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KR100647141B1 - non-fire panel with expansive stone - Google Patents

non-fire panel with expansive stone Download PDF

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Publication number
KR100647141B1
KR100647141B1 KR1020040008983A KR20040008983A KR100647141B1 KR 100647141 B1 KR100647141 B1 KR 100647141B1 KR 1020040008983 A KR1020040008983 A KR 1020040008983A KR 20040008983 A KR20040008983 A KR 20040008983A KR 100647141 B1 KR100647141 B1 KR 100647141B1
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vermiculite
weight
pearlite
particle size
pearl
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KR1020040008983A
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Korean (ko)
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KR20050080832A (en
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김동수
이길우
이종수
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김동수
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    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04MTELEPHONIC COMMUNICATION
    • H04M1/00Substation equipment, e.g. for use by subscribers
    • H04M1/02Constructional features of telephone sets
    • H04M1/0202Portable telephone sets, e.g. cordless phones, mobile phones or bar type handsets
    • H04M1/0206Portable telephones comprising a plurality of mechanically joined movable body parts, e.g. hinged housings
    • H04M1/0208Portable telephones comprising a plurality of mechanically joined movable body parts, e.g. hinged housings characterized by the relative motions of the body parts
    • H04M1/0214Foldable telephones, i.e. with body parts pivoting to an open position around an axis parallel to the plane they define in closed position
    • H04M1/0216Foldable in one direction, i.e. using a one degree of freedom hinge

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  • Engineering & Computer Science (AREA)
  • Signal Processing (AREA)
  • Building Environments (AREA)
  • Special Wing (AREA)

Abstract

본 발명의 방화문판재는, 버미큘라이트(질석)와 펄라이트(진주암)를 분쇄가공 후, 상기 분쇄가공된 버미큘라이트 및 펄라이트를 1~5 mm 크기로 입도 선별한 다음, 입도 선별된 상기 버미큘라이트와 펄라이트를 800 ~ 1200℃로 급속히 가열하여 10 ~ 15배로 박리팽창시킨 후, 상기 팽창된 버미큘라이트 30 ~ 42 중량%와 펄라이트 40 ~ 50 중량%에, 미분 황토 10 ~ 18 중량% 와, 규산 나트륨 0.92 ~ 1.3 중량%와, 실리카 겔 0.59 ~ 0.97 중량%와, Mg-Al 설폰산염 나트륨 바인다 0.17 ~ 0.30 중량% 를 배합한 다음, 상기 배합된 원료를 두 개의 강판사이에 적층하여 가열 가압하여 성형하여 제조되므로, 보온 단열효과 및 흡 차음효과가 우수하고 경량이며 불연성이고 인체의 건강을 증진하며 환경오염을 방지하는 효과가 있다.Fireproof door plate of the present invention, after pulverizing the vermiculite (vermiculite) and pearlite (pearl pearl), after the particle size of the pulverized and vermiculite and pearlite pulverized 1 ~ 5 mm size, the particle size screened vermiculite and pearlite 800 ~ After rapid heating to 10 to 15 times by peeling and expanding at 1200 ℃, 30 to 42% by weight of the expanded vermiculite and 40 to 50% by weight of pearlite, 10 to 18% by weight of finely divided ocher, 0.92 to 1.3% by weight of sodium silicate and , 0.59 ~ 0.97% by weight of silica gel, 0.17 ~ 0.30% by weight of Mg-Al sulfonate sodium bicarbonate, and then prepared by laminating the blended raw material between the two steel sheets and molded by heating and pressing, heat insulation effect And the sound absorption and sound effect is excellent, light weight, non-combustible, has the effect of promoting the health of the human body and preventing environmental pollution.

팽창성광물, 질석, 황토, 결합재Expandable minerals, vermiculite, loess, binder

Description

팽창성 광물을 이용한 방화문 판재{non-fire panel with expansive stone}Non-fire panel with expansive stone}

본 발명은 팽창성 광물을 이용한 방화문 판재에 관한 것이다.The present invention relates to a fire door plate using an expandable mineral.

건축물의 내부재로 사용되는 소재들은 대부분 가연성 재료로서, 화재 발생시에는 상기의 건물 내부재들이 연소 매개체가 되어, 독성가스를 방출하고 인접시설로 화재를 급속히 전파시키게 된다. 따라서 최근에는 일반건물 등에도 내부를 방화성 소재로 많이 시공하고 있다. Most of the materials used as the interior materials of buildings are combustible materials. In the event of a fire, the building interior materials become combustion media, releasing toxic gas and rapidly spreading the fire to adjacent facilities. Therefore, in recent years, a lot of interiors are constructed of fire-resistant materials in general buildings.

상기 방화성 소재에 가해지는 가혹한 환경의 특성상 그 재질은 극히 제한적일 수 밖에 없으며, 현재는 1000℃ 이상의 온도에서도 견딜 수 있는 세라믹, 철판등과 발포수지 등이 주로 사용되고 있다. 하지만 상기의 재료 중 세라믹 소재를 제외하고는 내열성이 약하여 고온에 일정시간 이상 노출시 방화문이 용융되는 현상이 발생하며, 세라믹 소재는 내열성은 좋으나 강도가 약하고 성형성이 떨어진다.Due to the characteristics of the harsh environment applied to the fire-proof material, the material is extremely limited, and at present, ceramics, iron plates, and foamed resins, etc., which can withstand temperatures of 1000 ° C. or higher are mainly used. However, except for the ceramic material among the above materials, the heat resistance is weak, so that the fire door melts when exposed to high temperature for a predetermined time or more, and the ceramic material has good heat resistance, but the strength is weak and the moldability is poor.

종래 방화문 구조는, 주로 방화용 판재 사이에 하니컴 스페이서를 두고 금속재로 판재를 연결한 형상을 하고 있다. 하지만 이러한 구조는 고열을 받으면 판재가 심하게 뒤틀리며 틈이 생겨 화기와 고열이 차단되지 못하고 외부로 누출된다.Conventionally, the fire door structure has a shape in which a honeycomb spacer is interposed between fireproof plate materials and a plate is connected with a metal material. However, such a structure, when subjected to high heat, the board is severely distorted and a gap is formed, and the fire and high heat are not blocked, and leaks to the outside.

이러한 종래 방화문의 문제점을 해결하기 위해 팽창성 광물을 이용한 방화문 판재가 개시되어 있으나, 최근에는 건강에 대한 관심이 높아지게 되어 종래 방화문 판재가 실내거주자의 건강에 미치는 영향을 충분히 고려하지 않았으므로 평시에 인체의 건강을 증진시키는 방화문 판재에 대한 요구가 있어 왔다.In order to solve the problems of the conventional fire door has been disclosed fireproof door plate using an expandable mineral, but in recent years the interest in health has been increased and the conventional fire door plate has not sufficiently considered the effect on the health of indoor residents, There has been a need for fire door boards that promote health.

본 발명은 이러한 요구에 부응하기 위해 이루어진 것으로서, 본 발명의 목적은 보온 단열효과 및 흡 차음효과가 우수하고 경량이며 불연성이고 인체의 건강을 증진하며 환경오염을 방지하는 팽창성 광물을 이용한 방화문 판재를 제공하는 데 있다.The present invention has been made to meet these demands, and an object of the present invention is to provide a fire door door using an expandable mineral that is excellent in thermal insulation and sound absorption and sound insulation, lightweight, non-combustible, improve the health of the human body and prevent environmental pollution There is.

이하 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

본 발명에 의해 제조되는 팽창성 광물을 이용한 방화문 판재는 다음과 같이 제조한다.Fireproof door plate using the expandable mineral produced by the present invention is prepared as follows.

먼저, 버미큘라이트(질석)와 펄라이트(진주암)를 분쇄가공한다.First, vermiculite (pearl vermiculite) and pearlite (pearl stone) are pulverized.

상기 분쇄가공된 버미큘라이트 및 펄라이트를 1~5 mm 크기로 입도 선별한 다음, 입도 선별된 상기 버미큘라이트와 펄라이트를 800 ~ 1200℃로 급속히 가열하여 10 ~ 15배로 박리팽창시킨다. 상기 박리팽창은 공지의 팽창로(expansion furnace)로 된 팽창장치를 사용한다.The pulverized vermiculite and pearlite are screened to a particle size of 1 to 5 mm in size, and then the vermiculite and pearlite selected for particle size are rapidly heated to 800 to 1200 ° C. to be peeled and expanded 10 to 15 times. The exfoliation expansion uses an expansion device made of a known expansion furnace.

다음에, 상기 팽창된 버미큘라이트 30 ~ 42 중량%와 팽창된 펄라이트 40 ~ 50 중량%에, 미분 황토 10 ~ 18 중량% 와, 규산 나트륨 0.92 ~ 1.3 중량%와, 실리카 겔 0.59 ~ 0.97 중량%와, Mg-Al 설폰산염 나트륨 바인다 0.17 ~ 0.30 중량% 를 배합한 다음, 상기 배합된 원료를 두 개의 강판 사이에 적층하여 가열 가압하여 성형한다.Next, 30 to 42% by weight of the expanded vermiculite and 40 to 50% by weight of expanded pearlite, 10 to 18% by weight of finely divided ocher, 0.92 to 1.3% by weight of silicate silica, 0.59 to 0.97% by weight of silica gel, Mg-Al sulfonate sodium bicarbonate 0.17 to 0.30% by weight is blended, and then the blended raw material is laminated between two steel sheets to be molded by heating and pressing.

본 발명에 사용되는 버미큘라이트(질석)는 흑운모가 풍화 또는 열수 변질에 의해 생성된 광물로서, 그 내부에 물분자가 결합되어 있어, 고온으로 가열되면 광물 내부의 수분이 증발하면서 형성되는 기포로 인해 내부에 무수한 기공이 형성되고 원석부피의 20 ~ 40배까지 팽창한다.Vermiculite (vermiculite) used in the present invention is a mineral produced by weathering or hydrothermal alteration of biotite, and water molecules are bonded therein, and when heated to a high temperature, bubbles are formed while moisture inside the mineral evaporates. Innumerable pores are formed in and expands up to 20 to 40 times the volume of gemstones.

본 발명에 사용되는 펄라이트(진주암)는 화산암이 급속히 냉각될 때 형성되는 흑요석으로서, 그 내부에 함유된 수분은 고온으로 가열될 때 증발하고 부풀어 올라 미세한 다공질의 하얀 광물성이 되고 산도가 중성이며 양분함량이 거의 없으며 잡초, 종자, 병원균 및 해충 등이 전혀 서식하지 않는다.Pearlite (pearl stone) used in the present invention is a obsidian formed when the volcanic rock is rapidly cooled, the water contained therein evaporates and swells when heated to a high temperature, becomes a fine porous white mineral, acidity is neutral, nutrient content There is little and weeds, seeds, pathogens and pests do not live at all.

무공해인 펄라이트와 버미큘라이트는 3층 구조형 운보성 광물질로서 층수간에 수분이 함유되어 가열하면 층수간에 탈수 현상이 일어나며 박리팽창되어 무수히 많은 다공질의 보온 방음 무기질 단열재의 역할을 하게 된다.Pollution-free pearlite and vermiculite are three-layer structured clouding minerals, which contain moisture between layers, causing dehydration between layers and exfoliating and expanding, thus acting as a myriad of porous thermal insulation soundproof inorganic insulating materials.

질석은 그 품질에 따라 질석골드와 질석실버로 나누어지는데, 다음 표1은 질석골드, 질석실버, 진주암 및 황토(고령토)에 대해 한국건자재시험연구원에서 시험한 시험성적서에 의한 주성분이다.Vermiculite is divided into vermiculite gold and vermiculite silver according to its quality. The following Table 1 shows the main components of the vermiculite gold, vermiculite silver, pearl rock, and ocher (kaolin) according to the test report tested by Korea Institute of Construction Materials.

[표 1]TABLE 1

화학성분(중량%)Chemical composition (% by weight) SiO2 SiO 2 Fe2O3 Fe 2 O 3 Al2O3 Al 2 O 3 CaOCaO Mg0Mg0 K2OK 2 O Na2ONa 2 O 강열감량Ignition loss 수분moisture 질석골드Vermiculite gold 33.433.4 11.7611.76 19.019.0 2.362.36 20.0920.09 3.793.79 0.420.42 5.35.3 2.02.0 질석실버Vermiculite Silver 30.730.7 7.267.26 18.418.4 2.222.22 21.4021.40 2.212.21 0.220.22 8.98.9 7.57.5 진주암Mother-of-pearl 71.171.1 0.880.88 19.019.0 0.730.73 0.310.31 5.495.49 1.191.19 1.01.0 0.20.2 황토ocher 61.361.3 1.091.09 22.822.8 0.050.05 0.110.11 1.091.09 0.030.03 11.911.9 1.31.3

상기 시험은 KSL 4007-96 및 KSE 3808-98에 따라 시험하였으며, 측정온도 20.8℃에서 질석골드의 pH는 9.1이었고 질석실버의 pH는 8.1이었으며, 진주암의 pH는 6.7이었고, 황토의 pH는 3.8이었다. The test was conducted according to KSL 4007-96 and KSE 3808-98. At a measurement temperature of 20.8 ° C., vermiculite gold had a pH of 9.1, vermiculite silver had a pH of 8.1, pearlite had a pH of 6.7, and loess had a pH of 3.8. .

그리고, 중간품질의 질석에 대해 측정온도 40℃에서 FT-IR 스펙트로메터(Spectrometer)를 이용하여 흑체(Black Body)와 대비한 방사율 및 방사에너지를 시험한 결과, 질석의 방사율은 0.898(5 ∼ 20 ㎛)이었고 질석의 방사에너지는 3.62 x 100 W/m2 (40℃)이었다.In addition, the emissivity and radiant energy of the vermiculite of the vermiculite were measured by using the FT-IR spectrometer at a measurement temperature of 40 ° C., and compared with the black body. Μm) and vermiculite was 3.62 × 100 W / m 2 (40 ° C.).

한편 본 발명은 방화문 판재의 제조를 위하여 상기 팽창성 광물과 함께 황토를 혼합한 것으로 황토의 방사율은 0.93(5 ∼ 20 ㎛)이었고 황토의 방사에너지는 4.31 x 100 W/m2 (40℃)이었다. 본 발명은 상기 황토의 첨가에 의하여 판재의 강도가 증가되었으며, 인체에 유익한 원적외선 방사에 의한 효과, 축열에 의한 에너지 절감 효과, 유해 곤충 또는 균의 서식을 억제하는 항균효과 및 습도조절 능력에 의한 결로방지 효과가 있다는 특징이 있다.On the other hand, the present invention is a mixture of the loess with the expandable mineral for the manufacture of fire door plate material, the emissivity of the loess was 0.93 (5 ~ 20 ㎛) and the emission energy of the loess was 4.31 x 100 W / m 2 (40 ℃). The present invention is the strength of the plate by the addition of the ocher, the effect of far-infrared radiation beneficial to the human body, the energy saving effect by the heat storage, condensation by the antibacterial effect and humidity control ability to suppress the habitat of harmful insects or bacteria It is characterized by the prevention effect.

상기 규산나트륨과 실리카겔과 Mg-Al 설폰산염 나트륨 바인다는 무기질 접착제이다.The sodium silicate, silica gel and Mg-Al sulfonate sodium binder is an inorganic adhesive.

상기 규산나트륨의 물리적 특성은 규산이온, 폴리 규산이온 및 콜로이드 상의 규산이온 미셀(Micell)이 존재하며 그 형태는 SiO2/Na2O이며 대체로 550 ~ 700℃에서 유동이 생겨 1300℃에서 융해된다.The physical properties of the sodium silicate are silicate ions, polysilicate ions and silicate ions micelles (Micell) in the colloidal form, SiO 2 / Na 2 O in the form of a flow at 550 ~ 700 ℃ generally melt at 1300 ℃.

상기 팽창성 광물에 무기질 접착제를 혼합하여 가열하는 온도는 80 ~ 120℃이고, 가압력은 180 ~ 220 kg/cm2이다. 상기 가열온도에서 접착제의 점도가 충분히 낮아지며 상기 가압력에 의해 무기질 접착제가 광물질 입자 사이에 끼어 들어가면서 단단히 접착하게 되므로 강도가 우수하다.The temperature for mixing and heating the inorganic adhesive to the expandable mineral is 80 ~ 120 ℃, the pressing force is 180 ~ 220 kg / cm 2 . The viscosity of the adhesive is sufficiently low at the heating temperature, and the strength is excellent because the inorganic adhesive is firmly adhered while being sandwiched between the mineral particles by the pressing force.

상기 박리 팽창된 질석과 바이오 미네랄 원적외석이 방사되는 황토는 경량이면서 내화도 1400℃ 이상이며 습도(RH) 75%에서 1% 이하이며 내외부의 기온차이에 의한 결로현상이 방지된다. 따라서 실내의 온도변화를 조절하여 내부공기정화와 바이오 미네랄 원적외선으로 정상체온을 유지하고 피부건강 신진대사를 왕성하게 하여, 스트레스 해소, 소화촉진, 근육통 해소 및 노폐물 분비촉진 등 인체의 공명 공진 작용의 효과를 얻을 수 있다. The ocher from which the exfoliated expanded vermiculite and bio mineral far-infrared is radiated is light and has a fire resistance of 1400 ° C. or more and humidity (RH) of 75% to 1% or less, and condensation is prevented due to a temperature difference between inside and outside. Therefore, by controlling the temperature change in the room to maintain normal body temperature with internal air purification and bio mineral far-infrared rays and vitalize skin health metabolism, the effects of the resonance resonance effect of the human body such as stress relief, digestion promotion, muscle pain relief and waste product promotion Can be obtained.

본 발명에 의해 제조되는 방화문 판재는, 버미큘라이트와 펄라이트와 특수한 광물질인 무해무독성인 무기질과 인체에 많은 도움을 주는 황토 점토인 무기질 점토로 미네랄 바이오 원적외선을 방사하는 독특한 광물과 적당량을 혼가하여 여러 형의 틀을 만들어 경량인 불연성으로서, 화재시에는 완벽한 불연재로서 방화의 역할을 할 뿐만 아니라 평상시에는 실내거주자의 건강을 증진하는 효과가 있다.The fire door board produced by the present invention is mixed with vermiculite and pearlite, a special mineral, a non-toxic non-toxic mineral, and mineral clay, which is yellow clay, which is helpful to the human body. Lightweight non-combustible by making a frame, in the event of a fire as a perfect non-flammable material, as well as acting as a fire, it is effective to improve the health of indoor residents in normal.

이하 실시예를 설명한다.Examples will be described below.

[실시예]EXAMPLE

버미큘라이트(질석) 및 펄라이트(진주암)를 분쇄기로 분쇄 가공하고, 상기 분쇄가공된 버미큘라이트 직경 2mm의 크기로 입도 선별한다.Vermiculite (vermiculite) and pearlite (pearlstone) are pulverized by a pulverizer, and the pulverized vermiculite has a particle size of 2 mm in diameter.

상기 입도 선별된 버미큘라이트 및 펄라이트를 900℃로 급속히 가열하여 원석의 12배 크기로 팽창시키고, 상기 팽창된 버미큘라이트 3.5kg과 펄라이트 4.2kg에 황토 1kg과 규산나트륨 100g과 실리카겔 70g과 Mg-Al 설폰산염 나트륨 바인다 20g을 배합한다.The particle size screened vermiculite and pearlite is rapidly heated to 900 ℃ to expand to 12 times the size of the ore, the expanded vermiculite and pearlite 4.2kg 1kg ocher and 100g sodium silicate, silica gel 70g and Mg-Al sulfonate sodium Combine 20 g of vinegar.

상기 배합된 원료를 2mm두께의 상, 하측강판사이에 적층하여 100℃ 로 가열하고 200 kg/cm2로 가압하여 방화문 판재를 제조하였다.The blended raw material was laminated between 2 mm thick upper and lower steel plates, heated to 100 ° C., and pressurized to 200 kg / cm 2 to prepare a fire door.

본 발명에 의한 팽창성 광물을 이용한 방화문 판재에 의하면, 보온 단열효과 및 흡 차음효과가 우수하고 경량이며 불연성이고 인체의 건강을 증진하며 환경오염을 방지하는 효과가 있다.According to the fireproof door plate using the expandable mineral according to the present invention, the thermal insulation and sound absorption and sound insulation effect is excellent, light weight, non-combustible, improve the health of the human body and prevent the environmental pollution.

Claims (1)

버미큘라이트(질석)와 펄라이트(진주암)를 분쇄가공 후, After grinding vermiculite (pearl vermiculite) and pearlite (pearl stone), 상기 분쇄가공된 버미큘라이트 및 펄라이트를 1~5 mm 크기로 입도 선별한 다음, The pulverized vermiculite and pearlite are screened to a particle size of 1 to 5 mm in size, 입도 선별된 상기 버미큘라이트와 펄라이트를 800 ~ 1200℃로 급속히 가열하여 10 ~ 15배로 박리팽창시킨 후, After the particle size screened vermiculite and pearlite rapidly heated to 800 ~ 1200 ℃ by peeling expansion 10 to 15 times, 상기 팽창된 버미큘라이트 30 ~ 42 중량%와 펄라이트 40 ~ 50 중량%에, 미분 황토 10 ~ 18 중량% 와, 규산 나트륨 0.92 ~ 1.3 중량%와, 실리카 겔 0.59 ~ 0.97 중량%와, Mg-Al 설폰산염 나트륨 바인다 0.17 ~ 0.30 중량% 를 배합한 다음, 30 to 42% by weight of the expanded vermiculite and 40 to 50% by weight of pearlite, 10 to 18% by weight of finely divided clay, 0.92 to 1.3% by weight of sodium silicate, 0.59 to 0.97% by weight of silica gel, and Mg-Al sulfonate Sodium Vidder 0.17 ~ 0.30% by weight, and then 상기 배합된 원료를 두 개의 강판사이에 적층하여 가열 가압하여 성형하여 이루어지되,The compounded raw material is laminated between two steel sheets and formed by heating and pressing, 상기 팽창된 버미큘라이트와 펄라이트에 상기 규산 나트륨과 실리카 겔과 Mg-Al 설폰산염 나트륨 바인다를 혼합하여 가열하는 온도는 80 ~ 120℃로 하고, 가압력은 180 ~ 220 kg/㎠으로 하여 이루어지는 것을 특징으로 하는 팽창성 광물을 이용한 방화문 판재.Mixing and heating the expanded vermiculite and pearlite, the sodium silicate, silica gel and Mg-Al sulfonate sodium binder is heated to 80 ~ 120 ℃, the pressing force is characterized in that the 180 ~ 220 kg / ㎠ Fire door board using expandable minerals.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101059569B1 (en) 2011-04-15 2011-08-26 송은섭 Nonflammable panel manufacturing method using expandable ceramics and nonflammable panel manufactured by this
KR101171547B1 (en) 2010-07-29 2012-08-09 임찬묵 A non-flammable panel fire door
KR101229107B1 (en) 2010-04-01 2013-02-06 김동수 Sandwich Panel using a neutralized industrial by-product and expansive stone

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KR100913485B1 (en) * 2008-11-18 2009-08-25 (주)헬프텍 A process for manufacturing fire-resisting adhesive of variously functional corpuscular electrolysis silver and the fire-resisting adhesive and the fire-resisting insulation pannel with the fire-resisting adhesive
KR101252586B1 (en) * 2011-08-10 2013-04-09 대구한의대학교산학협력단 eco-friendly interior materials for building using expanded perlite and its manufacturing method
KR102177822B1 (en) * 2018-04-12 2020-11-11 이종철 A fire door comprising a coated and expanded vermiculite and an anti-condensation heat insulating layer
KR102180239B1 (en) * 2019-06-14 2020-11-18 조선제 Fireproof door and manufacturing method thereof

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Publication number Priority date Publication date Assignee Title
KR101229107B1 (en) 2010-04-01 2013-02-06 김동수 Sandwich Panel using a neutralized industrial by-product and expansive stone
KR101171547B1 (en) 2010-07-29 2012-08-09 임찬묵 A non-flammable panel fire door
KR101059569B1 (en) 2011-04-15 2011-08-26 송은섭 Nonflammable panel manufacturing method using expandable ceramics and nonflammable panel manufactured by this

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