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KR101141757B1 - Manufacturing Method for High Glossy Metallic Sheet with Improved Adhesive Power - Google Patents

Manufacturing Method for High Glossy Metallic Sheet with Improved Adhesive Power Download PDF

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KR101141757B1
KR101141757B1 KR1020040118497A KR20040118497A KR101141757B1 KR 101141757 B1 KR101141757 B1 KR 101141757B1 KR 1020040118497 A KR1020040118497 A KR 1020040118497A KR 20040118497 A KR20040118497 A KR 20040118497A KR 101141757 B1 KR101141757 B1 KR 101141757B1
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weight
parts
layer
film
high gloss
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KR1020040118497A
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Korean (ko)
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KR20060078530A (en
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윤선근
박종열
김효섭
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주식회사 케이씨씨
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B32B2255/205—Metallic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/406—Bright, glossy, shiny surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00—Metals, their alloys or their compounds
    • B32B2311/24—Aluminium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

본 발명에 따른 철판이나 알루미늄판 등에 부착하여 금속효과를 내는 고광택시트를 제공하는 것으로서, 기존의 알루미늄 증착막의 박리현상을 개선하기 위하여 헤어무늬가 형성된 열가소성 수지(PET) 필름과 알루미늄증착막 사이에 아디피산 20 ~ 30중량부, 테레프탈산 10 ~ 20중량부, 이소프탈산 10 ~ 15중량부, 에틸렌글리콜 25 ~ 30중량부, 네오펜틸글리콜 20 ~ 25중량부를 포함하여 제조한 폴리에스테르 공중합체와 용매 30 ~ 60중량부로 제조된 프라이머를 코팅함으로써, 열가소성 수지필름과 알루미늄증착막의 접착력을 개선하였다. 본 발명의 구체적인 고광택성 시트의 형태로는 일면에 열 또는 자외선 경화형 수지층이 형성되고 다른 일면에는 헤어라인 무늬가 형성된 PET 필름과, 상기 헤어라인 무늬의 하부에 순차적으로 프라이머층과 알루미늄 증착층, 우레탄 접착제층, 열가소성수지층으로 이루어진다.
In order to improve the peeling phenomenon of the existing aluminum vapor deposition film, to provide a high gloss sheet attached to an iron plate or an aluminum plate according to the present invention, adipic acid between the thermoplastic resin (PET) film formed of a hair pattern and the aluminum deposition film 20 to 30 parts by weight, 10 to 20 parts by weight of terephthalic acid, 10 to 15 parts by weight of isophthalic acid, 25 to 30 parts by weight of ethylene glycol, 20 to 25 parts by weight of neopentyl glycol and a solvent 30 to 60 By coating the primer prepared in parts by weight, the adhesion between the thermoplastic resin film and the aluminum deposition film was improved. In the form of a specific high gloss sheet of the present invention, a PET film having a heat or ultraviolet curable resin layer formed on one surface and a hairline pattern formed on the other surface thereof, a primer layer and an aluminum deposition layer sequentially below the hairline pattern, It consists of a urethane adhesive layer and a thermoplastic resin layer.

고광택시트, 프라이머층, 헤어라인, 증착막, 알루미늄증착막, 라미네이션, PET, 폴리염화비닐High gloss sheet, primer layer, hairline, evaporation film, aluminum deposition film, lamination, PET, polyvinyl chloride

Description

부착력이 향상된 금속효과를 내는 고광택시트 제조방법{Manufacturing Method for High Glossy Metallic Sheet with Improved Adhesive Power}Manufacturing Method for High Glossy Metallic Sheet with Improved Adhesive Power}

도 1은 본 발명에 따른 금속효과를 내는 고광택시트의 단면도이다.1 is a cross-sectional view of a high gloss sheet having a metal effect according to the present invention.

도 2는 인쇄무늬 층을 포함하는 금속효과를 내는 고광택시트의 일예를 나타낸 단면도이다.2 is a cross-sectional view showing an example of a high gloss sheet having a metal effect including a printed pattern layer.

도 3은 인쇄무늬 층을 포함하는 금속효과를 내는 고광택시트의 또 다른 일예를 나타낸 단면도이다.3 is a cross-sectional view showing another example of a high gloss sheet having a metal effect including a printed pattern layer.

- 도면의 주요부분에 대한 부호 설명 --Explanation of symbols on main parts of drawing-

1 - 자외선경화형 또는 열경화형 수지층 1-UV curable or thermosetting resin layer

2 - 헤어라인 무늬가 형성된 PET 필름2-PET film with hairline pattern

3 - 프라이머층3-primer layer

4 - 금속 증착층4-metal deposition layer

5 - 접착제층5-adhesive layer

6 - 열가소성수지시트층6-thermoplastic resin sheet layer

7a, 7b - 인쇄무늬 층
7a, 7b-Printed Layer

본 발명은 금속효과를 내는 고광택 시트에 관한 것이다. 본 발명은 폴리에틸렌테레프탈레이트(PET) 필름의 일면에 헤어라인을 형성시켜 심도 있고 미려한 금속광택을 가지도록 하여, 명함, 합판, 라벨, 건축자재나 가구 또는 가전제품 등에 적용할 수 있는 시트를 제공하는 것이다. The present invention relates to a high gloss sheet having a metal effect. The present invention is to provide a sheet that can be applied to business cards, plywood, labels, building materials or furniture or home appliances by forming a hairline on one surface of the polyethylene terephthalate (PET) film to have a deep and beautiful metallic gloss will be.

금속성의 고광택성 시트는 헤어라인가공을 한 PET등의 합성수지 필름의 상부층에 진공증착방법으로 알루미늄을 증착하여 헤어라인을 가공한 금속판이나 시트와 동일한 정도의 미려한 금속광택을 가지는 합성지를 제공하는 기술이 일본공개실용 소61-37925호에 공지되어 있다.Metallic high gloss sheet is a technology that provides synthetic paper with the same beautiful metallic gloss as metal sheet or sheet processed hairline by depositing aluminum on the upper layer of synthetic resin film such as PET after hairline processing. It is known from Japanese Patent Application Laid-Open No. 61-37925.

그러나 이러한 종래의 기술들은 PET 필름과 알루미늄 증착층의 부착력이 약하여 철판 가공 시 박리가 일어나는 단점이 있어 이를 해결할 필요가 있었으며 이를 해결하기 위하여 필름과 증착막 사이에 탑-코팅 층을 매개로 하여 접착력을 향상시키는 시도가 있었으나 만족할 만한 성과를 보여주지 못하였다.
However, these conventional technologies have a weak adhesive force between the PET film and the aluminum deposition layer, so that peeling occurs during iron plate processing, which needs to be solved. To solve this problem, the adhesion between the film and the deposition layer is improved through the top-coating layer. Attempts have been made, but they have not been satisfactory.

본 발명은 상기의 문제점을 해결하기 위한 것으로, 금속효과를 내는 고광택 시트의 제조 시, 헤어라인 무늬가 형성된 합성수지판위에 알루미늄 막을 증착하였을 경우 알루미늄 막의 접착력을 보강하기 위하여 연구한 결과 본 발명을 완성하게 되었다. The present invention is to solve the above problems, when manufacturing a high gloss sheet having a metal effect, when the aluminum film is deposited on a synthetic resin plate formed with hairline pattern to study to reinforce the adhesive strength of the aluminum film to complete the present invention It became.                         

따라서, 본 발명은 금속막 효과를 나타내는 고광택성 합성수지필름을 제조할때, 합성수지 필름과 금속증착막의 접착력을 증가시킨 신규한 고광택성 시트를 제공하는 것이다.Accordingly, the present invention provides a novel high gloss sheet which increases the adhesion between the synthetic resin film and the metal deposition film when producing a high gloss synthetic resin film exhibiting a metal film effect.

또한 본 발명은 가공이 용이한 철판 또는 알루미늄판에 금속효과를 부여한 고광택시트를 접착시킨 장식판을 가공하여 가전제품 등에 사용함에 있어, PET 필름과 알루미늄 증착층 사이에 프라이머를 도포하여 가공 시 필름의 박리현상이 일어나지 않도록 하는 것을 목적으로 한다.
In addition, the present invention is used in home appliances by processing a decorative plate bonded to a high-strength sheet imparting a metal effect to an easy-to-process iron plate or aluminum plate, by applying a primer between the PET film and the aluminum deposition layer peeling the film during processing It aims at preventing a phenomenon from occurring.

상기의 알루미늄증착막이 PET 필름과의 접착력의 약화에 의해 박리되는 단점을 해결하기 위하여, 본 발명은 PET 필름에 알루미늄막을 증착하기 전에 PET 표면에 접착력보강 프라이머층을 도포함으로써 알루미늄증착막이 단단히 접착되어 고정될 수 있는 부착력이 향상된 금속효과를 내는 고광택시트 제조하였다. In order to solve the disadvantage that the aluminum deposition film is peeled off by the weakening of the adhesive force with the PET film, the present invention is applied by fixing the adhesion reinforcing primer layer on the PET surface before depositing the aluminum film on the PET film, the aluminum deposition film is firmly bonded and fixed A high-gloss sheet was produced to produce a metal effect with improved adhesion.

본 발명에 따른 금속효과를 내는 고광택시트는 도 1에서와 같이 일면에 열 또는 자외선 경화형 수지층(1)이 형성되고 다른 일면에는 헤어라인 무늬가 형성된 PET 필름(2)을 형성하고, 상기 헤어라인 무늬의 하부에 프라이머층(3)과 금속 증착층(4)이 순차적으로 형성되며, 우레탄 접착제(5)로 도장한 후 건조 라미네이션(Dry lamination)하고, 열가소성수지시트층(6)을 적층하여 제조된다. The high gloss sheet having a metal effect according to the present invention has a heat or ultraviolet curable resin layer 1 formed on one surface and a PET film 2 having a hairline pattern formed on the other surface, as shown in FIG. The primer layer 3 and the metal deposition layer 4 are sequentially formed on the lower part of the pattern, and are coated with a urethane adhesive 5, followed by dry lamination, and lamination of the thermoplastic resin sheet layer 6. do.

또한 본 발명에서 있어서, 도 2 및 3에서 보이는 바와 같이 상기 자외선 경화형 수지층(1)을 형성하기 전, 또는 PET 필름에 헤어라인을 형성한 후 다양한 무 늬층(7a, 7b)을 포함하는 고광택 시트를 추가로 더 포함하는 것도 가능하다.In addition, in the present invention, as shown in Figures 2 and 3, before forming the ultraviolet curable resin layer (1), or after forming a hairline on a PET film, a high gloss sheet including various layered layers (7a, 7b) It is also possible to further include more.

본 발명에 따른 하층기재인 상기 열가소성수지시트층(6)은 유연성, 투명성 및 내열성 등의 관점에서 폴리염화비닐필름이 선호되지만, 폴리염화비닐 이외에도 통상의 플라스틱 필름이라면 크게 제한 받지 않는다. 예를 들면, 폴리프로필렌필름을 포함하는 폴리올레핀필름, 폴리스티렌필름 및 폴리에틸렌테레프탈레이트나 폴리부틸렌테레프탈레이트와 같은 폴리에스테르 필름, 또는 폴리이미드, 폴리설폰등의 엔지니어링플라스틱 필름 등에서 선택가능하며 통상 두께는 50 ~ 1000㎛의 두께를 가지는 것을 사용하는 것이 강도나 유연성등의 기계적 물성을 만족하여 좋다.The thermoplastic resin sheet layer 6, which is a base material according to the present invention, is preferably polyvinyl chloride film in view of flexibility, transparency, heat resistance, and the like, but is not particularly limited as long as it is a normal plastic film in addition to polyvinyl chloride. For example, a polyolefin film including a polypropylene film, a polystyrene film and a polyester film such as polyethylene terephthalate or polybutylene terephthalate, or an engineering plastic film such as polyimide or polysulfone may be selected. Using a material having a thickness of ˜1000 μm may satisfy mechanical properties such as strength and flexibility.

본 발명의 상층기재에 사용하는 PET필름(2)은 헤이즈도가 1 ~ 10%, 빛투과율 90%이상, 광택도 150%이상, 두께 20 ~ 50㎛인 고투명 PET 필름을 사용하는 것이 더욱 선명한 금속성 효과를 부여할 수 있다.PET film (2) used in the upper substrate of the present invention has a haze of 1 to 10%, light transmittance of 90% or more, gloss of 150% or more, it is more vivid metallic to use a highly transparent PET film having a thickness of 20 ~ 50㎛ It can give an effect.

본 발명에서 상기 PET 필름의 일면에 헤어라인 무늬를 형성시킴으로서 미려한 금속성의 느낌을 갖도록 하는데, 헤어라인 무늬를 형성하는 방법은 통상의 헤어라인 무늬 생성방법, 부직포 등에 연마제를 균일하게 부착한 후 필름표면에 연마하여 생성시키는 방법, 샌드패이퍼 등의 수단을 이용하여 표면에 연마함으로써 형성시키는 등 다양한 방법을 사용할 수 있는데 그 방법에는 특별한 제한을 받지 않는다, In the present invention, by forming a hairline pattern on one surface of the PET film to have a beautiful metallic feeling, the method of forming the hairline pattern is a conventional hairline pattern generating method, the surface of the film after uniformly attaching an abrasive to a nonwoven fabric It is possible to use a variety of methods such as forming by polishing on the surface by means of grinding, sandpaper, etc., the method is not particularly limited,

본 발명의 헤어라인 무늬는 통상적으로 깊이가 0.1 ~ 1.0㎛ 이하이고, 평균 폭은 5㎛ 이하로 연속적으로 표면에 형성되게 하는 것이 더욱 금속과 같은 효과를 부여할 수 있어서 좋다. 상기 범위를 벗어날 경우에는 본 발명에서 목적으로 하는 금속광택이 충분히 얻어질 수 없으므로 가능한 상기 범위내로 조절하는 것이 좋다.The hairline pattern of the present invention usually has a depth of 0.1 to 1.0 mu m or less, and an average width of 5 mu m or less can be provided on the surface continuously, which may further impart a metal-like effect. If it is out of the above range, the metal gloss desired in the present invention may not be sufficiently obtained, so it is better to adjust it within the above range.

본 발명은 헤어라인을 형성한 PET 필름(2)의 일면에 알루미늄 등의 금속층(4)을 증착하기 전에 PET 필름과 알루미늄증착층의 접착력을 강화하기 위하여 프라이머층(3)을 형성시키는데, PET 필름과 알루미늄증착층 간의 접착력을 향상시키기 위하여 코팅하는 프라이머층(3)은, 아디프산 20 ~ 30중량부, 테레프탈산 10 ~ 20중량부, 이소프탈산 10 ~ 15중량부, 에틸렌글리콜 25 ~ 30중량부, 네오펜틸글리콜 20 ~ 25중량부를 포함하여 제조한 폴리에스테르 공중합체를 사용하는 것을 특징으로 한다. The present invention forms a primer layer (3) to enhance the adhesion between the PET film and the aluminum deposition layer before depositing a metal layer (4) such as aluminum on one surface of the PET film (2) formed hairline, PET film The primer layer 3 coated in order to improve the adhesion between the aluminum deposition layer and 20 parts by weight of adipic acid, 10 to 20 parts by weight of terephthalic acid, 10 to 15 parts by weight of isophthalic acid, 25 to 30 parts by weight of ethylene glycol , Characterized in that to use a polyester copolymer prepared by including 20 to 25 parts by weight of neopentyl glycol.

본 발명의 폴리에스테르 공중합체는 통상의 벌크중합 또는 용액중합 또는 계면중합으로 제조할 수 있으며, 폴리에스테르 공중합체를 제조한 후, 용매에 용해하여 그 용액을 통상의 코팅방법 예를 들면, 그라비아코팅법, 바코팅법, 플로우크팅 등의 방법으로 코팅하며, 좋게는 그라비아코팅법이 좋다. The polyester copolymer of the present invention may be prepared by conventional bulk polymerization or solution polymerization or interfacial polymerization, and after preparing the polyester copolymer, the polyester copolymer is dissolved in a solvent and the solution is coated in a conventional coating method, for example, gravure coating. It is coated by a method such as a method, a bar coating method, a flow coating, and preferably, a gravure coating method is preferable.

프라이머층(3)의 코팅은 용매로서, 톨루엔, 자이렌, 메틸에틸케톤을 포함하는 케톤류, 클로로포름등의 할로겐화탄화수소 등이 용매 30 ~ 60중량부에 상기의 폴리에스테르 공중합체를 용해한 용액을 코팅한다. 코팅두께는 0.1 ~ 1.0㎛ 로 도포하는데, 상기의 두께는 용액의 점도를 조절하여 두께를 조절할 수 있으므로 더 이상의 설명은 생략한다. 본 발명의 프라이머층을 구성하는 중합체의 단량체로서 아디피산 20 ~ 30중량부, 테레프탈산 10 ~ 20중량부, 이소프탈산 10 ~ 15중량부, 에틸렌글리콜 25 ~ 30중량부, 네오펜틸글리콜 20 ~ 25중량부를 포함하여 제조한 폴리에스테르 공중합체를 사용하는 경우에 PET 필름과 알루미늄증착막의 접착력이 가 장 우수한 시트를 얻을 수 있었다.Coating of the primer layer 3 is a solvent, toluene, xylene, ketones containing methyl ethyl ketone, halogenated hydrocarbons such as chloroform and the like to coat a solution in which the polyester copolymer is dissolved in 30 to 60 parts by weight of the solvent. . Coating thickness is applied in 0.1 ~ 1.0㎛, the above thickness can be adjusted by adjusting the viscosity of the solution, so further description is omitted. As a monomer of the polymer which comprises the primer layer of this invention, 20-30 weight part of adipic acids, 10-20 weight part of terephthalic acids, 10-15 weight part of isophthalic acids, 25-30 weight part of ethylene glycol, 20-25 weight of neopentyl glycol In the case of using the polyester copolymer prepared by including the part, the sheet having the best adhesion between the PET film and the aluminum deposition film was obtained.

본 발명의 금속증착층(4)은 통상적으로 알루미늄막을 사용한다. 알루미늄 증착막은 통상의 진공증착법을 사용하여 증착하는데, 10-2 ~ 10-6토르의 진공에서 300 ~ 1800℃의 온도에서 진공증착을 실시하여 200 ~ 500Å 두께의 증착막을 형성한다. As the metal deposition layer 4 of the present invention, an aluminum film is usually used. Aluminum deposition film is deposited using a conventional vacuum deposition method, the vacuum deposition at a temperature of 300 ~ 1800 ℃ in a vacuum of 10 -2 ~ 10 -6 Torr to form a deposited film of 200 ~ 500Å thickness.

본 발명의 상기 PET 필름의 헤어라인이 형성되고 진공증착막이 순차적으로 형성되는 반대 면은 열경화 또는 자외선경화형 수지층을 형성시켜 표면의 투명성을 유지하면서 표면을 보호하는 효과를 나타내도록 한다. 자외선 경화형 수지는 아크릴단량체와 자외선에 의한 광개시제 및 용매로 구성되는 통상의 자외선 경화형 조성물이라면 어떤 것이라도 사용할 수 있으며 또한 당 분야에서는 많은 기술이 공지되어 있고, 그 경화에 의해 광투과성이 우수한 성분이라면 어떠한 것이라도 좋으므로, 본 발명에서는 이에 대한 구체적 한정을 하지 않는다. 또한 본 발명에서는 열경화 수지도 사용가능한데, 예를 들면 투명 우레탄 경화형수지나 에폭시수지 등이 사용될 수 있고 자외선 경화시 사용한 아크릴 또는 메타아크릴기, 비닐기, 알릴기 등의 열중합 가능한 어떠 것이라도 사용될 수 있다. The opposite side on which the hairline of the PET film of the present invention is formed and the vacuum deposition film is sequentially formed is formed to form a thermosetting or ultraviolet curing resin layer to protect the surface while maintaining the transparency of the surface. The ultraviolet curable resin can be used as long as it is a conventional ultraviolet curable composition composed of an acryl monomer, an ultraviolet photoinitiator and a solvent, and many techniques are known in the art, and any component having excellent light transmittance by the curing can be used. May be used, and the present invention does not specifically limit it. In the present invention, a thermosetting resin may also be used, for example, a transparent urethane curable resin or an epoxy resin may be used, and any one capable of thermal polymerization such as acrylic or methacrylic group, vinyl group, allyl group, etc. used during ultraviolet curing may be used. Can be.

본 발명에 따른 상층기재와 하층기재를 접착하는 접착제(5)로는 이소프탈산 20 ~ 30중량부, 아디피산 25 ~ 30중량부, 네오펜틸글리콜 30 ~ 40중량부, 에틸렌글리콜 5 ~ 15중량부, 1,6 헥산디올 1 ~ 10중량부, 톨루엔디이소시아네이트 1 ~ 10중량부로 이루어진 폴리에스터우레탄수지에 톨루엔디이소시아네이트 65 ~ 75중량부, 트리메틸로프로판 15 ~ 25중량부로 이루어진 경화제에 50 ~ 100중량부의 용제로 구 성된 우레탄 2액형 접착제를 5 ~ 15㎛ 도포한 후 접착하는 것이 필름의 유연성이나 내충격성, 작업성 면에서 좋다. 우레탄 접착제는 그 사용에 따라 투명성이 그대로 유지되어 최종 시트의 금속과 같은 미려한 효과를 얻을 수 있다.Adhesive 5 for bonding the upper substrate and the lower substrate according to the present invention is 20 to 30 parts by weight of isophthalic acid, 25 to 30 parts by weight of adipic acid, 30 to 40 parts by weight of neopentyl glycol, 5 to 15 parts by weight of ethylene glycol, 50 to 100 parts by weight of a curing agent consisting of 65 to 75 parts by weight of toluene diisocyanate and 15 to 25 parts by weight of trimethyllopropane in a polyester urethane resin composed of 1 to 10 parts by weight of 1,6 hexanediol, 1 to 10 parts by weight of toluene diisocyanate The urethane two-component adhesive composed of solvent is applied after applying 5 ~ 15㎛, and it is good in terms of flexibility, impact resistance and workability of the film. The urethane adhesive can maintain transparency as it is used, thereby obtaining a beautiful effect such as the metal of the final sheet.

또한 본 발명의 층구조에서 자외선 경화형 수지층(1)을 형성하기 전에 인쇄무늬층(7a)을 형성하거나, 또는 PET 필름에 헤어라인을 형성한 후 인쇄무늬층(7b)을 포함하여 외관을 더욱 향상시키는 효과를 가져올 수 있다.In addition, in the layer structure of the present invention, the printed pattern layer 7a is formed before the ultraviolet curable resin layer 1 is formed, or after the hairline is formed on the PET film, the printed pattern layer 7b is further included. It can have the effect of improving.

이하는 본 발명에 따른 부착력이 향상된 금속효과를 내는 고광택시트 제조방법을 구체적으로 설명한다.Hereinafter, a method of manufacturing a high gloss sheet having an improved metal adhesion effect according to the present invention will be described in detail.

금속효과를 내는 고광택시트는 도 1에서와 같이 하층기재인 폴리염화비닐(PVC) 시트(6)와, 일면에 자외선경화형 수지조성물 또는 열경화형 수지조성물(1)이 도포되고, 다른 일면에는 헤어라인 무늬(2)를 형성하고, 프라이머층(3) 및 알루미늄 증착층(4)을 순차적으로 형성한 상층기재인 PET 필름을, 우레탄 접착제(5)로 도포하여 건조 라미네이션(Dry lamination)하여 제조한다.The high gloss sheet having a metallic effect is a polyvinyl chloride (PVC) sheet 6, which is a base material as shown in FIG. A PET film, which is an upper substrate based on which the pattern 2 is formed and the primer layer 3 and the aluminum deposition layer 4 are sequentially formed, is coated with a urethane adhesive 5 to produce a dry lamination.

이때 PET 상부에 도포되는 자외선 경화형 수지조성물 또는 열경화형 수지조성물에 염료 및 안료를 첨가하여 다양한 색상을 낼 수 있다.
In this case, dyes and pigments may be added to the ultraviolet curable resin composition or the thermosetting resin composition applied on the PET to give various colors.

이하는 본 발명의 실시예 및 비교예를 통하여 더욱 구체적으로 본 발명을 설명하며, 본 발명은 그 기술 사상내에서 당업자가 다양하게 변형하여 실시할 수 있는 것으로서, 본 발명이 하기의 실시예에 의해만 한정되지는 않는다.
Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples of the present invention, and the present invention can be variously modified and implemented by those skilled in the art within the spirit of the present invention. It is not limited.

실시예Example

헤이즈도가 6%, 빛투과율 92%이상, 광택도 160%이고 두께가 25㎛인 고투명 PET필름 표면에, 에폭시아크릴레이트(SK-UCB Ebecryl 3700) 47중량%, 펜타에리쓰리톨 트리아크릴레이트 20중량%, 트리메틸올프로판트리아크릴레이트 15중량%, 1,6-핵산디올디아크릴레이트 12중량%, 광개시제(시바-가이기 D1173) 5중량% 및 레벨링제(SK-UCB Ebecryl 350) 1중량%로 구성된 자외선 경화형 도료 조성물을 바코팅에 의해 6㎛ 도포하여 자외선을 조사하여 경화시키고, 다른 일면에 평균 깊이 0.24㎛의 폭 3.2㎛ 헤어라인 무늬를 형성하였다. 상기 헤어라인이 형성된 표면에 아디피산 25중량부, 테레프탈산 15중량부, 이소프탈산 13중량부, 에틸렌글리콜 27중량부, 네오펜틸글리콜 22중량부를 중합하여 제조한 폴리에스테르계 프라이머가 용해된 톨루엔 용액을 코팅하여 건조함으로써 0.7㎛ 두께의 프라이머층을 형성하고, 이를 충분히 건조한 후, 10-4토르 1420℃에서 진공증착하여 400Å의 평균두께를 가지는 알루미늄 진공증착막을 형성하여 상층기재층을 제조하였다.47% by weight of epoxy acrylate (SK-UCB Ebecryl 3700), pentaerythritol triacrylate 20, on the surface of a highly transparent PET film having a haze of 6%, a light transmittance of 92%, a gloss of 160%, and a thickness of 25 μm. Wt%, 15 wt% trimethylolpropanetriacrylate, 12 wt% 1,6-nucleodiol diacrylate, 5 wt% photoinitiator (Ciba-Geigi D1173) and 1 wt% leveling agent (SK-UCB Ebecryl 350) The UV curable coating composition composed of 6 μm was coated by bar coating to irradiate ultraviolet rays and cured, thereby forming a 3.2 μm wide hairline pattern having an average depth of 0.24 μm on the other surface. A toluene solution containing a polyester primer prepared by polymerizing 25 parts by weight of adipic acid, 15 parts by weight of terephthalic acid, 13 parts by weight of isophthalic acid, 27 parts by weight of ethylene glycol, and 22 parts by weight of neopentyl glycol was formed on the surface of the hairline. The coating layer was dried to form a primer layer having a thickness of 0.7 μm, and after sufficiently drying, an aluminum vacuum deposition film having an average thickness of 400 kV was formed by vacuum depositing at 10-4 torr at 1420 ° C. to prepare an upper base layer.

상기 상층기재층 하부에 폴리우레탄 2액형 접착제를 12㎛의 두께로 도포한 후, 105㎛ 두께의 폴리염화비닐필름의 하층기재를 상층기재와 건조 라미네이션하여 고광택 금속성 시트를 제조하였다. 그 결과를 표 1에 기재하였다.
After the polyurethane two-component adhesive was applied to the lower portion of the upper substrate layer to a thickness of 12㎛, the lower substrate of the polyvinyl chloride film of 105㎛ thickness dry lamination with the upper substrate to prepare a high-gloss metallic sheet. The results are shown in Table 1.

비교예Comparative example

상기 실시예에서 프라이머층을 형성하지 않은 것으로 제외하고는 동일하게 제조하였다. 그 결과를 표 1에 기재하였다.
Except that did not form a primer layer in the Example was prepared in the same manner. The results are shown in Table 1.

표 1. 박리시험Table 1. Peel Test

Figure 112004063258664-pat00001

Figure 112004063258664-pat00001

본 발명에서는 PET필름과 알루미늄증착층의 부착력을 높이기 위한 프라이머의 사용으로 에릭슨 시험 시 박리현상이 일어나지 않고, 표면에 도포되는 수지조성물에 염료 및 안료를 첨가하여 여러 가지 색상을 가지는 금속효과를 내는 고광택시트를 제조할 수 있다.In the present invention, the use of a primer for enhancing the adhesion between the PET film and the aluminum deposition layer does not cause peeling during the Ericsson test, and adds dyes and pigments to the resin composition applied to the surface to give a metallic effect having various colors. Sheets can be produced.

Claims (6)

철판 및 알루미늄판에 합지되어 사용되는 금속효과를 내는 고광택시트로서, 일면에 자외선경화형 또는 열경화형 수지층이 도포된 PET 필름의 다른 이면에 헤어라인 무늬층을 형성하고, 순차적으로 폴리에스테르 공중합체로 이루어지는 프라이머층, 알루미늄 증착층, 우레탄계 접착제층, 열가소성 수지시트층으로 이루어진 금속효과를 내는 고광택 시트.A high gloss sheet that produces a metal effect used by lamination to an iron plate and an aluminum plate, wherein a hairline pattern layer is formed on the other side of a PET film coated with an ultraviolet curable or thermosetting resin layer on one surface, and sequentially a polyester copolymer. A high gloss sheet having a metallic effect comprising a primer layer, an aluminum deposition layer, a urethane adhesive layer, and a thermoplastic resin sheet layer. 제 1항에 있어서,The method of claim 1, 자외선 경화형 수지층을 형성하기 전, 또는 PET 필름에 헤어라인을 형성한 후 PET 필름의 일측면에 인쇄무늬 층을 포함하는 것을 특징으로 하는 금속효과를 내는 고광택 시트.Before forming the UV-curable resin layer, or after forming the hairline on the PET film, a high gloss sheet having a metallic effect, comprising a printed pattern layer on one side of the PET film. 제 1항에 있어서,The method of claim 1, 상기 열가소성 수지시트는 폴리염화비닐, 폴리프로필렌을 포함하는 폴리올레핀, 폴리스티렌, 폴리에틸렌테레프탈레이트 또는 폴리부틸렌테레프탈레이트를 포함하는 폴리에스테르 및 폴리이미드 또는 폴리설폰을 포함하는 엔지니어링플라스틱에서 선택되는 어느 하나를 사용하는 금속효과를 내는 고광택시트.The thermoplastic resin sheet may be any one selected from polyvinyl chloride, polyester including polypropylene, polystyrene, polyethylene terephthalate or polyester including polybutylene terephthalate and engineering plastic including polyimide or polysulfone. High gloss sheet with a metallic effect. 1항 내지 2항에서 선택되는 어느 한 항에 있어서,The compound according to any one of claims 1 to 2, 헤어라인이 형성된 PET필름과 알루미늄증착층 사이의 상기 프라이머층은 아디피산 20 ~ 30중량부, 테레프탈산 10 ~ 20중량부, 이소프탈산10 ~ 15중량부, 에틸렌글리콜 25 ~ 30중량부, 네오펜틸글리콜 20 ~ 25중량부를 포함하는 폴리에스테르 공중합체와 용매 30 ~ 60중량부로 이루어진 것을 특징으로 하는 금속효과를 내는 고광택시트.The primer layer between the hair film formed PET film and the aluminum deposition layer is 20 to 30 parts by weight of adipic acid, 10 to 20 parts by weight of terephthalic acid, 10 to 15 parts by weight of isophthalic acid, 25 to 30 parts by weight of ethylene glycol, neopentyl glycol High-gloss sheet with a metal effect, characterized in that consisting of 20 to 25 parts by weight of a polyester copolymer and 30 to 60 parts by weight of a solvent. 제 1항에 있어서,The method of claim 1, 상기 PET필름의 표면에 형성되는 헤어라인의 무늬는 0.1 ~ 1.0㎛ 깊이이고, 평균 폭은 3.2 ~ 5㎛인 것을 특징으로 하는 금속효과를 내는 고광택시트.The pattern of the hairline formed on the surface of the PET film is 0.1 ~ 1.0㎛ deep, the average width is 3.2 ~ 5㎛ high gloss sheet having a metal effect, characterized in that. 제 1항에 있어서, The method of claim 1, 프라이머층의 두께는 0.1 ~ 1.0㎛ 인 것을 특징으로하는 금속효과를 내는 고광택시트.The thickness of the primer layer is 0.1 ~ 1.0㎛ high gloss sheet having a metal effect, characterized in that.
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