KR100344098B1 - Manufacturing process of the transparent soap which contains opuntia ficus-indica powder as an ingredient - Google Patents

Abstract

The present invention relates to a method for producing a transparent soap containing a palm cactus in powder form, and more particularly, in a method for preparing a transparent soap, by adding a sugar component of a single or a mixture selected from glucose and sorbitol By adding cactus in the form of powder, which removes the unique viscosity of cactus, to the transparent soap base to make transparent soap, it shows antioxidant activity, tyrosinase inhibitory effect and anti-allergic effect that does not irritate the skin and contains medicinal ingredients. The present invention relates to a method for producing a transparent soap containing a powdered palm cactus that can be applied to a functional beauty soap that is effective for skin care and a tourist product of a character product with a unique color and aroma.

Description

Manufacturing process of the transparent soap which contains opuntia ficus-indica powder as an ingredient}

The present invention relates to a method for producing a transparent soap containing a palm cactus in powder form, and more particularly, in a method for preparing a transparent soap, by adding a sugar component of a single or a mixture selected from glucose and sorbitol By adding cactus in the form of powder, which removes the unique viscosity of cactus, to the transparent soap base to make transparent soap, it shows antioxidant activity, tyrosinase inhibitory effect and anti-allergic effect that does not irritate the skin and contains medicinal ingredients. The present invention relates to a method for producing a transparent soap containing a powdered palm cactus that can be applied to a functional beauty soap that is effective for skin care and a tourist product of a character product with a unique color and aroma.

Cactus stems have long been used as a folk remedy for skin diseases, rheumatism and burn treatment, and the cactus containing these medicinal components is opuntiaficus-indica (aka prickly pear).

The palm cactus is designated as Jeju Island Local Monument No. 35, and is easy to cultivate and has been grown natively around Hallim-eup, Bukjeju-gun, Jeju Island, and various clinical effects have been known through folk medicine since ancient times. Among them, the therapeutic effect of inflammation is most known, and is used for the treatment of neuralgia, arthritis, swelling, burns, bronchitis and asthma, and is known to be particularly effective in swelling and bronchial asthma.

The medicinal component of the palm cactus is contained in the stem and fruit, in particular, the substance contains 2 to 5% by weight of flavonoids and phenolic substances which have antioxidant effects [Analysis of cactus and improvement of processed food quality Trial, 'Korea Food Development Institute Report', January 1997]. This material has a higher value than 2% by weight of aloe in very high amounts compared to other plants. It is well known that antioxidant effects are closely related to skin aging.

On the other hand, the antioxidant activity of the palm cactus has recently been reported to study the antioxidant effect of cactus fruit in senescence-accelerated mouse (SAM) [Paik, SK: Effects of opuntia ficus-indica on the passive avoidance and anti-oxidation in the senescence-accelerated mouse. MS thesis, graduate school, Cheju National University, Cheju, Korea (1998)]. According to the results of the study, oral administration of cactus fruit to the SAM system for 30 days showed that the lipid peroxide content of liver tissue was decreased and the concentration of antioxidant glutathione (GHS) was significantly increased compared to the control group. Therefore, palm cactus fruit has been shown to be closely related to antioxidant activity by increasing the content of the GHS with prevention of lipid peroxide production in vivo.

On the other hand, the whitening effect of the palm cactus can be measured through the tyrosinase enzyme (Tyrosinase) inhibitory effect, the tyrosinase is involved in the process of changing tyrosine (Tyrosine) to melanin in vivo. Melanin is a complex and heterogeneous biopolymer that is involved in the pigmentation of the skin, hair and eyes, and the accumulation of non-ideal melanin pigments is the cause of blemishes and freckles. Tyrosinase inhibitors have been used in the cosmetic industry as substances that can control the biosynthesis of melanin and have a whitening effect.

On the other hand, allergic (allergy) -induced diseases include asthma (asthma), allergic rhinitis (nasal rhinitis), allergic skin symptoms and the like. Among them, allergic skin itching and other serious life disorders, severe cases require drug treatment. Therefore, products such as cosmetics are required to contain an anti-allergic substance and there is an advantage to prevent these symptoms when using this substance.

The palm cactus is used for soap, which is a necessity of everyday life, in addition to the use for folk remedies. This conventional soap containing cactus is an opaque soap that is generally used, pulverized cactus pulp with a mixer or colloid mill to remove viscous properties, and then juiced with a compress to obtain a cactus juice, and then mixed with a soap raw material mixture. It is prepared by a general method for preparing soap, which is described in Korean Patent No. 178436. However, the soap is likely to deteriorate due to overheating of the active ingredient of cactus juice during manufacture.

Transparent soaps, on the other hand, are very different from opaque soaps in raw materials, manufacturing processes, and in the commercialization of polishing and packaging. In particular, since it contains a large amount of moisturizing ingredients, the sweating and softening properties of the soap dominates the marketability of the soap, and the visual effect on the properties of the transparent soap has an absolute effect on the marketability. Therefore, it is very important to add the cactus component homogeneously in the state where these various elements are controlled. However, when preparing a transparent soap containing a large amount of moisturizing ingredients in a conventional cactus juice, when the juice is added to the transparent soap base, there is a disadvantage in that the soap recedes due to moisture contained in the juice, making it difficult to manufacture a commercially available transparent soap.

In addition, the cactus of the palm cactus has a unique viscosity of cactus, if the soap is manufactured without removing the viscosity, the viscous material flows to the outside of the soap, making the appearance of the soap poor and stability and cracking There is a problem of dropping. Conventionally, such viscous property is simply compressed by a physical impact to extract juice and use in the manufacture of soap, there is a concern that the viscous components are contained in the juice, there is a problem that prevents evenly mixing the ingredients of the soap.

As such, the soap containing the conventional cactus has not yet been put to practical use due to the above problems.

Thus, the present invention has completed the present invention by adding a palm cactus containing medicinal ingredients to a soap that can be easily used by the general public. Therefore, the present invention provides an anti-oxidant activity by preparing a transparent soap by adding a palm cactus in a powder form to which a sugar component of a single or a mixture selected from glucose and sorbitol is added to the transparent soap base to remove the viscosity of the cactus. It can be used as a functional beauty soap with tyrosinase inhibitory effect and anti-allergic effect, thereby improving skin beauty and preventing disease. In addition, clear soap containing powdered palm cactus that can be developed as a colorless hypoallergenic soap can be applied to tourism products of character products with the unique color and aroma of cactus by showing the color of cactus without adding pigment. Its purpose is to provide a method of manufacturing.

The present invention is a method for producing a transparent soap,

A method of preparing a transparent soap containing a powdered palm cactus is prepared by adding 2 to 10% by weight of palm cactus powder to the transparent soap base, dissolving it by heating, and adding 0.1 to 0.5% by weight of fragrance components. It is characterized by.

Referring to the present invention in more detail as follows.

The present invention is to add a sugar form of a single or a mixture selected from glucose and sorbitol to the palm cactus having a medicinal component related to the skin aging suppression by adding a powder form to the transparent soap base by adding a powder form to the transparent soap base, The present invention relates to a method for producing a transparent soap containing the palm cactus in the form of powder having an antioxidant effect, a tyrosinase inhibitory effect, and an antiallergic effect.

Hereinafter, the method for preparing the transparent soap containing the palm cactus powder according to the present invention will be described in more detail.

The first step is to prepare a transparent soap base as follows.

17 to 22% by weight of coconut fatty acid, 21 to 26% by weight of palm oil fatty acid, 10 to 15% by weight of 50% sodium hydroxide, 23 to 33% by weight of triethanolamine, 10 to 15% by weight of sorbitol and 6 to 20% of purified water in the reaction vessel. 8 wt% is added, heated with stirring at a temperature of 80 to 100 ° C., and then cooled to dry aging in the shade when complete transparency is obtained.

The second step is to prepare a palm cactus raw powder as follows.

First, the stem or fruit of the palm cactus is washed with purified water, cut with chopper, and freeze-dried in a freeze dryer. Then, the dried palm cactus stem or fruit is finely pulverized with a mixer, in which thorns and the like present in the powder can be removed using a sieve (mesh inner diameter: about 200 nm).

The present invention is to add a 40 to 60% by weight of glucose and sorbitol (sorbitol) mixture of sugar components to the palm cactus powder in order to completely mix the cactus powder in the clear soap base and remove the viscosity of the cactus Another feature is to prepare a raw material powder to be added to the base. At this time, when added below the range of the cactus unique strong viscosity of the cactus cactus powder does not make a perfect mixture in the base of the transparent soap, it is agglomerated into a small lump on the transparent soap to reduce the commerciality of the transparent soap. The viscous mass may be suppressed by adding an appropriate amount of water to the cactus powder, but in this case, there is a problem in that the soap recedes. On the other hand, if it exceeds the above range there is a disadvantage in that the amount of the active ingredient cactus included in the soap is reduced.

The third step is a process for preparing a transparent soap containing the cactus raw powder.

The transparent soap base prepared above is placed in a reaction vessel, heated and completely dissolved, and then 2-10 wt% of the palm cactus raw material powder is added to the transparent soap base, followed by heating and stirring at a temperature of 70 to 80 ° C. At this time, if the addition of less than 2% by weight of the cactus peculiar efficacy and color does not appear, on the other hand, when the cactus powder is added to more than 10% by weight in the transparent soap base, the transparency of the soap is not preferred is not preferred .

According to the present invention, when palm cactus raw material powder is completely dissolved completely, 0.1 to 0.5% by weight of fragrance component is added, poured into a molding machine, cooled to room temperature, dried, and polished and packaged according to a conventional soap processing method. The present invention is completed by (wrapping).

The transparent soap containing the palm cactus powder according to the present invention has a pH of 9.0 to 9.5, a 10% solution of acidity, and contains 10 to 13% by weight of water and 45 to 50% by weight of fat.

On the other hand, palm cactus stem and fruit used in the preparation of the transparent soap according to the present invention has an antioxidant effect, a tyrosinase inhibitory effect and an antiallergic effect showing a whitening effect.

Antioxidative effect of palm cactus stem according to the present invention can be represented by a radical scavenging effect using a DPPH reagent, DPPH is a material having a stable free radical having a dark purple color has a strong UV absorbance at 518 nm, having an antioxidant effect There is a characteristic in which the absorbance of the wavelength region is lost by the phenolic substance. Therefore, it is possible to know the change in absorbance of the palm cactus stem using the DPPH solution, and the antioxidant activity may be indicated according to the change in absorbance. The antioxidant effect indicates the difference in absorbance (ΔA) from the control group, and the larger the value of ΔA, the higher the antioxidant activity. Therefore, since the polyphenol-based material contained in a large amount in the cactus according to the present invention affects the absorbance of the DPPH solution, the value of ΔA of the palm cactus stem is 0.7 to 0.8, indicating a high antioxidant effect.

In addition, the whitening effect of palm cactus stem according to the present invention is determined by the inhibition of tyrosinase enzyme of the extract extracted with methanol. Tyrosine is converted to L-DOPA by tyrosinase enzyme and the amount of L-dopa production can be measured by quantifying the wavelength of 475 nm. In other words, the absorbance at 475 nm before and after the culture was measured to show the degree of inhibition. The methanol extract of the substance was shown to inhibit the production of melanin associated with skin aging.

In addition, by extracting the methanol soluble components from the fruit and stem of the palm cactus of the present invention, allergic reactions of mice through in vivo (passive cutaneous anaphylaxis, PCA) through the antiallergic effect You can check it.

Thus, by using the cactus stem powder according to the present invention in the production of a transparent soap, it is possible to produce a functional beauty soap that is expected to improve skin beauty and disease prevention. In addition, it can be applied as a tourist product of character products with local characteristics in soaps or photographs with local characteristics by using the characteristics of transparent soaps having the unique color of cactus stem and fruit without adding coloring.

Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited thereto.

Preparation Example 1 Preparation of Transparent Soap Base

Next, a transparent soap base was prepared using the composition and content of Table 1. Coconut fatty acid, palm oil fatty acid, 50% sodium hydroxide solution, triethanolamine, sorbitol, purified water and a small amount of eddiedium sodium (EDTA, 4Na) and BHT (BHT) are added to the reaction vessel until it is completely transparent at 90 ° C. After heating while the reaction was cooled and dried in the shade dry aged to prepare a transparent soap base.

Preparation Example 2 Preparation of Palm Cactus Raw Powder

After washing the palm cactus stem portion, it was lyophilized in a freeze dryer, and the freeze-dried cactus stem was ground using a blender. The coarse grains in the pulverized powder were removed using a fine sieve (mesh inner diameter: 200 nm). 10 g of the pulverized fine powder was added with 10 g of glucose, and pulverized again using a blender as a raw cactus powder. In the case of fruit was prepared in the same manner.

Example 1 Preparation of Transparent Soap Containing Palm Cactus Powder

100 g of the transparent soap base prepared in the above preparation was dissolved in a beaker and heated to dissolve completely. 5 g of palm cactus raw powder was added to the soap solution, and then heated at 80 ° C. for 10 minutes to completely dissolve the cactus powder. . Then, 0.2 g of the fragrance component was added, transferred to a molding apparatus, cooled to room temperature, and processed according to a general processing method to prepare a transparent soap. Melting | fusing point of the said transparent soap became 65-70 degreeC.

Experimental Example 1

In order to investigate the effect of the transparent soap containing the palm cactus powder, the following experiment was performed on the stem and the fruit of the palm cactus.

① Antioxidant Activity Test

5 g of lyophilized palm cactus stem and fruit were dissolved in 250 ml of absolute methanol and stirred at room temperature for 24 hours. Insoluble solids were filtered out of the solution and the filtrate was concentrated using rotovap at 40 ° C. to obtain 0.73 g and 1.9 g of green solid state material, respectively.

Antioxidant activity was determined using the Blois method, which measures the radical scavenging effect using a DPPH (1,1-diphenyl-2-picrylhydrazyl) reagent. DPPH solution was prepared by dissolving about 20 mg of DPPH in 150 ml of ethanol. Then, 250 ml of DMSO was added to 600 µl of the prepared DPPH solution, and the ethanol was absorbed by UV-Visible at a wavelength of 518 nm of 0.94-0.97. After diluting with, shake for 10 seconds. The spectrophotometer used for the measurement used the UV-Visible spectrophotometer by KOTRON. 0.100 g of the sample extracted as powder was mixed with 10 ml of the solvent, and then sufficiently dissolved. 100 µl of the sample solution was added to 900 µl of the prepared DPPH, and the absorbance was measured after adjusting to a concentration of 1 mM. At this time, the absorbance decrease (ΔA) for the control at 518 nm as an antioxidant activity is shown in Table 2 the results.

② Tyrosinase inhibitory effect test (whitening effect measurement)

Tyrosinase inhibitory effect was measured using the dopachrome method as one of the means for measuring the whitening effect of the palm cactus. 150 μl of mushroom tyrosinase (150 units, Sigma Chemical Co.), 225 μl of L-tyrosine (2.5 mM), 0.4 M HEPES [4- (2-hydroxyethyl) -1-piperazineethanesulfonic acid] buffer After mixing 225 µl of the solution (pH 6.8) and 300 µl of the ethanol solution or 1 mg / mL of the specimen solution, the mixture was incubated for 15 minutes and the absorbance at 475 mm before and after incubation was measured, respectively. The measurement was performed using a Hewlett Packard (Model HP8452 diode array spectrophotometer), the degree of tyrosinase inhibition was measured as shown in Equation 1 shown in Table 3 below.

A: Absorbance before incubation of the specimen solution.

B: Absorbance after incubation of the specimen solution.

C: Absorbance before incubation of the reference solution.

D: absorbance after incubation of the reference solution.

③ anti-allergic effect test

In order to measure the antiallergic effect of the palm cactus, male Wistar experiment with 250 mg to 300 g of Ovalbumin (Grade IV, Sigma) 1 mg / rat and 0.7 ml of Pertussis antigen (Difco) Intramuscular and intraperitoneal injections were administered to rats (Wistar rats), and after 12 days, blood was collected from the abdominal aorta and serum was separated and used. PCA titer of this serum was measured and diluted to a concentration such that Evans blue diffusion diameter was between 10 and 20 mm. The serum was prepared by cutting the hair of the stomach of Wistar rats (180-230g, Japan B & K), and then diluting the serum (dilution in phosphate-buffered saline solution, pH 7.4) at 0.1 ml in two-fold dilution series. After 48 hours, 5 mg of ovalbumin was mixed with Evans blue dissolved in 0.5 ml of saline (1%) and administered to the tail vein. After 30 minutes of Ovalbumin administration, the skin was peeled off and subjected to a manual skin sensitization test (PCA) measuring the diffusion diameter of Evans blue. The results are shown in Table 4 below.

According to the results of Table 3, the cactus stem is less sensitive to the PCA than the cactus fruit, it can be seen that the cactus fruit has a higher anti-allergic effect.

Experimental Example 2 Preparation of Transparent Soap with Inserted Photo

50 g of a soap solution containing hot cactus in a hot state obtained in the preparation example was poured into a molding apparatus, and then cooled at room temperature for 10 minutes. After confirming that the solidification was partially, a cactus photograph or a solid symbol specific to Jeju Island was placed in a molding apparatus, and 50 g of a soap solution was added thereto and cooled at room temperature. After complete solidification, the soap was polished according to a general soap processing method to prepare a transparent soap containing the palm cactus powder, the contents of which were clearly visible.

As described above, the present invention is added to the sugar cactus powder alone or a mixture of sugars selected from glucose and sorbitol as a sugar component to remove the unique viscosity of the cactus and by adding the cactus powder to the conventional transparent soap base, It can be used as a functional beauty soap that improves beauty and prevents disease, and it is a colorless hypoallergenic soap that adds the color and scent of cactus without adding pigments. Can be used for tourism products.

Claims (4)

In the method for producing a transparent soap by adding the palm cactus raw material powder to the transparent soap base, After adding 2 to 10% by weight of palm cactus raw powder to the transparent soap base, dissolving it by heating and adding 0.1 to 0.5% by weight of fragrance component, the palm cactus raw powder is glucose to palm cactus powder. , 40 to 60% by weight of sorbitol or a mixture thereof and pulverized with a mixer to remove the viscous, characterized in that the method for producing a transparent soap containing a palm cactus in the form of a powder. According to claim 1, wherein the soap base is 17 to 22% by weight coconut fatty acid, 21 to 26% by weight palm oil fatty acid, 10 to 15% by weight 50% sodium hydroxide, 23 to 33% by weight triethanolamine, sorbitol 10 A method for producing a transparent soap containing powdered palm cactus, characterized in that it is produced by heating 15-15% by weight and 6-8% by weight of purified water at 80-100 ° C., followed by cooling. delete delete