KR20060046195A - Liquid crystal display panel and its manufacturing method - Google Patents

Abstract

The liquid crystal display panel (LCD) of the OCB mode is sandwiched between the pair of electrode substrates 1 and 2 and the pair of electrode substrates 1 and 2, and the orientation state of the liquid crystal molecules is in the display area. The liquid crystal layer LQ controlled by the driving voltage applied from the ()) and the pair of alignment films disposed on the pair of electrode substrates 1 and 2 adjacent to the liquid crystal layer LQ and whose rubbing directions are parallel to each other are provided. The impurity ion concentration contained in the liquid crystal layer LQ in the display area is set lower than the impurity ion concentration contained in the liquid crystal layer LQ outside the display area.

OCB mode, rubbing direction, nematic liquid crystal material

Description

Liquid crystal display panel and its manufacturing method {LIQUID CRYSTAL DISPLAY PANEL AND METHOD FOR MANUFACTURING THE SAME}

1 is a diagram showing a planar structure of a liquid crystal display panel of OCB mode according to a first embodiment of the present invention.

FIG. 2 is a diagram showing a circuit structure of the liquid crystal display panel shown in FIG. 1. FIG.

3A to 3C are cross-sectional views and liquid crystal molecular orientations of a liquid crystal display panel in OCB mode.

FIG. 4 is a diagram showing a rubbing process for the alignment film shown in FIGS. 3A to 3C.

5A to 5D are plan views illustrating a problem occurring in the liquid crystal display panel of the OCB mode.

<Explanation of symbols for the main parts of the drawings>

1: array board

2: opposing substrate

3: seal resin layer

4: inlet

5: sealing material

LQ: liquid crystal layer

RD1, RD2: rubbing direction

Patent Document 1: Japanese Patent Application Laid-Open No. 9-54325

The present invention relates to a liquid crystal display panel in an OCB (optically compensated bend) mode and a method of manufacturing the same.

Liquid crystal display panels are widely used for screen displays such as personal computers, car navigation systems, monitors, and TVs. As the liquid crystal display mode used for these liquid crystal displays, TN mode and STN mode using a nematic liquid crystal are used a lot. In addition, although a liquid crystal display mode using a ferroelectric liquid crystal or the like having a fast response speed and a wide viewing angle is known, improvement in shock resistance, temperature characteristics, and the like is required. On the other hand, as a mode with excellent high-speed response and a wide viewing angle, an optical compensation type, OCB mode in which liquid crystal molecules are aligned in parallel instead of twisted alignment has attracted attention as an image device, and development has been actively conducted.

In general, an active matrix liquid crystal display panel has a structure in which a liquid crystal layer is sandwiched between an array substrate and an opposing substrate. The array substrate includes, for example, a plurality of pixel electrodes arranged in a substantially matrix shape, a plurality of scan electrodes arranged along a row of the plurality of pixel electrodes, a plurality of data signal electrodes arranged along a column of the plurality of pixel electrodes, and a plurality of pixel electrodes. It has a some switching element arrange | positioned in the vicinity of the crossing position of a several scanning electrode and a some data signal electrode. Each switching element is made of, for example, a thin film transistor (TFT), and conducts when one scan electrode is driven to apply a potential of one data signal electrode to one pixel electrode. On the counter substrate, the counter electrode is formed to face the plurality of pixel electrodes arranged on the array substrate. The pair of pixel electrodes and the counter electrode constitute a pixel together with the pixel region of the liquid crystal layer, and control the arrangement of the liquid crystal molecules in the pixel region by an electric field corresponding to the driving voltage held between the pixel electrode and the counter electrode.

In the liquid crystal display panel of OCB mode, liquid crystal molecules are spray-oriented before power supply. This spray orientation is obtained by the alignment film rubbed in parallel with each other on the pixel electrode and the counter electrode with the liquid crystal molecules hardly moving. The display operation of this liquid crystal display panel is performed after an initialization process in which a transition voltage is applied to the liquid crystal layer with power on, and the alignment state of liquid crystal molecules is transferred from spray orientation to bend orientation by a relatively strong electric field corresponding to the transition voltage. Is done. The alignment state of the liquid crystal molecules is maintained in the bend alignment during the display operation, and excellent in the high-speed response characteristic peculiar to the OCB mode, thereby realizing display with a wide viewing angle.

In addition, the alignment state of the liquid crystal molecules is reversed from the bend orientation to the spray orientation when the voltage application state or the voltage non-application state below the level at which the energy of the spray orientation and the energy of the bend orientation are antagonized continues for a long time. . In the liquid crystal display panel of OCB mode, the black insertion drive system is taken in order to prevent this reverse transition. In the black insertion driving, a display voltage corresponding to the reverse transition prevention voltage and the image signal is alternately applied as the driving voltage to the liquid crystal layer in the frame period to maintain the bend alignment. The liquid crystal display panel of the OCB mode is a display panel of the normal white mode, and is called black insertion driving because the reverse transition prevention voltage corresponds to the black display voltage. The ratio of the application period of the reverse transition prevention voltage to the total application period of the display voltage and the reverse transition prevention voltage is called the black insertion rate.

In the manufacture of the liquid crystal display panel, after the array substrate 1 and the counter substrate 2 shown in FIG. 5A are separately formed, rubbing treatment is applied to the alignment film on the array substrate 1 side and the alignment film on the counter substrate 2 side. The array substrate 1 and the counter substrate 2 are bonded to each other via the seal resin layer 3. The seal resin layer 3 is applied to surround the liquid crystal injection space leaving the injection hole 4, and the injection hole 4 is in the vicinity of the second side opposite to the first side of the array substrate 1 on which the driver circuit element is disposed. Is formed. The rubbing treatment of each alignment film is performed in the same direction from the second side to the first side so as not to electrostatically destroy the driver circuit element. In FIG. 5A, RD1 represents the rubbing direction of the alignment film on the array substrate 1 side, and RD2 represents the rubbing direction of the alignment film on the opposite substrate 2 side. The liquid crystal material is filled from the injection hole 4 into the liquid crystal injection space as the liquid crystal layer LQ, and the injection hole 4 is sealed by the sealing material 5.

In the manufacturing process described above, it is inevitable that impurity ions are incorporated into the liquid crystal layer LQ. Specifically, the sealing material 5 most releases impurity ions to the liquid crystal layer LQ. These impurity ions lower the insulation resistance of the liquid crystal and cause deterioration of display characteristics due to a drop in voltage retention. In addition, when impurity ions move in the liquid crystal layer when the driving voltage is applied, and the distribution of impurity ions becomes uneven, display defects such as display unevenness occur. For example, Patent Document 1 discloses a technique of forming an ion trap electrode on a substrate and sequentially applying a plurality of electrodes arranged in one direction to prevent an uneven distribution of such impurity ions. It is described. However, it is difficult to apply this technique to solve the problem occurring in the liquid crystal display panel of OCB mode.

In the liquid crystal display panel of the OCB mode, liquid crystal molecules are bend aligned in the liquid crystal layer LQ for display operation. Between the white display state in which a low voltage is applied to the liquid crystal layer LQ, and the black display state in which a high voltage is applied to the liquid crystal layer LQ, the alignment angles of the liquid crystal molecules largely change. Since the change of the orientation angle involves the displacement of the liquid crystal molecules, the flow of liquid crystal molecules occurs in the direction of this displacement in the liquid crystal layer LQ. The direction of this flow corresponds to the rubbing direction of the alignment film which liquid crystal molecules orientate in the liquid crystal display panel of OCB mode. When the impurity ions move in the rubbing directions RD1 and RD2 shown in Fig. 5A, the impurity ion DF having a high concentration near the injection hole 4 diffuses into the liquid crystal layer LQ as shown in Fig. 5B, and the black insertion drive is performed. As a result of continuing the display, display unevenness occurs due to the partial drop in charge holding force. This can be verified, for example, by continuously performing an operation of displaying the image of the evaluation pattern shown in Fig. 5C while performing black insertion driving, and then displaying the image of the pattern of which is entirely black. In this case, the entirety does not turn black, and gray stripes as shown in Fig. 5D are observed as partial baking. Impurity ions flow into the black display region from the white display region shown in Fig. 5C and are concentrated during black insertion driving. Gray streaks are caused by a drop in charge retention by the concentrated impurity ions, i.e. a loss of applied voltage.

It is difficult to solve the problem of burnout occurring in the liquid crystal display panel of the OCB mode only by applying a high potential pulse as in the above-mentioned document.

An object of the present invention is to provide an OCB mode liquid crystal display panel capable of suppressing display unevenness caused by impurity ions when black insertion driving is performed in a display operation, and a method of manufacturing the same.

According to the present invention, a liquid crystal layer sandwiched between a pair of electrode substrates and a pair of electrode substrates, the alignment state of the liquid crystal molecules being controlled by a driving voltage applied from these electrode substrates inside the display area, adjacent to the liquid crystal layer Integrally forming, as a display panel, a pair of alignment films disposed on a pair of electrode substrates and in which rubbing directions are parallel to each other, and for black insertion driving for preventing the alignment state of liquid crystal molecules from reversing from bend orientation to spray orientation; Impurities contained in the liquid crystal layer by continuing the operation of generating a flow of liquid crystal molecules along the rubbing direction by applying a driving voltage periodically changing to a black insertion rate set independently of the black insertion rate for a predetermined period of time. An OCB including an aging process for moving ions out of the display area The method of manufacturing the liquid crystal display panel according to the DE is provided.

Further, according to the present invention, there is provided a liquid crystal layer sandwiched between a pair of electrode substrates and a pair of electrode substrates, in which an alignment state of liquid crystal molecules is controlled by a driving voltage applied from these electrode substrates inside the display area, An impurity included in the liquid crystal layer having a pair of alignment layers adjacent to the liquid crystal layer and having a rubbing direction parallel to each other, and having impurity ion concentration included in the liquid crystal layer positioned in the display area, positioned outside the display area The liquid crystal display panel of OCB mode set lower than ion concentration is provided.

In these OCB mode liquid crystal display panels and a method of manufacturing the same, the impurity ion concentration contained in the liquid crystal layer positioned in the display region is lower than the impurity ion concentration contained in the liquid crystal layer positioned outside the display region as a result of the aging treatment in the manufacturing process. By setting, it is possible to reduce the impurity ions concentrated in the display area when the black insertion driving is performed in the display operation, and to suppress the display unevenness caused by the concentrated impurity ions.

Additional objects and advantages of the invention will be set forth in the description which follows, and in part will be obvious from the description, or may be understood by practice of the invention. The objects and advantages of the present invention can be realized by the combination of the embodiments and the embodiments specifically pointed out hereinafter.

The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate preferred embodiments of the invention and, together with the foregoing general description and the following detailed description, serve to explain the principles of the invention.

Hereinafter, an LCD of an OCB mode according to a first embodiment of the present invention will be described with reference to the drawings. 1 shows a planar structure of a liquid crystal display panel LCD, FIG. 2 shows a circuit structure of a liquid crystal display panel LCD, and FIGS. 3A to 3C show a cross-sectional structure of a liquid crystal display panel LCD. As shown in FIG. 1, the liquid crystal display panel LCD includes an array substrate 1, an opposing substrate 2, and a liquid crystal layer LQ held between these substrates 1, 2. The array substrate 1 and the opposing substrate 2 are a pair of rectangular electrode substrates, each of which is a seal resin layer coated to surround the liquid crystal injection space by leaving the injection hole 4 in the gap between the substrates 1 and 2 ( It is joined through 3). The liquid crystal layer LQ is obtained by, for example, filling the nematic liquid crystal material from the injection hole 4 into the liquid crystal injection space and sealing the injection hole 4 with the sealing material 5.

In a liquid crystal display panel LCD, a display screen is comprised by the some pixel 11 shown in FIG. The array substrate 1 includes a plurality of pixel electrodes 23 arranged in a matrix in the display area 10 corresponding to the display screen, and a plurality of scan electrodes 12 arranged along the rows of the pixel electrodes 23. And a plurality of data signal electrodes 13 arranged along the columns of the pixel electrodes 23, a plurality of scanning electrodes 12, and a plurality of data signals electrodes 13 arranged as a switching element in the vicinity of the intersection. Thin film transistor (TFT) 17, an auxiliary capacitor 20 connected to a plurality of pixel electrodes 23 at one end thereof, a scan circuit 14 connected to a plurality of scan electrodes 12, and a plurality of data signal electrodes And a data signal circuit 15 connected to (13). Each scan electrode 12 is connected to the gate of the thin film transistor 17 of the corresponding row, and each data signal electrode 13 is connected to the drain of the thin film transistor 17 of the corresponding column. Each pixel electrode 23 is connected to the source of the corresponding thin film transistor 17. The plurality of storage capacitors 20 are connected to the common wiring 16 at the other end. Here, each thin film transistor 17 is formed as an n-channel MOS transistor. The opposing substrate 2 includes an opposing electrode 27 facing the plurality of pixel electrodes 23. Each pixel 11 includes a pixel electrode 23, a counter electrode 27, and a part of the liquid crystal layer LQ disposed between these electrodes 23, 27, and the pixel electrode 23 and the counter electrode 27 The liquid crystal capacitor which maintains the drive voltage corresponding to the electric potential difference between them is comprised. The storage capacitor 20 is formed in parallel with the liquid crystal capacitor in order to maintain this driving voltage stably.

The scanning circuit 14 sequentially outputs scanning signals to the plurality of scanning electrodes 12 in the scanning direction 7 shown in FIGS. 1 and 2 by one horizontal scanning period, and the data signal circuits 15 are each While the scan electrode 12 is driven by the scan signal, one row of image signals are converted into pixel voltages, and these pixel voltages are output to the plurality of data signal electrodes 13. These pixel voltages are applied to the pixel electrodes 23 of the corresponding rows through the thin film transistors 17 for one row that are conducted by the scan signal. This pixel voltage is a voltage applied to the pixel electrode 23 on the basis of the common voltage set on the counter electrode 27, and is polarized inverted with respect to the common voltage for one frame period and one horizontal scanning period, for example. The transmittance of each pixel 11 is controlled corresponding to the driving voltage between the pixel electrode 23 and the counter electrode 27.

As shown in FIG. 3A, in the array substrate 1, the pixel electrode 23 is formed on a transparent insulating substrate 22 such as a glass substrate, and covered with the alignment film 24. In the opposing substrate 2, the opposing electrode 27 is formed on the color filter layer 26 covering the transparent insulating substrate 25, such as a glass substrate, and covered by the alignment film 28. The array substrate 2 and the counter substrate 2 are joined so that the alignment films 24 and 28 are adjacent to the liquid crystal layer LQ. The liquid crystal display panel LCD also includes a pair of optical compensation phase difference plates 30, a pair of polarizing plates 31, and a light source backlight 32. The pair of phase difference plates 30 are bonded to the transparent insulating substrates 22 and 25 on the opposite side to the liquid crystal layer LQ, and the pair of polarizing plates 31 are bonded to the pair of phase difference plates 30. The backlight 32 for the light source is disposed adjacent to the polarizing plate 31 on the side of the array substrate 1.

In this liquid crystal display panel LCD, the alignment film 24 and the alignment film 28 are rubbed in directions parallel to each other. In FIG. 1, RD1 represents the rubbing direction of the alignment film 24, and RD2 represents the rubbing direction of the alignment film 28. Thereby, the liquid crystal molecules of liquid crystal layer LQ are spray-oriented as shown in FIG. 3A as an initial state. In this initial state, the liquid crystal molecules of the liquid crystal layer 29 near the surfaces of the alignment films 24 and 28 have a high pretilt angle (5 ° to 12 °) with respect to the surfaces of the alignment films 24 and 28.

The above-described rubbing process is performed as shown in FIG. 4, for example. In this rubbing process, the array substrate 1 and the opposing board | substrate 2 by which the alignment film material was apply | coated as the alignment film 24 and 28 are prepared similarly to the case of the other liquid crystal display mode. Each of the array substrate 1 and the opposing substrate 2 is mounted on the stage in a direction parallel to the axis of the rubbing roller 33 with a long side, and with the stage in the direction of arrow X across the rubbing roller 33. Move. The rubbing cloth 34 is wound around the rubbing roller 33. The rubbing cloth 34 rotates together with the rubbing roller 33 in contact with the alignment film 28. Thereby, each of the array substrate 1 and the opposing substrate 2 is rubbed in the rotational direction of the rubbing roller 33, that is, in the direction of an arrow Y orthogonal to the rotational axis of the rubbing roller 33.

In this liquid crystal display panel LCD, the scanning circuit 14 and the data signal circuit 15 apply a transition voltage different from the display voltage as the driving voltage to all the pixels 11 with the power-on, and thus the alignment state of the liquid crystal molecules. It is configured to perform the initialization of the transition from the spray orientation to the bend orientation shown in Figs. 3B and 3C. FIG. 3B shows the bend orientation obtained when the white display voltage is applied, and FIG. 3C shows the bend orientation obtained when the black display voltage is applied. The white display voltage in the case of adopting the black insertion drive is zero or a small value close to zero, and the pixel 11 is set in a high luminance state that transmits the backlight 32 light at a high transmittance. In addition, the back display voltage in the case of not employing the black insertion drive is set to a low voltage (for example, about 1 to 2 volts) in the range in which the bent aligned liquid crystal molecules do not return to the spray orientation. On the other hand, the black display voltage is larger than the white display voltage, and the pixel 11 is set in a low luminance state that transmits the backlight 32 light at a low transmittance. The luminance of each pixel 11 changes in the range of the luminance of these white displays and the luminance of black displays for displaying an image.

The scanning circuit 14 and the data signal circuit 15 may also have a predetermined black insertion rate, for example, every one frame period, in the display operation after initialization to prevent the alignment state of the liquid crystal molecules from the bend orientation to the spray orientation. The black insertion driving is performed so that the reverse transition prevention voltage corresponding to the black display voltage is sequentially applied to all the pixels 11 (liquid crystal layer LQ) in units of rows in the scanning direction 7.

In the manufacture of the liquid crystal display panel LCD, the formation process of integrally forming the array substrate 1, the counter substrate 2, the liquid crystal layer LQ, the pair of alignment films 24 and 28, etc. as described above as a display panel was performed. Thereafter, the white display voltage and the black display voltage are alternately applied to the liquid crystal layer LQ in each frame period to continue the operation of generating a flow of liquid crystal molecules along the rubbing direction over a predetermined period, thereby being included in the liquid crystal layer LQ along the rubbing direction. An aging process is performed to move the impurity ions to the outside of the display region 10. The black display voltage and black insertion rate for the aging treatment are set independently of the black insertion voltage and the black insertion rate for black insertion driving that prevent the state of alignment of the liquid crystal molecules from transitioning from the bend orientation to the spray orientation. As a result of this aging treatment, the impurity ion concentration contained in the liquid crystal layer LQ positioned in the display region 10 is about 1/2 to 1/5 of the impurity ion concentration contained in the liquid crystal layer LQ positioned outside the display region 10. Is set to a low value.

As shown in FIG. 1, when the rubbing directions RD and RD2 coincide with the scanning direction 7 from the top to the bottom of the screen of the display panel LCD, the drift of impurity ions is periodically corresponding to the white display voltage and the black display voltage. It occurs downwardly with respect to the pixels 11 of each row due to the change in the driving voltage, and also occurs in the pixels 11 of subsequent rows which are sequentially scanned. As a result, impurity ions continuously move to the lower end of the display area 10 in the direction of the arrow 8, and are efficiently discharged to the outside of the display area 10 as a whole. Therefore, by performing this aging process, it is possible to alleviate the display unevenness caused by impurity ions unevenly concentrated for black insertion driving in the display region 10 when displaying an image on the liquid crystal display panel.

As described above, if the rubbing directions RD1 and RD2 coincide with the scanning direction 7 as described above, it is possible to effectively move the impurity ions in the aging process. Even if the two are not opposite to each other, it is possible to surely discharge the impurity ions by appropriately setting the aging treatment conditions. For example, the black display voltage for aging processing is set to 6V slightly larger than the black display voltage for black insertion driving (= 5V). Thus, by setting the aging treatment voltage at, for example, 5 to 6 volts, a large aging treatment effect can be obtained.

In addition, when the ratio of the black insertion rate for the aging treatment, that is, the application period of the black display voltage to the total application period (one frame period) of the white display voltage and the black display voltage, was increased, the discharge efficiency of impurity ions was improved. However, there is an optimum value of black insertion rate of 50 to 80% in the aging treatment. In this embodiment, a black insertion rate of 70% was employed in the aging treatment, and good results were obtained.

The higher the aging treatment temperature, the more effectively the impurity ions can be discharged. In this embodiment, the aging process temperature is set to 60 degreeC higher than normal temperature, and the favorable result was obtained. However, if the processing temperature exceeds the NI temperature, good results may not be obtained. In addition, since the polarizing plate 31 is damaged by raising the aging treatment temperature, 70 ° C is the upper limit of the aging treatment temperature. It was confirmed that the effect of discharging impurity ions was obtained at an aging treatment temperature of 40 ° C. or higher.

The longer the aging treatment time, the more effectively the impurity ions can be discharged. The effect of discharging impurity ions is obtained by setting the aging treatment to 1 hour or more, but when set beyond 12 hours, it is saturated. Therefore, the aging treatment time is appropriately set in the range of 1 hour to 12 hours. However, considering the relationship between the effect of discharging the impurity time and the aging treatment time from the viewpoint of production efficiency, it is reasonable to set the aging treatment time in the range of 3 hours to 5 hours. In this embodiment, the aging process time was set to 3 hours, and the favorable result was obtained.

In addition, a dummy electrode is provided on one side of the display region 10 located at the terminal side in the rubbing direction adjacent to the upper side or the lower side, and the back display voltage is always applied to the dummy electrode to thereby display the display region 10. The effect of transferring the impurity ions to a position substantially distant from the terminal end of the c) can be obtained.

In addition, although the description of the subject of this invention demonstrated the removal of the display unevenness which appears as a line slit at the boundary of white and black, it is not limited to this, The same effect can be acquired by applying this invention. For example, in some cases, the display unevenness may arise at the location which penetrated about 2 mm in the black area by the effect of heat diffusion. In addition, although the flow (flow) to the rubbing direction was demonstrated in the above-mentioned example, there existed the example in which impurity ion drifts even in the reverse flow. In other words, depending on the difference in the mobility of ions, it is determined which flow drifts. In any case, display impurity can be suppressed by discharging impurity ions by the above-described aging treatment.

In addition, in the above-mentioned embodiment, although the scanning circuit 14 and the data signal circuit 15 are comprised using the some thin film transistor arrange | positioned at the array substrate 1 of a liquid crystal display panel LCD, they are the thing of a liquid crystal display panel LCD. It may be replaced by an integrated circuit IC disposed outside.

Moreover, you may apply this invention to the liquid crystal display panel of OCB mode which does not perform black insertion drive. In this case, if it is set to zero (V) as the back display voltage used in the aging process, since it is easy to reverse from the bend orientation to the spray orientation, it is recommended to set it to a low voltage of about 1 to 2 volts to prevent this reverse transition. desirable.

The above-described embodiments are to be considered in all respects only as illustrative and not restrictive. It is intended that the scope of the invention be defined not by the foregoing description of the embodiments, but rather within the scope of the claims, and include all modifications within the meaning and range equivalent to the scope of the claims.

According to the present invention, it is possible to provide an OCB mode liquid crystal display panel capable of suppressing display unevenness caused by impurity ions when black insertion driving is performed in a display operation, and a manufacturing method thereof.

Claims (11)

A liquid crystal layer sandwiched between a pair of electrode substrates and a pair of electrode substrates, the alignment state of the liquid crystal molecules being controlled by a driving voltage applied from these electrode substrates in the display area, disposed on the pair of electrode substrates adjacent to the liquid crystal layer; Integrally forming a pair of alignment films in which rubbing directions are parallel to each other as a display panel; A rubbing direction is applied to a liquid crystal layer by applying a driving voltage that periodically changes to a black insertion rate set independently of the black insertion rate for black insertion driving which prevents the alignment state of the liquid crystal molecules from the bend orientation to the spray orientation. Performing an aging process of moving the impurity ions included in the liquid crystal layer to the outside of the display area by continuing the operation of generating a flow of liquid crystal molecules along the predetermined period; The manufacturing method of the liquid crystal display panel of the OCB mode containing. The method of claim 1, And said driving voltage for aging is approximately black display voltage and approximately white display voltage applied alternately in each frame period. The method of claim 2, And the black insertion rate for aging treatment is a value exceeding the black insertion rate for black insertion driving. The method of claim 3, The black insertion rate for the aging treatment is 50% or more. The method of claim 4, wherein The black insertion rate for the aging treatment is 50% to 80%. The method of claim 2, And the black display voltage for aging treatment is set larger than the black display voltage for black insertion driving. The method of claim 2, The process temperature of the said aging process is a manufacturing method of the liquid crystal display panel set higher than normal temperature. The method of claim 2, The said predetermined period is a manufacturing method of the liquid crystal display panel set to the range of 1 to 12 hours. The method of claim 8, The said predetermined period is a manufacturing method of the liquid crystal display panel set to the range of 3 to 5 hours. A pair of electrode substrates, A liquid crystal layer sandwiched between the pair of electrode substrates, the alignment state of liquid crystal molecules being controlled by a driving voltage applied from these electrode substrates in a display region; A pair of alignment layers disposed on the pair of electrode substrates adjacent to the liquid crystal layer and having a rubbing direction parallel to each other, The liquid crystal display panel of the OCB mode in which the impurity ion concentration contained in the liquid crystal layer in the display area is set lower than the impurity ion concentration contained in the liquid crystal layer outside the display area. The method of claim 10, And a dummy electrode disposed in an outer region adjacent to the display region at the end side of the rubbing direction, and to which a back display voltage is always applied.

Images