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KR880001756A - 멀티로우벌 중합체조성물 - Google Patents

멀티로우벌 중합체조성물 Download PDF

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KR880001756A
KR880001756A KR1019870007526A KR870007526A KR880001756A KR 880001756 A KR880001756 A KR 880001756A KR 1019870007526 A KR1019870007526 A KR 1019870007526A KR 870007526 A KR870007526 A KR 870007526A KR 880001756 A KR880001756 A KR 880001756A
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코발스키_ 알렉산더
죤 윌진스키 죠셉
미첼 브랑켄쉽 로버트
첸-슝추
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윌리엄 이.램버트 3세
롬 앤드 하스 캄파니
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    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902—Core-shell
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    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

내용 없음

Description

멀티로우벌 중합체조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도:본 발명에 따라 제조된 멀티로우벌 중합체입자 함유 수성분산액의 팽윤전 암시야광학현미경 사진.
제2도:본 발명에 따라 제조된 멀티로우벌 중합체입자 함유 수성분산액의 명시야광학현미경 사진.
제3도:본 발명에 따라 제조되고 85℃에서 암모니아와 함께 중화된 멀티로우벌 중합체입자 함유수성 분산액의 명시야 광학현미경 사진.

Claims (30)

  1. 로우브들에 의하여 둘러싸인 중심코어를 갖는 중합체입자들을 함유하는 수성 분산액으로 구성된,결합제나 도료 및 접착제 조성물에 유용한 멀티로우벌 중합체조성물.
  2. 제1항에 있어서, 상기 로우브들이 광학 현미경에 의하여 관찰가능한 크기의 것임을 특징으로 하는 조성물.
  3. 제1항에 있어서, 상기 로우브들이 사산화루테늄 처리후 주사전자현미경에 의하여 관찰가능한 크기의 것임을 특징으로 하는 조성물.
  4. 제1항에 있어서, 중심코어가 중화시 팽윤되어지는 중합체임을 특징으로 하는 조성물.
  5. 제1항에 있어서, 중심코어가 카르복시산 기능기를 가진 불포화단량체를 포함하는 단량체조성물로부터 중합된 것임을 특징으로 하는 조성물.
  6. 제5항에 있어서, 상기 카르복시산 기능기를 가진 불포와 단량체가 메타크릴산이나 아크릴산임을 특징으로 하는 조성물.
  7. 제5항에 있어서,상기 카르복시산 기능기를 가진 불포화 단량체가 코어 단량체 조성물의 1-100%를 구성함을 특징으로 하는 조성물.
  8. 제7항에 있어서,상기 카르복시산 기능기를 가진 불포화 단량체가 코어 단량체 조성물의 20-50%를 구성함을 특징으로 하는 조성물.
  9. 제1항에 있어서, 중심코어가 기능기를 가진 단량체들로 구성된 단량체 조성물로부터 중합된 것임을 특징으로 하는 조성물.
  10. 제1항에 있어서, 중심코어는 코어단량체조성물로부터 중합된 중합체이고,로우브들은 로우브형성 단량체조성물로부터 중합된 중합체이며, 상기 두가지 중합체는 0.05이상 차이가 나는 상호작용 파라이터를 가짐을 특징으로 하는 조성물.
  11. 제1항에 있어서,상기 중합체 입자들이 코어단량체 조성물의 중합에 의하여 중심코어를 형성하고 이어, 로우브구조의 유지를 위하여 충반한 계면활성제 존재하에서 로우브 형성 단량체 조성물을 중합하여 코어에 도입하는 방법에 의하여 제조된 것임을 특징으로 하는 조성물.
  12. 제11항에 있어서, 상기 계면 활성제가 로우브형성단량체 조성물의 부가동안 연속적으로 첨가되는 방법에 의하여 제조된 것임을 특징으로 하는 조성물.
  13. 제11항에 있어서, 계면활성제가 로우브 형성단량체 조성물의 0.4~0.7wt%수준으로 첨가되는 방법에 의하여 제조된 것임을 특징으로 하는 조성물.
  14. 제11항에 있어서, 코어단량체 조성물이 0.01~10wt%의 교차결합성 단량체를 포함하는 것임을 특징으로 하는 조성물.
  15. 제14항에 있어서, 상기 교차결합성 단량체가 에틸렌글리콜 디메타크릴레이트 알릴 메타크릴레이트 1,3-부탄디올 디메타크릴레이트, 디에티렌 글리콜 디메타크릴데이트, 트리메틸올 프로판 트리메타 크릴레이트 및 디비닐벤젠으로 구성된 그룹으로부터 선택된 것임을 특징으로 하는 조성물.
  16. 제1항에 있어서, 상기 중합체입자들에 있어서 중심코어대 로우브 중량비가 1:2내지 1:500인것임을 특징으로 하는 조성물.
  17. 제1항에 있어서, 상기 중합체입자에 있어서, 로우브가 중심코어에 부착 내지 결합된 것임을 특징으로 하는 조성물.
  18. 제1항에 있어서, 중심코어가 15℃이상의 유리전이온도를 갖는 것임을 특징으로 하는 조성물.
  19. 제18항에 있어서, 중심코어가 100℃이상의 유리전이온도를 갖는 것임을 특징으로 하는 조성물.
  20. 제1항에 있어서, 중심코어가 0.05-1.5미크론의 직경을 갖는 것임을 특징으로 하는 조성물.
  21. 제1항에 있어서, 로우브가 스티렌을 하뮤한 로우브형성 단량제조성물로부터 중합된 것임을 특징으로 하는 조성물,
  22. 제1항에 기재한 조성물을 포함하여 구성된 결합제 도료 또는 접착제 조성물.
  23. 제22항에 기재한 도료 조성물에 의하여 도포된 물품.
  24. 제22항에 기재한 접착제 조성물에 의하여 접착된 물품.
  25. 제22항에 있어서, 통상의 결합제를 포함하는 조성물.
  26. 기존의 구상입자 조성물과 비교시 정해진 고체함량수준에서 향상된 필름성형성을 가지며 정해진 필름 형성수준에서 더낮은 고체함량을 필요로하는 결합제, 도료, 접착제 또는 그성분으로서의 제1항에 기재한 조성물의 용도.
  27. 기존의 구상입자 조성물에 비하여 향상된 습윤점착성을 갖는 접착제로서의 제1항에 기재한 조성물의 용도.
  28. 중심코어에 대한 중량비로 1이상되는 양의 로우브형성단량체조성물을 중심코어 입자상에서 중합생장시킴을 특징으로 하는, 제1항에 기재한 조성물의 제조방법.
  29. 제28항에 있어서, 로우브형성 단량체 조성물의 공급개시후 반응이 계속되는 동안 구조를 유지시키기위하여 충분한 계면활성제를 첨가함을 특징으로하는 제조방법.
  30. 제29항에 있어서, 상기 계면활성제가 로우브형성단량체조성물이 부가되는 동안 연속적으로 첨가됨을 특징으로하는 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870007526A 1986-07-14 1987-07-13 멀티로우벌 중합체 입자를 함유한 조성물 및 그 제조방법 KR960010839B1 (ko)

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US5204388A (en) * 1988-04-13 1993-04-20 Crown Decorative Products Limited Aqueous surface coating material prepared by emulsion polymerization
US5288771A (en) * 1988-06-15 1994-02-22 Kansai Paint Company, Limited Water-dispersible core-shell resin which exhibits excellent sagging resistance in coatings
GB9007199D0 (en) * 1990-03-30 1990-05-30 Tioxide Group Plc Preparation of polymeric particles
EP0467646B2 (en) * 1990-07-16 2006-05-17 Mitsui Chemicals, Inc. Process for the preparation of multi-shell emulsion particles
US5492966A (en) * 1992-04-03 1996-02-20 General Electric Company Impact modified resin compositions containing lobed graft copolymers and process for the making thereof
US5534310A (en) * 1994-08-17 1996-07-09 Rohm And Haas Company Method of improving adhesive of durable coatings on weathered substrates
FR2724843A1 (fr) 1994-09-28 1996-03-29 Lvmh Rech Vernis a ongles contenant des microgels
US6462109B1 (en) * 1999-10-12 2002-10-08 Eastman Chemical Company Surfactantless latex compositions and methods of making polymer blends using these compositions
MXPA01008706A (es) * 2000-09-03 2004-08-12 Rohm & Haas Sistemas aditivos polimericos altos en solidos: composiciones, procesos y productos de los mismos.
MXPA01008705A (es) * 2000-09-03 2004-08-12 Rohm & Haas Sistemas de aditivos polimericos multiples: composiciones, procesos y productos derivados.
MXPA01008532A (es) * 2000-09-03 2002-08-06 Rohm & Haas Sistema de acitivos funcionales de liquidos-solidos; sus composiciones, procesos y productos.
US6750050B2 (en) * 2000-10-19 2004-06-15 Rohm And Haas Company Porous non-friable polymer film
JP2003277455A (ja) * 2002-03-25 2003-10-02 Jsr Corp ポリマー粒子の製造方法、ポリマー粒子および生理活性物質担体
US7179531B2 (en) * 2002-09-12 2007-02-20 Rohm And Haas Company Polymer particles having select pendant groups and composition prepared therefrom
WO2005014805A1 (en) * 2003-08-08 2005-02-17 Regents Of The University Of Minnesota A structured material for the production of hydrogen
DE602005000882T2 (de) * 2005-09-14 2008-01-17 National Starch And Chemical Investment Holding Corporation, New Castle Neue wässrige Klebstoffe für gewerbliche Anwendungen
JP5487530B2 (ja) * 2006-01-27 2014-05-07 Ｊｓｒ株式会社 異形粒子、異形粒子組成物及びその製造方法、並びに光拡散成形品
CN101085884A (zh) * 2006-06-06 2007-12-12 罗门哈斯公司 可剥离涂料和工艺
US9878272B2 (en) 2010-05-28 2018-01-30 Corning Incorporated Porous inorganic membranes and method of manufacture
CN103764726B (zh) * 2011-08-30 2015-11-25 巴斯夫欧洲公司 用于不透明膜和涂层应用的水基聚合物乳液
TWI477521B (zh) * 2011-10-28 2015-03-21 Rohm & Haas 有用於懸浮粒子的網絡聚合物

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB847602A (en) * 1957-03-19 1960-09-07 Monsanto Chemicals Process of polymerisation
US2962465A (en) * 1958-01-22 1960-11-29 Monsanto Chemicals Production of acrylate interpolymer aqueous latices
NL133104C (ko) * 1961-09-22
GB1062338A (en) * 1963-11-19 1967-03-22 Dunlop Rubber Co Improvements in or relating to acrylic polymer emulsions
US3282876A (en) * 1964-04-13 1966-11-01 Monsanto Co Polymer latices comprising alpha, betaethylenically unsaturated monocarboxylic acids and copolymerizable monomers
US3297621A (en) * 1965-01-04 1967-01-10 Archer Daniels Midland Co Two step polymerization of tetrapolymer
GB1177778A (en) * 1967-09-08 1970-01-14 Ici Ltd Copolymers of Vinyl Acetate
US3784498A (en) * 1972-04-21 1974-01-08 Sinclair Koppers Co Process for preparing low emulsifier synthetic latex
DE2228515B1 (de) * 1972-06-12 1974-02-14 Röhm GmbH, 6100 Darmstadt Verfahren zur herstellung von polyacrylatdispersionen
US4150005A (en) * 1977-03-17 1979-04-17 Rohm And Haas Company Internally plasticized polymer latex
US4134872A (en) * 1977-05-20 1979-01-16 The Dow Chemical Company Heterogeneous polymer particles comprising an interpolymer domain of a monovinylidene aromatic monomer, an open chain aliphatic conjugated diene and a monoethylenically unsaturated acid
US4151143A (en) * 1977-08-19 1979-04-24 American Cyanamid Company Surfactant-free polymer emulsion coating composition and method for preparing same
US4308912A (en) * 1979-03-28 1982-01-05 Knecht Bernath L Heat transfer system
CA1180474A (en) * 1979-06-26 1985-01-02 Alexander Kowalski Sequential heteropolymer dispersion and a particulate material obtainable therefrom useful in coating compositions as a thickening and/or opacifying agent
JPS5655414A (en) * 1979-10-11 1981-05-16 Japan Synthetic Rubber Co Ltd Polymer particle
US4325856A (en) * 1980-01-02 1982-04-20 The Dow Chemical Company Sequential emulsion polymerization process
US4468498A (en) * 1980-06-12 1984-08-28 Rohm And Haas Company Sequential heteropolymer dispersion and a particulate materal obtainable therefrom, useful in coating compositions as a thickening and/or opacifying agent
US4427836A (en) * 1980-06-12 1984-01-24 Rohm And Haas Company Sequential heteropolymer dispersion and a particulate material obtainable therefrom, useful in coating compositions as a thickening and/or opacifying agent
US4504605A (en) * 1982-12-20 1985-03-12 The Standard Oil Company Film-forming olefinic nitrile polymer latex and method of preparing same
US4469825A (en) * 1983-03-09 1984-09-04 Rohm And Haas Company Sequential heteropolymer dispersion and a particulate material obtainable therefrom, useful in coating compositions as an opacifying agent
US4474923A (en) * 1983-06-14 1984-10-02 The Dow Chemical Company Self-curable latex compositions
US4594363A (en) * 1985-01-11 1986-06-10 Rohm And Haas Company Production of core-sheath polymer particles containing voids, resulting product and use
JPH062792B2 (ja) * 1985-05-10 1994-01-12 三菱レイヨン株式会社 熱可塑性樹脂用滑剤

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ZA875040B (en) 1988-03-30
FR2601374B1 (fr) 1993-05-14
DE3787934T2 (de) 1994-03-17
CN87104813A (zh) 1988-02-10
SE8702861L (sv) 1988-01-15
CA1299306C (en) 1992-04-21
IE871783L (en) 1988-01-14
IE64649B1 (en) 1995-08-23
JPH07103205B2 (ja) 1995-11-08
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FI95916B (fi) 1995-12-29
GB2194543B (en) 1990-03-21
PH23886A (en) 1989-12-18
HK35494A (en) 1994-04-22
US4791151A (en) 1988-12-13
DE3723274A1 (de) 1988-01-28
MY102137A (en) 1992-04-30
AU606875B2 (en) 1991-02-21
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IL83166A0 (en) 1987-12-31
NO872900L (no) 1988-01-15
TR25880A (tr) 1993-09-02
KR960010839B1 (ko) 1996-08-09
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BE1002557A5 (fr) 1991-03-26
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NO872900D0 (no) 1987-07-13
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EP0254467B1 (en) 1993-10-27
IT8767610A0 (it) 1987-07-14
LU86940A1 (fr) 1987-12-07
CN1027170C (zh) 1994-12-28
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IT1211341B (it) 1989-10-18
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