KR20020067674A - A composition for enrichment and water conditioning of soil using industrial waste and process for preparation thereof - Google Patents
A composition for enrichment and water conditioning of soil using industrial waste and process for preparation thereof Download PDFInfo
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- KR20020067674A KR20020067674A KR1020020008155A KR20020008155A KR20020067674A KR 20020067674 A KR20020067674 A KR 20020067674A KR 1020020008155 A KR1020020008155 A KR 1020020008155A KR 20020008155 A KR20020008155 A KR 20020008155A KR 20020067674 A KR20020067674 A KR 20020067674A
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- 239000000203 mixture Substances 0.000 title claims abstract description 72
- 239000002689 soil Substances 0.000 title claims abstract description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 11
- 239000002440 industrial waste Substances 0.000 title abstract description 11
- 238000000034 method Methods 0.000 title description 16
- 230000008569 process Effects 0.000 title description 9
- 238000002360 preparation method Methods 0.000 title description 4
- 230000003750 conditioning effect Effects 0.000 title 1
- 230000006872 improvement Effects 0.000 claims abstract description 39
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000010881 fly ash Substances 0.000 claims abstract description 18
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 15
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000010457 zeolite Substances 0.000 claims abstract description 15
- 239000000853 adhesive Substances 0.000 claims abstract description 14
- 230000001070 adhesive effect Effects 0.000 claims abstract description 14
- 239000010802 sludge Substances 0.000 claims abstract description 14
- 239000005909 Kieselgur Substances 0.000 claims abstract description 9
- 229910001562 pearlite Inorganic materials 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 6
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- 241000209140 Triticum Species 0.000 description 10
- 235000021307 Triticum Nutrition 0.000 description 10
- 235000004611 garlic Nutrition 0.000 description 10
- 238000010998 test method Methods 0.000 description 10
- 239000002699 waste material Substances 0.000 description 9
- 241000234282 Allium Species 0.000 description 8
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 230000001737 promoting effect Effects 0.000 description 7
- 238000004806 packaging method and process Methods 0.000 description 6
- 201000010099 disease Diseases 0.000 description 5
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 5
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- 230000029553 photosynthesis Effects 0.000 description 5
- 238000010672 photosynthesis Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
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- 241000282472 Canis lupus familiaris Species 0.000 description 4
- 230000004720 fertilization Effects 0.000 description 4
- 238000003306 harvesting Methods 0.000 description 4
- 240000004160 Capsicum annuum Species 0.000 description 3
- 244000241257 Cucumis melo Species 0.000 description 3
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 240000007594 Oryza sativa Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 3
- 238000009825 accumulation Methods 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
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- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
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- 239000011148 porous material Substances 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241001214984 Crinum thaianum Species 0.000 description 2
- 240000006394 Sorghum bicolor Species 0.000 description 2
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000013098 chemical test method Methods 0.000 description 2
- 238000012217 deletion Methods 0.000 description 2
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- 238000013461 design Methods 0.000 description 2
- 230000006806 disease prevention Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000035800 maturation Effects 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000009331 sowing Methods 0.000 description 2
- 235000013555 soy sauce Nutrition 0.000 description 2
- 230000005068 transpiration Effects 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000828585 Gari Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- -1 calcareous Chemical compound 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000002921 fermentation waste Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 208000037824 growth disorder Diseases 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000010150 least significant difference test Methods 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
- C09K17/42—Inorganic compounds mixed with organic active ingredients, e.g. accelerators
- C09K17/46—Inorganic compounds mixed with organic active ingredients, e.g. accelerators the inorganic compound being a water-soluble silicate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00732—Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S106/00—Compositions: coating or plastic
- Y10S106/90—Soil stabilization
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Processing Of Solid Wastes (AREA)
- Cultivation Of Plants (AREA)
- Treatment Of Sludge (AREA)
Abstract
제지슬러지 10∼30 중량%, 플라이 애쉬(Fly ash) 5∼15 중량%, 화이트카본 (White Carbon) 10∼30 중량%, 제올라이트(Zeolite) 10∼30 중량%, 퍼얼라이트 (pearlite) 20∼40 중량%, 수성접착제 1∼3 중량%로 구성된 조성물 또는 제지슬러지 10∼50 중량%, 플라이 애쉬(Fly ash) 5∼15 중량%, 제올라이트(Zeolite) 10∼40 중량%, 규조토 10∼40 중량%, 수성접착제 CMC 1∼3 중량%로 구성된 조성물을 로타리 혼합기에 투입하여 50∼100rpm으로 혼합한 다음, 익스트루더를 통하여 과립상으로 제조한 다음 130∼150℃의 가열 건조기에서 20∼30분간 가열건조하여서 되는 산업폐기물을 주재로한 토양개량 및 수분조절제 조성물은 논토양이나 밭토양 및 염류집적 토양에서 작물생육초기를 비롯하여 어느 생육단계에서 시용하더라도 뛰어난 보수력과 영양공급능에 의하여 생육촉진 효과가 있으며, 증수효과가 뛰어난 효과가 있다.Paper sludge 10-30% by weight, Fly ash 5-15% by weight, White Carbon 10-30% by weight, Zeolite 10-30% by weight, Pearlite 20-40 10% by weight, 10-50% by weight of composition or paper sludge, 5-15% by weight of fly ash, 10-40% by weight of zeolite, 10-40% by weight of diatomaceous earth , The composition consisting of 1 to 3% by weight of the aqueous adhesive CMC is added to a rotary mixer, mixed at 50 to 100rpm, granulated through an extruder, and then heated at 130 to 150 ° C. for 20 to 30 minutes. Soil improvement and moisture control composition mainly composed of industrial wastes, which are dried, can be used at any stage of growth, including early stages of crop growth, in paddy soils, field soils and salt-integrated soils. Increase There is an excellent effect.
Description
본 발명은 신규한 토양개량 및 수분조절제 조성물 및 그 제조방법에 관한 것이다. 더욱 상세하게는, 본 발명은 산업폐기물을 주재로하는 신규한 토양개량 및 수분조절제 조성물 및 그 제조방법에 관한 것이다.The present invention relates to a novel soil improvement and moisture control composition and a method for producing the same. More specifically, the present invention relates to a novel soil improvement and moisture control composition based on industrial waste and a method for producing the same.
종래에도 각종 작물의 건전한 생육을 위한 인공토양 조성물의 제조방법이 다수 공지되었다. 특히, 국내특허공개번호 제 98-63340 호에는 조미료 공장에서 발생되는 강산성의 아미노산 발효폐액을 비료화하기 위한 Fly ash 사용방법의 발명이 공지되어 있으나 이는 강산성의 아미노산 발효부산물을 비료화하기 위한 장점이 있는 반면, 최종산물(final product)에 유기물(organic materials)이 함유되어 있어서 작물의 생육단계 후기에는 사용할 수 없었을 뿐만 아니라, 토양의 종류에 따라서는 예컨대, 염류집적 토양인 대형 비닐하우스 재배단지 등에서는 그 사용이 극히 제한되는 폐단이 있어 왔다.Conventionally, a number of methods for preparing artificial soil compositions for the healthy growth of various crops have been known. In particular, Korean Patent Publication No. 98-63340 discloses a method of using fly ash for fertilizing strong acidic fermentation wastes generated in seasoning factories, but this has the advantage of fertilizing strong acidic fermentation by-products. In addition, the final product contained organic materials, which could not be used in the later stages of crop growth.In addition, depending on the type of soil, it may be used in large vinyl house cultivation complexes, such as salt-integrated soils. There has been this extremely limited closure.
본 발명은 상기와 같은 일반 토양의 수분조절효과가 우수한 국내 주요특허의 잇점들에도 불구하고 상기와 같은 단점들을 개선하기 위하여 유기물이 함유되어 있지 않아서 작물생육의 어느 단계에서든지 사용할 수 있으며 일반 논토양에서는 물론 염류집적이 큰 대형 비닐하우스 단지 및 일반 과수재배의 밭토양에 이르기까지 토양의 종류나 재배작물의 생육단계에 관계없이 항시적으로 사용하여 토양개량 및 수분조절 효과를 극대화하고 작물 생육을 현저히 촉진시킬 수 있는 산업폐기물을 주재로하고 무기물로만 구성된 신규한 토양개량 및 수분조절제 조성물을 제공하는 것을 그 목적으로 한다.The present invention can be used at any stage of crop growth because it does not contain organic matter in order to improve the above disadvantages despite the advantages of major domestic patents excellent moisture control effect of the general soil as described above Of course, regardless of the type of soil or the growing stage of cultivated crops, such as large plastic house complexes with large salt concentrations and field soils of general fruit cultivation, they can be used at all times to maximize the soil improvement and moisture control effect and significantly promote crop growth. It is an object of the present invention to provide a novel soil improvement and moisture control composition composed mainly of industrial wastes and consisting only of inorganic materials.
본 발명의 다른 목적은 상기 토양개량 및 수분조절제의 제조방법을 제공하며, 본 발명의 또다른 목적은 하기 명세서의 상세한 설명에 의하여 명백하여 질 것이다.Another object of the present invention to provide a method for producing the soil improvement and moisture control agent, another object of the present invention will become apparent by the detailed description of the following specification.
본 발명의 상기 목적은 산업폐기물중 무기재료를 선택하여 그 조성비율을 확정하고, 바람직한 토양개량 및 수분조절제 조성물을 제조한 다음 본 발명 토양개량 및 수분조절제 조성물을 다양한 작물재배에 적용하고 그 생육 실험결과를 평가하므로써 달성하였다.The above object of the present invention is to select the inorganic material in the industrial waste to determine its composition ratio, to prepare the desired soil improvement and moisture control composition, and then apply the soil improvement and moisture control composition of the present invention to various crop cultivation and its growth experiment Achieved by evaluating the results.
이하, 본 발명의 구성 및 효과를 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, the structure and effect of this invention are demonstrated.
본 발명은 산업폐기물 중 토양개량 및 수분조절 효과가 우수한 무기재료를 선택하여 그 조성비율을 확정하는 단계와; 토양개량 및 수분조절제 조성물을 제조하는 단계와; 본 발명 토양개량 및 수분조절제 조성물을 다양한 작물에 적용하여 성장촉진 효과 및 생산량 증대효과를 확인하기 위해 실제 재배시험을 실시하고 그 결과를 평가하는 단계로 구성됨을 특징으로 한다.The present invention comprises the steps of selecting the inorganic material excellent in soil improvement and moisture control effect of industrial wastes and determining the composition ratio; Preparing a soil improvement and moisture control composition; The present invention is characterized by consisting of a step of performing the actual cultivation test and evaluating the results in order to confirm the growth promoting effect and production increase effect by applying the soil improvement and moisture control composition to a variety of crops.
본 발명은 제지슬러지 10∼30 중량%, 플라이 애쉬(Fly ash) 5∼15 중량%, 화이트카본 (White Carbon) 10∼30 중량%, 제올라이트(Zeolite) 10∼30 중량%, 퍼얼라이트 (pearlite) 20∼40 중량%, 수성접착제 CMC 1∼3 중량%로 구성됨을 특징으로 하는 토양개량 및 수분조절제 조성물에 관한 것이다.The present invention is 10 to 30% by weight of paper sludge, 5 to 15% by weight of fly ash, 10 to 30% by weight of white carbon, 10 to 30% by weight of zeolite, pearlite It relates to a soil improvement and moisture control composition, characterized in that consisting of 20 to 40% by weight, 1 to 3% by weight of the aqueous adhesive CMC.
또한 본 발명은 제지슬러지 10∼30 중량%, 플라이 애쉬(Fly ash) 5∼15 중량%, 화이트카본 (White Carbon) 10∼30 중량%, 제올라이트(Zeolite) 10∼30 중량%, 퍼얼라이트 (pearlite) 20∼40 중량%, 수성접착제 CMC 1∼3 중량%로 구성된 조성물을 로타리 혼합기에 투입하는 단계와; 50∼100rpm으로 혼합하는 단계와; 익스크루더(Excluder)에서 과립상으로 제조하는 단계와; 상기 과립상 제품을 130∼150℃의 온도의 가열건조기에서 20∼30분간 가열건조하는 단계의 결합을 특징으로 하는 토양개량 및 수분조절제 조성물의 제조방법에 관한 것이다.In addition, the present invention is 10 to 30% by weight of paper sludge, 5 to 15% by weight of fly ash, 10 to 30% by weight of white carbon, 10 to 30% by weight of zeolite, pearlite A) a composition comprising 20 to 40% by weight, and 1 to 3% by weight of an aqueous adhesive CMC; Mixing at 50-100 rpm; Preparing the granules in an extruder; It relates to a soil improvement and a method for producing a moisture control composition characterized in that the granular product is combined with a step of heat drying 20-30 minutes in a heat dryer at a temperature of 130 ~ 150 ℃.
본 발명은 제지슬러지 10∼50 중량%, 플라이 애쉬(Fly ash) 5∼15 중량%, 제올라이트(Zeolite) 10∼40 중량%, 규조토 10∼40 중량%, 수성접착제 CMC 1∼3 중량%로 구성됨을 특징으로 하는 토양개량 및 수분조절제 조성물에 관한 것이다.The present invention is composed of 10 to 50% by weight of paper sludge, 5 to 15% by weight of fly ash, 10 to 40% by weight of zeolite, 10 to 40% by weight of diatomaceous earth, and 1 to 3% by weight of aqueous adhesive CMC. It relates to a soil improvement and moisture control composition characterized in that.
또한 본 발명은 제지슬러지 10∼50 중량%, 플라이 애쉬(Fly ash) 5∼15중량%, 제올라이트(Zeolite) 10∼40 중량%, 규조토 10∼40 중량%, 수성접착제 CMC 1∼3 중량%로 구성된 조성물을 로타리 혼합기에 투입하는 단계와; 50∼100rpm으로 혼합하는 단계와; 익스크루더(Excluder)에서 과립상으로 제조하는 단계와; 상기 과립상 제품을 130∼150℃의 온도의 가열건조기에서 20∼30분간 가열건조하는 단계의 결합을 특징으로 하는 토양개량 및 수분조절제 조성물의 제조방법에 관한 것이다.In the present invention, 10 to 50% by weight of paper sludge, 5 to 15% by weight of fly ash, 10 to 40% by weight of zeolite, 10 to 40% by weight of diatomaceous earth, and 1 to 3% by weight of aqueous adhesive CMC Introducing the constructed composition into a rotary mixer; Mixing at 50-100 rpm; Preparing the granules in an extruder; It relates to a soil improvement and a method for producing a moisture control composition characterized in that the granular product is combined with a step of heat drying 20-30 minutes in a heat dryer at a temperature of 130 ~ 150 ℃.
우리나라를 비롯하여 동남아시아의 수도작 재배용 논토양(畓土壤)은 질소 및 가리 등 무기질 비료의 연용에 의하여 계속 산성화하여 가면서 그 소출의 한계를 나타내 왔으며, 일반 밭토양이나 염류집적이 큰 대형 비닐하우스 단지 재배토양도 과다한 농약의 사용과 함께 N, P, K 위주의 화학비료 시용의 남용으로 인하여 토양내 과잉 염류집적과 작물의 연작피해가 심각하게 나타나고 있다.Paddy soils for cultivating water crops in South Korea and Southeast Asia, including Korea and Korea, continue to be acidified by the use of mineral fertilizers such as nitrogen and gari, and have shown their limitations. Excessive concentrations of salts in the soil and crop damage in the soil have been seriously affected by the use of N, P, and K chemical fertilizers, along with the use of excessive pesticides.
특히, 최근 다수확 수도품종의 보급과 함께 비료 및 농약의 사용량이 급격히 증가하게 되어 우리나라의 경우 1980년도 비료 소비량을 보면 ㏊당 285㎏에 불과하던 것이 1990년도에는 458㎏으로 약 60% 이상 급증하였으며, 농약사용량에 있어서도 1980년도 5.8㎏/㏊에서 1990년도에는 10.4㎏/㏊로 약 80% 증가하였다(농림수산 주요통계, 농림부, 1994).In particular, as the use of fertilizers and pesticides has increased rapidly with the spread of large-scale crop varieties, Korea's consumption of fertilizers in 1980 increased from only 285 kg per kilogram to 458 kg in 1990. Pesticide use increased by 80% from 5.8kg / kW in 1980 to 10.4kg / kW in 1990 (Ministry of Agriculture, Forestry and Fisheries, Ministry of Agriculture, 1994).
본 발명은 상기와 같은 문제점에 착안하여 안출한 것으로 신규한 형태의 무기물 주재의 토양개량 및 수분조절제 조성물을 제공하기 위하여 토양개량 및 수분조절제 조성물의 성능과 효과를 테스트하기 위한 공시재료로서 일품벼를 준시비법에 맞추어 실제 재배시험을 실시하고, 그 결과는 생육단계별 초장, 분얼수, 출수기 엽면적 및 건물중 성숙기의 특성 및 수량 등을 조사하였다.The present invention has been devised in view of the above problems to provide a new material of the soil reforming and moisture control composition to provide a soil modifier and a moisture control composition to test the performance and effect of the soil improvement and moisture control composition as a test material The actual cultivation test was carried out in accordance with the secret method, and the results were examined for the height, number of grains, leaf area of harvesting season, and the characteristics and quantity of maturation stage in the building.
한편, 본 발명 무기질 토양개량 및 수분조절제 시용에 의한 노지에 있어서의 소맥의 근부 병해 방지를 비롯 식물성장촉진 및 생육효과를 실험하였으며, 기타 채소 원예작물중 마늘 및 양파에 대한 포장시험에 의하여 성장촉진 효과를 확인하였다.On the other hand, plant growth promotion and growth effects, including the prevention of root diseases of wheat in the open field by the mineral soil improvement and the application of a moisture control agent of the present invention, and the growth promotion by the field test on garlic and onion among other vegetable horticultural crops The effect was confirmed.
이밖에도 본 발명품인 토양개량 및 수분조절제 조성물을 염류집적 장해가 극심한 참외 및 고추식물에 대한 성장 및 생육촉진 효과도 실제 재배시험 결과에 의거 확인하였다.In addition, the soil improvement and moisture control composition of the present invention was confirmed that the growth and growth promoting effects on the melon and red pepper plants with severe salt accumulation obstacles based on the actual cultivation test results.
본 발명에 있어서, 선택된 산업폐기물은, 펄프 및 제지공장에서 폐기되는 제지슬러지(Sludge)와 화력발전소에서 발생하는 플라이 애쉬(Fly ash), 그리고 고무가황촉진제 제조 부산물인 화이트카본(white carbon)이며, 토양의 보수력을 극대화하시키기에 적합한 원료성분으로서 제올라이트(Zeolite)와 퍼얼라이트(pearlite) 그리고 규조토가 선택되었다.In the present invention, the selected industrial waste is paper sludge disposed in pulp and paper mills, fly ash generated from thermal power plants, and white carbon, a by-product of rubber vulcanization accelerator production. Zeolite, pearlite and diatomaceous earth were selected as suitable raw materials for maximizing soil water retention.
본 발명에서 선택하는 플라이 애쉬에는 규산질, 알루미늄, 석회질, 철분 공급을 목적으로 하며 화이트카본의 주성분은 규산질이다. 따라서, 본 발명 조성물의 구성원료 중 플라이 애쉬와 화이트카본은 토양의 입단(粒團; aggregate) 형성에 촉진적 역할을 하여 결국 토양공극율을 극대화하게 된다. 또, 본 발명 조성물의 구성원료 중 퍼얼라이트 및 규조토는 미세분말로서 수성접착제인 CMC와 가교결합에 의해 본 발명 제품의 입상제품화에 유효한 작용을 하게 하기 위하여 선택된다.The fly ash selected in the present invention is for the purpose of supplying siliceous, aluminum, calcareous, iron and the main component of the white carbon is siliceous. Therefore, fly ash and white carbon in the composition of the present invention plays a role in promoting the formation of aggregates in the soil and eventually maximizes the soil porosity. In addition, the ferrite and diatomaceous earth in the composition of the present invention are selected to make effective action in the granular product of the present invention by crosslinking with the aqueous adhesive CMC as fine powder.
실시예 1 : 본 발명 토양개량 및 수분조절제 조성물(I)을 구성하는 산업폐기물 구성(단위 : 중량%)Example 1: Industrial waste composition constituting the present invention soil improvement and moisture control composition (I) (unit: weight%)
본 발명 토양개량 및 수분조절제 조성물의 바람직한 조성비는 전체 100에 대하여 하기 표 1의 상하한 중량%의 혼합구성이 바람직하며 제지슬러지 20 중량%, 플라이 애쉬 10 중량%, 화이트카본 18.5 중량%, 제올라이트 20 중량%, 퍼얼라이트 30 중량%, CMC 1.5 중량%가 가장 바람직하였다.Preferred composition ratio of the soil improvement and moisture control composition of the present invention is preferably a mixed composition of the upper and lower weight% of Table 1 with respect to the total 100, paper 20% by weight, fly ash 10% by weight, white carbon 18.5% by weight, zeolite 20 Most preferred were wt%, pearlite 30 wt% and CMC 1.5 wt%.
실시예 2 : 본 발명 토양개량 및 수분조절제 조성물(I) 제품의 제조Example 2 Preparation of the Soil Improvement and Moisture Control Composition (I) Product of the Invention
상기 실시예 1에 기재된 산업폐기물을 선택하여 수집 선별하고 이들을 각각 홉퍼(Hopper)에 투입한 다음, 상기 게기한 중량의 배합비로 로타리 혼합기(Rotary mixer)에 자동적으로 투입시켰다. 이때 홉퍼의 종류와 투입량의 결정은 사전에 계산하여 프로그램에 의하여 메모리를 거쳐 마이컴을 통하여 작동하도록 설계하였다. 이와 같은 프로그램의 설계 및 운영은 당업자간에 용이하게 실시할 수 있다.The industrial wastes described in Example 1 were selected, collected and sorted, and each of them was put into a hopper, and then automatically put into a rotary mixer at a mixing ratio of the weights. At this time, the determination of the type and the input amount of the hopper was calculated in advance and designed to operate through the microcomputer through the memory by the program. The design and operation of such a program can be easily carried out by those skilled in the art.
로타리 혼합기에서 구성원료 성분의 혼합속도는 중요하지 않으나 50∼100rpm이면 바람직하다.The mixing speed of the component ingredients in the rotary mixer is not critical but is preferably 50 to 100 rpm.
혼합된 원료성분은 혼합기의 측면에 설치된 콘베이어 시스템에 의하여 콘베이어 벨트를 타고 과립(顆粒)상으로 제품화하기 위한 끝단에 다이스(Dice)가 부착된 익스트루더 장치(Extruder)에 투입하여 입상제품화하고 이를 130∼150℃의 가열건조기에서 20∼30분간 건조시켜 최종제품화 하였다.The mixed raw material is granulated and put into an extruder with a die attached to the end for forming a granular product on a conveyor belt by a conveyor system installed on the side of the mixer. The product was dried by drying for 20 to 30 minutes in a heat dryer at 130 to 150 ° C.
이때, 상기 혼합기에서 원료성분간의 접착과 과립화 제품 촉진을 위하여 사용되는 수성접착제는 다양한 것을 사용할 수 있으나 CMC가 가장 바람직하다.At this time, the water-based adhesive used to promote the adhesion between the raw material components and granulated products in the mixer can be used a variety of CMC is most preferred.
실험예 1 : 본 발명 토양개량 및 수분조절제 조성물(I)의 토양화학적 특성 및 중금속 오염여부 조사Experimental Example 1 Investigation of Soil Chemical Characteristics and Heavy Metal Contamination of Soil Improvement and Moisture Control Composition (I) of the Present Invention
본 발명 상기 실시예 1의 조성과 실시예 2의 제조방법에 따라 제조된 신규한 토양개량 및 수분조절제 조성물의 토양화학적 특성과 중금속 오염여부에 관한 시험결과는 표 2 및 표 3와 같다.Test results of soil chemical properties and heavy metal contamination of the novel soil improvement and moisture control composition prepared according to the composition of Example 1 and the preparation method of Example 2 are shown in Table 2 and Table 3.
본 발명 제품의 pH는 7.8로서 나타났다.The pH of the product of the present invention was shown as 7.8.
실험예 2 : 조성물 I의 수도재배 포장시험Experimental Example 2: Tap water culture packaging test of composition I
본 발명 토양개량 및 수분조절제 조성물 I을 1ton/10a을 이앙기 30일전에 전량 기비로 사용하고 쎄레질한 다음 표준 시비법에 의거 대조구(본 발명품 무시용구)와 대비하여 생육단계별 생육지수를 조사하였다. 생육조사는 지표면으로부터 최상위 잎 선단 끝까지 6주를 측정하였고, 분얼수는 잎이 3매 전개된 것만 3반복으로 조사하고 건물중은 순환열풍건조기 80℃에서 3일간 건조후 무게를 측정한 값이며, 수량은 1평(坪)당 3반복에서 예취후 정조와 짚의 생산량을 조사한 것이다(표 4 내지 7 참조).The soil improvement and moisture control composition I of the present invention was used as a total amount of 1ton / 10a 30 days before the rice transplanter and ceres, and then investigated the growth index of each growth stage compared to the control (inventive disregard) according to the standard fertilization method. The growth survey measured 6 weeks from the ground surface to the tip of the top leaf, and the number of grains was measured with 3 repetitions of only 3 leaf spreads, and the weight of the building was measured after drying for 3 days at 80 ℃ in a circulating hot air dryer. Yields were the yields of crude and straw produced after harvesting at three repetitions per square foot (see Tables 4-7).
이상, 실험을 통하여 확인된 바와 같이 본 발명 제품을 시용한 제1년도부터 논토양의 개량 및 수분조절효과에 의하여 수도작물의 특성이 크지는 않으나 대체적으로 2∼5% 정도 모두 향상된 것을 확인할 수 있으며, 본 발명 제품을 2년이상 시용예는 20% 이상 증수효과가 기대될 수 있다고 판단되었다.As described above, the characteristics of the crops are not large due to the improvement of paddy soil and moisture control effect from the first year of applying the present invention as confirmed through experiments, but it can be confirmed that the overall improvement is about 2 to 5%. In the case of using the present invention for more than 2 years, it was judged that the increase effect could be expected more than 20%.
실험예 3 : 조성물 I의 소맥 병해방지 및 성장촉진 포장실험Experimental Example 3: wheat disease prevention and growth promoting packaging experiment of composition I
본 발명의 조성물 I을 1ton/10a 파종전 시용하고 시용하지 않은 대조구와 대비하여 표준 시비법에 따라 재배한 후 소맥의 생육지수를 조사하였다(표 8 내지 표 9).The growth index of wheat was investigated after the composition I of the present invention was grown according to the standard fertilization method in comparison with the control group that was applied and not applied to 1ton / 10a before sowing (Tables 8 to 9).
실험결과, 본 발명 조성물 I을 처리한 소맥종자들은 근부병과 같은 질병의 이완율이 현저히 감소되고(약 45% 이상) 성장이 촉진되어 생산성은 약 20%이상 향상되었다.As a result, the wheat seeds treated with the composition I of the present invention significantly reduced the relaxation rate of diseases such as root disease (about 45% or more) and promoted growth, thereby improving the productivity by about 20% or more.
실험예 4 : 조성물 I의 마늘 및 양파 식물에 대한 시용실험Experimental Example 4: Application Test of Garlic and Onion Plants of Composition I
실시예 2에 따라 제조된 본 발명 조성물 I을 공시작물 마늘과 양파에 대하여1ton/10a 포장 시용한 결과 그들의 광합성율, 증산율을 각각 측정하고 수확후 생체중을 측정한 결과는 표 10와 같았다.When the composition 1 of the present invention prepared according to Example 2 was subjected to 1ton / 10a packaging for the starting garlic and onions, their photosynthesis rate and transpiration rate were measured, respectively, and the results of the measurement of the live weight after harvest were shown in Table 10.
이상, 실험결과에서 명백한 바와 같이 본 발명 조성물 I을 시용한 경우 Rf값 0.95의 경우, 양파와 마늘의 경우 모두 45% 이상의 성장촉진에 의한 증수효과가 나타났다.As is apparent from the experimental results, when the composition I of the present invention was applied, the Rf value of 0.95, and the onion and garlic were all increased by 45% or more.
실험예 5 : 조성물 I의 염류집적 장해가 큰 참외 및 고추식물에 대한 시용실험Experimental Example 5: Application Experiments on Melon and Red Pepper Plants with a High Salt Integrity of Composition I
본 발명 조성물 I을 일산시 화훼단지 근처 김삼례씨 농장의 염류집적 장해가 큰 비닐하우스에서 500㎏/10a를 기비(基肥)로 시용한 실험구와 이를 시용하지 않은 대조구에서 고추식물을 재배한 결과는 표 11과 같았다.The results of cultivating red pepper plants in the experimental group and the control group that did not apply 500 kg / 10a to the base in a plastic house with high salt accumulation obstacle in Kim Sam-rye plant farm near Ilhwa city flower garden It was like eleven.
상기 실험결과에서 확인할 수 있듯이 본 발명 조성물 I의 처리구에서 광합성량, 엽록소함량, 기공 컨덕턴스가 향상되어 결실율이 54%이상 향상되었다.As can be seen from the experimental results, the photosynthesis amount, chlorophyll content, and pore conductance were improved in the treatment section of the composition I of the present invention, and the deletion rate was improved by 54% or more.
실시예 3 : 본 발명 토양개량 및 수분조절제 조성물(II)을 구성하는 산업폐기물 구성(단위 : 중량%)Example 3 Industrial Waste Composition Constituting Soil Improvement and Moisture Control Composition (II) of the Present Invention (Unit: wt%)
본 발명 토양개량 및 수분조절제 조성물의 바람직한 조성비는 전체 100에 대하여 하기 표 12의 상하한 중량%의 혼합구성이 바람직하며 제지슬러지 38.5 중량%, 플라이 애쉬 10 중량%, 제올라이트 30 중량%, 규조토 20 중량%(토지개량을 주목적으로 사용하는 경우: 15 중량%, 수분조절을 주목적으로 사용하는 경우: 25 중량%), CMC 1.5 중량%가 가장 바람직하였다.Preferred composition ratio of the present invention soil improvement and moisture control agent composition is preferably a mixed composition of the upper and lower weight% of Table 12 with respect to the total 100, 38.5% by weight of paper sludge, 10% by weight of fly ash, 30% by weight of zeolite, 20% by weight of diatomaceous earth The most preferred were% (15% by weight for the main purpose of land improvement: 25% by weight for the main purpose of moisture control) and 1.5% by weight of CMC.
실시예 4 : 본 발명 토양개량 및 수분조절제 조성물(II) 제품의 제조Example 4 Preparation of the Soil Improvement and Moisture Control Composition (II) Product of the Invention
상기 실시예 3에 기재된 산업폐기물을 선택하여 수집 선별하고 이들을 각각 홉퍼(Hopper)에 투입한 다음, 상기 게기한 중량의 배합비로 로타리 혼합기(Rotary mixer)에 자동적으로 투입시켰다. 이때 홉퍼의 종류와 투입량의 결정은 사전에 계산하여 프로그램에 의하여 메모리를 거쳐 마이컴을 통하여 작동하도록 설계하였다. 이와 같은 프로그램의 설계 및 운영은 당업자간에 용이하게 실시할 수 있다.The industrial wastes described in Example 3 were selected, collected and sorted, and each of them was put into a hopper, and then automatically put into a rotary mixer at a mixing ratio of the weights. At this time, the determination of the type and the input amount of the hopper was calculated in advance and designed to operate through the microcomputer through the memory by the program. The design and operation of such a program can be easily carried out by those skilled in the art.
로타리 혼합기에서 구성원료 성분의 혼합속도는 중요하지 않으나 50∼100rpm이면 바람직하다.The mixing speed of the component ingredients in the rotary mixer is not critical but is preferably 50 to 100 rpm.
혼합된 원료성분은 혼합기의 측면에 설치된 콘베이어 시스템에 의하여 콘베이어 벨트를 타고 과립(顆粒)상으로 제품화하기 위한 끝단에 다이스(Dice)가 부착된 익스트루더 장치(Extruder)에 투입하여 입상제품화하고 이를 130∼150℃의 가열건조기에서 20∼30분간 건조시켜 최종제품화 하였다.The mixed raw material is granulated and put into an extruder with a die attached to the end for forming a granular product on a conveyor belt by a conveyor system installed on the side of the mixer. The product was dried by drying for 20 to 30 minutes in a heat dryer at 130 to 150 ° C.
이때, 상기 혼합기에서 원료성분간의 접착과 과립화 제품 촉진을 위하여 사용되는 수성접착제는 다양한 것을 사용할 수 있으나 CMC가 가장 바람직하다.At this time, the water-based adhesive used to promote the adhesion between the raw material components and granulated products in the mixer can be used a variety of CMC is most preferred.
실험예 6 : 조성물 II의 수도재배 포장시험Experimental Example 6: Water cultivation packaging test of composition II
본 발명 토양개량 및 수분조절제 조성물 II를 1ton/10a을 이앙기 30일전에 전량 기비로 사용하고 쎄레질한 다음 표준 시비법에 의거 대조구(본 발명 조성물 II 무시용구)와 대비하여 생육단계별 생육지수를 조사하였다. 생육조사는 다음에 나타난 사항에 대해서 행해졌다. 생육조사는 지표면으로부터 최상위 잎 선단 끝까지 6주를 측정하였고, 분얼수는 잎이 3매 전개된 것만 3반복으로 조사하고 건물중은 순환열풍건조기 80℃에서 3일간 건조후 무게를 측정한 값이며, 수량은 1평(坪)당 3반복에서 예취후 정조와 짚의 생산량을 조사한 것이다.Using the soil improvement and moisture control composition II of the present invention 1ton / 10a 30 days before the rice transplanter as a total amount of air and ceres, the growth index of each growth stage was investigated in comparison with the control (inventive composition II disregarding tool) according to the standard fertilization method . Growth surveys were conducted on: The growth survey measured 6 weeks from the ground surface to the tip of the top leaf, and the number of grains was measured with 3 repetitions of only 3 leaf spreads, and the weight of the building was measured after drying for 3 days at 80 ℃ in a circulating hot air dryer. Yield is the yield of straw and straw after harvesting at three repetitions per square foot.
그 결과, 실험구와 대조구에서의 생육단계별 잎길이의 변화(cm)에 있어서, 수 %정도 실험구가 우수한 것을 확인할 수 있었다. 또한, 분열수의 변화(단위 : 개/주), 그 위에 출수기의 옆면적 및 건조중량, 성숙기의 작물학적 특성(간장(cm), 수장(cm), 수수(개/주), 정조수량(kg/10a), 짚수량(kg/10a))도 실험구와 대조구에서 동일한 경향을 나타내었다.As a result, in the change (cm) of leaf length for each growth stage in the experimental and control groups, it was confirmed that the experimental group was excellent by about several%. In addition, changes in fission water (unit: dogs / week), side area and dry weight of the extraction stage, crop characteristics of the maturation period (soy sauce (cm), water length (cm), sorghum (dogs / weeks), and crude water quantity ( kg / 10a), the amount of straw (kg / 10a) also showed the same trend in the experimental and control.
이상, 실험을 통하여 확인된 바와 같이 본 발명 조성물 II를 시용한 제1년도부터 논토양의 수분조절효과에 의하여 수도작물의 특성이 크지는 않으나 대체적으로 2∼5% 정도 모두 향상된 것을 확인할 수 있으며, 본 발명 제품을 2년이상 시용예는 20% 이상 증수효과가 기대될 수 있다고 판단되었다.As described above, it was confirmed that the characteristics of the crops were not large due to the moisture control effect of the non-soil from the first year of applying the composition II of the present invention as shown in the experiment, but the overall improvement was about 2 to 5%. It was determined that the application of the present invention for more than two years can be expected to increase more than 20%.
실험예 7 : 조성물 II의 소맥 병해방지 및 성장촉진 포장실험Experimental Example 7: wheat disease prevention and growth promoting packaging experiment of composition II
본 발명 조성물 II를 1ton/10a 파종전 시용하고 시용하지 않은 대조구와 대비하여 표준 시비법에 따라 재배한 후 소맥의 생육지수를 조사하였다. 조사항목은, 발아종자수(개), 싹의 길이(cm), 뿌리길이(cm), 싹 및 뿌리의 건조중량(mg)이다.The growth index of wheat was investigated after cultivating the composition II of the present invention in accordance with the standard fertilization method in contrast to the control, which was applied and not applied to 1ton / 10a before sowing. The items to be examined are the number of germinated seeds (dog), shoot length (cm), root length (cm), dry weight of shoots and roots (mg).
실험결과, 본 발명품을 처리한 소맥종자들은 근부병과 같은 질병의 이완율이 현저히 감소되고(약 45% 이상) 성장이 촉진되어 생산성은 약 20%이상 향상되었다.As a result, the wheat seed treated with the present invention significantly reduced the relaxation rate of diseases such as root disease (about 45% or more) and promoted the growth, thereby improving the productivity by about 20% or more.
실험예 8 : 조성물 II의 마늘 및 양파 식물에 대한 본 발명품 시용실험Experimental Example 8: Application of the Invention to Garlic and Onion Plants of Composition II
실시예 4에 따라 제조된 본 발명 조성물 II를 공시작물 마늘과 양파에 대하여 1ton/10a 포장 시용한 결과 그들의 광합성율, 증산율을 각각 측정하였다.The composition II of the present invention prepared according to Example 4 was subjected to 1ton / 10a packaging for the starting garlic and onion, and their photosynthesis rate and transpiration rate were respectively measured.
실험 결과, 본 발명품을 시용한 경우 Rf값 0.95의 경우, 양파와 마늘의 경우 모두 45% 이상의 성장촉진에 의한 증수효과가 나타났다.As a result of the experiment, when the present invention was applied, in the case of Rf value of 0.95, the onion and garlic both showed the effect of increasing the growth by more than 45%.
실험예 9 : 조성물 II의 염류집적 장해가 큰 참외 및 고추식물에 대한 본 발명품 시용실험Experimental Example 9 Experimental Application of the Invention for Melon and Red Pepper Plants with a High Salt Integrity of Composition II
본 발명 조성물 II를 일산시 화훼단지 근처 김삼례씨 농장의 염류집적 장해가 큰 비닐하우스에서 500㎏/10a를 기비(基肥)로 시용한 실험구와 이를 시용하지 않은 대조구에서 고추식물을 재배하였다.Composition II of the present invention was grown red pepper plants in the experimental group and 500 kg / 10a was applied to the base in the salt house of the Kim Samrye seed farm near the flower garden in Ilsan City with a large salt accumulation obstacle.
실험결과, 본 발명 조성물 II의 처리구에서 광합성량, 엽록소함량, 기공 컨덕턴스가 향상되어 결실율이 54%이상 향상되었다.As a result, the photosynthesis amount, chlorophyll content, and pore conductance were improved in the treatment section of the composition II of the present invention, and the deletion rate was improved by 54% or more.
이상의 실시예 및 실험예에 의하여, 본 발명의 토양개량 및 수분조절제를 시용한 경우 화본과 작물인 벼와 소맥을 비롯하여 기타 원예작물 중 공시 작물의 현저한 생육촉진 효과가 있음을 확인하였다. 본 발명에서는 생육초기에 본 발명제품을 시용하였지만, 본 발명제품은 무기물을 주성분으로 하여 조성된 것이므로 생육장애를 초래하지 않는 효과를 가지므로 다양한 작물의 다양한 생육단계에서도 사용이 가능한 뛰어난 효과가 있으므로 토양의 개량산업, 수분조절산업, 폐기물처리산업 및 비료산업상 매우 유용한 발명인 것이다.According to the above examples and experimental examples, when the soil improvement and moisture control agent of the present invention was applied, it was confirmed that there is a marked growth promoting effect of the public crops among other horticultural crops, including rice and wheat, which are flowers and crops. In the present invention, the present invention was applied at the beginning of growth, but since the present invention is composed of inorganic ingredients as a main ingredient, it has an effect that does not cause growth disorders, so it can be used in various growth stages of various crops. It is a very useful invention in the improvement industry, moisture control industry, waste disposal industry and fertilizer industry.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR20040035205A (en) * | 2002-10-18 | 2004-04-29 | 최병권 | A Manufacturing device for Lightweight Earth using the Diatomite and Method for Manufacture thereof |
| CN103262688A (en) * | 2013-05-08 | 2013-08-28 | 四川海吉尔环保科技开发有限公司 | Method utilizing gray gangue in coal gangue to prepare soil |
| US20150376061A1 (en) * | 2014-06-25 | 2015-12-31 | CR Minerals Company, LLC | Pozzolanic compositions containing fly ash and remediation agents for use in cementitious materials |
| US10457601B2 (en) | 2017-02-24 | 2019-10-29 | CR Minerals Company, LLC | Settable compositions comprising remediated fly ash (RFA) and methods of cementing in subterranean formations |
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| JP2003096452A (en) * | 2001-07-19 | 2003-04-03 | Soruteko Kk | Composition for soil consisting of industrial waste |
| JP6079489B2 (en) * | 2013-07-23 | 2017-02-15 | 栗田工業株式会社 | Soil classification treatment agent and classification treatment method |
| CN112195029B (en) * | 2020-10-28 | 2021-07-27 | 东北大学 | Method and device for preparing soil conditioner by using coal ash synthetic zeolite to treat wastewater |
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| JPS6017440B2 (en) * | 1980-08-29 | 1985-05-02 | 高崎化成株式会社 | Method for manufacturing soil improvement material using activated sludge as raw material |
| JPS627787A (en) * | 1985-07-05 | 1987-01-14 | Sunaken Kk | Soil amending agent |
| JPH06133644A (en) * | 1992-02-05 | 1994-05-17 | Akira Oguri | Lightweight admixture and its production |
| JP2717222B2 (en) * | 1994-06-14 | 1998-02-18 | 日本セメント株式会社 | Filling material for vegetation in pores of alkali-cured material |
| JPH09111238A (en) * | 1995-10-18 | 1997-04-28 | Honsyu Sangyo Kk | Soil modifier and its production |
| JPH11217566A (en) * | 1998-02-04 | 1999-08-10 | Sekisui Chem Co Ltd | Soil-improving agent, production of soil-improving agent, planting substrate using soil improving agent and production of the same planting substrate |
| JP4573924B2 (en) * | 1999-05-27 | 2010-11-04 | 奥多摩工業株式会社 | Agglomerated zeolite, production method thereof and seedling culture soil |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040035205A (en) * | 2002-10-18 | 2004-04-29 | 최병권 | A Manufacturing device for Lightweight Earth using the Diatomite and Method for Manufacture thereof |
| CN103262688A (en) * | 2013-05-08 | 2013-08-28 | 四川海吉尔环保科技开发有限公司 | Method utilizing gray gangue in coal gangue to prepare soil |
| US10377667B2 (en) | 2014-06-25 | 2019-08-13 | CR Minerals Company, LLC | Pozzolanic compositions containing fly ash and remediation agents for use in cementitious materials |
| US9561983B2 (en) * | 2014-06-25 | 2017-02-07 | CR Minerals Company, LLC | Pozzolanic compositions containing fly ash and remediation agents for use in cementitious materials |
| US10017418B2 (en) | 2014-06-25 | 2018-07-10 | CR Minerals Company, LLC | Pozzolanic compositions containing fly ash and remediation agents for use in cementitious materials |
| US10370295B2 (en) | 2014-06-25 | 2019-08-06 | CR Minerals Company, LLC | Pozzolanic compositions containing fly ash and remediation agents for use in cementitious materials |
| US20150376061A1 (en) * | 2014-06-25 | 2015-12-31 | CR Minerals Company, LLC | Pozzolanic compositions containing fly ash and remediation agents for use in cementitious materials |
| US10689292B2 (en) | 2014-06-25 | 2020-06-23 | CR Minerals Company, LLC | Pozzolanic compositions containing fly ash and remediation agents for use in cementitious materials |
| US11299424B2 (en) | 2014-06-25 | 2022-04-12 | CR Minerals Company, LLC | Pozzolanic compositions containing fly ash and remediation agents for use in cementitious materials |
| US11773018B2 (en) | 2014-06-25 | 2023-10-03 | CR Minerals Company, LLC | Pozzolanic compositions containing coal ash and remediation agents for use in cementitious materials |
| US12221380B2 (en) | 2014-06-25 | 2025-02-11 | CR Minerals Company, LLC | Pozzolanic compositions containing coal ash and remediation agents for use in cementitious materials |
| US10457601B2 (en) | 2017-02-24 | 2019-10-29 | CR Minerals Company, LLC | Settable compositions comprising remediated fly ash (RFA) and methods of cementing in subterranean formations |
| US10829414B2 (en) | 2017-02-24 | 2020-11-10 | CR Minerals Company, LLC | Settable compositions comprising remediated fly ash (RFA) and methods of cementing in subterranean formations |
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