KR19980033680A - A method for producing colored patterned artificial marble without peeling or alteration based on glass or transparent synthetic resin board. - Google Patents
A method for producing colored patterned artificial marble without peeling or alteration based on glass or transparent synthetic resin board. Download PDFInfo
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- KR19980033680A KR19980033680A KR1019980016370A KR19980016370A KR19980033680A KR 19980033680 A KR19980033680 A KR 19980033680A KR 1019980016370 A KR1019980016370 A KR 1019980016370A KR 19980016370 A KR19980016370 A KR 19980016370A KR 19980033680 A KR19980033680 A KR 19980033680A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/34—Printing on other surfaces than ordinary paper on glass or ceramic surfaces
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/12—Stencil printing; Silk-screen printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/14—Multicolour printing
- B41M1/18—Printing one ink over another
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
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Abstract
유리나 투명 합성수지판의 일면에 아크릴수지, 비닐수지, 사이크로헥산, 에텔-3-에톡시 프로피오네이트, 솔벤트 나프타 및 안료로된 속건성 실크 스크린 인쇄 잉크로 천연 대리석과 같은 무늬를 색상별로 다색무늬 인쇄를 하여 인조 대리석을 제조함에 있어서, 유리는 물론 아크릴수지판, 폴리카보네이트 수지판을 기재로 하여 그 일면에 상기와 같은 공지의 아크릴수지, 비닐수지, 사이크로 헥산, 에틸-3-에폭시프로피오네이트, 솔벤트나프타 및 안료로된 속건성 실크 스크린 인쇄 잉크에 보강 충전제(filler)로서 300∼400메쉬 입자크기의 규사분을 전체 잉크 중량에 대하여 1∼10중량%를 혼합한 인쇄 잉크로 인쇄하고 150∼220℃의 고온 로(爐 )에서 가열 경화시킨후 냉각시켜 칼라무늬 인조 대리석으로 하거나 그 인쇄 표면에 에폭시 수지액을 표면 보호 및 탈색 방지제로 도포하여 칼라 인조 대리석을 제조하므로서 표면 인쇄 잉크층의 박리 및 변질이 없이 단단하게 고착되어 변색되지 않는 천연 대리석과 같은 효과를 내는 우수한 칼라무늬 인조 대리석에 관한 것이다.Fast-drying silk screen printing inks made of acrylic resin, vinyl resin, cyclohexane, ethyl-3-ethoxy propionate, solvent naphtha and pigments on one side of glass or transparent synthetic resin boards to print multicolored patterns such as natural marble In preparing the artificial marble by using a glass as well as an acrylic resin plate, a polycarbonate resin plate on the one side of the known acrylic resin, vinyl resin, cyclohexane, ethyl-3-epoxypropionate Fast-drying silk screen printing inks, solvent naphtha and pigments, and printing powders containing 1 to 10% by weight based on the total ink weight of 300 to 400 mesh particles of silica sand as reinforcing fillers. Heat-harden in a high-temperature furnace at 0 ℃ and cool it to make colored patterned artificial marble or to protect the epoxy resin liquid on the printed surface. Coated with a bleaching agent and relates to a color pattern excellent artificial marble that the same effect as that is securely fixed to discoloration of natural marble with no peeling and deterioration of the production hameuroseo surface printing ink layer to color the artificial marble.
Description
본 발명은 투명 유리나 폴리카보네이트 수지판이나 아크릴 수지판과 같은 투명 합성수지판을 기재로 하여 그 일면에 각종의 다양한 천연 대리석과 같은 칼라 무늬를 박리되지 않고 변색되지 않도록 현출하는 건축물 내외장용의 칼라무늬 인조 대리석의 제조방법에 관한 것이다.The present invention is based on a transparent synthetic resin board such as transparent glass, polycarbonate resin board or acrylic resin board as a base material for the interior and exterior of the building to display the color pattern such as various various natural marbles on the one surface without peeling and discoloring. It relates to a method for producing marble.
본 발명은 투명 유리나 폴리카보네이트 수지판 및 아크릴 수지판과 같은 투명 합성수지판을 이용한 칼라무늬 인조 대리석으로서, 종래에는 유리를 이용한 칼라무늬 인조 대리석을 제조하려면 먼저 그라비아 인쇄나 실크 스크린 인쇄등으로 정밀하게 각종 색상의 대리석 무늬가 인쇄된 무늬지를 유리면에 접착제로 부착하여 투명 유리면을 통하여 자연무늬 대리석과 같은 색상무늬가 현출되게 하여 천연대리석 효과를 내게하였으나 이 경우에 투명 유리면을 통하여 현출되는 대리석 무늬층이 짧은 기간내에 태양광선의 자외선에 의하여 노화되어 변색되거나 탈색되어 금방 천연 대리석 무늬를 상실하게 되므로 인조 대리석임이 금방 노출되게 되는 결점이 있었고 또한 이때 인쇄된 무늬지가 태양광선이나 수분의 영향으로 쉽게 기재로 부터 박리되기 쉬워서 내구성이 약한 결점이 있었다.The present invention is a colored patterned artificial marble using a transparent synthetic resin plate such as transparent glass or polycarbonate resin plate and acrylic resin plate, conventionally, to manufacture colored patterned artificial marble using glass, variously precisely by gravure printing or silk screen printing, etc. The marble pattern of colored marble pattern is attached to the glass surface with adhesive, so that the color pattern like natural pattern marble is revealed through the transparent glass surface to give natural marble effect, but in this case, the marble pattern layer that is displayed through the transparent glass surface is short. It is a defect that artificial marble is exposed immediately because it is discolored or discolored by UV rays of sunlight within a period of time and natural marble pattern is quickly lost. Also, the printed pattern is easily peeled from the substrate due to the influence of sunlight or moisture. Be There was a drawback of weak durability because it was easy to do.
이상과 같은 유리를 이용한 칼라무늬 인조 대리석의 결점을 해소하기 위하여 각종 색상의 인쇄잉크를 이용하여 유리면에 각종 색상의 무늬를 실크 스크린 인쇄 방법으로 직접 인쇄하여 인조 대리석을 제조하고져 시도한바 있으나 이 경우에 유리는 인쇄 잉크를 흡수하지 못하기 때문에 한가지 색상의 무늬만 인쇄시에도 실크스크린에 의해 인쇄된 망점(網点)(스크린의 망에 의해서 점 형태로 인쇄된 것)들이 인쇄된 상태로 있지 않고 경화되기전에 퍼져서 섬세한 대리석 색상 무늬를 나타내지 못하고 이에 따라 다수 색상의 표현과 경계과 불분명하여 선명한 칼라무늬를 현출하지 못하였으며 뿐만 아니라 다색무늬를 인쇄시에는 먼저 인쇄된 색상의 망점들이 경화되기전에 인쇄하게 되면 서로 다른 색상 무늬들이 뒤섞여서 섬세한 다색무늬의 인쇄가 불가능한 결점이 있었다.In order to solve the drawbacks of the colored patterned artificial marble using the glass as described above, the artificial marble was manufactured by directly printing the patterns of various colors on the glass surface using a silk screen printing method using printing inks of various colors. Glass does not absorb printing ink, so when printing only one color pattern, the dots printed by the silkscreen (printed in the form of dots by the screen of the screen) are not printed and cured. It did not show a delicate marble color pattern before spreading, and accordingly, it did not show a vivid color pattern because it was unclear with the expression and boundary of many colors.In addition, when printing multicolored patterns, the dots of the printed color were printed before hardening. Intricate multicolored pattern with different color patterns There were defects is impossible.
그렇다고 인쇄잉크의 속성건조를 위하여 먼저 인쇄된 것을 가열하게 되면 융점이 극히 낮은 유리가 고열에 의해서 용융되어 균형을 잃게 되므로 인쇄면을 가열하면서 인쇄하게 되면 정밀한 다색무늬의 인쇄가 불가능하였다.However, if the first printing for heating the drying properties of the printing ink, the glass having a very low melting point is melted by high heat and loses its balance, so when printing while heating the printing surface, it is impossible to print a precise multicolored pattern.
결국 유리면에 각종 색상의 인쇄 잉크로 직접 인쇄하여 가열하는 방법으로는 섬세한 색상을 현출하는 유리로된 인조 대리석을 제조하는 것이 거의 불가능 하였다.As a result, it was almost impossible to produce artificial marble made of glass that displays delicate colors by directly printing the glass surface with printing inks of various colors.
특히 종래 유리면의 인쇄 기술은 에나멜에 안료를 첨가하여 스크린 인쇄하거나 초자(유리)안료를 텔핀유에 교반하여 스크린 인쇄한 후 가열로에서 섭씨 450°∼-500°에서 서서히 가열하여 인쇄층이 유리에 고착되게 하였으므로서 다색 인쇄의 경우에는 한가지색 인쇄시마다 가열 과정을 거쳐야 하므로 매우 비 생산적이고 비능률적이며 정밀성이 결여되었다.In particular, the conventional printing technique of glass printing is screen printing by adding a pigment to enamel or screen printing by stirring a glass (glass) pigment with telpine oil, and then gradually heating it at 450 ° to 500 ° C in a heating furnace to fix the printing layer to glass. In the case of multicolor printing, since the heating process is performed every single color printing, it is very unproductive, inefficient, and lacks precision.
상기와 같은 고전적인 방법에 의한 유리를 이용한 인조 대리석의 제조방법의 결점을 해소하기 위하여 최근에 개발된 유리를 이용한 칼라무늬 인조 대리석의 또 다른 예로는 짧은 시간에 인쇄잉크가 속성 건조되고 다양한 무늬를 인쇄하여 다양한 색상의 천연 대리석과 같은 무늬를 직접 유리면에 인쇄하더라도 망점의 손상이 없이 각종 색상의 경계면이 뚜렸하면서 다른 무늬의 잉크에 손상을 주지 않고 각각의 색상을 선명하게 현출할 수 있으면서 인쇄후 태양광선에 노출시에도 자외선에 의하여 색상이 변하지 않아 천연 대리석 무늬 그대로의 색상을 영구적으로 유지하도록 한 것으로서 투명 유리의 일면(1)에, 솔벤트 나프타, 에틸-3-에톡시 프로피오네이트 및 사이크로헥사논으로 된 유기 혼합용제에 아크릴 수지, 비닐수지 및 필요한 색상의 안료를 적량 혼합한 것을 실크 스크린 인쇄 잉크로 하여 천연대리석 무늬와 같은 칼라무늬를 통상의 실크 스크린 인쇄방법으로 인쇄한 후 먼저 인쇄된 스크린 부분부터 경사지게 잡고 나중 인쇄된 부분의 스크린까지 차례로 떼어내는 방법으로 색상별로 인쇄를 반복한후 건조되면 그 인쇄층(2)위에 인쇄층 보호용 유브이(UV) 코팅층을 도포하지 않으면 UV 보호층 도포전 취급과정에서 인쇄 무늬층이 쉽게 유리 표면으로 부터 박리되기 쉬워서 인쇄와 동시에 필수적으로 U.V 코팅을 해야하는 번거로움이 있음은 물론이고, 또한 상기와 같은 인쇄 잉크 재료만으로는 접착력이 약하여 폴리 카보네이트나 아크릴 수지판과 같은 투명 합성수지판에는 인쇄무늬층을 인쇄하더라도 인쇄된 대로 유지되지 못하는 결점이 있었다.Another example of the recently developed color-patterned artificial marble using glass to solve the shortcomings of the manufacturing method of artificial marble using glass by the classical method as described above is that the printing ink is quickly dried and various patterns Even if you print and print the pattern like natural marble of various colors directly on the glass surface, you can see each color vividly without damaging the ink of other patterns while the border of various colors is covered without damaging the dots. When exposed to light, the color does not change due to ultraviolet rays, so that the color of the natural marble pattern is maintained permanently. On one side of the transparent glass, solvent naphtha, ethyl-3-ethoxy propionate and cyclohexa Acrylic resins, vinyl resins and required colors in organic mixed solvents After a suitable amount of pigments are mixed with silk screen printing ink, a color pattern such as a natural marble pattern is printed by a conventional silk screen printing method, and then the slant is first grasped from the first printed screen and then separated from the first printed screen. If the printing is repeated after the color is dried, and the printing layer protective UV coating layer is not applied on the printed layer 2, the printed pattern layer is easily peeled from the glass surface during the handling process before the UV protective layer is applied. At the same time, there is a need to apply UV coating, and of course, the printing ink material as described above is weak in adhesive strength, so that even if a printed pattern layer is printed on a transparent synthetic resin board such as a polycarbonate or an acrylic resin board, it is not maintained as printed. There was a fault that could not be.
본 발명은 상기한 바와 같은 유리를 기재로 하여 각종 칼라 인쇄잉크를 인쇄하여 유리를 이용한 인조 대리석을 제조함에 있어서 인쇄층의 약한 접착력으로 인한 인쇄층 인쇄과정에서나 인쇄후 표면 보호층 코팅 직전까지의 취급시에 인쇄층이 박리 및 훼손되는 결점을 제거하기 위하여 인쇄 잉크에 특수 보강 충전제를 첨가하여 인쇄층 무늬를 가열 경화하므로써 인쇄 무늬층을 보호하기 위한 보호피막을 형성하지 않아도 인쇄 무늬층의 접착력 및 강도가 우수하여 기재 표면으로 부터 박리되지 않는 특징이 부여되고 또한 유리뿐 아니라 폴리카보네이트수지판이나 아크릴수지판과 같은 투명 합성수지판을 기재로 하여 상기 본 발명 인쇄 잉크로 인쇄하였을 경우에도 접착력 및 강도가 우수하여 인쇄 및 건조후 취급시에 인쇄 무늬층이 박리되거나 파손되지 않게한 칼라무늬 인조 대리석을 제조하는 방법을 제공코저 하는 것으로서 이를 실예를 들어 상세히 설명하면 다음과 같다.In the present invention, in the manufacture of artificial marble using glass by printing various color printing inks based on the glass as described above, in the printing layer printing process due to the weak adhesive force of the printing layer or until the surface protective layer coating immediately after printing. The adhesive force and strength of the printed pattern layer without the need to form a protective film to protect the printed pattern layer by adding a special reinforcing filler to the printing ink to heat-harden the printed layer pattern in order to remove the defect that the printed layer is peeled off and damaged. It is excellent in adhesion and strength even when printed with the printing ink of the present invention based on a transparent synthetic resin plate such as a polycarbonate resin plate or an acrylic resin plate, as well as glass, which is endowed with a feature that does not peel off from the surface of the base material. Printing and drying the printed pattern layer after handling As to prevent damage or a color pattern artificial kojeo provide a process for producing the marble when it contains a silye described in detail as follows.
도1은 본 발명 칼라무늬 인조 대리석의 인쇄층을 보호하지 않은 상태의 단면도.BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a sectional view of the present invention in which the printing layer of the colored patterned artificial marble is not protected.
도2는 본 발명 칼라무늬 인조 대리석의 인쇄층을 보호층으로 보호한 상태 의 단면도.Figure 2 is a cross-sectional view of the printing layer of the present invention colored pattern artificial marble protected with a protective layer.
* 도면중 주요 부분에 대한 부호의 설명 *Explanation of symbols on main parts of drawing
1 : 투명기재판 2 : 칼라무늬 인쇄층1: transparent substrate 2: color pattern printed layer
3 : 에폭시 수지보호층3: epoxy resin protective layer
투명 유리와 같은 투명 기재판(1)의 일면에 솔벤트나프타, 에틸-3-에톡시프로피오네이트 및 사이크로 헥사논으로 된 유기 혼합용제에 아크릴수지, 비닐수지 및 소정의 색상 안료를 혼합한 공지된 칼라무늬 인조 대리석 제조용 속건성 인쇄 잉크를 칼라별로 차례로 도포 인쇄하여 다양한 칼라무늬 인쇄층(2)을 형성하여 칼라무늬 인조 대리석을 제조함에 있어서, 상기 통상의 칼라무늬 인조 대리석용 인쇄 잉크에 보강충전제로 약 200∼500메쉬 크기의 규사분(석분)을 전체 잉크 중량에 대하여 1∼10%범위로 첨가 혼련 교반하여 인쇄 잉크로 한 후 통상의 실크 스크린 인쇄 방법으로 투명 유리는 물론 폴리카보네이트 수지판이나 아크릴 수지판중에서 선택된 투명 기재판(1)의 일면에 다양한 칼라무늬를 인쇄한 후 120∼250℃범위내의 터널로(爐)를 적정시간 통과시키면서 열 경화시켜 칼라무늬 인쇄층(2)이 인쇄된 칼라무늬 대리석으로 하거나, 상기 칼라 무늬인쇄층(2)의 상부에 통상의 에폭시수지액을 피복하여 보호막(3)을 형성할수도 있는 것으로 구성된다.Known mixture of acrylic resin, vinyl resin and predetermined color pigment with organic mixed solvent of solvent naphtha, ethyl-3-ethoxypropionate and cyclohexanone on one surface of transparent base plate 1 such as transparent glass In order to produce colored patterned artificial marble by coating and printing the fast-drying printing ink for manufacturing colored patterned artificial marble for each color one by one, as a reinforcing filler in the printing ink for ordinary color patterned artificial marble. Approximately 200 to 500 mesh sized silica sand (stone powder) is added in the range of 1 to 10% with respect to the total ink weight, and kneaded and agitated to print ink. After printing various color patterns on one surface of the transparent base plate 1 selected from the resin plates, titrating a tunnel path within a range of 120 to 250 ° C. It may be heat-hardened while passing through to make a color patterned marble on which the color pattern printing layer 2 is printed, or a protective film 3 may be formed by coating a normal epoxy resin solution on the color pattern printing layer 2. It consists of.
이상과 같이 구성되는 본 발명 칼라무늬 인조 대리석은 인쇄잉크에 충전제로서 규사분(석분)이 함유되어 있는데다가 가열에 의해 잉크가 경화되었기 때문에 잉크의 강도와 접착력이 우수하여 칼라무늬 인쇄층(2)을 다른 피복층으로 보호하지 않더라도 파손, 와해 또는 박리되지 않고 고착력과 강도를 유지하게 되어 칼라무늬를 장시간 변형 박리되지 않은채 유지할 수가 있고 잉크와 충전제인 규사분과의 강한 결착력에 의하여 변색이 되지 않으므로 장시간 칼라무늬를 유지할 수 있는 장점이 있으며 더욱이 칼라무늬 인쇄층(2)을 에폭시 수지층(3)으로 보호하게 되면 완벽하게 표면 보호는 물론 변질, 변색되는 것을 막아주는 장점이 있다.The colored patterned artificial marble of the present invention constituted as described above contains silica sand (stone powder) as a filler in the printing ink, and the ink is cured by heating, so the strength and adhesion of the ink are excellent, and the colored patterned printing layer (2) Even if it is not protected by another coating layer, it will not be broken, broken or peeled, and it will maintain fixation strength and strength, so that the color pattern can be maintained without deformation and peeling for a long time. There is an advantage to maintain the color pattern and moreover, if the color pattern printing layer (2) to protect with the epoxy resin layer (3) has the advantage of completely preventing the surface, as well as deterioration, discoloration.
본 발명 칼라무늬 인조 대리석은 기재로서 유리는 물론 폴리카보네이트나 아크릴 수지판등 다양한 투명판을 이용할 수가 있어서 재료 선택이 용이한 효과가 있고 취급시에 파손 우려도 적은 효과가 있으며, 잉크의 강도가 우수하여 취급이 용이한 장점이 있다고 하겠다.Color-patterned artificial marble of the present invention can use various transparent plates such as polycarbonate or acrylic resin as well as glass as a base material, thereby making it easy to select materials and less likely to be damaged during handling. There is an advantage that it is easy to handle.
Claims (1)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019980016370A KR19980033680A (en) | 1998-05-08 | 1998-05-08 | A method for producing colored patterned artificial marble without peeling or alteration based on glass or transparent synthetic resin board. |
| KR1019990010164A KR100286013B1 (en) | 1998-05-08 | 1999-03-24 | Artificial color marble and a process for preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019980016370A KR19980033680A (en) | 1998-05-08 | 1998-05-08 | A method for producing colored patterned artificial marble without peeling or alteration based on glass or transparent synthetic resin board. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR19980033680A true KR19980033680A (en) | 1998-07-25 |
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Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019980016370A KR19980033680A (en) | 1998-05-08 | 1998-05-08 | A method for producing colored patterned artificial marble without peeling or alteration based on glass or transparent synthetic resin board. |
| KR1019990010164A KR100286013B1 (en) | 1998-05-08 | 1999-03-24 | Artificial color marble and a process for preparation thereof |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019990010164A KR100286013B1 (en) | 1998-05-08 | 1999-03-24 | Artificial color marble and a process for preparation thereof |
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| Country | Link |
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| KR (2) | KR19980033680A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100316825B1 (en) * | 1999-05-18 | 2001-12-22 | 오기환 | Artificial marble based on glass plates having multiple color patterns and a process for preparation thereof. |
| KR20020089974A (en) * | 2001-05-25 | 2002-11-30 | 이영수 | A printing method of glassy materias |
| KR101124856B1 (en) * | 2009-07-24 | 2012-03-27 | 윤종호 | Manufacturing method for glass shelf for refrigerator using glass beads and the glass shelf manufactured by the method |
| KR101124746B1 (en) * | 2009-07-23 | 2012-04-12 | 윤종호 | Method for producing glass shelf for refrigerator and the glass shelf manufactured by the method |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100478340B1 (en) * | 2002-03-08 | 2005-03-24 | 김애숙 | Artificial Glass Marble having Elasticity |
| KR20020026916A (en) * | 2002-03-08 | 2002-04-12 | 김애숙 | Artificial Glass Marble having Excellent Elasticity |
| US9487947B2 (en) | 2011-04-19 | 2016-11-08 | F Consultant Co., Ltd. | Decorative laminated plate |
| KR102717502B1 (en) * | 2023-09-04 | 2024-10-15 | 정광영 | Acrylic with graphic image therein and manufacturing method therefor |
-
1998
- 1998-05-08 KR KR1019980016370A patent/KR19980033680A/en active Search and Examination
-
1999
- 1999-03-24 KR KR1019990010164A patent/KR100286013B1/en not_active IP Right Cessation
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100316825B1 (en) * | 1999-05-18 | 2001-12-22 | 오기환 | Artificial marble based on glass plates having multiple color patterns and a process for preparation thereof. |
| KR20020089974A (en) * | 2001-05-25 | 2002-11-30 | 이영수 | A printing method of glassy materias |
| KR101124746B1 (en) * | 2009-07-23 | 2012-04-12 | 윤종호 | Method for producing glass shelf for refrigerator and the glass shelf manufactured by the method |
| KR101124856B1 (en) * | 2009-07-24 | 2012-03-27 | 윤종호 | Manufacturing method for glass shelf for refrigerator using glass beads and the glass shelf manufactured by the method |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100286013B1 (en) | 2001-03-15 |
| KR19990046117A (en) | 1999-06-25 |
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