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KR100971290B1 - Sputtering wheel manufacturing method with thermosetting paint - Google Patents

Sputtering wheel manufacturing method with thermosetting paint Download PDF

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KR100971290B1
KR100971290B1 KR1020080020839A KR20080020839A KR100971290B1 KR 100971290 B1 KR100971290 B1 KR 100971290B1 KR 1020080020839 A KR1020080020839 A KR 1020080020839A KR 20080020839 A KR20080020839 A KR 20080020839A KR 100971290 B1 KR100971290 B1 KR 100971290B1
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aluminum wheel
aluminum
washing
wheel
drying
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Korean (ko)
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KR20090095728A (en
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승현창
김창헌
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승현창
김창헌
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/02Pretreatment of the material to be coated
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/02Pretreatment of the material to be coated
    • C23C14/021Cleaning or etching treatments
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3407Cathode assembly for sputtering apparatus, e.g. Target
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58After-treatment

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

본 발명은 알루미늄 휠 건식 도금방법에 관한 것으로 기존의 방법에서 적용되는 일반적인 공정을 구체화하고 공정을 추가함으로서 알루미늄휠의 표면 광택성이 우수하고 염 또는 염수에 대한 내식성 및 내산성이 우수하여 크롬휠에 대응하여 제조원가는 물론이고 친환경적인 부가가치를 높일 수 있도록 한 열건 도료에 의한 스퍼터링 휠 제조방법에 관한 것으로서,The present invention relates to an aluminum wheel dry plating method by specifying a general process applied in the existing method and adding the process to excellent surface gloss of aluminum wheels and to excellent corrosion resistance and acid resistance to salt or saline to cope with chrome wheels. It relates to a manufacturing method of sputtering wheels by heat-drying paint that can increase not only manufacturing cost but also environmentally-friendly added value.

본 발명인 열건 도료에 의한 스퍼터링 휠 제조방법에 관한 구체적인 해결적 수단은,The specific solving means regarding the sputtering wheel manufacturing method by the hot-dry paint of this inventor,

"알루미늄 휠 표면에 쇼트볼을 쏘아 알루미늄휠 표면에 이물질을 제거하고 도장의 부착성을 향상시키는 소재준비단계와, 알루미늄 휠 표면의 이물질, 유분 등의 오물을 제거하기 위하여 탕세, 예비탈지, 본탈지, 제1,2차 수세, 중화, 제3,4차 수세, 피막, 제5,6차 수세, 순수세, 수절건조와 같은 공정을 순차적으로 진행하는 전처리 단계와, 폴리에스테르수지 또는 폴리에스테르수지와 에폭시수지가 혼합된 것으로, 색상은 회색 또는 검정색 의 혼합분체도료를 에어분사압력(Total Air Volume) 3-6N㎡/hr, 토출량(Power Output) 15~90%, 발생전류 10~50㎂로 코로나 정전도장으로 도포하여 건조로에서 230±10℃로 10분간 건조시키는 하도분체도장 단계와, 알루미늄 휠 표면의레벨링((Leveling)을 확보하기 위해 폴리에스테르 액체도료를 토출량 80~170kgf/㎠, 분사폭 2.5~5.0kgf/㎠, 미립화 2.0~3.5kgf/㎠,로 에어스프레이 방식으로 도포하여 셋팅룸에서 도장하는 중도도장단계와, 진공챔버내에 불활성기체인 아르곤(Ar)를 넣고 알루미늄, 티타늄, 크롬, 스테인레스중 어느 하나의 재질로 된 타겟에 음전압을 걸어 음극(Cathode)으로 부터 방출된 전자들이 아르곤 기체와 충돌 아르곤을 이온화되어 알루미늄휠 표면으로 부터 튀어나온 원자와 운동량 교환에 의해 알루미늄 휠 표면에 박막을 형성하는 스퍼터링단계와, 상기 스퍼터링 단계의 후 공정으로 아크릴분체 또는 아크릴 액체 도료를 사용하여 알루미늄 휠 표면에 투명 코팅하는 상도단계로 이루어진 것"을 그 구성적 특징으로 하고 있다."The material preparation step is to shoot the shot ball on the surface of aluminum wheel to remove foreign substances on the surface of aluminum wheel and improve the adhesion of paint, and to remove dirt, oil, etc. from the surface of aluminum wheel. , Pre-treatment step of sequentially processing such as 1st, 2nd washing, neutralization, 3rd, 4th washing, coating, 5th, 6th washing, pure water, water drying, and polyester resin or polyester resin And Epoxy Resin are mixed. The color is gray or black mixed powder paint with 3-6Nm2 / hr of total air volume, 15 ~ 90% of discharge power and 10 ~ 50㎂ of generated current. The powder coating step is applied by corona electrostatic coating and dried at 230 ± 10 ℃ in the drying furnace for 10 minutes, and 80 ~ 170kgf / ㎠, spray width of polyester liquid paint is applied to secure the leveling of aluminum wheel surface. 2.5 ~ 5.0kgf / ㎠, fine The middle coating step is applied by air spray method at 2.0 ~ 3.5kgf / ㎠, and it is applied in the setting room, and the argon (Ar) which is inert gas is put in the vacuum chamber and made of any one of aluminum, titanium, chromium and stainless steel. A sputtering step of applying a negative voltage to the target and electrons emitted from the cathode collide with argon gas to form a thin film on the surface of the aluminum wheel by exchanging momentum with an atom protruding from the surface of the aluminum wheel; After the sputtering step, a top coat step of transparently coating the surface of the aluminum wheel using an acrylic powder or an acrylic liquid paint is used.

상기와 같이 구성된 본 발명인 열건 도료에 의한 스퍼터링 휠 제조방법은 알루미늄휠의 표면 광택성이 우수하고 염 또는 염수에 대한 내식성 및 내산성, 내마모성이 우수하여 크롬휠에 대응하여 제조원가는 물론이고 친환경적인 부가가치를 높일 수 있다.The sputtering wheel manufacturing method according to the present invention heat-drying paint configured as described above is excellent in surface glossiness of aluminum wheels and excellent in corrosion resistance, acid resistance, and abrasion resistance to salt or salt water to increase the production cost as well as eco-friendly added value in response to chrome wheels. Can be.

전처리단계, 하도분체도장단계, 중도도장단계, 스퍼터링단계, 상도단계. Pretreatment step, undercoat powder coating step, middle coating step, sputtering step, top coat step.

Description

열건 도료에 의한 스퍼터링 휠 제조방법{Sputtering wheel manufacturing method with thermosetting paint}Sputtering wheel manufacturing method with thermosetting paint

본 발명은 알루미늄 휠 건식 도금방법에 관한 것으로 기존의 방법에서 적용되는 일반적인 공정을 구체화하고 공정을 추가함으로서 알루미늄휠의 표면 광택성이 우수하고 염 또는 염수에 대한 내식성 및 내산성이 우수하여 크롬휠에 대응하여 제조원가는 물론이고 친환경적인 부가가치를 높일 수 있도록 한 열건 도료에 의한 스퍼터링 휠 제조방법에 관한 것이다.The present invention relates to an aluminum wheel dry plating method by specifying a general process applied in the existing method and adding the process to excellent surface gloss of aluminum wheels and to excellent corrosion resistance and acid resistance to salt or saline to cope with chrome wheels. The present invention relates to a method for manufacturing a sputtering wheel by heat-drying paint that can increase manufacturing costs as well as environment-friendly added value.

일반적으로 자동차 타이어를 지지하여 주는 휠은 철판을 구부려 만든 철제 휠 즉, 주철휠과 알루미늄을 소재로 한 알루미늄휠로 나누어지며, 오늘날에서는 대부분의 중소형 및 대형차도 대부분이 알루미늄 휠을 사용하는 것이 일반적인 것으로서 알루미늄휠은 외관이 미려할 뿐만 아니라 가벼워 핸들 조작이 용이하며, 열전도율이 높아 주행중 지면과 마찰에 의해 타이어에 발생된 열을 신속히 흡수 방출하므로 타이어를 과열로부터 보호하게 되며, 또한, 강하고 탄성력이 있어 타이어가 펑크날 경우 주철휠과 같이 쉽게 찌그러지거나 쉽게 깨지지 않아 안전에 크게 기여 하게 된다. In general, the wheels that support automobile tires are divided into steel wheels made of iron plate, that is, cast iron wheels and aluminum wheels made of aluminum. Today, most of small and medium-sized and large vehicles use aluminum wheels. The aluminum wheel is not only beautiful in appearance but also light in weight, so it is easy to operate the handle.The high thermal conductivity allows the tire to quickly absorb and release heat generated by friction with the ground while driving, thus protecting the tire from overheating. If it is a punctured blade, it is not easily crushed or broken like cast iron wheels, which greatly contributes to safety.

이와 같이 기능적으로 효과가 우수한 알루미늄휠은 외관을 아름답게 하며, 표면의 내마모성을 증가시키기 위하여 표면처리를 행하게 되는 바, 종래 알루미늄휠 표면처리 방법으로는, As described above, aluminum wheels having excellent functional effects are beautifully coated and subjected to surface treatment in order to increase the wear resistance of the surface. As a conventional aluminum wheel surface treatment method,

첫 번째로, 알루미늄휠 표면에 도료를 도장하는 표면처리 방법이 있으며, Firstly, there is a surface treatment method for painting the aluminum wheel surface.

두 번째로, 알루미늄휠 표면을 도금에 의한 표면처리 방법이 수행되고 있다. Secondly, a surface treatment method by plating an aluminum wheel surface is performed.

상기와 같이 도료를 이용한 도장처리 방법에 의한 알루미늄휠 표면처리 방법은 공정이 간단하며, 저렴하게 행할 수 있으나, 표면이 고급스럽지 못하고, 칠해지는 도료와 알루미늄휠과의 밀착성이 양호하지 못해 충격에 의해 쉽게 벗겨지는등 내마모성이 떨어져 고급차종에 있어서는 도장에 의해 표면처리한 알루미늄휠은 널리 채택되지 못하는 실정이다. As described above, the aluminum wheel surface treatment method using the coating method using the paint is simple and inexpensive, but the surface is not high-quality, and the adhesion between the painted paint and the aluminum wheel is not good, so It is not easy to peel off and wear resistance, high-grade aluminum wheel surface treatment by painting is not widely adopted.

반면에, 도금에 의한 알루미늄휠 표면처리 방법에 있어서는 표면에 금색, 은색, 코발트색등 광택성의 색상을 얻을 수 있어 화려하며, 고급스러운 표면 광택을 얻을 수 있으며, 도금처리할시 표면이 경화되어 쉽게 흠집이 발생하지 않는 등 내마모성이 강화된 알루미늄휠을 얻을 수 있는 장점이 있다.On the other hand, in the method of surface treatment of aluminum wheels by plating, gloss colors such as gold, silver, and cobalt colors can be obtained on the surface, resulting in a brilliant, high-quality surface gloss. There is an advantage in that an aluminum wheel with abrasion resistance is enhanced such that no scratch is generated.

그러나, 알루미늄휠의 표면을 도금처리하려면 도금에 앞서 알루미늄휠 표면을 곱게 연마 가공하여 표면의 거친 것을 제거해야만 도금이 가능하게 된다. However, in order to plate the surface of the aluminum wheel, the surface of the aluminum wheel may be polished finely to remove the roughness of the surface of the aluminum wheel before plating.

알루미늄은 그 소재의 특성상 경도가 낮고, 탄력성이 있는 금속이라 표면을 매끄럽게 연마하는 데에는 많은 시간이 필요하며, 숙련된 작업자라야만 비로소 가능하게 된다. 따라서, 알루미늄휠의 도금처리 비용중 대부분의 비용은 도금 자체의 비용보다는 도금을 위해 표면을 연마하는 전처리 비용이 대부분을 차지하게 된다. Aluminum is a material with low hardness and elasticity due to its material, so it takes a lot of time to smoothly polish the surface, and only a skilled worker can make it possible. Therefore, most of the cost of the aluminum wheel plating treatment is mainly due to the cost of pretreatment for polishing the surface for plating rather than the cost of the plating itself.

따라서, 도금처리를 위해 실시하는 표면 연마 비용을 절감하면 낮은 비용으로 알루미늄휠을 도금할 수 있게 되는 것이다. Therefore, it is possible to plate the aluminum wheel at low cost by reducing the cost of surface polishing performed for the plating treatment.

한편, 상기 알루미늄 휠에 크롬도금을 한 크롬도금 알루미늄 휠이 크롬의 특징인 장식성이 뛰어난 점을 이용하여 고급자동차에 사용되고 있는데, 이와 같은 크롬도금 알루미늄 휠의 경우는 내마모성 및 외관이 화려한 면을 갖으나, 국제적인 환경규제인 EU 자동차내 중금속 적용규제와 크롬도금 알루미늄 휠의 생산가격 상승과 악성 중금속 폐수를 배출하는 문제점과 휠 자체의 무게 증가로 인하여 서스펜션에 부담을 주게 되며 이 부담은 접지력 약화로 이어지고 이는 로드홀딕화(노면추종성)가 떨어지며 따라서 자동차의 순발력과 연비의 증가가 발생하는 문제점이 있다.On the other hand, the chromium-plated aluminum wheel chromium-plated aluminum wheel is used in high-end cars using the excellent decoration characteristics of the chromium, such as the chrome-plated aluminum wheel has a wear-resistant and colorful appearance In addition, due to the international environmental regulations, heavy metals in EU automobiles, increased production prices of chromium-plated aluminum wheels, the discharge of malignant heavy metal wastewater, and the increased weight of the wheels themselves put a strain on the suspension, which leads to weaker grip. There is a problem in that the roadholding (road followability) is falling and therefore the quickness and fuel economy of the car are increased.

본 발명은 상기와 같은 문제점을 해결하기 위한 것으로서,The present invention is to solve the above problems,

우선, 본 발명은 알루미늄휠을 도금하기에 앞서 수행하는 표면 연마 비용을 절감하는데에 주안점을 두고 개발한 것으로, 종래 일반적으로 행하여지는 연마나 절삭공정을 통해 알루미늄휠 표면을 연마하는 대신에 알루미늄휠 표면을 도장함으로 말미암아 도장 알루미늄휠 표면이 마치 연마 처리한 것과 같은 효과를 가한 후 그 후에 건식도금을 수행토록 하여 도금에 소요되는 전단계 비용인 표면처리 비용을 절감시켜 결국 알루미늄휠의 비용을 저렴하게 할 수 있도록 함에 그 목적이 있고, First, the present invention was developed with the focus on reducing the cost of surface polishing performed prior to plating aluminum wheels. Instead of grinding the surface of aluminum wheels through a conventional grinding or cutting process, the surface of aluminum wheels is polished. By coating, the surface of the painted aluminum wheel can be applied as if it is polished and then dry-plated afterwards, thereby reducing the surface treatment cost, which is the previous step for plating, and thus reducing the cost of the aluminum wheel. To ensure that

다음, 기존의 크롬도금 알루미늄휠과 마찬가지의 내마모성 및 외관의 화려함을 나타내는 고광택 기술을 달성함에도 불구하고 상대적으로 제조원가의 상승을 방지하여 경제성과 품질의 우수성을 동시에 달성함에 그 목적이 있고,Next, despite achieving a high gloss technology that shows the wear resistance and the splendor of appearance similar to the existing chromium-plated aluminum wheels, it aims to simultaneously achieve economic and quality excellence by preventing a rise in manufacturing costs.

다음, 상기와 같은 목적을 달성함에도 불구하고 환경친화적인 알루미늄 휠을 제조 가능하도록 하여 환경폐해를 최소화함에 그 목적이 있고,Next, despite achieving the above object, it is possible to manufacture environmentally friendly aluminum wheel to minimize the environmental harm,

다음, 기존의 일반적인 공정을 구체화 및 추가함으로서 알루미늄휠의 표면 광택성이 우수하고 염 또는 염수에 대한 내식성 및 내산성이 우수한 알루미늄 휠을 제조함으로서 제조원가의 상승을 방지함에도 불구하고 제품의 고급화를 추구함에 본 발명의 목적이 있다.Next, by incorporating and adding existing general processes to manufacture aluminum wheels having excellent surface glossiness of aluminum wheels and excellent corrosion resistance and acid resistance to salt or brine, the present invention seeks to improve the quality of products despite preventing increase in manufacturing cost. There is an object of the invention.

상기와 같은 본 발명의 목적을 달성하기 위한 구체적인 해결적 수단은,Specific solving means for achieving the object of the present invention as described above,

"알루미늄 휠 표면에 쇼트볼을 쏘아 알루미늄휠 표면에 이물질을 제거하고 도장의 부착성을 향상시키는 소재준비단계와, 알루미늄 휠 표면의 이물질, 유분 등의 오물을 제거하기 위하여 탕세, 예비탈지, 본탈지, 제1,2차 수세, 중화, 제3,4차 수세, 피막, 제5,6차 수세, 순수세, 수절건조와 같은 공정을 순차적으로 진행하는 전처리 단계와, 폴리에스테르수지 또는 폴리에스테르수지와 에폭시수지가 혼합된 것으로, 색상은 회색 또는 검정색 의 혼합분체도료를 에어분사압력(Total Air Volume) 3-6N㎡/hr, 토출량(Power Output) 15~90%, 발생전류 10~50㎂로 코로나 정전도장으로 도포하여 건조로에서 230±10℃로 10분간 건조시키는 하도분체도장 단계와, 알루미늄 휠 표면의레벨링((Leveling)을 확보하기 위해 폴리에스테르 액체도료를 토출량 80~170kgf/㎠, 분사폭 2.5~5.0kgf/㎠, 미립화 2.0~3.5kgf/㎠,로 에어스프레이 방식으로 도포하여 셋팅룸에서 도장하는 중도도장단계와, 진공챔버내에 불활성기체인 아르곤(Ar)를 넣고 알루미늄, 티타늄, 크롬, 스테인레스중 어느 하나의 재질로 된 타겟에 음전압을 걸어 음극(Cathode)으로 부터 방출된 전자들이 아르곤 기체와 충돌 아르곤을 이온화되어 알루미늄휠 표면으로 부터 튀어나온 원자와 운동량 교환에 의해 알루미늄 휠 표면에 박막을 형성하는 스퍼터링단계와, 상기 스퍼터링 단계의 후 공정으로 아크릴분체 또는 아크릴 액체 도료를 사용하여 알루미늄 휠 표면에 투명 코팅하는 상도단계로 이루어진 것과,"The material preparation step is to shoot the shot ball on the surface of aluminum wheel to remove foreign substances on the surface of aluminum wheel and improve the adhesion of paint, and to remove dirt, oil, etc. from the surface of aluminum wheel. , Pre-treatment step of sequentially processing such as 1st, 2nd washing, neutralization, 3rd, 4th washing, coating, 5th, 6th washing, pure water, water drying, and polyester resin or polyester resin And Epoxy Resin are mixed. The color is gray or black mixed powder paint with 3-6Nm2 / hr of total air volume, 15 ~ 90% of discharge power and 10 ~ 50㎂ of generated current. The powder coating step is applied by corona electrostatic coating and dried at 230 ± 10 ℃ in the drying furnace for 10 minutes, and 80 ~ 170kgf / ㎠, spray width of polyester liquid paint is applied to secure the leveling of aluminum wheel surface. 2.5 ~ 5.0kgf / ㎠, fine The middle coating step is applied by air spray method at 2.0 ~ 3.5kgf / ㎠, and it is applied in the setting room, and the argon (Ar) which is inert gas is put in the vacuum chamber and made of any one of aluminum, titanium, chromium and stainless steel. A sputtering step of applying a negative voltage to the target and electrons emitted from the cathode collide with argon gas to form a thin film on the surface of the aluminum wheel by exchanging momentum with an atom protruding from the surface of the aluminum wheel; As a post-sputtering step, a top coating step of transparent coating on the surface of the aluminum wheel using acrylic powder or acrylic liquid paint,

상기 소재준비단계에서 알루미늄 휠 표면에 쇼트볼을 쏘아 쇼트후 분체도장을 향상시키기 위해 알루미늄 휠 표면을 정삭하는 정삭공정을 추가하여 된 것과,In the material preparation step to shoot a shot ball on the surface of the aluminum wheel to add a finishing process for finishing the surface of the aluminum wheel to improve the powder coating after the shot,

상기 전처리단계는,The pretreatment step,

알루미늄 휠 표면의 이물질, 유분 등의 오염물질을 제거하기 위하여 55±10℃의 온수를 분사압력 0.5kgf/㎠으로 한 탕세공정과, 알루미늄 휠 표면의 활성화와 적은 농도의 계면활성제 성분을 가지고 있는 관계로 본탈지 공정이 용이하게 진행 되도록 알루미늄 휠 표면에 55±10℃의 온수를 분사압력 1.0~2.0kgf/㎠으로 분사하여 오염물질을 제거하는 예비탈지공정과, 온수에 계면활성제를 5~10% 희석 혼합한 55±10℃의 액상 세척제를 분사압력 1.0~2.0kgf/㎠으로 알루미늄 휠 표면에 분사하여 알루미늄 휠 표면의 오염물질을 완전히 제거하는 본탈지공정과, 알루미늄 휠 표면의 계면활성제 성분을 완전히 제거키 위하여 분사압력 1.0~2.0kgf/㎠, 전도도 500㎲/㎝이하로 세척하는 제1 수세공정과, 알루미늄 휠 표면의 계면활성제 성분을 재차 완전히 제거키 위하여 분사압력 1.0~2.0kgf/㎠, 전도도 200㎲/㎝이하로 세척하는 제2 수세공정과, 분사압력 1.0~2.0kgf/㎠, 산도 18~36% 조건의 황산 성분의 에칭액을 사용하여 알루미늄 휠 표면을 에칭시킴으로 알루미늄 휠 표면의 산화 피막의 제거 및 후공정인 피막 공정의 안정성을 확보하기 위한 중화공정과, 분사압력 1.0~2.0kgf/㎠, 전도도 300㎲/㎝이하의 이온 교환수를 사용하여 에칭액이 세척하는 제3 수세공정과, 분사압력 1.0~2.0kgf/㎠, 전도도 50㎲/㎝이하의 이온 교환수를 사용하여 에칭액이 완전히 제거, 세척하는 제4 수세공정과, 분사압력 1.0~2.0kgf/㎠, 산도 14.5~10.5, pH 3.5~4.5의 논크롬액을 분사하여 알루미늄 휠 표면에 막을 형성하게 하여 내식성 및 부착성을 향상시키는 피막공정과, 분사압력 1.0~2.0kgf/㎠, 전도도 100㎲/㎝이하의 이온 교환수를 사용하여 잔존하는 피막액인 논크롬액을 세척하는 제5 수세공정과, 분사압력 1.0~2.0kgf/㎠, 전도도 40㎲/㎝이하의 이온 교환수를 사용하여 잔존하는 피막액인 논크롬액을 완전히 제거, 세척하는 제6 수세공정과, 분사압력 1.0~2.0kgf/㎠, 순도(비저항) 0.5㏁/㎝이상의 이온 교환수를 사용하여 알루미늄 휠 표면을 최종적으로 세척하는 순수세공정과, 온도 140±10℃하에서 알루미늄 휠에 잔존하는 수분을 완전히 제거하는 수절건조공정으로 이루어진 것과,In order to remove contaminants such as foreign substances and oil on the surface of aluminum wheels, the hot water process with a spray pressure of 0.5kgf / cm2 with 55 ± 10 ℃ hot water, activation of the aluminum wheel surface and a small concentration of surfactant Preliminary degreasing process to remove contaminants by spraying 55 ± 10 ℃ hot water at the spray pressure 1.0 ~ 2.0kgf / ㎠ on the surface of aluminum wheel to facilitate the main degreasing process, and 5 ~ 10% of surfactant on hot water Diluted and mixed 55 ± 10 ℃ liquid detergent is sprayed on aluminum wheel surface with spray pressure 1.0 ~ 2.0kgf / ㎠ to completely remove contaminants on aluminum wheel surface and surfactant component on aluminum wheel surface In order to remove the first washing process to clean the spray pressure 1.0 ~ 2.0kgf / ㎠, the conductivity below 500㎲ / ㎝, and to completely remove the surfactant component on the surface of the aluminum wheel spray pressure 1 The surface of the aluminum wheel was cleaned using a second water washing process for washing at .0 to 2.0 kgf / cm 2 and conductivity of 200 kW / cm or less, and an etching solution containing sulfuric acid with a spray pressure of 1.0 to 2.0 kgf / cm 2 and an acidity of 18 to 36%. The etching solution is neutralized to remove the oxide film on the surface of the aluminum wheel by etching and to ensure the stability of the film coating process, and ion exchange water having a spray pressure of 1.0 to 2.0 kgf / cm 2 and a conductivity of 300 kW / cm or less. The third washing step to wash, the fourth washing step to completely remove and wash the etching liquid by using ion exchanged water having a spray pressure of 1.0 to 2.0 kgf / cm 2 and a conductivity of 50 kW / cm or less, and a spray pressure of 1.0 to 2.0 kgf / Coating process to improve corrosion resistance and adhesion by spraying non-chromium solution with 2cm2, acidity 14.5 ~ 10.5, pH 3.5 ~ 4.5 and forming film on the surface of aluminum wheel, spray pressure 1.0 ~ 2.0kgf / ㎠, conductivity 100㎲ / Non-chromium liquid, the remaining coating liquid, is washed with ion-exchanged water of less than Is a fifth washing process, a sixth washing process for completely removing and washing the non-chromium liquid, which is a remaining coating liquid, by using ion exchange water having a spray pressure of 1.0 to 2.0 kgf / cm 2 and a conductivity of 40 kV / cm or less, and spraying Pure washing process to clean the surface of aluminum wheels with ion exchanged water with pressure 1.0 ~ 2.0kgf / ㎠ and purity (resistance) 0.5 비 / ㎝ or more and completely remove moisture remaining on aluminum wheels under the temperature of 140 ± 10 ℃. Consisting of a hand drying process to remove,

상도단계에서 아크릴 분체를 사용할 경우,When using acrylic powder in the top coat step,

상기 아크릴 분체를 공기압력 4.0~5.0kgf/㎠, 토출량(Power Output) 35~70%, 정전력 35~60kv, 발생전류(Output current) 30~60㎂로 코로나 정전도장으로 도포하여 건조로에서 건조온도 230±10℃로 건조시키는 것과,The acrylic powder is coated with a corona electrostatic coating at an air pressure of 4.0 to 5.0 kgf / ㎠, discharge output (Power output) 35 to 70%, constant power 35 to 60 kv, output current (Output current) 30 to 60 Hz, and the drying temperature in the drying furnace. Drying at 230 ± 10 ° C.,

상도단계에서 아크릴 액체 도료를 사용할 경우,When using acrylic liquid paint in the top coat phase,

토출량 150~300kgf/㎠, 분사폭 3.0~6.0kgf/㎠, 미립화 2.0~3.5kgf/㎠, 정전력 70±10kv로 정전도장 방식과 에어스프레이 방식을 혼합사용하여 도포한 후 건조로에서 190±10℃로 10분간 건조시키는 것"을 그 구성적 특징으로 함으로서 상기의 목적을 달성할 수 있다.Discharge amount 150 ~ 300kgf / ㎠, injection width 3.0 ~ 6.0kgf / ㎠, atomization 2.0 ~ 3.5kgf / ㎠, electrostatic painting method using air electrostatic coating method mixed with 70 ± 10kv and 190 ± 10 ℃ in drying furnace The above object can be attained by making it dry for 10 minutes. "

상기와 같이 구성된 본 발명인 열건 도료에 의한 스퍼터링 휠 제조방법은 알루미늄 휠의 표면을 연마치 아니하더라도 알루미늄휠의 표면 광택성이 우수하고 염 또는 염수에 대한 내식성 및 내산성, 내마모성이 우수하여 크롬휠에 대응하여 제조원가는 물론이고 친환경적인 부가가치를 높일 수 있는 것이다.Sputtering wheel manufacturing method according to the present invention hot-drying paint configured as described above is excellent in the surface glossiness of aluminum wheels and excellent corrosion resistance, salt and salt resistance to salt or salt water, even if the surface of the aluminum wheels to respond to the chrome wheels In addition to manufacturing costs, eco-friendly added value can be increased.

이상에서는 본 발명을 특정의 바람직한 실시예를 예를들어 설명하였으나, 본 발명은 상기한 실시예에 한정되지 아니하며 본 발명의 정신을 벗어나지 않는 범위내에서 당해 발명이 속하는 기술분야에서 통상의 지식을 가진자에 의해 다양한 변경과 수정이 가능할 것이다.In the above, the present invention has been described with reference to specific preferred embodiments, but the present invention is not limited to the above-described embodiments, and the present invention is not limited to the above-described embodiments. Various changes and modifications may be made by the user.

이하, 본 발명인 열건 도료에 의한 스퍼터링 휠 제조방법에 관하여 그 구체적인 구성 및 작용을 설명하고자 한다.
도 1은 본 발명인 열건 도료에 의한 스퍼터링 휠 제조방법의 제조 단계를 나타내는 단계도이며, 도 2는 본 발명인 열건 도료에 의한 스퍼터링 휠 제조방법에 있어서 전처리 단계의 구체 공정도이다.
Hereinafter, the specific configuration and operation of the sputtering wheel manufacturing method according to the present invention hot-dry paint.
1 is a step diagram showing a manufacturing step of the sputtering wheel manufacturing method by a hot-dry paint of the present invention, Figure 2 is a specific process diagram of the pre-treatment step in the method of manufacturing a sputtering wheel by a hot-drying paint of the present invention.

일반적인 공정인 알루미늄 잉곳(ingot)을 프레스로 주조 가공하여 휠 형상으로 가공한 다음,After casting the aluminum ingot which is a general process by pressing, it is processed into wheel shape,

본 발명의 구체적인 방법에 대하여 설명하면,Referring to the specific method of the present invention,

[소재준비단계][Material preparation stage]

상기와 같이 알루미늄 휠을 가공한 상태에서 상기 알루미늄 휠 표면에 쇼트볼을 쏘아 알루미늄휠 표면에 이물질을 제거하고 도장의 부착성을 향상시키는 단계로서,As a step to shoot a short ball on the surface of the aluminum wheel in the state of processing the aluminum wheel as described above to remove foreign substances on the surface of the aluminum wheel and to improve the adhesion of the coating,

본 단계는 가공된 알루미늄 휠 표면에 묻은 여러가지 이물질을 쇼트볼로 타격하여 제거하고 아울러 하기에서 이루어지는 도장의 부착성을 높이기 위한 것이다.This step is to remove the various foreign matters on the surface of the machined aluminum wheel by hitting the shot ball to increase the adhesion of the coating made in the following.

바람직하게는, 상기 알루미늄 휠 표면에 쇼트볼을 쏘아 쇼트후 분체도장을 향상시킨 다음에 표면이 넓은 디스크 타입의 알루미늄 휠에는 알루미늄 휠 표면을 정삭하는 정삭공정을 추가함으로서 더욱 도장의 부착성을 향상시킬 수 있다.Preferably, the shot ball is shot on the surface of the aluminum wheel to improve the powder coating after the shot, and then to the disk type aluminum wheel having a wide surface, a finishing process of finishing the surface of the aluminum wheel is added to further improve the adhesion of the coating. Can be.

[전처리 단계][Preprocessing Step]

본 단계는 다수개의 공정으로 이루어진 것으로서 상기와 같이 알루미늄 휠 표면에 부착된 이물질을 제거하였다고 하더라도 그 제거율은 미흡하고 따라서 더욱 완전히 이물질을 제거하기 위한 단계로서 이와 같은 단계를 거치는 이유는 하기에서 설명하는 하도분체도장이나 상도 등의 단계에서 더욱 도장의 부착성 및 알루미늄 휠 표면의 부드럽고 매끄러우며 광택성을 향상시키기 위한 것이다.This step is composed of a plurality of processes, even if the foreign matter adhering to the surface of the aluminum wheel as described above, even if the removal rate is insufficient and thus a step for removing the foreign matter more completely, the reason for going through this step is described below. It is to improve the adhesion of the coating and the smooth, smooth and glossiness of the aluminum wheel surface at the stage of powder coating or top coat.

본 단계의 공정을 크게 나누면,If you divide the process of this step largely,

탕세공정, 예비탈지공정, 본탈지공정, 제1,2차 수세공정, 중화공정, 제3,4차 수세공정, 피막공정, 제5,6차 수세공정, 순수세공정, 수절건조공정이 순차적으로 진행되는 것으로서,Hot water washing process, preliminary degreasing process, main degreasing process, 1st, 2nd washing process, neutralization process, 3rd, 4th washing process, coating process, 5th, 6th washing process, pure washing process, water drying process Proceeds to

구체적으로 살펴보면,Specifically,

첫번째 공정이 탕세공정으로서 탕세공정은 알루미늄 휠 표면의 이물질, 유분 등의 오염물질을 제거하기 위하여 55±10℃의 온수를 분사압력 0.5kgf/㎠으로 알루미늄 휠 표면에 분사하여 알루미늄 휠 표면에 부착된 이물질을 제거하는 공정이다.The first process is the hot water washing process, which removes contaminants such as foreign substances and oils from the aluminum wheel surface by spraying 55 ± 10 ℃ hot water onto the aluminum wheel surface with a spray pressure of 0.5kgf / ㎠. It is a process to remove foreign substances.

다음, 상기 탕세공정을 거친 알루미늄 휠은 예비탈지공정을 거치게 되며,Next, the aluminum wheel that has undergone the hot water washing step is subjected to a preliminary degreasing step,

상기 예비탈지공정은 상기 탕세공정을 거친 알루미늄 휠 표면의 활성화와 더 불어 적은 농도의 계면활성제 성분이 부착되어 있는 관계로 하기에서 설명하는 본탈지 공정이 용이하게 진행되도록 하기 위한 것으로서,The preliminary degreasing step is intended to facilitate the main degreasing process described below, since the surface of the aluminum wheel that has undergone the hot water washing step is activated, and a surfactant component having a small concentration is attached thereto.

알루미늄 휠 표면에 55±10℃의 온수를 분사압력 1.0~2.0kgf/㎠으로 분사하여 재차 오염물질을 제거하는 공정을 지칭하는 것이다.It refers to a process of removing contaminants by spraying hot water at 55 ± 10 ° C. on an aluminum wheel surface with a spray pressure of 1.0˜2.0 kgf / cm 2.

다음, 상기 예비탈지공정을 거친 알루미늄 휠은 본탈지공정을 거치게 되는데 상기 본탈지공정은 온수에 계면활성제를 5~10% 희석 혼합한 55±10℃의 액상 세척제를 분사압력 1.0~2.0kgf/㎠으로 알루미늄 휠 표면에 분사하여 알루미늄 휠 표면의 오염물질을 완전히 제거하는 공정을 말하는 것이다.Next, the aluminum wheel that has undergone the preliminary degreasing step is subjected to the main degreasing step, wherein the degreasing step is carried out with a liquid cleaning agent of 55 ± 10 ° C. in which 5 to 10% of a surfactant is diluted and mixed with hot water, and a spray pressure of 1.0 to 2.0 kgf / cm 2. This refers to a process of completely removing contaminants on the surface of the aluminum wheel by spraying on the surface of the aluminum wheel.

상기와 같이 본탈지공정까지 거치면 알루미늄 휠 표면에 묻어 있는 유분이나 기타 이물질은 완전히 제거되는 것이다.After the degreasing process as described above, oil or other foreign matter on the surface of the aluminum wheel is completely removed.

다음, 상기 본탈지공정을 거치는 과정에서 알루미늄 휠 표면에 부착된 계면활성제 성분을 완전히 제거키 위한 것으로,Next, to completely remove the surfactant component attached to the surface of the aluminum wheel during the main degreasing process,

그 조건은 분사압력 1.0~2.0kgf/㎠, 전도도 500㎲/㎝이하로 세척하는 제1 수세공정을 거치게 되는 것이다.The condition is to undergo a first washing step of washing at a spray pressure of 1.0 ~ 2.0kgf / ㎠, 500 ㎲ / ㎝ or less.

다음, 상기 제1 수세공정을 거치더라도 알루미늄 휠 표면에 부착된 계면활성제가 완전히 제거는 되지 아니한 상태이므로 이와 같이 알루미늄 휠 표면의 계면활성제 성분을 완전히 제거키 위하여 제2 수세공정을 거치게 되는데,Next, since the surfactant attached to the surface of the aluminum wheel is not completely removed even after the first washing process, the second washing process is performed to completely remove the surfactant component from the surface of the aluminum wheel.

상기 제2 수세공정의 조건은 분사압력 1.0~2.0kgf/㎠, 전도도 200㎲/㎝이하로 세척하는 것이다.The condition of the second washing step is to wash at a spray pressure of 1.0 ~ 2.0kgf / ㎠, the conductivity of 200 ㎲ / ㎝ or less.

다음, 상기와 같이 제2 수세공정을 거친 알루미늄 휠 표면에 분사압력 1.0~2.0kgf/㎠, 산도 18~36% 조건의 황산 성분의 에칭액을 사용하여 알루미늄 휠 표면을 에칭시킴으로 알루미늄 휠 표면의 산화 피막의 제거 및 후공정인 피막 공정의 안정성을 확보하기 위하여 중화공정을 거치게 된다.Next, an oxide film on the surface of the aluminum wheel is etched by etching the surface of the aluminum wheel using an etching solution of a sulfuric acid component having a spray pressure of 1.0 to 2.0 kgf / cm2 and an acidity of 18 to 36% on the surface of the aluminum wheel which has undergone the second washing process as described above. The neutralization process is performed to remove the and to ensure the stability of the coating process.

다음, 상기 중화공정에서 알루미늄 휠 표면에 남아 있는 에칭액을 세척하기 위하여 제3 수세공정을 거치게 되며,Next, a third washing process is performed to wash the etching liquid remaining on the surface of the aluminum wheel in the neutralization process.

상기 제3 수세공정의 조건은 분사압력 1.0~2.0kgf/㎠, 전도도 300㎲/㎝이하의 이온 교환수를 사용하여 에칭액이 세척하는 공정이다.The third washing step is a step of washing the etching liquid using ion exchange water having a spray pressure of 1.0 to 2.0 kgf / cm 2 and a conductivity of 300 kW / cm or less.

다음, 상기 제3 수세공정을 거친 후 더욱 완벽히 에칭액을 제거하기 위하여 제4 수세공정을 거치도록 하며 상기 제4 수세공정의 조건은 분사압력 1.0~2.0kgf/㎠, 전도도 50㎲/㎝이하의 이온 교환수를 사용하여 에칭액이 완전히 제거, 세척하는 공정이 상기 제4 수세공정이다.Next, after the third washing step to go through the fourth washing step to more completely remove the etching solution, the conditions of the fourth washing step is ion pressure of 1.0 ~ 2.0kgf / ㎠, 50 ㎲ / ㎝ or less of the injection pressure The fourth washing step is a step of completely removing and washing the etchant using the exchange water.

다음, 상기와 같이 알루미늄 휠 표면에 에칭을 시키고 에칭액을 완전히 제거한 상태에서 Next, as described above, the surface of the aluminum wheel is etched and the etching solution is completely removed.

분사압력 1.0~2.0kgf/㎠, 산도 14.5~10.5, pH 3.5~4.5의 논크롬액을 분사하 여 알루미늄 휠 표면에 막을 형성하게 하여 내식성 및 부착성을 향상시키는 공정이 피막공정으로 상기 논크롬액을 사용하는 이유는 도장의 접착성을 향상시키기 위한 것이다.Non-chromium solution is a coating process to improve the corrosion resistance and adhesion by spraying a non-chromium solution with a spray pressure of 1.0 to 2.0 kgf / cm 2, an acidity of 14.5 to 10.5, and a pH of 3.5 to 4.5 to form a film on the surface of an aluminum wheel. The reason for using is to improve the adhesion of the coating.

다음, 상기와 같은 피막공정을 완료한 후에 상기 알루미늄 휠 표면에 잔존하는 피막액 즉, 논크롬액을 제거하기 위하여,Next, in order to remove the coating liquid remaining on the surface of the aluminum wheel, that is, non-chromium liquid after completing the coating process as described above,

분사압력 1.0~2.0kgf/㎠, 전도도 100㎲/㎝이하의 이온 교환수를 사용하여 잔존하는 피막액인 논크롬액을 세척하는 공정이 제5 수세공정이며,The fifth washing process is a process of washing the non-chromium liquid, which is the remaining coating liquid, using ion exchange water having a spray pressure of 1.0 to 2.0 kgf / cm 2 and a conductivity of 100 kV / cm or less.

다음, 상기 논크롬액의 완전히 제거를 위하여,Next, in order to completely remove the non-chromium liquid,

분사압력 1.0~2.0kgf/㎠, 전도도 40㎲/㎝이하의 이온 교환수를 사용하여 잔존하는 피막액인 논크롬액을 완전히 제거, 세척하는 제6 수세공정을 거치게 되는 것이다.The sixth washing process is performed to completely remove and wash the non-chromium liquid, which is the remaining coating liquid, using ion exchange water having a spray pressure of 1.0 to 2.0 kgf / cm 2 and a conductivity of 40 kW / cm or less.

다음, 상기와 같이 제6 수세공정을 거친 알루미늄 휠의 표면을 최종적으로 세척하기 위한 공정으로서 순수세공정을 거치게 되는데,Next, as a process for finally cleaning the surface of the aluminum wheel after the sixth washing process as described above, the pure washing process,

이에 대한 조건은 분사압력 1.0~2.0kgf/㎠, 순도(비저항) 0.5㏁/㎝이상의 이온 교환수를 사용하여 알루미늄 휠 표면을 최종적으로 세척하는 공정이 순수세공정이다.The condition for this is a pure washing process in which the surface of the aluminum wheel is finally cleaned using ion exchange water having a spray pressure of 1.0 to 2.0 kgf / cm 2 and a purity (specific resistance) of 0.5 kPa / cm or more.

다음, 상기와 같이 알루미늄 휠의 세척을 완료한 후에는 알루미늄 휠 표면에 남아있는 수분을 제거하여야 하며 이와 같은 역할을 수행키 위하여, Next, after completing the cleaning of the aluminum wheel as described above to remove the moisture remaining on the surface of the aluminum wheel, in order to perform this role,

온도 140±10℃하에서 알루미늄 휠에 잔존하는 수분을 완전히 제거하는 수절건조공정을 거침으로서 본 단계인 전처리 단계가 완료되는 것이다.The pretreatment step, which is this step, is completed by undergoing a water drying process to completely remove water remaining on the aluminum wheel at a temperature of 140 ± 10 ° C.

[하도분체도장 단계][Coated powder coating step]

본 단계는 상기 다수개의 공정으로 이루어진 전처리 단계를 거친 다음에 이루어지는 단계로서 알루미늄 휠 표면에 폴리에스테르수지 또는 폴리에스테르수지와 에폭시수지가 혼합된 것으로, 색상은 회색 또는 검정색의 혼합분체도료를 에어분사압력(Total Air Volume) 3-6N㎡/hr, 토출량(Power Output) 15~90%, 발생전류 10~50㎂로 코로나 정전도장으로 도포한 다음, 건조로에서 230±10℃로 10분간 건조시키는 단계를 말하는 것이다.This step is performed after the pre-treatment step consisting of a plurality of processes, the polyester resin or the polyester resin and the epoxy resin is mixed on the surface of the aluminum wheel, the color is gray or black mixed powder coating air spray pressure (Total Air Volume) 3-6N㎡ / hr, Power Output 15 ~ 90%, Generating Current 10 ~ 50㎂ and applied with corona electrostatic coating, and then drying at 230 ± 10 ℃ in drying furnace for 10 minutes. I speak.

[중도도장단계][Middle painting stage]

본 단계는 하도분체도장 단계를 거쳐 상기 혼합분체도료가 알루미늄 휠 표면에 도장된 후 건조된 상태에서,In this step, the mixed powder paint is coated on the surface of the aluminum wheel through a powder coating step and then dried.

알루미늄 휠 표면의 레벨링(Leveling) 개선 즉, 매끄럽고, 부드럽우며 광택성을 발휘하기 위한 것으로서,To improve the leveling of the aluminum wheel surface, that is, to achieve smooth, smooth and glossy,

본 단계에 사용되는 액체도료는 연질의 폴리에스테르계 액체도료를 토출량 80~170kgf/㎠, 분사폭 2.5~5.0kgf/㎠, 미립화 2.0~3.5kgf/㎠,로 에어스프레이 방식 으로 도포하여 셋팅룸에서 도장하는 것을 지칭하는 것이다.The liquid paint used in this step is a soft polyester-based liquid paint with a spraying amount of 80 ~ 170kgf / ㎠, spraying width 2.5 ~ 5.0kgf / ㎠, atomization 2.0 ~ 3.5kgf / ㎠, by air spray method in the setting room It refers to painting.

[스퍼터링 단계][Sputtering Step]

본 단계는 알루미늄 휠 표면에 박막을 형성키 위한 것으로서, 구체적으로는 우선 본 단계의 스퍼터링 단계의 전처리 공정으로서 진공챔버내에 불활성기체인 아르곤(Ar)를 넣고 알루미늄, 티타늄, 크롬, 스테인레스중 어느 하나의 재질로 된 타겟에 음전압을 걸어 음극(Cathode)으로 부터 방출된 전자들이 아르곤 기체와 충돌 아르곤을 이온화되어 알루미늄휠 표면으로 부터 튀어나온 원자와 운동량 교환에 의해 알루미늄 휠 표면에 박막을 형성하는 일련의 과정을 스퍼터링 단계라고 한다.This step is to form a thin film on the surface of the aluminum wheel. Specifically, as the pretreatment step of the sputtering step of this step, an argon (Ar), which is an inert gas, is placed in a vacuum chamber, and any one of aluminum, titanium, chromium and stainless steel is used. A series of electrons emitted from the cathode by applying a negative voltage to a material target ionizes argon gas and collides argon to form a thin film on the aluminum wheel surface by exchanging momentum with atoms protruding from the aluminum wheel surface. The process is called the sputtering step.

[상도단계][Top Level]

상기와 같이 스퍼터링 단계를 거친 후, 알루미늄 휠은 최종적으로 상도단계를 거치게 됨으로서 모든 단계가 종료되는 것으로 상기 상도단계는, After the sputtering step as described above, the aluminum wheel is finally subjected to the top coat step, so that all the steps are completed.

아크릴분체 또는 아크릴 액체 도료를 사용하여 알루미늄 휠 표면에 투명 코팅하는 단계를 말하며,Transparent coating on the surface of aluminum wheels using acrylic powder or acrylic liquid paint,

구체적으로,Specifically,

본 상도단계에서 아크릴 분체를 사용할 경우의 조건은,In the case of using the acrylic powder in this top coat step,

상기 아크릴 분체를 공기압력 4.0~5.0kgf/㎠, 토출량(Power Output) 35~70%, 정전력 35~60kv, 발생전류(Output current) 30~60㎂로 코로나 정전도장으로 도포하여 건조로에서 건조온도 230±10℃로 건조시키는 것으로 종료되며,The acrylic powder is coated with a corona electrostatic coating at an air pressure of 4.0 to 5.0 kgf / ㎠, discharge output (Power output) 35 to 70%, constant power 35 to 60 kv, output current (Output current) 30 to 60 Hz, and the drying temperature in the drying furnace. Ends with drying at 230 ± 10 ° C.,

삭제delete

본 상도단계에서 아크릴 액체 도료를 사용할 경우의 조건은,In the case of using the acrylic liquid paint in this top coat step,

토출량 150~300kgf/㎠, 분사폭 3.0~6.0kgf/㎠, 미립화 2.0~3.5kgf/㎠, 정전력 70±10kv로 정전도장 방식과 에어스프레이 방식을 혼합사용하여 도포한 후 건조로에서 190±10℃로 10분간 건조시키는 것으로 모든 단계 및 공정이 완료되어 완제품인 알루미늄 휠이 제조되는 것이다.Discharge amount 150 ~ 300kgf / ㎠, injection width 3.0 ~ 6.0kgf / ㎠, atomization 2.0 ~ 3.5kgf / ㎠, electrostatic painting method using air electrostatic coating method mixed with 70 ± 10kv and 190 ± 10 ℃ in drying furnace Drying for 10 minutes to complete all steps and processes to produce a finished aluminum wheel.

상기와 같은 다단의 단계 및 공정을 거친 알루미늄 휠은 그 표면 광택성이 우수하고 염 또는 염수에 대한 내식성 및 내산성, 내마모성이 우수하여 크롬휠에 대응하여 제조원가는 물론이고 친환경적인 부가가치를 높일 수 있다The aluminum wheel that has undergone the above-described multi-stage steps and processes has excellent surface gloss, and has excellent corrosion resistance, salt resistance, and acid resistance and abrasion resistance to chrome wheels, thereby increasing manufacturing costs and eco-friendly added value.

도 1은 본 발명인 열건 도료에 의한 스퍼터링 휠 제조방법의 제조 단계를 나타내는 단계도이며,1 is a step diagram showing the manufacturing steps of the method for producing a sputtering wheel by the inventors hot-rolled paint,

도 2는 본 발명인 열건 도료에 의한 스퍼터링 휠 제조방법에 있어서 전처리 단계의 구체 공정도이다.Figure 2 is a specific process diagram of the pretreatment step in the method for producing a sputtering wheel by the hot-dry paint of the present invention.

Claims (5)

알루미늄 휠 표면에 쇼트볼을 쏘아 알루미늄휠 표면에 이물질을 제거하고 도장의 부착성을 향상시키는 소재준비단계와, A material preparation step of shooting a short ball on the surface of the aluminum wheel to remove foreign substances on the surface of the aluminum wheel and improving the adhesion of the coating; 알루미늄 휠 표면의 이물질, 유분 등의 오물을 제거하기 위하여 탕세, 예비탈지, 본탈지, 제1,2차 수세, 중화, 제3,4차 수세, 피막, 제5,6차 수세, 순수세, 수절건조와 같은 공정을 순차적으로 진행하는 전처리 단계와, Hot water, pre-degreasing, main stripping, first and second washing, neutralization, third and fourth washing, coating, fifth and sixth washing, pure water, A pretreatment step of sequentially carrying out a process such as water drying, 폴리에스테르수지 또는 폴리에스테르수지와 에폭시수지가 혼합된 것으로, 색상은 회색 또는 검정색 의 혼합분체도료를 에어분사압력(Total Air Volume) 3-6N㎡/hr, 토출량(Power Output) 15~90%, 발생전류 10~50㎂로 코로나 정전도장으로 도포하여 건조로에서 230±10℃로 10분간 건조시키는 하도분체도장 단계와, It is a mixture of polyester resin or polyester resin with epoxy resin. The color of gray or black mixed powder paint is 3-6Nm2 / hr of total air volume, 15 ~ 90% of power output. Undercoat powder coating step of applying 10 ~ 50 mA of generated current with corona electrostatic coating and drying it at 230 ± 10 ℃ for 10 minutes in a drying furnace; 알루미늄 휠 표면의 레벨링((Leveling)을 확보하기 위해 폴리에스테르 액체도료를 토출량 80~170kgf/㎠, 분사폭 2.5~5.0kgf/㎠, 미립화 2.0~3.5kgf/㎠,로 에어스프레이 방식으로 도포하여 셋팅룸에서 도장하는 중도도장단계와, In order to secure the leveling of the aluminum wheel surface, the polyester liquid paint is applied by air spraying with a discharge amount of 80 to 170 kgf / ㎠, a spraying width of 2.5 to 5.0 kgf / ㎠, and an atomization of 2.0 to 3.5 kgf / ㎠. The middle painting stage to paint in the room, 진공챔버내에 불활성기체인 아르곤(Ar)를 넣고 알루미늄, 티타늄, 크롬, 스테인레스중 어느 하나의 재질로 된 타겟에 음전압을 걸어 음극(Cathode)으로 부터 방출된 전자들이 아르곤 기체와 충돌 아르곤을 이온화되어 알루미늄휠 표면으로 부터 튀어나온 원자와 운동량 교환에 의해 알루미늄 휠 표면에 박막을 형성하는 스퍼터링단계와, After argon (Ar), which is an inert gas, is put in a vacuum chamber, a negative voltage is applied to a target made of any one of aluminum, titanium, chromium and stainless steel, and electrons emitted from the cathode are ionized with argon gas and colliding argon. A sputtering step of forming a thin film on the surface of the aluminum wheel by exchanging momentum with the atoms protruding from the surface of the aluminum wheel, 상기 스퍼터링 단계의 후 공정으로 아크릴분체 또는 아크릴 액체 도료를 사용하여 알루미늄 휠 표면에 투명 코팅하는 상도단계로 이루어진 것을 특징으로 하는 열건 도료에 의한 스퍼터링 휠 제조방법.The sputtering wheel manufacturing method according to the heat-drying paint, characterized in that consisting of a top coat step of transparent coating on the surface of the aluminum wheel using an acrylic powder or an acrylic liquid paint as a post-sputtering step. 제 1 항에 있어서,The method of claim 1, 상기 소재준비단계에서 알루미늄 휠 표면에 쇼트볼을 쏘아 쇼트후 분체도장을 향상시키기 위해 알루미늄 휠 표면을 정삭하는 정삭공정을 추가하여 된 것을 특징으로 하는 열건 도료에 의한 스퍼터링 휠 제조방법.The method of manufacturing a sputtering wheel by heat-drying paint, characterized in that the addition of a finishing process for finishing the aluminum wheel surface in order to improve the powder coating after the shot by shooting the shot ball on the surface of the aluminum wheel in the material preparation step. 제 1 항에 있어서,The method of claim 1, 상기 전처리단계는,The pretreatment step, 알루미늄 휠 표면의 이물질, 유분 등의 오염물질을 제거하기 위하여 55±10℃의 온수를 분사압력 0.5kgf/㎠으로 한 탕세공정과,In order to remove contaminants such as foreign substances and oil on the surface of aluminum wheels, a hot water washing process using a hot water of 55 ± 10 ° C. with a spray pressure of 0.5kgf / ㎠, 알루미늄 휠 표면의 활성화와 적은 농도의 계면활성제 성분을 가지고 있는 관계로 본탈지 공정이 용이하게 진행되도록 알루미늄 휠 표면에 55±10℃의 온수를 분사압력 1.0~2.0kgf/㎠으로 분사하여 오염물질을 제거하는 예비탈지공정과,Because of the activation of the aluminum wheel surface and the small amount of surfactant, the degreasing process can be easily carried out by spraying 55 ± 10 ℃ hot water at the spray pressure 1.0 ~ 2.0kgf / ㎠ on the aluminum wheel surface. Preliminary degreasing process to remove, 온수에 계면활성제를 5~10% 희석 혼합한 55±10℃의 액상 세척제를 분사압력 1.0~2.0kgf/㎠으로 알루미늄 휠 표면에 분사하여 알루미늄 휠 표면의 오염물질을 완전히 제거하는 본탈지공정과,Main degreasing process to completely remove contaminants on aluminum wheel surface by spraying 55 ± 10 ° C liquid detergent at 55 ± 10 ° C with hot water diluted to 10 ~ 10kgf / ㎠ 알루미늄 휠 표면의 계면활성제 성분을 완전히 제거키 위하여 분사압력 1.0~2.0kgf/㎠, 전도도 500㎲/㎝이하로 세척하는 제1 수세공정과,In order to completely remove the surfactant component on the surface of the aluminum wheel, the first washing process for washing at a spray pressure of 1.0 ~ 2.0kgf / ㎠, below 500 ㎲ / ㎝, 알루미늄 휠 표면의 계면활성제 성분을 재차 완전히 제거키 위하여 분사압력 1.0~2.0kgf/㎠, 전도도 200㎲/㎝이하로 세척하는 제2 수세공정과, In order to completely remove the surfactant component on the surface of the aluminum wheel again, the second washing process to wash at a spray pressure of 1.0 ~ 2.0kgf / ㎠, conductivity below 200㎲ / ㎝, 분사압력 1.0~2.0kgf/㎠, 산도 18~36% 조건의 황산 성분의 에칭액을 사용하여 알루미늄 휠 표면을 에칭시킴으로 알루미늄 휠 표면의 산화 피막의 제거 및 후공정인 피막 공정의 안정성을 확보하기 위한 중화공정과,Etching the aluminum wheel surface using sulfuric acid etching solution with spray pressure 1.0 ~ 2.0kgf / ㎠ and acidity 18 ~ 36%, neutralization to remove oxide film on aluminum wheel surface and to secure stability Fair, 분사압력 1.0~2.0kgf/㎠, 전도도 300㎲/㎝이하의 이온 교환수를 사용하여 에칭액이 세척하는 제3 수세공정과,A third washing step of washing the etching liquid using ion exchange water having a spray pressure of 1.0 to 2.0 kgf / cm 2 and a conductivity of 300 kW / cm or less, 분사압력 1.0~2.0kgf/㎠, 전도도 50㎲/㎝이하의 이온 교환수를 사용하여 에칭액이 완전히 제거, 세척하는 제4 수세공정과,A fourth washing step of completely removing and washing the etching liquid using ion exchange water having a spray pressure of 1.0 to 2.0 kgf / cm 2 and a conductivity of 50 kV / cm or less; 분사압력 1.0~2.0kgf/㎠, 산도 14.5~10.5, pH 3.5~4.5의 논크롬액을 분사하여 알루미늄 휠 표면에 막을 형성하게 하여 내식성 및 부착성을 향상시키는 피막공정과,Coating process to improve the corrosion resistance and adhesion by spraying non-chromium liquid with spray pressure 1.0 ~ 2.0kgf / ㎠, acidity 14.5 ~ 10.5, pH 3.5 ~ 4.5 to form a film on the surface of aluminum wheel, 분사압력 1.0~2.0kgf/㎠, 전도도 100㎲/㎝이하의 이온 교환수를 사용하여 잔존하는 피막액인 논크롬액을 세척하는 제5 수세공정과,A fifth washing step of washing the non-chromium liquid, the remaining coating liquid, using ion-exchanged water having an injection pressure of 1.0 to 2.0 kgf / cm 2 and a conductivity of 100 kV / cm or less; 분사압력 1.0~2.0kgf/㎠, 전도도 40㎲/㎝이하의 이온 교환수를 사용하여 잔존하는 피막액인 논크롬액을 완전히 제거, 세척하는 제6 수세공정과,A sixth washing step of completely removing and washing the non-chromium liquid, which is a remaining coating liquid, by using ion exchange water having a spray pressure of 1.0 to 2.0 kgf / cm 2 and a conductivity of 40 kW / cm or less; 분사압력 1.0~2.0kgf/㎠, 순도(비저항) 0.5㏁/㎝이상의 이온 교환수를 사용하여 알루미늄 휠 표면을 최종적으로 세척하는 순수세공정과,Pure washing process to finally clean the surface of aluminum wheels using ion exchanged water with injection pressure 1.0 ~ 2.0kgf / ㎠, purity (resistance) 0.5 저항 / ㎝ or more, 온도 140±10℃하에서 알루미늄 휠에 잔존하는 수분을 완전히 제거하는 수절건조공정으로 이루어진 것을 특징으로 하는 열건 도료에 의한 스퍼터링 휠 제조방법.A method for producing a sputtering wheel by hot-drying paint, characterized by consisting of a water-drying drying process for completely removing water remaining on the aluminum wheel at a temperature of 140 ± 10 ° C. 제 1 항에 있어서,The method of claim 1, 상도단계에서 아크릴 분체를 사용할 경우,When using acrylic powder in the top coat step, 상기 아크릴 분체를 공기압력 4.0~5.0kgf/㎠, 토출량(Power Output) 35~70%, 정전력 35~60kv, 발생전류(Output current) 30~60㎂로 코로나 정전도장으로 도포하여 건조로에서 건조온도 230±10℃로 건조시키는 것을 특징으로 하는 열건 도료에 의한 스퍼터링 휠 제조방법.The acrylic powder is coated with a corona electrostatic coating at an air pressure of 4.0 to 5.0 kgf / ㎠, discharge output (Power output) 35 to 70%, constant power 35 to 60 kv, output current (Output current) 30 to 60 Hz, and the drying temperature in the drying furnace. A method for producing a sputtering wheel by hot-drying paint, characterized in that drying at 230 ± 10 ℃. 제 1 항에 있어서,The method of claim 1, 상도단계에서 아크릴 액체 도료를 사용할 경우,When using acrylic liquid paint in the top coat phase, 토출량 150~300kgf/㎠, 분사폭 3.0~6.0kgf/㎠, 미립화 2.0~3.5kgf/㎠, 정전력 70±10kv로 정전도장 방식과 에어스프레이 방식을 혼합사용하여 도포한 후 건조로에서 190±10℃로 10분간 건조시키는 것을 특징으로 하는 열건 도료에 의한 스퍼터링 휠 제조방법.Discharge amount 150 ~ 300kgf / ㎠, injection width 3.0 ~ 6.0kgf / ㎠, atomization 2.0 ~ 3.5kgf / ㎠, electrostatic painting method using air electrostatic coating method mixed with 70 ± 10kv and 190 ± 10 ℃ in drying furnace Method for producing a sputtering wheel by heat-drying paint, characterized in that the drying for 10 minutes.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04131232A (en) * 1990-09-22 1992-05-01 Totsuka Sogyo:Kk Metallic surface treatment method
JPH10130822A (en) 1996-10-28 1998-05-19 Totsuka Sogyo:Kk Treatment of metal surface
KR100707513B1 (en) 2006-04-03 2007-04-13 김철진 Surface treatment for alloy wheel and the alloy wheel
KR20070044420A (en) * 2007-04-09 2007-04-27 주식회사 아텍 The alloy wheel dry process gilding method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04131232A (en) * 1990-09-22 1992-05-01 Totsuka Sogyo:Kk Metallic surface treatment method
JPH10130822A (en) 1996-10-28 1998-05-19 Totsuka Sogyo:Kk Treatment of metal surface
KR100707513B1 (en) 2006-04-03 2007-04-13 김철진 Surface treatment for alloy wheel and the alloy wheel
KR20070044420A (en) * 2007-04-09 2007-04-27 주식회사 아텍 The alloy wheel dry process gilding method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20170032747A (en) 2015-09-15 2017-03-23 금강페인트공업(주) Paint composition for dry plating of automobile aluminum wheel

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