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JPS60157156A - Exhaust valve for lead storage battery - Google Patents

Exhaust valve for lead storage battery

Info

Publication number
JPS60157156A
JPS60157156A JP59012551A JP1255184A JPS60157156A JP S60157156 A JPS60157156 A JP S60157156A JP 59012551 A JP59012551 A JP 59012551A JP 1255184 A JP1255184 A JP 1255184A JP S60157156 A JPS60157156 A JP S60157156A
Authority
JP
Japan
Prior art keywords
battery
cut
plate
elastic body
exhaust valve
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP59012551A
Other languages
Japanese (ja)
Inventor
Kunio Yonezu
米津 邦雄
Teruhiro Hatanaka
畑中 照弘
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Storage Battery Co Ltd
Nihon Denchi KK
Original Assignee
Japan Storage Battery Co Ltd
Nihon Denchi KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Storage Battery Co Ltd, Nihon Denchi KK filed Critical Japan Storage Battery Co Ltd
Priority to JP59012551A priority Critical patent/JPS60157156A/en
Publication of JPS60157156A publication Critical patent/JPS60157156A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/317Re-sealable arrangements
    • H01M50/325Re-sealable arrangements comprising deformable valve members, e.g. elastic or flexible valve members
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/342Non-re-sealable arrangements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Gas Exhaust Devices For Batteries (AREA)

Abstract

PURPOSE:To enable the cut of an elastic plate to open when the internal pressure of a lead storage battery is high and to close when the internal pressure is low by causing the outer area of the elastic plate to more easily expand and deform than its inner area. CONSTITUTION:An exhaustion valve for a negative electrode absorption type sealed battery is formed by interposing an elastic plate 1 made of rubber or the like and having a pin-hole or cut 2 between a lower frame 3, which has a hole 3' having a smaller diameter and opening into the internal space of the battery, and an upper frame 5, which has a larger diameter and opening into external air. Due to the difference in diameter between the openings 3' and 5', the outer area of the elastic plate 1 easily expands and deforms and the inner area hardly expands and deforms, Therefore, the cut 2 opens when the internal pressure of the battery is high and the cut 2 is closed when the internal pressure is low. As a result, external air is prevented from permeating into the battery, thereby improving its reliability.

Description

【発明の詳細な説明】 本発明は密閉形鉛蓄電池の排気弁の構造の改良に関する
ものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an improvement in the structure of an exhaust valve for a sealed lead-acid battery.

正極板から発生した酸素ガスを負極板と反応、吸収させ
る負極吸収式密閉形電池では、外気すなわち空気を電池
内へ侵入させないことが必須条件となついる。これは空
気中の酸素ガスによって、負極板が酸化、放電するため
である。したがって電池内のガスを外部へ放出すると共
に、外気を内部へ侵入させない機能を持つ信頼性のある
排気弁が必要となる。
In a negative electrode absorption type sealed battery in which oxygen gas generated from the positive electrode plate is reacted with and absorbed by the negative electrode plate, it is essential that outside air, that is, air, is not allowed to enter the battery. This is because the negative electrode plate is oxidized and discharged by oxygen gas in the air. Therefore, there is a need for a reliable exhaust valve that has the function of releasing the gas inside the battery to the outside and preventing outside air from entering the battery.

この種の排気弁としては従来から種々のものが提案され
実用化されてきた。最近になって密閉形電池には小形化
の要求が強くなり、小形でかつ信頼性のある排気弁の必
要性が高まっている。
Various types of exhaust valves of this type have been proposed and put into practical use. Recently, there has been a strong demand for smaller sealed batteries, and the need for small and reliable exhaust valves has increased.

この要求にそった簡便な弁として、弾性体にピンホール
または切れ目を入れたものが提案されている。これは電
池内が加圧状態になると、弾性体が外部に膨張、変形し
てピンホールや切れ目が開口するものであるが、他方、
電池内が減圧状態になっても同じように弾性体が間口す
るので、外気が電池内へ侵入する欠点があった。
A simple valve that meets this requirement has been proposed by having a pinhole or cut in an elastic body. This is because when the inside of the battery is pressurized, the elastic body expands and deforms to the outside, opening pinholes and cuts.
Even when the inside of the battery is in a reduced pressure state, the elastic body opens in the same way, so there is a drawback that outside air can enter the inside of the battery.

本発明は小形でかつ電池内が減圧状態となっても外気が
電池内に侵入しない排気弁を提供するものである。その
要旨は、ある限度を越えて膨張、変形したときに開口す
るピンホールまたは切れ目を有する板状弾性体を支持部
で気密に保持し、該板状弾性体の周囲を外側に対して内
側よりも膨張、変形しやすい構造とすることにある。
The present invention provides an exhaust valve that is small in size and prevents outside air from entering the battery even if the interior of the battery is in a reduced pressure state. The gist of this method is to airtightly hold a plate-like elastic body with pinholes or cuts that open when it expands or deforms beyond a certain limit on a support, and to wrap the periphery of the plate-like elastic body from the inside to the outside. The aim is to create a structure that is easy to expand and deform.

以下、本発明をその一実施例を示す第1図によって説明
すると、1は合成ゴム、天然ゴムあるいは柔軟なプラス
チックなどからなる板状弾性体で、その形状は円形、四
角形、六角形などである。2は板状弾性体1のピンホー
ルであるが、+、−などの切れ目でもよい。3は板状弾
性体1を支える下部枠体で、電池蓋への装着部4を有し
、これはねじ込み、嵌合圧着あるいは接着などでvt着
するものである。5は板状弾性体1を押える上部枠体で
、下部枠体3とは符号6で示す部分によって一体化され
ている。3′は下部枠体3の開口部で、電池内の空間に
連なっており、電池内のガスの初出経路である。5′は
上部枠体5の間口部で、柔軟な板状弾性体1が外側へ膨
張、変形し得る空間であり、ピンホールや切れ口2から
排出された電池内ガスの経路ともなっている。下部枠体
3の開口部3′は上部枠体5の開口部5′よりも小さく
、柔軟な板状弾性体1が電池内側へ変形するのが難しく
なっている。
Hereinafter, the present invention will be explained with reference to FIG. 1 showing one embodiment thereof. Reference numeral 1 denotes a plate-shaped elastic body made of synthetic rubber, natural rubber, flexible plastic, etc., and the shape thereof is circular, square, hexagonal, etc. . 2 is a pinhole in the plate-like elastic body 1, but it may also be a + or - cut. Reference numeral 3 denotes a lower frame body supporting the plate-like elastic body 1, and has a mounting portion 4 for attaching to the battery cover, which is attached by screwing, fitting, pressure bonding, adhesion, or the like. Reference numeral 5 denotes an upper frame body that presses down the plate-shaped elastic body 1, and is integrated with the lower frame body 3 through a portion indicated by the reference numeral 6. 3' is an opening in the lower frame 3, which is connected to the space inside the battery, and is the initial path for the gas inside the battery. Reference numeral 5' denotes a frontage of the upper frame 5, which is a space in which the flexible plate-shaped elastic body 1 can expand and deform outward, and also serves as a path for gas inside the battery discharged from the pinholes and cuts 2. The opening 3' of the lower frame 3 is smaller than the opening 5' of the upper frame 5, making it difficult for the flexible elastic plate 1 to deform into the battery.

本発明になる排気弁は以上のような構造であるから゛、
電池内の圧力が高くなったときには、柔軟な板状弾性体
1が外側へ膨張、変形してピンホールあるいは切れ口2
が開口して内部のガスを排出する。しかし電池内が減圧
となっても下部枠体3の開口部3′が小さいために、柔
軟な板状弾性体1はほとんど変形せず、したがってピン
ホールあるいは切れ口2は開口しないので、外気が電池
内へ侵入することを防ぐ。また間口部3′の大きさや形
状を適当に選択することにより、電池内の圧力が極めて
小さくなったときにはピンホールあるいは切れ口2が間
口して、その減圧状態を緩和して電槽の破損を防止する
ことができる。
Since the exhaust valve according to the present invention has the structure as described above,
When the pressure inside the battery increases, the flexible plate-like elastic body 1 expands and deforms outward, creating a pinhole or cut 2.
opens and discharges the gas inside. However, even if the pressure inside the battery is reduced, the opening 3' of the lower frame 3 is small, so the flexible plate-like elastic body 1 hardly deforms, and therefore the pinhole or cut 2 does not open, so the outside air Prevent it from entering the battery. In addition, by appropriately selecting the size and shape of the opening 3', when the pressure inside the battery becomes extremely low, a pinhole or cut 2 will open, which will alleviate the reduced pressure and prevent damage to the battery case. It can be prevented.

厚さ0,5n+mのブヂルゴムシートにピンホールを1
ケあけて板状弾性体1どし、下部枠体3の開口部3′を
直径2mll1の円形、上部枠体5の開口部5′を直径
4Iの円形とした排気弁について、内外の圧力差と出入
りするガス量との関係をめて第2図に示ず。なお、この
図では、負の圧力は内部が減圧、負のガス量は外部から
の内部への侵入を意味している。図から明らかなように
、内部が加圧状態になると、約0.2気圧で弁が作動す
るが、減圧になった場合には、約0.6気圧にならない
と外部のガスは内部へ侵入しない。
One pinhole is made in a Butil rubber sheet with a thickness of 0.5n+m.
For an exhaust valve in which the plate-like elastic bodies 1 are opened, the opening 3' of the lower frame 3 is circular with a diameter of 2 ml1, and the opening 5' of the upper frame 5 is circular with a diameter of 4I, the pressure difference between the inside and outside is determined. The relationship between this and the amount of gas flowing in and out is not shown in Figure 2. In this figure, negative pressure means reduced pressure inside, and negative gas amount means intrusion into the inside from the outside. As is clear from the figure, when the inside is pressurized, the valve operates at about 0.2 atm, but when the pressure is reduced, the external gas has to reach about 0.6 atm before the outside gas enters the inside. do not.

第1図の本発明実施例においては、電池蓋への装着部を
有する下部枠体3で柔軟な板状弾性体1を支持するもの
を示したが、電池蓋の上面を利用して板状弾性体1を支
持させ、下部枠体3を省略してもよい。
In the embodiment of the present invention shown in FIG. 1, the flexible plate-shaped elastic body 1 is supported by the lower frame 3 having a mounting part for the battery lid. The elastic body 1 may be supported and the lower frame body 3 may be omitted.

なお、電池内のガスは板状弾性体1のピンホールや切れ
目2を通してのみ移動することが重要であって、板状弾
性体1と下部枠体3または上部枠体5との間から電池内
のガスや外気が出入りしてはならない。
It is important that the gas inside the battery moves only through the pinholes and cuts 2 in the elastic plate 1, and the gas inside the battery moves from between the elastic plate 1 and the lower frame 3 or the upper frame 5. No gas or outside air should be allowed to enter or exit.

柔軟な板状弾性体1が内部へ膨張、変形し難くするには
図示したように、枠体の開口部の面積について、下部枠
体のそれを上部枠体のそれよりも小さくすることのほか
に、板状弾性体1の下面にピンホールや切れ口2を閉塞
しないような格子状あるいは網状などの支持体を設けて
もよい。
In order to make it difficult for the flexible plate-like elastic body 1 to expand and deform inward, as shown in the figure, the area of the opening of the frame is made smaller than that of the upper frame. In addition, a grid-like or net-like support may be provided on the lower surface of the plate-like elastic body 1 so as not to block the pinholes or the cuts 2.

以上述べたことから明らかなように本発明による排気弁
は、小形でかつ電池内が減圧状態となっても外気が電池
内に侵入せず、信頼性が高いなどのすぐれた利点を有す
るものである。
As is clear from the above, the exhaust valve according to the present invention has excellent advantages such as being small, preventing outside air from entering the battery even when the battery is under reduced pressure, and being highly reliable. be.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明鉛蓄電池用排気弁の一実施例を示す要部
縦断面図、第2図は本発明鉛蓄電池用排気弁の内外の圧
力差と排出ガスmとの関係を示す特性図である。 1・・・板状弾性体、2・・・ピンホールまたは切れ目
、3・・・下部枠体、3′・・・間口部、5・・・上部
枠体、5′・・・開口部
FIG. 1 is a longitudinal cross-sectional view of a main part showing an embodiment of an exhaust valve for a lead-acid battery according to the present invention, and FIG. 2 is a characteristic diagram showing the relationship between the pressure difference between the inside and outside of the exhaust valve for a lead-acid battery according to the present invention and the exhaust gas m. It is. DESCRIPTION OF SYMBOLS 1... Plate-shaped elastic body, 2... Pinhole or cut, 3... Lower frame body, 3'... Frontage part, 5... Upper frame body, 5'... Opening part

Claims (1)

【特許請求の範囲】[Claims] (1)ある限度を越えて膨張、変形したときに開口する
ピンホールまたは切れ目を有する板状弾性体の周囲を支
持部で気密に保持し、該板状弾性体を外側に対して内側
よりも膨張、変形しやすい構造どした鉛蓄電池用排気弁
。 〈2)板状弾性体が膨張、変形しうる外側間口部を内側
開口部よりも広くした支持部を有する特許請求の範囲第
(1)項に記載の鉛蓄電池用排気弁。
(1) A supporting part is used to airtightly hold the periphery of a plate-shaped elastic body that has pinholes or cuts that open when expanded or deformed beyond a certain limit, and the plate-shaped elastic body is held on the outside more than on the inside. Exhaust valve for lead-acid batteries with a structure that easily expands and deforms. (2) The exhaust valve for a lead-acid battery according to claim (1), which has a support portion in which an outer opening in which the plate-like elastic body can expand and deform is wider than an inner opening.
JP59012551A 1984-01-25 1984-01-25 Exhaust valve for lead storage battery Pending JPS60157156A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59012551A JPS60157156A (en) 1984-01-25 1984-01-25 Exhaust valve for lead storage battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59012551A JPS60157156A (en) 1984-01-25 1984-01-25 Exhaust valve for lead storage battery

Publications (1)

Publication Number Publication Date
JPS60157156A true JPS60157156A (en) 1985-08-17

Family

ID=11808463

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59012551A Pending JPS60157156A (en) 1984-01-25 1984-01-25 Exhaust valve for lead storage battery

Country Status (1)

Country Link
JP (1) JPS60157156A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008111356A1 (en) * 2007-03-09 2008-09-18 Asahi Rubber Inc. Excessive pressure relief valve, and relief valve unit having the relief valve

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5821957B2 (en) * 1978-04-01 1983-05-04 川崎製鉄株式会社 Surface oil for protection of surface-treated steel sheets

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5821957B2 (en) * 1978-04-01 1983-05-04 川崎製鉄株式会社 Surface oil for protection of surface-treated steel sheets

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008111356A1 (en) * 2007-03-09 2008-09-18 Asahi Rubber Inc. Excessive pressure relief valve, and relief valve unit having the relief valve
JPWO2008111356A1 (en) * 2007-03-09 2010-06-24 株式会社朝日ラバー Overpressure release valve and release valve unit having the same
JP5111490B2 (en) * 2007-03-09 2013-01-09 株式会社朝日ラバー Overpressure release valve and release valve unit having the same
US8443840B2 (en) 2007-03-09 2013-05-21 Asahi Rubber Inc. Excessive pressure release valve and release valve unit having the release valve

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