1+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+2.0% fumed silica+15% 150# oil solvent+methyl oleate as balance .

113. Dispersible oil suspension 60% fluorochloridone A2 (50+10)

50% fluorochloridone + 10% A2 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene castor oil ether + 10% cyclopentanone + 150# oil solvent as balance.

114. Dispersible oil suspension 31% fluorochloridone A3 (25+6)

25% fluorochloridone+6% A3+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.8% organobentonite+1.8% fumed silica+15% 150# oil solvent+methyl oleate as balance .

115. Dispersible oil suspension 38% clomazone A1 (30+8)

30% clomazone+8% A1+5% calcium dodecylbenzenesulfonate+6% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.5% organobentonite+2.5% pyrogenic silica+5% 150# oil solvent+methyl oleate as balance.

116. Emulsifiable concentrate 40% clomazone A2 (30+10)

30% clomazone + 10% A2 + 6% calcium dodecylbenzenesulfonate + 10% castor oil, polyoxyethylene ether + 10% ethanol + 150# oil solvent as balance.

117. Dispersible oil suspension 42% clomazone A4 (30+12)

30% clomazone + 12% A4 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 2.2% organobentonite + 1.8% fumed silica + 15% 150# oil solvent + methyl oleate as balance .

118. Suspoemulsion 10% carfentrazone-ethyl A1 (2+8)

2% carfentrazone ethyl+8% A1+3% phenylethylphenol polyoxyethylene ether triethanolamine phosphate+4% isooctyl alcohol block polyester+3% castor oil polyoxyethylene ether+10% 150# oil solvent+0.25% xanthan gum+2.0% Magnesium aluminum silicate + 2% ethylene glycol + deionized water as balance.

119. Aqueous emulsion 12% carfentrazone-ethyl A2 (2+10)

2% carfentrazone ethyl + 10% A2 + 3% triethanolamine phosphate phenylethylphenol polyoxyethylene ether + 5% castor oil polyoxyethylene ether + 10% 150# oil solvent + 3% ethylene glycol + deionized water as balance.

120. Aqueous emulsion 14% carfentrazone-ethyl A3 (2+12)

2% carfentrazone ethyl + 12% A3 + 3% triethanolamine phosphate phenylethylphenol polyoxyethylene ether + 5% polyoxyethylene castor oil ether + 10% 150# oil thinner + 0.25% xanthan gum + 2% ethylene glycol + deionized water as balance.

121. Aqueous solution of 33% fomesafen A1 (25+8)

25% fomesafen + 8% A1 + 4% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water as balance.

122. Microemulsion 35% fomesafen A2 (25+10)

25% fomesafen + 10% A2 + 10% cyclohexanone + 10% ethanol + 6% sodium di-sec-octyl maleate sulfonate + 10% C8-10 alkyl glucoside + deionized water as balance.

123. Aqueous solution of 37% fomesafen A3(25+12)

25% fomesafen + 12% A3 + 4.5% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water as balance.

124. Dispersible oil suspension 9% fluoroglycophene A1 (1+8)

1% fluoroglycophene + 8% A1 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 2.0% organobentonite + 2.0% fumed silica + 10% 150# oil solvent + methyl oleate as balance .

125. Aqueous emulsion 11% fluoroglycophene A2 (1+10)

1% fluoroglycophene + 10% A2 + 3% triethanolamine phosphate phenylethylphenol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 10% 150# oil solvent + 0.1% xanthan gum + 2% ethylene glycol + deionized water as balance.

126. Dispersible oil suspension 13% fluoroglycophene A3 (1+12)

1% fluoroglycophene+12% A3+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+2.0% organobentonite+1.5% pyrogenic silica+10% 150# oil solvent+methyl oleate as balance.

127. Dispersible oil suspension 20% oxyfluorfen A1 (12+8)

12% oxyfluorfen + 8% A1 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 5% oil-soluble polycarboxylate + 1.4% organobentonite + 10% soybean oil + methyl oleate as balance.

128. Emulsifiable concentrate 22% oxyfluorfen A2(12+10)

12% oxyfluorfen+10% A2+10% cyclopentanone+3% calcium dodecylbenzenesulfonate+4% polyoxyethylene fatty alcohol ether+4% polyoxyethylene castor oil ether+150# oil solvent as balance.

129. Dispersible oil suspension 24% oxyfluorfen A3 (12+12)

12% oxyfluorfen + 12% A3 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 5% oil-soluble polycarboxylate + 1.4% organobentonite + 10% soybean oil + methyl oleate as balance.

130. Dispersible oil suspension 16% lactofen A1 (8+8)

8% lactofen + 8% A1 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.8% organobentonite + 1.8% fumed silica + 5% 150# oil solvent + methyl oleate as balance .

131. Emulsifiable concentrate 18% lactofen A2 (8+10)

8% lactofen + 10% A2 + 3% calcium dodecylbenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 150# oil solvent as balance.

132. Dispersible oil suspension 20% lactofen A3 (8+12)

8% lactofen + 12% A3 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.6% organobentonite + 1.6% fumed silica + 10% 150# oil solvent + methyl oleate as balance .

133. Aqueous solution of 38% acifluorfen-sodium A1 (30+8)

30% acifluorfen sodium + 8% A1 + 4.5% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water as balance.

134. Dispersible oil suspension 20% acifluorfen-sodium A2 (15+5)

15% acifluorfen sodium + 5% A2 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.6% organobentonite + 1.6% fumed silica + 10% 150# oil solvent + methyl oleate in as a balance.

135. Aqueous solution of 42% acifluorfen-sodium A3 (30+12)

30% acifluorfen sodium + 12% A3 + 5% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water as balance.

136. Dispersible oil suspension of 14% flumioxazin A1 (6+8)

6% flumioxazin + 8% A1 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.6% organobentonite + 10% soybean oil + methyl oleate as balance.

137. Emulsifiable concentrate 16% flumioxazin A2 (6+10)

6% flumioxazin + 10% A2 + 15% cyclopentanone + 3% calcium dodecylbenzenesulfonate + 4% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene castor oil ether + 150# oil solvent as balance.

138. Dispersible oil suspension 18% flumioxazin A3 (6+12)

6% flumioxazin + 12% A3 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether of cardanol + 4% polyoxyethylene ether of castor oil + 1.4% organobentonite + 10% soybean oil + methyl oleate as balance.

139. Dispersible oil suspension 32% sulfentrazone A1 (24+8)

24% sulfentrazone + 8% A1 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.3% organobentonite + 10% 150# oil solvent + methyl oleate as balance.

140. Suspoemulsion 34% sulfentrazone A2 (24+10)

24% sulfentrazone + 10% A2 + 8% 150# oil solvent + 4% triethanolamine phosphate phenylethylphenol polyoxyethylene ether + 4% propylene glycol block polyether + 4% castor oil polyoxyethylene ether + 0.15% xanthan gum + 2% ethylene glycol + deionized water in as a balance.

141. Aqueous suspension 36% sulfentrazone A4 (24+12)

24% sulfentrazone + 12% A4 + 4% triethanolamine phenylethylphenol polyoxyethylene ether phosphate + 3% naphthalene sulfonate as dispersant + 2% polyoxyethylene fatty alcohol ether + 0.15% xanthan gum + 1% magnesium aluminum silicate + 3% ethylene glycol + deionized water as balance .

142. Dispersible oil suspension 32% saflufenacil A1 (24+8)

24% saflufenacil + 8% A1 + 4% calcium dodecyl benzene sulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.2% organobentonite + 1.0% fumed silica + 10% 150# oil solvent + methyl oleate as balance .

143. Suspoemulsion 34% saflufenacil A2(24+10)

24% saflufenacil + 10% A2 + 8% 150# oil solvent + 4% triethanolamine phosphate phenylethylphenol polyoxyethylene ether + 4% propylene glycol block polyether + 4% castor oil polyoxyethylene ether + 0.12% xanthan gum + 2% ethylene glycol + deionized water in as a balance.

144. Aqueous suspension 36% saflufenacil A3(24+12)

24% saflufenacil + 12% A3 + 4% triethanolamine phosphate phenylethylphenol polyoxyethylene ether + 3% naphthalene sulfonate as a dispersant + 2% polyoxyethylene fatty alcohol ether + 0.15% xanthan gum + 1.2% magnesium aluminum silicate + 3% ethylene glycol + deionized water in as a balance.

145. Dispersible oil suspension 24% oxadiazone A1 (20+4)

20% oxadiazone+4% A1+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.2% organobentonite+1.0% fumed silica+10% 150# oil solvent+methyl oleate as balance .

146. Dispersible oil suspension 25% oxadiazone A2 (20+5)

20% oxadiazone + 5% A2 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene castor oil ether + 1.0% organobentonite + 10% 150# oil solvent + methyl oleate as balance.

147. Dispersible oil suspension 26% oxadiazone A4 (20+6)

20% oxadiazone + 6% A4 + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% polyoxyethylene ether castor oil + 1.2% organobentonite + 10% 150# oil solvent + methyl oleate as balance.

148. Dispersible oil suspension 14% oxadiargyl A1 (6+8)

6% oxadiargyl+8% A1+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.6% organobentonite+1.5% fumed silica+10% 150# oil solvent+methyl oleate as balance .

149. Dispersible oil suspension 16% oxadiargyl A2 (6+10)

6% oxadiargyl+10% A2+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.5% organobentonite+1.5% fumed silica+10% 150# oil solvent+methyl oleate as balance .

150. Dispersible oil suspension 18% oxadiargyl A4 (6+12)

6% oxadiargyl+12% A4+4% calcium dodecylbenzenesulfonate+8% polyoxyethylene cardanol ether+4% polyoxyethylene castor oil ether+1.4% organobentonite+1.2% fumed silica+10% 150# oil solvent+methyl oleate as balance .

151. Dispersible oil suspension A172+glyphosate (20+30)

20% A172+30% glyphosate+6% calcium dodecylbenzenesulfonate+6% polyoxyethylene fatty alcohol ether+6% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

152. Dispersible oil suspension A67+glyphosate (10+30)

10% A67+30% glyphosate+5% calcium dodecyl benzene sulfonate+6% polyoxyethylene fatty alcohol ether+5% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

153. Dispersible oil suspension A1+glyphosate (9+30)

9% A1+30% glyphosate+5% calcium dodecylbenzenesulfonate+6% polyoxyethylene fatty alcohol ether+5% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

154. Dispersible oil suspension A4+glyphosate (12+30)

12% A4+30% glyphosate+5% calcium dodecyl benzene sulfonate+6% polyoxyethylene fatty alcohol ether+5% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

155. Dispersible oil suspension A171+glyphosate (20+30)

20% A171+30% glyphosate+5% calcium dodecylbenzenesulfonate+6% polyoxyethylene fatty alcohol ether+6% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

156. Dispersible oil suspension A211+glyphosate (10+30)

10% A211+30% glyphosate+5% calcium dodecylbenzenesulfonate+6% polyoxyethylene fatty alcohol ether+6% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

157. Dispersible oil suspension A94+glyphosate (20+30)

20% A94+30% glyphosate+5% calcium dodecyl benzene sulfonate+6% polyoxyethylene fatty alcohol ether+6% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

158. Dispersible oil suspension A173+glyphosate (10+30)

10% A173+30% glyphosate+5% calcium dodecyl benzene sulfonate+6% polyoxyethylene fatty alcohol ether+6% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

159. Dispersible oil suspension A212+glyphosate (20+30)

20% A212+30% glyphosate+5% calcium dodecyl benzene sulfonate+6% polyoxyethylene fatty alcohol ether+6% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

160. Dispersible oil suspension A141+glyphosate (10+30)

10% A141+30% glyphosate+5% calcium dodecylbenzenesulfonate+6% polyoxyethylene fatty alcohol ether+6% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

161. Dispersible oil suspension A163+glyphosate (10+30)

10% A163+30% glyphosate+5% calcium dodecylbenzenesulfonate+8% polyoxyethylene fatty alcohol ether+5% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

162. Dispersible oil suspension A130+glyphosate (10+30)

10% A130+30% glyphosate+5% calcium dodecylbenzenesulfonate+7% polyoxyethylene fatty alcohol ether+5% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

163. Dispersible oil suspension A213+glyphosate (10+30)

10% A213+30% glyphosate+5% calcium dodecylbenzenesulfonate+7% polyoxyethylene fatty alcohol ether+5% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent + methyl oleate as balance.

164. Dispersible oil suspension A214+glyphosate (10+30)

10% A214+30% glyphosate+5% calcium dodecylbenzenesulfonate+7% polyoxyethylene fatty alcohol ether+5% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

165. Dispersible oil suspension A2+glyphosate (10+30)

10% A2+30% glyphosate+5% calcium dodecyl benzene sulfonate+7% polyoxyethylene fatty alcohol ether+5% polyoxyethylene castor oil ether+0.5% organobentonite+15% 100# oil solvent+methyl oleate as balance.

Equipment for processing the above dispersed oil suspensions: mixing tank, colloid mill, sand mill, mechanical shears, etc.

The processing process of the above dispersible oil suspensions: all the materials are loaded into the mixing tank and mixed with stirring, introduced into the colloid mill, then subjected to 3rd grade grinding in the sand mill, and finally crushed evenly by mechanical shears and transferred to the storage tank after passing the inspection.

Equipment for processing the above aqueous suspensions: mixing tank, colloid mill, sand mill, mechanical shears, etc.

Processing process of the above water suspensions: All the materials are loaded into the mixing tank and mixed with stirring, introduced into the colloid mill, then subjected to 3 degree grinding in the sand mill, and finally crushed evenly by mechanical shears and transferred to the storage tank after passing the inspection.

Equipment for processing the above suspoemulsions: mixing tank, colloid mill, sand mill, mechanical shears, etc.

The processing process of the above suspoemulsions: some of the materials and additives are fed into the mixing tank and mixed with stirring, introduced into the colloid mill, then subjected to 3rd degree grinding in a sand mill, and then transferred to the intermediate tank as an aqueous phase; then the remainder of the materials and the co-solvent are fed into the loading container and dissolved with stirring until they become completely transparent, and then stirred until an oil phase is formed; and finally crushed with mechanical scissors; the oil phase is slowly dripped into the aqueous phase; After all the material has been drained, grinding is continued for 1 hour and, after passing inspection, transferred to a storage tank.

Equipment for processing the above aqueous emulsions: vacuum pump, dispenser, storage tank, grinding tank.

The process of processing the above aqueous emulsions: technical materials and solvent are fed into the dispenser, mixed and dissolved until completely transparent; and an emulsifier is added and then mixed until an oil phase is formed; Glycol, defoamer and deionized water are then pumped into the grinding tank; and finally, in the shear state, the oil phase is slowly pumped into the grinding tank; After all materials have been pumped, grinding is continued for 1 hour, and after passing the inspection, it is transferred to a storage tank.

Equipment for processing the above microemulsion: vacuum pump, dispenser, storage tank.

Processing of the above microemulsions: technical materials and solvent are fed into the dispenser, mixed and dissolved until completely transparent; and add the emulsifier, and then mix until smooth; and add deionized water, and then stir until completely clear; and transferred to a storage tank after passing inspection.

Equipment for processing the above emulsifiable concentrate: vacuum pump, dispenser and storage tank.

The process of processing the above emulsifiable concentrate: technical materials and solvent are fed into the dispenser, mixed and dissolved until completely transparent; and add the emulsifier, and then mix until completely transparent; and transferred to a storage tank after passing inspection.

Equipment for processing the above aqueous solution: vacuum pump, dispenser and storage tank.

The process of processing the above aqueous solution: technical materials and deionized water are fed into the dispenser, mixed and dissolved until completely transparent; and add the emulsifier, and then mix until completely transparent; and transferred to a storage tank after passing inspection.

B) Performance Analyzes

Post-emergence treatment by foliar spray

1) Experimental conditions

1.1) Tested targets

Table 1-48, 51-98, 101-148: Echinochloa crusgalli var. zelayensis, Eclipta prostrate, Galium aparine L., Alopecurus aequalis, Alopecurus japonicus, Lindernia procumbens, Veronica persica ¹ , Malachium aquaticum, Beckmannia syzigachne, Stellaria media are collected in Huai'an of Jiangsu Province; Commelina communis, Sonchus arvensis, Setaria glauca, Chloris virgata, Setaria faberi, Sonchus oleraceus L., Echinochloa oryzoides, Cirsium setosum, Xanthium strumarium are collected from Qiqiha'er of Heilongjiang Province; Sinapis arvensis, Veronica persica ² collected in Zhumadian of Henan Province; Ludwigia prostrate, Ammannia arenaria collected in Zhuji of Zhejiang Province; Amaranthus retroflexus, Descurainia sophia, Digitaria sanguinalis, Setaria viridis, Conyza Canadensis, Capsella bursa-pastoris, Eleusine indica, Ipomoea purpurea, Abutilon theophrasti, Chenopodium album, Acalypha australis, Solanum nigrum are collected in Qingdao of Shandong Province; Echinochloa caudate is collected from Pingluo of Ningxia Province.

Table 151-206: Digitaria sanguinalis, Amaranthus retroflexus, Conyza Canadensis, Capsella bursa-pastoris, Eleusine indica collected in Huangdao of Shandong Province, Sinapis arvensis collected in Sixian of Anhui Province, Alopecurus japonicus collected in Tianchang of Anhui Province, Veronica didyma collected in Siyang of Jiangsu Province.

The above weeds are grown using the pot method. A plastic nutrient bowl measuring 180 x 140 mm, containing 4/5 of the topsoil from the field, is placed in an enamel container in which the soil has been air-dried and sieved and has an initial moisture content of 20%. Complete and uniform weed seeds are selected, soaked in warm water at 25°C for 6 hours and germinated in a biochemical incubator at 28°C (dark). Newly germinated weed seeds are placed evenly on the soil surface and then covered with 0.5-1 cm of soil, depending on the size of the seeds.

1.2) Cultivation conditions

Cultivation is carried out in a greenhouse with controlled sunlight at a temperature of 20 to 30°C, natural light and a relative humidity of 57% to 72%.

The soil is loam with an organic matter content of 1.63%, a pH value of 7.1, alkaline hydrolyzable nitrogen 84.3 mg/kg, readily available phosphorus 38.5 mg/kg, readily available potassium 82.1 mg/kg.

1.3) Equipment and apparatus

Walking irrigation tower type 3WP-2000 (Nanjing Institute of Agricultural Machinery, the Ministry of Agriculture); Electronic scales with ten-thousandth scale type GA10 (Germany); intelligent data logger type ZDR2000 (Hangzhou Zeda Instrument Co., Ltd.); and SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory).

2) Experimental designs

2.1) Reagents

The desired active ingredient A is obtained based on patent CN201911321469.4. Below are examples of typical compounds; methods for synthesizing other compounds are similar and are not described in detail herein.

(1) Synthesis of compound A67 and A1

Compound a (0.5 g, 2.13 mmol), compound b (313 mg, 2.55 mmol), catalytic amount of TBAB (10 mg) and DMF (10 ml) were added to the round bottom flask and stirred at room temperature 15° C within 24 hours. When LC-MS indicates that a small amount of starting materials remains, further processing is carried out. The reaction solution was poured into 50 ml of water and extracted twice with methyl tert-butyl ether (50 ml x 2). The organic phase is dried, concentrated and separated by column chromatography to give compound A67 (300 mg, 50% yield) as a white solid.

Compound A67 (0.3 g, 1.06 mmol), methanol (20 ml) was added to a 100 ml single port flask, lithium hydroxide (44.5 mg, 1.06 mmol) was dissolved in 2 ml water and slowly added drops into a single-port flask at room temperature, followed by stirring at room temperature for 12 hours. After completion of the reaction of the starting materials according to LC-MS, the reaction solution is adjusted to pH 5-6 with 0.5 M dilute HCl, concentrated and then extracted with water and ethyl acetate. The organic phase is dried and concentrated to give Compound A1 (200 mg, 70% yield) as a white solid.

(2) Synthesis of compound A2

Compound A1 (200 mg, 0.74 mmol), compound c (75 mg, 0.74 mmol), DCC (152 mg, 0.74 mmol) and anhydrous DCM (20 ml) were added to a 100 ml round bottom flask and reacted at room temperature for 12 hours. After the reaction of the starting materials was complete by LC-MS, the reaction solution was concentrated and separated by column chromatography to obtain Compound A2 (200 mg, 77% yield) as a white solid.

(3) Synthesis of compound A211

Compound A1 (200 mg, 0.74 mmol), compound c (85 mg, 0.74 mmol), DCC (152 mg, 0.74 mmol) and anhydrous DCM (20 ml) were added to a 100 ml round bottom flask and reacted at room temperature for 12 hours. After the reaction of the starting materials was complete by LC-MS, the reaction solution was concentrated and separated by column chromatography to obtain compound A211 (200 mg, 73% yield) as a white solid.

(4) Synthesis of compound A173

Compound d (2 g, 18.16 mmol), compound b (3.64 g, 21.80 mmol), catalytic amount of TBAB (10 mg) and DMF (20 ml) were added to the round bottom flask and stirred at room temperature 15° C for 24 hours. When LC-MS shows that a small amount of starting materials remains, further processing is carried out. The reaction solution was poured into 50 ml of water and extracted twice with methyl tert-butyl ether (100 ml x 2). The organic phase is dried, concentrated and separated by column chromatography to give compound e (1.5 mg, 42% yield) as a white solid.

Compound e (0.5 g, 2.55 mmol) was dissolved in acetonitrile (20 ml) and placed in a 100 ml single port flask. NCS (850.7 mg, 6.37 mmol) and a catalytic amount of BPO (10 mg) were added at room temperature, the temperature was raised to 70°C and the reaction was continued for 2 hours. After reaction of the starting materials was complete by LC-MS, the reaction solution was concentrated and separated by column chromatography to obtain compound A173 (300 mg, 44% yield) as a white solid.

(5) Synthesis of compounds A174 and A212

Compound e (0.5 g, 2.55 mmol) was dissolved in acetonitrile (20 ml) and placed in a 100 ml single port flask. NBS (1.13 mg, 6.37 mmol) and a catalytic amount of BPO (10 mg) were added at room temperature, the temperature was raised to 70°C and the reaction was continued for 2 hours. After reaction of the starting materials was complete by LC-MS, the reaction solution was concentrated and separated by column chromatography to obtain compound A174 (500 mg, 54% yield) as a white solid.

Compound A174 (0.5 g, 1.41 mmol) and methanol (20 mL) are added to a 100 mL single port flask, lithium hydroxide (59.3 mg, 1.41 mmol) is dissolved in 2 mL water and slowly added drops into a single-port flask at room temperature, followed by stirring at room temperature for 12 hours. After completion of the reaction of the starting materials according to LC-MS, the reaction solution is adjusted to pH 5-6 with 0.5 M dilute HCl, concentrated and then extracted with water and ethyl acetate. The organic phase is dried and concentrated to give compound A212 (350 mg, 73% yield) as a white solid.

Active ingredient B, such as cipirafluone, bipyrazone, phenpyrazone and tripirasulfone, is produced by our company, and the rest is purchased from reagent manufacturing companies. All technical materials are dissolved in acetone and diluted with an aqueous solution containing 0.1% Tween-80 emulsifier. Dilution is carried out as needed.

2.2) Experimental treatments

2.2.1) Determination of dosage

The ratio of active ingredient A to active ingredient B and their quantity in each group depends on the characteristics and toxicity of the two agents, as well as on the primary purpose of use of the respective formulation. Based on preliminary testing in this study, the dosage of active ingredients A and B, used individually and in combination, is shown in the tables. As a blank control, use water containing a solvent and emulsifier, the same as the above groups, but not containing agents.

2.2.2) Repeating experiments

Tables 1-48, 51-98, 101-148, 151-206: 3 pots of 20 weed seeds per pot are treated in one treatment with 4 replicates per treatment, that is, a total of 60 weeds are treated in one treatment.

Tables 207-216: 10 pots with 10 weed seeds per pot are treated in one treatment with 4 replicates per treatment, and then kept at 3 weeds per pot.

2.3) Processing method

2.3.1) Processing times and frequency

Tables 1-48, 51-98, 101-148: Agents are used only once in the experiment. At the 3~4 leaf stage, the weeds are thinned to leave 15 weeds per pot and 45 weeds in each treatment, then continue to be cultivated to the 5~6 leaf stage of grassy weeds, 6~7 leaf stage of broadleaf weeds and treated.

Table 151-206: Agents are used only once per experiment. At the 3~4 leaf stage, the weeds are thinned to leave 15 weeds per pot and 45 weeds for each treatment, then continue to be cultivated to the 4~5 leaf stage of grassy weeds, 5~6 leaf stage of broadleaf weeds and treated.

Table 207-216: Agents are used only once in an experiment. At the 6~8 leaf stage, the weeds are thinned to leave 3 weeds per pot and 30 weeds per treatment, then continue to be cultivated to Conyza Canadensis 10cm tall and treated.

2.3.2) Equipment and methods of applying agents

Well-cultivated weeds are evenly placed on an area of 0.5 ^m2 and their stems and leaves are sprayed with a solution of preparations using a walking spray tower type 3WP-2000 at a dosage of 450 kg/ha and at a spray pressure of 0.3 MPa. After spraying all the solution, the valve is closed. After 30 seconds, the spray tower door is opened and the feed cup is removed. The valve is then opened and the spray tube is cleaned by spraying 50 ml of water.

3) Experimental methods

They use the pot growing method. For weed cultivation, see section 1.1) and "Pesticide guidelines for laboratory bioactivity tests - herbicides". Regarding methods of application of agents, see section 2.3.2), that is, foliar treatment is used. After treatment, the weeds are grown in a greenhouse in the usual manner.

4) Data research and statistical analysis

4.1) Research methods

A method is used to determine the absolute abundance, in which whole shoots of germinating weeds are cut with a knife along the soil surface and the wet mass of weeds is weighed on an analytical balance. For dead weeds, their fresh weight is zero.

4.2) Timing and frequency of research

Tables 1-48, 51-98, 101-148, 207-216: The study is carried out 24 days after treatment only once.

Table 151-206: The study is carried out 20 days after treatment only once.

4.3) Statistical data analysis

The theoretical inhibition rate of the combination of two active ingredients in each group is calculated by Gowing's method (E0=X+YX*Y/100), and then compared with the actually measured inhibition rate (E), thereby assessing the effect of the combination (hereinafter referred to as the combination effect) on weeds: an E-E0 value greater than 10% corresponds to a synergistic effect, an E-E0 value less than -10% corresponds to an antagonistic effect, and an E-E0 value between -10% and 10% corresponds to an additive effect. The optimal ratio of the two active ingredients is determined by the actual control effect, the characteristics of the herbicides and the balance of the corresponding formula. Where, in the formula, X represents the degree of wet weight inhibition of active ingredient A at dosage P, and Y represents the degree of wet weight inhibition of active ingredient B at dosage Q.

Treatment for silted soil:

1) Experimental conditions

1.1) Tested targets

Echinochloa crusgalli var. zelayensis collected in Huai'an of Jiangsu Province; Echinochloa caudate collected from Pingluo of Ningxia Province; Echinochloa oryzoides was collected from Qiqiha'er of Heilongjiang Province.

1.2) Cultivation conditions

Cultivation is carried out in a greenhouse with controlled sunlight at a temperature of 20 to 30°C, natural light and a relative humidity of 57% to 72%. The soil was loam with an organic matter content of 1.63%, a pH value of 7.1, alkaline hydrolyzable nitrogen 84.3 mg/kg, readily available phosphorus 38.5 mg/kg, readily available potassium 82.1 mg/kg. The soil to be tested is quantitatively placed on 3/4 of the pots, and then moistened from the bottom of the pots until the soil is completely moistened to saturation. Pre-treated seeds of the tested weeds are sown evenly on the surface, then covered with soil 0.5-2 cm depending on the size of the seeds and 24 hours after sowing they are ready for use.

1.3) Equipment and apparatus

Electronic scales with ten-thousandth scale type GA10 (Germany); intelligent data logger type ZDR2000 (Hangzhou Zeda Instrument Co., Ltd.); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory), pipette dispenser, etc.

2) Experimental designs

2.1) Reagents

All technical materials are dissolved in acetone and diluted with an aqueous solution containing 0.1% T-80 emulsifier. Dilution is carried out as necessary.

2.2) Experimental treatments

2.2.1) Determination of dosage

The ratio of A to active ingredient B and their quantity in each group depends on the characteristics and toxicity of the two agents, as well as on the main purpose of use of the respective composition. Based on preliminary tests in this study, the dosage of A and active ingredient B, used individually and in combination, is shown in the tables. As a blank control, use water containing a solvent and emulsifier, the same as in the above groups, but not containing agents.

2.2.2) Repeating experiments

3 pots with 30 weed seeds per pot are treated with one treatment with 4 repetitions per treatment.

3) Experimental methods

The pots, which are seeded and mulched, are evenly placed on a platform with an area of 0.5 m ² and the soil surface is sprayed with a solution of agents using a walking spray tower type 3WP-2000 at a dosage of 675 kg/ha and at a spray pressure of 0.3 MPa. After spraying all the solution, the valve is closed. After 30 seconds, the spray tower door is opened and the feed cup is removed. The valve is then opened and the spray tube is cleaned by spraying 50 ml of water.

4) Data research and statistical analysis

This section is the same as Section 4) for post-emergence foliar spray treatment and is not repeated here.

The statistical results are presented in Tables 1-216 below. Apart from those labeled as siltation treatments, all others are post-emergence foliar spray treatments.

Table 1. Controlling effect of A2 or penoxsulam alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B
g a.i./ha A: B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Controlling action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 75.3 2.4 89.4 75.9 13.5 150+3.75 40:1 75.3 10.9 90.2 78.0 12.2 75+7.5 10:1 54.2 48.8 88.9 76.6 12.3 75+15 5:1 54.2 70.1 99.7 86.3 13.4

Table 2. Controlling effect of A2 or bispiribac sodium individually and their combination on Echinochloa crusgalli var. zelayensis Dose A+B g a.i./ha A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Controlling action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 75.3 5.3 87.9 76.6 11.3 150+3.75 40:1 75.3 17.4 92.1 79.6 12.5 75+7.5 10:1 54.2 43.4 86.2 74.1 12.1 75+15 5:1 54.2 62.9 95.2 83.0 12.2

Table 3. Controlling effect of A2 or pyrazosulfuron-ethyl individually and their combination on Eclipta prostrate Dose A+B g a.i./ha A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Controlling action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 68.4 9.5 83.5 71.4 12.1 150+3.75 40:1 68.4 19.9 87.2 74.7 12.5 75+7.5 10:1 32.3 51.0 80.4 66.8 13.6 75+15 5:1 32.3 76.1 96.2 83.8 12.4

Table 4. Controlling effect of A2 or nicosulfuron alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B g a.i./ha A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Controlling action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 75.3 7.3 88.1 77.1 11.0 150+7.5 20:1 75.3 15.4 91.4 79.1 12.3 75+15 5:1 54.2 39.3 86.5 72.2 14.3 75+30 5:2 54.2 58.7 94.0 81.1 12.9

Table 5. Controlling effect of A2 or florasulam individually and their combination on Galium aparine L. Dose A+B g a.i./ha A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Controlling action A+B (%), E E0 (%) E-E0 (%) 15+0.375 40:1 68.5 4.8 82.6 70.0 12.6 15+0.75 20:1 68.5 20.6 88.2 75.0 13.2 7.5+1.5 5:1 34.8 56.3 86.4 71.5 14.9 7.5+3.0 5:2 34.8 76.2 98.2 84.5 13.7

Table 6. Controlling effect of A2 or rimsulfuron alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B g a.i./ha A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Controlling action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 75.3 7.7 88.4 77.2 11.2 150+3.75 40:1 75.3 25.5 93.6 81.6 12.0 75+7.5 10:1 54.2 39.7 87.0 72.4 14.6 75+15 5:1 54.2 67.7 97.9 85.2 12.7

Table 7. Controlling effect of A2 or imazethapyr alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B g a.i./ha A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Controlling action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 75.3 3.2 86.6 76.1 10.5 150+15 10:1 75.3 19.8 93.9 80.2 13.7 75+30 5:2 54.2 31.2 83.3 68.5 14.8 75+60 5:4 54.2 59.2 93.7 81.3 12.4

Table 8. Controlling effect of A2 or imazapic alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B g a.i./ha A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Controlling action A+B (%), E E0 (%) E-E0 (%) 150+9.375 16:1 75.3 1.2 87.9 75.6 12.3 150+18.75 8:1 75.3 18.6 92.3 79.9 12.4 75+37.5 2:1 54.2 26.9 82.2 66.5 15.7 75+75 1:1 54.2 57.0 92.4 80.3 12.1

Table 9. Controlling effect of A2 or imazamox alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B g a.i./ha A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Controlling action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 75.3 6.9 89.2 77.0 12.2 150+7.5 20:1 75.3 14.2 91.4 78.8 12.6 75+15 5:1 54.2 25.1 81.1 65.7 15.4 75+30 5:2 54.2 54.8 91.1 79.3 11.8

Table 10. Controlling effect of A2 or sulfometuron-methyl individually and their combination on Echinochloa crusgalli var. zelayensis Dose A+B g a.i./ha A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Controlling action A+B (%), E E0 (%) E-E0 (%) 150+9.375 16:1 75.3 2.0 85.9 75.8 10.1 150+18.75 8:1 75.3 13.8 94.5 78.7 15.8 75+37.5 2:1 54.2 24.5 79.1 65.4 13.7 75+75 1:1 54.2 54.8 91.8 79.3 12.5

Table 11. Controlling effect of A2 or cloransulam-methyl individually and their combination on Commelina communis Dose A+B g a.i./ha A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Controlling action A+B (%), E E0 (%) E-E0 (%) 60+1.875 32:1 67.8 4.7 81.2 69.3 11.9 60+3.75 16:1 67.8 15.2 86.9 72.7 14.2 30+7.5 4:1 32.3 53.5 82.3 68.5 13.8 30+15 2:1 32.3 71.8 93.4 80.9 12.5

Table 12. Controlling effect of A2 or cyhalofop-butyl alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+9.375 16:1 75.3 1.6 86.7 75.7 11.0 150+18.75 8:1 75.3 17.4 89.8 79.6 10.2 75+37.5 2:1 54.2 31.0 81.3 68.4 12.9 75+75 1:1 54.2 70.3 98.6 86.4 12.2

Table 13. Controlling effect of A2 or clodinafope-propargyl alone and in combination on Alopecurus aequalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 45.5 6.1 61.1 48.8 12.3 150+7.5 20:1 45.5 16.3 68.2 54.4 13.8 75+15 5:1 23.8 59.3 83.4 69.0 14.4 75+30 5:2 23.8 81.1 98.3 85.6 12.7

Table 14. Controlling effect of A2 or pinoxaden alone and their combination on Alopecurus aequalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 45.5 3.5 58.8 47.4 11.4 150+7.5 20:1 45.5 14.1 67.3 53.2 14.1 75+15 5:1 23.8 43.0 71.9 56.6 15.3 75+30 5:2 23.8 72.4 92.1 79.0 13.1

Table 15. Controlling effect of A2 or clethodim alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 75.3 8.5 87.9 77.4 10.5 150+15 10:1 75.3 23.9 93.1 81.2 11.9 75+30 5:2 54.2 44.3 87.6 74.5 13.1 75+60 5:4 54.2 68.8 98.4 85.7 12.7

Table 16. Controlling effect of A2 or sethoxydim alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+15 10:1 75.3 6.5 88.1 76.9 11.2 150+30 5:1 75.3 22.3 93.4 80.8 12.6 75+60 5:4 54.2 42.4 87.9 73.6 14.3 75+120 5:8 54.2 62.4 97.2 82.8 14.4

Table 17. Controlling effect of A2 or quizalofop-P-methyl alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 75.3 8.5 89.3 77.4 11.9 150+7.5 20:1 75.3 12.6 91.7 78.4 13.3 75+15 5:1 54.2 40.4 88.2 72.7 15.5 75+30 5:2 54.2 71.0 99.4 86.7 12.7

Table 18. Controlling effect of A2 or fluazifop-p-butyl alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 75.3 2.0 88.6 75.8 12.8 150+7.5 20:1 75.3 18.2 92.8 79.8 13.0 75+15 5:1 54.2 37.3 87.1 71.3 15.8 75+30 5:2 54.2 73.1 98.1 87.7 10.4

Table 19. Controlling effect of A2 or haloxyfop-P-methyl alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 75.3 3.6 87.9 76.2 11.7 150+7.5 20:1 75.3 11.7 90.9 78.2 12.7 75+15 5:1 54.2 40.8 86.0 72.9 13.1 75+30 5:2 54.2 74.5 99.8 88.3 11.5

Table 20. Controlling effect of A2 or atrazine alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 75.3 4.5 89.4 76.4 13.0 150+150 1:1 75.3 15.4 90.2 79.1 11.1 75+300 1:4 54.2 26.9 78.8 66.5 12.3 75+600 1:8 54.2 65.5 94.7 84.2 10.5

Table 21. Controlling effect of A2 or isoproturon alone and their combination on Alopecurus aequalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 45.5 2.6 59.4 46.9 12.5 150+150 1:1 45.5 11.9 64.7 52.0 12.7 75+300 1:4 23.8 57.2 81.9 67.4 14.5 75+600 1:8 23.8 76.5 95.3 82.1 13.2

Table 22. Controlling effect of A2 or chlortoluron alone and their combination on Alopecurus aequalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 45.5 1.7 56.5 46.4 10.1 150+150 1:1 45.5 12.8 63.9 52.5 11.4 75+300 1:4 23.8 40.6 68.5 54.7 13.8 75+600 1:8 23.8 71.9 91.2 78.6 12.6

Table 23. Controlling effect of A2 or diuron alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 75.3 2.0 86.6 75.8 10.8 150+150 1:1 75.3 13.0 91.3 78.5 12.8 75+300 1:4 54.2 29.3 79.1 67.6 11.5 75+600 1:8 54.2 55.0 91.5 79.4 12.1

Table 24. Controlling effect of A2 or bentazone individually and their combination on Lindernia procumbens Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 15+18.75 4:5 78.9 4.3 91.2 79.8 11.4 15+37.5 2:5 78.9 10.0 93.2 81.0 12.2 7.5+75 1:10 42.3 45.4 82.3 68.5 13.8 7.5+150 1:20 42.3 76.1 98.7 86.2 12.5

Table 25. Controlling effect of A2 or bromoxynil individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+18.75 8:1 52.4 3.2 64.2 53.9 10.3 150+37.5 4:1 52.4 9.2 68.1 56.8 11.3 75+75 1:1 22.9 57.8 81.2 67.5 13.7 75+150 1:2 22.9 83.7 99.6 87.4 12.2

Table 26. Controlling effect of A2 or propanil individually and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 75.3 6.1 88.9 76.8 12.1 150+150 1:1 75.3 18.6 93.4 79.9 13.5 75+300 1:4 54.2 35.2 82.1 70.3 11.8 75+600 1:8 54.2 52.6 90.2 78.3 11.9

Table 27. Controlling effect of A2 or cipirafluon alone and their combination on Alopecurus aequalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+18.75 8:1 45.5 4.6 60.2 48.0 12.2 150+37.5 4:1 45.5 10.1 64.7 51.0 13.7 75+75 1:1 23.8 55.9 79.3 66.4 12.9 75+150 1:2 23.8 81.8 97.6 86.1 11.5

Table 28. Controlling effect of A2 or bipyrazone individually and their combination on Descurainia sophia Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 30+1.875 16:1 74.2 4.3 86.5 75.3 11.2 30+3.75 8:1 74.2 19.0 92.7 79.1 13.6 15+7.5 2:1 35.7 48.7 80.2 67.0 13.2 15+15 1:1 35.7 82.9 99.3 89.0 10.3

Table 29. Controlling effect of A2 or phenpyrazone individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 48.9 5.3 62.4 51.6 10.8 150+15 10:1 48.9 14.7 72.3 56.4 15.9 75+30 5:2 22.4 40.2 67.2 53.6 13.6 75+60 5:4 22.4 79.6 95.4 84.2 11.2

Table 30. Controlling effect of A2 or tripirasulfone alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+18.75 8:1 75.3 6.9 88.2 77.0 11.2 150+37.5 4:1 75.3 16.2 94.5 79.3 15.2 75+75 1:1 54.2 42.8 87.9 73.8 14.1 75+150 1:2 54.2 74.5 98.9 88.3 10.6

Table 31. Controlling effect of A2 or tefuryltrione alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 75.3 6.9 89.2 77.0 12.2 150+15 10:1 75.3 17.0 91.6 79.5 12.1 75+30 5:2 54.2 44.3 86.8 74.5 12.3 75+60 5:4 54.2 68.3 97.6 85.5 12.1

Table 32. Controlling effect of A2 or mesotrione individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+15 10:1 48.9 6.3 62.6 52.1 10.5 150+30 5:1 48.9 13.3 69.2 55.7 13.5 75+60 5:4 22.4 38.5 64.7 52.3 12.4 75+120 5:8 22.4 75.6 93.2 81.1 12.1

Table 33. Controlling effect of A2 or tembotrione individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 48.9 3.7 61.5 50.8 10.7 150+7.5 20:1 48.9 12.1 69.9 55.1 14.8 75+15 5:1 22.4 41.2 68.6 54.4 14.2 75+30 5:2 22.4 73.8 91.2 79.7 11.5

Table 34. Controlling effect of A2 or topramesone individually and their combination on Setaria viridis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 60+1.875 32:1 56.3 2.3 69.5 57.3 12.2 60+3.75 16:1 56.3 11.0 74.7 61.1 13.6 30+7.5 4:1 32.7 37.0 72.1 57.6 14.5 30+15 2:1 32.7 76.1 95.3 83.9 11.4

Table 35. Controlling effect of A2 or isoxaflutole alone and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 75.3 6.1 89.6 76.8 12.8 150+15 10:1 75.3 17.8 94.5 79.7 14.8 75+30 5:2 54.2 49.0 89.2 76.7 12.5 75+60 5:4 54.2 64.4 94.5 83.7 10.8

Table 36. Controlling effect of A2 or benzobicilone individually and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+37.5 4:1 75.3 7.3 90.2 77.1 13.1 150+75 2:1 75.3 16.2 91.8 79.3 12.5 75+150 1:2 54.2 44.9 86.5 74.8 11.7 75+300 1:4 54.2 55.9 91.3 79.8 11.5

Table 37. Controlling effect of A2 or diflufenican individually and their combination on Veronica persica ¹ Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+15 10:1 38.4 2.1 51.2 39.7 11.5 150+30 5:1 38.4 14.4 61.8 47.3 14.5 75+60 5:4 18.2 41.3 65.8 52.0 13.8 75+120 5:8 18.2 76.7 93.3 80.9 12.4

Table 38. Controlling effect of A2 or fluorochloridone individually and their combination on Veronica persica ¹ Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 38.4 4.9 53.7 41.4 12.3 150+150 1:1 38.4 13.1 59.9 46.5 13.4 75+300 1:4 18.2 45.5 71.2 55.4 15.8 75+600 1:8 18.2 80.0 97.2 83.6 13.6

Table 39. Controlling effect of A2 or clomazone individually and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+45 10:3 75.3 5.7 89.4 76.7 12.7 150+90 5:3 75.3 10.1 90.2 77.8 12.4 75+180 5:12 54.2 48.8 88.9 76.6 12.3 75+360 5:24 54.2 70.7 99.7 86.6 13.1

Table 40. Controlling effect of A2 or carfentrazone-ethyl individually and their combination on Veronica persica ¹ Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 38.4 2.4 51.8 39.9 11.9 150+3.75 40:1 38.4 11.5 58.3 45.5 12.8 75+7.5 10:1 18.2 37.3 62.4 48.7 13.7 75+15 5:1 18.2 68.7 87.1 74.4 12.7

Table 41. Controlling effect of A2 or fomesafen individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+22.5 20:3 52.4 5.0 64.9 54.8 10.1 150+45 10:3 52.4 11.3 71.2 57.8 13.4 75+90 5:6 22.9 45.5 72.6 58.0 14.6 75+180 5:12 22.9 82.0 98.5 86.1 12.4

Table 42. Controlling effect of A2 or fluoroglycophene individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+0.9375 160:1 52.4 2.5 65.4 53.6 11.8 150+1.875 80:1 52.4 14.5 71.3 59.3 12.0 75+3.75 20:1 22.9 40.1 67.6 53.8 13.8 75+7.5 10:1 22.9 70.7 89.9 77.4 12.5

Table 43. Controlling effect of A2 or oxyfluorfen individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 52.4 3.2 64.1 53.9 10.2 150+15 10:1 52.4 11.1 68.4 57.7 10.7 75+30 5:2 22.9 30.9 59.8 46.7 13.1 75+60 5:4 22.9 68.1 87.3 75.4 11.9

Table 44. Controlling effect of A2 or lactofen individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 52.4 1.3 63.5 53.0 10.5 150+15 10:1 52.4 12.2 71.2 58.2 13.0 75+30 5:2 22.9 39.8 65.8 53.6 12.2 75+60 5:4 22.9 65.5 84.2 73.4 10.8

Table 45. Controlling effect of A2 or acifluorfen sodium individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+37.5 4:1 52.4 4.4 65.7 54.5 11.2 150+75 2:1 52.4 10.3 67.6 57.3 10.3 75+150 1:2 22.9 45.1 70.8 57.7 13.1 75+300 1:4 22.9 85.0 98.7 88.4 10.3

Table 46. Controlling effect of A2 or flumioxazin individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 52.4 5.5 67.5 55.0 12.5 150+15 10:1 52.4 12.4 71.3 58.3 13.0 75+30 5:2 22.9 37.4 63.9 51.7 12.2 75+60 5:4 22.9 78.9 94.5 83.7 10.8

Table 47. Controlling effect of A2 or sulfentrazone individually and their combination on Echinochloa crusgalli var. zelayensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 75.3 2.8 87.1 76.0 11.1 150+3.75 40:1 75.3 15.4 92.4 79.1 13.3 75+7.5 10:1 54.2 26.9 78.8 66.5 12.3 75+15 5:1 54.2 54.1 90.2 79.0 11.2

Table 48. Controlling effect of A2 or saflufenacil alone and their combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 57.2 3.0 70.8 58.5 12.3 150+7.5 20:1 57.2 11.9 75.5 62.3 13.2 75+15 5:1 36.7 39.2 75.7 61.5 14.2 75+30 5:2 36.7 76.5 98.3 85.1 13.2

Table 49. Controlling effect of A2 or oxadiazone individually and their combination on Echinochloa crusgalli var. zelayensis (cultivation of silted soil) Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+37.5 4:1 45.2 4.2 59.1 47.5 11.6 150+75 2:1 45.2 25.4 71.2 59.1 12.1 75+150 1:2 21.4 41.5 66.3 54.0 12.3 75+300 1:4 21.4 64.2 85.2 71.9 13.3

Table 50. Controlling effect of A2 or oxadiargyl alone and their combination on Echinochloa crusgalli var. zelayensis (cultivation of silted soil) Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 45.2 1.6 56.5 46.1 10.4 150+15 10:1 45.2 10.4 61.2 50.9 10.3 75+30 5:2 21.4 38.8 64.2 51.9 12.3 75+60 5:4 21.4 63.5 82.7 71.3 11.4

Table 51. Controlling effect of A1 or penoxsulam individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 76.3 3.8 87.4 77.2 10.2 150+3.75 40:1 76.3 15.6 92.2 80.0 12.2 75+7.5 10:1 55.2 46.5 88.9 76.1 12.8 75+15 5:1 55.2 69.4 99.7 86.3 13.4

Table 52. Controlling effect of A1 or bispiribac sodium individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 76.3 5.5 88.9 77.6 11.3 150+3.75 40:1 76.3 16.0 92.8 80.1 12.7 75+7.5 10:1 55.2 44.9 87.2 75.3 11.9 75+15 5:1 55.2 62.1 95.6 83.0 12.6

Table 53. Controlling effect of A1 or pyrazosulfuron-ethyl individually and their combination on Ludwigia prostrate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 72.4 7.6 86.8 74.5 12.3 150+3.75 40:1 72.4 13.0 89.1 76.0 13.1 75+7.5 10:1 34.3 52.2 81.2 68.6 12.6 75+15 5:1 34.3 75.3 95.9 83.8 12.1

Table 54. Controlling effect of A1 or nicosulfuron alone and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 76.3 3.8 88.4 77.2 11.2 150+7.5 20:1 76.3 14.3 91.6 79.7 11.9 75+15 5:1 55.2 40.2 87.5 73.2 14.3 75+30 5:2 55.2 58.5 94.3 81.4 12.9

Table 55. Controlling effect of A1 or florasulam individually and their combination on Malachium aquaticum Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 15+0.375 40:1 69.6 3.6 80.9 70.7 10.2 15+0.75 20:1 69.6 17.4 86.2 74.9 11.3 7.5+1.5 5:1 35.8 56.4 85.9 72.0 13.9 7.5+3.0 5:2 35.8 77.6 98.2 85.6 12.6

Table 56. Controlling effect of A1 or rimsulfuron individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 76.3 5.5 87.8 77.6 10.2 150+3.75 40:1 76.3 25.3 94.6 82.3 12.3 75+7.5 10:1 55.2 37.9 87.8 72.2 15.6 75+15 5:1 55.2 65.8 97.6 84.7 12.9

Table 57. Controlling effect of A1 or imazethapyr alone and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 76.3 4.2 87.8 77.3 10.5 150+15 10:1 76.3 18.1 94.3 80.6 13.7 75+30 5:2 55.2 34.8 85.6 70.8 14.8 75+60 5:4 55.2 55.6 93.7 80.1 13.6

Table 58. Controlling effect of A1 or imazapic alone and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+9.375 16:1 76.3 6.8 89.9 77.9 12.0 150+18.75 8:1 76.3 21.5 92.8 81.4 11.4 75+37.5 2:1 55.2 28.6 81.2 68.0 13.2 75+75 1:1 55.2 55.6 93.4 80.1 13.3

Table 59. Controlling effect of A1 or imazamox alone and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 76.3 7.6 90.2 78.1 12.1 150+7.5 20:1 76.3 16.5 93.4 80.2 13.2 75+15 5:1 55.2 24.8 81.8 66.3 15.5 75+30 5:2 55.2 53.8 92.1 79.3 12.8

Table 60. Controlling effect of A1 or sulfometuron-methyl individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+9.375 16:1 76.3 3.8 87.3 77.2 10.1 150+18.75 8:1 76.3 13.9 95.5 79.6 15.9 75+37.5 2:1 55.2 24.6 79.6 66.2 13.4 75+75 1:1 55.2 52.7 91.6 78.8 12.8

Table 61. Controlling effect of A1 or cloransulam-methyl individually and their combination on Sonchus arvensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 60+1.875 32:1 70.7 6.5 84.1 72.6 11.5 60+3.75 16:1 70.7 15.0 89.6 75.1 14.5 30+7.5 4:1 33.3 52.8 82.2 68.5 13.7 30+15 2:1 33.3 72.9 93.8 81.9 11.9

Table 62. Controlling effect of A1 or cyhalofop-butyl individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+9.375 16:1 76.3 5.9 87.9 77.7 10.2 150+18.75 8:1 76.3 11.4 89.6 79.0 10.6 75+37.5 2:1 55.2 29.9 81.4 68.6 12.8 75+75 1:1 55.2 69.6 97.6 86.4 11.2

Table 63. Controlling effect of A1 or clodinafope-propargyl individually and their combination on Alopecurus japonicus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 48.1 3.0 61.4 49.7 11.8 150+7.5 20:1 48.1 10.6 69.0 53.6 15.4 75+15 5:1 25.6 57.8 83.8 68.6 15.2 75+30 5:2 25.6 79.9 98.8 85.1 13.8

Table 64. Controlling effect of A1 or pinoxaden alone and their combination on Alopecurus japonicus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 48.1 2.5 61.3 49.4 11.9 150+7.5 20:1 48.1 12.1 68.6 54.4 14.2 75+15 5:1 25.6 41.7 72.7 56.6 16.1 75+30 5:2 25.6 71.8 92.5 79.0 13.5

Table 65. Controlling effect of A1 or clethodim individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 76.3 3.4 87.3 77.1 10.2 150+15 10:1 76.3 27.0 93.6 82.7 10.9 75+30 5:2 55.2 43.8 87.4 74.8 12.6 75+60 5:4 55.2 67.4 98.1 85.4 12.7

Table 66. Controlling effect of A1 or sethoxydim individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+15 10:1 76.3 5.1 88.6 77.5 11.1 150+30 5:1 76.3 21.5 93.8 81.4 12.4 75+60 5:4 55.2 42.6 88.2 74.3 13.9 75+120 5:8 55.2 61.6 97.2 82.8 14.4

Table 67. Controlling effect of A1 or quizalofop-P-methyl alone and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 76.3 3.4 88.7 77.1 11.6 150+7.5 20:1 76.3 12.2 93.2 79.2 14.0 75+15 5:1 55.2 40.8 89.2 73.5 15.7 75+30 5:2 55.2 72.1 99.6 87.5 12.1

Table 68. Controlling effect of A1 or fluazifop-p-butyl alone and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 76.3 4.2 88.9 77.3 11.6 150+7.5 20:1 76.3 13.9 92.3 79.6 12.7 75+15 5:1 55.2 38.4 87.2 72.4 14.8 75+30 5:2 55.2 74.1 98.6 88.4 10.2 Table 69. Controlling effect of A1 or haloxyfop-P-methyl alone and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 76.3 3.0 87.2 77.0 10.2 150+7.5 20:1 76.3 15.6 92.1 80.0 12.1 75+15 5:1 55.2 40.2 86.2 73.2 13.0 75+30 5:2 55.2 73.4 98.8 88.1 10.7

Table 70. Controlling effect of A1 or atrazine alone and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 76.3 3.8 89.5 77.2 12.3 150+150 1:1 76.3 13.5 90.4 79.5 10.9 75+300 1:4 55.2 24.8 78.6 66.3 12.3 75+600 1:8 55.2 66.5 95.7 85.0 10.7

Table 71. Controlling effect of A1 or isoproturon individually and their combination on Alopecurus japonicus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 48.1 2.5 62.3 49.4 12.9 150+150 1:1 48.1 11.4 67.2 54.0 13.2 75+300 1:4 25.6 56.5 82.2 67.6 14.6 75+600 1:8 25.6 75.9 96.1 82.1 14.0

Table 72. Controlling effect of A1 or chlortoluron individually and their combination on Alopecurus japonicus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 48.1 2.9 60.5 49.6 10.9 150+150 1:1 48.1 13.1 66.7 54.9 11.8 75+300 1:4 25.6 39.8 69.6 55.2 14.3 75+600 1:8 25.6 71.9 91.9 79.1 12.7

Table 73. Controlling effect of A1 or diuron individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 76.3 3.0 87.9 77.0 10.9 150+150 1:1 76.3 16.5 93.3 80.2 13.1 75+300 1:4 55.2 28.6 79.2 68.0 11.2 75+600 1:8 55.2 52.2 90.9 78.6 12.3

Table 74. Controlling effect of A1 or bentazone individually and their combination on Abutilon theophrasti Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 15+18.75 4:5 79.6 5.9 91.7 80.8 10.9 15+37.5 2:5 79.6 11.8 94.1 82.0 12.1 7.5+75 1:10 44.3 49.0 85.2 71.6 13.6 7.5+150 1:20 44.3 69.1 94.7 82.8 11.9

Table 75. Controlling effect of A1 or bromoxynil alone and their combination on Chenopodium album Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+18.75 8:1 55.6 3.1 67.5 57.0 10.5 150+37.5 4:1 55.6 10.8 72.1 60.4 11.7 75+75 1:1 23.1 57.7 81.5 67.5 14.0 75+150 1:2 23.1 83.6 99.7 87.4 12.3

Table 76. Controlling effect of A1 or propanil individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 76.3 3.8 88.8 77.2 11.6 150+150 1:1 76.3 21.1 94.4 81.3 13.1 75+300 1:4 55.2 36.4 82.3 71.5 10.8 75+600 1:8 55.2 52.5 90.4 78.7 11.7

Table 77. Controlling effect of A1 or cipirafluon individually and their combination on Alopecurus japonicus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+18.75 8:1 48.1 4.0 62.5 50.2 12.3 150+37.5 4:1 48.1 24.9 75.5 61.0 14.5 75+75 1:1 25.6 54.8 79.7 66.4 13.3 75+150 1:2 25.6 81.3 98.1 86.1 12.0

Table 78. Controlling effect of A1 or bipyrazone individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 30+1.875 16:1 75.9 2.9 88.1 76.6 11.5 30+3.75 8:1 75.9 12.9 93.2 79.0 14.2 15+7.5 2:1 36.2 51.1 82.4 68.8 13.6 15+15 1:1 36.2 80.3 98.1 87.4 10.7

Table 79. Controlling effect of A1 or phenpyrazone individually and their combination on Eleusine indica Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 52.2 2.9 64.6 53.6 11.0 150+15 10:1 52.2 10.9 73.6 57.4 16.2 75+30 5:2 24.4 38.6 67.5 53.6 13.9 75+60 5:4 24.4 79.1 95.6 84.2 11.4

Table 80. Controlling effect of A1 or tripirasulfone individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+18.75 8:1 76.3 4.6 88.4 77.4 11.0 150+37.5 4:1 76.3 16.0 94.7 80.1 14.6 75+75 1:1 55.2 42.6 88.2 74.3 13.9 75+150 1:2 55.2 74.3 98.6 88.5 10.1

Table 81. Controlling effect of A1 or tefuryltrione individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 76.3 6.8 89.7 77.9 11.8 150+15 10:1 76.3 13.1 91.4 79.4 12.0 75+30 5:2 55.2 41.3 86.8 73.7 13.1 75+60 5:4 55.2 65.4 96.6 84.5 12.1

Table 82. Controlling effect of A1 or mesotrione individually and their combination on Eleusine indica Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+15 10:1 52.2 4.0 64.8 54.1 10.7 150+30 5:1 52.2 10.9 71.1 57.4 13.7 75+60 5:4 24.4 36.9 65.0 52.3 12.7 75+120 5:8 24.4 75.0 93.5 81.1 12.4

Table 83. Controlling effect of A1 or tembotrione individually and their combination on Eleusine indica Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 52.2 5.4 65.8 54.8 11.0 150+7.5 20:1 52.2 12.3 73.1 58.1 15.0 75+15 5:1 24.4 39.7 68.8 54.4 14.4 75+30 5:2 24.4 73.1 91.5 79.7 11.8

Table 84. Controlling effect of A1 or topramesone individually and their combination on Setaria glauca Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 60+1.875 32:1 57.6 7.3 72.5 60.7 11.8 60+3.75 16:1 57.6 10.6 76.3 62.1 14.2 30+7.5 4:1 34.7 35.8 71.1 58.1 13.0 30+15 2:1 34.7 72.3 94.3 81.9 12.4

Table 85. Controlling effect of A1 or isoxaflutole individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 76.3 2.1 89.8 76.8 13.0 150+15 10:1 76.3 14.3 94.7 79.7 15.0 75+30 5:2 55.2 47.9 89.4 76.7 12.7 75+60 5:4 55.2 63.6 94.7 83.7 11.0

Table 86. Controlling effect of A1 or benzobicilone individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+37.5 4:1 76.3 2.1 90.5 76.8 13.7 150+75 2:1 76.3 11.7 92.0 79.1 12.9 75+150 1:2 55.2 43.3 86.6 74.6 12.0 75+300 1:4 55.2 54.4 91.5 79.6 12.0

Table 87. Controlling effect of A1 or diflufenican individually and their combination on Veronica persica ² Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+15 10:1 42.4 2.3 55.7 43.7 12.0 150+30 5:1 42.4 10.2 63.3 48.3 15.0 75+60 5:4 19.6 40.3 66.3 52.0 14.3 75+120 5:8 19.6 76.2 93.8 80.9 12.9

Table 88. Controlling effect of A1 or fluorochloridone individually and their combination on Veronica persica ² Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 42.4 2.1 56.4 43.6 12.8 150+150 1:1 42.4 12.3 63.4 49.5 13.9 75+300 1:4 19.6 44.5 71.7 55.4 16.3 75+600 1:8 19.6 79.6 97.7 83.6 14.1

Table 89. Controlling effect of A1 or clomazone individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+45 10:3 76.3 8.6 89.6 78.3 11.3 150+90 5:3 76.3 19.0 93.5 80.8 12.7 75+180 5:12 55.2 47.7 89.1 76.6 12.5 75+360 5:24 55.2 70.1 99.8 86.6 13.2

Table 90. Controlling effect of A1 or carfentrazone-ethyl individually and their combination on Veronica persica ² Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 42.4 2.6 56.3 43.9 12.4 150+3.75 40:1 42.4 11.6 62.4 49.1 13.3 75+7.5 10:1 19.6 36.2 62.9 48.7 14.2 75+15 5:1 19.6 68.2 87.6 74.4 13.2

Table 91. Controlling effect of A1 or fomesafen individually and their combination on Chenopodium album Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+22.5 20:3 55.6 2.7 67.0 56.8 10.2 150+45 10:3 55.6 18.6 77.5 63.9 13.6 75+90 5:6 23.1 45.4 73.0 58.0 15.0 75+180 5:12 23.1 81.9 98.8 86.1 12.7

Table 92. Controlling effect of A1 or fluoroglycophene individually and their combination on Chenopodium album Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+0.9375 160:1 55.6 2.3 68.7 56.6 12.1 150+1.875 80:1 55.6 12.8 73.4 61.3 12.1 75+3.75 20:1 23.1 40.0 67.9 53.9 14.0 75+7.5 10:1 23.1 70.6 90.3 77.4 12.9

Table 93. Controlling effect of A1 or oxyfluorfen individually and their combination on Chenopodium album Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 55.6 3.6 67.8 57.2 10.6 150+15 10:1 55.6 11.9 71.9 60.9 11.0 75+30 5:2 23.1 30.7 59.9 46.7 13.2 75+60 5:4 23.1 68.1 87.6 75.5 12.1

Table 94. Controlling effect of A1 or lactofen individually and their combination on Chenopodium album Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 55.6 3.3 67.8 57.1 10.7 150+15 10:1 55.6 10.4 73.6 60.2 13.4 75+30 5:2 23.1 39.7 66.1 53.6 12.5 75+60 5:4 23.1 65.4 84.3 73.4 10.9

Table 95. Controlling effect of A1 or acifluorfen sodium individually and their combination on Chenopodium album Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+37.5 4:1 55.6 2.0 67.8 56.5 11.3 150+75 2:1 55.6 13.7 72.2 61.7 10.5 75+150 1:2 23.1 45.0 71.2 57.7 13.5 75+300 1:4 23.1 81.0 96.0 85.4 10.6

Table 96. Controlling effect of A1 or flumioxazin individually and their combination on Chenopodium album Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 55.6 3.4 69.9 57.1 12.8 150+15 10:1 55.6 12.8 74.4 61.3 13.1 75+30 5:2 23.1 37.3 64.2 51.8 12.4 75+60 5:4 23.1 78.8 94.9 83.7 11.2

Table 97. Controlling effect of A1 or sulfentrazone individually and their combination on Echinochloa caudate Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 76.3 6.6 89.2 77.9 11.4 150+3.75 40:1 76.3 10.8 92.6 78.9 13.8 75+7.5 10:1 55.2 24.5 79.1 66.2 12.9 75+15 5:1 55.2 52.6 90.4 78.8 11.6

Table 98. Controlling effect of A1 or saflufenacil individually and their combination on Ipomoea purpurea Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 59.5 7.9 74.0 62.7 11.3 150+7.5 20:1 59.5 16.0 78.1 66.0 12.1 75+15 5:1 37.7 41.3 76.9 63.4 13.5 75+30 5:2 37.7 75.9 97.8 85.0 12.8

Table 99. Control effect of A1 or oxadiazone alone and their combination on Echinochloa caudate (silted soil treatment) Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+37.5 4:1 47.2 6.0 62.2 50.4 11.9 150+75 2:1 47.2 22.1 71.4 58.9 12.6 75+150 1:2 23.4 39.5 66.6 53.7 12.9 75+300 1:4 23.4 63.0 85.4 71.7 13.7

Table 100. Controlling effect of A1 or oxadiargyl individually and their combination on Echinochloa caudate (silted soil treatment) Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 47.2 1.7 58.7 48.1 10.6 150+15 10:1 47.2 10.8 63.3 52.9 10.4 75+30 5:2 23.4 37.2 64.4 51.9 12.5 75+60 5:4 23.4 62.5 83.0 71.3 11.7

Table 101. Controlling effect of A4 or penoxsulam individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 74.7 4.7 86.6 75.9 10.7 150+3.75 40:1 74.7 13.8 90.2 78.2 12.0 75+7.5 10:1 52.6 47.9 87.8 75.3 12.5 75+15 5:1 52.6 68.4 98.7 85.0 13.7

Table 102. Controlling effect of A4 or bispiribac sodium individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 74.7 4.7 87.4 75.9 11.5 150+3.75 40:1 74.7 18.2 91.3 79.3 12.0 75+7.5 10:1 52.6 44.1 85.2 73.5 11.7 75+15 5:1 52.6 62.0 94.3 82.0 12.3

Table 103. Controlling effect of A3 or pyrazosulfuron-ethyl individually and their combination on Ammannia arenaria Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 66.2 16.3 82.7 71.7 11.0 150+3.75 40:1 66.2 26.1 86.4 75.0 11.4 75+7.5 10:1 30.4 52.8 79.6 67.1 12.5 75+15 5:1 30.4 77.2 95.4 84.1 11.3

Table 104. Controlling effect of A4 or nicosulfuron individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 74.7 9.9 88.4 77.2 11.2 150+7.5 20:1 74.7 18.2 91.8 79.3 12.5 75+15 5:1 52.6 40.5 86.2 71.8 14.4 75+30 5:2 52.6 62.4 94.3 82.2 12.1

Table 105. Controlling effect of A3 or florasulam individually and their combination on Stellaria media Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 15+0.375 40:1 67.9 6.8 82.3 70.1 12.3 15+0.75 20:1 67.9 22.3 87.9 75.1 12.9 7.5+1.5 5:1 34.1 56.9 86.1 71.6 14.6 7.5+3.0 5:2 34.1 76.6 97.9 84.6 13.4

Table 106. Controlling effect of A4 or rimsulfuron individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 74.7 10.3 88.3 77.3 11.0 150+3.75 40:1 74.7 26.9 93.7 81.5 12.2 75+7.5 10:1 52.6 43.7 88.0 73.3 14.7 75+15 5:1 52.6 69.6 98.1 85.6 12.5

Table 107. Controlling effect of A4 or imazethapyr alone and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 74.7 6.7 86.8 76.4 10.4 150+15 10:1 74.7 17.8 92.7 79.2 13.5 75+30 5:2 52.6 34.6 83.1 69.0 14.1 75+60 5:4 52.6 58.2 93.0 80.2 12.8

Table 108. Controlling effect of A4 or imazapic alone and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+9.375 16:1 74.7 4.0 87.0 75.7 11.3 150+18.75 8:1 74.7 21.3 92.1 80.1 12.0 75+37.5 2:1 52.6 30.4 82.4 67.0 15.4 75+75 1:1 52.6 59.7 93.4 80.9 12.5

Table 109. Controlling effect of A4 or imazamox alone and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 74.7 4.0 88.4 75.7 12.7 150+7.5 20:1 74.7 12.6 90.4 77.9 12.5 75+15 5:1 52.6 27.6 80.1 65.7 14.4 75+30 5:2 52.6 54.4 91.2 78.4 12.8

Table 110. Controlling effect of A4 or sulfometuron-methyl individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+9.375 16:1 74.7 3.2 85.9 75.5 10.4 150+18.75 8:1 74.7 12.6 92.7 77.9 14.8 75+37.5 2:1 52.6 38.0 84.1 70.6 13.5 75+75 1:1 52.6 53.8 90.8 78.1 12.7

Table 111. Controlling effect of A3 or cloransulam-methyl individually and their combination on Cirsium setosum Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 60+1.875 32:1 64.3 13.6 80.8 69.1 11.6 60+3.75 16:1 64.3 23.1 86.5 72.5 13.9 30+7.5 4:1 31.5 53.8 81.9 68.3 13.5 30+15 2:1 31.5 71.9 93.0 80.7 12.2

Table 112. Controlling effect of A4 or cyhalofop-butyl individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+9.375 16:1 74.7 5.5 87.5 76.1 11.4 150+18.75 8:1 74.7 15.0 89.7 78.5 11.2 75+37.5 2:1 52.6 32.1 81.5 67.8 13.7 75+75 1:1 52.6 63.5 97.9 82.7 15.2

Table 113. Controlling effect of A3 or clodinafop-propargyl individually and their combination on Beckmannia syzigachne Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 42.8 10.3 60.7 48.7 12.0 150+7.5 20:1 42.8 20.1 67.8 54.3 13.5 75+15 5:1 23.0 59.6 83.0 68.9 14.1 75+30 5:2 23.0 81.2 97.9 85.5 12.4

Table 114. Controlling effect of A3 or pinoxaden alone and their combination on Beckmannia syzigachne Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 42.8 7.9 58.4 47.3 11.1 150+7.5 20:1 42.8 18.0 66.9 53.1 13.8 75+15 5:1 23.0 43.5 71.5 56.5 15.0 75+30 5:2 23.0 72.6 91.7 78.9 12.8

Table 115. Controlling effect of A4 or clethodim individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 74.7 6.7 88.0 76.4 11.6 150+15 10:1 74.7 19.0 92.4 79.5 12.9 75+30 5:2 52.6 37.8 85.6 70.5 15.1 75+60 5:4 52.6 62.7 96.0 82.3 13.7

Table 116. Controlling effect of A4 or sethoxydim individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+15 10:1 74.7 5.5 87.8 76.1 11.7 150+30 5:1 74.7 13.8 93.0 78.2 14.8 75+60 5:4 52.6 35.4 87.7 69.4 18.3 75+120 5:8 52.6 68.4 97.4 85.0 12.4

Table 117. Controlling effect of A4 or quizalofop-p-methyl individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 74.7 5.9 86.3 76.2 10.1 150+7.5 20:1 74.7 14.6 88.7 78.4 10.3 75+15 5:1 52.6 38.6 86.2 70.9 15.3 75+30 5:2 52.6 63.3 95.4 82.6 12.8

Table 118. Controlling effect of A4 or fluazifop-p-butyl alone and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 74.7 5.5 87.6 76.1 11.5 150+7.5 20:1 74.7 14.2 90.3 78.3 12.0 75+15 5:1 52.6 32.9 85.0 68.2 16.8 75+30 5:2 52.6 71.5 97.1 86.5 10.6

Table 119. Controlling effect of A4 or haloxyfop-P-methyl individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 74.7 7.9 88.0 76.7 11.3 150+7.5 20:1 74.7 19.0 92.0 79.5 12.5 75+15 5:1 52.6 30.4 86.1 67.0 19.1 75+30 5:2 52.6 66.9 97.8 84.3 13.5

Table 120. Controlling effect of A4 or atrazine alone and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 74.7 6.7 87.4 76.4 11.0 150+150 1:1 74.7 21.7 91.3 80.2 11.1 75+300 1:4 52.6 26.4 75.4 65.1 10.3 75+600 1:8 52.6 61.8 92.7 81.9 10.8

Table 121. Controlling effect of A3 or isoproturon individually and their combination on Beckmannia syzigachne Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 42.8 7.0 59.0 46.8 12.2 150+150 1:1 42.8 15.9 64.3 51.9 12.4 75+300 1:4 23.0 57.6 81.5 67.3 14.2 75+600 1:8 23.0 76.6 94.9 82.0 12.9

Table 122. Controlling effect of A3 or chlortoluron individually and their combination on Beckmannia syzigachne Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 42.8 5.5 56.1 45.9 10.2 150+150 1:1 42.8 16.8 63.5 52.4 11.1 75+300 1:4 23.0 41.1 68.1 54.6 13.5 75+600 1:8 23.0 72.1 90.8 78.5 12.3

Table 123. Controlling effect of A4 or diuron individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 74.7 4.1 86.3 75.7 10.6 150+150 1:1 74.7 14.0 90.8 78.2 12.6 75+300 1:4 52.6 31.3 78.7 67.4 11.3 75+600 1:8 52.6 56.2 91.1 79.2 11.9

Table 124. Controlling effect of A3 or bentazone individually and their combination on Xanthium strumarium Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 15+18.75 4:5 77.2 10.9 91.4 79.7 11.7 15+37.5 2:5 77.2 16.1 93.4 80.9 12.5 7.5+75 1:10 40.8 46.6 82.5 68.4 14.1 7.5+150 1:20 40.8 76.5 98.9 86.1 12.8

Table 125. Controlling effect of A3 or bromoxynil individually and their combination on Acalypha australis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+18.75 8:1 51.6 4.6 64.5 53.8 10.6 150+37.5 4:1 51.6 10.6 68.4 56.7 11.6 75+75 1:1 20.7 58.9 81.5 67.4 14.0 75+150 1:2 20.7 84.0 99.9 87.3 12.5

Table 126. Controlling effect of A4 or propanil individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 74.7 7.6 88.5 76.6 11.9 150+150 1:1 74.7 19.9 93.0 79.7 13.3 75+300 1:4 52.6 37.0 81.7 70.1 11.6 75+600 1:8 52.6 53.9 89.8 78.1 11.7

Table 127. Controlling effect of A3 or cipirafluon individually and their combination on Beckmannia syzigachne Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+18.75 8:1 42.8 9.0 59.8 47.9 11.9 150+37.5 4:1 42.8 14.2 64.3 50.9 13.4 75+75 1:1 23.0 56.3 78.9 66.3 12.6 75+150 1:2 23.0 81.8 97.2 86.0 11.2

Table 128. Controlling effect of A3 or bipyrazone individually and their combination on Sinapis arvensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 30+1.875 16:1 72.7 9.9 87.0 75.4 11.6 30+3.75 8:1 72.7 23.8 93.2 79.2 14.0 15+7.5 2:1 33.2 50.8 80.7 67.1 13.6 15+15 1:1 33.2 83.7 99.8 89.1 10.7

Table 129. Controlling effect of A3 or phenpyrazone individually and their combination on Chloris virgata Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 48.3 5.5 62.2 51.2 11.0 150+15 10:1 48.3 14.8 72.1 56.0 16.1 75+30 5:2 22.0 39.9 67.0 53.2 13.8 75+60 5:4 22.0 79.2 95.2 83.8 11.4

Table 130. Control effect of A4 or tripirasulfone individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+18.75 8:1 74.7 8.9 87.9 77.0 11.0 150+37.5 4:1 74.7 18.0 94.2 79.3 15.0 75+75 1:1 52.6 44.6 87.6 73.8 13.9 75+150 1:2 52.6 75.2 98.6 88.3 10.4

Table 131. Controlling effect of A4 or tefuryltrione individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 74.7 8.9 88.9 77.0 12.0 150+15 10:1 74.7 18.8 91.3 79.5 11.9 75+30 5:2 52.6 46.1 86.5 74.5 12.1 75+60 5:4 52.6 69.3 97.3 85.5 11.9

Table 132. Controlling effect of A3 or mesotrione individually and their combination on Chloris virgata Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+15 10:1 48.3 6.5 62.4 51.7 10.7 150+30 5:1 48.3 13.4 69.0 55.3 13.7 75+60 5:4 22.0 38.3 64.5 51.9 12.6 75+120 5:8 22.0 75.2 93.0 80.7 12.3

Table 133. Controlling effect of A3 or tembotrione individually and their combination on Chloris virgata Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 48.3 4.0 61.3 50.4 10.9 150+7.5 20:1 48.3 12.3 69.7 54.7 15.0 75+15 5:1 22.0 41.0 68.4 54.0 14.4 75+30 5:2 22.0 73.4 91.0 79.3 11.7

Table 134. Controlling effect of A3 or topramesone individually and their combination on Setaria faberi Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 60+1.875 32:1 55.4 3.2 69.2 56.8 12.4 60+3.75 16:1 55.4 11.7 74.4 60.6 13.8 30+7.5 4:1 32.5 36.5 71.8 57.1 14.7 30+15 2:1 32.5 75.4 95.0 83.4 11.6

Table 135. Controlling effect of A4 or isoxaflutole individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 74.7 8.1 89.3 76.8 12.6 150+15 10:1 74.7 19.6 94.2 79.7 14.6 75+30 5:2 52.6 50.6 88.9 76.6 12.3 75+60 5:4 52.6 65.5 94.2 83.7 10.6

Table 136. Controlling effect of A4 or benzobicilone individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+37.5 4:1 74.7 9.3 89.9 77.1 12.9 150+75 2:1 74.7 18.0 91.5 79.3 12.3 75+150 1:2 52.6 46.6 86.2 74.7 11.5 75+300 1:4 52.6 57.3 91.0 79.8 11.3

Table 137. Controlling effect of A3 or diflufenican individually and their combination on Solanum nigrum Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+15 10:1 37.5 6.0 52.9 41.3 11.6 150+30 5:1 37.5 15.0 61.5 46.9 14.6 75+60 5:4 16.9 41.7 65.5 51.6 13.9 75+120 5:8 16.9 76.5 93.0 80.5 12.5

Table 138. Controlling effect of A3 or fluorochloridone individually and their combination on Solanum nigrum Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 37.5 5.5 53.4 41.0 12.4 150+150 1:1 37.5 13.7 59.6 46.1 13.5 75+300 1:4 16.9 45.8 70.9 55.0 15.9 75+600 1:8 16.9 79.7 96.9 83.2 13.7

Table 139. Controlling effect of A4 or clomazone individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+45 10:3 74.7 8.6 89.1 76.9 12.3 150+90 5:3 74.7 12.9 89.9 78.0 12.0 75+180 5:12 52.6 50.9 88.6 76.7 11.9 75+360 5:24 52.6 72.1 99.4 86.8 12.7

Table 140. Controlling effect of A3 or carfentrazone-ethyl individually and their combination on Solanum nigrum Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 37.5 6.3 53.5 41.5 12.0 150+3.75 40:1 37.5 12.1 58.0 45.1 12.9 75+7.5 10:1 16.9 38.0 62.1 48.5 13.6 75+15 5:1 16.9 68.7 86.8 74.0 12.8

Table 141. Controlling effect of A3 or fomesafen individually and their combination on Acalypha australis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+22.5 20:3 51.6 6.4 65.2 54.7 10.4 150+45 10:3 51.6 12.6 71.5 57.7 13.7 75+90 5:6 20.7 46.9 72.9 57.9 14.9 75+180 5:12 20.7 82.4 98.8 86.0 12.7

Table 142. Controlling effect of A3 or fluoroglycophene individually and their combination on Acalypha australis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+0.9375 160:1 51.6 4.0 65.7 53.5 12.1 150+1.875 80:1 51.6 15.7 71.6 59.2 12.3 75+3.75 20:1 20.7 41.6 67.9 53.7 14.1 75+7.5 10:1 20.7 71.4 90.2 77.3 12.8

Table 143. Controlling effect of A3 or oxyfluorfen individually and their combination on Acalypha australis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 51.6 4.6 64.4 53.8 10.5 150+15 10:1 51.6 12.4 68.7 57.6 11.0 75+30 5:2 20.7 32.7 60.1 46.6 13.4 75+60 5:4 20.7 68.9 87.6 75.3 12.2

Table 144. Controlling effect of A3 or lactofen individually and their combination on Acalypha australis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 51.6 2.7 63.8 52.9 10.8 150+15 10:1 51.6 13.5 71.5 58.1 13.3 75+30 5:2 20.7 41.4 66.1 53.5 12.5 75+60 5:4 20.7 66.4 84.5 73.3 11.1

Table 145. Controlling effect of A3 or acifluorfen sodium individually and their combination on Acalypha australis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+37.5 4:1 51.6 5.8 66.0 54.4 11.5 150+75 2:1 51.6 11.6 67.9 57.2 10.6 75+150 1:2 20.7 46.6 71.1 57.6 13.4 75+300 1:4 20.7 85.3 99.0 88.3 10.6

Table 146. Controlling effect of A3 or flumioxazin individually and their combination on Acalypha australis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 51.6 6.9 67.8 54.9 12.8 150+15 10:1 51.6 13.7 71.6 58.2 13.3 75+30 5:2 20.7 39.0 64.2 51.6 12.5 75+60 5:4 20.7 79.3 94.8 83.6 11.1

Table 147. Controlling effect of A4 or sulfentrazone individually and their combination on Echinochloa oryzoides Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 74.7 5.8 86.8 76.2 10.7 150+3.75 40:1 74.7 18.1 92.1 79.3 12.9 75+7.5 10:1 52.6 29.7 78.5 66.7 11.9 75+15 5:1 52.6 56.1 89.9 79.2 10.8

Table 148. Controlling effect of A3 or saflufenacil individually and their combination on Sonchus oleraceus L. Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 55.5 5.4 70.6 57.9 12.7 150+7.5 20:1 55.5 13.9 75.3 61.7 13.6 75+15 5:1 33.8 40.9 75.5 60.9 14.6 75+30 5:2 33.8 76.6 98.1 84.5 13.6

Table 149. Control effect of A4 or oxadiazone individually and their combination on Echinochloa oryzoides (silted soil treatment) Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+37.5 4:1 42.5 5.1 56.8 45.4 11.4 150+75 2:1 42.5 10.3 60.3 48.4 11.9 75+150 1:2 18.9 39.7 63.2 51.1 12.1 75+300 1:4 18.9 50.8 73.2 60.1 13.1

Table 150. Controlling effect of A4 or oxadiargyl individually and their combination on Echinochloa oryzoides (treatment of silted soil) Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 42.5 2.6 54.2 44.0 10.2 150+15 10:1 42.5 12.7 59.9 49.8 10.1 75+30 5:2 18.9 41.6 64.7 52.6 12.1 75+60 5:4 18.9 63.3 81.4 70.2 11.2

Table 151. Controlling effect of A172 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 38.9 12.3 62.1 46.4 15.7 150+150 1:1 38.9 24.6 73.9 53.9 20.0 75+300 1:4 21.2 43.5 78.1 55.5 22.7 75+600 1:8 21.2 76.4 93.1 81.4 11.7

Table 152. Controlling effect of A172 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 47.9 2.1 65.2 49.0 16.2 150+150 1:1 47.9 8.7 72.3 52.4 19.9 75+300 1:4 22.4 15.3 53.7 34.3 19.4 75+600 1:8 22.4 34.5 74.2 49.2 25.0

Table 153. Controlling effect of A67 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 62.2 12.3 82.4 66.8 15.6 150+150 1:1 62.2 24.6 93.3 71.5 21.8 75+300 1:4 23.4 43.5 78.1 56.7 21.4 75+600 1:8 23.4 76.4 95.9 81.9 14.0 Table 154. Controlling effect of A67 or glyphosate alone and their combination on Eleusine indica Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 75.3 6.9 88.7 77.0 11.7 150+150 1:1 75.3 13.6 92.3 78.7 13.6 75+300 1:4 42.5 21.3 71.4 54.7 16.7 75+600 1:8 42.5 68.9 93.9 82.1 11.8

Table 155. Controlling effect of A67 or glyphosate individually and their combination on Sinapis arvensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 72.8 2.5 86.2 73.5 12.7 150+150 1:1 72.8 9.4 90.9 75.4 15.5 75+300 1:4 45.7 19.8 73.6 56.5 17.1 75+600 1:8 45.7 37.2 85.2 65.9 19.3

Table 156. Controlling effect of A67 or glyphosate individually and their combination on Alopecurus japonicus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 52.4 7.6 71.3 56.0 15.3 150+150 1:1 52.4 19.5 75.4 61.7 13.7 75+300 1:4 28.7 30.8 65.5 50.7 14.8 75+600 1:8 28.7 66.9 89.4 76.4 13.0

Table 157. Controlling effect of A67 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 75.6 2.1 87.4 76.1 11.3 150+150 1:1 75.6 8.7 91.6 77.7 13.9 75+300 1:4 51.4 15.3 83.2 58.8 24.4 75+600 1:8 51.4 34.5 90.3 68.2 22.1

Table 158. Controlling effect of A67 or ammonium glufosinate individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 63.9 10.2 82.6 67.6 15.0 150+150 1:1 63.9 19.6 89.4 71.0 18.4 75+300 1:4 31.7 28.6 83.7 51.2 32.5 75+600 1:8 31.7 54.1 92.3 68.7 23.6

Table 159. Control effects of A67 or paraquat dichloride alone and in combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 65.6 3.2 78.4 66.7 11.7 150+150 1:1 65.6 17.2 85.1 71.5 13.6 75+300 1:4 45.9 47.9 84.9 71.8 13.1 75+600 1:8 45.9 75.2 97.6 86.6 11.0

Table 160. Controlling effect of A67 monohydrate or diquat dibromide alone and in combination on Veronica didyma Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 43.1 5.5 57.7 46.2 11.5 150+150 1:1 43.1 12.6 73.8 50.3 23.5 75+300 1:4 23.2 41.3 78.3 54.9 23.4 75+600 1:8 23.2 80.4 95.8 84.9 10.9

Table 161. Controlling effect of A1 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 69.1 12.3 85.3 72.9 12.4 150+150 1:1 69.1 24.6 94.6 76.7 17.9 75+300 1:4 25.9 43.5 75.4 58.1 17.3 75+600 1:8 25.9 76.4 96.1 82.5 13.6

Table 162. Controlling effect of A1 or glyphosate alone and their combination on Eleusine indica Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 81.2 6.9 95.7 82.5 13.2 150+150 1:1 81.2 13.6 97.8 83.8 14.0 75+300 1:4 46.9 21.3 76.4 58.2 18.2 75+600 1:8 46.9 68.9 97.9 83.5 14.4

Table 163. Controlling effect of A1 or glyphosate individually and their combination on Sinapis arvensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 79.9 2.5 93.1 80.4 12.7 150+150 1:1 79.9 9.4 97.3 81.8 15.5 75+300 1:4 50.4 19.8 79.8 60.2 19.6 75+600 1:8 50.4 37.2 87.4 68.9 18.5

Table 164. Controlling effect of A1 or glyphosate individually and their combination on Alopecurus japonicus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 57.6 7.6 79.7 60.8 18.9 150+150 1:1 57.6 19.5 83.8 65.9 17.9 75+300 1:4 31.3 30.8 75.2 52.5 22.7 75+600 1:8 31.3 66.9 95.1 77.3 17.8

Table 165. Controlling effect of A1 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 82.4 2.1 95.8 82.8 13.0 150+150 1:1 82.4 8.7 98.7 83.9 14.8 75+300 1:4 56.5 15.3 82.5 63.2 19.3 75+600 1:8 56.5 34.5 90.5 71.5 19.0

Table 166. Controlling effect of A1 or ammonium glufosinate individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 71.7 10.2 91.4 74.6 16.8 150+150 1:1 71.7 19.6 97.2 77.2 20.0 75+300 1:4 35.4 28.6 76.7 53.9 22.8 75+600 1:8 35.4 54.1 90.2 70.3 19.9

Table 167. Controlling effect of A4 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 56.4 12.3 72.5 61.8 10.7 150+150 1:1 56.4 24.6 82.1 67.1 15.0 75+300 1:4 22.2 43.5 68.8 56.0 12.8 75+600 1:8 22.2 76.4 94.4 81.6 12.8

Table 168. Controlling effect of A4 or glyphosate alone and their combination on Eleusine indica Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 69.2 6.9 84.1 71.3 12.8 150+150 1:1 69.2 13.6 89.2 73.4 15.8 75+300 1:4 38.5 21.3 69.8 51.6 18.2 75+600 1:8 38.5 68.9 94.9 80.9 14.0

Table 169. Controlling effect of A4 or glyphosate individually and their combination on Sinapis arvensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 65.9 2.5 82.1 66.8 15.3 150+150 1:1 65.9 9.4 89.3 69.1 20.2 75+300 1:4 41.1 19.8 71.2 52.8 18.4 75+600 1:8 41.1 37.2 81.2 63.0 18.2

Table 170. Controlling effect of A4 or glyphosate individually and their combination on Alopecurus japonicus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 47.2 7.6 67.1 51.2 15.9 150+150 1:1 47.2 19.5 72.3 57.5 14.8 75+300 1:4 24.9 30.8 63.4 48.0 15.4 75+600 1:8 24.9 66.9 87.2 75.1 12.1

Table 171. Controlling effect of A4 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 67.2 2.1 79.1 67.9 11.2 150+150 1:1 67.2 8.7 86.4 70.1 16.3 75+300 1:4 44.2 15.3 70.2 52.7 17.5 75+600 1:8 44.2 34.5 79.2 63.5 15.7

Table 172. Controlling effect of A4 or ammonium glufosinate individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 57.2 10.2 72.5 61.6 10.9 150+150 1:1 57.2 19.6 82.6 65.6 17.0 75+300 1:4 26.7 28.6 71.4 47.7 23.7 75+600 1:8 26.7 54.1 84.7 66.4 18.3

Table 173. Controlling effect of A171 or glyphosate alone and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 31.9 12.3 52.3 40.3 12.0 150+150 1:1 31.9 24.6 64.2 48.7 15.5 75+300 1:4 19.2 43.5 69.2 54.3 14.9 75+600 1:8 19.2 76.4 92.3 80.9 11.4

Table 174. Controlling effect of A171 or glufosinate ammonium alone and in combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 28.9 2.1 42.2 30.4 11.8 150+150 1:1 28.9 8.7 53.2 35.1 18.1 75+300 1:4 12.2 15.3 46.2 25.6 20.6 75+600 1:8 12.2 34.5 61.3 42.5 18.8

Table 175. Controlling effect of A211 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 68.3 12.3 83.2 72.2 11.0 150+150 1:1 68.3 24.6 90.9 76.1 14.8 75+300 1:4 31.3 43.5 85.2 61.2 24.0 75+600 1:8 31.3 76.4 98.7 83.8 14.9

Table 176. Controlling effect of A211 or glufosinate ammonium alone and in combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 14.6 2.1 34.2 16.4 17.8 150+150 1:1 14.6 8.7 43.8 22.0 21.8 75+300 1:4 5.8 15.3 41.9 20.2 21.7 75+600 1:8 5.8 34.5 61.3 38.3 23.0

Table 177. Controlling effect of A94 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 51.7 12.3 72.3 57.6 14.7 150+150 1:1 51.7 24.6 82.5 63.6 18.9 75+300 1:4 23.4 43.5 79.5 56.7 22.8 75+600 1:8 23.4 76.4 95.3 81.9 13.4

Table 178. Controlling effect of A94 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 12.6 2.1 31.2 14.4 16.8 150+150 1:1 12.6 8.7 42.7 20.2 22.5 75+300 1:4 6.2 15.3 38.9 20.6 18.3 75+600 1:8 6.2 34.5 52.8 38.6 14.2

Table 179. Controlling effect of A173 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 73.6 12.3 89.7 76.8 12.9 150+150 1:1 73.6 24.6 93.2 80.1 13.1 75+300 1:4 38.2 43.5 84.3 65.1 19.2 75+600 1:8 38.2 76.4 95.9 85.4 10.5

Table 180. Controlling effect of A173 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 52.4 2.1 66.9 53.4 13.5 150+150 1:1 52.4 8.7 76.8 56.5 20.3 75+300 1:4 24.8 15.3 52.5 36.3 16.2 75+600 1:8 24.8 34.5 67.3 50.7 16.6

Table 181. Controlling effect of A212 or glyphosate alone and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 24.6 12.3 51.4 33.9 17.5 150+150 1:1 24.6 24.6 62.1 43.1 19.0 75+300 1:4 11.5 43.5 70.4 50.0 20.4 75+600 1:8 11.5 76.4 95.3 79.1 16.2

Table 182. Controlling effect of A212 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 14.5 2.1 34.8 16.3 18.5 150+150 1:1 14.5 8.7 46.2 21.9 24.3 75+300 1:4 8.6 15.3 43.7 22.6 21.1 75+600 1:8 8.6 34.5 61.2 40.1 21.1

Table 183. Controlling effect of A141 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 55.8 12.3 76.4 61.2 15.2 150+150 1:1 55.8 24.6 83.1 66.7 16.4 75+300 1:4 27.7 43.5 73.2 59.2 14.0 75+600 1:8 27.7 76.4 95.1 82.9 12.2

Table 184. Controlling effect of A141 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 16.4 2.1 31.1 18.2 12.9 150+150 1:1 16.4 8.7 42.9 23.7 19.2 75+300 1:4 7.8 15.3 36.2 21.9 14.3 75+600 1:8 7.8 34.5 54.8 39.6 15.2

Table 185. Controlling effect of A163 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 45.4 12.3 71.2 52.2 19.0 150+150 1:1 45.4 24.6 81.6 58.9 22.7 75+300 1:4 16.6 43.5 74.9 52.9 22.0 75+600 1:8 16.6 76.4 95.8 80.3 15.5

Table 186. Controlling effect of A163 or glyphosate alone and their combination on Eleusine indica Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 56.0 6.9 73.7 59.0 14.7 150+150 1:1 56.0 13.6 86.1 62.0 24.1 75+300 1:4 31.7 21.3 65.0 46.2 18.8 75+600 1:8 31.7 68.9 91.7 78.8 12.9

Table 187. Controlling effect of A163 or glyphosate individually and their combination on Sinapis arvensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 47.2 2.5 69.7 48.5 21.2 150+150 1:1 47.2 9.4 77.3 52.1 25.2 75+300 1:4 29.6 19.8 70.4 43.6 26.8 75+600 1:8 29.6 37.2 81.1 55.8 25.3

Table 188. Controlling effect of A163 or glyphosate individually and their combination on Alopecurus japonicus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 44.0 7.6 61.8 48.3 13.5 150+150 1:1 44.0 19.5 71.8 54.9 16.9 75+300 1:4 24.1 30.8 62.3 47.5 14.8 75+600 1:8 24.1 66.9 89.3 74.9 14.4

Table 189. Controlling effect of A163 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 60.5 2.1 73.9 61.3 12.6 150+150 1:1 60.5 8.7 88.0 63.9 24.1 75+300 1:4 41.1 15.3 74.3 50.1 24.2 75+600 1:8 41.1 34.5 86.2 61.4 24.8

Table 190. Controlling effect of A163 or ammonium glufosinate individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 53.7 10.2 70.1 58.4 11.7 150+150 1:1 53.7 19.6 85.8 62.8 23.0 75+300 1:4 26.6 28.6 70.5 47.6 22.9 75+600 1:8 26.6 54.1 88.5 66.3 22.2

Table 191. Controlling effect of A163 or paraquat dichloride alone and in combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 55.8 3.2 75.9 57.2 18.7 150+150 1:1 55.8 17.2 81.5 63.4 18.1 75+300 1:4 39.0 47.9 81.7 68.2 13.5 75+600 1:8 39.0 75.2 97.5 84.9 12.6

Table 192. Controlling effect of A163 or diquat dibromide monohydrate alone and in combination on Veronica didyma Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 34.5 5.5 55.2 38.1 17.1 150+150 1:1 34.5 12.6 70.2 42.7 27.5 75+300 1:4 18.6 41.3 75.1 52.2 22.9 75+600 1:8 18.6 80.4 97.7 84.0 13.7

Table 193. Controlling effect of A130 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 36.8 12.3 66.3 44.6 21.7 150+150 1:1 36.8 24.6 75.5 52.3 23.2 75+300 1:4 16.7 43.5 72.7 52.9 19.8 75+600 1:8 16.7 76.4 93.9 80.3 13.6

Table 194. Controlling effect of A130 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 13.2 2.1 32.6 15.0 17.6 150+150 1:1 13.2 8.7 45.8 20.8 25.0 75+300 1:4 5.4 15.3 41.1 19.9 21.2 75+600 1:8 5.4 34.5 56.2 38.0 18.2

Table 195. Controlling effect of A213 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 31.2 12.3 53.9 39.7 14.2 150+150 1:1 31.2 24.6 67.9 48.1 19.8 75+300 1:4 14.9 43.5 68.2 51.9 16.3 75+600 1:8 14.9 76.4 91.3 79.9 11.4

Table 196. Controlling effect of ammonium glufosinate A213 individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 26.8 2.1 43.9 28.3 15.6 150+150 1:1 26.8 8.7 52.8 33.2 19.6 75+300 1:4 14.6 15.3 48.7 27.7 21.0 75+600 1:8 14.6 34.5 61.2 44.1 17.1

Table 197. Controlling effect of A214 or glyphosate alone and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 44.6 12.3 63.9 51.4 12.5 150+150 1:1 44.6 24.6 74.7 58.2 16.5 75+300 1:4 21.9 43.5 74.6 55.9 18.7 75+600 1:8 21.9 76.4 95.6 81.6 14.0

Table 198. Controlling effect of A214 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 46.2 2.1 65.8 47.3 18.5 150+150 1:1 46.2 8.7 73.8 50.9 22.9 75+300 1:4 24.8 15.3 68.8 36.3 32.5 75+600 1:8 24.8 34.5 72.3 50.7 21.6

Table 199. Controlling effect of A2 or glyphosate individually and their combination on Digitaria sanguinalis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 51.6 12.3 73.8 57.6 16.2 150+150 1:1 51.6 24.6 87.2 63.5 23.7 75+300 1:4 19.4 43.5 74.7 54.5 20.2 75+600 1:8 19.4 76.4 94.5 81.0 13.5

Table 200. Controlling effect of A2 or glyphosate alone and their combination on Eleusine indica Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 63.3 6.9 83.2 65.8 17.4 150+150 1:1 63.3 13.6 88.7 68.2 20.5 75+300 1:4 35.7 21.3 68.2 49.4 18.8 75+600 1:8 35.7 68.9 91.8 80.0 11.8

Table 201. Controlling effect of A2 or glyphosate alone and their combination on Sinapis arvensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 60.4 2.5 81.1 61.4 19.7 150+150 1:1 60.4 9.4 88.2 64.1 24.1 75+300 1:4 37.9 19.8 72.5 50.2 22.3 75+600 1:8 37.9 37.2 83.3 61.0 22.3

Table 202. Controlling effect of A2 or glyphosate alone and their combination on Alopecurus japonicus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 44.5 7.6 65.4 48.8 16.6 150+150 1:1 44.5 19.5 73.9 55.4 18.5 75+300 1:4 24.4 30.8 63.6 47.7 15.9 75+600 1:8 24.4 66.9 89.8 75.0 14.8

Table 203. Controlling effect of A2 or ammonium glufosinate individually and their combination on Capsella bursa-pastoris Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 65.0 2.1 79.3 65.8 13.5 150+150 1:1 65.0 8.7 85.9 68.1 17.8 75+300 1:4 44.2 15.3 76.3 52.7 23.6 75+600 1:8 44.2 34.5 84.1 63.5 20.6

Table 204. Controlling effect of A2 or ammonium glufosinate individually and their combination on Amaranthus retroflexus Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 51.8 10.2 69.7 56.7 13.0 150+150 1:1 51.8 19.6 82.5 61.2 21.3 75+300 1:4 25.7 28.6 72.4 46.9 25.5 75+600 1:8 25.7 54.1 83.5 65.9 17.6

Table 205. Control effects of A2 or paraquat dichloride alone and in combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 54.4 3.2 67.2 55.9 11.3 150+150 1:1 54.4 17.2 78.9 62.3 16.6 75+300 1:4 38.1 47.9 82.2 67.7 14.5 75+600 1:8 38.1 75.2 98.4 84.6 13.8

Table 206. Controlling effect of A2 or diquat dibromide monohydrate alone and in combination on Veronica didyma Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 36.6 5.5 61.7 40.1 21.6 150+150 1:1 36.6 12.6 75.3 44.6 30.7 75+300 1:4 19.7 41.3 79.0 52.9 26.1 75+600 1:8 19.7 80.4 97.3 84.3 13.0

Table 207. Controlling effect of A2 or triclopyr alone and in combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 60+300 1:5 22.6 78.4 95.1 83.3 11.8

Table 208. Control effects of A2 or MCPA alone and their combinations on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 120+75 1.6:1 47.9 18.8 71.3 57.7 13.6

Table 209. Controlling effect of A2 or dicamba alone and in combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 60+150 1:2.5 22.6 58.7 81.4 68.0 13.4

Table 210. Controlling effect of A2 or picloram alone and their combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 120+7.5 16:1 47.9 5.0 60.8 50.5 10.3 60+60 1:1 22.6 69.4 88.4 76.3 12.1

Table 211. Controlling effect of A2 or aminopyralide alone and their combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 120+15 8:1 47.9 19.0 71.2 57.8 13.4 60+30 2:1 22.6 40.7 65.8 54.1 11.7

Table 212. Controlling effect of A2 or fluroxypyr alone and in combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 120+37.5 3.2:1 47.9 5.8 63.4 50.9 12.5

Table 213. Controlling effect of A2 or florpyraoxyphenbenzyl alone and their combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 120+1.875 64:1 47.9 3.5 59.8 49.7 10.1 60+7.5 8:1 22.6 47.4 73.2 59.3 13.9

Table 214. Controlling effect of A2 or halauxifen-methyl alone and their combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 120+3.75 32:1 47.9 20.5 72.4 58.6 13.8 60+15 4:1 22.6 81.5 99.3 85.7 13.6

Table 215. Controlling effect of A2 or quinclorac alone and their combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 120+30 4:1 47.9 11.7 72.5 54.0 18.5 120+60 2:1 47.9 28.8 82.2 62.9 19.3 60+120 1:2 22.6 53.7 87.4 64.2 23.2 60+240 1:4 22.6 76.2 94.7 81.6 13.1

Table 216. Controlling effect of A2 or clopyralid alone and their combination on Conyza Canadensis Dose A+B (g a.i./ha) A:B Controlling effect (%) A applied separately in the appropriate dose Controlling effect (%) B applied separately at the appropriate dose Control action A+B (%), E E0 (%) E-E0 (%) 120+15 8:1 47.9 6.1 78.3 51.1 27.2 120+30 4:1 47.9 29.8 85.5 63.4 22.1 60+60 1:1 22.6 53.5 86.7 64.0 22.7 60+120 1:2 22.6 82.8 98.6 86.7 11.9

C) Experimental areas

Tests in which the herbicidal compositions prepared in Examples 1 to 150 are used to control weeds in fields.

In 2018, a popularization demonstration test was conducted at pilot sites in Qingdao City in Shandong Province. The weeds in the fields mainly included: Digitaria sanguinalis, Eleusine indica, Echinochloa crus-galli, Setaria viridis, Panicum miliaceum L., Amaranthus retroflexus, Acalypha australis, Equisetum arvense, Mollugo pentaphylla L., Juncellus serotinus and so on.

Experimental methods:

Foliar treatment: At the 3-5 leaf stage of weeds, the product is evenly sprayed onto the stems and leaves through a hand sprayer, and the amount of water added is 30 kg/667 ^m2 .

The specific agents tested and their dosage are shown in Table 217. The experimental area is 50 square meters and each treatment is repeated 4 times. Weed control effectiveness after 45 days of application is shown in Table 217.

Weed control effect expressed as fresh weight (%) = (fresh weight of control weed - fresh weight of treated weed) / fresh weight of control weed x 100

Table 217 Controlling effect of the claimed compositions in experimental areas Example No. Dosage
(g a.i./ha) Controlling effect expressed on fresh weight (%) 1 150 97.8 2 180 95.6 3 210 93.8 4 150 98.3 5 180 95.2 6 210 94.6 7 150 97.5 8 180 96.7 9 210 94.9 10 180 96.6 eleven 210 96.7 12 240 94.1 13 124.5 97.1 14 154.5 96.3 15 184.5 94.9 16 150 96.3 17 180 97.8 18 210 95.2 19 210 95.4 20 240 97.8 21 270 94.4 22 270 95.9 23 300 97.4 24 330 95.2 25 180 95.1 26 210 98.9 27 240 95.5 28 270 94.2 29 300 98.9 thirty 330 94.7 31 150 94.7 32 180 98.5 33 210 95.5 34 270 93.9 35 300 98.3 36 330 95.8 37 165 97.5 38 195 95.1 39 225 93.6 40 195 97.6 41 225 94.9 42 255 94.1 43 210 97.3 44 240 95.8 45 270 94.6 46 345 96.1 47 375 96.5 48 405 93.4 49 180 96.8 50 210 95.8 51 240 94.7 52 180 95.6 53 210 97.5 54 240 94.7 55 180 95.1 56 210 97.3 57 240 94.2 58 870 95.2 59 900 97.1 60 930 94.7 61 870 94.9 62 900 97.8 63 930 95.2 64 870 93.7 65 900 98.7 66 930 93.5 67 1020 94.4 68 1050 97.7 69 1080 95.3 70 720 93.2 71 750 97.5 72 780 95.3 73 300 92.7 74 330 96.5 75 360 95.3 76 1620 94.5 77 1650 94.9 78 1680 97.2 79 255 94.1 80 285 94.8 81 315 96.3 82 150 93.5 83 180 94.5 84 210 96.8 85 255 94.2 86 285 94.7 87 315 96.2 88 300 94.9 89 330 93.2 90 360 98.5 91 210 92.3 92 240 94.1 93 270 96.9 94 270 95.1 95 300 92.5 96 330 96.7 97 210 94.8 98 240 92.2 99 270 96.3 100 165 94.2 101 195 93.8 102 225 94.4 103 210 97.9 104 240 95.7 105 270 94.5 106 420 97.1 107 450 93.3 108 480 93.8 109 270 97.2 110 300 93.7 111 330 94.2 112 870 96.5 113 900 93.8 114 930 92.9 115 570 99.8 116 600 92.6 117 630 92.9 118 150 96.6 119 180 94.3 120 210 92.3 121 495 97.9 122 525 94.6 123 555 96.8 124 135 95.4 125 165 95.8 126 195 97.4 127 300 92.1 128 330 93.5 129 360 96.4 130 240 93.5 131 270 95.4 132 300 96.3 133 570 93.1 134 600 93.2 135 630 99.3 136 210 92.1 137 240 92.7 138 270 95.5 139 480 95.1 140 510 93.6 141 540 98.2 142 480 93.4 143 510 97.9 144 540 94.6 145 720 91.5 146 750 96.7 147 780 94.9 148 210 93.7 149 240 95.8 150 270 96.3

D) In-lab assessment tests

The indoor evaluation test was conducted using the herbicidal composition prepared in accordance with A) Examples 151-165, and the specific testing method was the same as in the corresponding part B) Efficacy Assays.

Test weeds: Echinochloa crus-galli, Digitaria sanguinalis, Eleusine indica, Setaria viridis, Panicum miliaceum L., Amaranthus retroflexus, Abutilon theophrasti, Acalypha australis.

Test Crop (Containing Glyphosate Resistance Trait, 2,4-D): SmartStax™ Pro x Enlist™ Corn (Event Name MON87427 x MON89034 x TC1507 x MON87411×59122 x DAS40278), Conkesta Enlist E3™ Soybean (Event Name DAS81419 x) (DAS44406).

Leaf age for stem and leaf treatments: weeds at the 3-5 leaf stage, corn at the 3-5 leaf stage with one leaf that has not fully blossomed, and soybeans at the 2-3 trilobed stage.

The specific agents tested, dosages, and 20-day post-administration survey results are presented in Table 218.

Weed control effect expressed as fresh weight (%) = (fresh weight of control weed - fresh weight of treated weed) / fresh weight of control weed x 100

Table 218 Application of compound compositions on transgenic crops with signs of resistance to herbicides Agents Dosage
(g a.i./ha) Weed control effect expressed per fresh weight (%) Corn safety Soybean safety 151 1125 93.1 Safety Safety 152 900 96.4 Safety Safety 153 877.5 97.2 Safety Safety 154 945 95.2 Safety Safety 155 1125 94.9 Safety Safety 156 900 92.3 Safety Safety 157 1125 91.7 Safety Safety 158 900 93.9 Safety Safety 159 1125 94.6 Safety Safety 160 900 92.0 Safety Safety 161 900 95.5 Safety Safety 162 900 94.2 Safety Safety 163 900 91.6 Safety Safety 164 900 93.2 Safety Safety 165 900 96.0 Safety Safety

After extensive experimentation and research, the inventors of the present invention unexpectedly discovered that the claimed compositions are useful for controlling broadleaf weeds such as Ammannia arenaria, Amaranthus retroflexus, Acalypha australis, Solanum nigrum, Eclipta prostrate, Galium aparine L., Convolvulus arvensis, Conyza Canadensis, Capsella Bursa-Pastoris, Abutilon Theophrasti, Veronica Persica, Malachium Aquaticum, Stellaria Media, Sinapis Arrenensis, Ludwigia Prostratrate, Lindernia ProCumbens, Sonchus Arevens Sis, Sonchus Oleraceus L., Cirsium Setosum, Xanthium Strumarium, Descurainia Sophia, Chenopodium album, Commelina Communis, iPomoeaa, iPomoea purpurea, etc.; herbaceous weeds such as Alopecurus aequalis, Alopecurus japonicus, Chloris virgata, Echinochloa crus-galli, Echinochloa crusgalli var. zelayensis, Echinochloa oryzoides, Echinochloa caudate, Setaria faberi, Setaria viridis, Setaria glauca, Digitaria sanguinalis, Eleusine indica, Beckmannia syzigachne, Eriochloa villosa, Panicum miliaceum, etc.; and algae such as Equisetum arvense, etc., and surprising and unexpected synergistic effects are achieved, the synergistic effects being particularly significant at low doses, thereby reducing application rates and reducing environmental pollution, and rational formulation leading to reduced agricultural costs and highly effective control of weeds resistant to ALS and ACCase inhibitors. The inventive compositions have a good prospect of application. At the same time, it has been experimentally shown that the claimed compositions exhibit good selectivity and excellent synergistic effects on fields such as wheat, corn and rice fields, as well as on crops such as peanuts, sugar cane, sorghum, millet, potatoes, rapeseed , soybeans, cotton, vegetables, bluegrass, tall fescue and Zoysia japonica, and can be developed into herbicide mixtures with wide market value.

Claims (41)

1. A herbicidal composition containing active ingredient A and active ingredient B in a herbicidal effective amount, where the mass ratio of ingredient A to ingredient B is 1:30~100:1, where active ingredient A is one or more compounds selected from R-pyridyloxycarbonate acid represented by formula I and its salt, ester derivative, where each of R ₁ , R ₂ is independently chlorine or bromine; R ₃ is hydrogen or fluorine; Q is methyl, ethyl or phenyl; Y is amino; salt is a metal salt, ammonium salt NH ₄ ⁺ , primary amine salt R”NH ₂ , secondary amine salt (R”) ₂ NH, tertiary amine salt (R”) ₃ N, quaternary amine salt (R”) ₄ N+, salt polyamine, morpholine salt, N-methylmorpholine salt, piperidine salt, pyridine salt, aminopropylmorpholine salt, Jeff D-230 amine salt, 2,4,6-tri(dimethylaminomethyl)phenol sodium hydroxide salt, C1-C16 alkylsulfonium salt, C1 salt -C16 alkylsulfoxonium, C1-C16 alkylphosphonium salt or C1-C16 alkanolphosphonium salt; wherein R" is each independently C1-C16 alkyl, unsubstituted or substituted by one or more of the following groups: halogen, hydroxy, C1-C6 alkoxy, C1-C6 alkylthio, hydroxy C1-C6 alkoxy; C2-C12 alkenyl, C2-C12 alkynyl, C3-C12 cycloalkyl; or phenyl or benzyl, unsubstituted or substituted with C1-C6 alkyl; ester is , where X is O or S; M is methyl, undecyl, tetrahydrofurylmethylene, furylmethylene, , ; or benzyl, substituted or unsubstituted with fluorine, methyl; active ingredient B is selected from the following one or more compounds, or acids, or salts thereof, or ester derivatives, (1) an ALS inhibitor selected from penoxsulam, bispiribac sodium, pyrazosulfuron-ethyl, nicosulfuron, florasulam, rimsulfuron, imazethapyr, imazapic, imazamox, sulfometuron-methyl and cloransulam-methyl; (2) an ACCase inhibitor selected from: cyhalofop-butyl, clodinafop-propargyl, pinoxaden, clethodim, sethoxydim, quizalofop-P-methyl, fluazifop-P-butyl and haloxyfop-P-methyl; (3) a PSII inhibitor selected from: atrazine, isoproturon, chlortoluron, diuron, bentazone, bromoxynil and propanil; (4) an HPPD inhibitor selected from: cipirafluone, bipyrazone, phenpyrazone, tripirasulfone, tefuryltrione, mesotrione, tembotrione, topramesone, isoxaflutole and benzobicilone; (5) a PDS inhibitor selected from: diflufenican and fluorochloridone; (6) DOXP inhibitor: clomazone; (7) a PPO inhibitor selected from: carfentrazone-ethyl, fomesafen, fluoroglycofen, oxyfluorfen, lactofen, acifluorfen-sodium, flumioxazin, sulfentrazone, saflufenacil, oxadiazone and oxadiargyl; (8) a synthetic hormone inhibitor selected from: triclopyr, MCPA, dicamba, picloram, aminopyralid, fluroxypyr, florpyraoxyphenbenzyl, halauxifenmethyl, quinclorac and clopyralid; (9) EPSPS inhibitor: glyphosate; (10) a GS inhibitor selected from glufosinate ammonium; (11) a PSI inhibitor selected from diquat monohydrate dibromide and paraquat dichloride. 2. Herbicidal composition according to claim 1, characterized in that salt is an alkali metal salt (for example, sodium, lithium, potassium, cesium or rubidium), an alkaline earth metal salt (for example, calcium, magnesium, barium or strontium) and metal salts such as antimony, bismuth, cadmium, cerium, chromium, cobalt , scandium, titanium, manganese, copper, iron, silver, gold, zinc, aluminum, etc., amine salts such as ammonium salt, tetramethylammonium salt, tetraethylammonium salt, tetrapropylammonium salt, tetrabutylammonium salt, N-hexadecyltrimethylamine salt, salt N-benzyltrimethylammonium, benzyltriethylammonium salt, choline amine salt, monomethylamine salt, dimethylamine salt, trimethylamine salt, monoethylamine salt, diethylamine salt, triethylamine salt, n-propylamine salt, dipropylamine salt, tripropylamine salt, monoisopropylamine salt, diisopropylamine salt, triisopropylamine salt, salt n-butylamine, dibutylamine salt, tributylamine salt, isobutylamine salt, tert-butylamine salt, pentylamine salt, hexylamine salt, heptylamine salt, octylamine salt, dodecylamine salt, tetradecylamine salt, diallylamine salt, cyclohexylamine salt, cyclododecylamine salt, aniline salt, o salt -toluidine, m-toluidine salt, p-toluidine salt, dianiline salt, benzylamine salt, monoethanolamine salt, N-methylmonoethanolamine salt, N, N-dimethylethanolamine salt, N-ethylmonoethanolamine salt, N, N-diethylethanolamine salt, N-propylmonoethanolamine salt , N,N-di-n-propylethanolamine salt, N-butylmonoethanolamine salt, diethanolamine salt, N-methyldiethanolamine salt, N-ethyldiethanolamine salt, N-propyldiethanolamine salt, N-butyldiethanolamine salt, N,N-dibutylethanolamine salt, triethanolamine salt, tripropanolamine salt, triisopropanolamine salt, tri(2-hydroxypropyl)amine salt, diglycolamine salt, polyamine salt (e.g. hexamethylenetetramine salt, ethylene diamine salt, diethylenetriamine salt, dimethylaminopropylamine salt, 1,2-propyldiamine salt, triethylene diamine salt, triethylene tetramine salt, benzidine salt , N,N-bis[aminopropyl]methylamine salt), 2-methylthiopropylamine salt, 2-butoxyethylamine salt, AEPD salt, tri(methylol)aminomethane salt, morpholine salt, N-methylmorpholine salt, piperidine salt, pyridine salt, aminopropylmorpholine salt, Jeff D-230 amine salt, 2,4,6-tri(dimethylaminomethyl)phenol sodium hydroxide salt, trimethylsulfonium salt or triethylsulfonium salt. 3. Herbicidal composition according to claim 1 or 2, characterized in that the active ingredient A is one or more compounds selected from 4. Herbicidal composition according to any one of paragraphs. 1-3, characterized in that the mass ratio of ingredient A to ingredient B is 1:20~100:1 or 1:20~50:1, or 1:20~30:1 or 1:20~20:1, or 1:10~10:1 or 1:8~8:1 or 1:5~5:1 or 1:1~2:1 or 1:1~1:2. 5. Herbicidal composition according to any one of paragraphs. 1-4, characterized in that ingredients A and B together constitute 1-95% of the total weight of the herbicidal composition or 10-80%. 6. Herbicidal composition according to any one of paragraphs. 1-4, characterized in that the herbicidal composition additionally contains a conventional auxiliary substance and/or a surfactant. 7. Herbicidal composition according to any one of paragraphs. 1-4, characterized in that the herbicidal composition additionally contains one or more antidotes. 8. Herbicidal composition according to any one of paragraphs. 1-7, characterized in that the herbicidal composition is in the form of a composition selected from: dispersible oil suspension, aqueous suspension, suspension emulsion, wettable powder, emulsifiable concentrate, water dispersible granules, aqueous emulsion and microemulsion. 9. Use of the herbicidal composition according to any one of paragraphs. 1-7 for weed control. 10. A method of combating unwanted plant growth, including applying a herbicidal composition according to any one of claims. 1-7 on plants, plant parts, plant seeds or plant growing area.