KR20020046762A - Gel Type Detergent Putting In an Instrument For a Toilet Stool and The Preparation Method of thereof - Google Patents
Gel Type Detergent Putting In an Instrument For a Toilet Stool and The Preparation Method of thereof Download PDFInfo
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- KR20020046762A KR20020046762A KR1020000077090A KR20000077090A KR20020046762A KR 20020046762 A KR20020046762 A KR 20020046762A KR 1020000077090 A KR1020000077090 A KR 1020000077090A KR 20000077090 A KR20000077090 A KR 20000077090A KR 20020046762 A KR20020046762 A KR 20020046762A
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- 239000003599 detergent Substances 0.000 title claims description 7
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 claims abstract description 55
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 15
- 235000010418 carrageenan Nutrition 0.000 claims abstract description 11
- 239000000679 carrageenan Substances 0.000 claims abstract description 11
- 229920001525 carrageenan Polymers 0.000 claims abstract description 11
- 229940113118 carrageenan Drugs 0.000 claims abstract description 11
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical group [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 229920002148 Gellan gum Polymers 0.000 claims abstract description 6
- 235000010493 xanthan gum Nutrition 0.000 claims abstract description 6
- 239000000230 xanthan gum Substances 0.000 claims abstract description 6
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 6
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000000465 moulding Methods 0.000 claims abstract description 4
- 239000002781 deodorant agent Substances 0.000 claims description 8
- 239000002861 polymer material Substances 0.000 claims description 7
- 239000003349 gelling agent Substances 0.000 claims description 5
- 229920005615 natural polymer Polymers 0.000 claims description 5
- 230000000844 anti-bacterial effect Effects 0.000 claims description 3
- 239000003899 bactericide agent Substances 0.000 claims description 3
- 239000000645 desinfectant Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract 3
- 230000001877 deodorizing effect Effects 0.000 abstract 2
- 235000010492 gellan gum Nutrition 0.000 abstract 1
- 239000000216 gellan gum Substances 0.000 abstract 1
- 239000011874 heated mixture Substances 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 12
- 239000000975 dye Substances 0.000 description 12
- 238000004140 cleaning Methods 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 238000004090 dissolution Methods 0.000 description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 8
- -1 polyoxyethylene Polymers 0.000 description 8
- 239000002994 raw material Substances 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 229920002114 octoxynol-9 Polymers 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 229920003169 water-soluble polymer Polymers 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0068—Deodorant compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
본 발명은 용기형 겔타입 변기세정제 및 이의 제조 방법에 관한 것으로서, 보다 상세하게는 양변기의 급수를 위해 설치되어 있는 저수조에 용기속에 겔타입의세정제를 담가두면 용기 속의 일정 공간에서 세정액이 일정량 서서히 용해되어 있다가 조수조 속의 물이 변기통으로 쏟아져 들어갈때 상기의 용기 속에 일정량 용해되어 있는 세정제가 함께 들어가 변기를 세척해주는 용기형 겔타입의 변기세정제 및 상기한 용기형 겔타입 변기세정제의 제조방법에 관한 것이다.The present invention relates to a container-type gel-type toilet cleaner and a method for manufacturing the same, and more particularly, when a gel-type detergent is immersed in a container installed in a water tank installed for water supply of a toilet bowl, a predetermined amount of cleaning solution is gradually dissolved in a predetermined space in the container. When the water in the tank is poured into the toilet bowl, and the cleaning agent dissolved in a certain amount in the container is added together to clean the toilet bowl-type gel type toilet cleaner and the manufacturing method of the container-type gel type toilet cleaner will be.
종래의 변기세정제에 관한 특허로는 프랑스 특허 제2118767호, 유럽특허 제184416호, 동제55100호, 독일특허 제2407947호, 영국특허 제601123호, 동제2021143호, 동제2061996호 등이 있는바, 이들의 내용은 모두가 세척주성분인 계면활성제와 이들의 용해도 조절을 위한 용해도 조절을 필수 구성성분으로 하고, 여기에 향, 염료, 살균제 등을 함유하고 있다. 그러나 이렇게 조성된 무용기형 변기세정제는 원료비가 저렴한 장점이 있는 반면 용융점이 낮은 계면활성제와 용해도 조절제가 사용되기 때문에 물탱크 안에 장시간 담가둘 경우 형태가 변형되거나 쉽게 녹아버리는 결과로 사용시 색상의 변화가 심해지고 사용기간이 단축되어 소비자들의 불만 및 제품의 이미지를 손상시키는 단점이 있었다. 또한 이러한 단점을 극복하기 위하여 용융점이 높은 왁스류나 무기염들을 첨가하여 사용하고 있으나, 이 경우에는 조성물의 물성에 심각한 악영향을 끼치게 되고 실제 사용시 수면에 왁스 등의 부유물이 뜨게 되고, 무기염의 빠른 용해에 따른 제품의 수명단축 등의 심각한 문제점을 보여 새로운 형태의 변기세정제가 요구되어 왔었다.Patents related to conventional toilet cleaners include French Patent No. 2118767, European Patent No. 184416, Copper No. 55100, German Patent No. 2407947, British Patent No. 601123, Copper No. 2021143, No. 2061996, etc. The contents of the present invention include surfactants, which are all main components of washing, and solubility control for controlling solubility thereof as essential components, and contains fragrances, dyes, fungicides, and the like. However, this type of toilet-type toilet cleaner has the advantage of low raw material cost, but the low melting point surfactant and solubility control agent are used, so if it is immersed in the water tank for a long time, the shape changes or melts easily. However, there is a disadvantage in that the use period is shortened and the customer's dissatisfaction and the image of the product are damaged. In addition, in order to overcome these disadvantages, waxes or inorganic salts having a high melting point are added and used, but in this case, they have a serious adverse effect on the physical properties of the composition. Due to serious problems such as shortening the life of the product, a new type of toilet cleaner has been required.
또한 종래의 변기세정제는 케익형으로 1종이상의 비이온 계면활성제와 1종이상의 음이온 계면활성제, 요소 및 물을 주성분으로 하여 제조되고 60℃이상에서 액상으로 전환하기 위해 상기 원료들을 고온에서 가열 용해하여 혼합하는 방법이 사용되었다. 그러나 상기와 같은 방법으로 혼합할 경우에 기타 첨가제로 사용되는 분말색소 원료가 액체원료와 균일하게 혼합되기 어려워 실제로 사용시 온도 변화에 따라 용해 및 분산에 의해 색도의 차이가 크고 용해 속도가 불균일하여 지속적이고 균일한 세정효과를 기대하기 어려운 문제점이 있었다.In addition, a conventional toilet cleaner is prepared in the form of a cake with at least one nonionic surfactant and at least one anionic surfactant, urea and water as the main components and by heating and dissolving the raw materials at a high temperature to convert to a liquid at 60 ℃ or more The method of mixing was used. However, when it is mixed in the above way, the powder pigment raw materials used as other additives are difficult to be uniformly mixed with the liquid raw materials. Therefore, the color difference is large due to dissolution and dispersion depending on the temperature change during use, and the dissolution rate is uneven. There was a problem that it is difficult to expect a uniform cleaning effect.
본 발명은 상기와 같은 종래기술의 문제점을 해결하기 위한 것으로, 본 발명자들이 예의 연구한 결과, 주 세척 성분인 비이온 계면활성제에 천연고분자 물질을 용해도 조절 및 겔화제로 사용하고 보조 성분으로 살균제, 염료 및 탈취제를 배합하고, 상기 배합된 조성물을 80℃이상의 물로 용해한 후 실온으로 냉각하여 겔상의 변기세정제 조성물을 제조한 결과 온도 변화에 따라 용해, 분산에 의한 색도 차이가 적고 용해 속도가 균일한 것을 확인하고 본 발명을 완성하게 되었다.The present invention is to solve the problems of the prior art as described above, the present inventors earnestly researched, using a natural polymer material as a solubility control and gelling agent in the non-ionic surfactant as the main cleaning component, as a secondary component bactericide, dye And a deodorant, and the blended composition was dissolved in water of 80 ° C. or higher, and then cooled to room temperature to prepare a gel-type toilet cleaner composition. As a result, the difference in color due to dissolution and dispersion was small and the dissolution rate was uniform. This invention was completed.
결국 본 발명은 천연 수용성 고분자물질, 비이온계면활성제, 탈취제 및 살균제 등의 성분을 혼합하여 사용기간 동안 용해도와 색상을 일정하게 유지할 수 있는 용기형 겔타입 변기세정제의 조성물을 제공하는 것을 목적으로 한다.After all, an object of the present invention is to provide a composition of a container-type gel type toilet cleaner capable of maintaining a constant solubility and color during use by mixing components such as natural water-soluble polymers, nonionic surfactants, deodorants and fungicides. .
또한 본 발명은 사용기간 동안 용해도와 색상을 일정하게 유지할 수 있는 용기형 겔타입 변기세정제 조성물에 사용할 수 있는 천연수용성고분자물질과 이의 구성비를 제공하는 것을 목적으로 한다.In addition, an object of the present invention is to provide a natural water-soluble polymer material and a composition ratio thereof that can be used in a container-type gel toilet bowl composition that can maintain a constant solubility and color over the period of use.
본 발명의 또 다른 목적은 사용기간동안 용해도와 색상을 일정하게 유지할 수 있는 용기형 겔타입 변기세정제의 제조방법을 제공하는 것을 목적으로 한다.It is another object of the present invention to provide a method for preparing a container-type toilet bowl cleanser which can maintain a constant solubility and color during use.
제도1은 본 발명의 용기형 겔타입의 변기세정제가 용기에 담겨져 있는 A-A단면도Draft 1 is a cross-sectional view of the container-type toilet gel cleaner of the present invention contained in a container A-A
제도2는 본 발명의 용기형 겔타입 변기세정제의 제조방법을 나타낸 모식도.Scheme 2 is a schematic diagram showing the manufacturing method of the container-type gel toilet bowl cleaner of the present invention.
♣ 도면의 주요 부분에 대한 부호의 설명♣♣ Explanation of symbols for the main parts of the drawing ♣
1: 배출구 2: 캡1: outlet 2: cap
3: 용기 4: 겔타입 세정제3: container 4: gel type cleaner
S1: 혼합단계 S2: 승온단계S1: mixing step S2: heating step
S3: 혼합단계 S4:교반단계S3: Mixing Step S4: Stirring Step
S5:냉각단계S6:성형단계S5: Cooling step S6: Molding step
이하, 본 발명을 더욱 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail.
본 발명의 목적을 달성하기 위한 용기형 겔타입 변기세정제는 천연 수용성 고분자물질 0.1∼10중량부; 비이온계면활성제 1∼30중량부; 탈취제 0.1∼5중량부; 살균제 0.1∼5중량부 및 염료 0.1∼10중량부로 구성되어 있는 것을 특징으로 한다.Container-type gel-type toilet cleaner for achieving the object of the present invention is 0.1 to 10 parts by weight of a natural water-soluble polymer material; 1 to 30 parts by weight of nonionic surfactant; 0.1 to 5 parts by weight of deodorant; It is characterized by consisting of 0.1 to 5 parts by weight of fungicide and 0.1 to 10 parts by weight of dye.
또한 상기의 용해도 조절제 및 겔화제의 용도로 사용되는 천연수용성 고분자물질은 카라게난, 젤란, 크산탄검 중에서 선택된 1종을 사용하는 것을 특징으로 한다.In addition, the natural water-soluble polymer material used for the solubility control agent and the gelling agent is characterized by using one selected from carrageenan, gellan, xanthan gum.
또한 본 발명의 용기형 겔타입 변기세정제의 제조방법은 물과 천연고분자 물질을 혼합하는 단계(S1); 상기한 혼합물의 온도를 70∼80℃로 승온하는 단계(S2); 70∼80℃로 승온된 혼합물에 비이온 계면활성제, 탈취제, 살균제 및 염료 등의 조성물을 혼합하는 단계(S3); 상기 혼합된 조성물을 균일하게 교반하는 단계(S4); 상기 균일하게 혼합된 조성물을 실온으로 냉각하는 단계(S5); 및 냉각된 세정제 조성물을 용기형으로 성형하는 단계(S6)로 구성되어 있는 것을 특징으로 한다.In addition, the method for preparing a container-type toilet bowl cleaner of the present invention comprises the steps of mixing water and natural polymer material (S1); Raising the temperature of the mixture to 70 to 80 ° C. (S2); Mixing a composition such as a nonionic surfactant, a deodorant, a bactericide, and a dye to the mixture heated to 70 to 80 ° C. (S3); Uniformly stirring the mixed composition (S4); Cooling the uniformly mixed composition to room temperature (S5); And molding the cooled detergent composition into a container shape (S6).
용해도 조절제 및 겔화제로 사용하는 수용성 천연고분자들은 구아검, 크산탄검, 알긴산 나트륨, 카라기난 및 젤란 등을 사용할 수 있으며, 그의 배합량은 전 조성물에 대하여 0.1 내지 10 중량부를 사용하는 것이 바람직하다. 0.1중량부 이하에서는 겔화시킬 수 없으며, 10중량부 이상에서는 점성이 너무 높아 다른 성분과 상용성이 좋지 않아 최종 제품에 좋지 않은 영향을 끼칠 수 있다.The water-soluble natural polymers used as solubility regulators and gelling agents may use guar gum, xanthan gum, sodium alginate, carrageenan and gellan, and the amount thereof is preferably 0.1 to 10 parts by weight based on the total composition. It may not gelate at 0.1 parts by weight or less, and at 10 parts by weight or more, the viscosity may be too high and may not be compatible with other components, which may adversely affect the final product.
계면활성제는 세정 작용의 중심적 역할을 하고 있으며, 각종 첨가제와 어울려 흡착, 표면장력 및 계면 장력 저하능, 미셀화, 가용화, 습윤, 유화, 분산 등의종합적이고도 복합적인 작용으로 세정작용이 발휘된다.Surfactants play a central role in the cleaning action. In combination with various additives, the cleaning action is exerted by a comprehensive and complex action of adsorption, surface tension and interfacial tension lowering ability, micelleization, solubilization, wetting, emulsification, and dispersion.
본 발명에서 사용하는 계면활성제는 세정력이 우수한 것이면 특히 한정하지는 않으나, 알코올페닐계, 지방알코올계 및 솔비탄지방산 유도체 등을 사용할 수 있으며, 특히 탄소수 10 내지 16개의 2급 알코올에 에틸렌옥사이드(EO) 부가몰수가 2 내지 40인 알코올계 비이온 계면활성제를 사용사는 것이 바람직하다. 이들 비이온 계면활성제의 배합량은 전 조성에 대하여 1 내지 30중량부가 적당하고, 비이온 계면활성제의 사용량이 1 중량부 이하로 배합하는 경우에는 세정효과를 기대하기 어렵고, 30중량부 이상에서는 사용 후 다량의 기포가 발생하여 수질 환경에 악영향을 끼칠 수 있다.The surfactant used in the present invention is not particularly limited as long as it has excellent detergency, but alcohol phenyl, fatty alcohol, and sorbitan fatty acid derivatives may be used, and in particular, ethylene oxide (EO) may be used for secondary alcohols having 10 to 16 carbon atoms. It is preferable to use the alcohol type nonionic surfactant whose addition mole number is 2-40. The amount of these nonionic surfactants is 1 to 30 parts by weight relative to the total composition, and when the amount of the nonionic surfactant is used in an amount of 1 parts by weight or less, it is difficult to expect a washing effect, and after use, the amount of the nonionic surfactants is higher than 30 parts by weight. A large amount of bubbles can be generated and adversely affect the water environment.
본 발명의 조성물에 사용하는 염료는 0.1 내지 10중량부가 적당하고, 0.1중량부 이하에서는 제품의 청결미가 떨어지게 되고, 10중량부 이상에서는 너무 짙은 색상으로 인하여 거부감을 나타낼 수 있다. 또한 본 발명의 염료 색은 특별히 한정하는 것은 아니지만, 조성물의 청결한 이미지를 부각시키기 위하여 청색염료를 사용하는 것이 바람직하다.The dye used in the composition of the present invention is suitable for 0.1 to 10 parts by weight, the cleanness of the product is less than 0.1 parts by weight, and may be rejected due to too dark color at more than 10 parts by weight. In addition, the dye color of the present invention is not particularly limited, but it is preferable to use a blue dye in order to highlight a clean image of the composition.
본 발명의 용기형 겔타입 변기세정제에는 필요에 따라 향료 등의 첨가제를 함유할 수 있다.The container-type toilet bowl cleanser of the present invention may contain additives such as fragrance if necessary.
용기형 겔타입 변기세정제는 적당량의 물과 0.1∼10중량부의 천연고분자 물질을 혼합(S1)하고 염료 및 분말원료를 균일하게 혼합하기 위해 혼합물의 온도를 70∼80℃로 승온(S2)한다. 승온단계(S2)에서 70℃ 이하의 온도로 조성물을 용해하면 색소 및 분말원료가 균일(homogeneous)하게 혼합되지 않아 사용시 용해 및 분산에 의한 색도 차이가 크게 되고 용해 속도가 일정하지 않아 지속적이고 균일한 세정효과를 기대할 수 가 없게 된다. 70∼80℃로 승온된 혼합물에 1∼30중량부의 비이온 계면활성제, 0.1∼5중량부의 탈취제, 0.1∼5중량부의 살균제 및 0.1∼10중량부의 염료를 혼합(S3)하고 상기 혼합된 조성물을 균일하게 교반(S4)하여 균일(homogeneous)한 상태의 조성물을 제조한 후 상기 균일하게 혼합된 조성물을 실온으로 냉각(S5)하여 겔상의 변기세정제 조성물을 제조한다. 그리고 제조된 겔상의 변기세정제를 용기에 용적하기에 적당한 크기로 성형(S6)한 후 용기에 담아 사용하면 온도변화에 따라 용해 및 분산 속도가 일정하고 균일한 변기세정제로 사용할 수 있다.The container-type gel-type toilet cleaner mixes (S1) an appropriate amount of water and 0.1-10 parts by weight of a natural polymer material and raises the temperature of the mixture to 70-80 ° C. in order to uniformly mix the dye and the powder raw material (S2). When dissolving the composition at a temperature of 70 ° C. or lower in the temperature increase step (S2), the pigment and powder raw materials are not homogeneously mixed, so the difference in chromaticity due to dissolution and dispersion during use is large, and the dissolution rate is not constant. The cleaning effect cannot be expected. 1 to 30 parts by weight of a nonionic surfactant, 0.1 to 5 parts by weight of a deodorant, 0.1 to 5 parts by weight of a disinfectant, and 0.1 to 10 parts by weight of a dye are mixed (S3) and the mixed composition is heated to 70 to 80 ° C. After uniformly stirring (S4) to prepare a homogeneous composition, the uniformly mixed composition is cooled to room temperature (S5) to prepare a gel-like toilet cleaner composition. Then, the gel-type toilet cleaner prepared in a size suitable for the volume of the container (S6) and used in the container can be used as a uniform toilet cleaner with a constant dissolution and dispersion rate according to the temperature change.
상기한 방법으로 제조된 용기형 겔타입 변기세정제는 종래의 변기 세정제보다 우수한 세정력을 가지며, 일정하게 용해 및 분산됨에 따라 세정액의 색상이 일정하게 유지되고 사용기간이 일정하게 유지된다.The container-type gel type toilet cleaner prepared by the above method has superior cleaning power compared to the conventional toilet cleaner, and the color of the cleaning liquid is kept constant and the period of use is kept constant as it is dissolved and dispersed constantly.
이하 실시예에 의하여 본 발명을 보다 구체적으로 설명하고자 한다. 이들 실시예는 오로지 본 발명을 설명하기 위한 것으로, 본 발명의 요지에 따라 본 발명의 범위가 이들 실시예에 국한되지 않는다는 것은 당업계에서 통상의 지식을 가진 자에게 자명할 것이다.Hereinafter, the present invention will be described in more detail with reference to the following examples. These examples are only for illustrating the present invention, and it will be apparent to those skilled in the art that the scope of the present invention is not limited to these examples according to the gist of the present invention.
이하, 본 발명의 실시예 및 비교예에 의하여 상세히 설명한다.It will be described below in detail by Examples and Comparative Examples of the present invention.
[실시예1] 84중량부의 물과 1중량부의 카라기난을 혼합하고 온도를 80℃로 승온한 후 2중량부의 폴리옥시에틸렌글리콜, 5중량부의 탈취제, 3중량부의 살균제 및 5중량부의 염료를 혼합, 교반하여 균일(homogeneous)한 상태의 조성물을 제조한다. 그리고 상기 균일하게 혼합된 조성물을 실온으로 냉각하여 겔상의 변기세정제 조성물을 제조하였다.Example 1 84 parts by weight of water and 1 part by weight of carrageenan were mixed and the temperature was raised to 80 ° C., followed by 2 parts by weight of polyoxyethylene glycol, 5 parts by weight of deodorant, 3 parts by weight of disinfectant, and 5 parts by weight of dye, Agitated to prepare a composition in a homogeneous state. The uniformly mixed composition was cooled to room temperature to prepare a gel-type toilet cleaner composition.
[실시예2] 89중량부의 물과 5중량부의 폴리옥시에틸렌글리콜과 3중량부의 카라기난을 사용한 것 이외에는 실시예1과 동일한 방법 및 조성으로 겔타입의 변기세정제 조성물을 제조하였다.Example 2 A gel-type toilet cleaner composition was prepared in the same manner and composition as in Example 1, except that 89 parts by weight of water, 5 parts by weight of polyoxyethylene glycol, and 3 parts by weight of carrageenan were used.
[실시예3] 73중량부의 물과 6중량부의 카라기난, 3중량부의 폴리옥시에틸렌글리콜, 5중량부의 폴리옥시에틸렌옥틸페닐에테르을 사용한 것 이외에는 실시예1과 동일한 방법 및 조성으로 겔타입의 변기세정제 조성물을 제조하였다.Example 3 Gel-type toilet cleaner composition in the same manner and composition as in Example 1, except that 73 parts by weight of water, 6 parts by weight of carrageenan, 3 parts by weight of polyoxyethylene glycol, and 5 parts by weight of polyoxyethyleneoctylphenylether were used. Was prepared.
[실시예4] 74중량부의 물과 8중량부의 카라기난, 2중량부의 폴리옥시에틸렌글리콜, 3중량부의 폴리옥시에틸렌옥틸페닐에테르을 사용한 것 이외에는 실시예1과 동일한 방법 및 조성으로 겔타입의 변기세정제 조성물을 제조하였다.Example 4 A gel-type toilet cleaner composition in the same manner and composition as in Example 1, except that 74 parts by weight of water, 8 parts by weight of carrageenan, 2 parts by weight of polyoxyethylene glycol, and 3 parts by weight of polyoxyethyleneoctylphenyl ether were used. Was prepared.
[실시예5] 74중량부의 물과 10중량부의 카라기난, 3중량부의 폴리옥시에틸렌글리콜을 사용한 것 이외에는 실시예1과 동일한 방법 및 조성으로 겔타입의 변기세정제 조성물을 제조하였다.Example 5 A gel-type toilet cleaner composition was prepared in the same manner and composition as in Example 1, except that 74 parts by weight of water, 10 parts by weight of carrageenan, and 3 parts by weight of polyoxyethylene glycol were used.
[실시예6] 74중량부의 물과 3중량부의 젤란, 5중량부의 폴리옥시에틸렌글리콜, 5중량부의 폴리옥시에틸렌옥틸페닐에테르을 사용한 것 이외에는 실시예1과 동일한 방법 및 조성으로 겔타입의 변기세정제 조성물을 제조하였다.Example 6 Gel-type toilet cleaner composition in the same manner and composition as in Example 1, except that 74 parts by weight of water, 3 parts by weight of gellan, 5 parts by weight of polyoxyethylene glycol, and 5 parts by weight of polyoxyethyleneoctylphenylether were used. Was prepared.
[실시예7] 72중량부의 물과 5중량부의 크산탄검, 7중량부의 폴리옥시에틸렌글리콜, 3중량부의 폴리옥시에틸렌옥틸페닐에테르을 사용한 것 이외에는 실시예1과 동일한 방법 및 조성으로 겔타입의 변기세정제 조성물을 제조하였다.Example 7 A gel-type toilet in the same manner and composition as in Example 1 except that 72 parts by weight of water, 5 parts by weight of xanthan gum, 7 parts by weight of polyoxyethylene glycol, and 3 parts by weight of polyoxyethyleneoctylphenylether were used. A detergent composition was prepared.
[비교예1] 84중량부의 물과 1중량부의 카라기난을 혼합하고 온도를 60℃로 승온한 후 10중량부의 폴리옥시에틸렌글리콜 및 5중량부의 염료를 혼합, 교반하여 변기세정제 조성물을 제조하였다.[Comparative Example 1] 84 parts by weight of water and 1 part by weight of carrageenan were mixed, and the temperature was raised to 60 ° C., 10 parts by weight of polyoxyethylene glycol and 5 parts by weight of dye were mixed and stirred to prepare a toilet cleaner composition.
[비교예2] 90중량부의 물과 5중량부의 젤란을 혼합한 것 이외에는 비교예1과 동일한 조성 및 방법으로 변기세정제 조성물을 제조하였다.[Comparative Example 2] A toilet cleaner composition was prepared in the same composition and method as in Comparative Example 1 except that 90 parts by weight of water and 5 parts by weight of gellan were mixed.
[비교예3] 60중량부의 물과 10중량부의 카라기난, 5중량부의 크산탄검 및 20중량부의 폴리옥시에틸렌옥틸페닐에테르를 혼합한 것 이외에는 비교예1과 동일한 조성 및 방법으로 변기세정제 조성물을 제조하였다.[Comparative Example 3] A toilet cleaner composition was prepared in the same composition and method as in Comparative Example 1 except that 60 parts by weight of water, 10 parts by weight of carrageenan, 5 parts by weight of xanthan gum, and 20 parts by weight of polyoxyethyleneoctylphenylether were mixed. It was.
상기한 실시예 1 내지 7에 의한 용기형 겔타입 변기세정제 조성물과 비교예 1 내지 3에 의한 통상적인 변기세정제 조성물을 다음의 표1에 정리하여 비교하였다.The container-type toilet bowl composition according to Examples 1 to 7 and the conventional toilet bowl composition according to Comparative Examples 1 to 3 were compared in the following Table 1.
상기 실시예1 내지 7 및 비교예 1 내지 3에서 제조된 용기형 겔타입 변기세정제에 대하여 다음의 안정성과 사용성을 비교한다.For the container-type gel-type toilet cleaners prepared in Examples 1 to 7 and Comparative Examples 1 to 3, the following stability and usability are compared.
1. 안정성 시험1. Stability test
실시예1 내지 7 및 비교예 1 내지 3에서 제조한 용기형 겔타입 변기세정제를 각각 제1도와 같이 용기에 담아, 이를 25℃로 유지하는 수조에서 1개월간 방치하여 내부의 세정제 변화를 육안으로 관찰하여 상태가 안정한 것을 "○"으로, 형태가 깨진 것을 "×"로 표시하였다.The container-type toilet bowl cleaners prepared in Examples 1 to 7 and Comparative Examples 1 to 3 were respectively placed in a container as shown in FIG. 1, and left for 1 month in a water bath maintained at 25 ° C. to visually observe the change of the detergent inside. The state whose stability was stable was indicated by "○" and the one whose form was broken was indicated by "×".
2. 사용성 시험2. Usability test
실시예1 내지 7 및 비교예 1 내지 3에서 제조된 용기형 변기세정제를 각각 제1도와 같이 용기에 담아 수세식 변기 수조내의 물 속에 넣고 수조의 온도를5∼15℃로 온도를 유지하면서 10리터의 물을 600회 교환하였다. 이 때 색소가 분산된 정도에 따라 세정제가 용해된 상태를 판단하여 색소 및 용해상태가 양호하 것을 "○"로, 단기소모 및 분균일한 색도를 나타낸 것을 "×"로 표시하였다.10 liters of the vessel-type toilet cleaners prepared in Examples 1 to 7 and Comparative Examples 1 to 3 were placed in water in a flush toilet and kept at a temperature of 5 to 15 ° C. while keeping the temperature of the tank at 5 to 15 ° C. The water was exchanged 600 times. In this case, the state in which the detergent was dissolved was judged according to the degree to which the dye was dispersed, and the dye and the dissolved state were good, and the ones showing short-term consumption and uniform chromaticity were indicated by "x".
3. 세정력 시험3. Cleaning power test
실시예 1 내지 7 및 비교예 1 내지 3에서 제조된 용기형 변기세정제를 제1도와 같이 용기에 담아 3평 정도의 밀폐된 공간에서 60와트(W) 백열전구 3개의 조도에서 30일간 10명이 직접 사용하면서 변기 내부의 물때 및 이물질의 발생정도를 관찰하였다. 이 때 물때 및 이물질이 변기 내부에 끼지 않은 것을 "○"로, 물때 및 이물질이 변기 내부에 생긴 것을 "×"로 표시하였다.The container-type toilet bowl cleaners prepared in Examples 1 to 7 and Comparative Examples 1 to 3 were placed in a container as shown in FIG. 1, and 10 people directly for 30 days at the illuminance of three 60-watt (W) incandescent lamps in a closed space of about 3 pyeong. The use of scale and foreign matter inside the toilet was observed during use. At this time, the scale and foreign matter not caught in the toilet is indicated by "○", and the scale and foreign matter generated inside the toilet are indicated by "x".
실시예1 내지 7 및 비교예 1 내지 3에서 제조된 용기형 겔타입 변기세정제의 상기와 같은 안정성과 사용성을 비교한 결과는 다음의 표2와 같다.The results of comparing the above stability and usability of the container-type gel-type toilet cleaners prepared in Examples 1 to 7 and Comparative Examples 1 to 3 are shown in Table 2 below.
본 발명에 따른 용기형 겔타입 변기세정제의 제조방법에 따라 제조된 변기세정제는 세정력이 우수한 비이온 계면활성제와 겔화제를 배합하여 사용기간동안 일정한 용해 및 분해 속도로 사용시 색상이 균일하고 사용기간이 일정하게 유지되어 비용이 절감될 뿐만 아니라 오랜 동안 기계적인 힘을 가하지 않고도 자동적으로 청결한 변기 상태를 유지할 수 있는 효과가 있다.The toilet bowl prepared according to the method of manufacturing a container-type gel toilet bowl cleaner according to the present invention is a non-ionic surfactant and a gelling agent with excellent cleaning power, the color is uniform and the period of use is constant when used at a constant dissolution and decomposition rate during use. It not only saves money by being constant, but also automatically maintains a clean toilet without the need for long periods of mechanical force.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020000077090A KR20020046762A (en) | 2000-12-15 | 2000-12-15 | Gel Type Detergent Putting In an Instrument For a Toilet Stool and The Preparation Method of thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020000077090A KR20020046762A (en) | 2000-12-15 | 2000-12-15 | Gel Type Detergent Putting In an Instrument For a Toilet Stool and The Preparation Method of thereof |
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| Publication Number | Publication Date |
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| KR20020046762A true KR20020046762A (en) | 2002-06-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1020000077090A KR20020046762A (en) | 2000-12-15 | 2000-12-15 | Gel Type Detergent Putting In an Instrument For a Toilet Stool and The Preparation Method of thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020023694A (en) * | 2001-12-06 | 2002-03-29 | 이재식 | Microcapsule-type toilet cleaner |
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|---|---|---|---|---|
| KR930002967A (en) * | 1991-07-29 | 1993-02-23 | 죤 디. 크래인 | Store and retrieve non-text targets |
| US5320783A (en) * | 1992-11-04 | 1994-06-14 | The Procter & Gamble Company | Detergent gels containing ethoxylated alkyl sulfate surfactants in hexagonal liquid crystal form |
| GB2288186A (en) * | 1994-02-17 | 1995-10-11 | Kelco Int Ltd | Toilet cleansing gel block |
| JPH08283123A (en) * | 1995-04-10 | 1996-10-29 | Kao Corp | Aqueous gellike detergent composition |
| KR20010100419A (en) * | 2000-05-02 | 2001-11-14 | 박성기 | Gel type detergent composition for a urinal |
| EP0972009B1 (en) * | 1997-03-14 | 2002-06-26 | Unilever Plc | Lavatory cleansing compositions |
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- 2000-12-15 KR KR1020000077090A patent/KR20020046762A/en not_active Application Discontinuation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR930002967A (en) * | 1991-07-29 | 1993-02-23 | 죤 디. 크래인 | Store and retrieve non-text targets |
| US5320783A (en) * | 1992-11-04 | 1994-06-14 | The Procter & Gamble Company | Detergent gels containing ethoxylated alkyl sulfate surfactants in hexagonal liquid crystal form |
| GB2288186A (en) * | 1994-02-17 | 1995-10-11 | Kelco Int Ltd | Toilet cleansing gel block |
| JPH08283123A (en) * | 1995-04-10 | 1996-10-29 | Kao Corp | Aqueous gellike detergent composition |
| EP0972009B1 (en) * | 1997-03-14 | 2002-06-26 | Unilever Plc | Lavatory cleansing compositions |
| KR20010100419A (en) * | 2000-05-02 | 2001-11-14 | 박성기 | Gel type detergent composition for a urinal |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020023694A (en) * | 2001-12-06 | 2002-03-29 | 이재식 | Microcapsule-type toilet cleaner |
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