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KR20080006685A - The antibiosis ink by nano-silver and using process - Google Patents

The antibiosis ink by nano-silver and using process Download PDF

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Publication number
KR20080006685A
KR20080006685A KR1020060065696A KR20060065696A KR20080006685A KR 20080006685 A KR20080006685 A KR 20080006685A KR 1020060065696 A KR1020060065696 A KR 1020060065696A KR 20060065696 A KR20060065696 A KR 20060065696A KR 20080006685 A KR20080006685 A KR 20080006685A
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ink
antimicrobial
nanosilver
glass plate
glass
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KR1020060065696A
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Korean (ko)
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KR100840182B1 (en
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안병선
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주식회사 에스아이 앤 지
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Printing Methods (AREA)

Abstract

A method for preparing a nanosilver-containing antimicrobial ink is provided to produce a functional ink which has sterilizing or antibacterial functions even without deteriorating the quality of ink and embodies a fine design on a glass plate. A method for preparing a nanosilver-containing antimicrobial ink includes the steps of: mixing 60-70% by mass of acrylic oils with 2-3% of a dispersant; adding 20-30% of a pigment, glass beads, or pearl powder, etc, 2-3% of an antifoaming agent and a leveling agent, and 1-2% of an anti-discoloring agent to the mixed acrylic oils; and dispersing the admixture at high speed to prepare ink. To impart an antibacterial property to the ink, 0.3% of a nanosilver solution having a nanosilver size of 1-5 nm and a nanosilver concentration of 10% is added to the ink and uniformly mixed in an agitator.

Description

나노실버를 함유한 항균성 잉크 및 사용방법{The antibiosis ink by nano-silver and using process}The antibiosis ink by nano-silver and using process}

본 발명은 나노은을 함유한 실크스크린 잉크에 관한 것으로 나노은의 입자를 1~5nm의 10% 농도로 함축한 용액을 잉크에 혼합하여 유리판재에 인쇄하여 인쇄를 통한 이미지 전달과 동시에 항균기능을 부여하도록 하는 나노실버를 함유한 항균성 잉크 및 사용방법에 관한 것이다.The present invention relates to a silk screen ink containing nano silver, and a solution containing nano silver particles impregnated at a concentration of 10% of 1 to 5 nm in ink to be printed on a glass plate to impart antimicrobial function simultaneously with image transfer through printing. It relates to an antimicrobial ink containing nano silver and a method of use.

일반적으로 유리판재에 실크스크린 인쇄를 무의식적으로 폭넓게 사용되고 있으며, 다수의 혼합물을 혼합하여 제조되고 그의 조성물 중에는 미량이나마 오염원을 포함하고 있다. 이 때문에 이의 사용에는 상당한 주의를 요하고 있지만 현실정은 그러하지 못한 것이 사실이다.In general, silkscreen printing is widely used unconsciously on glass sheets, and is prepared by mixing a plurality of mixtures, and contains a small amount of contaminant in its composition. For this reason, its use requires considerable attention, but it is true that it is not so.

특히, 이런 유리판재를 에어컨, 냉장고, 김치냉장고, 공기청정기 등의 가전제품이나 병원 등의 의료기관이나, 찜질방, 학교 등의 실내인테리어 등 건물 내장재로 사용될 경우 세균의 전염에 용이한 장소에 사용된다면 세균 감염 문제가 발생되는 등 사회적 문제로 대두 될 수 있다.In particular, when the glass plate is used as a building interior material such as an air conditioner, a refrigerator, a kimchi refrigerator, an air cleaner, a medical institution such as a hospital, an indoor interior of a jjimjilbang, a school, or the like, It can be a social problem such as an infection problem.

이러한 병원성 세균의 감염을 막기 위하여 살균성을 가지고 있는 항균제를 유리에 첨가하거나 또는 정기적으로 살균 소독, 세척, 청소를 하도록 하고 있다. In order to prevent the infection of pathogenic bacteria, antimicrobial agents having bactericidal properties are added to the glass or regularly sterilized, cleaned and cleaned.

이와 같이, 일반 유기화합물을 이용해서 항균제의 경우 항균의 지속성에 한계를 가지고 있었으며 항균제 자체가 유기화학제로 이루어지는 관계로 그 자체가 인체에 해를 주고 있다. 그리고 항균성 나노실버 등 항균제를 유리 자체에 혼합하는 경우 그 비용면에서 엄청난 부담이 되는 것이 현 실정이다.As described above, in the case of antimicrobial agents using general organic compounds, the antimicrobial had a limit on the persistence of the antimicrobial agent, and since the antimicrobial agent itself is composed of an organic chemical agent, it harms the human body itself. In addition, when an antimicrobial agent such as antimicrobial nano silver is mixed with the glass itself, it is a huge burden in terms of cost.

따라서, 본 발명의 목적은 나노은 화합물의 실크스크린잉크로 잉크의 질을 저하시키지 않고도 살균이나 항균기능을 갖게하는 기능성 잉크를 제조하여 유리판재에 인쇄를 함으로써 아름다운 디지인 구현과 동시에 제조비용 또한 저렴하고 지속적이고 인체에 무해한 항균성 유리판재의 제조 방법을 제공하는데 있다.Therefore, an object of the present invention is to produce a functional ink that has a sterilization or antibacterial function without reducing the ink quality by the silk screen ink of the nano silver compound to print on the glass plate material to realize a beautiful design and at the same time low cost and continuous manufacturing And to provide a method for producing an antimicrobial glass plate material harmless to the human body.

이에 본 발명은 나노실버의 항균 능력과 지속성을 이용하여, 외적인 심미감과 안정감을 줄 수 있도록 한 유리판재 인쇄방법을 제공함에 있다.Accordingly, the present invention provides a method for printing a glass plate material that can give an external aesthetic and stability by using the antimicrobial ability and persistence of nanosilver.

본 발명은 유성 아크릴 수지로 구성되는 실크스크린 잉크와 나노화된 은화합물 그밖의 첨가제 등으로 조성된 잉크로 유리 판재에 실크스크린 인쇄를 하여 기능성 유리판재를 이루는 것을 결론으로 한다.The present invention concludes that a silkscreen printing on a glass plate is made of a silkscreen ink composed of an oil-based acrylic resin, a nanonized silver compound, and other additives to form a functional glass plate.

아크릴 오일 60 ~ 70무게%(이하, 비율은 모두 중량%)에 2 ~ 3%의 분산제를 넣고 혼합한 다음, 안료, Glass bead 또는 Pearl Powder 등을 20 ~ 30%(색상에 따라 함량과 성분은 다소 차이가 날 수 있음), 소포제, 레벨링제 첨가제 2~3%, 변색방지제 1~2%를 넣고 고속 분산하여 잉크를 제조한다.Add 2 ~ 3% of dispersant to 60 ~ 70% by weight of acrylic oil (hereafter, all percentages by weight), and then mix 20 ~ 30% of pigment, glass bead or pearl powder. It may be slightly different), the antifoaming agent, the leveling agent additive 2 ~ 3%, discoloration inhibitor 1 ~ 2% in the high-speed dispersion to prepare the ink.

이때, 소포제 및 레빌링제를 기준 함량보다 적게 사용하면 기포가 발생하여 미 인쇄된 부분이 발생할 수 있고, 과잉으로 사용하면 유리판재의 부착을 저하할 수 있다.At this time, if the antifoaming agent and the refrigerating agent are used less than the reference content, bubbles may be generated and an unprinted part may be generated, and when used excessively, the adhesion of the glass plate may be reduced.

이렇게 제조된 잉크에 항균성을 부여하기 위하여 나노실버 용액을 혼합하고 유리판재에 실크스크린하게 된다.In order to impart antimicrobial properties to the ink thus prepared, the nanosilver solution is mixed and silkscreened onto the glass plate.

항균성을 부여하기 위한 나노실버 용액은 1~5nm의 크기에 10% 농도의 나노실버 용액으로 상기 잉크에 0.3% 첨가하여 교반기로 잘 혼합한다.Nanosilver solution for imparting antimicrobial is added to the ink by 0.3% to 10% concentration of nanosilver solution in the size of 1 ~ 5nm and mixed well with a stirrer.

이렇게 제조된 항균성과 유리 부착성을 부여한 잉크를 제조하여 유리 판재의 이면에 실크스크린 인쇄를 통하여 인쇄하고 600~700℃로 30분 이상 건조를 하면 항균성 인쇄막을 형성하게 된다.Thus, the antimicrobial and glass adhesiveness-provided inks were prepared and printed on the back side of the glass plate through silk screen printing and dried at 600 to 700 ° C. for 30 minutes or more to form an antimicrobial printing film.

이에 본 발명은 항균력을 검증하기 위하여 강원대학교와 한국FITI시험연구원에서 공동으로 세균증식 시험한 결과(FITI 시험성적서 H217-06-00019) 세균감소율이 99.9%에 이르는 것으로 나타났다.In this regard, the present invention showed that the bacterial reduction rate reached 99.9% of the bacterial growth test (FITI test report H217-06-00019) jointly from Kangwon National University and Korea FITI Testing Institute in order to verify antibacterial activity.

상기와 같이 실크스크린 인쇄를 통한 항균성 유리판재는 외적으로 다양한 형태의 무늬로 표현되어지게 되어 외적 심미감을 줄 수 있게 되는 것이다.As described above, the antimicrobial glass plate material through silk screen printing is to be expressed in various forms of external patterns to give an external aesthetic sense.

본 발명은 상술한 특정의 바람직한 실시 예에 한정되지 아니하며, 청구범위에서 청구하는 본 발명의 요지를 벗어남이 없이 당해 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 누구든지 다양한 변형실시가 가능한 것은 물론이고, 그와 같은 변경은 청구범위 기재의 범위내에 있게 된다.The present invention is not limited to the above-described specific preferred embodiments, and various modifications can be made by any person having ordinary skill in the art without departing from the gist of the present invention claimed in the claims. Of course, such changes will fall within the scope of the claims.

이상에서와 같이 본 발명은 유리판재 이면에 실크스크린을 통한 항균성 유리의 제조는 항균, 살균, 항곰팡이, 탈취, 원적외선 방출 등의 복합적인 기능을 가지며, 이러한 특징은 장시간 지속시켜 자연환경에 친화적이고 인체에 유익하다는 우수한 효과를 갖는다. 또한, 제조 공정이 간단하고 미적 효과도 우수하며, 제조비용 또한 저렴하여 산업적인 기여가 클 것으로 기대한다.As described above, the present invention has a complex function such as antibacterial, antiseptic, anti-mildew, deodorant, far-infrared radiation, and the like for the production of antimicrobial glass through the silk screen on the back of the glass plate, and this feature is sustainable for a long time It has an excellent effect that it is beneficial to the human body. In addition, it is expected that the manufacturing process is simple, the aesthetic effect is excellent, the manufacturing cost is also low, and the industrial contribution is large.

Claims (3)

아크릴 오일 60 ~ 70무게%에 2 ~ 3%의 분산제를 넣고 혼합하고, 상기 혼합이 완료된 아크릴 오일에 안료, Glass bead 또는 Pearl Powder 등을 20 ~ 30%와, 소포제, 레벨링제 첨가제 2~3%, 변색방지제 1~2%를 넣고 고속 분산하여 잉크를 제조하게 된 것을 특징으로 하는 나노실버를 함유한 항균성 잉크 제조방법.Add 2 ~ 3% dispersant to 60 ~ 70 weight% of acrylic oil, mix with 20 ~ 30% of pigment, glass bead or pearl powder, etc., and defoaming agent, leveling agent additive 2 ~ 3% Method for producing an antimicrobial ink containing nano silver, characterized in that the discoloration inhibitor 1 to 2% by high-speed dispersion to prepare the ink. 제 1 항에 있어서,The method of claim 1, 상기 잉크에 항균성을 부여하기 위하여 나노실버 용액 1~5nm의 크기에 10% 농도의 나노실버 용액으로 상기 잉크에 0.3% 첨가하여 교반기로 잘 혼합하여 된 것을 특징으로 하는 나노실버를 함유한 항균성 잉크 제조방법.In order to impart antimicrobial activity to the ink, nanosilver solution containing antimicrobial ink containing nanosilver solution, which was mixed well with a stirrer by adding 0.3% to the ink with a nanosilver solution having a concentration of 10% at a size of 1-5 nm. Way. 상기 제1항과 제2항에 의해 항균성과 유리 부착성을 부여한 잉크를 유리 판재의 이면에 실크스크린 인쇄를 통하여 인쇄하고 600~700℃로 30분 이상 건조를 하면 항균성 인쇄막이 형성되도록 한 것을 특징으로 하는 나노실버를 함유한 항균성 잉크의 사용방법.According to claim 1 and 2, the antimicrobial and glass adhesion-provided ink is printed on the back surface of the glass plate through silk screen printing, and the antimicrobial printing film is formed when dried at 600 to 700 ° C. for at least 30 minutes. Method of using an antimicrobial ink containing nano silver.
KR1020060065696A 2006-07-13 2006-07-13 The antibiosis ink by nano-silver and using process KR100840182B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10696471B2 (en) 2017-10-31 2020-06-30 Medline Industries, Inc. Enclosure for gloves with antimicrobial ink coating and methods for making the same
US11219786B2 (en) 2017-11-13 2022-01-11 3M Innovative Properties Company Inner shell and mask including same

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000072487A (en) 1998-08-27 2000-03-07 Nippon Electric Glass Co Ltd Antibacterial crystallized glass article and its production
KR100609602B1 (en) * 2003-08-13 2006-08-04 주식회사 케이씨씨 Composition for coating nonmetallic surface
JP4078283B2 (en) 2003-10-16 2008-04-23 ゼネラル株式会社 Ink composition
KR100730577B1 (en) * 2004-04-28 2007-06-20 이종철 A multifunction paints for cases of electronic apparatus and a method thereof
KR100654185B1 (en) * 2004-11-08 2006-12-06 (주)월드팬시 Sterilized micro nano-silver film having nonpoisonous and the process thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10696471B2 (en) 2017-10-31 2020-06-30 Medline Industries, Inc. Enclosure for gloves with antimicrobial ink coating and methods for making the same
US11219786B2 (en) 2017-11-13 2022-01-11 3M Innovative Properties Company Inner shell and mask including same

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