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KR890002833B1 - A process for the producing solid fuel - Google Patents

A process for the producing solid fuel Download PDF

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Publication number
KR890002833B1
KR890002833B1 KR1019860011326A KR860011326A KR890002833B1 KR 890002833 B1 KR890002833 B1 KR 890002833B1 KR 1019860011326 A KR1019860011326 A KR 1019860011326A KR 860011326 A KR860011326 A KR 860011326A KR 890002833 B1 KR890002833 B1 KR 890002833B1
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South Korea
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parts
weight
sawdust
ignition
potassium
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KR1019860011326A
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Korean (ko)
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KR880007702A (en
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심재석
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심재석
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L11/00Manufacture of firelighters
    • C10L11/04Manufacture of firelighters consisting of combustible material

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Manufacturing & Machinery (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The solid fuel is prepd. by heat-compressive molding. The fuel consisting of (1) an upper ignition layer composed of sawdust 100 wt. parts, barium acetate 20-50 wt. parts, potassium acetate 0-10 wt. parts, and paraffin wax 1-2 wt. parts, and (2) fuel main body:composed of sawdust 100 wt. parts, potassium permanganate 0.005- 5 wt. parts, potassium dichromate 0.005-5 wt. parts, potassium acetate 0.05-5 parts, zeolite 0.02-5 wt. parts and paraffin wax 0.1-5 wt. parts.

Description

고형 연료의 제조방법Solid Fuel Production Method

본 발명은 톱밥을 주원료로 하는 고형 연료 특히 건조 톱밥을 고형화한 착화탄 또는 바섹크탄 형태의 고형연료에 관한 것이다.The present invention relates to a solid fuel having sawdust as a main raw material, in particular, a solid fuel in the form of a complex coal or a bassek charcoal obtained by solidifying dry sawdust.

종래 대부분의 고형연료는 무연탄분, 목탄분, 톱밥숯 왕겨숯을 단독으로 또는 적당한 비율로 혼합하고 이에 점화제, 조연제등의 첨가제를 가하여 착화를 쉽게하고 고형연료의 열량을 높이거나 연소시간을 장시간으로 하려는 시도가 있었으며, 종래의 착화탄은 불쏘시개용으로 그 사용이대중화되어있고통상 그 원료는 톱밥숯 및 기타 탄(소)분을 접착제 접결제를 사용하여 가압성형한 것으로 점화제로서 초산소다(일명 초석)를 다량 배합한 것을 점화층으로 한 것이 사용되어 왔다. 그러나 이러한 종래의 고형원료 및 착화탄을 점회시 유독가스가 다량 발생하고, 또한 탄 자체가 흡습성을 가져 장기 보관상 문제가 있으며 품질상 문제가 많았다.Most conventional solid fuels are mixed with anthracite coal, charcoal powder, sawdust charcoal chaff charcoal alone or in an appropriate ratio, and by adding additives such as ignition agent and auxiliaries, it is easy to ignite and increase the heat of solid fuel or burn time. Attempts have been made for a long time, and the conventional ignition coal has been popularized for fire extinguishing. Generally, the raw material is press-molded sawdust charcoal and other charcoal powder using an adhesive binder. What used as a ignition layer what mix | blended a large amount of soda (aka cornerstone) has been used. However, when the conventional solid raw materials and the ignition coal ignited, a large amount of toxic gas is generated, and the coal itself has hygroscopicity, which causes long-term storage problems and quality problems.

이러한 종래의 착화탄이나 소형탄이 분탄, 각종춧을 한가지를 사용하거나 또는 혼합하여 사용하거나 또는 조연제 점화제를 혼합하여 제조함에 비하여 본 발명의 소형연료 또는 착화탄은 목재 가공시 얻어지는 톱밥을 건조시켜 수분함유량을 3 내지 10% 양호하게는 5 내지 7%로 한것을 주원료로 하여 조연제, 점화제로서 초산 바리륨, 초산칼륨 환제로서 파라핀 왁스를 사용한 것을 점화층으로 하고, 동체부는 과망간산 칼륨, 중크롬산 칼륨, 초산칼륨, 제오라이트, 파라핀왁스를 조연제 및 활제로 사용하여 혼합, 가압성형하여 차고하탄 또는 소형 연료를 제조한다. 즉 본 발명에서는 복재의 톱밥을 턴낼식 건조시(로내 최고온도 150℃) 또는 기타 건조장치로 건조시켜 수분 함유량이 3 내지 15% 바림직하게는 약 6%로 될때까지 건조하고 고형연료 또는 착화탄의 상부로부터 점화층과 통체부로 구성하여 점화층은 건조톱밥 100중량부에 대하여 초산 바리윰 20 내지 50중량부 양호하게는 24 내지 30중량부, 초산 칼륨 내지 10중량부, 양호하게는 4 내지 5중량부 및 파라핀왁스 1 내지 2중량부를 가하여 혼합하고 동체부는 건조톱밥 100중량부에 대하여 과망간산칼륨 0.005내지 5중량부 양호하게는 0.01 내지 0.02중량부, 중크롬산칼륨 0.005 내지 5중량부 양호하게는 0.01 내지 0.02중량부, 초산칼륨 0.05 내지 5중량부 양호하게는 1중량부, 제오라이트 0.2 내지 5중량부 양호하게는 0.5중량부, 파라핀왁스 0.1 내지 5중량부 양호하게 0.5중량부를 가하여 혼합하고 이를 60 내지 150℃로 예비 가열하여 성형기의 온도를 140 내지 220℃ 양호하게는 160 내지 180℃로 가열 유지하면서(이때 성형기의 온도를 전열 또는 열 매체유를 사용하여 가열 유지한다) 가압 성형한다. 이때 가열 및 가압에 의하여 톱밥에서 용출되는 로진 등과 파라핀왁스에 의하여 성형품(제품) 외피에 발수성 피막이 형성된다. 성형시 점화층과 동체부의 조성비는 5 내지 20 : 80 내지 95 양호하게는 10 : 90의 비율로 하여 제조한다.The compact fuel or complex coal of the present invention dries the sawdust obtained during wood processing, whereas the conventional complex coal or compact coal is manufactured by using one or a combination of powdered and various peppers, or by mixing a ignition agent. The water content is 3 to 10%, preferably 5 to 7%, and the main material is baririum acetate as a softener, an ignition agent, and paraffin wax as a potassium acetate pill, and the body part is potassium permanganate, Potassium dichromate, potassium acetate, zeolite, paraffin wax are mixed and press-molded using a softener and a lubricant to produce a garage or small fuel. In other words, in the present invention, the sawdust of the composite material is dried by a turn-on drying method (150 ° C maximum temperature in a furnace) or other drying device, and dried until the moisture content is 3 to 15%, preferably about 6%, and solid fuel or ignition coal. The ignition layer is composed of an ignition layer and a tubular portion from the top of 20 to 50 parts by weight, preferably 24 to 30 parts by weight, potassium to 10 parts by weight, and preferably 4 to 5 parts by weight of bariacetic acid per 100 parts by weight of dry sawdust. 1 part by weight and 1 part by weight of paraffin wax are added and mixed, and the body part is 0.005 to 5 parts by weight of potassium permanganate, preferably 0.01 to 0.02 parts by weight, and 0.005 to 5 parts by weight of potassium dichromate, preferably 0.01 to 1 part by weight of dry sawdust. 0.02 parts by weight, potassium acetate 0.05-5 parts by weight preferably 1 part by weight, zeolite 0.2-5 parts by weight preferably 0.5 parts by weight, paraffin wax 0.1-5 parts by weight preferably 0.5 parts by weight By mixing and preheating it to 60 to 150 ° C. to pressurize the molding machine while maintaining the temperature of the molding machine at 140 to 220 ° C., preferably 160 to 180 ° C. (at this time, the temperature of the molding machine is maintained by using heat transfer or heat medium oil). Mold. At this time, a water-repellent coating is formed on the outer shell of the molded article (product) by rosin and paraffin wax eluted from sawdust by heating and pressurization. At the time of molding, the composition ratio of the ignition layer and the body portion is prepared in a ratio of 5 to 20:80 to 95, preferably 10:90.

또한 톱밥의 수분함유량이 많으면 성형시 수증기가 발생되어 접착불량이 되어 성형이 잘 되지않으며, 파라핀왁스는 성형시 톱밥이 기계에 붙는 것을 방지하는 활제의 역할을 하면서 연소조제의 역할을하고 외형을 깨끗이 하여 톱밥 자체에서 용추되는 송진등과 함께 외피를 이루어 외부 습기를 차단하고 장기 보관시 방습층을 이룬다.In addition, if the moisture content of sawdust is high, water vapor is generated during molding, which leads to poor adhesion, and molding is not good. Paraffin wax plays a role of a combustion aid to prevent sawdust from sticking to the machine during molding and plays a role of combustion aid and cleans the appearance. It forms an outer skin with rosin etc. invaded from sawdust itself to block external moisture and forms a moisture proof layer for long term storage.

상기와 같이 제조된 고형연료는 점화층의 점화제는 고온에서 분해 인화되는 초산 바리윰(585℃에 분해)을 사용하고 초산 칼륨은 소량을 사용하므로 성형시 인화우려는 없다. 동체부의 과망산 칼륨은 240℃에서 분해하며 연소가 활발히 진행하도록 산소를 발생공급하며 중크롬산칼륨, 초산칼륨은 조연제로 사용된다. 제오라이트는 다공성으로 동체부에 산소를 공급하고 탈취효과가 있다.The solid fuel prepared as described above does not want to ignite during molding because the ignition agent of the ignition layer uses barium acetate (decomposed at 585 ° C.) which is decomposed and flammable at high temperatures, and potassium acetate is used in small amounts. Potassium permanganate in the fuselage decomposes at 240 ° C and generates oxygen to burn actively. Potassium dichromate and potassium acetate are used as a supporting agent. Zeolite is porous and supplies oxygen to the fuselage and has a deodorizing effect.

본 발명의 고형연료는 점화층의 점화력이 우수하고 동체부의 톱밥이 화광연소하여 숯이 되어 지속력이 착화탄 또는 고형연로로서 우수하다.The solid fuel of the present invention is excellent in the ignition power of the ignition layer, the sawdust of the fuselage of the fuselage of the fuselage is charcoal, the durability is excellent as a ignition coal or solid fuel.

[실시예 1]Example 1

톱밥을 턴넬식 리본 혼합건조 장치로 가열 건조시켜 수분 함유량이 약 6%가 되게한다. 이를 약 60℃로 유지하면서 다음 조성(표1)으로 조성하여 온도 160 내지 180℃로 유지하는 성형기로 점화층(상층)을 약 3mm 동체부를 27mm로 가압 성형한다.The sawdust is heated and dried by means of a turnnel ribbon mixing dryer to achieve a moisture content of about 6%. While maintaining this at about 60 ℃ to form the next composition (Table 1) to maintain a temperature of 160 to 180 ℃ by pressing the ignition layer (upper layer) of about 3mm body part to 27mm.

[표 1]TABLE 1

Figure kpo00001
Figure kpo00001

상기한 바와같이 제조한 본 발명의 착화탄을 성냥불로 점화시커니 신속하고 용이하게 점화가 되었으며, 점화층에서의 동체부로의 연소가 연결되었으며 악취 유해가스의 발생이 없이 활발히 화공 연소 되었으며 종래의 연탄에의 착화연결이 잘 되었다.The ignition coal of the present invention manufactured as described above was ignited with a match fire, and it was ignited quickly and easily, the combustion to the fuselage in the ignition layer was connected, and active combustion was carried out without generation of odorous harmful gas, and conventional briquettes Ignition connection to was good.

[실시예 2]Example 2

다음 표 2와 같은 조성으로 제조하여 실험한 결과 실시예 1과 같을 결과를 얻을 수 있었다.As a result of preparing and experimenting with the composition shown in Table 2, the same results as in Example 1 were obtained.

종래 착화탄에 있어서는 초산카칼을 30중량부 사용하여 점화층을 제조할 경우 흑연(黑煙), 검붉은 불꽃, 악취가 발생하였으나 본 발명의 경우는 톱밥과 파라핀 왁스를 같이 사용함으로써 폭발적 연소를 억제시키면서 조연제의 역활을 하여 공해가 없이 화공 연소됨을 볼 수 있었다.In the conventional ignition coal, when the ignition layer is manufactured by using 30 parts by weight of cakal acetate, graphite, dark red flames, and odor are generated. However, in the present invention, explosive combustion is suppressed by using sawdust and paraffin wax together. While acting as a flame retardant, it could be seen that the combustion without chemical pollution.

[표 2]TABLE 2

Figure kpo00002
Figure kpo00002

이상과 같은 본 발명의 고체 연료는 레저용 연료, 착화불씨, 숯대용으로 사용할 수 있으며 점화층을 없이 제조한 동체부만의 고형연료는 숯 조개탄, 과탄 대용으로 사용할 수 있으며 특기할 것은 본 고형연료가 연소시작할때 연소공간을 조절하면 심한 백연이 동반되며 양초가 꺼질때 비슷한 냄새가 가정 연탄 착화시 사용하면 연탄가스가 누출되는 곳을 발견할 수가 있는 가스 발견탄으로 사용할 수 있다.Solid fuel of the present invention as described above can be used for leisure fuel, ignition embers, charcoal bar, solid fuel only manufactured without ignition layer can be used as a substitute for charcoal briquettes and charcoal. If the combustion space is controlled at the start of combustion, severe white smoke is accompanied, and when the candles are turned off, a similar smell can be used as a gas detector to find a place where briquette gas leaks when used for ignition of home briquettes.

Claims (3)

건조톱밥과 첨가제를 사용하여 상부 점화층을 건조톱밥 100중량부당 초산바리움 20 내지 50중량부, 초산칼륨 0 내지 10중량부 및 파라핀왁스 1 내지 2중량부로서 조성하고, 연료 동체부를 건조톱밥 100중량부에 대하여 과망간산칼륨 0.005 내지 5중량부, 중크롬산칼륨 0.005 내지 5중량부, 초산칼륨 0.05 내지 5중량부, 제오라이트 0.02 내지 5중량부 파라핀왁스 0.1 내지 5중량부를 가하여 조성혼합한 것을 가열 압착 성형하여 제조하는 소형연료 또는 착화탄의 제조방법.Using the dry sawdust and additives, the upper ignition layer is formed as 20 to 50 parts by weight of barium acetate, 0 to 10 parts by weight of potassium acetate and 1 to 2 parts by weight of paraffin wax per 100 parts by weight of dry sawdust, and the fuel fuselage part is 100 parts by weight of dry sawdust. It is prepared by heating and compression molding the composition mixture by adding 0.005 to 5 parts by weight of potassium permanganate, 0.005 to 5 parts by weight of potassium dichromate, 0.05 to 5 parts by weight of potassium acetate, and 0.1 to 5 parts by weight of zeolite 0.02 to 5 parts by weight of paraffin wax. Method for producing small fuel or ignition coal. 제 1 항에 있어서, 각층의 조성비를 점화층 10% 대 동체부 90%로 구성하고 건조톱밥 100중량부에 대하여 그 조성을 점화층은 초산칼륨 20 내지 40중량부, 파라핀왁스 2 내지 5중량부로 조성하고 동체부는 파라픽왁스 1 내지 5중량부로 조성하는 소형 연료-착화탄 또는 가스 발견탄의 제조방법.According to claim 1, wherein the composition ratio of each layer is composed of 10% of the ignition layer to 90% of the fuselage part, and the composition of the ignition layer is 20 to 40 parts by weight of potassium acetate and 2 to 5 parts by weight of paraffin wax with respect to 100 parts by weight of dried sawdust. And the fuselage part is made of 1 to 5 parts by weight of parapic wax. 제 1 항에 있어서, 건조톱밥의 수분함유량을 6%이하로 하고전 공정에서 톱밥의 온도를 150-℃로 유지하면서 성형기 금형의 온도를 140 내지 220℃로 하여 점화층만으로서 구성하거나 연료 동체부난으로서 구성하여 악착성형하는 소형연료 또는 착화탄의 제조방법.The method according to claim 1, wherein the moisture content of the dry sawdust is 6% or less and the mold saw mold temperature is 140-220 ° C. while maintaining the sawdust temperature at 150- ° C. in the previous step. Method for producing small fuel or complex coal to form and adhere.
KR1019860011326A 1986-12-27 1986-12-27 A process for the producing solid fuel KR890002833B1 (en)

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