JPS6338475B2 - - Google Patents
Info
- Publication number
- JPS6338475B2 JPS6338475B2 JP57046867A JP4686782A JPS6338475B2 JP S6338475 B2 JPS6338475 B2 JP S6338475B2 JP 57046867 A JP57046867 A JP 57046867A JP 4686782 A JP4686782 A JP 4686782A JP S6338475 B2 JPS6338475 B2 JP S6338475B2
- Authority
- JP
- Japan
- Prior art keywords
- polyvinyl chloride
- acrylate
- dye
- pattern
- cured film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 21
- 239000004800 polyvinyl chloride Substances 0.000 claims description 21
- 239000004014 plasticizer Substances 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000000859 sublimation Methods 0.000 claims description 5
- 230000008022 sublimation Effects 0.000 claims description 5
- 239000000975 dye Substances 0.000 description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 10
- 238000000034 method Methods 0.000 description 7
- 238000007639 printing Methods 0.000 description 7
- -1 2-ethylhexyl Chemical group 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N Diethylhexyl phthalate Natural products CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000010345 tape casting Methods 0.000 description 2
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- ISAOCJYIOMOJEB-UHFFFAOYSA-N desyl alcohol Natural products C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- DJDSLBVSSOQSLW-UHFFFAOYSA-N mono(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(O)=O DJDSLBVSSOQSLW-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 238000007763 reverse roll coating Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
- Decoration By Transfer Pictures (AREA)
- Coloring (AREA)
Description
【発明の詳細な説明】
本発明は可塑剤を含有するポリ塩化ビニル成形
品上への染料転写方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for transferring dyes onto polyvinyl chloride moldings containing plasticizers.
一般に顔料インキによる印刷よりも染料インキ
による印刷の方が美麗で鮮明な着色模様を与える
が、可塑剤を含む軟質ポリ塩化ビニル成形品の場
合、その表面に染料インキにて着色若しくは絵付
けを行なうと、可塑剤の作用によつて染料が経時
的に樹脂中に拡散し、絵柄模様ににじみが生じ、
不鮮明となる。更に、軟質ポリ塩化ビニルの長尺
のシートやフイルムの場合には、印刷時に伸縮す
るので、多色印刷の場合に柄ずれが起こりやすい
問題がある。このように従来、軟質ポリ塩化ビニ
ル成形品は、染料インキを用いて鮮明で柄ずれの
ない着色模様若しくは絵付けを施すことが困難で
あつた。 In general, printing with dye ink gives a more beautiful and clear colored pattern than printing with pigment ink, but in the case of soft polyvinyl chloride molded products containing plasticizers, the surface is colored or painted with dye ink. Then, due to the action of the plasticizer, the dye diffuses into the resin over time, causing bleeding in the design.
It becomes unclear. Furthermore, in the case of a long sheet or film of soft polyvinyl chloride, it expands and contracts during printing, so there is a problem in that patterns are likely to be misaligned when printing in multiple colors. As described above, in the past, it has been difficult to apply vivid colored patterns or decorations using dye ink to soft polyvinyl chloride molded products without pattern deviation.
本考案は上記に鑑みてなされたものであつて、
可塑剤を含有するポリ塩化ビニル成形品に染料に
より鮮明で柄ずれの起こらない染料転写方法を提
供することを目的とする。 This invention was made in view of the above, and
The purpose of the present invention is to provide a method for transferring dye onto a polyvinyl chloride molded article containing a plasticizer, which is clear and does not cause pattern shift.
本発明による可塑剤を含有するポリ塩化ビニル
成形品上への染料転写方法は、可塑剤を含有する
ポリ塩化ビニル成形品上に紫外線硬化性樹脂の硬
化皮膜を形成し、この皮膜上に昇華性染料転写紙
を重ねて加圧加熱することを特徴とする。 The method of dye transfer onto a polyvinyl chloride molded product containing a plasticizer according to the present invention involves forming a cured film of an ultraviolet curable resin on the polyvinyl chloride molded product containing a plasticizer, and applying a sublimation property on this film. It is characterized by stacking dye transfer papers and heating them under pressure.
紫外線硬化性樹脂は既に種々の組成のものが市
販されており、通常、エポキシアクリレート、ポ
リエステルウレタンアクリレート、ポリエステル
アクリレート等の重合性オリゴマー、２−エチル
ヘキシル（メタ）アクリレート、２−ヒドロキシ
エチル（メタ）アクリレート、２−ヒドロキシプ
ロピル（メタ）アクリレート、１，３−ブタンジ
オールジ（メタ）アクリレート、１，６−ヘキサ
ンジオールジ（メタ）アクリレート、ジエチレン
グリコールジ（メタ）アクリレート、ネオペンチ
ルグリコールジ（メタ）アクリレート、トリメチ
ロールプロパントリ（メタ）アクリレート、ペン
タエリスリトールトリ（メタ）アクリレート等の
重合性モノマー、アセトフエノン、２，２−ジエ
トキシアセトフエノン、ベンゾフエノン、ミヒラ
ーケトン、ベンジル、ベンゾインアルキルエーテ
ル、ベンジルメチルケタール、チオキサン等の光
重合開始剤及び必要に応じて光重合開始助剤等か
らなる液状組成物である。本発明においては重合
性オリゴマーとしてポリエステルウレタンアクリ
レートを含有する紫外線硬化性樹脂がその硬化皮
膜への染料転写性にすぐれるところから特に好ま
しく用いられる。 UV-curable resins are already commercially available in various compositions, and usually include polymerizable oligomers such as epoxy acrylate, polyester urethane acrylate, and polyester acrylate, 2-ethylhexyl (meth)acrylate, and 2-hydroxyethyl (meth)acrylate. , 2-hydroxypropyl (meth)acrylate, 1,3-butanediol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, diethylene glycol di(meth)acrylate, neopentyl glycol di(meth)acrylate, Polymerizable monomers such as trimethylolpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, acetophenone, 2,2-diethoxyacetophenone, benzophenone, Michler's ketone, benzyl, benzoin alkyl ether, benzyl methyl ketal, thioxane, etc. This is a liquid composition consisting of a photopolymerization initiator and, if necessary, a photopolymerization initiation aid. In the present invention, an ultraviolet curable resin containing polyester urethane acrylate as a polymerizable oligomer is particularly preferably used because of its excellent dye transferability to the cured film.
本発明においては、ポリ塩化ビニル成形品上に
上記のような紫外線硬化性樹脂を厚み１〜100μ
程度に塗布し、この塗布面に紫外線を照射して硬
化皮膜を形成させる。塗布方法は特に限定され
ず、グラビアコート、ナチユラルコート、リバー
スロールコート、ナイフコート、バーコート等に
よればよい。 In the present invention, the above-mentioned ultraviolet curable resin is applied to a thickness of 1 to 100 μm on a polyvinyl chloride molded product.
The coated surface is then irradiated with ultraviolet rays to form a cured film. The coating method is not particularly limited, and gravure coating, natural coating, reverse roll coating, knife coating, bar coating, etc. may be used.
本発明において用いる昇華性染料転写紙も既に
知られている。通常、紙のような基材シートに所
要の絵柄模様が昇華性染料インキによつて印刷さ
れて形成されており、昇華性染料としては一般に
分散染料が用いられている。 Sublimable dye transfer papers used in the present invention are also already known. Usually, a desired pattern is printed on a base sheet such as paper using sublimable dye ink, and disperse dyes are generally used as the sublimable dye.
このような昇華性染料転写紙の印刷インキ面を
前記紫外線硬化性樹脂の硬化皮膜上に重ね、転写
紙の種類にもよるが、通常、加圧しながら60〜
260℃程度の温度で数十秒乃至数分加熱すること
により、転写紙の着色模様が硬化皮膜上に転写さ
れるので、基材シートを剥離すれば、硬化皮膜上
に絵付けが施される。 The printed ink side of such sublimation dye transfer paper is placed on the cured film of the ultraviolet curable resin, and is usually heated for 60 to 60 minutes while applying pressure, although it depends on the type of transfer paper.
By heating at a temperature of about 260°C for several tens of seconds to several minutes, the colored pattern on the transfer paper is transferred onto the cured film, so when the base sheet is peeled off, the painting can be applied on the cured film. .
尚、本発明において、ポリ塩化ビニルには塩化
ビニルの単独重合体のほか、塩化ビニル−酢酸ビ
ニル重合体のような塩化ビニルを含有する共重合
体及び塩化ビニル単独重合体と他の重合体との混
合物をも含むものとし、これら樹脂が含む可塑剤
は特に限定されない。可塑剤としては例えばジ−
２−エチルヘキシルフタレート、ジノルマルオク
チルフタレート、ジヘキシルフタレート、ジイソ
デシルフタレート等のフタル酸エステル系可塑剤
のほか、リン酸エステル系可塑剤、ポリエステル
系可塑剤、トリメリツト酸エステル系可塑剤、エ
ポキシ化大豆油等が挙げられる。軟質ポリ塩化ビ
ニルは、通常、このような可塑剤の一種又は二種
以上をポリ塩化ビニル100重量部について１〜80
重量部含有している。また、金属石ケン類、スズ
化合物、亜リン酸エステル系化合物等の安定剤を
適宜量含有していてもよい。本発明の方法はこの
ような通常の軟質ポリ塩化ビニル成形品に好適に
適用することができる。 In addition, in the present invention, polyvinyl chloride includes not only vinyl chloride homopolymers, but also copolymers containing vinyl chloride such as vinyl chloride-vinyl acetate polymers, and vinyl chloride homopolymers and other polymers. The plasticizer contained in these resins is not particularly limited. Examples of plasticizers include di-
In addition to phthalate ester plasticizers such as 2-ethylhexyl phthalate, di-normal octyl phthalate, dihexyl phthalate, and diisodecyl phthalate, phosphate ester plasticizers, polyester plasticizers, trimellitic acid ester plasticizers, epoxidized soybean oil, etc. can be mentioned. Soft polyvinyl chloride usually contains one or more of these plasticizers in an amount of 1 to 80 parts by weight per 100 parts by weight of polyvinyl chloride.
Contains parts by weight. Further, an appropriate amount of stabilizers such as metal soaps, tin compounds, phosphite compounds, etc. may be contained. The method of the present invention can be suitably applied to such ordinary flexible polyvinyl chloride molded products.
本発明の方法は、以上のように可塑剤を含有す
るポリ塩化ビニル成形品上に予め紫外線硬化性樹
脂を塗布し、紫外線照射により硬化皮膜を形成さ
せ、この硬化皮膜上に染料を転写するので、硬化
皮膜によつて染料が可塑剤の含まれるポリ塩化ビ
ニル樹脂内に拡散することが阻止され、この結
果、硬化皮膜上の絵柄にはにじみが生じず、鮮明
であり、かくして、従来は困雑であつた軟質ポリ
塩化ビニル成形品への塗料による美麗且つ鮮明な
絵付けを可能にするものである。更に、本発明方
法によれば、染料は転写時に硬化皮膜表面層内部
にまで昇華、拡散していることが認められ、この
ため、転写された絵柄模様は耐摩耗性にすぐれ、
表面摩耗によつても絵柄が鮮明に保持され、ま
た、硬化皮膜のすぐれた耐擦傷性、耐汚染性、耐
薬品性、耐熱性と相俟つて、高品質の絵付けポリ
塩化ビニル成形品を得ることができる。 In the method of the present invention, as described above, an ultraviolet curable resin is applied in advance onto a polyvinyl chloride molded article containing a plasticizer, a cured film is formed by ultraviolet irradiation, and a dye is transferred onto this cured film. The cured film prevents the dye from diffusing into the polyvinyl chloride resin containing the plasticizer, and as a result, the pattern on the cured film does not bleed and is clear, which is difficult to achieve in the past. This makes it possible to paint beautiful and clear pictures on rough soft polyvinyl chloride molded products. Furthermore, according to the method of the present invention, it has been observed that the dye sublimes and diffuses into the surface layer of the cured film during transfer, and therefore, the transferred pattern has excellent abrasion resistance.
The pattern remains clear even when the surface is abraded, and the cured film's excellent scratch resistance, stain resistance, chemical resistance, and heat resistance make it possible to produce high-quality painted polyvinyl chloride molded products. Obtainable.
また、特に成形品が長尺シートやフイルムの多
色印刷においても、基材シートである紙に予め多
色印刷を施し、この転写紙によりシートやフイル
ムに転写するので、ポリ塩化ビニルシートやフイ
ルムに直接に多色印刷を施す場合と異なり、絵付
けされた模様には柄ずれが生じない。 In addition, especially in multicolor printing of molded products such as long sheets or films, multicolor printing is applied to the paper base sheet in advance and transferred to the sheet or film using this transfer paper. Unlike when multicolor printing is applied directly to the surface, there is no pattern shift in the painted pattern.
実施例 １
樹脂100重量部についてジオクチルフタレート
35重量部を含有する厚さ0.20mmのポリ塩化ビニル
シート表面に、ポリエステルウレタンアクリレー
ト60重量％、トリメチルロールプロパントリアク
リレート20重量％、２−エチルヘキシルアクリレ
ート15重量％及びベンゾフエノン５重量％からな
る紫外線硬化性樹脂をナイフコーテイングにより
厚さ50μに塗布した後、80W／cmの高圧水銀灯を
５秒間照射して硬化させた。Example 1 Dioctyl phthalate per 100 parts by weight of resin
On the surface of a 0.20 mm thick polyvinyl chloride sheet containing 35 parts by weight, ultraviolet curing consisting of 60% by weight of polyester urethane acrylate, 20% by weight of trimethylolpropane triacrylate, 15% by weight of 2-ethylhexyl acrylate and 5% by weight of benzophenone. The resin was applied to a thickness of 50μ by knife coating, and then cured by irradiation with a high-pressure mercury lamp of 80W/cm for 5 seconds.
次に、昇華性染料インキを用いてグラビア印刷
にて紙に３色刷りの着色模様に印刷した転写紙を
用意し、この転写紙を上記硬化皮膜上に重ね、連
続加熱圧着装置にて165℃、３Kg／cm2の条件で40
秒間加圧加熱した後、基材紙を剥離した。 Next, prepare a transfer paper printed with a three-color colored pattern on paper using gravure printing using sublimation dye ink, layer this transfer paper on the above-mentioned cured film, and heat it at 165°C using a continuous heat-pressing device. 40 under the condition of 3Kg/ cm2
After pressurizing and heating for seconds, the base paper was peeled off.
このようにして得られたポリ塩化ビニルシート
は鮮明且つ美麗な色彩で柄ずれのない絵柄を有
し、また、1000ｇ荷重で研摩紙Ｈ−22を用いてテ
ーパー摩耗試験機により50回転の摩耗試験を行な
つた後も、絵柄は鮮明に保持されていた。 The polyvinyl chloride sheet obtained in this way has a pattern with clear and beautiful colors and no pattern deviation, and was also subjected to an abrasion test of 50 revolutions using a taper abrasion tester using abrasive paper H-22 with a load of 1000g. Even after this process, the pattern remained clear.
実施例 ２
表面層が樹脂100重量部についてジオクチルフ
タレート80重量部含有する総厚さ1.0mmのポリ塩
化ビニルレザー表面に、ポリエステルウレタンア
クリレート62重量％、１，６−ヘキサンジオール
ジアクリレート20重量％、２−エチルヘキシルア
クリレート10重量％及びベンゾインエチルエーテ
ル８重量％からなる紫外線硬化性樹脂を100メツ
シユロールのグラビアコーテイングにより厚さ
10μに塗布した後、120W／cmの高圧水銀灯を３
秒間照射して硬化させた。Example 2 62% by weight of polyester urethane acrylate, 20% by weight of 1,6-hexanediol diacrylate, A thickness of 100 mesh rolls of ultraviolet curable resin consisting of 10% by weight of 2-ethylhexyl acrylate and 8% by weight of benzoin ethyl ether was gravure coated.
After applying 10μ, apply 120W/cm high pressure mercury lamp for 3 times.
It was cured by irradiation for seconds.
次に、昇華性染料インキを用いてシルクスクリ
ーン印刷にて基材紙５色刷りの着色模様を印刷し
た転写紙を用意し、この転写紙を上記硬化皮膜上
に重ね、連続加熱加圧着装置にて140℃、１Kg／
cm2の条件で１分間加熱した後、基材紙を剥離し
た。 Next, a transfer paper with a five-color colored pattern printed on the base paper using sublimation dye ink is prepared by silk screen printing, this transfer paper is layered on the cured film, and a continuous heating and pressure bonding machine is used. 140℃, 1Kg/
After heating for 1 minute at cm2 , the base paper was peeled off.
このようにして得られたポリ塩化ビニルシート
は鮮明且つ美麗な色採で柄ずれのない絵柄を有し
ていた。 The polyvinyl chloride sheet thus obtained had a pattern with clear and beautiful colors and no pattern deviation.
Claims (1)
紫外線硬化性樹脂の硬化皮膜を形成し、この皮膜
上に昇華性染料転写紙を重ねて加圧加熱すること
を特徴とするポリ塩化ビニル成形品上への染料転
写方法。1. A polyvinyl chloride molded product that is characterized by forming a cured film of an ultraviolet curable resin on a polyvinyl chloride molded product containing a plasticizer, overlaying sublimation dye transfer paper on this film and heating it under pressure. How to transfer dye on top.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57046867A JPS58162374A (en) | 1982-03-23 | 1982-03-23 | Transfering method of dye to polyvinyl chloride molding |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57046867A JPS58162374A (en) | 1982-03-23 | 1982-03-23 | Transfering method of dye to polyvinyl chloride molding |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58162374A JPS58162374A (en) | 1983-09-27 |
| JPS6338475B2 true JPS6338475B2 (en) | 1988-07-29 |
Family
ID=12759284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57046867A Granted JPS58162374A (en) | 1982-03-23 | 1982-03-23 | Transfering method of dye to polyvinyl chloride molding |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58162374A (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS615992A (en) * | 1984-06-20 | 1986-01-11 | Matsushita Electric Ind Co Ltd | Fixing method |
| KR900002183B1 (en) * | 1985-07-15 | 1990-04-02 | 마쯔시다덴기산교 가부시기가이샤 | Transfer type thermal recording receiving body |
| JPS6223790A (en) * | 1985-07-24 | 1987-01-31 | Matsushita Electric Ind Co Ltd | Image-receiving body for thermal transfer recording |
| JPS62158095A (en) * | 1986-01-07 | 1987-07-14 | Matsushita Electric Ind Co Ltd | Image-receiving material for thermal transfer recording |
| JPH0638099Y2 (en) * | 1988-08-11 | 1994-10-05 | 艶金興業株式会社 | Ceramic with picture pattern |
| WO2000032420A1 (en) * | 1998-12-03 | 2000-06-08 | Akzo Nobel N.V. | Process for the preparation of a decorated substrate |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51120812A (en) * | 1975-04-14 | 1976-10-22 | Sumitomo Chemical Co | Method of transfer dying |
-
1982
- 1982-03-23 JP JP57046867A patent/JPS58162374A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51120812A (en) * | 1975-04-14 | 1976-10-22 | Sumitomo Chemical Co | Method of transfer dying |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58162374A (en) | 1983-09-27 |
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