KR101872347B1

KR101872347B1 - Pellet composition for eco-friendly green tide and red tide removal and method for producing the same

Info

Publication number: KR101872347B1
Application number: KR1020170129746A
Authority: KR
Inventors: 박용칠
Original assignee: 주식회사 바이오테크; 박용칠
Priority date: 2017-10-11
Filing date: 2017-10-11
Publication date: 2018-06-28

Abstract

The present invention relates to a process for producing a granulated product, which comprises calcining a granite, a heavenly earth, a tourmaline, a zeolite, a germanium, a silicate and a raw ore at a high temperature of 1100 to 1300 ° C to a particle size of 600 to 700 mesh, Followed by kneading with a starch paste to be pelletized and dried, or a pellet for removing red tide.

Description

TECHNICAL FIELD [0001] The present invention relates to a pellet composition for eco-friendly green tide or red tide removal,

The present invention relates to a method for removing green algae or red tide when pellets are mixed with elvan or chrysotile, tourmaline, zeolite, germanium, silicate, biotite, charcoal or white carbon, The present invention relates to a pellet composition for removing green tide or red tide, which does not cause pollution of rivers or seawater and does not damage fishes, and a method for producing the same.

The worsening of the water quality caused by the excessive inflow of nitrogen or phosphorus, which is contaminated organic matter in stagnant water bodies such as lakes and rivers, is called eutrophication. The nutrients of such eutrophication are ammonia, nitrite, nitrate, organic nitrogen compound , Inorganic phosphates, organophosphates, silicates, etc. These are mainly introduced into rivers or the sea by domestic sewage, factory wastewater, fertilizers or organic materials. Green algae phenomenon refers to a phenomenon in which the green algae, which are phytoplankton, are greatly increased in eutrophic lakes or slow-flowing streams, and the water is changed to green. Especially, in Korea, as a part of the 4 major rivers development project, due to low water depth, the water flow rate is slow, causing the green algae phenomenon every year, causing damage such as the death of fishes and the like.

In addition, the red tide phenomenon occurring in the southern coast of Korea is a coastal area where geographical endurance is low and seawater exchange with the appearance is minimal, and the development of coastal cities has resulted in the rapid introduction of pollutants such as various industrial wastes, Of course, causing serious damage to coastal fishes. It is called red tide in the sense that water is red, but the colors such as orange, reddish brown, and brown can be changed variously depending on the color of plankton. Phytoplankton such as diatom and dinoflagellate are the most common plankton causing red tides. In Korea, green loess or red tide is sprayed with loess, which is a coagulant spraying agent. However, not only is efficiency in removing rust trough low, but also it is pointed out that there are problems such as high cost of treatment as well as damage to forests for securing loess with continuous use. Techniques for the development of a rust remover have been attempted.

Specifically, the Korean Registered Patent No. 10-1657171 discloses a green algae or red tidy removing agent containing a mineral powder and charcoal powder absorbed with hydrogen peroxide. The mineral powder includes 300 to 500 weight percent of sericite powder per 100 parts by weight of olivin powder A green tide or red tide removing agent comprising 100 to 300 parts by weight of zeolite powder, 200 to 260 parts by weight of diatomaceous earth powder, 5 to 20 parts by weight of germanium powder, 1 to 10 parts by weight of sulfur powder and 1 to 10 parts by weight of zirconium powder has been disclosed have. Korean Patent Laid-Open No. 2016-71667 and Korean Laid-Open Patent Application No. 2015-0137549 disclose a method in which a raw ore powder as a natural mineral is stirred in an acidic water and a stirrer obtained through an electrolytic water production apparatus, To thereby relieve red tides and green troughs of rivers and oceans. Korean Patent Laid-Open Publication No. 2015-0144448 discloses a composition for removing green tide or red tide, which comprises a mixture of loess, shell, and wastewater. Korean Patent No. 10-1355178 discloses a composition for removing seawater, loess, clay, Japanese Patent Laid-Open No. 10-1355177 discloses a water treatment agent for removing rust troughs and / or odors, which includes marine soil, caustic soda, charcoal powder, aluminum sulfate, And / or a water treatment agent for removing rust, red tide and / or odor, which contains a natural substance such as salt, charcoal, quicklime, clay powder, loess powder and oyster shell powder as a water treatment agent for removing odors. In Korean Patent No. 10-1190902, the present invention relates to a method for producing a chitosan powder, which comprises 1 to 5% by weight of chitosan, 3 to 15% by weight of an aqueous solution concentrated and extracted from bamboo leaves by hot water, The present invention relates to a water quality improving agent comprising at least one selected from the group consisting of benthonite, silica, and titanium dioxide (TiO2). In addition, Korean Patent No. 10-1260381 Discloses a technology relating to an eco-friendly liquid-gut liquor remedy and a malodor purifying agent which purify odor caused by red tide green tide and river sediment using natural minerals such as ceramic, quick lime and germanium as a green algae remedy and odor cleaner.

However, when the above-mentioned yellow loess is sprayed on water or sea water, there is a concern that the fish or the like may cause respiratory disturbance and may cause death or environmental pollution due to the use of chemicals and the like. Especially, There was a problem.

Korean Patent No. 10-1657171 Korean Patent No. 10-1355178 Korean Patent No. 10-1355177 Korean Patent No. 10-1190902 Korean Patent No. 10-1260381 Korean Patent No. 10-0820055 Korean Patent No. 10-0849460 Korean Patent Publication No. 2016-071667 Korean Patent Publication No. 2015-137549 Korean Patent Publication No. 2015-144448 Korean Patent Publication No. 2009-119793 Korean Patent Publication No. 2009-021551

The present inventors have conducted extensive researches on minerals for many years, The silicate and the raw ore are calcined at a high temperature of 1100 to 1300 ° C. and ground to a particle size of 600 to 700 meshes and powdered. The charcoal and the white carbon powder are mixed with the powder, and the mixture is kneaded with a starch paste and pelletized. There is a problem that the removing agent can drop easily into the water compared with the conventional loess, and when the loess is dropped, the physis of the fry is disturbed and the sucking of the loess is interrupted. However, the algae or red tanning agent of the present invention is pelletized, Therefore, the present inventors have found that the present invention is superior in removing green tide or red tide without causing damage to fishes by floating on water for a long time while maintaining a constant shape.

In order to achieve the above object, the green algae or red tidemaker of the present invention may be prepared by mixing powdered elvan, heavymetal, tourmaline, zeolite, germanium, silicate and biotite, charcoal and white carbon, and kneading with a dilute starch paste And then pelletized through the following steps.

1) First step

Zirconia, germanium, silicate and raw ore are calcined at a high temperature of 1100 to 1300 ° C and ground to a particle size of 600 to 700 mesh.

2) Second step

Charcoal and white carbon are crushed to a particle size of 600 to 700 mesh.

3) Third step

The above mineral powder, charcoal, white carbon powder, and starch paste are mixed together and then kneaded in a roller kneader to be uniformly mixed.

4) Fourth step

The kneaded product is cooked at 60 to 120 DEG C under a pressure of 20 to 60 psi for 5 to 10 minutes, and then processed into a pellet form.

5) Step 5

The processed pellet is put into a far-infrared ray drier and heated at 60 to 70 ° C for about 2 to 3 hours to dry to a moisture content of 8 to 10% by weight.

The composition ratio of the respective minerals is 20 to 50 parts by weight, 20 to 50 parts by weight of tourmaline, 60 to 80 parts by weight of zeolite, 40 to 60 parts by weight of germanium, 40 to 80 parts by weight of silicate, And 10 to 20 parts by weight of raw ore. Charcoal and white carbon are mixed in a ratio of 1: 1, the ratio of the mineral: charcoal and white carbon: starch paste is 2: 1: 0.5, The diameter of the pellet of red tanning agent is 3-5 cm.

As described above, the green or red tincture removing agent of the present invention in which the mineral powder, charcoal and white carbon are pelletized can be easily sprayed on the river or sea where the green tide is generated, and the green tide or red tide removing agent of the present invention can be easily It is an eco-friendly green algae or red tide remover that is harmless to sea creatures such as daphnia, while it can effectively kill rust and red tide when sprayed on the polluted water.

A green alga or a red tincture remover according to a preferred embodiment of the present invention will be described in detail.

The elvan stone used in the present invention has been recorded in Dongwoo-Bokwon, etc. as a record that it has been used as an anti-inflammatory agent for various skin diseases such as ankara, boar, etc. from ancient times. Especially in the modern era, it has been used as a raw material for fertilizer since it promotes the growth of living things with ceramic material that emits much far-infrared rays known to be beneficial to human body. Especially, since the elvan stone is a porous rock, It absorbs and decomposes contaminants and bacteria in the water, and acts to prevent odor removal and decay. In addition, it absorbs and removes heavy metals such as mercury and cadmium, neutralizes cement toxicity, and acts as an antibacterial, insecticide and deodorizing agent. In particular, even strong acid or strong alkaline water will turn into weak alkalinity (pH 7.2 ~ 7.4) and turn into water suitable for human body.

ChunGiTo is a complex alkaline mineral mineral that is non-toxic and has been used as a precious stone for skin diseases and traumatic treatments. It contains more than 45 kinds of minerals. It has excellent effect of improving water quality and has a high efficiency of more than 93% Tourmaline has the only permanent electrical properties among the minerals present on the earth. Tourmaline emits anions, weak currents and far-infrared rays, and is used as an energy source to stimulate biological growth and supply vitality. They promote cell activation, cardiac strengthening, growth and development, skin shine, and good effects on the kidneys, liver, pancreas and the like.

Zeolite (Zeolite) is an inorganic substance which causes ion exchange reaction. It is a mineral with remarkable ion exchange ability and belongs to a mineralogical zeolite group. The zeolite has excellent deodorizing power and antibacterial power along with the far-infrared radiation, which purifies the water quality. Such zeolites can use natural gemstones, but artificially synthesized zeolites can be used. The main components of the zeolite are, for example, 65.4 wt% of SiO2, 13.2 wt% of Al2O3, 1.62 wt% of Fe2O3, 3.57 wt% of CaO, 0.92 wt% of MgO, 1.77 wt% of K2O and 2.03 wt% of Na2O.

The zeolite is a fine porous formed by the action of the volcanic ash of the third layer and is excellent in adsorption power and chemical cation exchange function. It is used for removing and purifying automobile noxious gas components, various heavy metal harm removers, gas adsorption deodorizers, water softeners and agricultural land improvement agents It is a mineral that is used as a catalyst for environmental purification. These zeolites adsorb and purify various contaminants when they penetrate into water.

Germanium is an off-white mineral, composed of 32 electrons. When a foreign object touches it, one of the four outermost electrons protrudes out and combines with the electrons of the foreign substance, pulling the foreign substance into the vacant space, give. At this time, pure oxygen is generated to neutralize, neutralize and neutralize contaminants that are acidified by neutralizing, neutralizing, or eliminating the action, converting it into an alkali substance, and combining it with heavy metals to produce other toxic substances.

Silicate (SiO ₃ ) is pollution-free detergent mainly made of silica which has self-cleaning capability to decompose water organic matter, and it can remove the laundry poison by using laundry which is made of silicate as a main component, and moss It is said that the silicate has a self-cleaning ability (far-infrared ray) that cleans the water with strong alkalinity.

The physical properties of raw ore are silicate minerals, which generally have a high ion exchange capacity and have a plate-like structure. Due to the nature of this structure, H2O enters and exits the inside of the particles. Therefore, the surface area per unit mass including both the outer surface and the inner surface is very large, so that the surface area per 1 g reaches 500 to 1,000. Their surfaces have (-) or (+) charges and cause a variety of phenomena, such as attracting ions with the opposite sign. The chemical characteristics of raw ore have ion substitution, adsorption, reactivity with chemicals, formation ability of organic and inorganic complex, catalytic ability, swelling property, viscosity, plasticity and so on which are called chemical affinity, It may also exhibit the colloidal properties of suspended particles.

Among these various properties, it is very easy to utilize as a redox remover for raw ore because it is based on ionexchange capacity and cation exchange between interstitial layers reacts with organic minerals.

In addition, charcoal and white carbon are used in the rust and red tide removing agent of the present invention. The above-mentioned charcoal and white carbon are used as powders in the form of micronized powder having a particle size of 600 to 700 meshes like mineral powder. Particularly, since there are innumerable pores in the charcoal, hydrogen peroxide can be permeated into these pores, and hydrogen peroxide is gradually released to the outside, which has the advantage of continuously decomposing organic matters, and is particularly effective in removing rust and red tide .

&Lt; Example 1 >

1) First step

30 parts by weight of tourmaline, 30 parts by weight of tourmaline, 70 parts by weight of zeolite, 50 parts by weight of germanium, 60 parts by weight of silicate and 10 parts by weight of raw ore were mixed with 100 parts by weight of elvanite, Crush to size.

2) Second step

Charcoal and white carbon are mixed at a ratio of 1: 1 and ground to a particle size of 600 mesh.

3) Third step

The above mineral powder, charcoal, white carbon powder, and starch paste were mixed with each other at a ratio of 2: 1: 0.5, and the mixture was kneaded in a roller kneader.

4) Fourth step

The kneaded product is cooked at 80 캜 under a pressure of 50 psi for 10 minutes, and then processed into a pellet form.

5) Step 5

The processed pellet was placed in a far-infrared ray drier and heated at 70 DEG C for 2 hours to dry to a moisture content of 10 wt%.

&Lt; Examples 2 to 5 >

Each production process is the same as in Example 1, and the composition ratios of the components of the respective Examples are as shown in [Table 1].

The composition components and composition ratios of the respective Examples ingredient Example 2 Example 3 Example 4 Example 5 White stone 100 100 100 100 Heavenly earth 20 30 40 40 Tourmaline 20 30 30 40 Zeolite 60 70 70 80 germanium 40 50 40 50 Silicate 50 60 40 70 Raw ore 10 10 20 20 Charcoal and white carbon 150 175 170 200 Starch paste 75 88 85 100

Test group 1 is a green alga or a red tide removing pellet having the composition composition ratio of Example 1, Test group 2 is a green alga or a red tide removing pellet having the composition composition ratio of Example 2 according to the method of Example 1 , And yellow loess was used as a control.

The bird was collected in the ice box the day after the green algae alert in the Seomjin River dam in July, 2017, and it was transported to the air-conditioned car. The container used for the test was a 250 ml Erlenmeyer flask made of glass to facilitate visual observation. The same amount of freshwater algae was inoculated into three 250 ml Erlenmeyer flasks, and then 10 ml each of test group 1, test group 2 and control group was added to each flask inoculated with freshwater algae. After 30 minutes and 1 hour after the test sample treatment, The number of cells per mL was observed. Observation of freshwater algae water was observed under a microscope using a hemacytometer. The results of this experiment are shown in [Table 2].

Algae removal rate 30 minutes elapsed (% removal rate) 1 hour elapsed (% removal rate) Remarks Experiment 1 51 75 Experiment 2 48 72 Control group 25 38

As a result of this experiment, the efficiency (%) of freshwater algae removal at the elapsed time of 30 minutes and 2 hours was 51% and 75% in the experimental group 1, 48% and 72% in the experimental group 2, %, And 38%, respectively. Experimental group 1 showed that the removal efficiency of green algae or red tide removing pellet of Example 1 was high. In experiment 1 and 2, 62.5 and 75.0%, respectively. And it was confirmed that the removal efficiency of freshwater algae was superior at 30 minutes.

Claims

Wherein the pellet composition is a green algae or red tide removing composition comprising minerals consisting of elvan, heavymetal, tourmaline, zeolite, germanium, silicate and biotite and charcoal, white carbon and starch paste.

The method according to claim 1,
Wherein the mineral is 20 to 50 parts by weight of heavenly earth, 20 to 50 parts by weight of tourmaline, 60 to 80 parts by weight of zeolite, 40 to 60 parts by weight of germanium, 40 to 80 parts by weight of silicate, 20 parts by weight of a pellet composition for removing green alga or red tide.

The method according to claim 1,
Wherein the charcoal and the white carbon are mixed at a volume ratio of 1: 1, and the volume ratio of the mineral, charcoal, white carbon and starch paste is 2: 1: 0.5.

Calcining at a high temperature of 1100 to 1300 ° C to obtain a granular material having a particle size of 600 to 700 meshes, a step of calcining the granular material, the granular material, the granite, the granite, the tourmaline, the zeolite,
Pulverizing charcoal and white carbon to a particle size of 600 to 700 mesh;
Mixing the mineral powder, charcoal, white carbon powder, and starch paste into a roller kneader and kneading the mixture uniformly;
Treating the kneaded product at 60 to 120 DEG C under a pressure of 20 to 60 psi for 5 to 10 minutes and then processing the kneaded product into a pellet form;
The processed pellet is heated in a far-infrared ray dryer at 60 to 70 ° C for 2 to 3 hours to be dried to a moisture content of 8 to 10% by weight.
Wherein the pellet is removed from the pellet.