JPS6123275B2 - - Google Patents
Info
- Publication number
- JPS6123275B2 JPS6123275B2 JP13111376A JP13111376A JPS6123275B2 JP S6123275 B2 JPS6123275 B2 JP S6123275B2 JP 13111376 A JP13111376 A JP 13111376A JP 13111376 A JP13111376 A JP 13111376A JP S6123275 B2 JPS6123275 B2 JP S6123275B2
- Authority
- JP
- Japan
- Prior art keywords
- aluminum
- acid
- cleaning agent
- sulfuric acid
- phosphoric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 34
- 229910052782 aluminium Inorganic materials 0.000 claims description 33
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 28
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 24
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 22
- 239000012459 cleaning agent Substances 0.000 claims description 15
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims 1
- 239000002932 luster Substances 0.000 description 11
- 239000003973 paint Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000001172 regenerating effect Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- -1 amine compound Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- YXJYBPXSEKMEEJ-UHFFFAOYSA-N phosphoric acid;sulfuric acid Chemical compound OP(O)(O)=O.OS(O)(=O)=O YXJYBPXSEKMEEJ-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/12—Light metals
- C23G1/125—Light metals aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Description
【発明の詳細な説明】
本発明は、アルミニウム板表面の再生用洗浄
剤、特にアルミニウム製コンテナの表面の洗浄再
生に適した洗浄剤に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a cleaning agent for regenerating the surface of an aluminum plate, and particularly to a cleaning agent suitable for cleaning and regenerating the surface of an aluminum container.
トラツク等のコンテナは、その表面に文字等を
画くことにより一種の宣伝媒体としての機能を有
するため、その構成材料として、金属光沢性に優
れた外観上見映えのするアルミニウム板を用いた
ものが多い。 Containers such as trucks have the function of a kind of advertising medium by drawing letters etc. on their surface, so it is preferable to use aluminum plates with excellent metallic luster and good appearance as their construction material. many.
しかし、アルミニウム製コンテナは、製作後一
定期間は極めて美観に富むがその表面が汚染され
易く、また海上コンテナに用いた場合には海水に
より侵され易いため、比較的短期間で以てアルミ
ニウム本来の金属光沢が失せてしまうという問題
を有しており、また、その表面に画かれた文字が
落ち易い等の問題もある。そこで、このような問
題が生じた場合には、アルミニウム板の表面を化
学的又は物理的手段で元の金属光沢を有するよう
に再生し、文字等を画き直すことが行なわれてき
たが、従来の再生方法は種々の欠点を有してい
た。即ち、一つの再生方法としてアルカリ又は酸
により、表面が汚染又は腐蝕したアルミニウム表
面をエツチングする方法があるが、この方法によ
ると、例えば苛性ソーダによるエツチングは、エ
ツチング速度が極めて遅くしかも表面に金属光沢
を付与できず、また硫酸―リン酸系の混合物によ
る場合は常温では殆んどエツチングが不可能であ
る。また、別の再生方法として表面を研磨する方
法があるが、このような物理的手段は、労力を要
し作業効率が悪い。 However, although aluminum containers have an extremely beautiful appearance for a certain period of time after being manufactured, their surfaces are easily contaminated, and when used as maritime containers, they are easily eroded by seawater. There is a problem that the metallic luster is lost, and there are also other problems such as characters drawn on the surface easily falling off. Therefore, when such a problem occurs, the surface of the aluminum plate is regenerated to its original metallic luster by chemical or physical means, and the letters, etc. are repainted. The regeneration method had various drawbacks. That is, one regeneration method is to etch a contaminated or corroded aluminum surface with an alkali or acid. However, according to this method, etching with caustic soda, for example, has an extremely slow etching speed and does not give the surface a metallic luster. Furthermore, if a sulfuric acid-phosphoric acid mixture is used, etching is almost impossible at room temperature. Another regeneration method is to polish the surface, but such physical means requires labor and is inefficient.
また、表面が汚染又は腐蝕したアルミニウム製
コンテナの美観を回復する他の手段として、表面
全体を銀粉で塗布することも行なわれているが、
このような手段による場合、最早、アルミニウム
本来の金属光沢を全く有しない別のものとなつて
しまう。 Another method of restoring the aesthetic appearance of aluminum containers with contaminated or corroded surfaces is to coat the entire surface with silver powder.
If such a method is used, the aluminum will no longer have the metallic luster inherent to aluminum.
本発明者は、叙上の諸点に鑑み、表面が汚染又
は腐蝕したアルミニウム板を、作業効率良くアル
ミニウム本来の光沢に近い光沢を有するものに再
生し得る手段を見出すべく種々検討した結果、フ
ツ化水素酸と特定の２種の酸との混合液により、
表面が汚染又は腐蝕したアルミニウム板を効果的
に洗浄できることを知見した。また、上記混合液
により洗浄したアルミニウム板の表面に塗装を施
した場合又は文字等を画いた場合にそれ等が落ち
難いことを知見した。 In view of the above-mentioned points, the inventor of the present invention has conducted various studies in order to find a means of regenerating an aluminum plate whose surface has been contaminated or corroded into one having a gloss close to that of the original aluminum in an efficient manner. With a mixture of hydrogen acid and two specific acids,
It has been found that aluminum plates whose surfaces are contaminated or corroded can be effectively cleaned. Furthermore, it has been found that when paint is applied to the surface of an aluminum plate that has been cleaned with the above-mentioned mixed solution, or when letters or the like are drawn, it is difficult to remove the paint.
本発明は、上記知見に基づきなされたもので、
フツ化水素酸、硫酸及びリン酸を溶解した水溶液
からなり、水溶液に含まれるフツ化水素酸と硫酸
とリン酸とのモル比が、約１：約0.5〜約10：約
0.005〜0.5であるアルミニウム用洗浄剤を提供す
るものである。 The present invention was made based on the above findings, and
It consists of an aqueous solution in which hydrofluoric acid, sulfuric acid, and phosphoric acid are dissolved, and the molar ratio of hydrofluoric acid, sulfuric acid, and phosphoric acid contained in the aqueous solution is about 1: about 0.5 to about 10: about
The present invention provides a cleaning agent for aluminum having a concentration of 0.005 to 0.5.
以下本発明の洗浄剤について詳述する。 The cleaning agent of the present invention will be explained in detail below.
本発明の洗浄剤におけるフツ化水素酸はアルミ
ニウム板の表面に付着している汚染物又は、腐蝕
部分に作用してそれらを遊離させ、きれいなアル
ミニウムの金属面を露出させるものと考えられ、
また、硫酸は上記汚染物等を溶解させて上記イオ
ンの浸透を助けると共に、表面に画れた文字等の
樹脂塗膜の溶解に寄与するものと考えられる。更
に、この硫酸は露出したきれいなアルミニウム面
にフツ化アルミニウム等の皮膜が形成するのを抑
制し、清浄化されたアルミニウム板表面に金属光
沢を発現させる機能も有するものである。 It is believed that the hydrofluoric acid in the cleaning agent of the present invention acts on contaminants or corroded parts adhering to the surface of the aluminum plate, liberating them and exposing the clean aluminum metal surface.
It is also believed that sulfuric acid dissolves the above-mentioned contaminants and the like, aids in the penetration of the above-mentioned ions, and also contributes to the dissolution of resin coatings such as characters scratched on the surface. Furthermore, this sulfuric acid has the function of suppressing the formation of a film such as aluminum fluoride on the exposed clean aluminum surface and giving the surface of the cleaned aluminum plate a metallic luster.
また、本発明の洗浄剤におけるリン酸は、アル
ミニウム板の表面光沢を、一層高めると共に清浄
化されたアルミニウム板の表面に文字等を塗料で
画いた場合に塗膜とアルミニウム板表面との密着
性を良好にする。尚、上記硫酸は、このリン酸の
添加によよるリン酸膜の生成も抑制するものであ
る。 In addition, the phosphoric acid in the cleaning agent of the present invention further enhances the surface gloss of the aluminum plate, and also improves the adhesion between the paint film and the aluminum plate surface when letters, etc. are drawn on the surface of the cleaned aluminum plate. make it good. Note that the sulfuric acid described above also suppresses the formation of a phosphoric acid film due to the addition of phosphoric acid.
更に、本発明の洗浄剤に、リン酸の他に界面活
性剤、好ましくはトリエタノールアミン等の水溶
性アミン化合物、第四級アンモニウム塩系カチオ
ン活性剤又はこれらと非イオン界面活性剤との混
合物を添加することにより金属光沢をマイルドな
ものとすることができる。 Furthermore, in addition to phosphoric acid, the cleaning agent of the present invention may contain a surfactant, preferably a water-soluble amine compound such as triethanolamine, a quaternary ammonium salt-based cationic surfactant, or a mixture of these and a nonionic surfactant. By adding , the metallic luster can be made mild.
次に、本発明の洗浄剤におけるフツ化水素酸、
硫酸及びリン酸の組成比について説明すると、フ
ツ化水素酸：硫酸：リン酸はモル比で１：約0.5
〜約10：0.005〜約0.5であり必要に応じ水で稀釈
して用いられる。上記組成において、フツ化水素
酸が少な過ぎると洗浄効果が低下し、また過量に
なるとアルミニウムを侵しその表面を荒らしてし
まう。また、硫酸が少な過ぎると、塗膜等の除去
が困難になる上に、アルミニウム表面におけるフ
ツ化膜及びリン酸膜の生成の抑制が困難になり、
表面を白色化する。このように、硫酸は清浄化さ
れたアルミニウム表面の白色度のコントロール剤
としての機能も発揮する。また、リン酸は少な過
ぎると金属光沢を充分に向上させることができ
ず、過量になると白色膜の生成が過剰となり好ま
しくない。尚、これに加える界面性剤の量は、
0.2〜２％（重量）程度で充分である。而して、
本発明の洗浄剤により、表面が汚染又は腐蝕した
アルミニウム板を清浄化（再生）するには、必要
に応じ水で適度に稀釈してから、ハケ、スプレー
ガン等を使用して直接上記アルミニウム板に注ぐ
なり、吹き付ければ良く、その結果、上記アルミ
ニウム板板は容易に清浄化され金属光沢を有する
表面を露呈し、しかもその表面には耐蝕性皮膜が
形成されるため、爾後の表面腐蝕又は汚染が防止
される。また、その上に文字等を画いた場合、塗
膜とアルミニウム表面との密着性が耐蝕性皮膜に
より一層向上するので、塗膜は落ち難くなる。 Next, hydrofluoric acid in the cleaning agent of the present invention,
To explain the composition ratio of sulfuric acid and phosphoric acid, the molar ratio of hydrofluoric acid: sulfuric acid: phosphoric acid is 1: about 0.5.
~10:0.005~0.5, and is used after diluting with water if necessary. In the above composition, if the amount of hydrofluoric acid is too small, the cleaning effect will be reduced, and if it is in too much, it will attack the aluminum and roughen its surface. In addition, if the amount of sulfuric acid is too low, it will be difficult to remove the paint film, etc., and it will also be difficult to suppress the formation of a fluoride film and a phosphate film on the aluminum surface.
Whiten the surface. Thus, sulfuric acid also functions as a whiteness control agent for the cleaned aluminum surface. Further, if the amount of phosphoric acid is too small, the metallic luster cannot be sufficiently improved, and if the amount is too much, a white film will be excessively formed, which is not preferable. The amount of surfactant added to this is
About 0.2 to 2% (by weight) is sufficient. Then,
In order to clean (recycle) an aluminum plate whose surface has been contaminated or corroded with the cleaning agent of the present invention, after diluting it appropriately with water as necessary, use a brush, spray gun, etc. to directly clean the aluminum plate. As a result, the aluminum plate is easily cleaned to reveal a surface with metallic luster, and a corrosion-resistant film is formed on the surface, preventing subsequent surface corrosion or Contamination is prevented. Furthermore, when characters or the like are drawn on it, the corrosion-resistant film further improves the adhesion between the paint film and the aluminum surface, making it difficult for the paint film to come off.
叙上の如く、本発明の洗浄剤は、表面が汚染又
は腐蝕したアルミニウム板を、作業効率良く、清
浄化し得るものであるため、トラツクのコンテナ
のように、高価で且つ常時表面が美観を呈するこ
とを要求されるアルミニウム板の清浄剤として極
めて便利なものである。 As mentioned above, the cleaning agent of the present invention can efficiently clean aluminum plates whose surfaces are contaminated or corroded, so they can be used to clean aluminum plates that are expensive and always have a beautiful appearance, such as truck containers. It is extremely useful as a cleaning agent for aluminum plates that require
以下に本発明の実施例を示す。 Examples of the present invention are shown below.
実施例 １
49％フツ化水素酸 500c.c.
97％硫酸 500c.c.
75％リン酸 50c.c.
トリエタノーアミン 20ｇ
水 1000c.c.
上記成分を混和して洗浄剤を得た。次に本発明
の洗浄剤の効果をみるために、上記実施例で得ら
れた洗浄剤を用い、汚染度の高い、トラツクのア
ルミニウム製コンテナの表面を洗浄したところ、
アルミニウムの表面は美麗なでマイルドな金属光
沢を示した。Example 1 49% hydrofluoric acid 500 c.c. 97% sulfuric acid 500 c.c. 75% phosphoric acid 50 c.c. Triethanolamine 20 g Water 1000 c.c. The above components were mixed to obtain a cleaning agent. Next, in order to see the effect of the cleaning agent of the present invention, the surface of a highly contaminated aluminum truck container was cleaned using the cleaning agent obtained in the above example.
The aluminum surface had a beautiful, mild metallic luster.
また、比較のために、97％硫酸及び49％フツ化
水素酸をそれぞれ単独で用いて上記と同様に汚染
したアルミニウム製コンテナを洗浄したところ、
硫酸を用いた場合には表面を清浄化できず、また
フツ化水素酸を用いた場合にはアルミニウム表面
がエツチングされて金属光沢を呈しなかつた。 For comparison, a contaminated aluminum container was cleaned using 97% sulfuric acid and 49% hydrofluoric acid alone.
When sulfuric acid was used, the surface could not be cleaned, and when hydrofluoric acid was used, the aluminum surface was etched and did not exhibit metallic luster.
Claims (1)
溶液からなり、水溶液に含まれるフツ化水素酸と
硫酸とリン酸とのモル化が、約１：約0.5〜約
10：約0.005〜0.5であるアルミニウム板表面の再
生用洗浄剤。1 Consists of an aqueous solution in which hydrofluoric acid, sulfuric acid, and phosphoric acid are dissolved, and the molar ratio of hydrofluoric acid, sulfuric acid, and phosphoric acid contained in the aqueous solution is about 1: about 0.5 to about
10: A cleaning agent for recycling the surface of an aluminum plate with a concentration of about 0.005 to 0.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13111376A JPS5355307A (en) | 1976-10-29 | 1976-10-29 | Detergent for aluminum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13111376A JPS5355307A (en) | 1976-10-29 | 1976-10-29 | Detergent for aluminum |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5355307A JPS5355307A (en) | 1978-05-19 |
| JPS6123275B2 true JPS6123275B2 (en) | 1986-06-05 |
Family
ID=15050281
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13111376A Granted JPS5355307A (en) | 1976-10-29 | 1976-10-29 | Detergent for aluminum |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5355307A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT377539B (en) * | 1981-06-24 | 1985-03-25 | Badische Corp | MONOFILER, ELECTRICALLY CONDUCTING TEXTILE THREAD OF TWO COMPONENTS |
| ZA827263B (en) * | 1981-10-09 | 1984-05-30 | Occidental Chem Corp | Process and apparatus for cleaning aluminum surfaces |
| JPS6317997A (en) * | 1986-07-10 | 1988-01-25 | 及川 銀逸 | Cleaning composition |
| CN107345297B (en) * | 2015-12-10 | 2020-07-14 | 威海赤那思电子材料有限公司 | Alkaline cleaning solution, phosphating solution and metal surface treatment method |
| CN107620057B (en) * | 2015-12-10 | 2019-01-25 | 吴联凯 | A kind of application method of the phosphating solution for metal processing |
-
1976
- 1976-10-29 JP JP13111376A patent/JPS5355307A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5355307A (en) | 1978-05-19 |
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