KR20230040145A - Liquid hydrogen storage container and marine transportation means including the same - Google Patents

Abstract

The present invention provides a liquefied hydrogen storage container and a marine transportation means including the same. The liquefied hydrogen storage container comprises: a primary barrier which performs primary airtightness while directly contacting liquefied hydrogen stored therein; an insulating space which is formed of at least one layer on the outside of the primary barrier and filled with an insulating material therein; a cryogenic heat-blocking layer which is formed on the outside of the insulating space and contains liquefied nitrogen or LNG as a liquefied gas for heat-blocking in an inner space; and a final insulation layer which is formed on the outside of the cryogenic heat-blocking layer. The level of the heat-blocking liquefied gas is maintained to be higher than the uppermost layer of a structure dividing the insulating space. According to the present invention, the evaporation rate of liquefied hydrogen is significantly reduced, thereby minimizing energy loss during maritime transportation of hydrogen.

Description

Liquid hydrogen storage container and marine transportation means including the same

The present invention relates to a liquefied hydrogen storage container and a maritime transportation means including the same, and more particularly, to a liquefied hydrogen storage container optimized for storing and transporting hydrogen having a very low boiling point and a maritime transportation means including the same.

In general, hydrogen transportation can be largely divided into inland transportation and sea transportation. Hydrogen transportation inland can be carried out using pipelines, dedicated transport vehicles or railroads, and transportation of hydrogen on the sea can be carried out by ships equipped with special storage facilities.

A common feature of hydrogen transportation through inland and sea is that it is carried out by means of transportation equipped with special storage facilities capable of storing hydrogen. In particular, in the case of transportation means equipped with storage facilities capable of storing and transporting hydrogen, it is a general opinion that it is desirable to liquefy hydrogen in a gaseous state by cooling and/or pressurizing it and storing and transporting it in a liquid state for efficient transportation of hydrogen. am.

As a technology for storing liquefied hydrogen, that is, liquefied hydrogen, various technologies can be applied. The membrane type tank technology, which is applied both at sea and on land, and the independent tank technology, which is mainly applied at sea, can be applied. type tank) technology may be considered. In the case of an independent tank, it can be divided into a Type C tank referred to as a pressure vessel, a Type A tank and a Type B tank, which are atmospheric tanks.

The above storage technologies are currently commercialized and there is no great difficulty in technically implementing them, but the above existing storage technologies are mainly designed for the storage of LNG (Liquefied Natural Gas) or LPG (Liquefied Petroleum Gas), In the case of hydrogen, since the liquefaction temperature (boiling point) is significantly lower than that of LNG or LPG, it is difficult to store and transport liquefied hydrogen without loss for a considerable period of time with the insulation method of existing storage technologies.

In order to use the existing storage technologies for the storage of liquefied hydrogen, it is essential to increase the insulation thickness of the insulation system equipped in the storage container (or storage tank) by several to several dozen times or to additionally apply high-performance insulation materials such as vacuum insulation materials. Therefore, in the end, the existing storage technologies cannot be seen as suitable technologies for the storage of liquefied hydrogen with a very low boiling point.

Since gaseous hydrogen has a boiling point of -253 degrees below zero at atmospheric pressure, it must be cooled to that temperature before it is converted from gaseous to liquid. In addition, even in a pressurized environment, the temperature at which hydrogen is liquefied is quite low, and when pressurized at about 10 barg, hydrogen can be converted into a liquid state at -242 degrees Celsius.

Due to the phase change characteristics of hydrogen, a large temperature difference of approximately 300 degrees occurs between the external conditions of the storage container close to atmospheric temperature and the inside of the storage container storing liquefied hydrogen at minus 253 degrees Celsius. The temperature difference between the inside and outside of the storage container is a factor in heat transfer, and heat penetration by the heat flux generated by the heat transfer causes boil-off of the liquefied hydrogen stored inside the storage container. .

The evaporation of liquefied hydrogen that occurs inside the storage vessel eventually comes as a loss of hydrogen during the process of storing and transporting hydrogen. In the case of a pressurized storage container, it is possible to store boil-off gas (BOG) inside the storage container within the maximum design vapor pressure designed to withstand it, but at the critical point of hydrogen If it is required to be managed early, and it is expected to exceed the allowable internal pressure due to the continuous evaporation of liquefied hydrogen, the boil-off gas must be released to the outside of the storage container.

An object of the present invention to solve the above conventional problems is to be able to store and transport hydrogen with a very low boiling point for a considerable period of time without heat loss. It is to provide a liquefied hydrogen storage container equipped with a high-performance insulation system and a maritime transportation means including the same to minimize loss due to

In order to achieve the above object, the present invention is a liquefied hydrogen storage container for storing liquefied hydrogen, a primary barrier for performing a primary airtight while in direct contact with liquefied hydrogen stored therein; a heat insulating space formed of at least one layer outside the primary barrier and filled with a heat insulating material; a cryogenic thermal barrier layer formed on the outside of the thermal insulation space and accommodating liquefied nitrogen or LNG as a liquefied gas for thermal insulation in the internal space; And a final thermal insulation layer formed on the outside of the cryogenic thermal insulation layer, characterized in that the water level of the liquefied gas for thermal insulation is maintained higher than that of the uppermost layer of the structure partitioning the thermal insulation space. can

The liquefied hydrogen storage container according to the present invention is provided at a position spaced apart by a predetermined distance from the outside of the primary barrier to form the adiabatic space, and at least one of the primary barriers corresponds to the number of the adiabatic spaces. A first partition structure sequentially installed outward; And a first support structure for supporting and securing a space between the primary barrier and the first compartment structure and between the first compartment structures adjacent to each other when the heat insulation space is formed in a plurality of layers. there is.

In addition, the liquefied hydrogen storage container according to the present invention includes a second compartment structure provided at a position spaced a predetermined distance from the outside of the first compartment structure to form the cryogenic thermal barrier layer; and a second support structure for supporting and securing a space between the first compartment structure and the second compartment structure.

Inside the insulation space, a multi-layer insulation is disposed to form an insulation layer, or a powder type or bead type insulation including hollow glass microspheres or glass bubbles is filled. Thus, an insulating layer may be formed.

The final insulation layer may be composed of any one of a vacuum insulation panel, an organic insulation material in the form of a foam including polyurethane foam, and an inorganic insulation material including glass wool. .

Alternatively, the final insulating layer further includes a separate outer layer provided at a position spaced apart from the outside of the second compartment structure by a predetermined distance, and a multi-layer thin film insulation material is disposed in the space between the second compartment structure and the outer layer. Alternatively, it may be formed in a vacuum after filling a powder or bead-type insulating material including hollow glass microspheres and glass bubbles.

The liquefied hydrogen storage container may be a pressure tank in which the primary barrier can withstand a predetermined pressure.

On the other hand, in order to achieve the above object, the present invention may provide a marine transportation means including any one of the liquefied hydrogen storage containers disclosed above.

In the maritime transportation means including the liquefied hydrogen storage container according to the present invention, a plurality of liquefied hydrogen storage containers are disposed along the longitudinal direction of the hull from the bow to the stern side, and at the rear of the liquefied hydrogen storage container disposed at the rear end. A liquefied hydrogen treatment facility for processing evaporation gas of liquefied hydrogen stored inside the liquefied hydrogen storage container and a liquefied gas processing facility for processing evaporation gas of liquefied gas for thermal insulation accommodated inside the cryogenic thermal insulation layer may be provided. .

The liquefied hydrogen treatment facility includes a re-liquefaction device for re-liquefying the boil-off gas of the liquefied hydrogen, a fuel cell for generating electricity using the boil-off gas of the liquefied hydrogen, and a boil-off gas of the liquefied hydrogen or the liquefied hydrogen itself. It may include at least one of fuel supply systems supplying fuel to the dynamometer of the maritime transportation means.

The liquefied gas treatment facility includes a re-liquefaction device for re-liquefying the boil-off gas of the liquefied gas for thermal insulation, an ammonia synthesis device for synthesizing ammonia using boil-off gas of the liquid nitrogen when the liquefied gas for heat shield is liquefied nitrogen, At least one of a fuel supply system for supplying the boil-off gas of the liquefied gas for heat-shielding or the liquefied gas for heat-shielding itself as fuel for a power system of a maritime transportation means, and an exhaust system for discharging the boil-off gas of the liquefied gas for heat-shielding outboard. can include

According to the present invention as described above, among the factors occurring during storage of liquefied hydrogen, it is possible to reduce heat intrusion due to temperature difference to 1/4 to 1/5 level compared to conventional commercialized storage technologies, and during transportation It has the effect of significantly reducing the evaporation rate (Boil-Off Rate, BOR) of liquefied hydrogen.

The present invention is particularly optimized for the storage of liquefied hydrogen with a very low boiling point and provides a liquefied hydrogen storage container equipped with a high-performance insulation system capable of storing and transporting liquefied hydrogen for a considerable period of time without heat loss. It has an economical effect that energy loss can be minimized when transporting hydrogen through marine transportation means equipped with a storage container.

The effects of the present invention are not limited to the above-mentioned effects, and other effects not mentioned will be clearly understood from the description below.

1 is a diagram schematically showing the thermal insulation structure of a liquefied hydrogen storage container according to the present invention, showing an embodiment in which the thermal insulation space is formed of a single layer.
2 is a diagram schematically showing the thermal insulation structure of the liquefied hydrogen storage container according to the present invention, showing an embodiment in which the thermal insulation space is formed of a plurality of layers.
3 is a view schematically showing the arrangement structure of a maritime transport means equipped with a liquefied hydrogen storage container according to the present invention.

In order to fully understand the present invention and the operational advantages of the present invention and the objects and effects achieved by the practice of the present invention, reference should be made to the accompanying drawings illustrating preferred embodiments of the present invention and the contents described in the accompanying drawings.

Matters represented in the drawings accompanying this specification may be somewhat different from the form actually implemented as a schematic drawing to easily explain the embodiments of the present invention, and the size of each component shown in the drawings is for explanation. They may be exaggerated or reduced and are not meant to be of actual size.

Terms used in this specification are only used to describe specific embodiments and are not intended to limit the present invention. For example, in the present specification, 'including' a certain component means that other components may be further included, rather than excluding other components unless otherwise stated.

In addition, it should be understood that saying that a component is 'connected' to another component includes a direct connection as well as an indirect connection, and another component may exist between the two components. Singular expressions may be interpreted as including plural expressions unless the context clearly dictates otherwise.

The use of the terms 'primary' and 'secondary' for the liquefied hydrogen storage container in this specification refers to whether the liquefied hydrogen is primarily sealed or insulated based on the liquefied hydrogen stored inside the storage container, or is secondarily sealed. Or it is used as a criterion for whether to insulate.

Hereinafter, the present invention will be described in detail by describing preferred embodiments of the present invention with reference to the accompanying drawings. Embodiments described below are provided so that those skilled in the art can easily understand the technical idea of the present invention, and the present invention is not limited thereby.

1 and 2 are diagrams schematically showing the thermal insulation structure of the liquefied hydrogen storage container according to the present invention, respectively showing an embodiment in which the thermal insulation space is formed of a single layer and a plurality of layers. And Figure 3 is a view schematically showing the arrangement structure of the maritime transport means equipped with a liquefied hydrogen storage container according to the present invention.

Referring to Figures 1 and 2, the liquefied hydrogen storage container 100 according to the present invention, while directly contacting the liquefied hydrogen stored therein while performing a primary airtight primary barrier (primary barrier, 110); A heat insulation space 120 formed outside the primary barrier 110; a first partition structure 130 for partitioning the insulation space 120; a cryogenic thermal barrier layer 140 formed outside the first compartment structure 130; a second partition structure 150 for partitioning the cryogenic thermal barrier layer 140; and a final insulation layer 160 formed on the outside of the second compartment structure 150 to form an insulation system.

The liquefied hydrogen storage container 100 according to the present invention may include a primary barrier 110 partitioned to directly contact liquefied hydrogen as a pressure tank. For reference, based on the standards stipulated by the International Maritime Organization (IMO), a tank designed with a design vapor pressure of 0.7 barg or less can be classified as a normal pressure tank, and the above-mentioned Membrane type tanks and Type A and B stand-alone tanks may correspond to normal pressure tanks. Conversely, a tank designed so that the design gas pressure exceeds 2.0 barg may be classified as a pressurized tank, and the aforementioned Type C independent tank may correspond to the pressurized tank. Therefore, the liquefied hydrogen storage container 100 according to the present invention may be a Type C independent tank in which the primary barrier 110 is designed to withstand a pressure exceeding 2.0 barg.

The primary barrier 110 may be made of a metal material with strong low-temperature brittleness so as to safely store cryogenic liquefied hydrogen. For example, steel materials proven to be able to store liquefied hydrogen including stainless steel are applied can

Inside the primary barrier 110, that is, inside the space where liquefied hydrogen is stored, equipment such as pipes and pumps for loading and unloading of liquefied hydrogen and equipment such as structures for fixing the pump may be provided. In addition, the inside of the primary barrier 110 may be provided with a pipe and a pressure relief valve (PRV) for discharging boil-off gas of liquefied hydrogen.

The piping for loading and unloading liquefied hydrogen inside the primary barrier 110 and the piping for discharging boil-off gas inside the primary barrier 110 include an insulation space 120, a cryogenic thermal barrier layer 140, and a final insulation layer, which will be described later. It may be configured in a form connected to the outside through 160.

An insulating space 120 is formed outside the primary barrier 110, and the thermal insulation space 120 is partitioned by the first partition structure 130 provided at a position spaced apart from the primary barrier 110 by a predetermined distance. It can be.

The insulation space 120 is formed to surround the primary barrier 110 and functions to primarily insulate liquefied hydrogen stored in the primary barrier 110 .

In the insulation space 120 , at least one layer may be formed on the outer side of the primary barrier 110 in the insulation thickness direction. That is, in the present invention, the heat insulation space 120 may be formed of a single layer or more. 1 shows an embodiment in which the heat insulation space 120 is formed of a single layer, and FIG. 2 shows an embodiment in which the heat insulation space 120 is formed of two plural layers.

When the heat insulating space 120 is formed of a plurality of layers, correspondingly, the first partition structure 130 may also be provided on the outside of each heat insulating space 120 .

As will be described later, in the present invention, the insulation space 120 may be formed in a vacuum environment, and the first compartment structure 130 may be formed to meet design conditions such as a vacuum environment formed in the insulation space 120. . That is, the first compartment structure 130 must have structural strength to withstand the vacuum pressure formed in the heat insulating space 130 .

In addition, as will be described later, the cryogenic thermal barrier layer 140 formed outside the first compartment structure 130 is a space in which cryogenic liquefied gas such as liquid nitrogen is accommodated. Therefore, the first compartment structure 130 disposed on the outermost side must be able to withstand the cryogenic temperature of the liquefied gas accommodated outside and be designed to withstand the load between the structures. It can be designed to conform to the design of the primary barrier.

This means that the first compartment structure 130 may also be made of cryogenic steel similarly to the primary barrier 110 . However, the present invention is not limited thereto, and various materials can be applied as the first compartment structure 130 as long as they can be used at cryogenic temperatures and have sufficient mechanical strength, such as, for example, fiberglass reinforced plastics (FRP).

As described above, the pressure reducing valve installed on the pipe for discharging boil-off gas generated inside the liquefied hydrogen storage container 100 may be installed at the boundary of the first compartment structure 130, and the insulation space 120 When composed of a plurality of layers, it may be installed at the boundary of the first partition structure 130 for partitioning the heat insulation space 120 formed in the innermost part.

In the insulation space 120, between the primary barrier 110 and the first compartment structure 130 or between the adjacent first compartment structures 130 (when the insulation space is formed in multiple layers) is supported and the two structures A support structure (not shown) may be installed to secure a space between them.

The support structure (not shown) may be installed in the form of a support that supports between the primary barrier 110 and the first partition structure 130 or between the first partition structures 130 adjacent to each other, and is supported Materials capable of minimizing loss due to heat transfer between the two structures, such as PCTFE (PolyChloroTriFluoroEthylene), PTFE (PolyTetraFluoroEthylene), and UHMWPE (Ultra-High-Molecular-Weight PolyEthylene), can be composed of plastic materials usable at cryogenic temperatures. .

In the insulation space 120, except for the support structure (not shown), the rest of the space is equipped with a vacuum environment so as to block heat transfer. Multi-Layer Insulation (MLI) or hollow glass microspheres ) or a glass bubble, such as a powder/bead type insulating material that can be used under a vacuum environment, so as to be configured as a heat insulating layer.

More specifically, a multilayer thin film insulation is wound within 10 to 40 layers on the outside of the primary barrier 110 or inside the first compartment structure 130, or hollow glass microspheres and glass bubbles in the insulation space 120 Similarly, a heat insulating layer may be formed in the heat insulating space 120 by filling a powder/bead heat insulating material usable in a vacuum environment. After the heat insulating layer is formed in the heat insulating space 120 , a vacuum forming operation may be performed on the inner space of the heat insulating space 120 .

When a plurality of the insulating space 120 and the first partition structure 130 are provided, a support structure (not shown) may be installed for partitioning and supporting the space for each insulating space 120, and a plurality of insulating spaces 120 may be provided. Each space 120 is formed in a vacuum environment, and a multilayer thin film insulation material or a powder type/bead type insulation material may be filled in each space.

A sensor for measuring the temperature and pressure of the corresponding space may be provided in each of the at least one insulating space 120 . In addition, a pipe for implementing a vacuum in each heat insulation space 120 may be used as a passage for discharging leaked liquefied hydrogen in case of emergency.

A cryogenic thermal barrier layer 140 may be formed on the outside of the first compartment structure 130 to minimize heat penetration into the liquefied hydrogen stored inside the storage container. If the aforementioned insulation space 120 performs primary thermal insulation of liquefied hydrogen, the cryogenic thermal barrier layer 140 can be regarded as performing secondary thermal insulation of liquefied hydrogen.

For the partitioning of the cryogenic thermal barrier layer 140, the second compartment structure 150 may be provided at a position spaced apart from the first compartment structure 130 by a predetermined distance, and in the cryogenic thermal barrier layer 140, the first compartment structure ( 130) and the second partition structure 150, a support structure (not shown) may be installed to support the space between the two.

A support structure (not shown) installed on the cryogenic thermal barrier layer 140 may also be made of a plastic material usable at cryogenic temperatures, such as PCTFE, PTFE, or UHMWPE, similarly to the one installed in the heat insulation space 120 .

Nitrogen, oxygen, or natural gas that can be stored in a liquefied state at a cryogenic temperature may be accommodated in a liquefied state in the space of the cryogenic thermal barrier layer 140 . That is, liquefied gases such as liquid nitrogen (LN ₂ ), liquid oxygen (LO ₂ ), and LNG may be accommodated in the inner space of the cryogenic thermal barrier layer 140 .

As described in the background art, in the case of liquefied hydrogen, the liquid state is maintained at minus 253 degrees Celsius under normal pressure conditions, and considering the external temperature up to 45 degrees, the temperature difference between the space where liquefied hydrogen is stored and the outside is close to 300 degrees. It happens. However, as in the present invention, when the cryogenic thermal barrier layer 140 is formed outside the space in which liquefied hydrogen is stored and the liquefied gas is filled inside the space, the temperature difference experienced by liquefied hydrogen with the outside is significantly reduced.

For example, assuming that liquid nitrogen is accommodated inside the cryogenic thermal barrier layer 140, since liquid nitrogen has a boiling point of minus 196 degrees, from the point of view of liquid hydrogen, only a temperature difference of 60 degrees or less is experienced instead of the existing 300 degrees. . That is, since the temperature difference experienced by liquefied hydrogen is reduced to 1/5 or less, it is possible to reduce the insulation by that much, or significantly reduce the evaporation rate of liquefied hydrogen by greatly reducing heat penetration even with the same insulation layer.

In the present invention, among the liquefied gases exemplified above, liquefied nitrogen, which is the safest in terms of risk and has the lowest boiling point and has a small temperature difference with liquefied hydrogen, can be most preferably considered as a liquefied gas accommodated in the cryogenic thermal barrier layer 140.

However, acceptance of other liquefied gases other than liquid nitrogen in the cryogenic thermal barrier layer 140 is not refrained from or excluded, and the difference between liquid hydrogen and boiling point is not large, such as liquid oxygen or LNG, as well as liquid nitrogen. Preferably, various liquefied gases having a boiling point lower than the average temperature between the boiling point of liquefied hydrogen and the external temperature of the liquefied hydrogen storage container 100 can be used as the liquefied gas accommodated in the cryogenic thermal barrier layer 140 .

In the case of using LNG as the liquefied gas accommodated in the space of the cryogenic thermal barrier layer 140, the liquefied hydrogen storage container 100 according to the present invention is provided for evaporation gas generated from LNG or LNG itself. Marine transportation means (1) of dynamometer fuel.

Hereinafter, in order to be more clearly distinguished from liquefied hydrogen accommodated in the primary barrier 110, the liquefied gas accommodated in the cryogenic thermal barrier layer 140 is defined as 'liquefied gas for thermal insulation' and continues the description.

The liquefied gas for thermal insulation accommodated in the cryogenic thermal barrier layer 140 divides the insulation space 120 disposed at the outermost part during the transportation period of the maritime transportation means 1 equipped with the liquefied hydrogen storage container 100 according to the present invention. The water level can be maintained higher than the uppermost part of the first compartment structure 130 to be. That is, during the transportation period of the maritime transport means 1, the upper surface of the first compartment structure 130 disposed at the outermost part should not be exposed and all surfaces should be blocked by liquefied gas for thermal insulation.

Equipment such as pipes and pumps for loading and unloading of liquefied gas for thermal insulation accommodated in the space and equipment such as a structure for fixing the pump may be provided inside the cryogenic thermal barrier layer 140 . In addition, a pipe and a pressure reducing valve for discharging boil-off gas generated from liquefied gas for thermal insulation may be provided inside the cryogenic thermal barrier layer 140 .

The piping for loading and unloading the liquefied gas for thermal insulation inside the cryogenic thermal barrier layer 140 and the piping for discharging the boil-off gas inside the cryogenic thermal barrier layer 140 pass through the final thermal insulation layer 160 to be described later and are connected to the outside. can be configured.

In addition, when the boil-off gas of the liquefied gas for thermal insulation or the liquefied gas for thermal insulation contained in the space of the cryogenic thermal barrier layer 140 is used as a fuel for the maritime transportation means 1 (for example, when the liquefied gas for thermal insulation is LNG) , The cryogenic thermal barrier layer 140 may be designed according to the design criteria corresponding to the fuel tank.

On the outer side of the second compartment structure 150 , a final thermal insulation layer 160 may be formed to minimize evaporation of liquefied gas for thermal insulation accommodated inside the cryogenic thermal barrier layer 140 .

In the present invention, the final thermal insulation layer 160 performs tertiary thermal insulation of liquefied hydrogen and at the same time blocks heat penetration into the cryogenic thermal barrier layer 140 to insulate the liquefied gas for thermal insulation contained in the space. .

As described above, a support structure (not shown) may be installed inside the second compartment structure 150 for the purpose of securing and supporting a space between the first compartment structure 130 and the second compartment structure 150. ) A fixing structure (not shown) for installing the final insulating layer 160 may be installed on the outer side of the ).

The final insulation layer 160 is a foam-type organic insulation material such as a vacuum insulation panel (VIP) or polyurethane foam or an inorganic insulation material such as glass wool for insulation under normal pressure conditions. It may be formed by constructing any one of various heat insulating materials including the like on the outer surface of the second compartment structure 150 .

Alternatively, the final insulation layer 160 may be configured as a vacuum insulation layer. In this case, a separate outer layer (not shown) may be further included to provide a multilayer thin film insulation between the second compartment structure 150 and the outer layer (not shown). The insulating layer can be formed by filling the powder/bead type insulating material to create a vacuum environment. In the latter case, it can be understood that the inside of the final insulating layer 160 is formed in a structure similar to that of the inside of the aforementioned insulating space 120 .

In forming the final thermal insulation layer 160 on the outside of the cryogenic thermal barrier layer 140, the outer structure of the cryogenic thermal barrier layer 140 is specified according to the type of liquefied gas for thermal insulation accommodated in the cryogenic thermal barrier layer 140. IGC/IGF Code), a design corresponding to this may be reflected.

On the other hand, the insulation space 120 and the cryogenic thermal barrier layer 140 must be designed to be structurally safe against the internal pressure of each space. To this end, the insulation space 120 and the cryogenic thermal barrier layer 140 A monitoring device (not shown) for monitoring pressure and a pressure regulator (not shown) may be provided together.

Referring to FIG. 3, the maritime transportation means 1 equipped with the liquefied hydrogen storage container 100 according to the present invention is related to the liquefied hydrogen stored inside the primary barrier 110 of the liquefied hydrogen storage container 100. A liquefied hydrogen processing facility 200 that performs processing and a liquefied gas processing facility 300 that performs processing related to the liquefied gas for thermal insulation accommodated in the space of the cryogenic thermal barrier layer 140 may be provided.

The liquefied hydrogen processing facility 200 includes a re-liquefaction device for re-liquefying liquefied hydrogen boil-off gas, a fuel cell for generating electricity using boil-off gas of liquefied hydrogen, and synthesis of other substances using boil-off gas of liquefied hydrogen. and a fuel supply system for supplying liquefied hydrogen boil-off gas or liquefied hydrogen itself as fuel to the power system of the maritime transportation means 1.

In addition, the liquefied gas treatment facility 300 is a re-liquefaction device for re-liquefying the boil-off gas of the liquefied gas for thermal insulation, and an ammonia synthesis for synthesizing ammonia using the boil-off gas of the liquid nitrogen when the liquefied gas for heat shield is liquefied nitrogen. Device, a fuel supply system for supplying boil-off gas of liquefied gas for thermal insulation or liquefied gas for thermal insulation itself as fuel for the power system of the maritime transportation means (1), and an exhaust system for discharging boil-off gas of liquefied gas for thermal insulation overboard. It may be configured to include at least one.

As shown in FIG. 3, a plurality of liquefied hydrogen storage containers 100 in which liquefied hydrogen is stored may be disposed along the longitudinal direction of the hull from the bow to the stern, and the liquefied hydrogen treatment facility 200 and the liquefied gas treatment facility (300) may be disposed on the left / starboard side of the rear of the liquefied hydrogen storage container 100, which is disposed at the rearmost part. The liquefied hydrogen treatment facility 100 and the liquefied gas treatment facility 300 may have individual functions or integrated operation (if the functions are common).

The maritime transportation means 1 according to the present invention may be a liquefied hydrogen carrier that carries liquefied hydrogen and transports it to a destination by operating the sea. However, the present invention is not limited thereto, and the technical idea of the present invention is to store liquefied hydrogen at sea for a considerable period of time, as well as for ships having self-propelling capabilities, such as liquefied hydrogen carriers, even if they do not have self-propelling capabilities. It can be applied to various floating offshore structures floating on

According to the present invention as described above, among the factors occurring during the storage of liquefied hydrogen, it is possible to reduce heat intrusion due to temperature difference to 1/4 to 1/5 compared to conventional storage technologies, It has the effect of significantly reducing the evaporation rate of liquefied hydrogen during the transportation period.

The present invention is particularly optimized for the storage of liquefied hydrogen with a very low boiling point and provides a liquefied hydrogen storage container equipped with a high-performance insulation system capable of storing and transporting liquefied hydrogen for a considerable period of time without heat loss. It has an economical effect that energy loss can be minimized when transporting hydrogen through marine transportation means equipped with a storage container.

The present invention is not limited to the described embodiments, and it is obvious to those skilled in the art that various modifications and variations can be made without departing from the spirit and scope of the present invention. Therefore, such modifications or variations should fall within the scope of the claims of the present invention.

1: Sea transport
100: liquid hydrogen storage container
110: primary barrier
120: insulation space
130: first compartment structure
140: cryogenic thermal barrier layer
150: second compartment structure
160: final insulation layer
200: liquid hydrogen treatment facility
300: liquefied gas treatment facility

Claims (11)

As a liquefied hydrogen storage container for storing liquefied hydrogen,
A primary barrier that performs primary confidentiality while in direct contact with liquefied hydrogen stored therein;
a heat insulating space formed of at least one layer outside the primary barrier and filled with a heat insulating material;
a cryogenic thermal barrier layer formed on the outside of the thermal insulation space and accommodating liquefied nitrogen or LNG as a liquefied gas for thermal insulation in the internal space; and
Including a final thermal insulation layer formed on the outside of the cryogenic thermal barrier layer,
Characterized in that the water level of the liquefied gas for thermal insulation is maintained higher than the uppermost layer of the structure partitioning the insulation space,
Liquefied hydrogen storage container. The method of claim 1,
A first compartment structure provided at a position spaced apart by a predetermined distance from the outside of the primary barrier to form the thermal insulation space, at least one of which is sequentially installed outside the primary barrier corresponding to the number of the thermal insulation spaces ; and
A first support structure for supporting and securing a space between the primary barrier and the first compartment structure and between the first compartment structures adjacent to each other when the heat insulation space is formed in a plurality of layers Further comprising,
Liquefied hydrogen storage container. The method of claim 2,
a second partition structure provided at a position spaced apart by a predetermined distance from the outside of the first partition structure to form the cryogenic thermal barrier layer; and
Further comprising a second support structure for supporting and securing a space between the first compartment structure and the second compartment structure,
Liquefied hydrogen storage container. The method of claim 3,
Inside the insulation space, a multi-layer insulation is disposed to form an insulation layer, or a powder type or bead type insulation including hollow glass microspheres or glass bubbles is filled. characterized in that a heat insulating layer is formed,
Liquefied hydrogen storage container. The method of claim 4,
The final insulation layer is composed of any one of a vacuum insulation panel, an organic insulation material in the form of a foam including polyurethane foam, and an inorganic insulation material including glass wool. Characterized in that to do,
Liquefied hydrogen storage container. The method of claim 4,
The final insulation layer further includes a separate outer layer provided at a position spaced apart from the outside of the second compartment structure by a predetermined distance, and the space between the second compartment structure and the outer layer is a multilayer thin film insulation material is disposed or is hollow. Characterized in that it is formed in a vacuum after being filled with a powder or bead-type insulating material containing glass microspheres and glass bubbles,
Liquefied hydrogen storage container. The method of claim 1,
Characterized in that the liquefied hydrogen storage container is a pressurized tank in which the primary barrier can withstand a predetermined pressure,
Liquefied hydrogen storage container. Claims 1 to 7 of the maritime transportation means comprising a liquid hydrogen storage container according to any one of claims. The method of claim 8,
A plurality of the liquefied hydrogen storage containers are arranged along the longitudinal direction of the hull from the bow to the stern,
A liquefied hydrogen treatment facility for processing the boil-off gas of the liquefied hydrogen stored inside the liquefied hydrogen storage container at the rear of the liquefied hydrogen storage container disposed at the rear and the boil-off gas of the liquefied gas for thermal insulation accommodated inside the cryogenic thermal barrier layer Characterized in that a liquefied gas treatment facility for processing is provided,
A maritime transport vehicle containing a liquid hydrogen storage container. The method of claim 9,
The liquefied hydrogen treatment facility includes a re-liquefaction device for re-liquefying the boil-off gas of the liquefied hydrogen, a fuel cell for generating electricity using the boil-off gas of the liquefied hydrogen, and a boil-off gas of the liquefied hydrogen or the liquefied hydrogen itself. Characterized in that it includes at least one of the fuel supply systems that supply as the dynamometer fuel of the marine transportation means,
A maritime transport vehicle containing a liquid hydrogen storage container. The method of claim 10,
The liquefied gas treatment facility includes a re-liquefaction device for re-liquefying the boil-off gas of the liquefied gas for thermal insulation, an ammonia synthesis device for synthesizing ammonia using boil-off gas of the liquid nitrogen when the liquefied gas for heat shield is liquefied nitrogen, At least one of a fuel supply system for supplying the boil-off gas of the liquefied gas for heat-shielding or the liquefied gas for heat-shielding itself as fuel for a power system of a maritime transportation means, and an exhaust system for discharging the boil-off gas of the liquefied gas for heat-shielding outboard. Characterized in that it includes,
A maritime transport vehicle containing a liquid hydrogen storage container.

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