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JPS6232195A - 漂白性向上剤 - Google Patents

漂白性向上剤

Info

Publication number
JPS6232195A
JPS6232195A JP60172073A JP17207385A JPS6232195A JP S6232195 A JPS6232195 A JP S6232195A JP 60172073 A JP60172073 A JP 60172073A JP 17207385 A JP17207385 A JP 17207385A JP S6232195 A JPS6232195 A JP S6232195A
Authority
JP
Japan
Prior art keywords
bleaching
acid
present
fibers
improver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP60172073A
Other languages
English (en)
Other versions
JPS64502B2 (ja
Inventor
京近　直喜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to JP60172073A priority Critical patent/JPS6232195A/ja
Priority to CN86107481A priority patent/CN1007523B/zh
Priority to DE19863626361 priority patent/DE3626361A1/de
Priority to IT21410/86A priority patent/IT1197844B/it
Priority to KR1019860006465A priority patent/KR910002919B1/ko
Priority to GB8619058A priority patent/GB2178769B/en
Publication of JPS6232195A publication Critical patent/JPS6232195A/ja
Publication of JPS64502B2 publication Critical patent/JPS64502B2/ja
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B22D11/0605—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by two belts, e.g. Hazelett-process
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B61—RAILWAYS
    • B61B—RAILWAY SYSTEMS; EQUIPMENT THEREFOR NOT OTHERWISE PROVIDED FOR
    • B61B13/00—Other railway systems
    • B61B13/12—Systems with propulsion devices between or alongside the rails, e.g. pneumatic systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B22D11/0637—Accessories therefor
    • B22D11/068—Accessories therefor for cooling the cast product during its passage through the mould surfaces
    • B22D11/0685—Accessories therefor for cooling the cast product during its passage through the mould surfaces by cooling the casting belts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/14—Closures
    • B22D41/22—Closures sliding-gate type, i.e. having a fixed plate and a movable plate in sliding contact with each other for selective registry of their openings
    • B22D41/28—Plates therefor
    • B22D41/34—Supporting, fixing or centering means therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B25—HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
    • B25C—HAND-HELD NAILING OR STAPLING TOOLS; MANUALLY OPERATED PORTABLE STAPLING TOOLS
    • B25C5/00—Manually operated portable stapling tools; Hand-held power-operated stapling tools; Staple feeding devices therefor
    • B25C5/02—Manually operated portable stapling tools; Hand-held power-operated stapling tools; Staple feeding devices therefor with provision for bending the ends of the staples on to the work
    • B25C5/0285—Hand-held stapling tools, e.g. manually operated, i.e. not resting on a working surface during operation
    • B25C5/0292—Hand-held stapling tools, e.g. manually operated, i.e. not resting on a working surface during operation with the objects to be stapled together introduced perpendicularly to the longitudinal axis of the tool in an opening formed by an anvil and a plunger
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B27K3/0278—Processes; Apparatus involving an additional treatment during or after impregnation
    • B27K3/0292—Processes; Apparatus involving an additional treatment during or after impregnation for improving fixation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B27K3/08—Impregnating by pressure, e.g. vacuum impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/16—Inorganic impregnating agents
    • B27K3/22—Compounds of zinc or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/001—Heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/30—Extrusion nozzles or dies
    • B29C48/305—Extrusion nozzles or dies having a wide opening, e.g. for forming sheets
    • B29C48/307—Extrusion nozzles or dies having a wide opening, e.g. for forming sheets specially adapted for bringing together components, e.g. melts within the die
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41F—PRINTING MACHINES OR PRESSES
    • B41F13/00—Common details of rotary presses or machines
    • B41F13/08—Cylinders
    • B41F13/10—Forme cylinders
    • B41F13/12—Registering devices
    • B41F13/14—Registering devices with means for displacing the cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41F—PRINTING MACHINES OR PRESSES
    • B41F13/00—Common details of rotary presses or machines
    • B41F13/08—Cylinders
    • B41F13/10—Forme cylinders
    • B41F13/12—Registering devices
    • B41F13/16—Registering devices with means for displacing the printing formes on the cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60B—VEHICLE WHEELS; CASTORS; AXLES FOR WHEELS OR CASTORS; INCREASING WHEEL ADHESION
    • B60B39/00—Increasing wheel adhesion
    • B60B39/003—Vehicle mounted non-skid chains actuated by centrifugal force
    • B60B39/006—Vehicle mounted non-skid chains actuated by centrifugal force characterised by a control system for the actuation of the rotating chain wheel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60W—CONJOINT CONTROL OF VEHICLE SUB-UNITS OF DIFFERENT TYPE OR DIFFERENT FUNCTION; CONTROL SYSTEMS SPECIALLY ADAPTED FOR HYBRID VEHICLES; ROAD VEHICLE DRIVE CONTROL SYSTEMS FOR PURPOSES NOT RELATED TO THE CONTROL OF A PARTICULAR SUB-UNIT
    • B60W10/00—Conjoint control of vehicle sub-units of different type or different function
    • B60W10/02—Conjoint control of vehicle sub-units of different type or different function including control of driveline clutches
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60W—CONJOINT CONTROL OF VEHICLE SUB-UNITS OF DIFFERENT TYPE OR DIFFERENT FUNCTION; CONTROL SYSTEMS SPECIALLY ADAPTED FOR HYBRID VEHICLES; ROAD VEHICLE DRIVE CONTROL SYSTEMS FOR PURPOSES NOT RELATED TO THE CONTROL OF A PARTICULAR SUB-UNIT
    • B60W10/00—Conjoint control of vehicle sub-units of different type or different function
    • B60W10/04—Conjoint control of vehicle sub-units of different type or different function including control of propulsion units
    • B60W10/06—Conjoint control of vehicle sub-units of different type or different function including control of propulsion units including control of combustion engines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60W—CONJOINT CONTROL OF VEHICLE SUB-UNITS OF DIFFERENT TYPE OR DIFFERENT FUNCTION; CONTROL SYSTEMS SPECIALLY ADAPTED FOR HYBRID VEHICLES; ROAD VEHICLE DRIVE CONTROL SYSTEMS FOR PURPOSES NOT RELATED TO THE CONTROL OF A PARTICULAR SUB-UNIT
    • B60W10/00—Conjoint control of vehicle sub-units of different type or different function
    • B60W10/10—Conjoint control of vehicle sub-units of different type or different function including control of change-speed gearings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60W—CONJOINT CONTROL OF VEHICLE SUB-UNITS OF DIFFERENT TYPE OR DIFFERENT FUNCTION; CONTROL SYSTEMS SPECIALLY ADAPTED FOR HYBRID VEHICLES; ROAD VEHICLE DRIVE CONTROL SYSTEMS FOR PURPOSES NOT RELATED TO THE CONTROL OF A PARTICULAR SUB-UNIT
    • B60W10/00—Conjoint control of vehicle sub-units of different type or different function
    • B60W10/10—Conjoint control of vehicle sub-units of different type or different function including control of change-speed gearings
    • B60W10/11—Stepped gearings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60W—CONJOINT CONTROL OF VEHICLE SUB-UNITS OF DIFFERENT TYPE OR DIFFERENT FUNCTION; CONTROL SYSTEMS SPECIALLY ADAPTED FOR HYBRID VEHICLES; ROAD VEHICLE DRIVE CONTROL SYSTEMS FOR PURPOSES NOT RELATED TO THE CONTROL OF A PARTICULAR SUB-UNIT
    • B60W30/00—Purposes of road vehicle drive control systems not related to the control of a particular sub-unit, e.g. of systems using conjoint control of vehicle sub-units
    • B60W30/18—Propelling the vehicle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B55/00—Preserving, protecting or purifying packages or package contents in association with packaging
    • B65B55/02—Sterilising, e.g. of complete packages
    • B65B55/022—Sterilising, e.g. of complete packages of flexible containers having a filling and dispensing spout, e.g. containers of the "bag-in-box"-type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B7/00—Closing containers or receptacles after filling
    • B65B7/02—Closing containers or receptacles deformed by, or taking-up shape, of, contents, e.g. bags, sacks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D33/00—Details of, or accessories for, sacks or bags
    • B65D33/16—End- or aperture-closing arrangements or devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • B65D75/52—Details
    • B65D75/58—Opening or contents-removing devices added or incorporated during package manufacture
    • B65D75/5861—Spouts
    • B65D75/5872—Non-integral spouts
    • B65D75/5877—Non-integral spouts connected to a planar surface of the package wall
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/70—Pressure relief devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65G—TRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G47/00—Article or material-handling devices associated with conveyors; Methods employing such devices
    • B65G47/52—Devices for transferring articles or materials between conveyors i.e. discharging or feeding devices
    • B65G47/60—Devices for transferring articles or materials between conveyors i.e. discharging or feeding devices to or from conveyors of the suspended, e.g. trolley, type
    • B65G47/61—Devices for transferring articles or materials between conveyors i.e. discharging or feeding devices to or from conveyors of the suspended, e.g. trolley, type for articles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/003—Phosphorus
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/02—Preparation of phosphorus
    • C01B25/027—Preparation of phosphorus of yellow phosphorus
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/18—Phosphoric acid
    • C01B25/20—Preparation from elemental phosphorus or phosphoric anhydride
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/14—Aluminium oxide or hydroxide from alkali metal aluminates
    • C01F7/144—Aluminium oxide or hydroxide from alkali metal aluminates from aqueous aluminate solutions by precipitation due to cooling, e.g. as part of the Bayer process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/14—Aluminium oxide or hydroxide from alkali metal aluminates
    • C01F7/144—Aluminium oxide or hydroxide from alkali metal aluminates from aqueous aluminate solutions by precipitation due to cooling, e.g. as part of the Bayer process
    • C01F7/147—Apparatus for precipitation
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B7/00—Separation of mixtures of fats or fatty oils into their constituents, e.g. saturated oils from unsaturated oils
    • C11B7/0075—Separation of mixtures of fats or fatty oils into their constituents, e.g. saturated oils from unsaturated oils by differences of melting or solidifying points
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937—Stabilising agents
    • C11D3/394—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
    • C21D8/1222—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
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Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明はセルロース系繊維用漂白性向上剤に関する本の
である。更に詳しくは、セルロース系繊維の漂白浴に硬
度成分等の漂白阻害因子が含まれている場合にも、従来
以上の白皮、風合い、縫製性を付与できるセルロース系
繊維の漂白性向上剤に関するものである。
〔従来の技術〕
一般に、セルロース系繊維は精練後においてもなお繊維
中に天然色素が存在するので、この天然色素や更には二
次的に付着した着色物等を除去するために漂白操作がな
される。漂白の方法としては、過酸化漂白、塩素漂白、
亜塩素酸ナトリウム漂白などがあるが、なかでも過酸化
漂白は、繊維に損傷を与えることなく漂白が行なえ、操
作も簡単で、耐久性のある白さが得られることから一般
的に広く用いられている。
この過酸化漂白は、過酸化水素の分解によって生じる発
生期の酸累を利用してセルロース系繊維中の色素を酸化
分解させることによってなされるが、この酸化分解は、
…がアルカリ性である側の環境で行なわせる方が効率的
であるため、カセイソーダなどのアルカリ剤が併用さへ
更にアルカリ下での過酸化水素分解の安定化剤としてケ
イ酸ナトリウムも併用される。従って漂白液組成は、過
酸化水素、アルカリ（カセイソーダなど）、ケイ酸ナト
リウム（モル比で５ｉｎ２：　Ｎａ２Ｏ＝　２．５　：
　Ｉのものなど）から構成されることになる。このもの
を用いてセルロース系繊維の漂白を行なう際に使用する
水の硬度が高いと、ケイ酸ナトリウムが水の硬度成分と
結合してケイ酸カルシウムやケイ酸マグネシウムなどの
水に不溶性のケイ酸塩を生じ、これが繊維上に沈着して
布帛の白皮が向上せず、風合いも粗硬化し、更にはミシ
ン針との摩擦係数も大きくなって縫製性に支障をきたす
という問題点が生ずる。そこでこの点に関しての解決が
望まれていた。こゐ問題点を改善するために、エチレン
ジアミンテトラアセチックアシッド、ジエチレントリア
ミンペンタアセチックアシッド、ヒ□ドロキシルエチレ
ンジアミンドリアセチツクアシツド、ニトリロトリアセ
チックアシッド、トリポリリン酸ソーダなどが併用され
るケースもあるが、その効果は必ずしも充分ではなく、
問題点の抜本的な解決には至っていないのが現状である
。
〔発明が解決しようとする問題点〕
また、過酸化水素漂白における問題としては、金属イオ
ン、特に鉄、銅、マンガン等による、セルロース系繊維
の金属イオン接触による脆化の問題がある。つまシ、漂
白工程中に、使用する水あるいは装置中から持ち込まれ
る金属イオン（主に鉄イオン）や鉄サビなどが原因とな
って過酸化水素の分解が促進され、セルロース系繊維編
織布上にレザーカットマーク（カミソリで切ったような
傷）あるいはピンホールが発生するなどの問題点を有し
ている。この問題点を改善するために、アミノカルボキ
シレート系有機キレート剤、とくにジエチレントリアミ
ンペンタアセチックアシッドを添加することが試みられ
ているが、これらのキレート剤は高声領域（アルカリ側
）では鉄イオンに対するキレート力を示さないため、ア
ルカリ領域で行なう通常の過酸化水素漂白においては効
果的でなかった。
そこで、高声領域で鉄に対するキレート力を示スｌｌア
ルコールやアルドン酸等がアミノカルボキシレート系有
機キレート剤と併用されるケース（特公昭５１−５１−
３Ｃ号公報、特公昭５１−３０１８５号公報）もあるが
、その効果は必ずしも充分ではなく抜本的な解決までに
は至っていないのが現状である。
〔問題点を解決するための手段〕
そこで本発明者らはセルロース系繊維の前述のような漂
白不良の問題点を解決するために鋭意研究した結果、特
定のポリカルボン酸類と、糖アルコール及び／又はアル
ドン酸とを併用することくよシ上記の問題点を解決し得
ることを見出し、本発明を完成した。
即ち、本発明は （リ　マレイン酸、アクリル酸、メタクリル酸からなる
群から選ばれる１種もしくは２種以上を構成単位とする
重合体もしくは共重合体あるいはそれらの塩、及び （ｂ）　　一般式ａｎ２ｏＨ（ｃＨｏＨ）ｎｃＨ２ｏｎ
で表わされる糖アルコール（式中ｎは２〜乙の整数を示
す）及び／又は一般式〇）１２０）！（Ｏ）ｆＯＨ）ｎ
ＣＨ２ＣＯＯＨで表わされるアルドン酸（式中ｎは２〜
６の整数を示す）もしくはその水溶性塩類もしくはその
ラクトン からなるセルロース系繊維用漂白性向上剤を提供するも
のである。
本発明の漂白性向上剤中の（ａｌ成分としては、数平均
分子量が３００〜８０００のものが好ましい。
（ａ）成分中の塩としては、アルカリ金属塩やアンモニ
ウム塩、更にはジェタノールアミン、トリエタノールア
ミンなどのアルカノールアミン塩などの形が使用可能で
あり、性能を阻害しない程度に未中和部分を残しておい
ても差支えない。
更に、（ａｌ成分として使用される重合体又は共重合体
は性能を阻害しない程度にマレイン酸、アクリル酸、メ
タクリル酸以外の単量体を共重合させたものでもよく、
かかる単量体としてはアクリルアミド、メタクリルスル
ホン酸やビニルスルホン酸などの各種スルホン酸、２−
ヒドロキシエチルアクリレート、各種アクリル酸エステ
ル、各種メタクリル酸エステル、Ｎ−メチロールアクリ
ルアミドあるいはその他の共重合可能な物質などが使用
できる。
本発明の漂白性向上剤中の（ｂｌ成分である、一般式Ｃ
Ｈ２０Ｈ（ＣＨＯＨ）ｎＣＨ２０Ｈで表わされる糖アル
コールとしては、例えばＤ−ソルビット、Ｄ−グルジッ
ド、Ｄ−マンニット、Ｄ−キシリット、エリトロマンノ
オフチットなどが挙げられ、また一般式ＣＨ２０Ｈ（Ｃ
ＨＯＨ）ｎＣ００Ｈで表わされるアルドン酸としては、
例えばＤ−マンノース、Ｄ−キシロース、Ｄ−／’ルコ
ース等のアルドースから得られるアルドン酸が挙げられ
る。さらに、これらの酸の水溶性塩類、たとえばＮａ塩
、Ｋ塩等又はこれらの酸のラクトンを用いることもでき
る。
本発明のセルロース系繊維用漂白性向上剤は前記の（ａ
ｌ、　（ｂｌ成分を併せて用いるものであるが、（ａ）
成分と（ｂＪ成分の混合比は、重１比で（ａｌ　：　（
ｂｌ　＝１０〜９０：９０〜１０の範囲が好ましく、よ
り好ましい範囲は、（ａｔ：（ｂ）＝４０〜６ｏ　：　
６０〜４０である。
更に本発明のセルロース系繊維用漂白性向上剤は、その
性能が低下しない範囲においてアニオン性、カチオン性
、非イオン性の界面活性剤を含むことができる。本発明
のセルロース系繊維用漂白性向上剤が含むことのできる
界面活性剤トしては、ポリオキシエチレンアルキルエー
テル、ポリオキシエチレンアルキルアミン、ポリオキシ
エチレンアルキルエーテル硫酸化物、脂肪酸エステル硫
酸化物、ベタイン型両性活性剤等を例示することができ
る。
本発明の漂白性向上剤の使用に−は、一般的には漂白浴
に０．０１〜２０Ｉ（固形分換算）／ノ、好ましくは０
．０４〜１０９（固形分換算）／ノの範囲が望ましい。
本発明の際白性向上剤を適用することのできるセルロー
ス系繊維としては、木綿、麻などのセルロース天然繊維
の他に、これらのセルロース天然繊維とナイロン、ポリ
エステル、アクリルなどの合成繊維との混合繊維、更に
はアセテートなどの半合成繊維との混合繊維、レーヨン
、キュホラなどの再生繊維との混合繊維などにも適用す
ることが可能であり、漂白するときの形態も、繊維、糸
、総、チーズ、織物、編物、不織布、更には衣類、寝装
商品などの最終繊維製品などのいずれの形態であっても
差支えない。
本発明の抄白性向上剤を用いてセルロース系＊維を漂白
する際の漂白方法としては、通常行なわれている方法が
適用でき、バッド−スチーム法、加圧煮沸法、６０Ｃ程
度から１００Ｃまでの温度での浸漬法るるいはその他の
方法などが適用可能である。更に、本発明の漂白性向上
剤は、これまでに述べてきたような漂白だけのみならず
、精練・漂白、のシ抜き・精練・漂白などというように
他の工程と同時に行なわれる漂白にも適用することがで
きる。
〔作用〕
セルロース系繊維の漂白を、過酸化水素、アルカリ、ケ
イ酸ナトリウムと本発明の漂白性向上剤を共存させて行
なうことによシ、水の硬度が高い場合に於いても、水中
に過酸化水素の分層を促進する鉄イオンなどの金属イオ
ンを含む場合に於いても、従来の漂白方法に比較してす
ぐれた白変、風合、縫製性を付与することができるＯ セルロース系繊維の漂白時に過酸化水素、アルカリ、ケ
イ酸ナトリウムと共に本発明の漂白性向上剤を共存させ
ることによって漂白不良の問題点が解消される機構は必
ずしも明確ではないが、本発明の漂白性向上剤が有する
著しくすぐれた金属イオン封鎖能と分散力に起因するも
のと考えられる。即ち、水の硬度が高い場合には、本発
明の漂白性向上剤が硬度成分をキレートして水に不溶性
の物質の生成を防止したシ、水や繊維から持込まれる水
不溶性物質を分散させてｍ維への再付着を防止しておシ
、系内に鉄イオンなどの過酸化水素分解促進物質が含ま
れるときには、その金属イオンをキレート分散して繊維
との接触を防止しているためであると考えられる。
〔実施例〕
以下に、配合例及び実施例を挙げて本発明を具体的に説
明するが、本発明は、これらの実施例のみに限定される
ものではない。
（配合例） 本発明のセル四−ス系繊維用漂白性向上剤として、表１
に示す配合例のものを得た。
なお、比較配合例１としては、ジエチレントリアミンペ
ンタアセチックアシッドとＤ−ソルビットを５Ｇ：５０
（重量比）で配合したものを用意した。
（実施例１） 精練した綿天笠編ニットを、本発明の漂白性向上剤を用
いて漂白し、その原註性を調べた。
結果は表２に示すとおシである。
く漂白条件〉 便用水の硬度　　　２５°ＤＨ 浴　　　　　　比　　　　　１対２５ 温　　　　　　度　　　　　８０Ｃ 時　　　　　　間　　　　　３０分 使用薬剤　　表２参照 〈評　価〉 処理した布の風合いは、官能検査法によル判定した。白
変は、スガ試験機（株）製８’Ｍ力２−コンピューター
５Ｍ−５型を用いて測色し、Ｌａｂ系の白変式 ％式％ 但し、Ｌ＝測測定れた明度 ａ；測定されたフロマチラフネス指数 ｂ＝測定されたクロマチツクネ２指数 によって白変（Ｗ）を求め評価した。縫！Ｒ性は、布を
４枚重ねにし本縫ミシンで針＃１１Ｓを用いて３０ｃｒ
ｎ空縫いした場合の地糸切れ箇所数で評価した。
表２の結果から明らかなように１過酸化水素とカセイソ
ーダ、３号ケイ酸ナトリウムのみによるもの（Ａ１）は
風合が硬く白変、縫製性も劣ってお少、エチレンジアミ
ンテトラアセチックアシッドや、比較配合例のものを併
用したもの（４２、４）でも大巾な漂白性の改讐けなさ
れていなり０これに対して、本発明の漂白性向上剤を併
用したもの（扁５〜１２）では風合がソフトであって、
白変、縫製性にもすぐれていて良好な漂白性を示してい
る。また、本発明の配合品の原料の１つであるポリアク
リル酸ソーダを併用したもの（扁３）は風合がソフトで
あシ、白変、縫製性もよいが、本発明の漂白性向ｆ　剤
のレベルには至っていない。
（実施例２） ノリ抜きした未精練綿ブロードを鉄イオン存在下で漂白
し、その漂白性を調べた。結果を表５に示す。
く漂白条件〉 Ｆ０＋＋十の濃度　　　５　ｐｐｍ 浴　　　　　　比　　　　　１対８０ 温　　　　　　度　　　　　８００ 時　　　　　　間　　　　　３０分 使用薬剤　　表３参照 く評　価〉 実施例１と同じ方法で白変（司を求め評価した。
又、引裂強さは、エレメンドルフ形引裂強さ試験を用い
、６．５ｃｒｎ×１０ｃｒＲの試験片（１０副方向にた
て糸が走る）の両づかみの中央で直角に２ｃｍの切れ目
を入れ、残シの４．５ｃｒｎが引裂かれたときに示す最
大荷重（巧を３回はかり、その平均値を求めて、未処理
布の場合の数値で割り、引裂強さく％）とした。
表３の結果から明らかなように、過酸化水素とカセイソ
ーダのみによるもの（Ａ＋３）は白炭が劣っており、引
裂強さの低下も大きい。比較配合例１のもの、ジエチレ
ントリアミンペンタアセチックアシッド、ポリアクリル
酸ソーダ、グルコン酸ソーダを併用したもの（４１４〜
１７）でも漂白性の改良は充分でない。これに対して、
本発明の漂白性向上剤を併用したもの（扁１８〜２５）
では良好な漂白性を示している。
（実施例３） すでに精練漂白した綿ツイルを高濃度の鉄イオン存在下
で漂白し、布の汚染性を評価した。
結果を表４に示す。
く漂白条件〉 Ｆｅ　　　の濃度　　　２０　ｐｐｍ 浴　　　　　　比　　　　　１対８０ 温　　　　　　度　　　　　８００ 時　　　　　　間　　　　　３０分 使用薬剤　　表４参照 〈評　価〉 実施例２と同様の方法で白炭（Ｗ）と引裂強さを求め、
漂白性を評価した。
この場合、白炭が原布に比べて小さい程布の汚染が激し
いことを示している。
表４の結果から明らかなように、過酸化水素とカセイソ
ーダのみＫよるもの（４２６）は、激しく汚染されてお
シ、引裂強度も大きく低下している。ジエチレントリア
ミンペンタアセチックアシッドやＤ−ソルビット、比較
配合例品、共重合体Φ等を併用したもの（Ａ２７〜３０
）でも汚染の改良はなされていない。これに対して、本
発明による漂白性向上剤を併用したもの（４３１〜３８
）では汚染がほとんど防止されておシ、原布と変わらぬ
白変と引裂強度を示している。

Claims (1)

  1. 【特許請求の範囲】 １、（ａ）マレイン酸、アクリル酸、メタクリル酸から
    なる群から選ばれる１種もしくは２種 以上を構成単位とする重合体もしくは共重 合体あるいはそれらの塩、及び （ｂ）一般式ＣＨ＿２ＯＨ（ＣＨＯＨ）＿ｎＣＨ＿２Ｏ
    Ｈで表わされる糖アルコール（式中ｎは２〜６の整数を
    示 す）及び／又は一般式ＣＨ＿２ＯＨ（ＣＨＯＨ）＿ｎＣ
    Ｈ＿２ＣＯＯＨで表わされるアルドン酸（式中ｎは２〜
    ６ の整数を示す）もしくはその水溶性塩類も しくはそのラクトン からなるセルロース系繊維用の漂白性向上剤。 ２、前記の（ａ）及び（ｂ）の重量混合比が（ａ）：（
    ｂ）＝１０〜９０：９０〜１０である特許請求の範囲第
    １項記載のセルロース繊維用漂白性向上剤。 ３、前記（ａ）の重合体もしくは共重合体あるいはそれ
    らの塩が３００〜８０００の数平均分子量を有するもの
    である特許請求の範囲第１項もしくは第２項記載のセル
    ロース系繊維用漂白性向上剤。
JP60172073A 1985-08-05 1985-08-05 漂白性向上剤 Granted JPS6232195A (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP60172073A JPS6232195A (ja) 1985-08-05 1985-08-05 漂白性向上剤
CN86107481A CN1007523B (zh) 1985-08-05 1986-08-04 改进的漂白组合物
DE19863626361 DE3626361A1 (de) 1985-08-05 1986-08-04 Bleichverbesserungs-zusammensetzung
IT21410/86A IT1197844B (it) 1985-08-05 1986-08-05 Composizione per il miglioramento del candeggio
KR1019860006465A KR910002919B1 (ko) 1985-08-05 1986-08-05 표백 증진제
GB8619058A GB2178769B (en) 1985-08-05 1986-08-05 Bleaching improving composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60172073A JPS6232195A (ja) 1985-08-05 1985-08-05 漂白性向上剤

Publications (2)

Publication Number Publication Date
JPS6232195A true JPS6232195A (ja) 1987-02-12
JPS64502B2 JPS64502B2 (ja) 1989-01-06

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ID=15935039

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Country Link
JP (1) JPS6232195A (ja)
KR (1) KR910002919B1 (ja)
CN (1) CN1007523B (ja)
DE (1) DE3626361A1 (ja)
GB (1) GB2178769B (ja)
IT (1) IT1197844B (ja)

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DE19935258A1 (de) * 1999-07-27 2001-02-01 Henkel Kgaa Bleichmittelzusammensetzungen
DE102005005016A1 (de) * 2005-02-03 2006-08-10 Basf Ag Polymere hydrophobe Aminonitrilquats zur Bleichaktivierung
WO2013123673A1 (zh) * 2012-02-24 2013-08-29 日华化学株式会社 精炼漂白助剂及精炼漂白方法
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IT8621410A1 (it) 1988-02-05
KR910002919B1 (ko) 1991-05-10
JPS64502B2 (ja) 1989-01-06
CN1007523B (zh) 1990-04-11
KR870002323A (ko) 1987-03-30
GB8619058D0 (en) 1986-09-17
IT1197844B (it) 1988-12-06
CN86104895A (zh) 1987-02-04
GB2178769A (en) 1987-02-18
GB2178769B (en) 1989-04-05
DE3626361A1 (de) 1987-02-12
IT8621410A0 (it) 1986-08-05

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