JPS6123034B2 - - Google Patents
Info
- Publication number
- JPS6123034B2 JPS6123034B2 JP52114427A JP11442777A JPS6123034B2 JP S6123034 B2 JPS6123034 B2 JP S6123034B2 JP 52114427 A JP52114427 A JP 52114427A JP 11442777 A JP11442777 A JP 11442777A JP S6123034 B2 JPS6123034 B2 JP S6123034B2
- Authority
- JP
- Japan
- Prior art keywords
- conduit
- resin
- curable resin
- gas
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005989 resin Polymers 0.000 claims description 23
- 239000011347 resin Substances 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 239000003566 sealing material Substances 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 238000000576 coating method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- TVGGFVNRRGKACD-UHFFFAOYSA-N [2,2,4-trimethyl-3-(2-methylprop-2-enoyloxy)pentyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C(C)C)C(C)(C)COC(=O)C(C)=C TVGGFVNRRGKACD-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009412 basement excavation Methods 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L55/00—Devices or appurtenances for use in, or in connection with, pipes or pipe systems
- F16L55/10—Means for stopping flow in pipes or hoses
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Protection Of Pipes Against Damage, Friction, And Corrosion (AREA)
- Pipe Accessories (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
本発明は、例えば都市ガス用、天然ガス用、石
油用、水道用など各種の既設導管に対して、ライ
ニング材あるいはシール材により内面ライニング
あるいは漏洩箇所のシールを行なう方法に関す
る。
既設導管の内面処理を施すに、筒状ライニング
材を利用すると、ライニング材の導管内導入が困
難あるいは不可能になつたり、導管全周にわたつ
て付着した状態での内面処理が困難になつたりす
る等の不利があるが、液状等流動性のライニング
材あるいはシール材を導管内面に付着硬化させる
手段を採用すると、そのような不利を回避でき
る。そこで、従来、そのような流動性のライニン
グ材あるいはシール材として、熱硬化性や光硬化
性や常温硬化性の樹脂が使用されている。しか
し、熱硬化性樹脂を利用して、その樹脂を管内へ
の熱風供給によつて硬化させる場合には、その熱
風供給側ほど硬化が早くて全体に硬化むらが生
じ、また硬化速度を平均化させるために、導管を
加熱した状態で導管に樹脂を付着させる場合に
は、その処理長さが長くなるほどに大掛りな装置
を要し、かつ殊に埋設導管の場合には、大規模な
掘削工事を伴い、経済性や施工性において劣つ
た。また、熱硬化性や光硬化性の樹脂を、導管へ
の塗布と同時あるいはその後で、導管内を通過さ
せる加熱装置あるいは投光装置で硬化させる場合
それら装置を通す上で、殊に既設導管では曲りや
内径変化が存在しがちであるために、技術的問題
を伴う。また、常温硬化性樹脂を使用する場合に
は、その硬化に多大の時間を要し作業能率におい
て劣る。
本発明は、上述欠点を一挙に解消する事を目的
とし、その方法は、既設導管内に供給するライニ
ング材あるいはシール材として、嫌気硬化性樹脂
を使用する事を特徴とする。
すなわち、嫌気硬化性樹脂は、酸素ガスが存在
すると硬化しないあるいは硬化速度が低くて、酸
素ガスが少なくなるあるいは無くなると急速に硬
化する性質を有しているから、例えば既設導管内
を空気で置換させた後に樹脂を導管に付着させ、
その後空気に代えて窒素ガス等の酸素ガスを含ま
ないあるいは少量しか含まない気体を導管内に封
入する等の、極めて容易な手段で、しかも大掛り
な装置を要すことなくライニング材やシール材を
硬化させることができ、その際付着樹脂がその表
面から急速に硬化するため塗膜のたれあとが付き
にくく、全体として極めて均質良好な被覆処理を
経済性良く達成することができる。
次に、本発明の実施例を例示図に基づいて詳述
する。
第1図に示すように、上下あるいは左右曲り部
分のある既設導管1を、本来備えられているある
いは必要に応じて取付けた仕切弁2a,2bによ
つて両端を閉じ、その弁2a,2b間において導
管1の一部を切断あるいは取外して端部を開口さ
せると共に、その端部に空気加圧供給装置3と排
気装置4とを接続して、その導管1内に存在する
都市ガスなどの流体を空気に置換し、次いで第2
図に示すように、タンク5からの液状の嫌気硬化
性樹脂Aを導管1内に供給すると共に、これを排
出するための物体6を導管1内に挿入し、かつこ
の物体6を前記空気加圧供給装置3により圧送
し、もつて前記物体6により余剰の樹脂Aを容器
7に回収すると共に、空気雰囲気の導管内壁面に
嫌気硬化性樹脂Aを付着させ、次に第3図に示す
ように、窒素などの酸素を含まない気体を供給す
る装置8からの供給気体により、導管1の内部雰
囲気を窒素などの雰囲気に置換し、もつて嫌気硬
化性樹脂Aをその硬化速度を平均化する状態で迅
速に硬化させ、導管1の内壁面全体にわたつて均
質な樹脂Aの被覆を施すものである。
尚、嫌気硬化性樹脂Aの既設導管内への付着手
段として、これを窒素雰囲気状態でスプレー付着
させる、あるいは導管内に充満させるなど各種手
段を採用できる。
嫌気硬化性樹脂Aは、分子構造の一部に少なく
とも1個以上のアクリル酸基
あるいはメタクリル酸基
を有する化合物であり、少量の触媒(クメンハイ
ドロパーオキサイド、メチルエチルケトンパーオ
キサイド、t―ブチル・ハイドロパーオキサイド
等)、促進剤(第3級アミノ等)、安定剤(フエノ
ール類、多価フエノール類、キノン類、、オキシ
ム類、アミン類、銅塩等)を加えて用いる。ま
た、必要に応じ、充填剤、たれ防止剤を加え、シ
ールやライニングに必要な粘度、チクソ性に調整
してもよい。
以下に代表的な公知の嫌気硬化性樹脂Aを示
す。
(1) ポリエーテル型
但し 、
R:−H、−CH3、−C2H5、−CH2OH,
R′:−H、−Cl、−CH3、−C2H5、
R″:−H、OH、
The present invention relates to a method for lining the inner surface or sealing leakage points of various existing conduits, such as those for city gas, natural gas, petroleum, and water, using a lining material or sealing material. If a cylindrical lining material is used to treat the inner surface of an existing conduit, it may be difficult or impossible to introduce the lining material into the conduit, or it may be difficult to treat the inner surface with the lining material adhered to the entire circumference of the conduit. However, such disadvantages can be avoided by adopting a method of attaching and hardening a fluid lining material or sealing material to the inner surface of the conduit. Therefore, conventionally, thermosetting, photocurable, or room temperature curing resins have been used as such fluid lining materials or sealing materials. However, when thermosetting resin is used and the resin is cured by supplying hot air into the pipe, the cure is faster on the hot air supply side, resulting in uneven curing throughout the tube, and the curing speed is averaged. When applying resin to a conduit while heating it, the longer the length of the process, the more large-scale equipment is required, and especially in the case of buried conduits, large-scale excavation is required. It involved construction work and was inferior in terms of economy and workability. In addition, when thermosetting or photocurable resin is cured with a heating device or a lighting device that is passed through the pipe at the same time as or after it is applied to the pipe, it is difficult to pass the resin through the pipe, especially in existing pipes. It is associated with technical problems because bends and internal diameter changes tend to exist. Furthermore, when a room temperature curable resin is used, it takes a long time to cure, resulting in poor work efficiency. The present invention aims to eliminate the above-mentioned drawbacks at once, and its method is characterized by using an anaerobic curable resin as a lining material or sealing material to be supplied into the existing conduit. In other words, anaerobic hardening resins do not harden or have a slow hardening speed in the presence of oxygen gas, and harden rapidly when oxygen gas is reduced or eliminated. After that, the resin is attached to the conduit,
Afterwards, instead of air, a gas such as nitrogen gas that does not contain or contains only a small amount of oxygen gas can be sealed into the pipe, which is an extremely easy method, and without the need for large-scale equipment, lining material or sealing material can be used. In this case, since the adhering resin is rapidly cured from the surface, the coating film is less likely to sag, and an extremely homogeneous coating process can be economically achieved as a whole. Next, embodiments of the present invention will be described in detail based on illustrative drawings. As shown in Fig. 1, an existing conduit 1 with vertical or horizontal bends is closed at both ends with gate valves 2a and 2b, which are originally provided or installed as necessary, and between the valves 2a and 2b. At this point, a part of the conduit 1 is cut or removed to open the end, and an air pressurization supply device 3 and an exhaust device 4 are connected to the end to remove the fluid such as city gas present in the conduit 1. is replaced with air, then the second
As shown in the figure, a liquid anaerobic curable resin A from a tank 5 is supplied into a conduit 1, and an object 6 for discharging it is inserted into the conduit 1, and this object 6 is The excess resin A is fed under pressure by the pressure supply device 3, and the excess resin A is collected into the container 7 by the object 6, and the anaerobic curable resin A is adhered to the inner wall surface of the conduit in an air atmosphere, and then as shown in FIG. Then, the internal atmosphere of the conduit 1 is replaced with an atmosphere such as nitrogen using a gas supplied from a device 8 that supplies a gas such as nitrogen that does not contain oxygen, thereby equalizing the curing speed of the anaerobic curable resin A. The resin A is rapidly cured in a state where the resin A is uniformly coated over the entire inner wall surface of the conduit 1. In addition, various methods can be used to attach the anaerobic curable resin A to the inside of the existing conduit, such as spraying it in a nitrogen atmosphere or filling the conduit. Anaerobic curable resin A has at least one acrylic acid group in a part of its molecular structure. Or methacrylic acid group A compound with quinones, oximes, amines, copper salts, etc.). Further, if necessary, fillers and anti-sag agents may be added to adjust the viscosity and thixotropy required for sealing and lining. A typical known anaerobic curable resin A is shown below. (1) Polyether type However, R: -H, -CH3 , -C2H5 , -CH2OH , R′: −H, −Cl, −CH 3 , −C 2 H 5 , R″: −H, OH,
【式】
m:1〜8
n:2〜20
p:0又は1
例.テトラエチレングリコールジメタクリレー
ト。
但し、
R′:−H、−Cl、−CH3、−C2H5
n:1〜20
(1) エステル型
(A) 多価アルコールのメタクリル酸
エステル或いはアクリル酸エステル。
代表的な例として、
(a) トリメチロールプロパントリメタクリレ
ート。
(b) ブタンジオール1,4―ジメタクリレー
ト。
(c) 2,2,4―トリメチル―1,3―ペン
タンジオールジメタクリレート。
(B) ポリエステルアクリレート。
但し、R1:−H、−Cl、−CH3、−C2H5、
R2:−CH2−CH2−、[Formula] m: 1-8 n: 2-20 p: 0 or 1 Example. Tetraethylene glycol dimethacrylate. However, R': -H, -Cl, -CH 3 , -C 2 H 5 n: 1 to 20 (1) Ester type (A) Methacrylic acid ester or acrylic acid ester of polyhydric alcohol. Typical examples include (a) trimethylolpropane trimethacrylate. (b) Butanediol 1,4-dimethacrylate. (c) 2,2,4-trimethyl-1,3-pentanediol dimethacrylate. (B) Polyester acrylate. However, R 1 : -H, -Cl, -CH 3 , -C 2 H 5 , R 2 : -CH 2 -CH 2 -,
【式】− CH2−CH2−CH2、 R3:−(CH2−)m−(m=0〜8の整数) または、[Formula] −CH 2 −CH 2 −CH 2 , R 3 : −(CH 2 −)m− (m = integer from 0 to 8) or,
【式】【formula】
【式】 (C) エポキシアクリレート。 (D) その他 [Formula] (C) Epoxy acrylate. (D) Others
図面は本発明に係る既設導管の内面処理方法の
実施例を示し、第1図ないし第3図は処理工程の
説明図である。
1…既設導管、A…嫌気硬化性樹脂。
The drawings show an embodiment of the method for treating the inner surface of an existing conduit according to the present invention, and FIGS. 1 to 3 are explanatory diagrams of the treatment steps. 1... Existing conduit, A... Anaerobic curing resin.
Claims (1)
はシール材として、嫌気硬化性樹脂Aを使用する
事を特徴とする既設導管の内面処理方法。1. A method for treating the inner surface of an existing conduit, characterized by using anaerobic curable resin A as a lining material or sealing material supplied into the existing conduit 1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11442777A JPS5447767A (en) | 1977-09-21 | 1977-09-21 | Inner surface treatment of conduit already constructed |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11442777A JPS5447767A (en) | 1977-09-21 | 1977-09-21 | Inner surface treatment of conduit already constructed |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5447767A JPS5447767A (en) | 1979-04-14 |
JPS6123034B2 true JPS6123034B2 (en) | 1986-06-04 |
Family
ID=14637435
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11442777A Granted JPS5447767A (en) | 1977-09-21 | 1977-09-21 | Inner surface treatment of conduit already constructed |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5447767A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54142621A (en) * | 1978-04-28 | 1979-11-07 | Yasushi Nakashin | Leakage repair method of pipes laid underground |
GB8314209D0 (en) * | 1983-05-23 | 1983-06-29 | British Gas Corp | Sealing joints and leaks in mains |
JPS62201987A (en) * | 1986-02-28 | 1987-09-05 | Three Bond Co Ltd | Anaerobically hardenable composition for repair of gas facilities |
-
1977
- 1977-09-21 JP JP11442777A patent/JPS5447767A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5447767A (en) | 1979-04-14 |
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