RU2000110132A - Слоистый материал, защищающий от кислорода, способ защиты продукта и упаковочное изделие с его использованием, материал, поглощающий кислород - Google Patents
Слоистый материал, защищающий от кислорода, способ защиты продукта и упаковочное изделие с его использованием, материал, поглощающий кислородInfo
- Publication number
- RU2000110132A RU2000110132A RU2000110132/13A RU2000110132A RU2000110132A RU 2000110132 A RU2000110132 A RU 2000110132A RU 2000110132/13 A RU2000110132/13 A RU 2000110132/13A RU 2000110132 A RU2000110132 A RU 2000110132A RU 2000110132 A RU2000110132 A RU 2000110132A
- Authority
- RU
- Russia
- Prior art keywords
- oxygen
- material according
- packaging
- layered material
- segments
- Prior art date
Links
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 title claims 12
- 229910052760 oxygen Inorganic materials 0.000 title claims 12
- 239000001301 oxygen Substances 0.000 title claims 12
- 239000000463 material Substances 0.000 title claims 10
- 238000004806 packaging method and process Methods 0.000 title claims 4
- 239000005022 packaging material Substances 0.000 claims 6
- 239000004952 Polyamide Substances 0.000 claims 5
- 229920002647 polyamide Polymers 0.000 claims 5
- 239000011528 polyamide (building material) Substances 0.000 claims 5
- 229920000098 polyolefin Polymers 0.000 claims 5
- 239000011358 absorbing material Substances 0.000 claims 4
- 238000010521 absorption reaction Methods 0.000 claims 3
- 239000007787 solid Substances 0.000 claims 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 229910052803 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- 229910052723 transition metal Inorganic materials 0.000 claims 2
- 150000003624 transition metals Chemical class 0.000 claims 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-Methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims 1
- 239000005062 Polybutadiene Substances 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- QAEKNCDIHIGLFI-UHFFFAOYSA-L cobalt(2+);2-ethylhexanoate Chemical group [Co+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O QAEKNCDIHIGLFI-UHFFFAOYSA-L 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229920002857 polybutadiene Polymers 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- -1 polypropylene Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 229920001169 thermoplastic Polymers 0.000 claims 1
Claims (14)
1. Слоистый материал, защищающий от кислорода, включающий слой упаковочного материала и слой сополирмида, активно поглощающего кислород, содержащего в основном сегменты полиамида и сегменты олигомерного полиолефина в количестве, обеспечивающем поглощение кислорода, причем указанный сополиамид находится в твердом состоянии ниже его температуры стеклования и способен поглощать кислород в твердом состоянии при температурах в интервале от 0oС до 60oС.
2. Слоистый материал по п. 1, отличающийся тем, что упаковочный материал представляет собой термопластичный полимер.
3. Слоистый материал по п. 1, отличающийся тем, что упаковочный материал представляет собой сложный полиэфир.
4. Слоистый материал по п. 4, отличающийся тем, что упаковочный материал представляет собой полиамид.
5. Слоистый материал по п. 4, отличающийся тем, что сегменты полиамида в сополиамиде получены из полиамида, используемого в качестве упаковочного материала.
6. Слоистый материал по п. 1, отличающийся тем, что содержание сегментов олигомерного полиолефина равно от 0,5 до 12% от веса сополимера.
7. Слоистый материал по п. 1, отличающийся тем, что олигомерный полиолефин выбран из группы, состоящей из полипропилена, поли(4-метил)-1-пентена, полибутадиена и их смесей.
8. Слоистый материал по п. 1, отличающийся тем, что молекулярный вес олигомерного полиолефина равен 1000-3000.
9. Упаковочное изделие, стенка которого содержит слоистый материал по п. 1, расположенный внутри этой стенки.
10. Способ увеличения полезного срока хранения чувствительного к кислороду продукта, включающий упаковку указанного чувствительного к кислороду продукта в подходящее упаковочное изделие, стенка которого содержит упаковочный материал по п. 1, расположенный внутри этой стенки.
11. Материал, поглощающий кислород, включающий сополиамид, содержащий в основном сегменты полиамида и сегменты олигомерного полиолефина в количестве, обеспечивающем способность поглощать кислород, и катализатор, представляющий собой переходный металл в количестве 10-2000 ч/млн в расчете на вес сополиамида, причем сополиамид способен поглощать кислород в твердом состоянии при температуре окружающей среды.
12. Материал, поглощающий кислород по п. 11, отличающийся тем, что переходный металл представляет собой кобальт.
13. Материал, поглощающий кислород по п. 12, отличающийся тем, что источник кобальта представляет собой октоат кобальта.
14. Материал, поглощающий кислород по п. 11, отличающийся тем, что он дополнительно включает фотоактивные вещества, которые после достаточной облучением ускоряют поглощение кислорода сополиамидами.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/717,370 US6083585A (en) | 1996-09-23 | 1996-09-23 | Oxygen scavenging condensation copolymers for bottles and packaging articles |
PCT/US1997/016712 WO1998012244A1 (en) | 1996-09-23 | 1997-09-22 | Oxygen scavenging condensation copolymers for bottles and packaging articles |
USPCT/US97/16712 | 1997-09-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
RU2000110132A true RU2000110132A (ru) | 2002-12-10 |
RU2198123C2 RU2198123C2 (ru) | 2003-02-10 |
Family
ID=24881757
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU99107976/04A RU2182157C2 (ru) | 1996-09-23 | 1997-09-22 | Конденсационные сополимеры, поглощающие кислород, для изготовления бутылок и упаковок |
RU2000110132/13A RU2198123C2 (ru) | 1996-09-23 | 1998-02-17 | Слоистый материал, защищающий от кислорода, способ защиты продукта и упаковочное изделие с его использованием, материал, поглощающий кислород |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU99107976/04A RU2182157C2 (ru) | 1996-09-23 | 1997-09-22 | Конденсационные сополимеры, поглощающие кислород, для изготовления бутылок и упаковок |
Country Status (23)
Country | Link |
---|---|
US (5) | US6083585A (ru) |
EP (1) | EP0927218B1 (ru) |
JP (1) | JP3657275B2 (ru) |
KR (1) | KR100495207B1 (ru) |
CN (1) | CN1097067C (ru) |
AR (1) | AR008475A1 (ru) |
AU (1) | AU718541B2 (ru) |
BR (1) | BR9711522A (ru) |
CA (1) | CA2266402C (ru) |
CZ (1) | CZ298554B6 (ru) |
DE (1) | DE69701637T2 (ru) |
DK (1) | DK0927218T3 (ru) |
ES (1) | ES2147457T3 (ru) |
HK (1) | HK1020746A1 (ru) |
ID (1) | ID19778A (ru) |
IL (3) | IL160186A0 (ru) |
MY (1) | MY138894A (ru) |
NO (1) | NO325609B1 (ru) |
NZ (1) | NZ334570A (ru) |
RU (2) | RU2182157C2 (ru) |
UA (2) | UA56190C2 (ru) |
WO (1) | WO1998012244A1 (ru) |
ZA (1) | ZA978062B (ru) |
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