KR100588757B1 - Polyester Staple Fiber bases of Head liner for Vehicle and Method of the Same - Google Patents

Abstract

The polyester fiber base material of the present invention is a polyester fiber base material of a headliner of which the upper layer, the inner layer and the bottom layer are made of fibers in which low melting fiber (LMF) and regular fiber are mixed, respectively. The upper layer and the bottom layer are each composed of 60 to 80% by weight of low melting point fibers, 20 to 40% by weight of regular fibers, the inner layer is 20 to 40% by weight of low melting point fibers, 60 to 80% by weight of regular fibers It is contained, and relates to a polyester fiber base material of a car headliner and a method of manufacturing the same, characterized in that at least one of the top layer and the bottom layer is coated with a resin.

The present invention has excellent rigidity and formability by coating at least one of the upper layer and the lower layer of the polyester (PET) felt with a resin in order to improve the rigidity of the polyester (PET) felt has a stiffness or warpage of the molded product This does not occur can minimize the defects as well as the recycling of the material has an excellent effect.

In addition, the polyester felt is composed of a top layer, an inner layer and a bottom layer using regular fibers and low melting point fibers, and at least one layer of the top layer and the bottom layer is coated with a resin to provide excellent sound absorbing and insulating performance. The high noise absorption and outdoor noise isolation and good thermal conductivity eliminate the need for additional pads, simplifying the work process and increasing the efficiency of indoor air conditioners.

 Headliner, Polyester Fiber (PET Fiber) Base, PET Felt, Three Layer Structure, Resin Impregnation, Sound Absorption

Description

Polyester Staple Fiber bases of Head liner for Vehicle and Method of the Same}

1 is a cross-sectional view showing a PET felt laminated structure according to an embodiment of the present invention.

Figure 2 is a flow chart showing a process for producing a polyester fiber substrate of the headliner for automobiles according to the present invention.

* Explanation of symbols for main parts of the drawing

10: PET felt 11: upper layer

12: inner layer 13: bottom layer

The present invention is coated with a solvent containing a curable and plastic resin to the polyester fiber used as a sound absorbing and insulating material for automobiles and constructions to increase the strength of the molded product, lower the weight, improve air permeability and excellent sound absorption performance, working environment The present invention relates to a polyester fiber base material for an automobile headliner excellent in clean recycling and a method of producing the same.

In general, a head liner for a vehicle is embedded in the ceiling of a vehicle to absorb and block noise of a vehicle, and includes a skin material (polyester nonwoven fabric, a PVC sheet, etc.), a cushion material (foam such as PP, PE), It consists of a laminated structure of an adhesive film (hot melt film) and the substrate (resin felt, glass wool, paper board, etc.).

The headliner base includes resin felt, felt punched by mixing polypropylene fiber and natural hemp, felt bonded paper and film, polyurethane foam, glass mat, nonwoven fabric, and felt formed of film. Although it has been used, these substrates have a problem in that a large amount of material preheating and assembly odors are generated and recycling is not possible. In particular, resin felt has already been limited in use due to dust, gas, odor, etc., due to phenolic as a main raw material. Since it has been impossible to use in export models, there is a problem that the peeling occurs in the skin and lamination (lamination) a lot, the weight is heavy and difficult to handle, and the sound absorption rate is not good because the sound absorption rate is low.

Needle-punched felt mixed with polypropylene fiber and natural hemp has insufficient rigidity, resulting in post-deformation after molding the product, and sagging of the ceiling, and felt bonded to paper and film after molding the product due to lack of dimensional stability and material rigidity. Deformation is severe or warpage occurs, and moldability and NVH (Noise, Vibration, Hashness) performance is much lower than other materials. And the felt formed of polyurethane foam, glass mat, non-woven fabric and film is expensive and low economical efficiency, the lack of rigidity, product bending, cracks between the fillers (injectables) and the matching part occurs, There was a problem in that the surface quality of the product is not good, the emotional quality is lowered.

In order to solve the above problems, many patents using polyester staple fiber (hereinafter referred to as PET fiber) have been filed. Looking at these patents, sound absorbing material having a thickness of 20 mm "Automotive soundproofing material and its manufacturing method" characterized in that a synthetic resin film layer having a thickness of 40 ~ 100㎛ in the longitudinal direction in the middle position of the PET fiber fiber layer is disclosed in Korea Patent Publication No. 0013840 (2001) 2. 14), but it is difficult to apply due to the lack of rigidity and formability for materials and headliners developed to improve sound absorption and sound insulation for Dash Pad & Hood Insulator. Problems occurred, and after cutting and masking the polyester fibers and acrylic fibers, mixed with a low melting polyester-based fibers in a certain ratio, The method of manufacturing a sound absorbing insulation for automobile interiors and the sound absorbing insulation, which is characterized by the construction of heating the sound absorbing insulation in the form of a nonwoven fabric, was disclosed in Korean Patent Publication No. 0008773 (No. 29, 2002). In order to use it as a base material for liner, there is a problem that it cannot be used as a base material for headliner because it has a single layer structure, which has no stiffness or formability and causes bending or warping.

In addition, it is NVH (Noise, Vibration, Hashness) technology to reduce the interior noise of the car. It is manufactured in a multilayer structure made of PET staple fiber and installed in the interior or engine room of the car, which is superior to existing sound absorbing and insulating materials. Although "car sound absorbing and insulating material for automobiles" to be used to create a more pleasant vehicle atmosphere has been registered as Republic of Korea Patent Publication No. 10-0416100 (January 24, 2004), but not enough rigidity and moldability deteriorated However, there was a problem such as lack of economics due to the rise in cost.

Therefore, the present invention is excellent in formability by improving the rigidity of the polyester (PET) felt to improve the above problems, it is possible to minimize the defect as the bending or bending of the molded product does not occur It is an object of the present invention to provide a polyester fiber base material and a method for manufacturing the same for a headliner for automobiles having excellent recycling.

In addition, due to the excellent sound absorption performance, the indoor noise absorption and outdoor noise blocking ability is high, and the thermal conductivity is good, so no additional pad is required, which simplifies the work process and increases the efficiency of operating the indoor air conditioner. Another object is to provide an ester fiber substrate and a method for producing the same.

The present invention is composed of a three-layer structure of the upper layer, the inner layer and the bottom layer using polyester fibers as a main material, and at least one of the top layer and the bottom layer is coated with a resin to increase rigidity. The present invention relates to a polyester fiber base material of an automotive headliner that is excellent in sound absorbing and insulating performance and is also recyclable.

The polyester fiber substrate of the headliner is a polyester felt (hereinafter referred to as a 'PET felt'), the structure of which consists of an upper layer, an inner layer and a bottom layer, each of which is a low melting fiber (low melting fiber, LMF) and regular fiber (regular fiber) mixed is used as a raw material. The upper layer and the bottom layer are each comprised of 60 to 80% by weight of low melting point fibers, 20 to 40% by weight of regular fibers, the inner layer contains 20 to 40% by weight of low melting point fibers, 60 to 80% by weight of regular fibers And at least one of the top layer and the bottom layer is coated with a resin.

In the present invention, the upper layer may also be coated with a resin in order to further increase the rigidity of the PET felt, which is a polyester fiber base of the headliner.

The content of the low melting point fibers and the regular fibers of the upper layer and the bottom layer is 60 to 80% by weight and 20 to 40% by weight, respectively, and when the content of the low melting point fiber is less than 60% by weight, the rigidity of the product is lowered and the merchandise deteriorates. If the content exceeds 80% by weight, the rigidity is very good, but the cost increases due to the shrinkage of the low melting point fiber fabric (fabric width). When the content of the regular fiber is less than 20% by weight and the content is more than 40% by weight, the same phenomenon occurs when the content of the low melting point fiber is more than 80% by weight, respectively, when the content is less than 60% by weight.

The resin coating amount of each layer in which at least one of the top layer and the bottom layer is coated with a resin is 130 to 150 g / m 2, respectively.

The coating resin is polymethyl methacrylate (PMMA) 36.0 to 44.0% by weight, solvent ethyl acetate (EA) 53.5 to 63.5% by weight, initiator initiator Azobisisobutyronitrile (Azobisisobutyronitrile) 0.5 to 1.5 weight It contains%.

The coating resin further enhances the rigidity, serves to suppress the shrinkage phenomenon of the fabric due to heat when heating the regular fibers and low melting point fibers, the use content is 36.0 to 44.0% by weight. If the content is less than 36.0% by weight, the effect of the resin coating is insignificant, the rigidity does not increase, and if the content exceeds 44.0% by weight, the work efficiency is reduced due to excessive cost increase and excessive drying time during resin drying.

And it can be used instead of the polymethyl methacrylate (PMMA) epoxy resin, butyl methacrylate (BMA), butyl melamine (Butyl-Melamine), methacryl acrylate (Methacrylic Acrylate), urea melamine (Urea-Melamine ), Diethylene glycol (Diethylene Glycol), monoethylene glycol (Monoethylene Glycol), styrene (Styrene) and the like can be used to select one or more.

The content of the solvent is 53.5 to 63.5 wt%. If the content is less than 53.5% by weight, dissolution of the resin is not performed smoothly, and if the content is more than 63.5% by weight, the drying time is long and work efficiency is reduced.

Instead of solvent ethyl acetate (EA), methanol, toluene, acetone, acetone, xylene, methyl ethyl ketone (MEK), benzyl alcohol, etc. You can choose one or more from.

The initiator is used to smooth the reaction rate at room temperature, the use content is 0.5 to 1.5% by weight, the content is less than 0.5% by weight the effect is insignificant, when the content is more than 1.5% by weight is economical due to excessive use Is lowered.

Benzoyl Peroxide may be used instead of Azobisisobutyronitrile as an initiator.

The upper layer and the bottom layer are 170 to 230g / ㎡, respectively, the inner layer is 350 to 450g / ㎡, the low melting point fibers are 2 to 6 denier, regular fibers are used fineness 4 to 15 denier.

Instead of the regular fibers, weeds and acrylic fibers may be used.

And the manufacturing method of the polyester fiber base material of the headliner for automobiles according to the present invention

Iii) mixing and carding the raw fibers of the top layer, the inner layer and the bottom layer, respectively, to form a web and laminating to prepare respective web laminates;

Ii) sequentially laminating an inner layer and a bottom layer on top of the web laminate of the bottom layer prepared in step iii);

Iii) needle-punching the laminate laminated with the bottom layer and the inner layer and the top layer to produce a PET felt;

Iii) impregnating the bottom layer of the PET felt into a coater to coat the resin;

Iii) drying the resin coated PET felt in the step iii) through a dryer;

Iii) winding the dried PET felt to cut to a predetermined standard;

It is manufactured through.

The raw material fibers of the upper layer and the bottom layer of step iii) are composed of 60 to 80% by weight of low melting point fiber, 20 to 40% by weight of regular fiber, and the inner layer is 20 to 40% by weight of low melting point fiber, regular fiber 60 to 80 weight percent.

In the step iii), the PET layer is impregnated with a resin in order to increase the rigidity of the PET felt and to suppress the shrinkage of the fabric due to heat when the temperature of the raw material fiber is heated. It can also be coated with resin.

Resin coating amount of the at least one layer of the top layer and the bottom layer is coated with a resin is 130 to 150 g / ㎡, respectively.

The coating resin is polymethyl methacrylate (PMMA) 36.0 to 44.0% by weight, solvent ethyl acetate (EA) 53.5 to 63.5% by weight, initiator initiator Azobisisobutyronitrile (Azobisisobutyronitrile) 0.5 to 1.5 weight It contains%.

In addition, the temperature of the dryer of step iii) is 145 to 165 ℃, and dried through the dryer for 4 to 6 M / min. If the temperature is less than 145 ° C, the coated resin is not dried, so that the peeling phenomenon with the PET felt and the odor only after the residual solvent are extracted. If the temperature exceeds 165 ° C, the weight increases due to shrinkage due to heat setting of the material.

Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

1 is a cross-sectional view showing a PET felt laminated structure according to an embodiment of the present invention, wherein the base PET felt 10 of the headliner for a vehicle includes three layers of an upper layer 11, an inner layer 12, and a bottom layer 13. The upper layer 11 and the bottom layer 13 are composed of 60 to 80% by weight of low melting point fibers, 20 to 40% by weight of regular fibers, respectively, the inner layer 12 is a low melting point fiber 20 40 wt% to 60 wt% of the regular fiber, and the top layer 11 and the bottom layer 13 are coated with a resin and have an impregnation amount of 130 to 150 g / m 2.

Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited by Examples.

(Examples 1 to 6 and Comparative Examples 1 to 6)

Examples 1 to 6 and Comparative Examples 1 to 6 are prepared by the PET felt with the base material of the headliner by the production method as described above in the PET fiber mixing ratio as shown in [Table 1] to prepare the headliner and the test results It is shown in [Table 2].

(Examples 1 to 3)

Examples 1 to 3 are experiments by producing a head felt liner based on PET felt prepared by impregnating the bottom layer with a resin, consisting of a three-layer structure of the upper layer, inner layer, and bottom layer at the PET fiber mixing ratio as shown in Table 1 below. One result is shown in [Table 2].

(Examples 4 to 6)

Examples 4 to 6 is a head liner based on a PET felt prepared by impregnating the upper layer and the bottom layer with a resin composed of a three-layer structure of the upper layer, inner layer, and bottom layer at the PET fiber mixing ratio as shown in Table 1 below. The experimental results are shown in [Table 3].

(Comparative Example 1)

Comparative Example 1 was tested by using a PET felt of a conventional general monolayer structure.

(Comparative Example 2)

Comparative Example 2 was prepared by configuring a PET felt in a three-layer structure of the upper layer, the inner layer, the bottom layer at the PET fiber mixing ratio as shown in Table 1 below, and the bottom layer was impregnated with a resin.

(Comparative Example 3)

Comparative Example 3 was prepared by configuring the PET felt in a three-layer structure of the upper layer, the inner layer, the bottom layer at the PET fiber mixing ratio as shown in Table 1 below, and the bottom layer was not impregnated with a resin.

(Comparative Example 4)

Comparative Example 4 was prepared by configuring the PET felt in a three-layer structure of the upper layer, the inner layer, the bottom layer at the PET fiber mixing ratio as shown in Table 1 below, and the bottom layer was impregnated with a resin.

(Comparative Examples 5 and 6)

Comparative Examples 5 and 6 were prepared by configuring a PET felt in a three-layer structure of the upper layer, the inner layer, the bottom layer at the PET fiber mixing ratio as shown in Table 1 below, and the upper layer and the bottom layer were impregnated with a resin.

TABLE 1

division PET fiber mixing ratio (%) Weight (g / ㎡) Coating amount (g / ㎡) LMF ReF Example 1 Upper layer 60 40 200 - Inner layer 20 80 400 - Floor 60 40 200 130 Example 2 Upper layer 70 30 200 - Inner layer 30 70 400 - Floor 70 30 200 140 Example 3 Upper layer 80 20 200 - Inner layer 40 60 400 - Floor 80 20 200 150 Example 4 Upper layer 60 40 200 130 Inner layer 20 80 400 - Floor 60 40 200 130 Example 5 Upper layer 70 30 200 140 Inner layer 30 70 400 - Floor 70 70 200 140 Example 6 Upper layer 80 20 200 150 Inner layer 40 60 400 - Floor 80 20 20 150 Comparative Example 1 Monolayer 30 70 800 - Comparative Example 2 Upper layer 50 50 200 - Inner layer 50 50 400 - Floor 50 50 200 130 Comparative Example 3 Upper layer 70 30 200 - Inner layer 30 70 400 - Floor 70 30 200 - Comparative Example 4 Upper layer 90 10 200 - Inner layer 10 90 400 - Floor 90 10 200 130 Comparative Example 5 Upper layer 70 30 200 120 Inner layer 30 70 400 - Floor 70 30 200 120 Comparative Example 6 Upper layer 70 30 200 160 Inner layer 30 70 400 - Floor 70 30 200 160

TABLE 2

division Example Comparative example One 2 3 One 2 3 4 Tensile Strength (㎏ / ㎠) condition Bell 86 87 88 71 76 79 80 Lateral 85 85 85 68 74 76 78 Heat resistant Bell 74 75 73 65 70 68 71 Lateral 73 72 70 62 68 68 69 inroad Bell 64 65 66 56 60 58 60 Lateral 62 63 64 52 58 56 58 Flexural Strength (㎏ / ㎠) condition Bell 55 57 59 48 50 51 52 Lateral 40 42 42 34 41 34 35 Heat resistant Bell 51 52 51 42 45 46 48 Lateral 35 38 36 30 34 34 35 inroad Bell 33 35 37 28 30 31 32 Lateral 28 30 31 23 28 26 28 Dimensional rate of change (%) Heat resistant 0.3 0.3 0.31 0.38 0.35 0.33 0.3 inroad 0.3 0.3 0.31 0.38 0.35 0.33 0.3 Thermal Conductivity (㎉ / mh ℃) materials 0.0349 0.0345 0.0355 0.0365 0.0357 0.349 0.0357 Assembly 0.0329 0.0327 0.0337 0.0347 0.0339 0.0342 0.0354 Sound absorption 1.06 1.07 1.09 0.63 0.86 0.79 0.88

TABLE 3

division Example Comparative example 4 5 6 5 6 Tensile Strength (㎏ / ㎠) condition Bell 92 94 95 86 96 Lateral 90 91 92 85 92 Heat resistant Bell 79 81 82 75 82 Lateral 78 79 79 72 80 inroad Bell 68 69 70 63 69 Lateral 65 65 66 61 65 Flexural Strength (㎏ / ㎠) condition Bell 62 65 67 54 68 Lateral 48 51 56 40 56 Heat resistant Bell 54 56 55 52 57 Lateral 40 43 46 36 48 inroad Bell 39 41 44 35 45 Lateral 36 38 38 29 39 Dimensional rate of change (%) Heat resistant 0.26 0.25 0.25 0.29 0.25 inroad 0.27 0.26 0.27 0.30 0.27 Thermal Conductivity (㎉ / mh ℃) materials 0.0334 0.0335 0.0332 0.0351 0.0332 Assembly 0.0321 0.0321 0.0319 0.0325 0.0318 Sound absorption 1.12 1.13 1.15 1.05 1.17

1) tensile strength

Condition-Using a Danishron tester or equivalent tensile tester, draw a 100mm mark at the center of the test piece and attach it to a tension tester so that the clamp distance is 150mm, and tension it at a speed of 200mm / min to find the maximum load. It was. However, the test pieces cut out between the marks were tested again by that number.

Heat Resistance-The test piece was tested by pulling out 250 × 50 mm in a thermostat for 3 hours.

Moisture resistance-The test piece 250 × 50 mm was measured after standing for 24 hours in 50 ℃, 90 ~ 100% humidity.

2) flexural strength

Condition-The specimen was loaded at a speed of 50 mm / min at the point of load on the smooth surface and its maximum load was measured. The flexural strength of five or more test specimens was calculated according to the following equation, and the average value of the horizontal and vertical values of each of these values was calculated to be the flexural strength of the product.

Heat resistance-Test piece 250 × 50 mm was left in the thermostat for 3 hours and then pulled out and tested.

Moisture resistance-The test piece 250 × 50 mm was measured after standing for 24 hours in 50 ℃, 90 ~ 100% humidity.

3) Dimensional rate of change

After immersing the specimen for 5 hours at room temperature and drying it for 24 hours at 80 ° C, take a test specimen of 200 × 200 mm, fill in the baseline parallel to the side from 50 mm inside each side, and measure the distance between the reference lines facing each other more than three points accurately. Obtained.

4) thermal conductivity

In the test box (W × D × H = 300 * 300 * 150mm), the specimen is placed in the center of the test box through a circular hole and the center surface temperature of the iron plate is measured at 30 ° intervals for 4 hours at 105 ° C. Thermal conductivity was obtained.

5) Sound absorption rate

It was tested according to ASTM E1050 using a vertical incident sound absorption tester (Two-microphone impedance measurement tube). A tester was set up to generate a frequency sound of 1/3 OCTAVE BAND of 100 ~ 6.4kHz as a speaker to generate standing waves in the straight pipe. .

As shown in Table 2, in Examples 1 to 3, tensile strength and flexural strength (state, heat resistance, and moisture resistance) were superior to those of Comparative Examples 1 to 4, indicating high stiffness, and high sound absorption rate. The dimensional change rate and the thermal conductivity were also low. However, in the case of Comparative Example 1 was not impregnated resin using a single-layered PET felt, the tensile strength and flexural strength was significantly low, showing low stiffness, high dimensional change rate and thermal conductivity, sound absorption rate In addition, the sound absorbing and insulating performance was poor. In Comparative Examples 2 and 4, the PET felt was formed into a three-layer structure of the upper layer, the inner layer, and the bottom layer at the PET fiber mixing rate, and the bottom layer was coated by resin impregnation. However, in the comparative example 2, the low melting point fiber mixing ratio of each layer was mixed with each other. The low tensile strength and flexural strength resulted in insufficient rigidity, low sound absorption, high dimensional change and high thermal conductivity. In Comparative Example 4, the low melting point fiber mixing ratio of each layer was mixed in an amount exceeding the content, and the tensile strength and the flexural strength were also low, the stiffness was low, the sound absorption was low, the dimensional change rate and the thermal conductivity were also high. 3 is not impregnated with the bottom layer, and showed an overall poor result compared to Examples 1 to 3.

And in the case of Examples 4 to 6, as shown in Table 3, by coating the resin by impregnating the upper layer and the lower layer of the prepared PET felt, the tensile strength and flexural strength (state, heat resistance, moisture resistance) is excellent It showed high stiffness, high sound absorption, low dimensional change and low thermal conductivity, and showed better results than the experimental results of Examples 1 to 3 shown in [Table 2].

However, in the case of Comparative Example 5, the overall experimental results were excellent by resin coating the upper layer and the lower layer of the PET felt, but the resin coating amount was less than the range of use, and showed similar experimental results as those of Examples 1 to 3 where only the lower layer was resin coated. The increase of the effect by resin coating was insignificant. Therefore, the synergistic effect was insignificant compared to the additional work process of resin coating the upper layer, and the work efficiency was lowered.

And Comparative Example 6 was excellent in the overall experimental results, but the drying time is longer because the resin coating amount exceeds the use range, the work efficiency and productivity is lowered.

TABLE 4

division Example Comparative example One 2 3 4 5 6 One 2 3 4 5 6 Formability ◎ ◎ ◎ ◎ ◎ ◎ × × △ △ ◎ ◎ smell radish radish radish radish radish radish radish radish radish radish radish radish Heat resistance ◎ ◎ ◎ ◎ ◎ ◎ × × △ △ ◎ ◎

* Sensory test: 10 and the relevant personnel in charge of the respective Examples 1 to 3 and Comparative Examples 1 to 4 each performed a sensory test. The results of the sensory test were shown as the average value.

1) formability

The molding thickness and the overall molding state of each part compared to the drawing dimensions after the mold molding were visually confirmed.

◎: Good, ○: Normal, ×: Poor

2) smell

DRY TYPE-Put the specimen in 4L test container and heat it in the heated oven for 1 hour and 30 minutes. After the container was removed, it was left to stand at room temperature (23 ± 2 ° C.) for 20 minutes to cool and evaluated.

WET TYPE-Apply 10% distilled water uniformly to the weight of the specimen. It was placed in a 4 L test container and sealed after standing in a laboratory at room temperature (23 ± 2 ° C.) for 1 hour.

3) Heat cycle resistance: The heat cycle resistance test was done 3 times.

-Heat resistance: 7 hours to 8 hours at 90 ~ 120 ℃

-Cold resistance: 5 hours at -30 ℃ ± 2 ℃

-Moisture resistance: over 9 hours at 50% ± 2 ℃ at 90% humidity

The change in thickness and overall appearance was then visually confirmed.

◎: Good, ○: Normal, ×: Poor

[Table 4] is a sensory test result of the headliner based on the PET felt prepared by the PET fiber mixing ratio of [Table 1], Examples 1 to 6 not only excellent moldability, but also smell after production It did not generate | occur | produce and was excellent in heat cycling resistance.

However, Comparative Example 1 was a headliner based on a single-layered PET felt, which did not have sufficient rigidity, so that the moldability of the headliner was poor, and the heat cycle resistance was also not excellent. Comparative Examples 2 and 4 are headliners based on a PET felt coated by resin impregnation of a three-layer structure, and the bottom layer of the three-layer structure was coated by impregnation with resin, but the mixing ratio of low melting point fibers was less than the content. The overall experimental results were not good.

In addition, Comparative Example 3 is a headliner based on PET felt, in which the bottom layer of the three-layer structure is not coated with a resin, and does not have sufficient rigidity of the headliner and thus does not have excellent moldability, and also has thermal cycle resistance in Examples 1 to 3. It was lower than three.

In addition, Comparative Examples 5 and 6 are headliners based on PET felt coated with resin by impregnating a top layer and a bottom layer of a three-layer structure, and Comparative Example 5 is similar to Examples 1 to 3 in terms of rigidity, moldability, and heat resistance cycle. The effect of resin coating on the upper layer was insignificant. And Comparative Example 6 was excellent in the overall experimental results, the resin coating amount of the upper layer and the lower layer exceeded the use range, not only the drying time is long, but also the economical efficiency was lowered.

The present invention has excellent rigidity and formability by coating at least one of the upper layer and the lower layer of the polyester (PET) felt with a resin in order to improve the rigidity of the polyester (PET) felt has a stiffness or warpage of the molded product This does not occur can minimize the defects as well as the recycling of the material has an excellent effect.

In addition, the polyester felt is composed of a top layer, an inner layer and a bottom layer using regular fibers and low melting point fibers, and at least one layer of the top layer and the bottom layer is coated with a resin to provide excellent sound absorbing and insulating performance. The high noise absorption and outdoor noise blocking and good thermal conductivity eliminate the need for additional pads, which simplifies the work process and increases the efficiency of operating indoor air conditioners.

Claims (13)

In the polyester fiber substrate of the headliner of which the upper layer, the inner layer, and the bottom layer are made of a mixture of low melting fiber (LMF) and regular fiber, respectively, the upper layer and the bottom layer are each low It comprises 60 to 80% by weight of the melting point fibers, 20 to 40% by weight of regular fibers, the inner layer is composed of 20 to 40% by weight of low-melting fibers, 60 to 80% by weight of regular fibers, the upper layer and At least one layer of the bottom layer is coated with a resin, And the resin coating amount of each layer to which at least one layer of the top layer and the bottom layer is coated with a resin is 130 to 150 g / ㎡, The upper layer and the bottom layer are 170 to 230g / ㎡, respectively, the inner layer is 350 to 450g / ㎡, The low melting point fiber is 2 to 6 denier, the regular fiber is a polyester fiber substrate of the headliner for automobiles, characterized in that 4 to 15 denier fineness. The method of claim 1, wherein the resin impregnated with the bottom layer is polymethyl methacrylate (PMMA) 36.0 to 44.0 wt%, ethyl acetate (EA) 53.5 to 63.5 wt% as a solvent, azobisisobuty is a catalyst initiator A polyester fiber substrate for an automotive headliner, comprising 0.5 to 1.5% by weight of ronitrile (Azobisisobutyronitrile). The method of claim 2, wherein the epoxy resin, butyl methacrylate (BMA), butyl melamine (Butyl-Melamine), methacryl acrylate (Methacrylic Acrylate) can be used instead of the polymethyl methacrylate (PMMA) impregnating the bottom layer Car head, which can be used by selecting one or more from urea melamine, urea melamine, diethylene glycol, monoethylene glycol and styrene Polyester fiber substrate of liner. The method of claim 2, wherein the solvent used in place of ethyl acetate (EA) may be methanol, toluene, acetone, xylene, methyl ethyl ketone (MEK), benzyl. Polyester fiber base material for automobile headliner, characterized in that it can be used to select one or more from alcohol (Benzyl Alcohol). 3. The polyester fiber base material for automobile headliners according to claim 2, wherein benzoyl peroxide can be used instead of azobisisobutyronitrile as a catalyst initiator. The polyester fiber base material for automobile headliners according to claim 1, wherein weave and acrylic fibers are used instead of the regular fibers. Iii) mixing and carding the raw fibers of the top layer, the inner layer and the bottom layer, respectively, to form a web and laminating to prepare respective web laminates; Ii) sequentially laminating an inner layer and a bottom layer on top of the web laminate of the bottom layer prepared in step iii); Iii) needle-punching the laminate laminated with the bottom layer and the inner layer and the top layer to produce a PET felt; Iii) impregnating the bottom layer of the PET felt into a coater to coat the resin; Iii) drying the resin coated PET felt in the step iii) through a dryer; Iii) winding the dried PET felt to cut to a predetermined standard; Including; And, in the step iii), the step of impregnating the upper layer in the coater resin coating step, Resin coating amount of the at least one layer of the top layer and the bottom layer is coated with a resin is a polyester fiber base material manufacturing method of the headliner for automobiles, characterized in that each of 130 to 150 g / ㎡. According to claim 7, wherein the raw material of the upper layer and the bottom layer of step iii) is composed of 60 to 80% by weight of low melting point fibers, 20 to 40% by weight of regular fibers, the inner layer is 20 to 40 weight of low melting point fibers %, 60 to 80% by weight of regular fibers, The resin coated in step iii) is 36.0 to 44.0 wt% of polymethyl methacrylate (PMMA), 53.5 to 63.5 wt% of ethyl acetate (EA) as a solvent, and azobisisobutyronitrile as an initiator. Using 0.5 to 1.5% by weight, The temperature of the dryer of step iii) is 145 to 165 ℃, and the polyester fiber base material manufacturing method of the headliner for automobiles, characterized in that the drying by passing through the dryer for 4 to 6 M / min. delete delete delete delete delete

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