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KR950701657A - 고온 반응에 의한 폴리아스파르트산의 염(Salts of polyaspartic acid by high temperature reaction) - Google Patents

고온 반응에 의한 폴리아스파르트산의 염(Salts of polyaspartic acid by high temperature reaction)

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Publication number
KR950701657A
KR950701657A KR1019940704048A KR19940704048A KR950701657A KR 950701657 A KR950701657 A KR 950701657A KR 1019940704048 A KR1019940704048 A KR 1019940704048A KR 19940704048 A KR19940704048 A KR 19940704048A KR 950701657 A KR950701657 A KR 950701657A
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South Korea
Prior art keywords
hydroxide
ammonia
salt
acid
alkali metal
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KR1019940704048A
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KR100264498B1 (ko
Inventor
엘.우드 루이스
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만프레트로벨. 볼프강페트로빅키
바이엘 아크티엔 게젤샤프트
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Publication of KR950701657A publication Critical patent/KR950701657A/ko
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Publication of KR100264498B1 publication Critical patent/KR100264498B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/12—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/12—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
    • C02F5/125—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen combined with inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/10—Alpha-amino-carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/48—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1092—Polysuccinimides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3719—Polyamides or polyimides
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Pest Control & Pesticides (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polyamides (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

물 및 중요하게는 세제 제형에서 경도를 유발하는 물질로 인한 스케일을 억제하는데 유용한 폴리아스파르테이트는 말레산 또는 푸마르산을 암모니아와 1:1 내지 2.1의 몰비로 170℃이상의 온도에서 반응시킨후, 이 반응에서 형성된 중합체를 염기성 가수분해에 염기성 가수분해에 의해 폴리아스파르트산의 염으로 전화시킴으로써 제조할 수 있다.

Description

고온 반응에 의한 폴리아스파르트산의 염(Salts of polyaspartic acid by high temperature reaction)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 탄산 칼슘 침착을 억제하는데 대한 첨가제의 효과를 도시한 것이도,
제2도는 열중합된 모노-암노늄 말레에이트 염의 칼슘 스케일 억제제로서의 효과를 도시한 것이며,
제3도는 열중합된 모노-암노늄 푸마레이트염의 칼슘 스케일 억제제로서의 효과를 도시한 것이고,
제4도는 열중합된 디-암모늄 푸마레이트 및 말레에이트 염의 칼슘 스케일 억제제로서의 효과를 도시한 것이며,
제5도는 분자량 컬럼의 검정을 도시한 것이고,
제6도는 실시예 2,4,10 및 11에 형성된 중합체의 분자량 측정을 도시한 것이다.

Claims (18)

  1. 암모니아가 몰 과량으로 존재하도록 하면서 말레산과 암모니아를 200 내지 300℃에서 반응시킨 후, 생성된 중합체에 수산화물을 가하여 염으로 전화시킴을 포함하여 폴리아스파르트산의 염을 제조하는 방법.
  2. 제1항에 있어서, 말레산과 암모니아를 200 내지 300℃로 가열시키고, 이 온도를 0 내지 4시간 동안 유지시킴을 특징으로 하여 폴리아스파르트산의 염을 제조하는 방법.
  3. 제1항에 있어서, 말레산과 암모니아를 240 내지 300℃로 가열시키고, 이 온도를 0 내지 4시간 동안 유지시킴을 특징으로 하여 폴리아스파르트산의 염을 제조하는 방법.
  4. 암모니아가 몰 과량으로 존재하도록 하면서 푸마르산과 암모니아를 220 내지 300℃에서 반응시킨 후, 생성된 중합체에 수산화물을 가하여 염으로 전환시킴을 포함하여 폴리아스파르트산의 염을 제조하는 방법.
  5. 제4항에 있어서, 푸마르산과 암모니아를 220 내지 300℃로 가열시키고, 이 온도를 0 내지 4시간 동안 유지시킴을 특징으로 하여 폴리아스파르트산의 염을 제조하는 방법.
  6. 제4항에 있어서, 푸마르산과 암모니아를 240 내지 300℃로 가열하고, 이 온도를 0 내지 4시간 동안 유지시킴을 특징으로 하여 폴리아스파르트산의 염을 제조하는 방법.
  7. 말레산 및 푸마르산으로 이루어진 구룹중에서 선택된 산을 암모니아와 1:1 내지 2.1의 몰 비로 200 내지 300℃에서 반응시킴을 포함하여 폴리석신이미드를 제조하는 방법.
  8. 제1항에 있어서, 수산화물을 수산화 나트륨, 수산화 칼륨 및 수산화 암모늄으로 이루어진 그룹중에서 선택하는 방법.
  9. 제4항에 있어서, 수산화물을 수산화 나트륨, 수산화 칼륨 및 수산화 암모늄 이루어진 그룹중에서 선택하는 방법.
  10. 말레산과 암모니아를 1:1 내지 2.1의 몰 비로 약170 내지 350℃에서 반응시킨 후, 생성된 중합체에 알칼리 토 금속 또는 알칼리 금속 수산화물 또는 수산화 암모늄을 가하여 염으로 전화시킴을 포함하여 폴리아스카르트산의 염을 제조하는 방법.
  11. 제10항에 있어서, 반응을 약200 내지 300℃에서 수행하는 방법.
  12. 제10항에 있어서, 반응을 약240 내지 300℃에서 수행하는 방법.
  13. 제10항에 있어서, 알칼리 금속 수산화물이 수산화 나트륨인 방법.
  14. 푸마르산과 암모니아를 1:1 내지 2.1의 몰 비로 약200 내지 300℃에서 반응시킨 후, 생성된 중합체에 알칼리 토 금속 또는 알칼리 금속 수산화물 또는 수산화 암모늄을 가하여 염으로 전환시킴을 포함하여 폴리아스카르트산의 염을 제조하는 방법.
  15. 제14항에 있어서, 반응을 약240 내지 300℃에서 수행하는 방법.
  16. 제14항에 있어서, 알칼리 금속 수산화물이 수산화 나트륨인 방법.
  17. 모노암모늄 말레에이트의 수용액을 약 160 내지 200℃에서 압출시킨 후, 생성된 중합체에 알칼리 토 금속 또는 알칼리 금속 수산화물 또는 수산화 암모늄을 가하여 염으로 전환시킴을 포함하여 폴리아스파르트산의 염을 제조하는 방법.
  18. 제17항에 있어서, 알칼리 금속 수산화물이 수산화 나트륨인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940704048A 1992-05-14 1993-05-07 고온 반응에 의한 폴리아스파르트산염의 제조방법 및 이의 중간체인 폴리석신이미드의 제조방법 KR100264498B1 (ko)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US88291992A 1992-05-14 1992-05-14
US7/882919 1992-05-14
US?07/882,919? 1992-05-14
US8/007376 1993-01-21
US08/007,376 US5288783A (en) 1992-05-14 1993-01-21 Preparation of salt of polyaspartic acid by high temperature reaction
US?08/007,376? 1993-01-21
PCT/US1993/004343 WO1993023452A1 (en) 1992-05-14 1993-05-07 Salts of polyaspartic acid by high temperature reaction

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KR950701657A true KR950701657A (ko) 1995-04-28
KR100264498B1 KR100264498B1 (ko) 2000-09-01

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US (4) US5288783A (ko)
EP (2) EP0641364B1 (ko)
JP (1) JP3220152B2 (ko)
KR (1) KR100264498B1 (ko)
AT (2) ATE204593T1 (ko)
AU (1) AU674144B2 (ko)
CA (1) CA2135638C (ko)
DE (2) DE69330641T2 (ko)
DK (2) DK0641364T3 (ko)
ES (2) ES2241540T3 (ko)
NO (1) NO307185B1 (ko)
PT (1) PT641364E (ko)
WO (1) WO1993023452A1 (ko)

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DE69330641T2 (de) 2002-03-07
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DK0641364T3 (da) 2001-11-05
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DE69333816T2 (de) 2006-02-02
US5773565A (en) 1998-06-30
KR100264498B1 (ko) 2000-09-01
EP0641364B1 (en) 2001-08-22
EP1085033A2 (en) 2001-03-21
DE69333816D1 (de) 2005-06-23
ES2241540T3 (es) 2005-11-01
CA2135638C (en) 2003-08-05
ATE295863T1 (de) 2005-06-15
NO944224L (no) 1994-11-04
JP3220152B2 (ja) 2001-10-22
US6072025A (en) 2000-06-06
EP0641364A4 (en) 1995-01-10
DE69330641D1 (de) 2001-09-27
DK1085033T3 (da) 2005-07-25
AU4239393A (en) 1993-12-13
CA2135638A1 (en) 1993-11-25
US5367047A (en) 1994-11-22
EP1085033B1 (en) 2005-05-18
EP1085033A3 (en) 2002-07-03
NO944224D0 (no) 1994-11-04
EP0641364A1 (en) 1995-03-08
ATE204593T1 (de) 2001-09-15
AU674144B2 (en) 1996-12-12
JPH07509019A (ja) 1995-10-05
ES2161717T3 (es) 2001-12-16
WO1993023452A1 (en) 1993-11-25

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